ALBERT

Description: Observation‐based quantification of ocean carbon dioxide (CO 2 ) uptake relies on synthesis data sets such as the Surface Ocean CO 2 ATlas (SOCAT). However, the data collection effort has dramatically declined and the number of annual data sets in SOCATv2023 decreased by ∼35% from 2017 to 2021. This decline has led to a 65% increase (from 0.15 to 0.25 Pg C yr −1 ) in the standard deviation of seven SOCAT‐based air‐sea CO 2 flux estimates. Reducing the availability of the annual data to that in the year 2000 creates substantial bias (50%) in the long‐term flux trend. The annual mean CO 2 flux is insensitive to the seasonal skew of the SOCAT data and to the addition of the lower accuracy data set available in SOCAT. Our study highlights the need for sustained data collection and synthesis, to inform the Global Carbon Budget assessment, the UN‐led climate negotiations, and measurement, reporting, and verification of ocean‐based CO 2 removal projects. Plain Language Summary The Surface Ocean CO 2 ATlas (SOCAT) data set plays a crucial role in estimating the ocean carbon sink component of the Global Carbon Budget. However, the number of data sets available in SOCAT each year has drastically decreased since 2017. This study shows that the uncertainty in the data‐based ocean CO 2 flux estimate has increased by 65% due to this decline in data availability. The estimated fluxes, especially the long‐term flux trend, are remarkably affected by the data availability in SOCAT, reducing the reliability of ocean CO 2 uptake estimates in years and regions with sparse observations. Key Points Lower surface ocean f CO 2 data availability leads to higher uncertainty in data‐based estimates of ocean CO 2 uptake The long‐term trend in the ocean CO 2 flux increases by 1.5 times for subsequent years if the data availability is reduced to that in 2000 The annual mean CO 2 flux is not sensitive to the seasonal skew in the data and to the addition of low accuracy data

Description: In order not to significantly overshoot maximum levels of warming like the 1.5 and 2°C target we must stay within a fixed emissions budget. How to fairly distribute the entitlements to emit within such a budget is perhaps the most intensely discussed question in all of climate justice. In our review we discuss the most prominent proposals in moral and political philosophy on how to solve this question and put a special emphasis on scholarly contributions from the last decade. We canvass the arguments for and against emissions egalitarianism, emissions sufficientarianism, and emissions grandfathering as well as the debates surrounding them. These are how to deal with non‐compliance, how to split emissions between producers and consumers, how to best account for terrestrial carbon sinks, and whether emissions from having children should be subtracted from parents' emissions budgets. From the viewpoint of justice, it matters not only that we act against climate change but also how we do so. This review aims to elucidate one of the major ways in which our reaction to climate change could be just or unjust.

Description: Freshwater input from Greenland ice sheet melt has been increasing in the past decades from warming temperatures. To identify the impacts from enhanced meltwater input into the subpolar North Atlantic from 1997 to 2021, we use output from two nearly identical simulations in the eddy-rich model VIKING20X (1/20°) only differing in the freshwater input from Greenland: one with realistic interannually varying runoff increasing in the early 2000s and the other with climatologically (1961–2000) continued runoff. The majority of the additional freshwater remains within the boundary current enhancing the density gradient toward the warm and salty interior waters yielding increased current velocities. The accelerated boundary current shows a tendency to enhanced, upstream shifted eddy shedding into the Labrador Sea interior. Further, the experiments allow to attribute higher stratification and shallower mixed layers southwest of Greenland and deeper mixed layers in the Irminger Sea, particularly in 2015–2018, to the runoff increase in the early 2000s. Key Points The West Greenland Current (WGC) freshens and cools with the observed recent increase in meltwater runoff from Greenland The density gradient across the boundary current intensifies, strengthening the WGC and increasing local eddy formation Enhanced meltwater runoff contributed to an eastward shift in deep convection towards the Irminger Sea (2015–2018) Plain Language Summary Global warming has accelerated the melting of the Greenland ice sheet over the past few decades resulting in enhanced freshwater input into the North Atlantic. The additional freshwater can potentially inhibit deep water formation and have future implications on ocean circulation. To determine the influence from Greenland melt, we compare two high-resolution model experiments all with the same forcing but differing input of Greenland freshwater fluxes from 1997 to 2021. We find that in the experiment with realistically increasing Greenland meltwater, the water becomes fresher and cooler along the continental shelf and boundary of the subpolar gyre. The density difference between the shelf and interior increases with more freshwater, resulting in faster West Greenland Current speeds and enhanced eddy formation. Deeper mixed layers are found in the eastern Irminger Sea, particularly in 2015–2018. From 2009 to 2013, there were shallower mixed layers in the Labrador Sea where less Greenland meltwater was mixed downwards and spread eastward, causing mixed layers to deepen in the Irminger Sea.

Description: The potential for future earthquakes on faults is often inferred from inversions of geodetically derived surface velocities for locking on faults using kinematic models such as block models. This can be challenging in complex deforming zones with many closely spaced faults or where deformation is not readily described with block motions. Furthermore, surface strain rates are more directly related to coupling on faults than surface velocities. We present a methodology for estimating slip deficit rate directly from strain rate and apply it to New Zealand for the purpose of incorporating geodetic data in the 2022 revision of the New Zealand National Seismic Hazard Model. The strain rate inversions imply slightly higher slip deficit rates than the preferred geologic slip rates on sections of the major strike‐slip systems including the Alpine Fault, the Marlborough Fault System and the northern part of the North Island Fault System. Slip deficit rates are significantly lower than even the lowest geologic estimates on some strike‐slip faults in the southern North Island Fault System near Wellington. Over the entire plate boundary, geodetic slip deficit rates are systematically higher than geologic slip rates for faults slipping less than one mm/yr but lower on average for faults with slip rates between about 5 and 25 mm/yr. We show that 70%–80% of the total strain rate field can be attributed to elastic strain due to fault coupling. The remaining 20%–30% shows systematic spatial patterns of strain rate style that is often consistent with local geologic style of faulting. Plain Language Summary The potential for future earthquakes on faults is often inferred from velocities of the ground surface derived from satellite geodesy, but this approach can be challenging in complex deforming zones with many closely spaced faults. We present a new methodology for estimating the rate at which energy is accumulating on faults using measurements of surface strain rates. The method is applied to New Zealand for the purpose of incorporating geodetic data in the 2022 revision of the New Zealand National Seismic Hazard Model. We show that 70%–80% of the total deformation field can be attributed to energy accumulation on known active faults while the source of the remaining 20%–30% remains unknown. Along some of the major faults in New Zealand we find some important differences in rates of energy accumulation from what is expected from geologic data. Estimated rates are significantly lower than even the lowest geologic estimates on some faults in the fault system near highly‐populated Wellington. Key Points We develop a method to invert geodetically derived strain rates for slip deficit rates on faults We find small but systematic differences between slip deficit rates and geologic slip rates About 70%–80% of the surface strain can be attributed to elastic strain due to coupling on faults

Description: Oceanic detachment faulting, a major mode of seafloor accretion at slow and ultraslow spreading ridges, is thought to occur during magma‐poor phases and be abandoned when magmatism increases. In this framework, detachment faulting is the result of temporal variations in magma flux, which is inconsistent with recent geophysical observations at the Longqi segment on the Southwest Indian Ridge (49°42′E). In this paper, we focus on this sequentially active detachment faulting system that includes an old, inactive detachment fault and a younger, active detachment fault. We investigate the mechanisms controlling the temporal evolution of this tectonomagmatic system by using 2D mid‐ocean ridge spreading models that simulate faulting and magma intrusion into a visco‐elasto‐plastic continuum. Our models show that temporal variations in magma flux alone are insufficient to match the inferred temporal evolution of the sequentially active detachment system. Rather we find that sequentially active detachment faulting spontaneously occurs at the Longqi segment as a function of lithospheric thickness. This finding is in agreement with an analytical model, which shows that a thicker axial lithosphere results in a smaller fault heave and that a flatter angle in lithosphere thickening away from the accretion axis stabilizes the active fault. A thicker axial lithosphere and its flatter off‐axis angle combined have the potential to modulate sequentially active detachment faulting at the Longqi segment. Our results thus suggest that temporal changes of magmatism are not necessary for the development and abandonment of detachment faults at ultraslow spreading ridges.

Description: Mesoscale eddies are common in the subtropical Northwest Pacific, however, relatively little is known about their spatial variability and temporal evolution, and how these impact upper ocean biogeochemistry. Here we investigate these using observations of a cyclonic eddy carried out along four sequential transects. Consistent with previous observations of cyclonic eddies, the eddy core had doming isopycnals, bringing elevated nutrient waters nearer to the surface. However, we also found that the upper layer of the eddy above the nutricline had significantly lower phosphate concentrations within its core relative to its edge. We attributed this to elevated N 2 fixation within the eddy core, which was likely driven by enhanced subsurface iron supply, ultimately resulting in increased phosphate consumption. Eddy‐enhanced N 2 fixation was additionally supported by the elevation of nitrate + nitrite to phosphate ratios below the euphotic zone. Moreover, we observed that while the upward displacement of isopycnals within the eddy core led to an increase in phytoplankton biomass in the lower euphotic zone, there was no significant increase in total phytoplankton biomass across the entire euphotic zone. Cyclonic eddies in the subtropical North Pacific are projected to be becoming more frequent, implying that such dynamics could become increasingly important for regulating nutrient biogeochemistry and ultimately productivity of the region. Key Points Lower phosphate concentrations were observed above the nutricline within the eddy core in comparison to the edge Enhanced N2 fixation within the eddy core is proposed to have driven increased phosphate consumption No substantial total phytoplankton biomass increase was found within the eddy core

Description: Scientific Significance Statement Millions of predator–prey interactions between deep-diving toothed whales and cephalopods occur daily in the dark deep sea. While predatory whales developed traits to detect and hunt their prey, cephalopods had to expand their anti-predatory strategies specialized for visual predators, to counteract acoustic predators. Since toothed whale-cephalopod interactions have never been directly observed in the deep sea, it remains unknown what selective pressures and traits evolved from this arms race. Combining current knowledge, we formalize four hypotheses and associated research approaches that will guide future investigation on oceanic predator–prey systems. We identify whale echolocation as an unprecedented armament to hunt distant prey and propose that deep-sea squids avoid acoustic predators by (1) reducing their acoustic cross-section through body shape and posture, (2) deep-sea migration, and (3) not schooling. Toothed whale predation emerges as a potential driver of the cephalopod live-fast-die-young strategy—which may now leave cephalopods at competitive advantage under global change.

Description: Aims Within the intensively‐studied, well‐documented latitudinal diversity gradient, the deep‐sea biodiversity of the present‐day Norwegian Sea stands out with its notably low diversity, constituting a steep latitudinal diversity gradient in the North Atlantic. The reason behind this has long been a topic of debate and speculation. Most prominently, it is explained by the deep‐sea glacial disturbance hypothesis, which states that harsh environmental glacial conditions negatively impacted Norwegian Sea diversities, which have not yet fully recovered. Our aim is to empirically test this hypothesis. Specific research questions are: (1) Has deep‐sea biodiversity been lower during glacials than during interglacials? ( 2) Was there any faunal shift at the Mid‐Brunhes Event (MBE) when the mode of glacial–interglacial climatic change was altered? Location Norwegian Sea, deep sea (1819–2800 m), coring sites MD992277, PS1243, and M23352. Time period 620.7–1.4 ka (Middle Pleistocene–Late Holocene). Taxa studied Ostracoda (Crustacea). Methods We empirically test the deep‐sea glacial disturbance hypothesis by investigating whether diversity in glacial periods is consistently lower than diversity in interglacial periods. Additionally, we apply comparative analyses to determine a potential faunal shift at the MBE, a Pleistocene event describing a fundamental shift in global climate. Results The deep Norwegian Sea diversity was not lower during glacial periods compared to interglacial periods. Holocene diversity was exceedingly lower than that of the last glacial period. Faunal composition changed substantially between pre‐ and post‐MBE. Main conclusions These results reject the glacial disturbance hypothesis, since the low glacial diversity is the important precondition here. The present‐day‐style deep Norwegian Sea ecosystem was established by the MBE, more specifically by MBE‐induced changes in global climate, which has led to more dynamic post‐MBE conditions. In a broader context, this implies that the MBE has played an important role in the establishment of the modern polar deep‐sea ecosystem and biodiversity in general.

Description: The marine cyanobacterium Trichodesmium has the remarkable ability to interact with and utilize air‐borne dust as a nutrient source. However, dust may adversely affect Trichodesmium through buoyancy loss and exposure to toxic metals. Our study explored the effect of desert dust on buoyancy and mortality of natural Red Sea puff‐shaped Trichodesmium thiebautii . Sinking velocities and ability of individual colonies to stay afloat with increasing dust loads were studied in sedimentation chambers. Low dust loads of up to ∼400 ng per colony did not impact initial sinking velocity and colonies remained afloat in the chamber. Above this threshold, sinking velocity increased linearly with the colony dust load at a slope matching prediction based on Stoke's law. The potential toxicity of dust was assessed with regards to metal dissolution kinetics, differentiating between rapidly released metals, which may impact surface blooms, and gradually released metals that may impact dust‐centering colonies. Incubations with increasing dust concentrations revealed colony death, but the observed lethal dose far exceeded dust concentrations measured in coastal and open ocean systems. Removal of toxic particles as a mechanism to reduce toxicity was explored using SEM‐EDX imaging of colonies incubated with Cu‐minerals, yet observations did not support this pathway. Combining our current and former experiments, we suggest that in natural settings the nutritional benefits gained by Trichodesmium via dust collection outweigh the risks of buoyancy loss and toxicity. Our data and concepts feed into the growing recognition of the significance of dust for Trichodesmium 's ecology and subsequently to ocean productivity. Plain Language Summary Trichodesmium spp. are abundant cyanobacteria, forming extensive blooms in low latitude warm oceans, and contribute significantly to carbon (C) and nitrogen (N) fixation, recycling and export. Desert dust deposited on the ocean surface was shown to supply Trichodesmium with the scarce micronutrient iron. Spherical, millimeter‐sized colonies of Trichodesmium from different ocean basins were reported to actively accumulate dust in their cores. While dust accumulation likely helps Trichodesmium obtain nutrients, it may come at a cost. Metals released from dust may induce toxicity and the dust weight could send Trichodesmium to the ocean depth. Our experimental study with natural Red Sea colonies examined some trade‐offs of dust accumulation. Links between dust load and colony buoyancy were examined in sedimentation experiments. Toxicity thresholds for surface blooms and dust‐accumulating colonies were determined from mortality assays and dust dissolution measurements. We found that metal‐induced toxicity to Trichodesmium is unlikely at typical oceanic dust fluxes, and that dust‐containing colonies can remain buoyant. At high loads, dust weight determined the colony's sinking velocity. Our findings and concepts can be extended to additional aerosols and Trichodesmium ‐rich habitats, and may assist in assessing Trichodesmium 's distribution, ecophysiology, and contribution to C or N transport to the deep ocean. Key Points Dust collected by Trichodesmium colonies from seawater as a nutrient source may result in metal toxification and buoyancy loss At moderate dust loads, colonies kept their buoyancy, but above 400 ng, sinking velocities increased linearly with dust loads Desert dust induced Trichodesmium mortality through toxic metal release, yet the lethal dose far exceeded oceanic dust concentrations

Description: Every piece of plastic is made up of a unique combination of the host polymer, with some residual monomers or catalysts, as well as chemical additives added during processing of the plastic. This chapter aims to introduce plastic additives with a focus on their chemistry and function, transport and fate, detection in marine environments, and toxicities. The extensive list of additives can be simplified by dividing the types of additives into three groups: functional additives, colorants, and fillers/reinforcements. Plasticizers are added to plastics to improve their flexibility, durability, and elasticity over a broad range of temperatures while also reducing the glass transition temperature and the melt flow. Additives are well known to leach from plastics in the marine environment. Like their plastic counterparts, plastic additives are also susceptible to oxidative degradation and biodegradation. The toxicity of plastic additives is quite variable given the diversity of their chemical classes.