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  • hydrothermal synthesis  (1)
  • laser damage threshold  (1)
  • polyethoxydisiloxanes  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 19 (2000), S. 271-274 
    ISSN: 1573-4846
    Keywords: sol-gel processing ; HR coatings ; ZrO2 ; hydrothermal synthesis ; laser damage threshold
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract High laser-damage resistant coatings are very important in high power laser systems. In this study ZrO2 thin films are prepared by sol-gel spin-coating technology from suitable zirconia aqueous colloidal suspensions containing nano-crystalline ZrO2 at room temperature synthesized by a hydrothermal process from an inorganic precursor (ZrOCl2·8H2O). By adding a soluble organic binder PVP to the suspension prior to application, it is possible to substantially increase the coating refractive index and the abrasion-resistance as well as the laser damage threshold. The features of the coatings and the colloidal suspensions are investigated. Multilayer highly reflective dielectric coatings are also elaborated by applying quarterwave-thick alternating coatings of the binder-aided zirconia and silica, which is prepared with the sol-gel process from TEOS. To achieve 99% reflectivity, 19–21 layers are required. Single shot laser damage tests are carried out using a high power laser at 1064 nm wavelength with a pulse duration of 2.5 ns. The laser damage thresholds of 18 and 15 J/cm2 are achieved for single ZrO2-PVP coating and ZrO2-PVP/SiO2 multilayers respectively.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 19 (2000), S. 677-680 
    ISSN: 1573-4846
    Keywords: silica aerogel ; sol-gel ; polyethoxydisiloxanes ; supercritical drying
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Silica aerogels were made by sol-gel techniques using industrial silicon derivatives (polyethoxydisiloxanes, E-40), followed by supercritical drying with ethanol. The morphology and microstructure of the silica aerogels were investigated by using specific surface area, SBET, SEM, TEM and the pore size distribution techniques. The thermal conductivity was also measured as a function of air pressure. The results show that the diameter of the silica particles is about 13 nm and the pore size of the silica aerogels is 20–80 nm. The specific surface area of the silica aerogel is about 470 m2/g and the thermal conductivity of the silica aerogel prepared with E-40 is 0.014 w m−1 K−1 at room temperature and 1 atm.
    Type of Medium: Electronic Resource
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