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  • fluids
  • Elsevier  (3)
  • International Union of Crystallography (IUCr)
  • 2020-2024  (3)
  • 1
    Publikationsdatum: 2023-02-02
    Beschreibung: We analyzed from meso-to microscale the chemical interaction (e.g., bleaching) between deep fluids and carbonate rocks in pelagic limestones exposed along the seismically active Gubbio normal fault (Northern Apennines), exhumed from ca. 2 km depth. Bleaching is enhanced by the exploitation of inherited stylolitic seams by fluids and is favored by the progressive leaching and mobilization of primary components (i.e., Ca, Fe, Pb, and Cu) and the precipitation of authigenic baryte due to temperature and/or redox potential contrast. Analysis of fluid inclusions trapped in calcite veins in the damage zone precipitated from a H2O–NaCl-bearing fluid(s), with low salinity (1.22–2.57 wt%NaCleq) and a range of trapping temperature between 107 ◦C and 185 ◦C, higher than the host rock peak T conditions. Analysis of fluid inclusions and noble gases from syn-kinematic calcite and mineralogy of altered rocks suggests a mixed contribution between crustal-derived fluids with diagenetic fluids containing sulphates and CO2. We speculate that bleaching is a by-product of the circulation of such aggressive fluids with mixed contributions, likely mobilized during seismic event(s) and injected into the damage zone at shallow depths. Such processes, affecting the chemical-physical properties of limestones, are generally underestimated and should be considered when modelling hydraulic connectivity in fractured carbonate reservoirs.
    Beschreibung: Published
    Beschreibung: 104668
    Beschreibung: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Beschreibung: JCR Journal
    Schlagwort(e): fluids ; eartquakes ; Gubbio Fault ; noble gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2023-04-04
    Beschreibung: With the aim of deepening our understanding of deep-seated fluids upwelling and mixing in large regional aquifers, we performed a hydrogeochemical study of twenty-two springs in the Contursi area (upper Sele river valley, southern Apennines) by means of the measurements of chemical-physical parameters, major ions, trace elements, and stable and radioactive isotopes. Besides, we realized two updated geo-structural cross-sections inorder to reconstruct the groundwater flowpath in the study area. The hydrogeochemical composition, as well a the water temperature allow to identify-three main groups of groundwater: Cold and Low salinity Groundwater (CLGW), Intermediate Salinity Groundwater (ISGW), and Thermal Salinity Groundwater (TSGW). The CLGW group, mostly emerging at the boundary of carbonate aquifers, is characterized by alkaline earth-bicarbonate hydrofacies. Instead, ISGW and TSGW, situated in the inner zone of the valley, show gradually a hydrogeochemical evolution towards sodium-chloride type hydrofacies domain with the highest salinity value. Stable isotope (δ18O-δD) of CLGW reveal the local meteoric origin of groundwater, while isotopic signatures of ISGW and TSGW is associated with the deep fluids inflow. CLGW hydrogeochemistry is clearly related to dissolution of carbonate rocks. On the other hand, for ISGW and TSGW an additional contribution from evaporitic rocks is supported by saturation indices values (gypsum and anhydrite) and validated by isotopic signature of dissolved sulphate (δ34S-δ18O). The application of two models based on tritium data (i.e., the piston-flow and well-mixed reservoir) attributes longer and deeper groundwater flowpaths to TSGW. Through geothermometric calculations (e,g., K-Mg and SiO2-quartz), the equilibrium temperature of deep fluids reservoir is also extrapolated (i.e., 75–96 ◦C). The results of the adopted hydrogeochemical multi-component approach allowed us to propose an interpretative model of groundwater flowpath for the Contursi area, where deep-seated tectonic discontinuities play a significant role for the upwelling of saline deep thermal fluids in shallow aquifers.
    Beschreibung: Published
    Beschreibung: 129258
    Beschreibung: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Beschreibung: JCR Journal
    Schlagwort(e): fluids ; earthquakes ; crust ; geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2024-01-22
    Beschreibung: The Tibetan Plateau is growing by both vertical uplift and horizontal extension. It is a continuing debate how the Tibetan Plateau interacts with its surrounding plates and blocks. Due to intense tectonic activity, which produced catastrophic earthquakes, the tectonic zone between the northeast margin of the horizontal extending Tibetan Plateau and the stable Ordos Block has garnered considerable interest. This study investigated the spatial distribution of gas geochemical anomalies (e.g., high flux of CO2 in correspondence of the main faults) at regional scale together with the seismic tomography in correspondence of this tectonic zone with the aim to figure out the domain of convergent boundary between the Ordos block and Tibetan plateau, and trace the tectonic discontinuities which are able to transfer fluids through the crustal layers between the two main geological units. From northwest to southeast, obvious difference of spatial distributions of geochemical and geophysical features in the tectonic zone between the northeast margin of the Tibetan Plateau and the Ordos Block is inferred. The northeast area (Zone A) is dominated by thrust and strike-slip faults with clear velocity boundary underneath, where low crack density (ε), saturation rate (ξ) and Poisson’ ratio (σ) in the middle-lower crust coincided with the low values of heat flow and CO2 emissions, tectonic compression and regional locked-fault can be inducements. The southeast area (Zone C) is dominated by extensional tectonics with roughly E-W fast-velocity direction (FVD) of P-wave azimuthal anisotropy, where high permeability and porosity can be deduced from crustal high ε, ξ and relatively high σ anomalies, resulting in high heat flow, CO2 concentrations and fluxes at the surface, and predominantly crustal-derived gases. The intermediate area (Zone B) also dominated by thrust and strike-slip faults is an extraordinary zone, where intensely locked-fault were clearly revealed, while the predominant anisotropic FVDs in the middle crust changed obviously, more contribution of shallow gas component was detected, and CO2 flux, heat flow, and regional ε, ξ, and σ in the upper crust were higher, compared with those in Zone A, which indicated the regional crushing fragmentation underneath Zone B. The adopted multidisciplinary approach demonstrated that Zone B is the convergent boundary between the Tibetan Plateau and the Ordos Block.
    Beschreibung: Published
    Beschreibung: 121386
    Beschreibung: OST3 Vicino alla faglia
    Beschreibung: JCR Journal
    Schlagwort(e): fluids ; earthquakes ; helium ; Tibetan plateau
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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