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  • Wiley-Blackwell  (471,888)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 100 (1967), S. 1289-1295 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ein neues Verfahren zur Synthese von Aminalen und Enaminen durch Umsetzung von Tris(dimethylamino)-arsin mit Aldehyden oder Ketonen wird beschrieben. Diese Reaktion ist auch auf andere Tris(dialkylamino)-arsine übertragbar.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Latexes based on styrene-glycidyl methacrylate copolymers were prepared by the emulsifier-free dispersion copolymerization technique. The main factors affecting the size and morphology of the latex particles and their distribution are the initiator concentration (K2S2O8), the total ionic strength of the aqueous phase, and the total monomer concentration. The existence of critical values for these variables was demonstrated. In the range in which these factors had values below the critical, the synthesized latex particles were spherical, homogeneous, and in varied sizes, depending on the abovementioned parameters in the range of 220-500 nm. Above the critical values of these variables the latex particles consisted of spherical aggregates of smaller particles. The reactive oxirane groups of the latex particles were modified later by hydrolysis, ammonolysis, reaction with Na2S, or periodic acid oxidation of the hydrolyzed or ammonolyzed forms of the latex particles.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 719-727 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of Thermoplastic polyurethane (TPU) and poly(styrene-co-acrylonitrile) (SAN) (34% acrylonitrile and 24% acrylonitrile) and polyurethane ionomer (PUI) with SAN (34% acrylonitrile) were prepared in the melt. The structural properties and morphology of the blends were investigated. TPU and SAN blends were immiscible in the composition range 30-70 wt % of TPU or SAN. In TPU-rich blends, SAN propagates the separation of hard and soft segements in TPU. In SAN-rich blends, the interaction stage depends on acrylonitrile contents. SEM measurements showed that the blends of TPU/SAN were fine dispersions and clearly showed a continuous and disperse phase, whereas the morphology of the PUI/SAN blends were different. © 1993 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 595-602 
    ISSN: 0887-6266
    Keywords: demixing ; spinodal quench ; polymer blends ; lower critical solution temperature ; isotope effect ; pressure dependence ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Liquid-liquid demixing, following spinodal quenches of poly-2-chlorostyrene/polystyrene blends, was followed by light scattering at 632.8 nm. The dependences of demixing on H/D substitution and molecular weight of the polystyrene, and on pressure, are reported. In the region of interest, the phase diagram is of the lower critical solution (LCS) type, and demixing is induced by raising the temperature. The transition temperature is lowered by deuterium substitution. At constant quench depth the transition proceeds more rapidly at elevated pressure. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 5
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The finite element implementation of a lamina-based elastic constitutive relation appropriate for describing the three-dimensional (3-D) behaviour of fibre composite laminated media is presented. Unconstrained by the two-dimensional restrictions accompanying plate and shell theories, this approach resolves the macro 3-D deformation fields found in 'thick' laminated or filament wound composites without requiring each lamina to be individually discretized to assign material properties. In rectangular isoparametric solid elements where laminae locally parallel an element 'face', the implementation represents 'exactly' the elastic laminate behaviour by replacing the discrete lamina stiffnesses with continuous polynomial moduli functions. Attributable directly to the lamina constitutive relationship used, appropriate for fibre-dominated material systems, the implementation automatically preserves interlaminar continuity of tractions and displacements within each element for laminates assembled from a single lamina type. The order of the effective moduli functions is determined by the element kinematics and by requiring identical net mid-surface elemental forces and moments. In general, this representation substantially reduces the number of stored variables and through-thickness integrations required, and allows 'exact' integration by higher-order Gaussian quadrature. Additionally a single element may span any portion or number of laminae, thus allowing nearly arbitrary meshing and solution resolution. Several numerical examples using 3-D 8-node isoparametric solid elements demonstrate the approach's convergence and overall behaviour.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 75-86 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Two finite element algorithms suitable for long term simulation of geothermal reservoirs are presented. Both methods use a diagonal mass matrix and a Newton iteration scheme. The first scheme solves the 2N unsymmetric algebraic equations resulting from the finite element discretization of the equations governing the flow of heat and mass in porous media by using a banded equation solver. The second method, suitable for problems in which the transmissibility terms are small compared to the accumulation terms, reduces the set of N equations for the Newton corrections to a symmetric system. Comparison with finite difference schemes indicates that the proposed algorithms are competitive with existing methods.
    Additional Material: 7 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 23 (1986), S. 1101-1109 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An incomplete factorization iterative scheme with ORTHOMIN acceleration is evaluated for three-dimensional finite element applications. Both heat conduction and combined heat and fluid flow are investigated. Computational efficiency is investigated for both linear (8 node) and quadratic (27 node) elements as well as for various degrees of LU Decomposition. The factorization schemes worked well with both types of elements, and a variable factorization scheme, which distributes the level of factorization, performed well on difficult heat and fluid flow problems.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 3 (1979), S. 355-366 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Two finite difference algorithms suitable for long-time simulation of the exploitation of a two-phase geothermal reservoir are presented. One is based on the hopscotch method proposed by Saul'yev1 and analysed further by Gordon2 and Gourlay.3 The other is based on the well-known ADI method. Both methods use a Newton-Raphson iterative technique in order to obtain accurate solutions of the non-linear difference equations involved. Rapid convergence of the iterative schemes occurs both for single-phase and two-phase reservoir problems. One- and two-dimensional model problems are presented.
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 17 (1986), S. 477-480 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The Raman spectrum of the ν3 mode of allene has been studied as a function of temperature throughout the temperature range of the liquid. Analysis of the spectral band shape shows that the vibrational dephasing is a fast-modulation process. Evidence is presented for a vibrational-rotational coupling involving the tumbling reorientation of the molecule. Dilution studies in GeH4 indicated significant resonant vibrational energy transfer.
    Additional Material: 1 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 2 (1978), S. 87-93 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Additional Material: 5 Ill.
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