ALBERT

Description: The quantum yield and reaction threshold for the photochemical dissociation of cyanoacetylene into a hydrogen atom and the cyanoethynyl radical have been determined. The quantum yield at 185 nm is approximately 0.09. The threshold is approximately 240 nm. Combination of this data with literature values shows that production of excited-state cyanoacetylene is the major primary process resulting from irradiation between 185 and 254 nm. Also determined are the relative rate constants for the abstraction of a hydrogen atom from hydrogen, methane, and ethane by the cyanoethynyl radical (k(H2):k(CH4):k(C2H6) = 1:9.3:63). Implications of these results for the proposal that hydrogen abstraction plays an important role in the conversion of methane to ethane and in the protection of unsaturated compounds from photoconsumption in the atmosphere of Titan are discussed.

Description: The atmospheric flow on Io is numerically computed in a flat 2-D axisymmetric geometry for a sublimation atmosphere on the trailing hemisphere subjected to plasma bombardment, UV heating, and IR cooling. Calculations are performed for subsolar vapor pressures of approximately 6.5 x 10(exp -3) Pa (approximately 3 x 10(exp 18) SO2/sq cm) and 6.8 x 10(exp -4) Pa (approximately 4 x 10(exp 17) SO2/sq cm); the latter approximates the vapor pressure of F. P. Fanale et al. (1982). The amount of plasma energy deposited in the atmosphere is 20% of the plasma flow energy due to corotation (J. A. Linker et al., 1988). It is found that plasma heating significantly inflates the upper atmosphere, increasing both the exobase altitude and the amount of surface covered by more than an exospheric column of gas. This in turn controls the supply of the Io plasma torus (M. A. McGrath and R. E. Johnson, 1987). The horizontal flow of mass and energy is also important in determining the exobase altitude; and it is shown that IR cooling can be important, although our use of the equilibrium, cool-to-space approximation for a pure SO2 gas (E. Lellouch et al., 1992) may overestimate this effect. The calculated exobase altitudes are somewhat lower than those suggested by McGrath and Johnson (1987) for supplying the torus, indicating the details of the plasma energy deposition and sputter ejection rate near the exobase, as well as the IR emission from this region need to be examined. In addition, the molecules sublimed (or sputtered) from the surface are transported to the exobase in times short compared to the molecular photodissociation time. Therefore, the exobase is dominated by molecular species and the exobase is supplied by a small region of the surface.

Description: Iapetus shows a greater hemispheric albedo asymmetry than any other body in the solar system. Hapke scattering theory and optical constants measured in the laboratory are used to identify possible compositions for the dark material on the leading hemisphere of Iapetus. The materials considered are poly-HCN, kerogen, Murchison organic residue, Titan tholin, ice tholin, and water ice. Three-component mixtures of these materials are modeled in intraparticle mixture of 25% poly-HCN, 10% Murchison residue, and 65% water ice is found to best fit the spectrum, albedo, and phase behavior of the dark material. The Murchison residue and/or water ice can be replaced by kerogen and ice tholin, respectively, and still produce very good fits. Areal and particle mixtures of poly-HCN, Titan tholin, and either ice tholin or Murchison residue are also possible models. Poly-HCN is a necessary component in almost all good models. The presence of poly-HCN can be further tested by high-resolution observations near 4.5 micrometers.

Description: A thermal model that can be easily adapted to craters of arbitrary shape is developed and applied to high-latitude impact craters on Mercury and the Moon, Chao Meng Fu crater at -87.5 deg L on Mercury, an unnamed bowl-shaped crater at 86.7 deg L on Mercury, and Peary crater at 88.6 deg L on the Moon. For an assumed input topography and grid of surface elements, the model computes for each element the irradiation from direct insolation and reflected and emitted radiation from other elements, taking into account shadowing by walls of the crater, partial obscuration of the solar disk near the poles and the diurnal, orbital, and seasonal cycles. Temperatures are computed over the surface grid as functions of depth and time from the surface to a specified depth and over the pertinent astronomical cycles, including the effects of direct and indirect surface irradiation, infrared radiation, heat conduction, and interior heating. Vapor fluxes and ice recession times are computed as functions of ice depth over the surface grid. Temperatures profiles, vapor fluxes, and ice recession times were computed for flat surfaces not associated with craters near the poles of Mercury and the Moon. It was found that water ice could have existed throughout geologic time within the maximum radar detection depth of recent observation of Mercury (J. K. Harmon and M. A. Slade, 1992, Science 258, 640-643) poleward of approximately 87 - 88 deg L on Mercury and poleward of approximately 73 deg L on the Moon. For Chao Meng Fu crater it was found that approximately 40% of the crater floor is permanently shadowed from direct solar insolation, while the remainder of the crater floor is periodically illuminated by a partially obscured Sun. Temperatures at the upper levels of the south wall can slightly exceed 550 K. Surface temperatures in the permanently shadowed region of the crater floor are under approximately 130 K, which could have allowed water ice to exist throughout geologic time within the radar detection depth of recent observation of Mercury. For small bowl-shaped crater on Mercury, it was found that most of the crater is permanently shadowed from direct solar radiation, except for a narrow semicircular band bordering the north rim. However, temperatures in the permanently shadowed region periodically reach a maximum near approximately 315 K due to efficient heating of the small crater by thermal emission and reflection from the small sunlit region, which periodically reaches temperatures exceeding 630 K. Water ice could not have existed throughout geologic time anywhere in this crater within the radar detection depth. For Peary crater on the Moon, the entire crater floor is permanently shadowed from direct solar insolation with maximum temperature under 120 K. The upper level of the north wall periodically reaches a maximum temperature near 310 K. The low temperatures on the crater floor would have allowed water ice to exist near the surface throughout geologic time, provided that the Moon's obliquity was always as low as it is at present.

Description: We examine the effects of the loss of Mars atmospheric constituents by solar-wind-induced sputtering and by photochemical escape during the past 3.8 billion years. Sputtering is capable of efficiently removing species from the upper atmosphere, including the light noble gases; nitrogen and oxygen are removed by photochemical processes as well. Due to diffusive separation (by mass) above the homopause, removal from the top of the atmosphere will fractionate the isotopes of each species, with the lighter mass being preferentially lost. For carbon and oxygen, this allows us to determine the size of nonatmospheric reservoirs which mix with the atmosphere; these reservoirs can be CO2 adsorbed in the regolith and H2O in the polar ice caps. We have constructed both simple analytical models and time-dependent models of the loss of volatiles from and supply to the martian atmosphere. Both argon and neon require continued replenishment from outgassing over geologic time. For argon, sputtering loss explains the fractionation of (Ar-36)/(Ar-38) without requiring a distinct epoch of hydrodynamic escape (although fractionation of Xe isotopes still requires very early hydrodynamic loss). For neon, the current (Ne-22)/(Ne-20) ratio represents a balance between loss to space and continued resupply from the interior; the similarity of the ratio to the terrestrial value is coincidental. For nitrogen, the loss by both sputtering and photochemical escape would produce a fractionation of (N-15)/(N-14) larger than observed; an early, thicker carbon dioxide atmosphere could mitigate the nitrogen loss and produce the observed fractionation, as could continued outgassing of juvenile nitorgen. Based on the isotopic constraints, the total amount of carbon dioxide lost over geologic time is probably on the order of tens of millibars rather than a substantial fraction of a bar. The total loss from solar-wind-induced sputtering and photochemical escape, therefore, does not seem able to explain the loss of a putative thick, early atmosphere withput requiring formation of extensive surface carbonate deposits or other nonatmospheric reservoirs for CO2.

Description: We prospose a new center and ring assignment for the original Chryse impact basin based upon photogeologic mapping of Noachian outcrops and re-examination of the published geology using orthographic projections. While others have centered the Chryse impact on the topographic low associated with Hesperian volcanic and fluvial deposits, we suggest that the center of the Noachian-age excavation cavity was located approximately 800 km to the north, and that the basin topography was modified significantly from the Noachian into the Hesperian. Evolution of the topographic low included structural modification by a later impact centered in Acidalia, restricted volcanic deposition and loading, localized subsidence, and restricted deposition from the circum-Chryse outlfow channels.

Description: Models for Venusian mountain belt formation are important for understanding planetary geodynamic mechanisms. A range of data sets at various scales must be considered in geodynamic modelling. Long wavelength data, such as gravity and geoid to topography ratios, need constraints from smaller-scale observations of the surface. Pre-Magellan images of the Venusian surface were not of high enough resolution to observe details of surface deformation. High-resolution Magellan images of Maxwell Montes and the other deformation belts allow us to determine the nature of surface deformation. With these images we can begin to understand the constraints that surface deformation places on planetary dynamic models. Maxwell Montes and three other deformation belts (Akna, Freyja, and Danu montes) surround the highland plateau Lakshmi Planum in Venus' northern hemisphere. Maxwell, the highest of these belts, stands 11 km above mean planetary radius. We present a detailed structural and kinematic study of Maxwell Montes. Key observations include (1) dominant structure fabrics are broadly distributed and show little change in spacing relative to elevation changes of several kilometers; (2) the spacing, wavelength and inferred amplitude of mapped structures are small; (3) interpreted extensional structures occur only in areas of steep slope, with no extension at the highest topographic levels; and (4) deformation terminates abruptly at the base of steep slopes. One implications of these observations is that topography is independent of thin-skinned, broadly distributed, Maxwell deformation. Maxwell is apparently stable, with no observed extensional collapse. We propose a 'deformation-from-below' model for Maxwell, in which the crust deforms passively over structurally imbricated and thickened lower crust. This model may have implications for the other deformation belts.

Description: We present the first maps of the apparent thermal inertia and albedo of the south polar region of Mars. The observations used to create these maps were acquired by the infrared thermal mapper (IRTM) instruments on the two Viking Orbiters over a 30-day period in 1977 during the Martian late southern summer season. The maps cover the region from 60 deg S to the south pole at a spatial resolution of 1 deg of latitude, thus completing the initial thermal mapping of the entire planet. The analysis and interpretation of these maps is aided by the results of a one-dimensional radiative convective model, which is used to calculate diurnal variations in surface and atmospheric temperatures, and brightness temperatures at the top of the atmosphere for a range of assumptions concerning dust optical properties and dust optical depths. The maps show that apparent thermal inertias of bare ground regions decrease systematically from 60 deg S to the south pole. In unfrosted regions close to the south pole, apparent thermal inertias are among the lowest observed anywhere on the planet. On the south residual cap, apparent thermal inertias are very high due to the presence of CO2 frost. In most other regions of Mars, best fit apparent albedos based on thermal emission measurements are generally in good agreement with actual surface albedos based on broadband solar reflectance measurements. The one-dimensional atmospheric model calculations also predict anomalously cold brightness temperatures close to the pole during late summer, and after considering a number of alternatives, it is concluded that the net surface cooling due to atmospheric dust is the best explanation for this phenomenon. The region of lowest apparent thermal inertia close to the pole, which includes the south polar layered deposits, is interpreted to be mantled by a continuous layer of aeolian material that must be at least a few millimeters thick. The low thermal inertias mapped in the south polar region imply an absence of surface water ice deposits, which is consistent with Viking Mars atmospheric water detector (MAWD) measurements which show low atmospheric water vapor abundances throughout the summer season.

Description: Venusian canali, outflow channels, and associated volcanic deposits resemble fluvial landforms more than they resmeble volcanic features on Earth and Mars. Some canali have meandering habits and features indicative of channel migration that are very similar to meandering river channels and flood plains on Earth, venusian outflow channels closely resemble water-carved outflow channels on Mars and the Channeled Scabland in Washington, collapsed terrains at the sources of some venusian channels resemble chaotic terrains at the sources of martian outflow channels, venusian lava deltas are similar to bird's-foot deltas such as the Mississippi delta, and venusian valley networks indicate sapping. We have developed an alternative possibility that the lava had a water-like rheology and a melting point slightly greater than Venus' surface temperature, thus accounting for the unusual behavior of the lava. Unlike silicate lavas, some carbonatites (including carbonate-sulfate-rich liquids) have these properties; thus they can flow great distances while retaining a high fluidity, significant mechanical erosiveness, and substantial capacity to transport and deposit sediment. Venusian geochemistry and petrology are consistent with extensive eruptions of carbonatite lavas, which could have crustal and/or mantle origins. Venus' atmosphere (especially CO2, HCl, and HF abundances) and rocks may be in local chemical equilibrium, which suggests that the upper crust contains large amounts of calcite, anhydrite, and other salts. Chemical analyses indicate, according to some models, that Venusian rocks may contain 4-19% calcite and anhydrite. Mixtures of crustal salts could melt at temperatures a few tens to a few hundred Kelvins higher than Venus' surface temperature; hence, melting may be induced by modest endogenetic or impact heating. Salts may have many of the same geologic roles on Venus as water and ice have on Mars. A molten salt (carbonatite) 'aquifer' may exist beneath a few hundred meters to several kilometers of solidified salt-rich 'permafrost.' Many geologic features can be explained by carbonatite magmatism: (1) impact melting of crustal salts can explain crater outflows, (2) small, sustained eruptions from molten salt aquifers can explain sapping valleys, (3) large, sustained eruptions may explain canali and their flood plans, and (4) catastrophic outbursts amy have formed outflow channels and chaotic terrain. Landforms created by carbonate-rich lavas would be thermally stable on Venus' surface, though some minerals may weather to other solid substances.

Description: We have analyzed high-resolution Magellan Doppler tracking data over Mead crater, using both line-of-sight and spherical harmonic methods, and have found a negative gravity anomaly of about 4-5 mgal (at spacecraft altitude, 182 km). This is consistent with no isostatic compensation of the present topography; the uncertainty in the analysis allows perhaps as much as 30% compensation at shallow dpeths (approximately 25 km). This is similar to observations of large craters on Earth, which are not generally compensated, but contrasts with at least some lunar basins which are inferred to have large Moho uplifts and corresponding positive Bouguer anomalies. An uncompensated load of this size requires a lithosphere with an effective elastic lithosphere thickness greater than 30 km. In order for the crust-mantle boundary not to have participated in the deformation associated with the collapse of the transient cavity during the creation of the crater, the yield strength near the top of the mantle must have been significantly higher on Earth and Venus than on the Moon at the time of basin formation. This might be due to increased strength against frictional sliding at the higher confining pressures within the larger planets. Alternatively, the thinner crusts of Earth and Venus compared to that of the Moon may result in higher creep strength of the upper mantle at shallower depths.

Description: The gravitational tidal response at the visible cloud level of Jupiter is obtained as a function of static stability in the planetary interior. It is suggested that confirmation of the presence of static stability in the planetary interior could be achieved by observing tidal fields at cloud level. We also calculate the mean flow acceleration induced by tidal fields and suggest that, if the interior is even marginally statically stable, the tides may provide the momentum source maintaining the alternating zonal jets observed at the cloud level of the planet.

Description: The formation of a large volcano loads the underlying lithospheric plate and can lead to lithospheric flexure and faulting. In turn, lithospheric deformation affects the stress field beneath and within the volcanic edifice and can influence magma transport. Modeling the interaction of these processes is crucial to an understanding of the history of eruption characteristics and tectonic deformation of large volcanoes. We develop models of time-dependent stress and deformation for the Tharsis volcanoes on Mars. By means of a finite element code, we calculate stresses and displacements due to a volcano-shaped load emplaced on an elastic plate overlying a viscoelastic mantle. Models variously incorporate growth of the volcanic load with time and a detachment between volcano and lithosphere. The models illustrate the manner in which time-dependent stresses induced by lithospheric plate flexure beneath the volcanic load may affect eruption histories, and the derived stress fields can be related to tectonic features on and surrounding Martian volcanoes. As a result of flexure there are three regions where stresses become sufficiently large to cause failure by faulting, according to the Mohr-Coulomb criterion: at the surface of the plate just outward of the volcano, near the base of the elastic lithosphere beneath the center of the volcano, and on the upper flanks of the volcano early in its growth history.

Description: We propose a quasigeostrophic, baroclinic model for heat transport within the interior of a stably stratified Jovian planet, based on motion in thin cylindrical annuli. Density decreases from the center outward and is zero at the surface of the planet. In the homogeneous case (no core), we find instability for the poles hotter than the equator, but not for the reverse. If the motion is bounded by an impenetrable core, instability occurs for both cases. Much of the behavior can be explained by analogy to conventional baroclinic instability theory. Motivated by our results, we explore a possible connection between the highly inclined rotation axis of Uranus and its anomalously low surface heat flux. We assume that the planets formed hot. Our conjecture is that heat was efficiently convected outwards by baroclinic instability in Uranus (with the poles hotter than the equator), but not in the other three Jovian planets. The surface temperature was higher for the stably stratified case (Uranus), leading to a higher rate of infrared emission and faster cooling. Therefore, we propose that Uranus lost its internal heat sooner than Neptune because baroclinic motions, permitted by its inclination to the sun, were able to extract its internal heat while the surface was still warm.

Description: Millimeter-wave observations of CO lines have provided a detailed picture of Venus' mesosphere dynamics in 1991 from simultaneous measurements of absolute wind velocities in two layers and of temperature and CO horizontal and vertical profiles at 75-115 km. Venus' circulation at 90-110 km was characterized in 1991 by the superposition of a zonal retrograde flow and a subsolar-to-antisolar flow of approximately equal velocities, increasing from about 40 +/- 15 m/sec at 95 km to 90 +/- 15 m/sec at 105 km altitude. The magnitude of the increase of the SS-AS flow is consistent with Venus thermosphere general circulation models (VTGCM). At 105 km, the data further indicate a cos(latitude) dependence of the zonal flow and marginally suggest the presence of a poleward meridional component of 35 +/- 30 m/sec. No obvious day-to-day variations of the circulation are evident in the data at the 20 m/sec level. Thermal profiles in the low-latitude region appear to be consistent with the Pioneer Venus nightside profile, except above 110 km, where they are somewhat colder. High-latitude warming is still found, but mid-latitudes appear to be colder than the equator. The atmosphere appears to be in cyclostrophic balance up to about 105 km. The horizontal distribution of CO on Venus' nightside is essentially uniform, both in latitude and in local time. This behavior agrees with VTGCM simulations in which the zonal flow velocity is prescribed to match the observations. Comparison with previous wind measurements indicates that the zonal flow experiences dramatic long-term variations. This variability, along with short-term fluctuations of the mesospheric zonal flow (evidenced by the variability in the O2 nightglow emissions), apparently controls the CO and O2 nightglow distributions. Gravity wave activity is a plausible mechanism that can drive these variations.

Description: The regions anitpodal to Mars' three largest impact basins, Hellas, Isidis, and Argyre, were assessed for evidence of impact-induced disrupted terrains. Photogeology and computer modeling using the Simplified Arbitrary Lagrangian Eulerian (SALE) finite element code suggest that such terrains could have been found by the Hellas impact. Maximum antipodal pressures are 1100 MPa for Hellas, 520 MPa for Isidis, and 150 MPa for Argyre. The results suggest that if antipodal fracturing were associated with later volcanism, then Alba Patera may be related to the Hellas event, as proposed by Peterson (1978). Alba Patera is a unique volcano in the solar system, being a shield volcano which emitted large volume lava flows. This volcanism could be the result of the focusing of seismic energy which created a fractured region that served as a volcanic conduit for the future release of large volumes of magma. No disrupted terrain features are observed antipodal to the Isidis or Argyre basins, although some of the old fractures in Noctis Labyrinthus could have originated in response to the Isidis impact, and later have been reactivated by the Tharsis tectonics assumed to have produced Noctis. If the lower calculated antipodal pressures for Argyre were capable of producing disrupted terrains, then the terrains have been covered subsequently by volcanic or aeolian material, or modified beyond recognition.

Description: Immediately after the flybys at comet Halley by a fleet of spacecraft in 1986, Gringauz et al. (1986a) reported the detection by the Vega-2 spacecraft of a chemical and sharp plasma boundary, which they named the 'cometopause,' at a distance of about 1.6 x 10(exp 5) km from the nucleus. Gringauz and Verigin (1991) presented the 'cometopause' as a permanent feature of the solar wind - Halley type comet interaction at about 1 UA from the Sun. This permanent boundary presumably separates an upstream region dominated by the solar wind from the downstream region where heavy cometary ions dominate. We present here the analysis of the results of the Giotto positive ion cluster composition analyzer - Reme plasma analyzer (PICCA-RPA2) ion mass spectrometer and electron electrostatic analyzer - Reme plasma analyzer (EESA-RPA1) electron spectrometer data, which clearly show that there is no such boundary at comet Halley.

Description: We have developed a comprehensive model to study the dynamics and energetics of the ionosphere of Titan. We solved the one-dimensional, time-dependent, coupled continuity and momentum equations for several ion species, together with single ion and electron energy equations, in order to calculate density, velocity, and temperature profiles. Calculations were carried out for several cases corresponding to different local times and configurations of the Titan-Saturn system. In our model the effects of horizontal magnetic fields were assumed to be negligible, except for their effect on reducing the electron and ion thermal conductivities and inhibiting vertical transport in the subram region. The ionospheric density peak was found to be at an altitude of about 1100 km, in accordance with earlier model calculations. The ionosphere is chemically controlled below an altitude of about 1500 km. Above this level, ion densities differ significantly from their chemical equilibrium values due to strong upward ion velocities. Heat is deposited in a narrow region around the ionospheric peak, resulting in temperature profiles increasing sharply and reaching nearly constant values of 800-1000 deg K for electrons and 300 deg K for ions in the topside, assuming conditions appropriate for the wake region. In the subram region magnetic correction factors make the electron heat conductivities negligible, resulting in electron temperatures increasing strongly with altitude and reaching values in the order of 5000 deg K at our upper boundary located at 2200 km. Ion chemical heating is found to play an important role in shaping the ion energy balance in Titan's ionosphere.

Description: To verify the quality and accuracy of Phobos-2 Imaging Spectrometer for Mars (ISM) spectra of Mars, we have performed comparisons with telescopic data obtained contemporaneously and which have spatial and spectral overlap with the ISM measurements. We find general agreement between the independently-calibrated data sets in terms of spectral shape and absorption band strength and position in the 0.77 to 0.93 micron overlap region. The telescopic data were scaled to the ISM reflectance values in this overlap region to yield new bright and dark region composite reflectance spectra from 0.40 to 3.14 microns. We ascribe the increase in band depth and overall spectral heterogeneity of the ISM data relative to previous telescopic observations to the more than order of magnitude increase in spatial resolution achieved by ISM from Martian orbit. Further increases in spatial resolution from future orbital imaging spectroscopic instruments can be expected to reveal even greater degrees of compositional and mineralogic diversity on Mars.

Description: The isotopic compositions of Mg, Ca, Ti, Cr, Zn, Sr, Ba, Nd, and Sm were measured in four relatively unaltered refractory inclusions from the Vigarano carbonaceous chondrite meteorite. Three of the inclusions (USNM 1623-2, 1623-3, and 1623-8) show similar Mg, Ca, Ti, and Cr isotopic compositions to those found in most inclusions in the Allende carbonaceous chondrite. This indicates that these Vigarano inclusions sampled the same isotopic reservoirs as the majority of the Allende inclusions that isotope signatures in the latter were not significantly modified by the secondary alteration that permeates most Allende inclusions. In contrast, inclusion 1623-5 has large deficits in Mg-26, Ca-48, and Ti-50 and small but distinct Cr-54, Zn-66, Sr-84, Ba-135, Ba-137, and Sm-144 anomalies. The magnitudes of these unusual anomalies in the refractory elements are within analytical uncertainty of those found in the Allende 'FUN" inclusion C1, yet 1623-5 has a very different bulk chemical composition from C1. The fact that 1623-5 and C1 have identical isotopic anomalies yet have significantly distinct major and trace element contents provide convincing evidence for the presence of isotopically distinct reservoirs in the early solar system.

Description: Statistics of witnessed and recovered meteorite falls found in Chinese historical texts for the period from 700 B.C. to A.D. 1920 are presented. Several notable features can be seen in the binned distribution as a function of time. An apparent decrease in the number of meteorite reports in the 18th century is observed. An excess of observed meteorite falls in the period from 1840 to 1880 seems to correspond to a similar excess in European data. A chi sq probability test suggest that the association between the two data sets are real. Records of human casualities and structural damage resulting from meteorite falls are also given. A calculation based on the number of casualty events in the Chinese meteorite records suggests that the probability of a meteroite striking a human is far greater than previous estimates. However, it is difficult to verify the accuracy of the reported casualty events.

Description: While primarily designed for radar studies of the Venus surface, the high effective isotropic radiated power (EIRP) from the Magellan spacecraft makes it an ideal transmitter for use in radio occultation measurements of the refractivity and absorptivity of the Venus atmosphere. Such experiments have been conducted involving transmissions at 2.3 GHz and 8.4 GHz (13 cm and 3.6 cm, respectively), during spacecraft ingress. Since the stability of the spacecraft transmitter is critical for accurately determining the Doppler shift and amplitude attenuation created as the ray penetrates the atmosphere, the spacecraft transmitter was locked to a 2.1 GHz uplink from a 70-meter DSN station which also received the signals. Because of the high directivity of the spacecraft antenna, and the significant ray bending in the deep Venus atmosphere, a spacecraft tracking maneuver was designed to keep the spacecraft antenna pointed in the direction of the refracted ray path back to Earth. This tracking maneuver, plus the high EIRP of the Magellan transmitter has yielded 3.6 cm refractivity and absorptivity profiles down to the 35 km altitude and 13 cm profiles down to the altitude of critical refraction (approximately 33 km). The statistical uncertainties in the derived profiles are significantly lower than those previously obtained, resulting in extremely accurate profiles of H2SO4 (g) abundance as discussed in an accompanying paper.

Description: A comprehensive study of Magellan Cycles 1 and 2 radar data from Venus reveals surface roughness and dielectric variations associated with fluidized ejecta blanket (FEB) craters that help illuminate styles of flow ejecta emplacement. This study develops new procedures of digital unit mapping and polygon-filling algorithms using Magellan synthetic aperture radar (SAR), altimetry, and radiometry data. These techniques allow the extraction of radiophysical information for FEB crater materials, nearby plains, and lava flows. Backscatter curve slopes of the FEBs studied here are consistent with surface textures that are transitional between a'a and pahoehoe-like. Average surface property values of ejecta units are relatively similar for a given crater, but are discernibly different from other craters. Individual crater ejecta reflectivity and emissivity values are relatively similar to those for the surrounding plains, which may suggest a link between plains material and ejecta dielectric properties. Increasing FEB roughness downflow are interpreted to be associated with more lava-like flows, while decreasing roughness are more similar to trends typical of gravity (pyroclastic-like or debris-like) flows. Most commonly, FEB crater flow materials exhibit transitions from proximal, lava/melt-like flow styles to distal, gravity flow-like styles. Some FEBs show more complicated behavior, however, or appear to be more dominated by dielectric differences downflow, as inferred from correlations between the data sets. Such transitions may result from changes in local topography or from overlapping of flow lobes during FEB emplacement.

Description: The temperature structure within the northern auroral region of Jupiter is studied by reanalyzing the Voyager 1/infrared interferometer and radiometer spectrometer (IRIS) spectra. The total measured excess infrared auroral zone emission (averaged over the IRIS field of view) in the hydrocarbon bands between 7 and 13 microns is found to be about 208 ergs/cm/s over an area of about 2 x 10(exp 18) sq cm with a resulting power output of 4 x 10(exp 13) W. In comparison, the total energy deposition by magnetospheric charged particles has been estimated on the basis of UV observations to range between 1 x 10(exp 13) and 4 x 10(exp 13) W over a comparable area. The large amount of radiated energy observed in the infrared may imply an additional heat source in the auroral regions (possibly Joule heating). A new set of thermal profiles of Jupiter's high-latitude upper atmosphere has also been derived. These profiles have a large temperature enhancement in the upper stratosphere and are constrained to reproduce the CH4 emission at 7.7 microns. The emission in the other hydrocarbon bands (C2H2 and C2H6) is found to depend on the depth to which the temperature enhancement extends, which further constrains the thermal profiles. This study shows that a large temperature enhancement in the upper stratosphere and lower thermosphere can explain the observed excess hydrocarbon emission bands; thus smaller variations in hydrocarbon abundances (between the high latitudes and the equatorial and middle latitudes) are required than has been assumed in previous models.

Description: Observations of (O I) 6300-A emission near Io have been obtained in 1990, 1991, and 1992 by the National Solar Observatory staff using the solar-stellar spectrography on the McMath-Pierce telescope at Kitt Peak. High-resolution spectra with a resolving power of about 1.2 x 10(exp 5) were obtained with an integration time of 10-15 min each. The viewing aperture for the observations was 5.2 arc sec x 5.2 arc sec centered on Io, with spatial resolution limited within this area by seeing conditions. Observations thus far have been reduced to obtain average brightness values over the aperture which range from approximately 200 to 1000 R for a number of different Io phase angles and Io system III longitudes. The (O I) 6300-A emission brightness exhibits an east-west asymmetry, where the average intensity for Io phase angles in the west (receding ansa) is 1.5 times brighter than in the east (approaching ansa). Similar east-west intensity ratios have also been observed for neutrals near Io and ions in the plasma torus for a number of other optical and ultraviolet emission lines which are excited by electron impact. In addition to the east-west asymmetry, the (O I) 6300-A emission brightness exhibits a strong dependence on the Io system III longitude angle, with a maximum value occurring in the range 200 deg +/- 50 deg. Earlier IUE observations of ultraviolet emission lines of O and S near Io obtained over a number of years have measured the east-west asymmetry, but the long IUE integration times of approximately 7-14 hours masked any detection of system III variability. For the (O I) 6300-A emission, the O(1D) state may be excited by electron impact of atomic oxygen and by electron impact dissociation of SO. The molecule SO may be present at the exobase or may be produced above the exobase as the dominant product of SO2 dissociation by electron impact. Preliminary assessment indicates that production of O(1D) by molecular dissociation may be more important. The (O I) 6300-A emission may therefore provide a remote signature for monitoring (1) the upward transport rates of molecular species in Io's atmosphere, (2) the relative abundance and time-variable dissociation of SO2 and/or SO at the exobase and in the corona of Io, and (3) the spatial distribution of these escaping molecular and atomic species and their ion production rates in the planetary magnetosphere.

Description: Multiangle Advanced Solid State Array Spectroradiometer (ASAS) and Portable Apparatus for Rapid Acquisition of Bidirectional Observations of Land and Atmosphere (PARABOLA) visible and near infrared reflectance data covering the Lunar Lake playa, Nevada, were modeled using specular and volume scattering theory. The volume component used to model the data was based on the Hapke (1986) model and the specular scattering component was based on Fresnel reflection from surface facets with a distribution of tilts. Specular scattering was needed to explain the several-fold increase in reflectance observed at high phase angles in the solar principal plane. Results imply single scattering albedos of approximately 0.93 to 0.95, a real index of refraction value of approximately 1.52 (at a wavelength of 0.66 micron), a small imaginary index of refraction and an exponential facet tilt probability function for the playa. Electron micrographs showed th playa surface to consist of ensembles of smooth, micrometer-scale ellipsoidal particles on gently undulating topography at the millimeter to centimeter scale. The exponential probability function is consistent with this observation. Mars and the icy satellites are discussed as possible places to look for a significant specular scattering component.

Description: We have measured activities of the long-lived cosmogenic radionuclides Al-26, Be-10, and Cl-36 in 12 fragments of the iron meteorite Canyon Diablo and have constructed production rate-versus-depth profiles of those radionuclides. Profiles determined using differential particle fluxes calculated with the LAHET code system are in good agreement with Al-26, Be-10, and Cl-36 experimental data, but the agreement for Cl-36 was obtained only after neutron-induced cross sections were modified. Profiles calculated with lunar particle fluxes are much lower than experimental Canyon Diablo profiles. The cosmic ray exposure ages of most samples are near 540 m.y.

Description: There are two types of glass-rich chondrules in unequilibrated ordinary chondrites (OC): (1) porphyritic chondrules containing 55-85 vol% glass or microcrystalline mesostasis and (2) nonporphyritic chondrules, containing 90-99 vol% glass. These two types are similar in mineralogy and bulk composition to previously described Al-rich chondrules in OC. In addition to Si-, Al- and Na-rich glass or Ca-Al-rich microcrystalline mesostasis, glass-rich chondrules contain dendritic and skeletal crystals of olivine, Al2O3-rich low-Ca pyroxene and fassaite. Some chondrules contain relict grains of forsterite +/- Mg-Al spinel. We suggest that glass-rich chondrules were formed early in nebular history by melting fine-grained precursor materials rich in refractory (Ca, Al, Ti) an moderately volatite (Na, K) components (possibly related to Ca-Al-rich inclusions) admixed with coarse relict forsterite and spinel grains derived from previously disrupted type-I chondrules.

Description: A study of enstatite grains separated from EL6 chondrites shows ferrosilite contents to be approx. 0.02-0.04 mol%, about an order of magnitude lower than reported in the literature. The higher values reported earlier can probably be attributed to the excitation of Fe atoms in Fe-Ni and FeS, in part from micrometer-sized blebs of FeS and Fe-Ni commonly present in enstatite grains but mainly from large neighboring opaque grains excited by bremsstrahlung or by doubly backscattered electrons. Our EL6 ferrosilite contents are similar to those observed in coarse enstatite grains in some aubrites. The equilibrium between ferrosilite and Si-bearing kamacite is highly temperature dependent. At constant Si concentration in kamacite, the equilibrium ferrosilite mole fraction drops by a factor of roughly 2.5 for each 100 K decrease in the equilibrium temperature. As a result, the compositions of these two most common EL6 phases can be used to estimate metamorphic equilibration temperatures. The inferred temperatures are near 1200 K.

Description: The National Center for Atmospheric Research thermospheric general circulation model for the Venus thermosphere is modified to examine two observed night airglow features, both of which serve as sensitive tracers of the thermospheric circulation. New O2 nightglow data from the Pioneer Venus Orbiter (PVO) star tracker (O2 Herzberg II at 400-800 nm) and ground-based telescopes (O2 IR at 1.27 microns) yield additional model constraints for estimating Venus winds over 100-130 km. Atomic oxygen, produced by dayside CO2 photolysis peaking near 110 km, and transported to the nightside by the global wind system, is partially destroyed through three-body recombination, yielding the O2 Herzberg II visible nightglow. This emission is very sensitive to horizontal winds at altitudes between 100 and 130 km. Other trace species catalytic reactions also contribute to the production of the very strong nightside infrared (1.27 microns) emission. This paper examines the dynamical and chemical implications of these new data using the Venus thermospheric general circulation model (VTGCM) as an analysis tool. Three-dimensional calculations are presented for both solar maximum and solar medium conditions, corresponding to early PVO (1979-1981) and PVO entry (mid-1992) time periods. Very distinct periods are identified in which zonal winds are alternately weak and strong in the Venus lower thermosphere. VTGCM sensitivity studies are conducted to assess the impacts of potential changes in thermospheric zonal and day-to-night winds, and eddy diffusion on the corresponding nightglow intensities. It appears that cyclostrophic balance extends above 80 km periodically, owing to a reversal of the upper mesosphere latitudinal temperature gradient, and thereby producing strong zonal winds and correspondingly modified O2 nightglow distributions that are observed.

Description: ALH84001, originally classified as a diogenite, is a coarse-grained, cataclastic, orthopyroxenite meteorite related to the martian (SNC) meteorites. The orthopyroxene is relatively uniform in composition, with a mean composition of Wo3.3En69.4Fs27.3. Minor phases are euhedral to subhedral chromite and interstitial maskelynite, An31.1Ab63.2Or5.7, with accessory augite, Wo42.2En45.1Fs12.7, apatite, pyrite and carbonates, Cc11.5Mg58.0Sd29.4Rd1.1. The pyroxenes and chromites in ALH84001 are similar in composition to these phases in EETA79001 lithology a megacrysts but are more homogeneous. Maskelynite is similar in composition to feldspars in the nakhlites and Chassigny. Two generations of carbonates are present, early (pre-shock) strongly zoned carbonates and late (post-shock) carbonates. The high Ca content of both types of carbonates indicates that they were formed at moderately high temperature, possibly approximately 700 C. ALH84001 has a slightly LREE-depleted pattern with La 0.67x and Lu 1.85x CI abundances and with a negative Eu anomaly (Eu/Sm 0.56x CI). The uniform pyroxene composition is unusual for martian meteorites, and suggests that ALH84001 cooled more slowly than did the shergottites, nakhlites of Chassigny. The nearly monomineralic composition, coarse-grain size, homogeneous orthopyroxene and chromite compositions, the interstitial maskelynite and apatite, and the REE pattern suggest that ALH84001 is a cumulate orthopyroxenite containing minor trapped, intercumulus material.

Description: The Rice convection model has been modified for application to the transport of Io-generated plasma through the Jovian magnetosphere. The new code, called the RCM-J, has been used for several ideal-magnetohydrodynamic (MHD) numerical simulations to study how interchange instability causes an initially assumed torus configuration to break up. In simulations that start from a realistic torus configuration but include no energetic particles, the torus disintegrates too quickly (approximately 50 hours). By adding an impounding distribution of energetic particles to suppress the interchange instability, resonable lifetimes were obtained. For cases in which impoundment is insufficient to produce ideal-MHD stability, the torus breaks up predominantly into long fingers, unless the initial condition strongly favors some other geometrical form. If the initial torus has more mass on one side of the planet than the other, fingers form predominatly on the heavy side (which we associate with the active sector). Coriolis force bends the fingers to lag corotation. The simulation results are consistent with the idea that the fingers are formed with a longitudinal thickness that is roughly equal to the latitudinal distance over which the invariant density declines at the outer edges of the initial torus. Our calculations give an average longitudinal distance between plasma fingers of about 15 deg which corresponds to 20 to 30 minutes of rotation of the torus. We point to some Voyager and Ulysses data that are consistent with this scale of torus longitudinal irregularity.

Description: We examine the evolution of baroclinic vortices in a time-dependent, nonlinear numerical model of a Jovian atmosphere. The model uses a normal-mode expansion in the vertical, using the barotropic and first two baroclinic modes. Results for the stability of baroclinic vortices on an f plane in the absence of a mean zonal flow are similar to results of Earth vortex models, although the presence of a fluid interior on the Jovian planets shifts the stability boundaries to smaller length scales. The presence of a barotropic mean zonal flow in the interior stabilizes vortices against instability and significantly modifies the finite amplitude form of baroclinic instabilities. The effect of a zonal flow on a form of barotropic instability produces periodic oscillations in the latitude and longitude of the vortex as observed at the level of the cloud tops. This instability may explain some, but not all, observations of longitudinal oscillations of vortices on the outer planets. Oscillations in aspect ratio and orientation of stable vortices in a zonal shear flow are observed in this baroclinic model, as in simpler two-dimensional models. Such oscillations are also observed in the atmospheres of Jupiter and Neptune. The meridional propagation and decay of vortices on a beta plane is inhibited by the presence of a mean zonal flow. The direction of propagation of a vortex relative to the mean zonal flow depends upon the sign of the meridional potential vorticity gradient; combined with observations of vortex drift rates, this may provide a constraint on model assumption for the flow in the deep interior of the Jovian planets.

Description: The 0.3-2.6 micrometers spectral reflectance properties of carbon polymorphs (graphite, carbon black, diamond), carbides (silicon carbide, cementite), and macromolecular organic-bearing materials (coal, coal tar extract, oil sand, oil shale) are found to vary from sample to sample and among groups. The carbon polymorphs are readily distinguishable on the basis of their visible-near infrared spectral slopes and shapes. The spectra of macromolecular organic-bearing materials show increases in reflectance toward longer wavelengths, exceeding the reflectance rise of more carbon-rich materials. Reflectance spectra of carbonaceous materials are affected by the crystal structure, composition, and degree of order/disorder of the samples. The characteristic spectral properties can potentially be exploited to identify individual carbonaceous grains in meteorites (as separates or in situ) or to conduct remote sensing geothermometry and identification of carbonaceous phases on asteroids.

Description: The goal of the conference was to assess the moon as a base for conducting astronomy, solar system observations, and space sciences. The lunar vacuum allows a complete opening of the electromagnetic window and distortion-free measurements at the highest angular resolution, precision, and temporal stability. The moon is perfect for continuous monitoring of the Sun, Solar System targets, and for deep observations of galactic and extragalactic objects. It is an in-situ laboratory for selenophysics, chemistry, and exobiology. The moon contains useful resources and is accessible from Earth for installation, operations maintenance, robotics, and human activities.

Description: This report describes a general plan and the pertinent technological requirements for TOPS (Toward Other Planetary Systems), a staged program to ascertain the prevalence and character of other planetary systems and to construct a definitive picture of the formation of stars and their planets. The first stages focus on discovering and studying a significant number of fully formed planetary systems, as well as expanding current studies of protoplanetary systems. As the TOPS Program evolves, emphasis will shift toward intensive study of the discovered systems and of individual planets. Early stages of the TOPS Program can be undertaken with ground-based observations and space missions comparable in scale to those now being performed. In the long term, however, TOPS will become an ambitious program that challenges our capabilities and provides impetus for major space initiatives and new technologies.

Description: Summaries of presentations by representatives of several space agencies and the International Academy of Astronautics concerning lunar activities are presented. Participating space agencies reported two different types of lunar planning, long term planning and scenarios and lunar missions competing within regular programs. The long term plans of the various agencies look remarkably similar. They all involve a phased approach (coincidentally all incorporating four phases) and all address three prime scientific elements: science of, on, and from the Moon. The missions under consideration by the second group of agencies could readily fit as elements in the longer term program. There is great interest in lunar astronomy. There is a great deal of potential infrastructure and lunar transport capability already available. There is also a wide range of interesting technological developments that could form part of a lunar program. A well concerted and coordinated international effort could lead to an affordable program. Recommendations are: an international conference on lunar exploration should be held every other year; an electronic network should be established for the daily exchange of information; and a mechanism should be established for regular working level coordination of activities.

Description: We present a comprehensive analysis of data obtained during the 1989 July 3 occultation of 28 Sgr by Titan. The data set includes 23 lightcurves from 15 separate stations, spanning wavelengths from 0.36 to 0.89 micron. A detailed model of the structure of Titan's atmosphere in the altitude range 250 to 450 km is developed, giving the distribution of temperature, pressure, haze optical depth, and zonal wind velocity as a function of altitude and latitude. Haze layers detected in Titan's stratosphere are about one scale height higher than inferred from Voyager data, and show a wavelength dependence indicative of particle sizes on the order of 0.1 micron. A marked north-south dichotomy in haze density is observed with a transition to lower density south of about -20 deg latitude. Zonal wind speeds are inferred from global distortions from spherical symmetry and are of the order of 100 m/s with significant increase toward higher latitudes. Titan's high atmosphere shows substantial axial symmetry; the position angle of the symmetry axis is equal to the position angle of Saturn's spin axis to within about 1 deg.

Description: The atmospheres of Uranus and Neptune are discussed in the light of the Voyager 2 flybys of these planets. A basic overview of their atmospheres is presented, with emphasis on thermal structure, composition, energy and opacity sources, cloud structure, and the horizontal structure of the atmospheres. The nature and implications of the different internal heat flows on the two planets, and the implications of the deuterium and helium abundances for the origin and evolution of these ice giants, as distinct from Jupiter and Saturn, are discussed. Selected chemical and physical processes in the atmospheres of Uranus and Neptune are illustrated.

Description: Our studies of the silicate-bearing inclusions in the IIICD iron meteorites Maltahohe, Carlton, and Dayton suggest that their mineralogy and mineral compositions are related to the composition of the metal in the host meteorites. An inclusion in the low-Ni Maltahohe is similar in mineralogy to those in IAB irons, which contain olivine, pyroxene, plagioclase, graphite, and troilite. With increasing Ni concentration of the metal, silicate inclusions become poorer in graphite, richer in phosphates, and the phosphate and silicate assemblages become more complex. Dayton contains pyroxene, plagioclase, SiO2, brianite, panethite, and whitlockite, without graphite. In addition, mafic silicates become more FeO-rich with increasing Ni concentration of the hosts. In contrast, silicates in IAB irons show no such correlation with host Ni concentration, nor do they have the complex mineral assemblages of Dayton. These trends in inclusion composition and mineralogy in IIICD iron meteorites have been established by reactions between the S-rich metallic magma and the silicates, but the physical setting is uncertain. Of the two processes invoked by other authors to account for groups IAB and IIICD, fractional crystallization of S-rich cores and impact generation of melt pools, we prefer core crystallization. We suggest that the solidification of the IIICD core may have been very complex, involving fractional crystallization, nucleation effects and, possibly, liquid immiscibility.

Description: Escape rates of oxygen atoms from dissociative recombination of O2(+) above the Martian exobase are computed in light of new information from ab initio calculations of the dissociative recombination process and our recently revised understanding of the Martian dayside ionosphere. Only about 60 percent of the dissociative recombinations occur in channels in which the O atoms are released with energies in excess of the escape velocity. Futhermore, we find that the computed escape fluxes for O depend greatly on the nature of the ion loss process that has been found necessary to reproduce the topside ion density profiles measured by Viking. If it is assumed that the ions are not lost from the gravitational field of the planet, as required by an analysis of nitrogen escape, the computed average O escape rate is 3 x 10 exp 6/sq cm/s, much less than half the H escape rates inferred from measurements of the Lyman-alpha dayglow, which are in the range (1-2) x 10 exp 8/sq cm/s. Suggestions for restoring the relative escape rates of H and O to the stoichiometric ratio of water are explored.

Description: Primitive meteorites contain a few parts per million (ppm) of pristine interstellar grains that provide information on nuclear and chemical processes in stars. Their interstellar origin is proven by highly anomalous isotopic ratios, varying more than 1000-fold for elements such as C and N. Most grains isolated thus far are stable only under highly reducing conditions (C/O greater than 1), and apparently are 'stardust' formed in stellar atmospheres. Microdiamonds, of median size about 10 A, are most abundant (about 400-1800 ppm) but least understood. They contain anomalous noble gases including Xe-HL, which shows the signature of the r- and p-processes. Silicon carbide, of grain size 0.2-10 microns and abundance about 6 ppm, shows the signature of the s-process and apparently comes mainly from red giant carbon (AGB) stars of 1-3 solar masses. Some grains appear to be not less than 10 exp 9 a older than the solar system. Graphite spherules of grain size 0.8-7 microns and abundance less than 2 ppm contain highly anomalous C and noble gases, as well as large amounts of fossil Mg-26 from the decay of extinct Al-26. They seem to come from at least three sources, probably AGB stars, novae, and Wolf-Rayet stars.

Description: Lunar soils contain micrometer-sized mineral grains surrounded by thin amorphous rims. Similar features have been produced by exposure of pristine grains to a simulated solar wind, leading to the widespread belief that the amorphous rims result from radiation damage. Electron microscopy studies show, however, that the amorphous rims are compositionally distinct from their hosts and consist largely of vapor-deposited material generated by micrometeorite impacts into the lunar regolith. Vapor deposits slow the lunar erosion rate by solar wind sputtering, influence the optical properties of the lunar regolith, and may account for the presence of sodium and potassium in the lunar atmosphere.

Description: The ion acoustic beam instability is suggested as a mechanism to produce wave turbulence observed in the Venus mantle at frequencies 100 Hz and 730 Hz. The plasma is assumed to consist of a stationary cold O(+) ion plasma and a flowing, shocked solar wind plasma. The O(+) ions appear as a beam relative to the flowing ionosheath plasma which provides the free energy to drive the instability. The plasma is driven unstable by inverse electron Landau damping of an ion acoustic wave associated with the cold ionospheric O(+) ions. The instability can directly generate the observed 100 Hz waves in the Venus mantle as well as the observed 730 Hz waves through the Doppler shift of the frequency caused by the satellite motion.

Description: The Broadband Array Spectrograph System with the NASA Infrared Telescope Facility was used to obtain 3- to 13-micron spectra of Io on June 14-16, 1991. The extinction correction and its error for each standard star (Alpha Boo, Alpha Lyr, and Mu UMa) were found individually by performing an unweighted linear fit of instrumental magnitude as a function of airmass. The model results indicate two significant trends: (1) modest differences between the two hemispheres at lower background temperatures and (2) a tendency to higher temperatures, smaller areas, and less power from the warm component at higher background temperatures with an increased contrast between the two hemispheres. The increased flux from 8 to 13 microns is due primarily to a greater area on the Loki (trailing) hemisphere for the warm component, although temperature also plays a role.

Description: Results are presented of an investigation of the geology, physical properties, and topography of Apollinaris Patera which was performed on the basis of geologic mapping, thermal inertia measurements, and analysis of the color (visual wavelengths) of this Martian volcano. Initially, the main edifice was formed over a period of about 10 exp 7 yr, and then the volcano experienced a period of quiescence during which the basal scarp formed and the valleys were incised in the main flanks. Activity at the summit formed the present large outer caldera and floor materials. After, or during late stages of outer calder activity, the materials that formed the fan were erupted over 10,000 yr. After emplacement of the fan materials, the smaller, inner caldera and associated floor materials formed over an unconstrained time period. Morphologic analysis suggests that a significant portion of the main edifice is composed of poorly to nonwelded pyroclastic deposits, possibly including a phreatomagmatic component.

Description: The hypothesis is explored that the crust-mantle boundary of Venus is not in phase equilibrium but rather is rate-limited by the temperature-dependent volume diffusion of the slowest ionic species. The 1D thermal evolution problem is solved assuming that the mountains formed by uniform horizontal shortening of the crust and the lithospheric mantle at a constant rate. The time-dependent density structure and surface elevation are calculated by assuming a temperature-dependent reaction rate and local Airy isostatic compensation. For a horizontal strain rate of 10 exp -15/s or greater, the temperature increase at the base of the crust during mountain formation is modest to negligible, the deepening lower crust is metastable, and the surface elevation increases as the crust thickens. For strain rates less than 10 exp -16/s, crustal temperature increases with time because of internal heat production and the lower crust is more readily transformed to the dense eclogite assemblage. For such models, a maximum elevation is reached during crustal shortening.

Description: This video describes Voyager 2's encounter with Neptune. Computer animation and actual data convey Voyager's discoveries such as turbulent storms and dark spots in Neptune's atmosphere, six new moons, Neptune's three rings, and the presence of frozen methane on Triton, as researchers at NASA's Jet Propulsion Laboratory describe Voyager's achievements.

Description: A combination of sophisticated computer animation and shuttle footage describe the missions of Ulysses, Galileo, and Magellan satellites to the solar system. Ulysses, launched in October 1990 by the European Space Agency, will study the sun. Galileo, launched in October 1989, will probe the Jovian system by releasing a probe that will descend into Jupiter's atmosphere and by using 12 instruments which will study Jupiter's 16 moons, its atmosphere, and its radiation and magnetic fields. Magellan, released from Space Shuttle Atlantis in May 1989, uses a synthetic aperture radar to probe through Venus' dense atmosphere to map its planetary surface. A computer animation simulates flying over the surface of Venus.

Description: Early results from Voyager's pass of Uranus and its moon, Miranda, are shown.

Description: The videotape includes footage of the following: Voyagers to Jupiter, Pioneer to Saturn, High Energy Astronomy Observatory, space telescope, space shuttle, astronauts Young and Crippen, 10th anniversary of Apollo 11, Skylab reentry, Landsat, satellite freeze warning, Fire Fighting Module, SAGE, wind generators, Solar Energy Project, electric car research, XV-15, HiMAT, and crash worthiness tests.

Description: This videotape discusses NASA's plans for a lunar base. Additionally, the videotape features interviews with George Keyworth, James Beggs, and Harrison Schmidt.

Description: Cantaloupe terrain is unique to Triton. It is Triton's oldest terrain and includes about 250,000 km sq. region displaying sparsely cratered, closely spaced, nearly circular dimples about 30-40 km across. This terrain is found on no other planet because, only on Triton the final major global thermal pulse (1) caused completed (or nearly) interior melting resulting in a cooling history where large thermal stresses shattered and contorted a thin, weak lithosphere, and (2) occurred after heavy bombardment so that the surface features were preserved. The cantaloupe terrain is composed of intersecting sets of structures (folds and/or faults) that have developed as a result of global compression generated by volumetric changes associated with cooling of Triton's interior. Further, it is proposed that these structures developed after the period of heavy bombardment, and resulted from the last major global thermal epoch in Triton's unique history (either caused by tidal or radio metric heating). Initially, as the body cooled and the structures formed, their surface topography was most likely modified by thermal relaxation of the warm surface ices. In other bodies like Mercury, thermal stresses generated from global cooling and contraction have resulted in widely spaced thrust faults, whereas on Triton, thermal stresses produced more closely-spaced folds and faults sets. This difference in structural style is probably due to differences in lithospheric properties (thickness, strength, etc.), the magnitude of stress (directly dependent on the thermal history), and when the structures formed, relative to the period of heavy bombardment.

Description: The stability of the Io plasma torus-atmosphere interaction is examined. A simple plasma deflection model describes how transients in the plasma flux and the content of the atmosphere affect the ionospheric conductance, limiting the plasma bombardment and, hence, the supply of atmospheric species to the torus. The supply of the torus is seen to be determined by the thermal structure of the plasma, namely, the amount of low energy plasma producing atmospheric erosion vs. that which produces ionization, so that the torus supply rate is not simply proportional to the torus ion density.

Description: Models of the emplacement of lateral dikes from magma chambers under constant (buffered) driving pressure conditions and declining (unbuffered) driving pressure conditions indicate that the two pressure scenarios lead to distinctly different styles of dike emplacement. In the unbuffered case, the lengths and widths of laterally emplaced dikes will be severely limited and the dike lengths will be highly dependent on chamber size; this dependence suggests that average dike length can be used to infer the dimensions of the source magma reservoir. On Earth, the characteristics of many mafic-dike swarms suggest that they were emplaced in buffered conditions (e.g., the Mackenzie dike swarm in Canada and some dikes within the Scottish Tertiary). On Venus, the distinctive radial fractures and graben surrounding circular to oval features and edifices on many size scales and extending for hundreds to over a thousand km are candidates for dike emplacement in buffered conditions.

Description: The paper describes the results from the development of improved high-resolution gravity models of Mars and Venus carried out at Goddard Space Flight Center, together with the solution design and the tracking data employed. These models are spherical harmonic expansions complete to degrees 50 and 36 for Mars and Venus, respectively. Both models result in improved orbital computation accuracies over previously available models, and in improved resolution of geophysical features. The paper also discusses new developments anticipated in the future.

Description: The properties of the gravity fields of the earth, Mars, and Venus, as expressed by spherical harmonic coefficients, are examined, using the harmonic expansions of the respective planetary topographies reported by Balmino et al. (1973), Bills and Ferrari (1978), and Bills and Kobrick (1985). The items examined include the spectral magnitudes and slopes of the gravity coefficients; the correlations between gravity and topography; and the correlations among different gravity harmonics, expressed by axiality and angularity. It was found that Venus differs from the other two planets in its great apparent depths of compensation, indicating a tectonics dominated by a stiff upper mantle. In addition, Venus has less activity deep in the mantle than do earth or Mars. Mars is marked by large gravity irregularities, as well as by their axial symmetry on a global scale. Although earth is probably the most peculiar planet, spherical harmonics do not bring out its varied characteristics. It is clearly a more active planet than Venus, with activity deep in the mantle. The lower magnitude of its higher harmonics is considered to be due to water recycled to the upper mantle.

Description: The purpose of the study is to provide an alternative perspective on both the mass balance issue and on the issue of secular change in the Rb-Cs ratio in the earth mantle. In particular, it is argued that the apparent secular change in the Rb/Cs ratio may be simply an artifact of alteration of older rocks through weathering and/or metamorphism subsequent to formation. It is also shown that there is not necessarily a need for a hidden, undepleted reservoir, and the consistency of this result with other mass calculations is explored. New methods for estimating the Rb/Cs ratio of the bulk silicate earth are suggested.

Description: Rate coefficients for the reaction C2H + C2H2 - C4H2 + H are measured over the temperature range 170-350 K. The reactions are carried out in a temperature variable flow cell. C2H radicals are produced by pulsed laser photolysis of C2H2 and a tunable infrared color-center laser is used to probe the transient removal of C2H in absorption to derive the rate coefficients. The rate coefficient is obtained and shown to be independent of temperature over the range 170-350 K. The reaction studied is of central importance for models of the photochemistry of the atmospheres of the outer planets, in particular for the satellite Titan, and the implications of the present results for these models are discussed.

Description: Reflectance spectra (0.3 to 2.6 micrometers) of 14 C, G, B, and F asteroids and 21 carbonaceous chondrite powders are compared in detail. Only three thermally metamorphosed CM-CI chondrites that have a weak UV absorption are shown to have close counterparts among those asteroids. Reflectance spectra of heated Murchison CM2 chondrite are compared with the average C and G type asteroid spectra. Murchison heated at 600 to 1000 C exhibits a similar weak UV absorption and provides the best analog for those spectra. Comparison of UV absorption strengths between 160 C, G, B, and F asteroids and carbonaceous chondrites suggests that surface minerals of most of those asteroids are thermally metamorphosed at temperatures around 600 to 1000 C.

Description: Global analysis of Magellan image data indicates that a major concentration of volcanic centers covering about 40 percent of the surface of Venus occurs between the Beta, Atla, and Themis regions. Associated with this enhanced concentration are geological characteristics commonly interpreted as rifting and mantle upwelling. Interconnected low plains in an annulus around this concentration are characterized by crustal shortening and infrequent volcanic centers that may represent sites of mantle return flow and net downwelling. Together, these observations suggest the existence of relatively simple, large-scale patterns of mantle circulation similar to those associated with concentrations of intraplate volcanism on earth.

Description: The controversy that raged through the 1950s to 1970s over similarities and differences between meteorite impact and volcanic processes is revisited. We propose that there are quantitative similarities in erosion caused by high-speed ejecta produced by either impacts or volcanic processes. Field and petrographic data from the Manicouagan impact crater, Canada, are used to demonstrate that, during the emplacement of the impact melt sheet, erosion occurred at a rate of 2562 kg/sq m per s. Field data for the Mount St. Helens lateral blast of May 18, 1980, suggest an erosion rate of 21 kg/sq m per s, and field data for a small pyroclastic flow on August 7, 1980, suggest an erosion rate of about 14 kg /sq m per s. It is proposed that these three rates were determined dominantly by the momentum of the ejecta, and a quantitative formulation based on lofting theory is given. A new application of the Monte Carlo approach to analysis provides minimum, most likely, and maximum estimates for both the field and the theoretical analyses. The substantial erosion that occurs by fast moving flows results in mixing of stratigraphic components over large distances and to very fine scales.

Description: Hellas Planitia, located within an enclosed basin which includes the lowest topography on Mars, appears to be undergoing net erosion. Dust is removed from the basin. It probably contributes to global dust storms and should leave behind a coarse lag. The particle size distributions and particularly the rock or boulder populations in this lag might be useful for distinguishing between processes which formed the lithologic units that comprise Hellas Planitia. This report concludes that the abundance of rock particles larger than coarse sand is very low. Although this hypothesis awaits confirmation from forthcoming spacecraft data, the origins for Hellas floor deposits favored by this study are indurated volcanic airfall or ancient loess, lacustrine deposits, and some types of volcanic mud flows. The conclusions of this study tend to disfavor such geologic processes as blocky lava flows, glacial deposits (e,g., moraines), or boulder-laden catastrophic flood outwash.

Description: Experiments were performed to measure, by electron impact, appearance potentials and the cross sections for ionization, dissociative ionization, and electron attachment for H2S. Results are presented, and discussed individually, for both positive and negative ions. A schematic diagram of the experimental setup is included.

Description: A series of heating experiments was performed on the condensed ammonia-water system using a differential scanning calorimeter (DSC). The water-rich samples were cooled quickly to below 130 K, then heated at a variety of rates. Rather than a single peritectic melt at 176 K, expected for the equilibrium system of water ice and ammonia dihydrate, four enthalpic transitions were repeatedly seen in the temperature range 150-176 K. These transitions are generally consistent with the earlier calorimetric results of Van Kasteren (1973), who interpreted the lowest temperature exotherm as crystallization of an amorphous ammonia-water compound formed during cooling. We propose that both sets of experiments are seeing the crystallization of ammonia monohydrate, which is metastable relative to the dihydrate, followed by partial remelting and crystallization of dihydrate upon further heating. The apparent stability of the monohydrate in the dihydrate equilibrium field implies a potentially complex behavior of ammonia-water ices in satellites. Possible self-heating of the mixture by several tens of degrees up to the 170 K eutectic could make mobilization of ammonia-water liquids in icy satellite interiors energetically easier than previously thought.

Description: Results are reported on 26 high-resolution (16-51 steps) Ar-40/Ar-39 age spectra obtained on 12 Apollo-15 melt rocks of different composition using a continuous laser system on submg fragments of recrystallized melt and single-crystal plagioclase clasts from impact melt rocks collected at the Apennine Front where the Imbrium and Serenitatis basins intersect. A table is presented with the summary of the Ar-40/Ar-39 spectrum data, which represent 891 individual temperature step analyses. Also presented are 20 of the 26 age spectra along with their respective K/Ca plots. Melt rock fragments and plagioclase clasts from seven of the 12 samples analyzed yielded reproducible, intermediate-T Ar-40/Ar-39 age spectrum plateaus, which were interpreted as crystallization ages that represent the times of impact of bolides onto the lunar surface.

Description: A model encompassing plasma transport and energy processes is applied to Neptune's magnetosphere. Starting with profiles of the neutral densities and the electron temperature, the model calculates the plasma density and ion temperature profiles. Good agreement between model results and observations is obtained for a neutral source of 5 x 10 exp 25/s if the diffusion coefficient is 10 exp -8 L3R(N)/2s, plasma is lost at a rate 1/3 that of the strong diffusion rate, and plasma subcorotates in the region outside Triton.

Description: An attempt is made to provide a balanced perspective regarding the knowledge of Titan's surface and how well current models address the various sets of data. Topics discussed include the Voyager data that led to the notion of a massive, global-scale hydrocarbon ocean; recent data sets including radar, radiometry, and NIR photometry that bear on the nature of the surface. Attention is also given to models of the surface that attempt to fit all of the constraints; and the Cassini investigations of Titan's surface. The surface and regolith of Titan are considered to be most likely a repository of liquid methane, other hydrocarbons, and dissolved nitrogen.

Description: Yamato-86032 is a shock-lithified anorthositic fragmental breccia. It consists mainly of highly feldspathic meta-breccias and meta-meltrocks and possibly contains a small contribution from mare lithologies, but there is no indication of a KREEP component. In many respects Y-86032 is similar to the previously described lunar meteorites Y-82192/3, but there are some notable differences. We have analyzed about 40 major and trace elements in bulk matrix, impact melt, and clast samples from two chips of Y-86032. The abundances of most lithophile and incompatible elements are lower in Y-86032 than in Y-82192 (which contains very low abundances compared to normal lunar highland rocks). The REE abundances are comparable to those of Y-82192. The elements Sc, Cr, Mn, Fe and Co have significantly lower abundances than in Y-82192, and the siderophile element pattern is also different. Since cosmic ray exposure data indicate pairing of Y-86032 with Y-82192/3, the source region for these meteorites on the moon must have been fairly heterogeneous.

Description: Recent spectral observations of both the leading and trailing hemispheres of Callisto confirm the conclusions of Calvin and Clark (1991) that the water ice is typically large-grained, and the general spectral trend from 3 to 43 microns is caused by an adsorbed water band associated with hydrous minerals. On the leading hemisphere, a broad absorption near 3.4 microns was definitively identified and interpreted as being caused by fine-grained water ice. This band, coupled with the slope in the region from 2 to 2.5 microns, is indicative of a small amount, on the order of 1 to 2 percent, of fine-grained ice on the leading side. It is suggested that in the longer wavelength spectral region on the leading hemisphere an additional band correlated with NH4-bearing clays may be indicated.

Description: Results of calculations performed to determine the conditions necessary for producing the opaque rims on chondrules and CAI rims by high-speed entry into the transient atmosphere of an accreting meteorite parent body are presented. The sensitivity of these results to variations in critical parameters is investigated. The range of entry velocities which can produce such rims is shown to depend on the size, melting temperature, and thermal conductivity of the particles. For particles greater than 2 mm in radius, with thermal conductivities of 20,000 ergs/sm s K or lower, entry velocities of about 3 km/s suffice. For particle sizes less than 1 mm in radius, the range of encounter velocities that can produce rims is narrow or vanishing, regardless of the thermal conductivity, unless the melting temperature in the outer part of the chondrule has been reduced by compositional heterogeneity.

Description: The distribution of hydrocarbons in the upper atmosphere of Neptune is determined on the basis of data from the Voyager UVS solar occultation experiment. Densities are inferred from the transmission properties of the atmosphere measured by the UVS. The CH4 mole fraction in the lower stratosphere is between 0.0006 and 0.005. It is inferred that CH4 in Neptune's lower stratosphere is oversaturated by at least a factor of 10, and possibly by as much as a factor of 100. The density of C2H6 reaches values of 3 x 10 exp 9/cu cm near 100 microbar; a C2H6 production efficiency of 35 +15/-5 percent is derived. The eddy diffusion coefficient is approximately constant at a value of 10,000 sq cm/s at altitudes below 300 km and increases at higher altitudes as the pressure to the 0.75 power. A mole fraction of 0.001 is found to be consistent with the CH4 vapor pressure at 3.4 mbar; consequently, CH4 ice particles must reach this level to produce the inferred oversaturation.

Description: Possible causes of observations of electron cyclotron maser emissions (ECMEs) at oblique angle (about 60 deg) to the magnetic field are investigated. The paper discusses general concepts of ECME in terms of resonant ellipses and considers electron distributions required to produce ECME at oblique angles, as well as the ways in which the most favorable of these distributions may be produced. A mechanism is proposed that might produce an appropriate 'spiraling beam' distribution, with a peak in velocity space at speed v - v(0) and pitch angle alpha = alpha(0) not equal to 0.

Description: Cantaloupe terrain on Neptune's large, icy satellite Triton comprises an organized cellular pattern of noncircular dimples that structurally and geologically most closely resemble salt diapirs exposed on Earth. The mean separation of these cells is 47 km. Modeling of the cells as compositionally driven diapirs suggests that cantaloupe terrain forms by gravity-driven overturn within an ice crust about 20 km thick with a maximum viscosity of 10 exp 22 Pa s. These diapirs probably formed as a result of a density inversion in a layered crust composed partly of ice phases other than water ice.

Description: The depths of 109 impact craters about 2-16 km in diameter, located on the ridged plains materials of Hesperia Planum, Mars, have been measured from their shadow lengths using digital Viking Orbiter images (orbit numbers 417S-419S) and the PICS computer software. On the basis of their pristine morphology (very fresh lobate ejecta blankets, well preserved rim crests, and lack of superposed impact craters), 57 of these craters have been selected for detailed analysis of their spatial distribution and geometry. We find that south of 30 deg S, craters less than 6.0 km in diameter are markedly shallower than similar-sized craters equatorward of this latitude. No comparable relationship is observed for morphologically fresh craters greater than 6.0 km diameter. We also find that two populations exist for older craters less than 6.0 km diameter. When craters that lack ejecta blankets are grouped on the basis of depth/diameter ratio, the deeper craters also typically lie equatorward of 30 S. We interpret the spatial variation in crater depth/diameter ratios as most likely due to a poleward increase in volatiles within the top 400 m of the surface at the times these craters were formed.

Description: We report on a series of 27 C-14 terrestrial ages of meteorites from four states in the central and southwestern U.S. These results were compared to the earlier work of Boeckl (1972). Our results showed that the weathering rate for destruction of meteorites is lower than suggested by Boeckl. We estimate a 'half-life' for removal of meteorites of about 10 to 15 ka, similar to that derived for Roosevelt County meteorites. We also studied the weathering of these meteorites compared to terrestrial age. Only a weak correlation was observed, and for these meteorites the degree of weathering can only be taken as a weak indicator of terrestrial residence time. We also measured the delta-C-13 and C-14 and amount of weathering-product carbonates which show some interesting variations with the length of time the meteorites have been exposed to weathering.

Description: Observations of thermal ions in Saturn's inner magnetosphere suggest distributed local sources rather than diffusive mass loading from a source located further out. We suggest that the plasma is produced and maintained mainly by 'self-sputtering' of E ring dust. Sputtered particles are 'picked up' by the planetary magnetospheric field and accelerated to corotation energies (of the order of 8 eV/amu). The sputter yield for oxygen on ice at, for example, 120 eV is about 5, which implies that an avalanche of self-sputtering occurs. The plasma density is built up until it is balanced by local losses, presumably pitch angle scattering into the loss cone and absorption in the planet's ionosphere. The plasma density determines the distribution of dust in the E ring through plasma drag. Thus a feedback mechanism between the plasma and the E ring dust is established. The model accounts for the principal plasma observations and simultaneously the radial optical depth profile of the E ring.

Description: A model of the annual cycle of pressure on Mars for a 2-yr period, chosen to include one year at the Viking Lander 2 and to minimize the effect of great dust storms at the 22-deg N Lander 1 site, was developed by weighted least squares fitting of the Viking Lander pressure measurements to an annual mean, and fundamental and the first four harmonics of the annual cycle. Close agreement was obtained between the two years, suggesting that an accurate representation of the annual CO2 condensation-sublimation cycle can be established for such years. This model is proposed as the 'nominal' Martian annual pressure cycle, and applications are suggested.

Description: The detection of neutral OH molecules near the orbit of Tethys is reported. The findings suggest that neutral OH is one of the dominant species in Saturn's inner magnetosphere, implying a source rate for H2O 20 times greater than current theoretical estimates. One possible explanation is that the micrometeorite erosion rates of the inner satellites are significantly higher than expected.

Description: We examine the rate of accretion of mass and spin angular momentum by a spherical solid body ('planet') immersed in a differentially rotating disk of particles ('planetesimals'). If the planet travels on a circular orbit, the accretion process is described by two dimensionless parameters r and s, which measure the ratio of the planet's radius to its Hill radius and the ratio of the rms radial velocity of the planetesimals to the shear across the Hill radius, respectively. Using a combination of analytic arguments and numerical simulations, we derive the mass and angular momentum accretion rates and their scaling with r and s. By introducing an additional parameter, the effective mass of the planetesimals relative to the planet, we can derive the obliquities and spins arising from the stochastic nature of the accretion process. Our results are consistent with those of previous calculations by Lissauer and Kary (1991) wherever there is overlap in parameter space. In particular, we conclude that ordered accretion from a uniform or slowly varying disk of small bodies cannot result in rotation as rapid as that of earth or Mars for any value of the disk velocity dispersion s. The spin rates of these planets are most naturally explained as arising from one or a few 'giant' impacts by planetesimals.

Description: The near-IR spectra of the Venus nightside emission are here simulated by means of a radiative transfer code that allows for emission, absorption, and scattering by atmospheric gases and particles. An effort is made to assess the adequacy of current gas data bases in simulating Venus' nightside near-IR spectra and, within these limitations, to derive information on gas abundances below the main clouds and these clouds' optical thickness. It is in this way established that the HITRAN data base for the permitted transitions of CO2 is completely inadequate for simulating the Venus nightside near-IR emissions.

Description: Aspects of satellite origin and evolution which bear on the formation of the solar system are addressed, with emphasis on the chemical evidence contained in satellites concerning the modification of the interstellar material which went to form the solar system. New results on the tidal evolution of outer-planet satellite systems are presented. The gross physical and chemical properties of the satellite systems of the outer planets are outlined. Models for regular satellite formation are reviewed. Attention is given to the evolution of the satellites, with emphasis on tidal evolution, including a discussion of the dynamical origin of Triton. The volatile budgets of Titan, Triton, and Pluto/Charon are discussed, and models are presented for the origin of these budgets which tie them to the larger set of processes associated with solar system formation.

Description: Lunar silicate glasses may possess superior mechanical properties compared to terrestrial glasses because the anhydrous lunar environment should prevent hydrolytic weakening of the strong Si-O bonds. This hypothesis was tested by melting, solidifying, and determining the fracture toughness of simulated mare and highlands composition glasses in a high vacuum chamber. The fracture toughness, K(IC), of the resulting glasses was obtained via microindentation techniques. K(IC) increased as the testing environment was changed from air to a vacuum of 10 exp -7 torr. However, this increase in toughness may not result solely from a reduction in the hydrolytic weakening effect; the vacuum-melting process produced both the formation of spinel crystallites on the surfaces of the glass samples and significant changes in the compositions which may have contributed to the improved K(IC).

Description: The 1600 km-long Maja Valles outflow system of Mars consists of three major divisions including the upper valley on Lunae Planum, the canyon section across Xanthe Terra, and the lower valley across western Chryse Planitia. Although water released from the source in Juventae Chasma could reach the terminus of the present day valley system in central Chryse Planitia within 44 hours, the original outflow did not traverse the Martian surface in a direct path. It ponded along its course on northern Lunae Planum and near the western edge of Chryse Planitia significantly prolonging the lifetime of surface flow. Calculation of pond volumes and discharge rates through various parts of the channel system indicates that water flowed through this system for nearly a (terrestrial) year. Discharge rates from the various basins along the Maja channels and the maximum flow rates within the various channels are calculated. With this data, it is possible to place reasonable estimates of the minimum length of time required to drain the various impoundments and the duration of flow in various parts of the channel system. The results of these calculations are discussed.

Description: The Ulysses mission detected quasi-periodic streams of high-velocity submicron-sized dust particles during its encounter with Jupiter. It is shown here how the dust events could result from the acceleration and subsequent ejection of small grains by Jupiter's magnetosphere. Dust grains entering the plasma environment of the magnetosphere become charged, with the result that their motion is then determined by both electromagnetic and gravitational forces. This process is modeled, and it is found that only those particles in a certain size range gain sufficient energy to escape the Jovian system. Moreover, if Io is assumed to be the source of the dust grains, its location in geographic and geomagnetic coordinates determines the exit direction of the escaping particles, providing a possible explanation for the observed periodicities. The calculated mass and velocity range of the escaping dust gains are consistent with the Ulysses findings.

Description: The modified Gaussian model (MGM) is used to explore spectra of samples containing multiple pyroxene components as a function of modal abundance. The MGM allows spectra to be analyzed directly, without the use of actual or assumed end-member spectra and therefore holds great promise for remote applications. A series of mass fraction mixtures created from several different particle size fractions are analyzed with the MGM to quantify the properties of pyroxene mixtures as a function of both modal abundance and grain size. Band centers, band widths, and relative band strengths of absorptions from individual pyroxenes in mixture spectra are found to be largely independent of particle size. Spectral properties of both zoned and exsolved pyroxene components are resolved in exsolved samples using the MGM, and modal abundances are accurately estimated to within 5-10 percent without predetermined knowledge of the end-member spectra.

Description: The structure and chemical composition of the Lafayette meteorite were examined using several methods. The meteorite contains abundant hydrous post-magnetic alteration material consisting of ferroan smectite clays, magnetite, and ferrihydrite. The textural relations, mineralogy, and composition of these materials were examined and their preterrestrial nature was documented. Olivine, pyroxene, and glass alteration are described and the bulk compositions of the alteration veinlets is discussed. Essential features of the geochemistry of the alteration processes are described. It is suggested that the alteration of the Lafayette meteorite occurred during episodic infiltrations of small volumes of saline water. Constraints placed on water chemistry and water-rock interactions in the Martian crust are outlined.

Description: We present evidence from analysis of Voyager data and numerical experiments that in Jupiter's troposphere at midlatitudes the potential vorticity is given simply by the reciprocal of the streamfunction. This relationship agrees with the results of a vortex-tube stretching analysis of the Voyager wind-field data of the Great Red Spot and White Oval BC, whereas other published models do not. The derivative of streamfunction with respect to potential vorticity is negative definite, and in the quasigeostrophic limit the relationship is neutrally stable with respect to Arnold's second stability theorem. Numerical experiments indicate that the relationship is also neutrally stable in the primitive shallow-water system. This resolves a long-standing question as to how Jupiter's cloud-top winds are able to violate the Rayleigh-Kuo stability criterion, and constrains the two-layer model to a single free parameter.

Description: A series of analytic and numerical calculations of the systematic component of angular momentum accretion is described. Wide ranges of planetesimal eccentricities and planetary radii are considered. Numerical simulations using a Rayleigh distribution of eH values show that very little prograde rotation is produced in a disk with a realistically broad range of planetesimal eccentricities. It is hypothesized that the observed spin rates may result from nonuniformities in the disk of planetesimals, specifically, a partial gap in planetesimal semimajor axes around that of the planet. This would yield an overabundance of impactors from the edges of the planet's accretion zone. Bodies from this region produce strongly prograde rotation at most values of eH.

Description: Partitioning coefficients for metal/sulfide liquid, troilite/sulfide liquid, and schreibersite/sulfide liquid were determined for Ag, Au, Mo, Ni, Pd, and Tl (using EMPA and proton-induced X-ray microprobe and ion microprobe analyses) in order to understand the chronometer systems of iron meteorites. In general, the obtained schreibersite/metal and troilite/metal partition coefficients for 'compatible' elements were quite similar to those inferred from natural assemblages, reinforcing an earlier made conclusion that there is a class of elements for which experimental troilite/metal and schreibersite/metal partition coefficients approximate those inferred from natural samples. The consistency between experimental and natural assemblages, however, was not observed for Ag, Pb, and Tl, indicating that the abundances of these elements determined in 'metal' and 'troilite' separates from iron meteorites are influenced by trace minerals that concentrate incompatible elements.

Description: Three-dimensional hybrid particle simulations of the dayside portion of the Mars/solar wind interaction have been performed. These simulations are compared with the in situ measurements taken during the elliptical orbits of Phobos 2. The comparisons show considerable agreement between the magnetic field data and the simulations results. The results of the simulations bring into question the type of structures created in the subsolar region of Mars. It appears that the large larmor radius of the solar wind ions prevents the formation of a traditional collisionless shock in the subsolar region of the interaction.

Description: Martian dust plays a key role in determining the current climate of Mars, and is suspected of having had a major influence on the evolution of the surface and the history of climatic conditions on the planet. From spacecraft and ground-based observations, some understanding has been acquired of the styles and frequency of dust motion in the atmosphere and at the surface, of atmospheric dust loading, dust particle properties, and their variability. Limited constraints have also been derived for the volumes and ages of some potential dust reservoirs on the surface. These data are adequate to frame questions about the seasonal and long-term cycles of dust of Mars. Additional data are needed to place quantitative constraints on components of these cycles, on their possible linkage to one another, and to draw conclusions from the dust budget about the climate history of Mars.

Description: The thermal structure of the Martian atmosphere, which varies diurnally, seasonally and episodically, is discussed. The atomic oxygen airglow at 1304 A is used to determine the density of atomic oxygen, and the 1216-A Lyman-alpha line is used to calculate the density of atomic hydrogen and, when coupled with the temperature measurement, the escape flux of atomic hydrogen. The most intense airglow is the IR atmospheric band of O2 at 1.27 micron that results from the photodissociation of ozone. The escape mechanism for atomic hydrogen is thermal, or Jeans, escape, while the atomic oxygen escape is caused by a nonthermal process, namely, the dissociative recombination of O2(+). The ratio of deuterium to hydrogen is enriched by a factor of 6. Three-dimensional models of the Mars thermospheric circulation show that planetary rotation has a significant effect on the wind, composition, and temperature structure.

Description: The current understanding of the seasonal water cycle on Mars is summarized. A brief history of the observations of water vapor in the Martian atmosphere and an outline of the seasonal water cycle are presented. Attention is given to the possible exchange of atmospheric water with nonatmospheric reservoirs of water, the role of transport of water through the atmosphere either as vapor or as condensate via the atmospheric circulation, and inferences about the behavior of the seasonal water cycle at other epochs, when the solar forcing would have been different from that at the present due to Mars having had different orbital elements. Measurements and analyses which are to play an important role in understanding the seasonal water cycle are summarized.

Description: Results of Viking investigations relevant to the CO2 cycle on Mars are presented, and the extensive modeling efforts directed towards understanding this cycle and its couplings to the seasonal cycles of water and dust are reviewed. It is found that winter condensation is suppressed either because the solid CO2 deposits are inefficient radiators or because of the scattering effects of CO2 clouds. With regard to the qualitative difference between the spring regression curves and between the wind systems for the two seasonal caps, it is suggested that the greater amount of aerosols in the atmosphere during northern winter results in a greater proportion of atmospheric condensation there than in the south. The seasonal pressure curves obtained by the Viking Landers during four Martian years are remarkably similar. It is suggested that the CO2 cycle is not sensitive to atmospheric dust and the meteorological variations accompanying global storms or that some subtle cancellation between different mechanisms suppresses variations.

Description: Layered deposits unique to the poles of Mars indicate long-term winter deposition of ice and sediment modulated by periodic climate change. The layered deposits contain at least two kinds of nonvolatile materials: one that is similar to the bright red dust raised in Martian dust storms, and one similar to dark sand dune materials observed at low and mild latitudes. The ice fraction of the deposits remains unknown. Because the present polar dust and ice budgets are poorly constrained, correlation of layer thicknesses with specific astronomical cycles remains very uncertain. Layered deposits in both polar regions appear to have been slightly more widespread in the past. Other sediments near the poles, and the estimated ages of the layered deposits, suggest that the polar sedimentary regime has evolved over the geologic history of Mars. Acquisition of good data on the vertical sequence of layer characteristics and better crater retention ages should allow revealing comparisons with astronomically driven cycles and secular atmospheric changes.

Description: The current understanding of the Martian atmospheric circulation and boundary layer is described. The available meteorological data and the first-order constraints that can be derived from them are reviewed. Pertinent aspects of atmospheric radiation on Mars are briefly presented; their main features are the short radiative time constraints on Mars, as compared to earth, and the important role of suspended dust in providing a potent thermal drive for the atmosphere. The current understanding of the Martian atmospheric circulation and its various components - the zonal-mean, zonal, and meridional flows, stationary and traveling planetary waves, atmospheric thermal tides, topographic wind systems, free modes, and gravity waves - is examined. Present-day knowledge of the PBL on Mars is reviewed, with particular attention given to the Viking Orbiter and Lander observations relating to the winds required for raising dust from the surface. The theory of the origin and decay of great dust storms on Mars is reviewed.

Description: Attention is given to Martian channels and valley networks, since they have become a principal element of evidence to the effect that the Martian atmosphere evolved from an early volatile-rich state to its present condition. The outflow channels are relatively young, later Hesperian or Amazonian in age. They formed by immense outbursts of fluid from subsurface sources. Complexity in outflow-channel morphology was generated by varying amounts of sediment and ice in the aqueous-fluid flow systems. The overall cataclysmic-flood morphology may thus be locally transitional to morphologies generated by ice and debris flowage. Although local areas of valley networks, such as on Alba Patera, formed coevally with outflow channel activity, regionally extensive networks dominate in the heavily cratered terrains. The morphology of many valleys suggests genesis by ground-water sapping; for some valleys, surface runoff may have been more important.

Description: The physical volcanology of Mars is reviewed, with particular attention given to the diversity of volcanic landforms, the implied styles of eruption associated with the construction of these landforms, the inferred internal structure of the volcanoes, and the influence that the eruptions have had on the Martian environment (both local and global in scale). Volcanism in the central highlands appears to have been explosive in character, while most of the constructional activity in the northern plains was effusive. Highlands volcanism appears to be relatively old compared to that in the northern hemisphere. There is evidence for the existence of large magma chambers and very high effusion rate eruptions on Mars. Tectonic deformation associated with volcanic constructs is primarily a consequence of loading and magma transport, while deformation in the volcanic plains reflects stresses associated with Tharsis and major impact basins.

Description: Attention is given to recent major advances in the definition and documentation of Martian stratigraphy and geology. Mariner 9 provided the images for the first global geologic mapping program, resulting in the recognition of the major geologic processes that have operated on the planet, and in the definition of the three major chronostratigraphic divisions: the Noachian, Hesperian, and Amazonian Systems. Viking Orbiter images permitted the recognition of additional geologic units and the formal naming of many formations. Epochs are assigned absolute ages based on the densities of superposed craters and crater-flux models. Recommendations are made with regard to future areas of study, namely, crustal stratigraphy and structure, the highland-lowland boundary, the Tharsis Rise, Valles Marineris, channels and valley networks, and possible Martian oceans, lakes, and ponds.

Description: The paper divides the high points of telescopic observations of Mars into three time periods: historical, missions support (recent), and present. Particular attention is given to visual and photographic observations, with brief discussions of spectroscopic and polarization studies. Major topics of Martian phenomena included are albedo features, polar caps, dust storms, and white clouds. The interannual variability of the recessions of seasonal polar caps has been compared to dust storm activity, but this relationship remains uncertain. Only a very limited number of canals can be related to markings on the Viking images. The remainder are argued to be optical illusions created by observers pushing their perceived resolution beyond practical limits.