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  • Articles  (861)
  • Chemistry  (861)
  • Inorganic Chemistry
  • Organic Chemistry
  • Architecture, Civil Engineering, Surveying  (861)
  • 1
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The coupling between the constituent reactions of a burning process, namely pyrolysis, combustion of volatiles, and (possibly) oxidation of char, is on the whole quite different for fires occurring in the open and for those that develop in an enclosure. Consequently, knowledge of the characteristics of free burning fires is of only limited value in studies related to compartment fire. Since the singe-rout communication between the fire compartment and its environment, always assumed in classical fire studies, is not at all common in real world fires, great sophistication in the mathematical modeling of classical fires is rarely warranted. An examination of pool-like fires and pile fires of noncharring fuels has shown that the severity of such fires in the fire compartment, as characterized by the so-called ‘fire severity product’, decreases slightly with an increase in ventilation. The principal danger presented by these fires, however, is not so much to the fire compartment itself as to the surrounding spaces.An interesting feature of fires involving charring fuels, cellulosies in particular, is that the rate of consumption of fuel, the so-called ‘rate of burning’, is practically independent of all process variables except ventilation. The severity of fires of cellulosics is, as a rule, much higher than that of fires of noncharring fuels. It exhibits a maximum at relatively low ventilations. From the point of view of spread of fire to the surrounding spaces, cellulosics are generally less dangerous than noncharring plastics. Fires involving cellulosics mixed with smaller amounts of noncharring plastics can be characterized as basically cellulosics fires, with a superimposed initial period of very high spread liability.
    Additional Material: 3 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. 218-222 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Glass reinforced polyesters (GRP), or the resins used, have to pass a wide variety of tests which vary considerably from country to country and from industry to industry. Some of these tests are carried out on a scale outside the capabilities of most laboratories and the results leave much to be desired in the matter of reproducibility. All these factors lead to problems for the formulator of fire-retardant unsaturated polyester resins.
    Additional Material: 12 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. 202-210 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Australian Standard ‘Test for Early Fire Hazard Properties of Materials’ (AS 1530 Part 3, 1976) has been studied in detail as a method of assessing the fire performance of plastics wall linings under the conditions of early fire development in a room. A particular feature of the standard test is that four parameters characterizing the reaction to fire are measured concurrently. Results from the standard test have been compared to corner-wall burns involving the same parameters as in the standard test. The suitability of these parameters and the ability of the standard test to rank the behaviour of the materials in the same order as indicated by corner-wall burns is discussed. A general relationship between ignition time and flame spread was observed and is discussed as support for the concept of concurrent measurement of different reaction-to-fire parameters under the one test procedure and condition.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. 211-217 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Over a six-year period, 530 fire fatalities resulting from 398 fires were studied in the State of Maryland. The study had two major objectives: (1) to determine the specific cause of death by a detailed autopsy stud of fire victims, and (2) to determine the specific cause of fatality-producing fire by an on-the-scene fire investigation. The fire fatality study was limited to residential fires and to fatalities that occurred within 6 h of the fire. The results of the toxicological analysis show that (1) 60% of the victims had a carboxyhemoglobin value greater than or equal to 50% carbon monoxide saturation, (2) an additional 20% had elevated carboxyhemoglobin with preexisting cardiovascular disease, (3) 11% of the victims had severe burns, (4) 9% were unexplained and (5) 40% of the victims had positive blood alcohol levels with 30% of these meeting the legal definition of intoxication (blood alcohol ≥0.1%). The fire investigations confirmed that the predominant fatal scenario is the cigarette ignition of upholstered furniture or bedding. This scenario accounted for 47% of the fires and 44% of the victims. Alcohol also appears to be significant factor in this scenario.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980), S. 60-60 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 7
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Measurement of the rate of oxygen consumption provides a simple, versatile and powerful tool for estimating the rate of heat release in fire experiments and fire tests. The method is based on the generalization that the heats of combustion per unit of oxygen consumed are approximately the same for most fuels commonly encountered in fires. A measurement of the rate of oxygen consumption can then be converted to a measure of rate of heat release. Data on heats of combustion are presented to support this generalization. The applicability of the technique to combustion under fire conditions is examined, possible sources of error in the measurements are discussed, and applications of the method are reviewed. It is concluded that the accuracy of oxygen consumption based rate of heat release measurements should compare favorably with those derived from conventional calorimetric measurements.
    Additional Material: 3 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980), S. 77-82 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Experiments using a thermobalance, a hot-plate and a moving furnace have all shown that polymers can evolve oxidation products in air even at moderate temperatures. These gases can include carbon monoxide, formaldehyde and acrolein. The amounts are generally low except near the very top of the temperature range used in some processes. Tests in the vicinity of three different extruders have confirmed some of these small-scale findings but also showed that the evolved gases were adequately handled by the ventilation installed. The evolution of other gases in certain cases has also been briefly studied. Some measure of the heat evolved in oxidative pyrolysis has also been obtained for polyethylene. The polymers investigated were low density and high density polyethylene, poly(ethylene vinylacetate), polypropylene, poly(vinylonitrille) polypropylene, poly(vinylchloride), polystyrene, poly(methylmethacrylate), polycarbonate, poly(ethylene terephthalate), nylon 6-6, acrylonitrile/butadiene/styrene and one nature material (wood).
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980), S. 83-86 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An important observation during full-scale fires was that burning behaviour is often determined by softening characteristics as well as ignitability, flame spread, etc. Examples include stacking chairs where thermoplastics give a rapid rate of fire growth and suspended ceilings where thermoplastics reduce fire hazard. A test rig has been progressively developed at RAPRA to reproduce the mechanisms and fire growth rates of stacked chairs and to evaluate the role of softening in fire growth. Although the ignitability of fire-retarded materials is less than that of non-fire-retarded grades, the fire growth rate in stacks is similar and may be related to the softening behaviour determined by exposing sheets of material to radiant heat. The rate of fire growth in stacks may be significantly reduced by modifying the softening behaviour of materials, e.g. by using asbestos-reinforced thermoplastics which can form an integral, non-melting felt or by using non-melting materials such as SMC or wood.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980), S. 87-91 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes work carried out on flame-retarded polypropylene comparing results on selected small-scale laboratory fire tests with those obtained on a larger-scale test designed to simulate the typical real life hazard situation. In the latter test a number of important parameters such as heat build-up, Hame spread, smoke development and gas evolution were assessed. The results indicate that there is need to use both types of tests to gain a fuller understanding prior to using new materials. An assessment based on small-scale tests alone could be misleading and allow the use of potentially hazardous material in the particular application involved.
    Additional Material: 4 Ill.
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