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  • 1
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    Accademia di Scienze Fisiche e Matematiche di Napoli
    Publication Date: 2017-04-04
    Description: This paper aims to trace the documentary history of the Royal Collection of Physics Apparatus,currently housed in the Physics Museum at the Federico II University of Naples...
    Description: Published
    Description: 47 - 59
    Description: 3.10. Storia ed archeologia applicate alle Scienze della Terra
    Description: N/A or not JCR
    Description: reserved
    Keywords: History of Science ; Physics ; Scientific Collection ; Naples ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-03
    Description: (extended abstract)
    Description: INGV, Regione Sicilia, Ministero Sviluppo Economico
    Description: Published
    Description: Ettore Majorana Foundation and Centre for Scientific Culture, Erice, Sicily
    Description: 5.9. Formazione e informazione
    Description: open
    Keywords: Inertia ; Physics ; Fluid Dynamics ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 3
    Publication Date: 2020-02-10
    Description: A discussion of several kinds of ether as they can be inferred from Geosciences, and what the existence of the ether could imply for Physics and Cosmology. A tribute to the memory of my mentor Franco Selleri.
    Description: This article is written in honor of my mentor Franco Selleri who has helped to consolidate my awareness of the existence of a medium subtended to ordinary matter, and from which everything comes. From my field, the Earth Sciences, come clues converging on an important role of the ether in the geological evolution of Earth and planets, as well as all the structures of the universe. Paleogeographic reconstructions allow a rough quantitative evaluation of the amount of new ordinary matter that is added to the planet in the unity of time, and the consequent statement of some cosmological consequences and on the inner energy balance of the Earth. The concept of central flow of ether defended here is different from the Lorentian stationary ether, but the two concepts could be made compatible.
    Description: SISFA
    Description: Published
    Description: 307-316
    Description: 2TM. Divulgazione Scientifica
    Keywords: Expanding Earth ; History ; Geophysics ; Physics ; Ether flow ; Earth's inner heat balance ; Cosmology ; History and Philosophy of Science
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 4
    Publication Date: 2022-05-26
    Description: In 2001, the Geophysical Fluid Dynamics Summer Study Program grappled with Conceptual Models of the Climate. Eli Tziperman (Weizman Institute), Paola Cessi (Scripps Institution of Oceanography) and Ray Pierre- Humbert (University of Chicago) provided the principal lectures. This introduction gave us all a glimpse into the complex problem of the climate, both in the present, past and future, and even on other planets. As always, the next weeks of the program were filled with many seminars from the visitors, and culminated in the fellow's reports.
    Keywords: Climatic changes ; Physics
    Repository Name: Woods Hole Open Access Server
    Type: Technical Report
    Format: 18131236 bytes
    Format: application/pdf
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  • 5
    ISSN: 0303-2647
    Keywords: Animals ; Cell nucleus ; Evolution ; Plants ; Protoctista ; Taxonomy
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    The visual computer 2 (1986), S. 159-163 
    ISSN: 1432-2315
    Keywords: Education ; Animation ; Computer graphics ; Physics ; Solar system
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract Within the Jet Propulsion Laboratory in Pasadena, California, state of the art computer graphics animation is done in the Computer Graphics Laboratory. The topics of the animations cover many scientific disciplines. Specific features of the system developed there, both hardware and software, are discussed. The prime mover of the effort is Dr. James F. Blinn of Pasadena; his role and experiences are elaborated. Their current largest project is The Mechanical Universe; the system is used for its production.
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  • 7
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    Springer
    Machine vision and applications 8 (1995), S. 187-193 
    ISSN: 1432-1769
    Keywords: Tracking ; Segmentation ; Pigs ; Animals ; Computer vision
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract An algorithm was developed for the segmentation and tracking of piglets and tested on a 200-image sequence of 10 piglets moving on a straw background. The image-capture rate was 1 image/140 ms. The segmentation method was a combination of image differencing with respect to a median background and a Laplacian operator. The features tracked were blob edges in the segmented image. During tracking, the piglets were modelled as ellipses initialised on the blobs. Each piglet was tracked by searching for blob edges in an elliptical window about the piglet's position, which was predicted from its previous two positions.
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  • 8
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    Springer
    Journal of molecular evolution 41 (1995), S. 238-246 
    ISSN: 1432-1432
    Keywords: Cellular slime molds ; Animals ; Fungi ; Plantae ; Maximum-likelihood method ; Evolution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The phylogenetic position of Dictyostelium inferred from 18S rRNA data contradicts that from protein data. Protein trees always show the close affinity of Dictyostelium with animals, fungi, and plants, whereas in 18S rRNA trees the branching of Dictyostelium is placed at a position before the massive radiation of protist groups including the divergence of the three kingdoms. To settle this controversial issue and to determine the correct position of Dictyostelium, we inferred the phylogenetic relationship among Dictyostelium and the three kingdoms Animalia, Fungi, and Plantae by a maximum-likelihood method using 19 different protein data sets. It was shown at the significance level of 1 SE that the branching of Dictyostelium antedates the divergence of Animalia and Fungi, and Plantae is an outgroup of the Animalia-Fungi-Dictyostelium clade.
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  • 9
    Electronic Resource
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    Springer
    Journal of molecular evolution 42 (1996), S. 183-193 
    ISSN: 1432-1432
    Keywords: Small-subunit ribosomal RNA ; Phylogeny ; Animals ; Fungi ; Plants ; Alveolates ; Heterokonts ; Stramenopiles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The evolutionary relationships of four eukaryotic kingdoms—Animalia, Plantae, Fungi, and Protista—remain unclear. In particular, statistical support for the closeness of animals to fungi rather than to plants is lacking, and a preferred branching order of these and other eukaryotic lineages is still controversial even though molecular sequences from diverse eukaryotic taxa have been analyzed. We report a statistical analysis of 214 sequences of nuclear small-subunit ribosomal RNA (srRNA) gene undertaken to clarify these evolutionary relationships. We have considered the variability of substitution rates and the nonindependence of nucleotide substitution across sites in the srRNA gene in testing alternative hypotheses regarding the branching patterns of eukaryote phylogeny. We find that the rates of evolution among sites in the srRNA sequences vary substantially and are approximately gamma distributed with size and shape parameter equal to 0.76. Our results suggest that (1) the animals and true fungi are indeed closer to each other than to any other “crown” group in the eukaryote tree, (2) red algae are the closest relatives of animals, true fungi, and green plants, and (3) the heterokonts and alveolates probably evolved prior to the divergence of red algae and animal-fungus-green-plant lineages. Furthermore, our analyses indicate that the branching order of the eukaryotic lineages that diverged prior to the evolution of alveolates may be generally difficult to resolve with the srRNA sequence data.
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  • 10
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    Springer
    Environmental management 8 (1984), S. 309-324 
    ISSN: 1432-1009
    Keywords: Animals ; Indicators ; Air pollution ; Ecosystem responses
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract With existing and proposed air-quality regulations, ecological disasters resulting from air emissions such as those observed at Copperhill, Tennessee, and Sudbury, Ontario, are unlikely. Current air-quality standards, however, may not protect ecosystems from subacute and chronic exposure to air emissions. The encouragement of the use of coal for energy production and the development of the fossil-fuel industries, including oil shales, tar sands, and coal liquification, point to an increase and spread of fossil-fuel emissions and the potential to influence a number of natural ecosystems. This paper reviews the reported responses of ecosystems to air-borne pollutants and discusses the use of animals as indicators of ecosystem responses to these pollutants. Animal species and populations can act as important indicators of biotic and abiotic responses of aquatic and terrestrial ecosystems. These responses can indicate long-term trends in ecosystem health and productivity, chemical cycling, genetics, and regulation. For short-term trends, fish and wildlife also serve as monitors of changes in community structure, signaling food-web contamination, as well as providing a measure of ecosystem vitality. Information is presented to show not only the importance of animals as indicators of ecosystem responses to air-quality degradation, but also their value as air-pollution indices, that is, as air-quality-related values (AQRV), required in current air-pollution regulation.
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  • 11
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    Springer
    Journal of agricultural and environmental ethics 10 (1997), S. 249-267 
    ISSN: 1573-322X
    Keywords: Animals ; Asia ; consciousness ; Australia ; Hong Kong ; India ; Israel ; Japan ; New Zealand ; The Philippines ; Russia ; Singapore ; Thailand
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract The interactions between humans, animals and the environment have shaped human values and ethics, not only the genes that we are made of. The animal rights movement challenges human beings to reconsider interactions between humans and other animals, and maybe connected to the environmental movement that begs us to recognize the fact that there are symbiotic relationships between humans and all other organisms. The first part of this paper looks at types of bioethics, the implications of autonomy and the value of being alive. Then the level of consciousness of these relationships are explored in survey results from Asia and the Pacific, especially in the 1993 International Bioethics Survey conducted in Australia, Hong Kong, India, Israel, Japan, New Zealand, The Philippines, Russia, Singapore and Thailand. Very few mentioned animal consciousness in the survey, but there were more biocentric comments in Australia and Japan; and more comments with the idea of harmony including humans in Thailand. Comparisons between questions and surveys will also be made, in an attempt to describe what people imagine animal consciousness to be, and whether this relates to human ethics of the relationships.
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  • 12
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    Pharmacy world & science 15 (1993), S. 105-115 
    ISSN: 1573-739X
    Keywords: Calcium phosphates ; Drug compounding ; Excipients ; Particle size ; Physics ; Powders ; Tablets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Ten commercially available calcium phosphates used for direct tableting were evaluated. The particle size distributions, powder properties, Sorption isotherms and pH values of aqueous slurries were compared. All samples showed good or at least sufficient flowability. Scanning electron micrographs illustrated the different kinds of manufacturing and gave hints on their expectable behaviour under compaction pressure. The sorption isotherms of identical chemical substances, which had been manufactured by different methods, differed strongly. This can be related to their specific surface areas. Most of the hydroxylapatites have large surface areas and can absorb up to more than 15% water at 93% relative humidity. Dibasic calcium phosphate dihydrate was non-hygroscopic and absorbed less than 1% water. With the exception of monobasic calcium phosphate monohydrate all calcium phosphates behaved quite neutral in water. Monobasic calcium phosphate monohydrate can be regarded as a solid acid. Although the calcium phosphates are usually stable substances, the role of crystal water in the case of dibasic calcium phosphate dihydrate and monobasic calcium phosphate monohydrate is problematic due to possible interactions with active ingredients.
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  • 13
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 14
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 2-2 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 15
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 14-20 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A description is given of the procedure and equipment used for the purpose of studying the effect of hydrostatic pressure upon the capillary flow properties of polymer melts. Flow properties are reported for a low density polyethylene over a wide range of temperatures, die sizes, different pressures and hydrostatic pressures.
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  • 16
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 3-8 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was designed to show the nature of weathering of an elastomer poly( ester-urethane), and to indicate methods of overcoining the deficiency. Unprotected polymer, when exposed to UV radiation in a Weatherometer, showed deterioration which is characterized by loss of tensile strength, some increase in modulus, and a decreased extensibility of surface skin.
    Additional Material: 6 Ill.
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  • 17
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    Polymer Engineering and Science 1 (1961), S. 9-13 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Translated from: Vysokomolekuliarnye Soedineniia 2, 778-84 (May 1960). A thermomechanical study was made of the softening of crystalline polymers during uniform, uniaxial stretch and also of the effect of the rate of heating upon the softening or amorphous polymers. The effect of the tensile force on the thermo-mechanical behavior of various polymers was measured over the range 20 to 100 kg/cm2 and within wide temperature limits (-150° to 250°C). Ribbons 50 mm long, 2-4 mm wide and 0.05 to 0.5 mm thick served as specimens.
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  • 18
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    Polymer Engineering and Science 1 (1961), S. 26-30 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effectiveness of ultraviolet stabilizers of various types of polyolefin, cellulose ester, and poly (vinyl chloride) plastics was investigated. Most of these stabilizers were of the ultraviolet-absorbing type but two were of the nonabsorbing type. Exposures were made both outdoors and indoors in a Twin-Arc Weatherometer. The latter was modified by the addition of ten 20-watt fluorescent sun lamps to remedy the short-ultraviolet deficiency of the enclosed carbon arcs.
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  • 19
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    Polymer Engineering and Science 1 (1961), S. 21-25 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The degradation of plastics by ultraviolet energy and the use of protective ultraviolet absorbers to improve stability necessitate studies along several lines. These include (a) the measurement of the ultraviolet spectral energy distribution of sunlight and of the indoor accelerated test sources, (b) the measurement of the extent of degradation as a function of the wavelength of the incident radiation, (c) an estimate of the absorbing effectiveness of the added protective agents, and (d) the stability of the protective ultraviolet absorbers themselves.
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  • 20
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    Polymer Engineering and Science 1 (1961), S. 40-46 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The non-Newtonian flow behavior of polyethylene has been investigated with respect to the effects of molecular weight and molecular weight distribution. Effects of die geometry on melt fracture as well as preliminary extrudate orientation studies are discussed.
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  • 21
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 31-39 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was designed to show the nature of weathering of an elastomer poly(ester-urethane), and to indicate methods of overcoming the deficiency. Unprotected polymer, when exposed to UV radiation in a Weatherometer, showed deterioration which is characterized by loss of tensile strength, some increase in modulus, and a decreased extensibility of surface skin.
    Additional Material: 16 Ill.
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  • 22
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    Polymer Engineering and Science 1 (1961), S. 52-52 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 23
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 47-51 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new curing system which yields room temperature curing epoxy adhesives with high bond strength and softening point has been developed for service in contact with high explosives. Bisphenol A type resins cured with hydroxyl alkyl phosphate acid esters are used. Short pot life and relatively low alkali resistance are drawbacks of the system.
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  • 24
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 25
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    Polymer Engineering and Science 1 (1961), S. 54-55 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 26
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    Polymer Engineering and Science 1 (1961), S. 56-56 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 27
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 73-79 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article includes a comparison of the adhesive properties of bisphenol-A expoxides at 300°K and 76°K with respect to the molecular weight of the uncured resins. Joints of 2024 aluminum were tested at 300°K and 76°K in tensile-shear and in impact-shear, and total linear thermal contraction of the cured resins was measured between the two temperatures. Results are discussed with respect to residual joint stresses and adsorptive properties of the resins.
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  • 28
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    Polymer Engineering and Science 1 (1961), S. 63-67 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method for measuring heat stability and temperature of degradation of thermosetting plastics is described, as well as an improved method for the determination of transition temperature into glassy or viscous state for thermosetting resins. Magnitude of elastic deformation is tied in with length of polymer chain and lattice density.
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  • 29
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    Polymer Engineering and Science 1 (1961), S. 68-72 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: During the last thrity years, dielectric measurements have been employed extensively to provide a better understanding of the interactions between polymer and plasticizer in various thermoplastic formulations. Recently, a series of melamine resins, plasticized to the extent that shrinkage and internal stress were modified, became available. Since there is little information in the literature concerning the dielectric properties of such thermosetting resins, a study was made of the variation of dielectric constant and loss as a function of frequency and temperature.
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  • 30
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    Polymer Engineering and Science 1 (1961), S. 57-62 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Derivatives of 2-hydroxybenzophenone are well-known stabilizers for such polymers as cellulose acetate butyrate and polyesters. Their stabilization effectiveness is commonly associated with their ability to screen a polymer from the harmful ultraviolet radiation found in sunlight. They also satisfy other requirements for effective stabilizers, namely, compatibility with many polymers and an inherent stability to ultraviolet light. Several other functions of 2 hydroxybenzophenones in stabilizing a polymer to ultraviolet light have been postulated, but little experimental data related to them are available. This paper deals with some of the additional functions of 2-hydroxybenzophenones in weathering stabilization as investigated by nuclear magnetic resonance spectroscopy (NMR) and electron paramagnetic resonance spectroscopy (EPR).
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  • 31
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    Polymer Engineering and Science 1 (1961), S. 80-85 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The magnitude and temperature dependence of the electrical resistivities of a number of thermoplastic and thermosetting high polymers have been determined. Activation energies for the electrical conduction process Ee have been calculated and found to vary from 12 to 60 Kcal/mole depending upon the structure of the polymer. Results are interpreted in terms of an ionic diffusion process and discussed in terms of the structure of the polymers.
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  • 32
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    Polymer Engineering and Science 1 (1961), S. 102-103 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 33
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 34
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    Polymer Engineering and Science 1 (1961), S. 86-92 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For broad ranges of operating conditions and a wide variety of high pressure polyethylenes, the flow data obtained from a high shear viscometer and a commercial extruder are identical. Discrepancies between flow data can result from non steady state viscosities in the high shear viscometer, or from cooled screw extruder operation. In the broad regions in which the flow data concur, the readily obtained viscometer data are suitable for predictions of extruder performance. The principle is illustrated by the good correlation of a viscometer flow curve parameter and the screw power consumption in the extruder. Principles outlined for flow data identity and extruder performance prediction are believed to be general, but the quantitative limits defined are specific to the extrusion devices involved.
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    Polymer Engineering and Science 1 (1961), S. 93-100 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Recent technology has evolved a number of dissimilar thermoplastics which under conditions of ambient temperature and impact loading show both the high modulus, which is mainly a property of brittle polymers in the glassy state, and also the impact resistance, such as may be expected of polymers in the rubbery state. Several of these special plastics were examined by electronmicroscopy and also with respect to several aspects of their mechanical behavior to establish by direct observation and inference whether or not different types of plastics exhibit some common features of structure which promote impact resistance. These observations suggest the hypothesis that special circumstances of domain heterogeneity can override many other variables of composition or molecular structures in controlling the fracture mechanism.
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    Polymer Engineering and Science 1 (1961), S. 104-104 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 1 (1961), S. 105-108 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For resins of room temperature density 0.91 to 0.96 g/cc, enthaply and internal energy diagrams have been developed from 0 to 200°C and up to 1000 atmospheres. These diagrams can be used for estimating properties for which data are not available, and provide unified view of many properties of polyethylene under conditions of fabrication and use. Extent of crystallinity estimates can be made from enthalpy, internal energy, specific volume, compressibility and melting point data provided for hypothetical amorphous, crystalline and actual resins.
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    Polymer Engineering and Science 1 (1961), S. 109-112 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Griffith theory for brittle fracture predicts that the tensile strength should be inversely proportional to the square root of the size of a defect or flaw in the sample tested. The validity of this relation has been investigated for the glassy polymers, poly(methyl methacrylate) and polystrene. The results indicate that the strength of the polymers depends on two factors: (1) the surface energy, and (2) the inherent flaw size. The surface energy is primarily that dissipated in a viscous flow process and the inherent flaw size is related to the tendency of the polymer to craze under stress.
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    Polymer Engineering and Science 1 (1961), S. 121-132 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanism of formation of tubular polythene film is a complicated process, and extensive studies have shown that the properties of the film made are influenced profoundly and in a complex way both by the processing conditions used by certain design features of the equipment. Studies of the effect of the extrusion variables on the more important film properties, both optical and mechanical, are reviewed in this paper. The results are discussed in terms of the fundamental nature of polythene film, its surface, its crystalline structure and its orientation.
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    Polymer Engineering and Science 1 (1961), S. 113-120 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow patterns in the channel of a screw extruder have been investigated in a study utilizing a model extruder with stationary screw and a rotating, transparent barrel. Photographs of flow streamlines at conditions over the full range of output restriction are presented for a non-Newtonian fluid. A technique employing photographs of particle tracers was used with the same apparatus to permit quantitative measurement of velocity profiles with both a Newtonian and a non-Newtonian fluid.
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    Polymer Engineering and Science 1 (1961), S. 139-142 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new series of inorganic-organic high polymers have been synthesized namely; the metaloxene polymers of phenolaldehyde. Titanium (IV), Zirconium (IV) and Hafnium (IV) phenolaldehyde have been prepared and other metals especially the refractory type metals may merit further development as calorobic plastic materials. The hafnium resin has been compression molded into a rocket-nozzle insert shape with satisfactory rocket-firing results.
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    Polymer Engineering and Science 1 (1961), S. 147-148 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 1 (1961), S. 143-146 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This article describes preparation of resins as described in the title above, and the effect of concentration of the diepoxide, dimer acid, and initiator (stannous octoate). Proportion of dimer acid and diepoxide has a marked influence on hardness and tensile properties of resins. Change in tensile properties upon aging correlates very well with change in hardness. Higher proportions of dimer acid produce softer, more flexible resins. The resins have unique electrical properties at temperature up to 175°C, apparently because of the high proportion of hydrocarbon in the resin.
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    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 1 (1961), S. 133-138 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Twelve plastics representing various chemical structures were studied as part of a program to determine the utility of plastics as packaging materials in the high radiation presentation of food. The plastics were exposed to selected dosages of Cobalt-60 gamma radiation in vacuum and in air. Gas evolution and changes in infrared spectra as a result of irradiation were used to hypothesize the relative stability of these plastics to irradiation. Based on these facts it was found that plastics containing conjugated ring systems, ionic linkages, and chlorine in side groups were the most stable.
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    Polymer Engineering and Science 1 (1961), S. 150-151 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 1 (1961), S. 152-152 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 1 (1961), S. 153-163 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Permeability properties depend on the size, shape and polarity of the permeating molecule. Permeability of organic liquids, polar or non-polar, can be quite accurately predicted if the chemical composition of the permeant is known. By the choice of an arbitrary value (unity) as an indicator for the carbon atom, numbers specific to each structural element of the permeating molecule can be computed from previous experimental data. These numbers, herein called “Permachor” values (π), then combine by simple addition to relate the logarithm of a liquid's permeation in polyethylene.
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    Polymer Engineering and Science 1 (1961), S. 169-176 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Mobile ions can be introduced thereby increasing the conductivity, with a limiting operating temperature range of 200°-250°C. Conductivity can be increased with the formation of conjugatd double bonds. Polymeric compounds may be synthesized with metallocyclic groups, where an atom of metal is bound to nitrogen atoms in a heterocyclic system in the basic chain of conjugation of the macromolecule. Here phtalocyanimes possess the greatest thermal stability. Lastly there are semiconducting polymers with conjugated double bonds containing hetero-atoms in the principle chain, having unpaired electrons of oxygen and nitrogen.
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    Notes: If temperature variations of forces in both directions are observed simultaneously at constant simple dimensions, internal energy and entropy changes on elongation in those directions may be calculated at constant volume and in the more common experimental condition of constant pressure. Thermodynamic derivatives at constant volume are important for fundamental molecular interpretation being related to configuration change. Constant pressure quantities were therefore changed into constant volume ones by the use of an evaluated correction term, involving average Young Moduli and thermal expansion coefficient.
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    Polymer Engineering and Science 1 (1961), S. 177-179 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Equipment is described for measurement of Young's and shear modulus on the same identical polymer sample, by a free-vibration method. Strain gauges are used as sensors in an automatic recorder. Young's modulus and damping, shear modulus and damping and Poisson's ratio are reported over a range of temperature for polypropylene, Nylon 66 and poly (methylmethacrylate). It is found that Poisson's ratio shows a dip in the glass transition region and that values greater than the infinitesimal strain limit of 0.5 are obtained in the rubbery region.
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    Polymer Engineering and Science 1 (1961), S. 180-180 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 1 (1961), S. 181-190 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Adsorption studies on powdered and planar surfaces yield significant information regarding the rate and degree of interaction between the substrate and the organic adsorbate. Investigative tools include contact angle measurement, radiotracer methods, ellipsometry, x-ray diffraction, electron diffraction, elegant infrared techniques, dynamic desorption techniques, and film balance applications.
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    Polymer Engineering and Science 1 (1961), S. 214-223 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A solution of substituted alkyl alkoxy silanes was applied to E-glass filament strands before forming glass-resin composite hoops, which were tested to relate changes in hoop physical properties to the nature of the coupling agent-size application. Continuously heat cleaning E-glass in oxygen-enriched air gives a strand that, when properly coated with size and laminated, makes a hoop with superior strength and modulus properties.
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    Polymer Engineering and Science 1 (1961), S. 224-233 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Theoretically a monolayer or insignificant weight per cent of coupling agent should give optimum properties for fiber glass-resin composites, contrary to commercial practice. Studies of variation of chemical bonding between the coupling agent and the resin and the study of the degree of bonding of the coupling agents to the glass by extraction techniques have not explained this effect. However, new techniques of electron microscopy have revealed details of loading distribution and agglomeration on the glass fiber which tend to explain this effect.
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    Polymer Engineering and Science 1 (1961), S. 199-213 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The chromium complex is chemically bonded by ion exchange with alkali cations to strongly acidic sites in the glass surface. These sites are formed by the isomorphous replacement of silicon by boron and aluminum in the network structure. Polymerized complexes are better bonding agents than monomeric ones. Specific interactions between organic groups on the chrome complex and the bonding resins also determine laminate strength and water resistance.
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    Polymer Engineering and Science 1 (1961), S. 191-198 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Interfacial reactions between organosilane-treated fiberglass and styrene, and bond conditions in these and in polymerized ethylene oxide and epichlorhydrin-E-glass systems were investigated. The vinyl functionality of some alkenylsilanes showed little effect on the polymerization of styrene on E-glass. The polymerization of this aromatic monomer on vinyltrichlorosilane-reacted fiberglass did not result in interfacial bond formation. Sorption of water on organosilane-coated glass at different temperatures suggested that permeation of the adsorbate into the bulk of the substrate was determined by diffusive transfer of water molecules.
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    Polymer Engineering and Science 2 (1962) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 1 (1961), S. 234-244 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Evidence indicates that there is a chemical bond between the coupling agent of either silane or chrome complex type and the glass substrate, but that this chemical bond may be strong or weak, depending on the elements making up the bond and the other elements in the immediate area surrounding the bond. These elements can exert either a beneficial or detrimental effect on the strength of that bond. Other evidence is given to show that a vapor phase treatment that applies silane coupling agents like A-1100 to “E” glass gives the highest known strength retention values. A mechanism is advanced to explain the bridging of unreactive sites on glass surfaces by silane coupling agents applied from solution.
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    Polymer Engineering and Science 2 (1962), S. 2-4 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: By following the changes in torsional modulus as a function of time, the kinetics of crystallization of three copolymers of vinylidene chloride containing 10% mole % alkyl acrylate were investigated and the geometrical growth and nucleation constant of the Avrami equation was determined. Isotherms were superimposable within certain temperature ranges while the nucleation constant decreased with a decrease in temperature. Rate of crystallization increased with increase of the alkyl side chain length.
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    Polymer Engineering and Science 2 (1962), S. 5-6 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: This paper compares results of four accelerated oxidation tests: the hot milling test, reaction with fuming nitric acid, absorption of oxygen gas at elevated temperature and the redox system - polyethylene - lead peroxide ignition test. The length of the induction period, is a product of antioxidant concentration but not of the inherent oxidizability of the resin. Discrepancies between induction periods as measured by oxygen absorption and hot milling differ because in the former the volume of pure oxygen absorbed is measured and in the latter the electrical consequences of air oxidation. In addition other polymeric degradation occur in milling. Nitric Acid treatment measures the effect of nitric acid upon the specific viscosity and is useful for chain scission comparisons. The ignition tests reflect both inherent oxidizability and presence of antioxidant. All four tests reflect oxidation parameters.
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    Polymer Engineering and Science 2 (1962), S. 21-24 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The effects of moisture and rather large doses of reactor radiation (∼4 × 1011 ergs/gm) on the dynamic properties of polymerized epoxy resins have been investigated over the temperature range of 80°-450°K and at frequencies from 200 to 1400 cps. Data are presented for both unfilled and aluminum-filled systems of a bisphenol A based epoxy, (Epon 828) cured with metaphenylenediamine. Moisture absorption (0.88%) causes a shift of the main glass transition near 440°K to lower temperatures (∼25 degrees for unfilled epoxy). This is similar to the plasticizing action of small molecules absorbed in other polymers such as nylon 6-6. Irradiation to a dose of 4 × 1011 ergs/gm (4 × 109 rads) causes a shift to lower temperatures (∼50 degrees) of the onset of the main transition, and, in addition, results in both a shift to lower temperatures and a decrease in maximum height of the damping peak near 250°K. Chain scission, in a loosening of the structure and the breaking up of the partially flexible connecting groups, may be responsible for these radiation effects.
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    Polymer Engineering and Science 2 (1962), S. 25-27 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: One of the reasons for purification of low-pressure polymerization products is the assumed degradation effects of retained catalysts. Degree of degradation was determined from the change in viscosity number. Effects of catalysts on active sights and deactivation were noted along with degradation in the presence of air and oxygen in addition to determining, the effect of antioxidants. Individual components of the catalyst may have the ability to intensify the effect of any antioxidant and affect the rate of degradation where catalyst influence was better defined in the presence of oxygen.
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    Polymer Engineering and Science 2 (1962), S. 55-56 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 2 (1962), S. 32-54 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A bibliography of references from 1957 through 1960 was prepared containing the following sub-headings: Protective Ultraviolet Absorbers, Light Sources, Light Fastness Evaluation, Plastics Degradation and Stabilization Polyesters, Polystyrene, Polyvinylchloride, Polyethylene, Polyacrylo and Methacrylonitrile, Polymethyl Methacrylate, Cellulose Acetate and Nitrate, Polyvinyl alcohol, Polyamides, Wool, Rubber, Silicone Resin, Wood, Dyes and Paint Films, Epoxy, Melamine and Urea Formaldehyde, Oil Films, General Mechanical Degradation, Free Radicals and ESR, Photochemistry, Photochemistry and Spectroscopy at Low Temperatures, Antioxidants and Free Radical Scavengers, Flash Photolysis, Energy Transfer, Phosphorence and the Triplet State, Fluorescence.
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    Polymer Engineering and Science 2 (1962), S. 65-73 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The experimental techniques used to measure the dynamic shear behaviour of polymers at low frequencies, that is below 10 sec-1, are discussed with particular reference to the torsion pendulum. The various types of relaxations which can occur in amorphous and semicrystalline polymers are considered. Polymethyl methacrylate, polyethyl methacrylate, and polystyrene are examples of amorphous polymers. The effects of crosslinking, intermolecular forces, steric effects, and plasticizers on the main glass transition of other amorphous polymers are also described. Polytetrafluorethylene is an example of a linear, semi-crystalline polymer. The effect of introducing trifluoromethyl groups along the chain in copolymers of tetrafluoroethylene and hexafluoropropylene is described. Results obtained with polypropylene are also discussed.
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    Polymer Engineering and Science 2 (1962), S. 57-64 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A brief description is given of the use of a resonant-bar type apparatus for measurement of the dynamic elastic modulus and the associated damping or internal friction of a solid polymer. Each different type of polymer is found to exhibit a characteristic internal friction spectrum when explored over the temperature range from liquid nitrogen temperatures to the melting point. These spectra are characterized by the occurrence of one or more peaks in the mechanical loss data centered about certain temperatures, accompanied by an associated drop in dynamic modulus. By variation of polymer composition and of polymer structure, by addition of low molecular weight compounds, and by subjection of samples to irradiation, considerable additional information can be gained that would be helpful in determining the nature of the molecular mechanisms that are responsible for the observed transitions. Dynamic mechanical data are presented and discussed for a series of poly(alpha olefins) with methyl, ethyl, propyl, isopropyl and isobutyl side chains to depict the effects of crystallinity, side chain length and side chain structure on the observed transitions.
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    Polymer Engineering and Science 2 (1962), S. 28-31 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A series of thirty-three phosphites of varied structural variations were tested at 177°C in a vinyl compound utilizing co-precipitated barium cadmium laurate or a combination of barium nonylphenate and cadmium 2-ethylhexoate as the primary stabilizer. Best activity was found with mixed alky-aryl phosphites.
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    Polymer Engineering and Science 2 (1962), S. 74-81 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: For polymers the isothermal creep compliance shows a major dispersion region from the glassy compliance Jg to the quasi-equilibrium compliance Je. Further increases in compliance are associated with viscous flow. There is no detailed molecular mechanism to explain these phenomena although the modified Rouse theory and the postulated entanglement coupling present a reasonable physical concept. To empirically describe the creep curves of polycrystalline metals, a power law (\documentclass{article}\pagestyle{empty}\begin{document}$ \dot \varepsilon $\end{document} = mt-n) has frequently been used, where \documentclass{article}\pagestyle{empty}\begin{document}$ \dot \varepsilon $\end{document} is the creep rate, t is the time and m and n are constants with O≤n≤. In particular, n equal to 2/3 leads to Andrade creep, a relationship which is applicable to both polymers and metals. A comparison of the creep behavior of polymers and polycrystalline metals shows many points of similarity.
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    Polymer Engineering and Science 2 (1962), S. 82-85 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Dielectric measurements were used to study dielectric constant and loss index of poly(p-chlorostyrene) and poly(m-chlorostyrene) over a temperature and frequency range. Relaxation processes are observed and mechanisms are proposed for crystalline structures. Axial rotation discussed here has been used to explain NMR data.
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    Polymer Engineering and Science 2 (1962), S. 94-96 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 2 (1962) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Notes: The principles of nuclear magnetic resonance, NMR, are briefly reviewed and the use of proton resonance for the study of segmental motion in solid high polymers is outlined. Studies of the temperature dependence of NMR spectra have shown that both completely amorphous and partially crystalline polymers exhibit NMR line narrowing processes at temperatures near the respective glass transition temperature due to increased segmental motion. The presence of small molecules, such as H2O or D2O in the polyamides, or a change of tacticity to a greater isotatic content, such as for poly(methyl methacrylate), is found to lower this line narrowing process on the temperature scale. Heating of polyethylene single crystal aggregates at temperatures somewhat below the melting point also leads to a decrease in temperature for this line narrowing process, presumeably due to the introduction of defects in the polymer crystals. In the ≤ 77°K to 200°K region numerous polymers having methyl and methyl group containing side chains are found to exhibit line width and second moment dispersions, attributed to methyl group rotation. If the methyl group is attached to a phenyl or ester side chain, methyl rotation takes place at 77° K and below.
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    Polymer Engineering and Science 2 (1962), S. 97-98 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 2 (1962), S. 99-99 
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    Notes: New methods, new structures leading to novel properties are presented in a collection of summaries. Areas discussed were: thiosemicarbazides, organometallic initiation of allene polymerization, poly(1,1,4,4,-tetramethyl-1,3-butadiene), emulsion polymerization of vinyl acetate with protein detergent solubilizing agents, alkali metal organic catalysts for stereospecific polymerization, anionic polymerization of dienes, rate constants in anionic polymerization, a series on polymerization by oxidative coupling with amine copper salt catalysts, block polymerization by vapor phase swelling, intra-intermolecular propagation in the solid-state and radiation induced polymerization.
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    Polymer Engineering and Science 2 (1962), S. 101-102 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 2 (1962), S. 102-103 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 2 (1962), S. 106-107 
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    Polymer Engineering and Science 2 (1962), S. 108-109 
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    Polymer Engineering and Science 2 (1962), S. 107-107 
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    Polymer Engineering and Science 2 (1962), S. 116-117 
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    Polymer Engineering and Science 2 (1962), S. 117-118 
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    Polymer Engineering and Science 2 (1962), S. 119-121 
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    Notes: α-Chloronaphthalene plus 30 weight percent of dimethylphthalate was the solvent with 0.5% ethyl cellulose as stabilizer. A polymer concentration of 0.0025% gave optimum results. A parameter S which is defined as the difference in temperature between 20% and 50% of the total reduction in phototube output is related linearly to a parameter of the Wesslau distribution.
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    Polymer Engineering and Science 2 (1962), S. 122-125 
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    Notes: Tris-hydroxymethylphosphine oxide (THPO) derived from commercially available tetrakishydroxy-methylphosphonium chloride (THPC), was studied for its flame retardant properties in reactions with carboxylic acids, anhydrides, diisocyanates, urea, phenol, acyl and aroyl halides. Then the monobenzylated derivative of THPO referred to as BHPO was studied, which is more stable and more reactive with difunctional molecules.
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    Polymer Engineering and Science 2 (1962), S. 126-134 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Failing stresses of glass-reinforced plastics and of polystyrene were determined at room temperature. It was found that if an initial load of 40% of the short-term tensile strength of the material is imposed, good agreement exists between the results of accelerated tests and long-term, fixed load measurements for periods of 10,000 hours for the reinforced plastics.
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    Polymer Engineering and Science 2 (1962), S. 139-139 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 2 (1962), S. 135-138 
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    Notes: Silicas have been synthesized of which the OH groups have been substituted for organic radicals with double bonds. The methanol, benzene and heptane sorption isotherms of the olefin-substituted silica specimens have been determined. It has been shown that the sorption of the vapors decreases with increasing substitution of the OH group by the organic radicals. The organosubstituted silicas were used as fillers of polymethylmethacrylate.
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    Polymer Engineering and Science 5 (1965), S. 246-253 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Studies of polypropylene oxyluminescence show the luminous intensity to be dependent upon the degre of oxidation. The length of the low intensity level portion of the luninescence curve, or pseudo induction period, was found to be a measure of the useful stabilizer life, and the intensity of this portion indicative of the effectiveness of stabilization. The effect of peroxide decomposers was studied and results indicate that peroxide reactions are major producers of luminescence. Analysis of the accepted modes of polymer oxidation, in view of our luminescence findings, indicate that the rate of luminescence buildup should depend upon ease of R. formation and the luminous intensity should be dependent on peroxy radical concentration. The effect of tertiary-carbon content on luminescence was also investigated, and luminous intensity was found to be dependent upon the amount of polymer branching. Model Compounds having slight structural variations were examined and were found to produce different intensity-time curves during oxidation, which may be attributed to ease of formation of a reactive site and subsequent peroxy radical reactions.
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    Polymer Engineering and Science 5 (1965), S. 263-269 
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    Notes: Sixteen polymers containing thiazole and aromatic rings in the polymer chain were prepared and investigated for the production of fibers and films that would be useful up to about 500°C. None of these polymers was completely satisfactory. Some of the polymers gave tough fibers and films, but they had relatively low melting points (〈300°C). Other polymers did not melt below 500°C, but they did not have good fiber and film forming properties because of their low molecular weights. Fibers and films of one of the polymers (polytetramethylenephenylenethiazole) were prepared, and their physical properties, hydrolytic stabilites under acid and alkaline conditions, and resistence to ultraviolet and gamma radiations were determined.
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    Notes: This paper is an account of some studies of the mechanism of degradation of an uncrosslinked polyurethan prepared from poly(propylene oxide) (PPO) and 2,4-tolylene diisocyanate (TDI) at temperatures up to 320°C in a vacuum or inert atmosphere. Fractionation of polymers before and after degradation provides information about the mechanism of degradation since the molecular weight distributions obtained are dependent on the mode and sites of bond scission. A recent publication describes the column elution method of fractionation developed for undergraded and slightly degraded PPG-TDI. PPO-TDI gives essentially most probable molecular weight distributions at an initial intrinsic viscosity [η] of ∼ 0.68 dl/g and also after degradation to [η] ∼ 0.24 dl/g. This invariancy of the distribution strongly suggests a randon scission process. Other types of degradation, e.g., free-radical unzipping initiated at the chain ends, could also give invariant most probable distributions. However, such depolymerizations would be accompanied by much larger extents of volatilization than were observed for these polymers (〈5% volatilization).
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    Polymer Engineering and Science 6 (1966), S. 65-70 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Moisture present in epoxy anhyride composites may hydrolyze the anhydride and cause major changes in the mechanical and chemical properties of the final composite. Heat distortion data and infrared spectroscopy are used to analyze the changes caused by the presence of the moisture. As the concentraton of water is increased, there is a decrease in the heat distortion or gass transition temperature. The decrease is due to a change in the crosslinking network and is caused by the reduction of the functonality of the epoxy group for acid as compared to the anhydride. Where rigid specifications must be met it is essential that the moisture level in the fillers, resins, etc. be kept constant.
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