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  • 05. General::05.02. Data dissemination::05.02.01. Geochemical data  (3)
  • Copernicus  (2)
  • International Association of Geochemistry  (1)
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Years
  • 1
    Publication Date: 2021-01-27
    Description: We present the first nitrogen isotope data from hydrothermal fluids of Graciosa, Terceira and S. Miguel Islands (Azores, Portugal), together with helium isotope composition. 15N values are slightly enriched in light isotopes (from -0.7‰ to -2.2‰) with respect to air, while 3He/4He ratios range from 5 to 6 Ra in Sao Miguel island and from 8 to 9.1 Ra in Graciosa and Terceira islands. The latter values are similar to those found in olivine phenocrysts of basalts (Moreira et al., 1999; Madureira et al., 2005). Such isotope signatures seem to point to the presence of two different deeply-derived end-members: a 3He-rich primitive end-member evident in Terceira and Graciosa islands samples and a 3He-poor end-member characterizing samples from S. Miguel island. According to Madureira et al. (2005), the He primitive component which is more evident in the central parts of the Azores archipelago has to be related to a lower mantle contribution into the prevailing MORB component. On the contrary, the origin of the radiogenic crustal component is still open and debated between the contribution of recycled terrigenous sediments (Turner et al., 1997) and oceanic mantle lithosphere (Schaefer et al., 2002). Since 15N values from fluids vents and inclusions in basalt glasses were discovered to be good geochemical tracers of magma genetic processes, we determined molecular and isotope nitrogen composition (15NN2) in some hydrothermal fluids with the aim to provide additional information on the mantle composition beneath the Azores archipelago. Based on the N2/36Ar ratio we computed for each samples the 15N values of the non-atmospheric nitrogen (15Ndeep). Volatiles emitted from Graciosa and Terceira islands seem to have a common deep nitrogen isotope signature of about -1.5‰ likely resulting from a mixing between lower mantle (15N from 1‰ to 4‰) and upper mantle (15NMORB from -3‰ to -7‰). On the other hand, the 15Ndeep feeding the fumaroles at S. Miguel is close to -5.5‰. Such a 15N-depleted values seem to indicate a probable nitrogen origin from a deep source derived from the recycling of ancient oceanic plate into the upper mantle (MORB). rather than from the recycling of terrigenous sediments transported on top of the descending plate that should have lead to 15N-enrichments.
    Description: Published
    Description: La Malbaie, Quebec, Canada
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 3.2. Tettonica attiva
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Nitrogen isotopes ; Hydrothermal fluids ; Azores Islands ; Volcanic gases ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 2
    Publication Date: 2017-04-04
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (IPCC, 2007). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Active or recent volcanic/geothermal areas represent one of these sources of geological methane. But due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been generally indirectly estimated (Etiope et al., 2007). The Greek territory is geodynamically very active and has many volcanic and geothermal areas. Here we report on methane flux measurements made at two volcanic/geothermal systems along the South Aegean volcanic arc: Sousaki and Nisyros. The former is an extinct volcanic area of Plio-Pleistocene age hosting nowadays a low enthalpy geothermal field. The latter is a currently quiescent active volcanic system with strong fumarolic activity due to the presence of a high enthalpy geothermal system. Both systems have gas manifestations that emit significant amounts of hydrothermal methane and display important diffuse carbon dioxide emissions from the soils. New data on methane isotopic composition and higher hydrocarbon contents point to an abiogenic origin of the hydrothermal methane in the studied systems. Measured methane flux values range from –48 to 29,000 (38 sites) and from –20 to 1100 mg/mˆ2/d (35 sites) at Sousaki and Nisyros respectively. At Sousaki measurement sites covered almost all the degassing area and the diffuse methane output can be estimated in about 20 t/a from a surface of about 10,000 mˆ2. At Nisyros measurements covered the Stephanos and Kaminakia areas, which represent only a part of the entire degassing area. The two areas show very different methane degassing pattern with latter showing much higher flux values. Methane output can be estimated in about 0.25 t/a from an area of about 30,000 mˆ2 at Stephanos and about 1 t/a from an area of about 20,000 mˆ2 at Kaminakia. The total output from the entire geothermal system of Nisyros probably should not exceed 2 t/a.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: methane output ; diffuse degassing ; volcanic/hydrothermal systems ; Greece ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 3
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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