ISSN:
0749-1581
Schlagwort(e):
1,3-Dinitroso-1,3-diazacycloalkanes
;
1-Nitroso-3-nitro-1,3-diazacycloalkanes
;
1,3-Dinitro-1,3-diazacycloalkanes
;
Multinuclea gHNMR
;
Rotamer populations
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
A series of five-, six-, and seven-membered 1,3-dinitroso-, 1-nitroso-3-nitro-, and 1,3-dinitro-1,3-diazacycloalkanes were investigated by 1H, 13C, and 15N NMR spectroscopy. Hindered rotation of the nitrosamine group leads to the existence of rotational isomers. The relative populations of rotamer forms are determined by steric and electrostatic interactions between nitroso groups and the remainder of the molecule, and by the size of the ring.
Zusätzliches Material:
3 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/mrc.1260260202
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