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  • Polymer and Materials Science  (21,194)
  • Chemical Engineering  (3,294)
  • GEOPHYSICS  (3,293)
  • 1990-1994  (27,781)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 75-87 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wholly aromatic liquid crystalline main chain polyesters derived from terephthalic acid, phenyl- or (1-phenylethyl)hydroquinone modified with either 3,4′- or 4,4′-dicarboxydiphenylether and p-hydroxybenzoic acid, have been prepared by acidolysis and thermally investigated. All prepared polyesters exhibit excellent thermal stability up to about 400°C, however, the (1-phenylethyl)hydroquinone polyesters generally showed lower stability. Melting points could be decreased to around 200°C without any decrease in the thermal stability or the nematic range.
    Additional Material: 7 Ill.
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  • 2
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Soapless emulsion copolymerization of styrene (S) and n-butyl acrylate (BuA) has been investigated using two types of initiator and different comonomer feed mixtures. When using K2S2O8 as initiator, the particle size and size distribution of the final latexes (500 nm and 1.003, respectively) is not significantly affected by the comonomer feed composition, whereas the molecular weight and surface characteristics were found to sharply change at high butyl acrylate content. Based on the most probable particle nucleation mechanism and type of chain termination in the monomer swollen particles, a tentative explanation of these results has been proposed. Replacing persulfate by a carboxylic initiator (4-4′-azobiscyanopentanoic acid) results in the formation of stable particles as α observed with the persulfate, provided the aqueous phase pH is fixed in between 6 and 7. Results on the initiator residue location as a function of the conversion point out that the particle flocculation mechanism is strongly significant in the preparation of such latexes.
    Additional Material: 13 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 193-204 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction rates and products of remote oxygen plasma treatment, corona discharge, and ozone treatment of high and low density polyethylenes have been examined using x-ray photoelectron spectroscopy. The oxygen uptake by remote plasma treatment was faster than that of other surface treatments using excited oxygen species. A steady state concentration of 18 ± 1% oxygen can be attained within 1 s of exposure in the remote plasma.
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 231-243 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Due to the particular rheological properties of thermotropic liquid crystalline polymers (TLCP), their application for imaging technology has been investigated. The first class of polymers investigated in this study are the thermotropic liquid crystalline polycarbonates prepared from the solution polycondensation of p,p-dihydroxybiphenyl with bischloroformate as the aliphatic flexible spacer. From the variety of bischloroformates employed, smectic TLCP's were generally obtained with the possible presence of a nematic mesostate. The introduction of comonomers such as substituted hydroquinones or bisphenols were found to lower both the melting transitions and mesophasic range of the TLCP. From rheological characterization, the amount of nonmesogenic moieties present in the copolycarbonates were found to correlate with the increase in the melt viscosity of TLCP.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 285-298 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Homopolyesters based on bicyclo[2.2.2]oct-2-ene as a mesogenic group were prepared and characterized. The use of bicyclo[2.2.2]oct-2-ene in these homopolyesters lowered the symmetry of the resulting systems enough to lead to the observation of melting behavior.
    Additional Material: 14 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 323-331 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of new polyimides containing fluorinated alkoxy side chains are prepared from novel fluorinated alkoxy diamines. The dieletric constant at 1 kHz in the fluorinated polyimides decreases from 3.3 to 2.6 as fluorine content increases. The refractive index also changes from 1.58 to 1.48, dependent on the fluorine content. In addition, the fluorinated polyimides exhibit lower water absorption than the reference polyimides prepared from m-phenylenediamine.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 411-424 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The emulsion polymerization of vinyl acetate using potassium persulfate and cyclohexanone sodium bisulfite as redox pair initiation system was studied. The rate of polymerization, maximum conversion, and the number of polymer particles produced were found to change with redox initiator, monomer and emulsifier concentrations, and temperature variation. The rate of polymerization was found to be dependent on the initiator, the monomer, and the emulsifier concentrations to the 0.88, 0.22, and 0.20 powers, respectively. The K2S2O8-NaHSO3 redox system was found to decrease maximum conversion and doesn't form a stable emulsion. The apparent arrhenius activation energy (Ea) estimated for the polymerization system was 65.6 kJ/mol. The viscosity average molecular weights for some obtained poly(vinyl acetate) were determined.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 479-503 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preparation of a variety of silicon-containing epoxy monomers and oligomers is described and their reactivity in photoinitiated cationic polymerization examined. Monomers and oligomers having terminal cycloaliphatic epoxy groups were found to be especially reactive in cationic polymerization. These materials are attractive candidates for use in coatings, adhesives, and elastomers.
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 551-558 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Six new gem-dicyanocyclobutanes containing carbomethoxy and hydroxyl/acetoxy functions were synthesized by cycloaddition of the appropriate vinyl ethers or alkoxystyrenes to methyl β,β-dicyanoacrylate. They proved to be too thermally labile to allow polycondensation to potentially piezoelectric linear polyesters.
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 573-583 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-(Chloromethyl)oxetane was prepared in 8% overall yield from 2-propen-1-ol by protection of the alcohol with dihydropyran, epoxidation, ring expansion with dimethylsulfoxonium methylide, acid deprotection, and chlorination with triphenylphosphine in CCl4. 3-(Chloromethyl)oxetane was prepared in 22% overall yield by hydroboration-oxidation of 3-chloro-2-chloromethyl-1-propene followed by base-catalyzed cyclization. Each of the oxetanes was converted to the corresponding elastomeric homopolymer by treatment with a triethylaluminum-acetylacetone-water mixture. Poly[2-(chloromethyl)oxetane] was found to be similar to polyepichlorophydrin in reactivity toward benzoate ion, whereas poly[3-(chloromethyl)oxetane] is more reactive by a factor of 2.
    Additional Material: 1 Ill.
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