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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Environmental Pollution 85 (1994), S. 153-160 
    ISSN: 0269-7491
    Keywords: grey seal ; harbour seal ; harp seal ; mercury ; ringed seal ; selenium
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1539-6924
    Keywords: Benchmark ; mercury ; risk assessment ; epidemiology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper presents benchmark (BMD) calculations and additional regression analyses of data from a study in which scores from 26 scholastic and psychological tests administered to 237 6- and 7-year-old New Zealand children were correlated with the mercury concentration in their mothers' hair during pregnancy. The original analyses of five test scores found an association between high prenatal mercury exposure and decreased test performance, using category variables for mercury exposure. Our regression analyses, which utilized the actual hair mercury level, did not find significant associations between mercury and children's test scores. However, this finding was highly influenced by a single child whose mother's mercury hair level (86 mg/kg) was more than four times that of any other mother. When that child was omitted, results were more indicative of a mercury effect and scores on six tests were significantly associated with the mothers' hair mercury level. BMDs calculated from five tests ranged from 32 to 73 mg/kg hair mercury, and corresponding BMDLs (95% lower limits on BMDs) ranged from 17 to 24 mg/kg. When the child with the highest mercury level was omitted, BMDs ranged from 13 to 21 mg/kg, and corresponding BMDLs ranged from 7.4 to 10 mg/kg.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 85 (1995), S. 823-828 
    ISSN: 1573-2932
    Keywords: fish ; mercury ; lake chemistry ; biomagnification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We determined mercury in fish (perch Perca fluviatilis) from 26 Russian lakes in three regions over four years. The lakes ranged in size from 2 to 395,000 ha, in pH from 4.5 to 10.0, and in color from 3 to 190 hazen. Sixteen lakes were drainage lakes, with permanent outlets, and 10 were seepage lakes, with no permanent inlets or outlets. The lakes were generally located in forested regions with little or no human habitation in the watershed. The three regions were geologically distinct: Precambrian Shield granitic bedrock covered with thin soil; Triassic bedrock covered with thick glacial tills; and Triassic bedrock covered with thin sediments. At each lake water samples were collected and analyzed for pH, add neutralizing capacity (ANC), major cations, and anions. Dissolved mercury species were estimated with a thermodynamic equilibrium model (MINTEQA2). Mercury content of dorsal muscle varied from 0.04 to 1.0 μg/g wet weight, and was linearly related to calculated HgCH3Cl (r20.68, p〈0.001). Lake HgCH3Cl, in turn, was related to lake pH (r2=0.86, p〈0.001). Stepwise multiple regression selected lake HgCH3Cl and color as the factors most highly related to fish mercury content, with the model accounting for 75% of the variation.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 80 (1995), S. 325-335 
    ISSN: 1573-2932
    Keywords: Atmospheric chemistry ; mercury ; plume model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A reactive plume model that includes atmospheric chemical reactions of mercury was developed. The model simulates advective transport with the mean wind flow; horizontal and vertical turbulent diffusion; gas phase; aqueous-phase and particulate chemistry; cloud microphysics; wet deposition and dry deposition. The model was applied to the simulation of clear sky, non-precipitating cloud and precipitating cloud scenarios. No significant mercury chemistry occurs in the absence of droplets. In clouds, Hg(II) is reduced to Hg(0) with more reduction taking place in precipitating clouds than in non-precipitating clouds.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 80 (1995), S. 1209-1216 
    ISSN: 1573-2932
    Keywords: gaseous ; particulate ; mercury ; sampling ; silver ; gold ; denuder
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A denuder-based method for sampling and separating gaseous and participate mercury in the air is described. Two different denuder configurations developed in Vilnius, Lithuania (silver) and in Gothenburg, Sweden (gold) are compared. Data were acquired at different sampling locations around the cities of Vilnius and Gothenburg. The concentration of particulate Hg was found to be 0.04 to 0.40 ng m−3 in the Vilnius region, and 0.11 to 0.57 ng m−3 in the Gothenburg region. Intel-calibration results for the silver and gold denuders are presented. The results obtained by the two different denuder configurations and sampling set-ups display satisfactory agreement.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 89 (1996), S. 267-275 
    ISSN: 1573-2932
    Keywords: mercury ; forest trees ; biomonitors ; contaminants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentration of mercury has been determined in assimilation organs of forest trees from 10 main industrial regions of Slovakia, four mountain forests and one military area and compared with concentration of mercury from 1356 permanent monitoring plots of Slovakia. The mercury concentration ranges for 2 yr old needles of Picea abies Karst. were (in mg kg−1): 1.249–4.402 (Rudnany iron ore mines), 0.013–0.749 (nine other industrial regions), 0.021–0.737 (four mountain forests) and 0.053–0.538 (military area). The mercury content in the soil (0–5 cm) from a mercury smelting plant ranged from 9.9 to 130 mg kg−1, and the moss Pleurozium schreberi contained 3.8–9.1 mg kg−1. The values obtained were compared with the available literature data.
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  • 7
    ISSN: 1573-2932
    Keywords: acid rain ; batch experiment ; Freundlich isotherm ; lysimeter experiment ; mercury ; simulation model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Increasing mercury contents are reported from freshwater systems and fish in northern Europe and North America. Mercury input from soils is a major source with the leaching being affected by increased atmospheric mercury deposition compared to pre-industrial times and by other environmental conditions such as acid rain. The results of a mathematical model-calculation of vertical inorganic Hg(II) leaching in a Scandinavian iron-humus podzol under different atmospheric input rates of mercury are presented. Leaching under background rain conditions was calculated to be considerably stronger than under acid rain conditions. Increasing fractions of deposited soluble or solute atmospheric mercury were leached from the O f(h)-horizon with decreasing soil content of soluble mercury under acid rain conditions; this effect was less pronounced under background rain conditions. The steady state concentrations of soluble mercury of the upper soil horizons were calculated and compared with the actual concentrations of total (= soluble + insoluble mercury) and extractable (= estimate of soluble) mercury measured in these horizons. The results indicate that even if the deposition of airborne mercury to soil is strongly reduced, the total mercury content of the soil decreases only slowly. It may take decades or even centuries before a new steady state concentration of total mercury is established in the soil. The decrease of the mercury concentration in the O f(h)-horizon is probably largely dependent on the turnover of organic matter, binding most of the deposited airborne mercury in an insoluble form. Hence, present day mercury leaching is likely to be dominated by mercury deposited during former times and temporarily retained in an insoluble form in the organic matter.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1573-2932
    Keywords: mercury ; foodplains ; humic substances ; complexation ; speciation ; mobilization ; risk assessment ; water solubility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The water-mobilizability of mercury from contaminated floodplain soils of the river Elbe in Northern Germany was evaluated by batch extraction experiments. It was shown that only a small amount of the total mercury present (about 1% per extraction) can be mobilized by water. This mercury is transported entirely in the form of a complex bound to humic acids (HA); particulates and fulvic acids (FA) did not seem to contribute to the process. It could not be removed from the HA even at pH 1, indicating an extremely strong complexation e.g. by sulfur-containing ligands. Furthermore, the influence of pH on the mobilization was investigated. It was found that in the range of natural pH-values, there was no observable effect of pH on the mobilization of either mercury or dissolved organic carbon (DOC). This surprising finding is explained by an unexpectedly high buffering capacity of the humics, both in the acidic and in the alkaline region. Only at extreme pH-values there was deviation from this behaviour. In contrast to other heavy metals, the amount of mobilized mercury decreases at pH 〈 3; and at pH 〉 12, an increased mobilization of mercury was observed because the humics are mobilized completely, accompanied by the total amount of mercury bound to them.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 97 (1997), S. 205-207 
    ISSN: 1573-2932
    Keywords: mercury ; gold mining ; ecosystems ; methyl-Hg ; cycling ; global sources
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract As described by Jemelov and Ramel (1995), the Scientific Committee on Problems of the Environment (SCOPE) sponsored an investigation of Hg in ecosystems with special emphasis on tropical regions. In these regions small-scale gold mining activities have occupied about 10 million people worldwide who use Hg for extracting gold.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 97 (1997), S. 257-263 
    ISSN: 1573-2932
    Keywords: mercury ; atmosphere ; rainwater ; marine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Total gaseous mercury (TGM) and rainwater were collected on board of two research vessels (F. S. ALKOR and R.V. BELGICA) positioned 200 km apart in the center of the North Sea during the North Sea Experiment, September 1991. On the F. S. ALKOR (up-wind ship) TGM concentrations ranged from 0.7 to 2.6 ng·m−3 with an average of 1.5 ng m−3 and on the R. V. BELGICA (down-wind ship) TGM ranged from 0.7 to 1.9 ng·m−3 with an average of 1.2 ng·m−3. An average 20% decrease is observed from the up-wind to the down wind ship. which may largely be affected by entrainment into the free troposphere. An overall removal (entrainment) velocity of 0.95 cm·s−1 was calculated for the whole experiment. The average removal velocity was 0.5 cm·s−1 for dry periods and varied between 1 to 5 cm·s−1 during rain events. Rainwater concentrations varied between 5 and 25 ng·1−1. Based on these data an annual wet deposition flux of 1.08 ng Hg cm−2 yr1− was estimated for the North Sea.
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