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  • Articles  (5,123)
  • Emerald  (3,512)
  • Blackwell Publishing Ltd
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (5,123)
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  • 1
    Electronic Resource
    Electronic Resource
    Elastic Properties of Nickel-Based Anodes for Solid Oxide Fuel Cells as a Function of the Fraction of Reduced NiO (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The changes in porosity and elastic moduli of YSZ-containing nickel-based anode materials for solid oxide fuel cells were studied as a function of the fraction of reduced NiO. Anode samples were reduced in a gas mixture of 4% hydrogen and 96% argon for different periods of time at 800°C and their Young's and shear moduli were determined afterward at room temperature using resonant ultrasound spectroscopy and impulse excitation. It was found that the magnitude of Young's and shear moduli decreased significantly with increasing fraction of reduced NiO and that the magnitude of the elastic moduli of a fully reduced Ni–YSZ anode was ∼45% lower than that of unreduced NiO–YSZ. Because the elastic moduli of NiO are close to those of Ni, the observed decrease in the magnitude of the elastic moduli was found to be caused mainly by the significant increase in the porosity of the sample as a result of NiO reduction. Expressions are presented for the amount of porosity and the magnitude of the elastic moduli as a function of the fraction of reduced NiO.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb07499.x
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  • 2
    Electronic Resource
    Electronic Resource
    Manufacturing SiC-Fiber-Reinforced SiC Matrix Composites by Improved CVI/Slurry Infiltration/Polymer Impregnation and Pyrolysis (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Two- and three-dimensional SiCr/SiC composites have been prepared starting from Tyranno SA(tm) fiber preforms. Preform densification has been performed by a modified preceramic polymer impregnation and pyrolysis (PIP) process consisting of filling the preform large interbundle voids with SiC powder before the PIP process. This step was accomplished by low-pressure infiltration of a SiC powder dilute slurry through the preform thickness. Specimens were further processed with polymer impregnation and pyrolysis to determine the effects on structural, thermal, and mechanical properties of the obtained composites. High-temperature pyrolysis treatment, which promoted polymer derived SiC matrix crystallization, markedly increased thermal diffusivity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.tb20093.x
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  • 3
    Electronic Resource
    Electronic Resource
    Fourier-Transform Infrared Spectrometry Measurement of Emissions Concentration from Glass Manufacturing (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Carbon is commonly added to sulfate-fined silicate-glass batches to enhance the fining process. Reactions between carbon and Na2SO4 modify the SOx emissions from Na2SO4 decomposition. Fourier-transform infrared (FTIR) spectrometry is used to analyze the emission of air pollutants from the isothermal decomposition of Na2SO4 + C undertaken using thermogravimetric analysis (TGA). The FTIR spectrometer is calibrated using standard gas mixtures containing CO, CO2, SO2, NO, and NO2. The collected spectra are quantified using the classical least-squares (CLS) approximation. The TGA-FTIR system provides SOx, and COx, concentrations versus time data from the isothermal decomposition of Na2SO4, in the presence of a carbon black. Mass spectrometry (MS) complements FTIR by being able to detect SO(g).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.tb20094.x
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  • 4
    Electronic Resource
    Electronic Resource
    Reexamination of the Role of SrMoO4 in the Enhancement of the Low-Field Magnetoresistance of Sr2FeMoO6 (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Different ratios of the precursor phases of SrFeO3–x (SFO) and SrMoO4 (SMO) were used to prepare Sr2FeMoO6 (SFMO) by a solid-state reaction. X-ray diffraction was used to identify the phases. A residual SMO was observed to exist in the sample with an SFO/SMO ratio of 0.9:1. The sample with a residual SMO phase had higher resistivity, lower magnetization, but higher low-field magnetoresistance (LFMR). High-resolution transmission electron microscopy was used to identify the compositions and phases. Nanometer-sized amorphous-like clusters of SMO phase were located inside the grains rather than at grain boundaries; however, some boundaries were rich in the strontium ion. The possible mechanisms for the conduction and the increase of LFMR of SFMO are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.tb20098.x
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  • 5
    Electronic Resource
    Electronic Resource
    Nanoindentation Characterization of Submicro- and Nano-Sized Liquid-Phase-Sintered SiC Ceramics (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Submicro- and nano-sized liquid-phase-sintered SiC ceramics were mechanically tested by nanoindentation in the peak load range 5–400 mN. The submicro-sized sample showed a marked indentation size effect which the nano-sized samples did not exhibit. The relevance of indentation depth with respect to the microstructural scale has been outlined. In the investigated grain-size range, the hardness dependence on the grain size could be described by a load-dependent inverse Hall–Petch relation. Young's modulus was less microstructure- and load-dependent. Because of the very fine microstructure, the nano-sized SiC materials gave lower elastic values than the submicro-sized SiC ceramic.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06366.x
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  • 6
    Electronic Resource
    Electronic Resource
    Insulating Properties of Lanthanum-Doped BaTiO3 Ceramics Prepared by Low-Temperature Synthesis (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Samples of composition Ba1−xLaxTi1−x/4O3, x= 0, 0.003, 0.03, and 0.10, were prepared by an alkoxide sol–gel route with final firing of ceramics at 1100°C, 2 h in air. All samples showed bulk insulating behavior with no evidence of semiconductivity caused by either direct donor doping or oxygen loss.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06370.x
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  • 7
    Electronic Resource
    Electronic Resource
    CORRECTION (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06375.x
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  • 8
    Electronic Resource
    Electronic Resource
    Cement Composition Effects on the Rheological Property Evolution in Concentrated Cement–Polyelectrolyte Suspensions (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have studied the rheological property evolution and hydration behavior of white and ordinary portland cement (type I) pastes and concentrated cement–polyelectrolyte suspensions. Cement composition had a marked effect on the elastic property evolution (G′(t)) and hydration behavior of these suspensions in the presence of poly(acrylic acid)/poly(ethylene oxide) copolymer (PAA/PEO), even though their affinity to adsorb such species was nearly identical. Both white and ordinary portland cement pastes exhibited G′0 values of ∼104 Pa and fully reversible G′(t) behavior until the onset of the acceleratory period (t= 2 h), where the pastes stiffened irreversibly. In contrast, cement–PAA/PEO suspensions exhibited G′0 values of ∼1 Pa and G′(t) behavior comprised of both reversible and irreversible features. Interestingly, ordinary portland cement–PAA/PEO suspensions experienced a gel-to-fluid transition on high shear mixing at short hydration times (〈1 h), and the particle network did not rebuild until ∼24 h of hydration. In sharp contrast, white portland cement–PAA/PEO suspensions remained weakly gelled throughout the initial stage of hydration even after high shear mixing. At longer hydration times (〉1 h), both cement–PAA/PEO suspensions exhibited G′i(t) ∼ exp(t/τc) with τc values of 5.6 and 1.3 h for ordinary and white portland cement, respectively. Our observations suggest that hydration phenomena impact interparticle forces during early stage hydration and, ultimately, lead to initial setting through the formation of solid bridges at the contact points between particles within the gelled network.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06327.x
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  • 9
    Electronic Resource
    Electronic Resource
    New Freeze-Casting Technique for Ceramics with Sublimable Vehicles (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new ceramic freeze-casting technique capable of manufacturing near room temperature with a sublimable vehicle was accomplished. Fluid-concentrated slurries of Al2O3 powder in molten camphene (C10H16) were prepared at 55°C. These slurries were quickly solidified (frozen) at room temperature to yield rigid solid green bodies, followed by frozen camphene removal by sublimation (freeze-drying) with negligible shrinkage. Sintering without any special binder burnout process yielded sintered bodies with over 98% theoretical density. The proposed advantages include (1) elimination of extremely cold temperatures, (2) elimination of troublesome binder burnout process, and (3) fast manufacturing cycle due to quick solidification.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06331.x
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  • 10
    Electronic Resource
    Electronic Resource
    Reactive Hot Pressing of Titanium Nitride–Titanium Diboride Composites at Moderate Pressures and Temperatures (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dense composites in the Ti-B-N system have been produced by reactive hot pressing of titanium and BN powders. The effect of the addition of a small amount of nickel (1–3 wt%) on the reaction kinetics and densification of TiN–TiB2 (40 vol%) composite has been studied. Composites of ∼99% of theoretical density have been produced at 1600°C under 40 MPa for 30 min with 1% nickel. The hardness and fracture toughness of these composites are 24.5 ± 0.97 GPa and 6.53 ± 0.27 MPa·m1/2, respectively. The microstructural studies on samples produced at lower temperatures indicate the formation of a transient liquid phase, which enhances the kinetics of the reaction and densification of the composite.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06333.x
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  • 11
    Electronic Resource
    Electronic Resource
    Ultrasonic Spray Pyrolysis for Synthesis of Spherical Zirconia Particles (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper presents new findings on ultrasonic spray pyrolysis of zirconium hydroxyl acetate precursor drops whose sizes were precisely measured using laser light diffraction technique. Precursor concentration plays a predominant role in determination of product particle size. At 0.01 wt% precursor concentration, conventional spray pyrolysis at 750°C using precursor drops 5–8 μm in diameter, generated by an ultrasonic nebulizer at 2.66 MHz, yielded uniform spherical yttria-stabilized zirconia (YSZ) particles 73 nm in diameter measured by scanning electron microscopy. The YSZ particle diameters were much smaller than those predicted by the one-particle-per-drop mechanism. Under similar reaction conditions, the high-throughput ultrasound-modulated two-fluid (UMTF) spray pyrolysis of larger precursor drops (28-μm peak diameter) also yielded spherical dense particles; they were significantly smaller in size than those produced by the low-throughput conventional ultrasonic spray pyrolysis of smaller drops (6.8-μm peak diameter).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06332.x
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  • 12
    Electronic Resource
    Electronic Resource
    Characterization of Thermoelectric Metal Oxide Elements Prepared by the Pulse Electric-Current Sintering Method (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermoelectric elements consisting of the layered polycrystalline materials of Al-doped ZnO and NaCo2O4 were prepared using the pulse electric-current sintering (PECS) method at 900°C for 3 min. Direct contact between the polycrystalline Al-doped ZnO and the NaCo2O4 was obtained in a single-step process for the stacked powders. The electrical conductivities of the polycrystalline materials prepared by PECS were higher than those of materials prepared by conventional sintering, despite their porous structure. The thermoelectric voltage of the 1-mol%-Al-doped ZnO and NaCo2O4 polycrystalline element (measuring ∼6 mm × 3 mm × 15 mm) was 83 mV at dT= 500 K, when the junction of the elements was at 800°C.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06336.x
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  • 13
    Electronic Resource
    Electronic Resource
    Low Temperature Coefficient of Resonance Frequency Composition in the System Pb(Zr,Ti)O3—Pb(Mn1/3 Nb2/3)O3 (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Pb(Zr,Ti)O3–Pb(Mn1/3 Nb2/3)O3 (PZT–PMnN) system has been studied for high-power piezoelectric applications. This study investigates this system to find out the composition with high-power density piezoelectric characteristics and low tem-perature coefficient of resonance frequency (TCF). It was found that the composition 0.9PZT–0.1PMnN (Zr/Ti = 0.51/0.49) modified with 6 mol% Sr exhibits a TCF of −8 ppm/°C (−20 to +80°C). Further, the dielectric and piezoelectric properties of this composition are as follows: kp= 0.53; Qm= 800; d33= 274; ε33/ε0= 1290 and tan δ=1.1%, which shows the suitability of this composition for ultrasonic devices used under fluctuating thermal environment.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06339.x
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  • 14
    Electronic Resource
    Electronic Resource
    Measuring Permeability of Rigid Materials by a Beam-Bending Method: V, Isotropic Rectangular Plates of Cement Paste (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Beam bending is an excellent method for measuring low permeabilities (≤10−18 m2) in homogeneous materials, because it is fast, requires no high pressure, and provides a concurrent measurement of the modulus of the material. The method was previously analyzed and substantiated for cylindrical or square beams. Recently, the analysis was extended to include isotropic and transversely isotropic rectangular beams. In this paper, the analysis is applied to measurements performed on cement paste, and it is shown that the solution for isotropic rectangular beams accounts for changes in the hydrodynamic behavior caused by changing the aspect ratio of the sample. The permeability and elastic modulus results are verified through comparison to previous measurements on cylindrical beams.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06342.x
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  • 15
    Electronic Resource
    Electronic Resource
    Compression Deformation Mechanism of Silicon Carbide: I, Fine-Grained Boron- and Carbon-Doped β-Silicon Carbide Fabricated by Hot Isostatic Pressing (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The deformation behavior of boron- and carbon-doped β-silicon carbide (B,C-SiC) with an average grain size of 260 ± 18 nm containing 1 wt% boron was investigated by compression testing at elevated temperatures. Extensive grain growth during deformation was observed. The stress–strain curves were compensated for grain growth by assuming power-law type of dependence on grain size and strain rate. The stress exponent n was ∼1.3 and the grain size exponent p was ∼2.7 at temperatures ranging from 1593° to 1758°C. The apparent activation energy of deformation Qd was ∼760 kJ/mol, which was lower than the activation energy for lattice diffusion of silicon and carbon in SiC and higher than that for grain-boundary diffusion of carbon in SiC. These results suggest that the deformation mechanism of the fine-grained B,C-SiC is grain-boundary sliding accommodated by the grain-boundary diffusion.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06341.x
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  • 16
    Electronic Resource
    Electronic Resource
    Structural Characterization of Lanthanum Chromite Perovskite Coating Deposited by Magnetron Sputtering on an Iron-Based Chromium-Containing Alloy as a Promising Interconnect Material for SOFCs (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
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    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Chromium-containing stainless steel (SS) is a prospective material for use as an interconnect in solid oxide fuel cells (SOFCs). However, during operations at high temperatures, the growth of oxide scales causes the performance of the interconnect and SOFC as a whole to deteriorate. The coating of SS 446 with a conducting perovskite is a potential method of slowing the growth of oxide scale and, therefore, improving overall SOFC performance. In the present research, the structural characterization of a pure LaCrO3 thin film on the SS 446 substrates has been performed as a model material that can be used as a barrier coating for the metallic interconnect. The deposition of an amorphous La-Cr-O thin film on SS 446 was performed using radio-frequency (rf) magnetron sputtering. The deposited amorphous film was annealed in air to form the desired perovskite phase. The film underwent an amorphous to LaCrO4 phase transition during annealing at 500°C with further transformation to LaCrO3 orthorhombic phase during annealing at 700°C. A self-organized dendritic structure was reported as a result of the perovskite-phase formation. Although formation of various oxides, such as Fe2O3 and Fe3O4, was observed during the annealing of uncoated SS 446 in air, the coating of SS 446 surface with LaCrO3 film prevented formation of various oxide phases at the interconnect surface. The structural characterization of the films and SS 446 surfaces was accomplished using scanning electron microscopy with energy-dispersive X-ray analysis, X-ray diffractometry, micro-Raman spectroscopy, and nanoindentation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06350.x
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  • 17
    Electronic Resource
    Electronic Resource
    Density, Surface Tension, and Viscosity of PbO-B2O3-SiO2 Glass Melts (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
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    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The density, surface tension, and viscosity of the melts from the PbO-B2O3-SiO2 system have been measured at temperatures in the range 1073–1473 K. The effect of composition on these properties was also investigated. The density of the melt was found to increase linearly with increasing PbO content. Molar volume was derived from the density data, and its deviation from the additivity of partial molar volumes was calculated. These deviations in molar volume from those obtained from additivity rules have been used along with the ratio of various coordination numbers of boron (as reported by Bray) to discuss the structure of the melts. The surface tension was found to decrease with decreasing SiO2/B2O3 ratio, and to increase in the range of the PbO content between 30 and 60 mol%, showing a maximum at ∼60 mol% PbO, and then decreased with further additions. This result suggested that the surface tension would be affected primarily by the B2O3 content in the range of the PbO content between 30–60 mol%, and mainly by the PbO content in the range of the PbO content 〉60 mol%, respectively. The viscosity of the melt was found to decrease linearly with increasing PbO content. The results obtained indicate that the increase in viscosity with B2O3 was half that of SiO2 (on a molar basis), and an empirical equation has been proposed for the viscosity as a function of mole fraction.
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    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb19937.x
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  • 18
    Electronic Resource
    Electronic Resource
    Effect of Core Materials on the Formation of Hollow Alumina Microspheres by Mechanofusion Process (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
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    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Core/shell structures have been prepared via a mechanofusion system by employing several kinds of spherical polymers as a core material and Al2O3 powder or a mixture of Al2O3 and SiO2 powders as a shell material. The effect of the kind of core polymers on the quality of the resulting hollow alumina microspheres has been discussed on the basis of the thermal decomposition behavior of spherical polymers used as a core material. A large fraction of hollow alumina microspheres reflecting the shape and the particle size distribution of the core polymer could be fabricated after sintering at 1600°3C for 3 h, when highly cross-linked poly(methyl methacrylate) (PMMA) microspheres with a gel fraction of 99.03% were used as a core polymer, and abrupt firing at temperatures higher than 500°3C was adopted to remove the PMMA microspheres. The addition of 5 mass% SiO2 to the Al2O3 shell layer was found to be useful for maintaining the spherical shell structure during the firing process and for fabricating a large fraction of hollow alumina microspheres after the sintering.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.00060.x
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  • 19
    Electronic Resource
    Electronic Resource
    Synthesis of BaTiO3 Particles with Tailored Size by Precipitation from Aqueous Solutions (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
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    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Well-defined and stoichiometric spherical particles of BaTiO3 of narrow size distribution were produced at 82° and 92°3C by precipitation from chloride solutions in a strong alkaline environment. The size of the particles can be tailored in the range from ≅103 to 70–80 nm by increasing the barium concentration from ≅0.07 to 0.7 mol/L. The particles are composed of tight aggregates resulting from the assembly of several nanocrystals. The size of the nanocrystals decreases from 200–300 to 30–40 nm by increasing reactant concentration. At low barium concentration (≤0.07 mol/L at 82°3C, ≤0.06 mol/L at 92°3C), formation of BaTiO3 is strongly slowed down and nonstoichiometric, Ti-rich powders are produced. Under these conditions, the particles have the tendency to develop a dendritic-like morphology.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.00079.x
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  • 20
    Electronic Resource
    Electronic Resource
    Thermal Expansion of δ-Yttrium Disilicate (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crystals of δ-Y2Si2O7 (space group P121/c1) were examined using high-temperature powder X-ray diffractometry to determine their unit-cell dimensions from 296 to 1473 K. The lattice deformation induced by thermal expansion was investigated using matrix algebra analysis to determine the directions and magnitudes of the principal distortions (Λi, i= 1,2, and 3). The directions of Λ1 and Λ3 were defined by the acute angle Λ1c, which linearly decreased from 5(2)° to —5.5(3)° with increased temperature from 504 to 1473 K. The Λ2-axis invariably coincided with the crystallographic b-axis. The magnitudes of Λ1 and Λ2 steadily increased to, respectively, 1.0061(1) and 1.0068(1) during heating to 1473 K, while Λ3 remained almost constant for the entire temperature range. The mean principal distortion, Λm (= (Λ1+Λ2+Λ3)/3), steadily increased to 1.0044(1) with increased temperature to 1473 K. The coefficient of mean linear thermal expansion (α) was derived from the mean principal strain (Λm - 1) as α= (Λm - 1)/ΔT. The temperature dependence was determined to be α= 2.03 times 103+ 1.36(T - 296) (10-9 K-1). Provided that the rule-of-mixtures holds for the Y2Si2O7/Y2SiO5 composites as protective coating on SiC substrates, the volume fractions of 0.72-0.77 (70–75 mass%) would be necessary for the Y2Si2O7 component to match the α-values of both materials.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.00089.x
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    Novel Microcellular Ceramics from a Silicone Resin (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Microcellular silicon oxycarbide open cell ceramic foams were fabricated from a silicone resin. Microcellular foams, with a cell size ranging from ∼1–80 μm, were fabricated using poly(methyl methacrylate) microbeads as sacrificial templates. The compression strength of the foams decreased with increasing cell size.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.00152.x
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    Influence of Microstructure Evolution on the Electroconducting Behavior of Intragranular TiN/ZTM Nanocomposites (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electroconductive zirconia-toughened mullite (TiN/ZTM) intragranular nanocomposite was fabricated by hot-pressing a powder mixture of nano-sized TiN, ZrO2(2Y), and mullite gel. The material showed a good sinterability and could be highly densified at a low temperature of 1300°3C. Sintering temperature strongly influenced the microstructure and electrical resistivity of the material. The electrical resistivity increased monotonously from 20 Ω-cm to 1.5 times 106°3Cm, as the sintering temperature was increased from 1300° to 1500°3C. TEM results indicated that such a phenomenon could be ascribed to the changes in the microstructure of the material, which led to a decrease in the connectivity of the TiN network in the sample as the sintering temperature was increased.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.00162.x
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  • 23
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    Effects of Fluids on the Simulated Clinical-Dental Machining of a Glass Ceramic (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Effects of fluids on material removal rate, chipping damage, and surface roughness in the simulated clinical-dental machining of a dental-type glass ceramic were investigated. Significant differences in removal rate were obtained among the fluids investigated, but only a 4 wt% boric acid solution gave a higher removal rate than conventionally used water. Chipping damage was substantially lower for the boric acid and an oil-emulsion coolant compared with other fluids tested. Surface roughness was independent of the fluids used. The results indicate that improvement can be achieved in both material removal rate and machining damage by the appropriate selection of coolant chemistry.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1551-2916.2004.00173.x
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  • 24
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    Electronic Structure and Bonding of All Crystalline Phases in the Silica–Yttria–Silicon Nitride Phase Equilibrium Diagram (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper reviews the structures and properties of 10 binary, ternary, and quaternary crystals within the equilibrium phase diagram of the SiO2–Y2O3–Si3N4 system. They are binary compounds SiO2, Y2O3, Si3N4; ternary compounds Si2N2O, Y2Si2O7, and YSi2O5; and quaternary crystals Y2Si3N4O3 (M-melilite), Y4Si2O7N2, (N-YAM), YSiO2N (wallastonite), and Y10(SiO4)6N2 (N-apatite, N-APT). Although the binary compounds are well-known and extensively studied, the ternary and the quaternary crystals are not. Most of the ternary and the quaternary crystals simply have been referenced as secondary phases in the processing of nitrogen ceramics. Their crystal structures are complex and not precisely determined. In the quaternary crystals, there exists O/N disorder in that the exact atomic positions of the anions cannot be uniquely determined. It is envisioned that a variety of cation–anion bonding configurations exist in these complex crystals. The electronic structure and bonding in these crystals are, therefore, of great interest and are indispensable for a fundamental understanding of structural ceramics. We have used ab initio methods to study the structure and bonding properties of these 10 crystals. For crystals with unknown or incomplete structural information, we use an accurate total energy relaxation scheme to obtain the most likely atomic positions. Based on the theoretically modeled structures, the electronic structure and bonding in these crystals are investigated and related to various local cation–anion bonding configurations. These results are presented in the form of atom-resolved partial density of states, Mulliken effective charges, and bond order values. It is shown that Y–O and Y–N bonding are not negligible and should be a part of the discussion of the overall bonding schemes in these crystals. Spectroscopic properties in the form of complex, frequency-dependent dielectric functions, X-ray absorption near-edge structure (XANES), and the electron energy-loss near-edge structure (ELNES) spectra in these crystals also are calculated and compared. These results are discussed in the context of specific bonding configurations between cations (silicon and yttrium) and anions (oxygen and nitrogen) and their implications on intergranular thin films in polycrystalline Si3N4 containing rare-earth elements.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06352.x
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  • 25
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    Simultaneous Synthesis and Sintering of α-Ti1–xAlx(N) (0 ≤x≤ 0.08) by a Self-Propagating High-Temperature Combustion Method (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Simultaneous synthesis and sintering of hexagonal α-Ti1−x-Alx(N) (0 ≤x≤ 0.08) solid solutions, which contain a small amount of nitrogen, have been performed by a self-propagating high-temperature combustion method under a nitrogen pressure of 4 MPa. Dense materials (∼99% of theoretical) prepared directly from a mixture of elemental (Ti and Al) powders reveal homogeneous microstructure composed of fine grains (12–16 μm). α-Ti1−xAlx(N) (x= 0.02; Ti0.98Al0.02N0.26) exhibits a three-point bending strength σb of 390 MPa, a Vickers hardness Hv of 9.24 GPa, and a fracture toughness KIC of 4.89 MPa·m1/2; their mechanical properties are much improved by doping Al into α-Ti(N), in comparison with those (σb= 245 MPa, Hv= 9.02 GPa, and KIC= 3.77 MPa·m1/2) of α-Ti(N) fabricated under the same conditions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06357.x
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  • 26
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    Nickel–Alumina Functionally Graded Materials by Electrophoretic Deposition (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electrophoretic deposition has been used to synthesize nickel–alumina, functionally graded materials from NiO and alumina suspensions in ethanol. Suspension stability and the kinetics of deposition were studied to determine optimum conditions. Deposition starts with an alumina suspension into which a stream of NiO suspension is injected at various flow rates to obtain the desired profiles. The latter were controlled by varying the deposition current density and component flow rate. The green bodies obtained were sintered in Ar/H2 atmosphere to reduce the NiO to nickel. Various gradation profiles were obtained illustrating the facility of EPD to synthesize continuously graded materials. NiO was used as the precursor for nickel to alleviate settling and rough columnar deposit problems.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.2004.tb06359.x
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  • 27
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    Computer Simulations of Diffraction Effects due to Stacking Faults in β-SiC: I, Simulation Results (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    Details
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: X-ray diffraction (XRD) patterns from nominally β-SiC specimens often differ from those expected for the cubic crystal structure. These differences include the presence of additional peaks, enhanced background intensities, peak broadening, changes in relative peak heights, and shifts in peak positions. It has long been recognized that they are due to the presence of stacking faults, and models relating the experimental observations to stacking fault population have continued to evolve. The presence and relative magnitude of these features vary among different β-SiC specimens. In this work, computer simulations were used to show that the variations are closely related to differences in the type and spatial distribution of stacking faults in each specimen. In these simulations, stacking sequences were generated using a selectively activated 1-D Ising model with a Boltzmann-type probability function for specifying errors, which allows a wide variety of fault configurations to be generated. Direct correlations between different features in the XRD data to the underlying fault population are demonstrated, which are discussed in this paper. It is also shown that this computer model is general, in the sense that many of the models presented in prior work can be interpreted as limiting cases of it.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1151-2916.1997.tb03034.x
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  • 28
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    THE BOUSSINESQ WEDGE AND THE Jk, L AND M INTEGRALS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— This paper examines the application of the Jk, L and M integrals, in complex-variable form, to the Boussinesq wedge. The wedge is symmetrical and subjected to a point couple and point forces at the apex of the wedge. In the case of a point couple acting at the wedge apex the Jy, L and M integrals are found to vanish for all wedge angles whereas Jx displays a 1/r3 path-dependence; where r is a radial dimension measured from the wedge apex. When the wedge is subjected to point forces at the wedge apex then Jx and Jy are 1/r path-dependent whereas L and M are path-independent.The property that the L and M integrals are path-independent for the Boussinesq wedge is applied to the problem of determining the modes I and II stress intensity factors for a corner-loaded edge crack in a half-plane subjected to both normal and parallel point forces to the free surface of the half-plane.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01534.x
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  • 29
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    A STUDY ON FATIGUE CRACK GROWTH UNDER OUT-OF-PHASE COMBINED LOADINGS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fatigue tests were performed on thin-walled tubular specimens of S45C steel under tension-compression, pure torsion, in-phase and out-of-phase axial-torsional loadings. The relationship between cracking behaviour and stress components on the crack plane was investigated. Measurement of microcrack density showed that microcracking was governed predominantly by the shear stress amplitude acting on the crack plane for all loading conditions. The failure crack was formed by coalescence of many cracks initiated near the maximum shear planes. The cracks grew turning their orientation to the direction perpendicular to the maximum normal stress. The transition of crack orientation occurred at relatively longer crack lengths at a higher stress ratio. The crack growth behaviour for all loading modes can be correlated using an equivalent strain intensity parameter based on shear and normal strains on the crack plane.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01536.x
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  • 30
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    ANALYSIS AND MODELISATION OF SHORT CRACK GROWTH BY DUCTILE FRACTURE MICROMECHANISMS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A ductile medium strength steel has been modelled by means of the Gurson model, and been used to investigate the effect of crack tip constraint in several fracture mechanics specimens. Both numerical and experimental results have been obtained, in the course of the crack extension process, for single edge notch bending specimens with different crack length-to-width ratios. The geometries with the shorter cracks always exhibited higher J values at initiation and steeper J crack growth resistance curves, and these results have been explained in terms of the stress and strain fields and damage development in the region ahead of the crack tip.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00297.x
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  • 31
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    LOW-TEMPERATURE AUTOFRETTAGE: AN IMPROVED TECHNIQUE TO ENHANCE THE FATIGUE RESISTANCE OF THICK-WALLED TUBES AGAINST PULSATING INTERNAL PRESSURE (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— It is shown that autofrettage at low temperatures is superior to autofrettage at room temperature in enhancing the fatigue resistance of thick-walled tubes against pulsating internal pressure. The physical reason is based on the well-known temperature dependence of the mechanical behaviour of metals and alloys which generally exhibit an enhancement of both the yield stress and strain hardening behaviour at lower temperatures. As a consequence, significantly larger compressive residual hoop stresses can be introduced during pressurization at low temperatures than at room temperature. Experimental data obtained on thick-walled tubes of the metastable austenitic stainless steel AISI 304 L which were subjected to pulsating internal pressure at room temperature after autofrettage at temperatures between-110°C and room temperature are presented. These data demonstrate convincingly the advantages offered by low-temperature autofrettage in enhancing both the fatigue life in the finite-life region and the fatigue endurance limit in comparison with autofrettage at room temperature. In conclusion, some specific materials requirements for optimum low-temperature autofrettage performance are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00291.x
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  • 32
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    APPLICATION OF A NORMALIZATION METHOD FOR DETERMINING J-R CURVES IN GLASSY POLYMER PVC AT DIFFERENT CROSSHEAD SPEEDS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A new single-specimen testing method, the normalization method with the so-called LMN calibration function, based on the load separation principle and function calibrations from an individual test record, was used to construct J-R curves directly from load versus load-line displacement records without any additional on-line crack-length monitoring equipment. The research was done on CT-specimens of a glassy polymer PVC at different crosshead speeds ranging from 0.01 to 50 mm/min. The J-R curves evaluated from the normalization method are in good agreement with those from the conventional multiple-specimen testing method in the whole range of the tested crosshead speeds. The results demonstrated the applicability of the normalization method for developing J-R curves at different crosshead speeds in PVC. The crack initiation J-integral values, J0.2, showed a two-regime dependence on the crosshead speeds in the tested crosshead speed range.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00272.x
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  • 33
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    EFFECT OF BIAXIAL MEAN STRESS ON CYCLIC STRESS-STRAIN RESPONSE AND BEHAVIOUR OF SHORT FATIGUE CRACKS IN A HIGH STRENGTH SPRING STEEL (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Biaxial fatigue tests were conducted on a high strength spring steel using hour-glass shaped smooth specimens. Four types of loading system were employed, i.e. (a) fully reversed cyclic torsion, (b) uniaxial push—pull, (c) fully reversed torsion with a superimposed axial static tension or compression stress, and (d) uniaxial push—pull with a superimposed static torque, to evaluate the effects of mean stress on the cyclic stress—strain response and short fatigue crack growth behaviour. Experimental results indicate that a biaxial mean stress has no apparent influence on the stress—strain response in torsion, however a superimposed tensile mean stress was detrimental to torsional fatigue strength. Similarly a superimposed static shear stress reduced the push—pull fatigue lifetime. A compressive mean stress was seen to be beneficial to torsion fatigue life. The role of mean stress on fatigue lifetime, under mixed mode loading, was investigated through experimental observations and theoretical analyses of short crack initiation and propagation. Using a plastic replication technique the effects of biaxial mean stress on both Stage I (mode II) and Stage II (mode I) short cracks were evaluated and analysed in detail. A two stage biaxial short fatigue crack growth model incorporating the influence of mean stress was subsequently developed and applied to correlate data of crack growth rate and fatigue life.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00276.x
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  • 34
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    CRACK INITIATION MECHANISMS IN TORSIONAL FATIGUE (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The development of fatigue damage in Co45Ni specimens during push—pull and reversed torsion tests, performed inside a scanning electron microscope, was observed and the different stress states compared. It appeared that transgranular crack initiation and development is delayed and intergranular crack initiation promoted under torsional loading. This was explained in terms of reduced surface distortion at the emergence of persistent slip bands (PSBs) and smaller compatibility stresses at the PSB-matrix interfaces. The influence of the mechanical strength of grain boundaries on the difference between tensile and torsional fatigue lives is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00280.x
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  • 35
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    STRESS INTENSITY FACTORS AND WEIGHT FUNCTIONS FOR SEMI-ELLIPTICAL SURFACE CRACKS IN FINITE-THICKNESS PLATES UNDER TWO-DIMENSIONAL STRESS DISTRIBUTION (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A Fourier series approach is proposed to calculate stress intensity factors using weight functions for semi-elliptical surface cracks in flat plates subjected to two-dimensional stress distributions. The weight functions were derived from reference stress intensity factors obtained by three-dimensional finite element analyses. The close form weight functions derived are suitable for the calculation of stress intensity factors for semi-elliptical surface cracks in flat plates under two-dimensional stress distributions with the crack aspect ratio in the range of 0.1 ≤a/c≤ 1 and relative depth in the range of 0 ≤a/t≤ 0.8. Solutions were verified using several two-dimensional non-linear stress distributions; the maximum difference being 6%.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01517.x
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    AN IMPROVED PROCEDURE FOR THE DETERMINATION OF HOT SPOT STRESSES IN TUBULAR JOINTS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A conventional finite element method may show a weakness when determining the hot spot stress distributions in the brace/chord intersection region of offshore tubular joints. This is because the chosen element displacement functions do not implicitly satisfy the conditions which prevail on the free surfaces. A procedure has been proposed to modify the conventional finite element method so as to allow the hot spot stresses, which occur at the free boundary of the weld toe of tubular joints, to be determined with improved accuracy. The results obtained by this modified method are compared with both an experimental and a traditional finite element solution. The comparison shows that the modified solution is in better agreement with the experimental data as compared with the traditional solution.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01523.x
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    INFORMATION ON CONFERENCES/SEMINARS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01504.x
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    A SIMPLE TEST METHOD FOR ENERGY DISSIPATION RATE, CTOA AND THE STUDY OF SIZE AND TRANSFERABILITY EFFECTS FOR LARGE AMOUNTS OF DUCTILE CRACK GROWTH (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Simple extensions to the standard deep notch bend test procedure are suggested to allow the collection of data relevant to the energy dissipation rate, D, crack opening angle, COA, and J, all for arbitrarily large amounts of growth in extensive plasticity. The methods of analysis are detailed for real elastic-plastic behaviour of a high strength low-hardening type metal with a view to encouraging use on a wider range of materials. A proposal is made, and equations given, that the particular version of J used for an R-curve derived from the area under the loading diagram, should correspond to the value of the far-field integral, Jff.The relationship between the global measure of COA that emerges from D and the local crack tip opening angle, CTOA, as used in computational studies, is established. Transferability of CTOA data is examined in the light of effects of size and configuration. An explicit rule of the form CTOA √G =f (material and configuration) is proposed for the modelling of ductile growth in finite element studies. It is applied to a set of data in the literature, for the variation of CTOA with size in the deep notch bend test and for the configurations, bending, double edge and centre cracked tension.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01507.x
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    THE ELECTRON CHANNELLING CONTRAST TECHNIQUE APPLIED TO THE CHARACTERISATION OF DISLOCATION STRUCTURES IN THE VICINITY OF A FATIGUE CRACK (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— In this investigation the Electron Channelling Contrast (ECC) technique in scanning electron microscopy (SEM) was applied to reveal the dislocation structures in the vicinity of surface fatigue cracks in comparison to those of cyclically-deformed recrystallized polycrystalline copper. The plastic zone around a fatigue crack was found to consist of an innermost region containing cells, followed by a region containing dense veins and PSBs, surrounded by a structure of loose veins, bundles and loop patches typical of the cyclically deformed matrix. A relation between plastic strain amplitude values deduced from cyclic stress-strain investigations and the dislocation structures near fatigue cracks are given. Typical regions of damage accumulation were identified and plastic strain contours for surface fatigue cracks established. The essentially non-destructive ECC technique is particularly suited to identify the changes in mesoscopic dislocation structures from surface layers to the interior of specimens over large specimen areas.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01510.x
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    INFORMATION ON CONFERENCES/SEMINARS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01494.x
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    PREDICTION OF THE FATIGUE LIMIT OF CRACKED SPECIMENS BASED ON THE CYCLIC R-CURVE METHOD (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The propagation behaviour of fatigue cracks emanating from pre-cracks was numerically simulated to evaluate the development of crack closure with crack growth. The crack opening stress intensity factor at the threshold was approximated as a function of the applied stress and the amount of crack extension. Pre-cracked specimens of a medium-carbon steel with a small surface crack and a single-edge crack were fatigued to investigate experimentally the initiation and propagation of cracks from pre-cracks. Crack closure was dynamically measured by using an interferometric strain/displacement gauge. The threshold condition of crack initiation from pre-cracks was given by a constant value of the effective stress intensity range which was equal to the threshold value for long cracks. The cyclic R-curve was constructed in terms of the threshold value of the maximum stress intensity factor as a function of crack extension approximated on the basis of the experimental and numerical results. The cyclic R-curve method was used to predict the fatigue thresholds of pre-cracked specimens. The predicted values of the fatigue limits for crack initiation and fracture, and the length of non-propagating cracks agreed very well with the experimental results.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01497.x
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    THREE-DIMENSIONAL CRACK-SHAPE EFFECTS DURING THE GROWTH OF SMALL SURFACE FATIGUE CRACKS IN A TITANIUM-BASE ALLOY (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A basic study was performed on the evolution of three-dimensional shapes of small surface fatigue cracks during fatigue, and the effect of this evolution on small-crack growth behavior of a titanium-base alloy. Specifically, the nature and the magnitude of variations in crack aspect ratio, a/c (a is the crack depth and c is the half-surface crack length), during cyclic crack growth and its impact on growth rates have been studied. Experiments were performed on naturally initiated micro-cracks in a microstructure consisting of equiaxed primary-α2 phase in a Widmanstätten (transformed β) matrix. Several cracks under stress ratio (R) levels of 0.1 and −1, were studied. A specialized experimental system, consisting of a laser interferometer (to measure precisely the small-crack surface displacements), and a photo microscope (to automatically and continuously photograph the fatigue micro-cracks) was employed in the study. Apparent aspect ratios of surface cracks were calculated from the compliance response and the surface crack length data as a function of fatigue cycles. These data enabled accurate calculations of growth rates at the surface crack tip as well as the tip at depth in the bulk over the entire crack growth period, thus giving an insight into the crack growth process. Measurements of closure levels of small cracks were also performed and were used to partly account for the differences in growth rates. In the comparisons of small-crack growth data with the large-crack data, surface growth rates correlated relatively well with the large-crack data. Growth rates at depth exhibited large variations due to the irregularity of crack fronts at this location, and these rates deviated significantly from the large-crack behavior. Additionally, these growth rates varied between different cracks. An attempt was made to rationalize these observations in terms of the effects of inhomogeneities present in the microstructure.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01500.x
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  • 43
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    PREDICTION OF FATIGUE FAILURE IN A CRANKSHAFT USING THE TECHNIQUE OF CRACK MODELLING (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A new technique, known as crack modelling, is used here to predict fatigue failure in a crankshaft component. The technique uses a linear elastic finite element (FE) analysis to derive a stress intensity factor (K) for the component under load. The novel feature of the technique is that K is calculated without introducing a crack into a component; the stress field around the maximum stress point is examined and compared to that for a standard centre-cracked plate. The fatigue limit for a crankshaft was successfully predicted, when compared to experimental data. The only material parameter required for this prediction was the threshold stress intensity range, ΔKth.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00397.x
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    EFFECTS OF DRAWING STRAIN AND BLUING ON THE FATIGUE STRENGTH OF EUTECTOID STEEL WIRES (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The effects of bluing, associated with drawing strain, on the fatigue strength of eutectoid steel wires have been investigated. The fatigue limit increases by bluing and the increase is more significant with higher drawing strain. The peak in the fatigue limit with regard to the drawing strain in the wires, at a strain of 2.5, disappears after bluing. On the other hand, in the ferritic steel wires investigated for comparison, the fatigue limit gradually increases with the drawing strain up to 7.7. Furthermore, no appreciable change in the fatigue limit due to bluing is found. Based on the results of hardness tests on fatigue specimens with- and without-bluing, it is deduced that the decrease of the fatigue limit beyond the peak drawing strain in the eutectoid steel wire can partly be attributed to insufficient locking of the high-density dislocations by solute atoms. The effect of relaxation of residual stress during bluing is also briefly discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01520.x
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  • 45
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    LIMITATIONS ON THE USE OF THE STRESS INTENSITY FACTOR, K, AS A FRACTURE PARAMETER IN THE FATIGUE PROPAGATION OF SHORT CRACKS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— It is well known that for very short cracks the stress intensity factor K is not a suitable parameter to estimate the stress level over the small but finite Stage II process zone activation region of size rs near the crack tip, within which crack growth events take place. A critical appreciation of the reasons for the limitations on the applicability of ΔK as a fatigue crack propagation (FCP) parameter, when the crack length a is of the same order of magnitude or smaller than the size of the ‘fatigue-fracture activation region’, rs is presented. As an alternative to ΔK the range Δσs of the cyclic normal stress at a point situated at the fixed distance s=rs/2, ahead of the crack tip, inside the fatigue-fracture activation region, is proposed. It is observed that the limitation on the use of ΔK when the crack is short, is mathematical (and not physical) but this inconvenience is easily circumvented if the stress Δσs at the prescribed distance is used instead of ΔK since nowadays Δσs can be obtained numerically by using finite element methods (FEM). It follows that the parameter Δσs is not restricted by the mathematical limitations on ΔK and so it would seem that there is, a priori, no reason why the validity of the parameter Δσs cannot be extended to short cracks. It is shown that if the Paris law is expressed in terms of Δσs (πrrs)½ instead of ΔK the validity of the modified Paris law can be extended to short cracks.A coherent estimate of the value of the fatigue-fracture activation region rs is derived in terms of the fatigue limit ΔσFL obtained from S-N tests and of the threshold value ΔKth obtained from tests on long cracks where both relate to Stage II crack growth that ends in failure, namely, rs= (ΔKth/ΔσFL)2/π. An overall, threshold diagram is presented based on the simple criterion that, for sustained Stage II FCP, Δσs must be greater than ΔσFL. The study is based on a simple continuum mechanics approach and its purpose is the investigation of the suitability of both ΔK and Δσs to characterise the crack driving force that activates complex fracture processes at the microstructure's scale. The investigation pertains to conditions that lead to the ultimate failure of the component at values of Δσs 〉 ΔσFL.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01521.x
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    A SINGULAR INTEGRAL EQUATION SOLUTION FOR THE LINEAR ELASTIC CRACK OPENING DISPLACEMENT OF AN ARBITRARILY SHAPED PLANE CRACK: PART II REGULAR INTEGRAL SOLUTIONS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The boundary value problem for an arbitrarily shaped plane crack embedded in a 3D linear elastic solid can be reduced to a governing hyper-singular integral equation. A discretizing procedure based on a triangulation of the crack area has been offered in Part I of this work. The main goal of Part I is to introduce the analytical results for the 18 resulting finite-part integrals defined over a triangular mesh area. The finite-part integrals occur in those triangles where the source point coincides with one of the element nodes. Mostly the source point lies outside of the considered triangle. In these cases the occurring area integrals are regular.The aim of Part II is, therefore, the derivation of the closed form expressions for the relevant 18 regular area integrals. The resulting relations are of algebraic form which can easily be coded in compact form. Their numerical proof by two different methods shows the highest accuracy and, therefore, the correctness of the final solutions. The relevant numerical results are offered in Appendix I.With the formulae provided in Part I and Part II of the paper the determination of the coefficient matrix, necessary for the calculation of COD values from a linear equation system, is precise and needs only minimum computer time.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01506.x
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    SUBINTERFACIAL FRACTURE IN FERRITE-AUSTENITE JOINTS UNDER MODE—III LOADING (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Circumferentially notched cylindrical specimens are tested in torsion to obtain critical J values from crack resistance curves. The specimens are explosion cladded, half ferrite, half austenite, with the interface perpendicular to the cylinder axis and the circumferential notch at, or parallel to, the interface. Critical J values for crack extension in mode III were found to be a factor 1.1 to 2.1 higher than under comparable mode I loading.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01511.x
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    THE MINIATURISATION OF THE 4-POINT-BEND TEST (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Strength measurements are becoming increasingly important for electroceramics. Bending of specimens small enough to be cut out of small electroceramic components may be one possibility. Therefore the miniaturisation of the 4-point bend-test for ceramic specimens is now being attempted. In this paper the errors in determining the flexural strength arising from the test principle itself, plus the geometry and measuring inaccuracies are calculated and expressed as a function of the outer span length. Contact pressure and a tolerable total measuring inaccuracy determines the dimensions of miniature specimens and fixtures. The possibilities of appropriate specimen preparation are also investigated.Ceramic materials show a volume (i.e. a specimen size) dependence of strength which is described by Weibull's statistical theory. The applicability of the miniature bend-fixtures is demonstrated by measuring this volume effect.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01514.x
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    AN IMPROVED NUMERICAL TECHNIQUE FOR SIMULATING THE GROWTH OF PLANAR FATIGUE CRACKS (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— This paper describes a versatile technique for simulating the fatigue growth of a wide range of planar cracks of practical significance. Crack growth is predicted on a step-by-step basis from the Paris law using stress intensity factors calculated by the finite element method. The crack front is defined by a cubic spline curve from a set of nodes. Both the 1/4-node crack opening displacement and the three-dimensional J-integral (energy release rate) methods are used to calculate the stress intensity factors. Automatic remeshing of the finite element model to a new position which defines the new crack front enables the crack propagation to be followed. The accuracy and capability of this finite element simulation technique are demonstrated in this paper by the investigation of various problems of both theoretical and practical interest. These include the shape growth trend of an embedded initially penny-shaped defect and an embedded initially elliptical defect in an infinite body, the growth of a semi-elliptical surface crack in a finite thickness plate under tension and bending, the propagation of an internal crack in a round bar and the shape change of an external surface crack in a pressure vessel.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01495.x
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  • 50
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    RELAXATION OF RESIDUAL STRESSES AT COLD-WORKED FASTENER HOLES DUE TO FATIGUE LOADING (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Cold-expansion of fastener holes is now commonly used within the aerospace industry to increase the fatigue endurance of airframes. Although a number of methods of cold expansion are possible, the split-sleeve cold-expansion process is the most widely accepted and is frequently used in the repair and manufacture stages of both military and civil aircraft. In the present work, the redistribution of residual hoop stresses due to the application of constant amplitude fatigue loading at 4% cold-expanded holes has been studied. A modified Sachs method was adopted to evaluate the residual stress profiles and a replication technique was used to quantify crack growth. It was found that the decay of the residual hoop stress profile near the bore of the hole was due to the initiation and growth of small fatigue cracks. Cracks were found to initiate both near and below the fatigue limit, but subsequently arrested so stabilising the overall residual stress profile.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb01501.x
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    FACTORS CONTROLLING THE FATIGUE STRENGTH OF NITRIDED TITANIUM (1997)
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    Details
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The factors affecting the fatigue strength of nitrided titanium were clarified. The fatigue strength depended strongly on the fracture strength of the compound layer formed on the surface by nitriding. We found a Hall-Petch relationship between the fatigue strength of nitrided titanium and the grain size. The findings indicated that the reduction in the fatigue strength by nitriding results from both the formation of the compound layer possessing low fracture strength and grain growth occurring from ordinary nitriding. Furthermore, low-temperature nitriding (620°C, 24 h) was proposed to suppress grain growth. This treatment method improved not only the wear resistance and the corrosion resistance but also the fatigue strength of titanium.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1460-2695.1997.tb00404.x
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    The inhibition effects of some heterocyclic nitrogenous compounds on the corrosion of the steel in CO-saturated NaCl solutions (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 34-39 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The corrosion inhibition efficiencies of five different nitrogenous heterocyclic bases 3-amino-1,2,4-triazole (ATA), 2-amino-1,3,4-thiadiazole (ATDA), (p-toly) 1,3,4-triazole (TTA), 3-amino-5-methylmercapto-1,2,4-triazole (AMTA) and 2-aminobenziotriazole (ABA) on carbon steel were investigated in relation to their molecular structure. Corrosion current densities, in the absence and presence of the compounds, were used to assess inhibition performances. The corrosion efficiencies were considered on the basis of their molecular planarity, aromaticity and p-electron donation assumption.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310456270
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    Crack-resistant and anticorrosive coatings based on vulcanized water dispersion of chlorine-sulpho-polyethylene (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 108-114 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Advanced crack-resistant coatings based on water dispersion of chlorine-sulpho-polyethylene (CSPE, Hypalon®) vulcanized by Mannich alkalis (MA) water solution were obtained. Application of MA as a CSPE structure component makes it possible to produce a vulcanized net of saturated polymer, and thus to receive ecologically safe impenetrable crack resistant coatings of any substrata (concrete, metal, plastic, etc.). The coatings can be applied in aircraft, automotive, shipbuilding, paint and varnish industries, civil engineering, etc. as a corrosion-resistant material. The optimal coating composition and its mechanical properties have been studied.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310463966
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    Prediction and measurement of mild steel corrosion inhibition by alkyl pyridinium chloride and alkyl trimethyl ammonium bromide surfactants in acidic chloride media (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 186-192 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Surfactants are important corrosion inhibitors that are used in different applications. This paper utilizes the recently developed methodology and formulae to predict mild steel corrosion inhibition by alkyl pyridinium chloride and alkyl trimethyl ammonium bromide compounds. By utilizing different surfactants of varying chain lengths in different acidic media and determining the associated corrosion inhibition, the relationship between surfactant concentration, surfactant hydrocarbon chain length, surfactant critical micelle concentration, and corrosion inhibition can be evaluated. The results from this study can be used to improve relevant industrial uses of surfactants for corrosion inhibition.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310471750
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    The cyclic hydroxylamines: a new class of corrosion inhibitors of carbon steel in acidic medium (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 201-207 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Several cyclic hydroxylamines containing hydrophobic substituents were prepared. All these hydroxylamines were tested for corrosion inhibition of carbon steel in 1M HCl at 60°C by gravimetric and electrochemical methods. All compounds showed excellent corrosion inhibition efficiency (IE per cent) in acidic solutions containing 400?ppm of the inhibitors; Inhibitor Efficiencies in the range 66-98 per cent were measured by the gravimetric method. Comparable results were obtained by the electrochemical method using Tafel plots for the IE of some of the selected synthesised compounds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310471778
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    Effect of divalent cations in low zinc ambient temperature phosphating bath (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 286-290 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new zinc phosphating bath, which produces coatings at relatively lower temperatures within a reasonable time by using of chemical accelerators has been devised. Improvement of the bath performance by the addition of divalent cations like calcium, manganese and magnesium has been studied. Bath formulation and operating conditions have been optimized by coating weight determinations. Corrosion resistance property of the resultant coatings has been evaluated in 1,000?ppm Cl- by electrochemical methods such as potentiodynamic polarization and impedance measurements. Results of the electrochemical techniques have been complemented by salt spray, humidity and immersion tests. Porosity and roughness of the coatings have also been studied. Results show that the phosphating bath with manganese addition gives good coatings within 30?min. Studies have shown that the corrosion resistance of the resultant coatings are much superior than the conventional coatings.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310482523
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    Severe corrosion in a waste incinerator plant due to flue gas and steam leakage (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 334-340 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In a new build waste incinerator, the waste (refuse derived fuel) was burned on a discontinuous moving grate. Frequent furnace overpressure peaks occurred because of this firing method and as a result, flue gas and fly-ash were pushed out of the boiler and into the building. During the plant start up period, a seal in a water-feed pipeline broke, and a large amount of condensed steam was discharged into the boiler house. Shortly thereafter, very severe corrosion was noticed on the galvanised gangways, steel building components, the boiler aluminium sheeting and on processing lines. A theoretical study of the condensation of the flue gas indicated that sulphuric acid would condense before it reached the external aluminium sheeting and that under normal conditions, dry hydrochloric acid fumes would be removed by the boiler house ventilators. However, the steam leakage had caused the hydrochloric acid to be dissolved in the condensed water and that had resulted in the severe corrosion damage, which had become evident subsequently.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310492243
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    Inhibition of CO corrosion of carbon steel by rosin amide (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 410-413 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The inhibition of sweet gas corrosion of carbon steel in high pressure CO2 saturated brine by rosin amine has been studied by weight-loss, electrochemical polarisation and electrochemical impedance spectrum measurements. The results obtained revealed that rosin amine compound is a good inhibitor. The inhibition efficiency increased with the increase of inhibitor concentration. Rosin amine acts mainly as a adsorptive mixed-type inhibitor. The adsorption of the inhibitor on the metal surface in high pressure CO2 saturated brine obey Langmuir isotherm. The adsorption mechanism of inhibitor was both electrostatic-adsorption and chemisorption.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310501567
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    Synthesis of some new bisquaternary ammonium salts as acid corrosion inhibitors for carbon steel (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 436-441 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A variety of bisquaternary ammonium salts was prepared for the first time by reacting N,N,N',N'-tetraallyl-1,6-hexanediamine with allyl chloride, propargyl chloride, benzyl chloride, and 1-bromododecane in excellent yields (〉90 per cent). Inhibition efficiency for different concentrations of the synthesised compounds for the inhibition of corrosion of carbon steel in 1?M HCl exposed for 6?h at 60°C was determined gravimetrically. The bisquaternary salts exhibited excellent inhibition efficiencies (97-99 per cent) in the acidic solution containing 400?ppm of the inhibitor. Comparable results were obtained by the electrochemical method using Tafel plots for the inhibition efficiency of the synthesised compounds. The adsorption of these compounds on carbon steel surface was found to obey Temkin's adsorption isotherm. The work marked the beginning of constituting an important class of new inhibitors containing multiple adsorption centres of positive nitrogens as well as p-donor moieties.
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    URL: http://dx.doi.org/10.1108/00035590310501594
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    A new corrosion-resistant material for use as an inert anode in electrolytic molten salt aluminium extraction systems (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 25-30 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The spinel NiFe2O4 has been identified as being a potentially successful anti-corrosion ceramic that can be used in aluminium electrolysis under molten salt corrosive conditions (970°C). The evaluation and fabrication processing of NiFe2O4 has been studied in this paper. According to the analysis and comparison of material properties, it has been concluded that fabrication technology for making anti-corrosion electrode material would not be exceptionally difficult and therefore that the material has a strong potential for use in this service.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410512708
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    Pitting corrosion of copper in chloride solutions (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 52-61 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The pitting corrosion of copper in chloride solution has been studied using potentiostatic polarisation and surface analysis techniques. X-ray photoelectron spectroscopy (XPS) results enabled conclusions to be drawn about the nature of the film formed in different chloride concentrations. In dilute chloride solutions (C=10-3?M), XPS proved the existence of Cu2O film on the copper surface. It was found that, depending on the chloride content, pitting of copper was evident only after the formation of a protective film of Cu2O. A current-time trend plot showed the onset of fluctuations, which were dependent on the NaCl content. On the other hand, introduction of O2 into the solution during prepolarisation time period increased the current value of the fluctuations at the same concentration of NaCl in comparison with the freely aerated solution. These results, together with the surface analysis, confirm the role of chloride ion on the mechanism of pitting attack on copper metal.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410512735
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    The sulphidation behaviour of hard chromium plated coatings on steel (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 130-135 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The sulphidation behaviour of high contraction (HC) and low contraction (LC) chromium plated steel was studied in sulphur with a partial pressure of 1?atm at 1, 3, 5 and 7?h and 0.1 and 0.01?atm at 5?h. The temperature was 600°C throughout the work. It was found that HC and LC chromium plating imparted significant sulphidation resistance to steel. It should be mentioned that by increasing sulphidation time and sulphur partial pressure, the hardness of chromium coating decreased. LC chromium coating had a lower thermal shock resistance than the HC coating. Thus, it was concluded that the HC chromium coating had the better sulphidation resistance.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410523229
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    The application of "grey system theory" in a molybdate inhibitive study (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 200-204 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this study, electrochemical parameters were used to evaluate the inhibition effects of molybdate and silicate inhibitors in tap water. With the aid of "grey system" theory, we determine the inhibitive state model of such systems.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410533147
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    A TEM study of the oxide scale development in Ni-Cr alloys (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 216-222 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study was undertaken to investigate the isothermal oxidation behaviour of Ni-Cr binary alloys with 10, 20 and 30?wt per cent Cr exposed in air for 50?h at 1,000°C. Analytical transmission electron microscopy along with light microscopy and X-ray diffraction were used to characterise the oxide scale. It was observed that the scaling behaviour exhibited by the Ni-Cr alloys changes from generally "non-protective" to "protective" as their Cr content increases from 10 to 30?wt per cent. The Ni-10Cr alloy formed a continuous network of NiO leading to scales of high thickness while Ni-30Cr exhibited only a-Cr2O3 at its surface. The Ni-20Cr alloy exhibited all three oxide phases and an intermediate scaling behaviour.
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    URL: http://dx.doi.org/10.1108/00035590410533174
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    The inhibition effects of a new heterocyclic bisquaternary ammonium salt in simulated oilfield water (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 272-276 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A kind of novel heterocyclic bisquaternary ammonium salt (MBQA) was successfully synthesised with metronidazole as matrix and dichloroethyl ether as the link agent. Weight loss measurement, potentiodynamic polarisation curves, electrochemical impedance spectroscopy and atomic force microscopy were used to evaluate the corrosion inhibiting performance of MBQA in simulated oilfield water. Experimental data revealed that MBQA acted as an inhibitor in the acidic environment and, furthermore, the compound was a mixed-type inhibitor. It was found that inhibition efficiency increased with an increase in MBQA concentration at different temperatures. The process of inhibition was attributed to the formation of an adsorbed film on the metal surface, which protected the metal against corrosive agents.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410541346
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    Performance evaluation of different hardener for epoxy resin (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 348-354 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Coatings with outstanding chemical and physical properties can be obtained from two-pack formulations without stoving. The epoxy resin was cured with different amine-based compounds, such as polyamide (PA), the aniline copolymer of triethanolamine titanate and aniline formaldehyde. The thermal resistance properties of the cured films were analysed using the thermo-gravimetric method. This study also examined the effect of coating resistance of 3 per cent sodium chloride solution by means of electrochemical impedance measurements. Coatings that included the epoxy triethanolamine titanate showed superior behaviour, compared to the other two systems tested. This hardener can be recommended instead of using conventional PA and polyamidoamide hardeners for epoxy two-pack systems that are to be used to protect the steel structures from highly corrosive chemical and marine environments.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410554919
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    Determination of suitable corrosion inhibitor formulation for a potable water supply (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 399-405 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The inhibition effects of sodium silicate and polyphosphate on corrosion of carbon steel in a potable water supply have been studied using weight loss, electrochemical impedance and Tafel polarization measurements. In the water supply under test there were sufficient calcium ions, (220?ppm), to form the normal polyphosphates salts, which is a requisite for good protection. It was concluded that the inhibition efficiency of polyphosphate was higher than that of silicate. The synergistic inhibition effects of polyphosphate on the inhibition of silicate were studied. The results illustrated that silicates and polyphosphates can be useful as corrosion inhibitors for reducing the corrosion of carbon steel in potable water supply distribution systems. The optimal concentration for silicate alone was determined to be 11?ppm and for polyphosphate alone was 8?ppm. The optimum ratio of concentration for sodium silicate to sodium polyphosphate was 4?:?3.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410560949
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    Review of materials for solar thermal collectors (2005)
    Bradford : Emerald
    Anti-corrosion 52 (2005), S. 199-206 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - To cover the main contributions and developments in solar thermal collectors through focusing on materials, heat transfer characteristics and manufacturing challenges. Design/methodology/approach - A range of published papers and internet research including research work on various solar thermal collectors (flat plate, evacuated tubes, and heat pipe tube) were used. Evaluation of solar collectors performance is critiqued to aid solar technologies make the transition into a specific dominant solar collector. The sources are sorted into sections: finding an academic job, general advice, teaching, research and publishing, tenure and organizations. Findings - Provides information about types of solar thermal collectors, indicating what can be added by using evacuated tube collectors instead of flat plate collectors and what can be added by using heat pipe collectors instead of evacuated tubes. Research limitations/implications - Focusing only on three types of solar thermal collectors (flat plate, evacuated tubes, and heat pipe tube). Practical implications - Useful source of information for consultancy and impartial advice for graduate students planning to do research in solar thermal technologies. Originality/value - This paper fulfils identified information about materials and heat transfer properties of materials and manufacturing challenges of these three solar thermal collectors.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590510603210
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    Corrosion inhibition of brass by benzotriazole derivatives in NaCl solution (2005)
    Bradford : Emerald
    Anti-corrosion 52 (2005), S. 226-232 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - Copper and its alloys are widely used in industries because of their good resistance to corrosion and are often used in cooling water systems. Brass has been widely used for shipboard condensers, power plant condensers and petrochemical heat exchangers. Brass is susceptible to the corrosion process known as dezincification by means of which brass looses its valuable physical and mechanical properties leading to failure of structure. The aim of this investigation was to control the dezincification of brass in 3 per cent NaCl solution using benzotriazole (BTA) derivatives. Design/methodology/approach - BTA derivatives namely 1-hydroxymethylbenzotriazole (HBTA) and N,N-dibenzotriazol-l-ylmethylamine(ABTA) were synthesised and their inhibition behaviour on brass in 3 per cent NaCl solution was investigated by the weight-loss method, potentiodynamic polarisation, electrochemical impedance and solution analysis techniques. The morphology of the brass after corrosion in the presence and absence of the BTA derivatives was examined using scanning electron microscopy (SEM). Findings - Potentiodynamic polarisation studies showed that the BTA derivatives investigated were mixed type inhibitors, inhibiting the corrosion of brass by blocking the active sites of the brass surface. Changes in the impedance parameters (charge transfer resistance and double layer capacitance) were related to the adsorption of BTA derivatives on the brass surface, leading to the formation of a protective film. Solution analysis revealed that the BTA derivatives excellently controlled the corrosion of brass. SEM micrographs showed the formation of compact surface film on the brass surface in the presence of inhibitors, thereby providing better corrosion inhibition. Originality/value - Contributes to research on corrosion protection for copper and its alloys.
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    URL: http://dx.doi.org/10.1108/00035590510603265
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    Application of numerical simulation to flow-induced corrosion in flowing seawater systems (2005)
    Bradford : Emerald
    Anti-corrosion 52 (2005), S. 276-279 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - To study flow-induced corrosion mechanisms for carbon steel in high velocity flowing seawater and explain corrosive phenomena. Design/methodology/approach - An overall mathematical model for flow-induced corrosion of carbon steel in high velocity flow seawater was established in rotating disk apparatus using both numerical simulation and test methods. By studying the impact of turbulent flow using the kinetic energy of turbulent approach and the effects of the computational near-wall hydrodynamic parameters on corrosion rates, corrosion behaviour and mechanism are discussed here. It is applicable to deeply understand the synergistic effect mechanism of flow-induced corrosion. Findings - It is scientific and reasonable to investigate carbon steel corrosion through correlation of the near-wall hydrodynamic parameters, which can accurately describe the influence of fluid flow on corrosion. The computational corrosion rates obtained by this model are in agreement with measured corrosion data. It is shown that serious flow-induced corrosion is caused by the synergistic effect between corrosion electrochemical factor and hydrodynamic factor. While corrosion electrochemical factor plays a dominant role in flow-induced corrosion. Originality/value - The corrosion kinetics and mechanism of metals in high velocity flowing medium is discussed in this paper. These results will help someone who is interested in flow-induced corrosion to understand in depth the type of issue.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590510615767
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    The inhibition by dodecylamine of enhanced dissolution of Cu-Ni alloy initiated by an AFM tip/surface interaction (2005)
    Bradford : Emerald
    Anti-corrosion 52 (2005), S. 323-327 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - To investigate the influence of an organic corrosion inhibitor on the enhanced dissolution of metal, initiated by AFM tip scratching in corrosive media. Design/methodology/approach - The test solutions were 1.5?M NaCl and 0.01?M HCl. AFM tip scratching experiments were performed for Cu-Ni alloys in solutions with or without 0.005?M dodecylamine. AFM frictional loop tests were also performed to investigate the effect of dodecylamine on the tip-surface frictional interaction. Findings - Enhanced dissolution of Cu-Ni alloy was observed as a result of AFM tip scratching both in NaCl and HCl solutions, and in HCl the effect was more severe than was the case in NaCl. Enhanced dissolution was inhibited markedly by adding 0.005?M dodecylamine to the corrosive media. The results of frictional loop tests indicated that frictional interaction between the tip and the alloy surface was diminished by the adsorption of dodecylamine on the sample surface. The weakening of tip-surface frictional interaction and the elevation of the ionization energy of metal atoms were responsible for the notable inhibition effect of dodecylamine on the accelerated dissolution. Originality/value - In this paper, the influence of an organic corrosion inhibitor on the corrosion of metal induced by outside forces was investigated. This was carried out initially by AFM scratching skill and the inhibition mechanism of dodecylamine on the enhanced dissolution of Cu-Ni alloy initiated by AFM tip scratching.
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    URL: http://dx.doi.org/10.1108/00035590510624659
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    Silica fume - formed during the manufacture of ferrosilicon alloys - as an extender pigment in anticorrosive paints (2005)
    Bradford : Emerald
    Anti-corrosion 52 (2005), S. 345-352 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - This paper is concerned with the study of silica fume that arises in tonnage amounts during the manufacture of ferrosilicon alloys; this was done in order to maximize productivity and to create new market for industrial by-product and/or waste material. Design/methodology/approach - The structure and particle shape of silica fume were identified using X-ray diffraction and electron microscope, respectively. Standard methods were used for the identification of chemical analyses, solubility, hydrogen ion concentration, specific gravity, bulking value, oil absorption, chemical resistance and particle size. The characterized and evaluated silica fume was applied in several paint formulations. The physico-mechanical, chemical and corrosion protective properties of the paint films were measured according to standard methods. Findings - The silica fume under investigation was a fine lightweight fluffy amorphous powder. It has a grayish-white color that makes it suitable for use as a filler and extender pigment in a wide variety of different fields of application; its amorphous nature favors safe use from a standpoint of industrial hygiene. It can be used as an economic pigment that possesses suitable values of specific gravity, bulking value and oil absorption. It also is inert, neutral and of an excellent chemical resistance. The material can be used successfully as an extender pigment in different paint formulations; taking into consideration that alkyd resin based paints should not be used in alkaline environments or mixed with basic pigments, or the paint film will deteriorate. Silica fume particles in the pigment mixture may offer a suitable opportunity for the voids formed by the larger particles to be occupied by smaller ones to produce a condition of maximum packing. It can be successfully used with the flaky aluminum or stainless steel anticorrosive pigments to produce a highly efficient corrosion protective film. Originality/value - There is increasing environmental concern with regard to excessive volumes of solid waste hazards accumulation. Silica fume that arises - as a disposal material - in tonnage amounts during the manufacture of ferrosilicon alloys can find a new market in paint industry. It can be used successfully for anticorrosive paints to provide well backed paint films.
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    URL: http://dx.doi.org/10.1108/00035590510624686
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    Corrosion inhibitory effects of a new synthetic symmetrical Schiff-base on carbon steel in acid media (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 266-271 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this investigation, the inhibitory effect of a new synthesised tetra-dentate Schiff-base, bis-(2-hydroxy-1-naphthaldehyde) 1,6-hexadiamine (A1), on the corrosion of carbon steel in 1?M HCl and 0.5?M H2SO4 media solutions was studied using various techniques including electrochemical impedance spectroscopy polarisation curves and weight loss. The new compound was shown to be a very good inhibitor and had better behaviour in 1?M HCl than was the case in 0.5?M H2SO4. Potentiodynamic polarisation tests showed that this inhibitor had both cathodic and anodic action. Changes in Tafel and impedance parameters (Icorr, Rct and Cdl) indicated that the absorbed protective film grows with increasing exposure time and concentration of inhibitor. The maximum inhibition efficiency was approximately 97 per cent and 95 per cent at 100?ppm (A1) in 1?M HCl and 0.5?M H2SO4. The adsorption of this inhibitor on a carbon steel surface in both acidic media followed Langmuir adsorption isotherm behaviour.
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    URL: http://dx.doi.org/10.1108/00035590410541337
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    A multi-point corrosion monitoring system applied in a 1,300?MW coal-fired boiler (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 321-330 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Combustion modifications to minimize NOX emissions have magnified the importance of waterwall corrosion in coal-fired boilers. The physics and chemistry controlling corrosion processes can be highly non-linear and are challenging to describe in terms of their likely overall combustion behavior. This paper describes the application of a multi-point, real time corrosion surveillance system to a large boiler firing high sulfur coal. This technology, incorporating electrochemical sensing and wireless signal transmission, enables combustion engineers and plant operating personnel to make informed decisions regarding the quantitative relationships between operating conditions, NOX emissions, and any resultant extent/magnitude of waterwall corrosion.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590410554883
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    Effect of deformation-induced martensite on the pit propagation behavior of 304 stainless steel (2004)
    Bradford : Emerald
    Anti-corrosion 51 (2004), S. 381-388 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Specimens of 304 stainless steel with various martensite contents were prepared by a low temperature (-70°C) elongation method. Optical microscopy and transmission electron micrography were used to study the phase structure of the samples. A simulated occluded cell (OC) and electrochemical impedance spectroscopy were used to study the chemical and the electrochemical changes within pits on 304 stainless steel containing the different martensite contents. The EIS results showed that the martensite phase decreased not only the solution resistance in pit, but also the polarization resistance value between metal and solution in pit. The composition of the passive film in OC solution was studied by X-ray photoelectron spectroscopy. It was observed that martensite transformation was a very important factor in changing the composition of the passive film. The martensite phase destroyed the integrality and compactness of the passive film. For these reasons, pit propagation in Type 304 stainless steel was accelerated with increasing martensite content.
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    URL: http://dx.doi.org/10.1108/00035590410560921
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    A study of carbon steels in basic pitting environments (2005)
    Bradford : Emerald
    Anti-corrosion 52 (2005), S. 365-370 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - Aims to study the behaviour of four polycrystalline carbon steels in basic pitting solutions. Design/methodology/approach - Electrochemical investigations were carried out on four steels: Fe.06C, Fe.18C, Fe.22C and Fe.43C. The analysis was made using an X-ray fluorescence apparatus. The performance indicator was the pitting potential, which was obtained through potentiodynamic sweeping. Emphasis was placed on the influence of the pH, chlorine concentration, phase proportions in the steel and the initial electrode surface state. Findings - The results showed that in a solution with a low chlorine concentration, the performance of the steels according to pitting corrosion resistance decreased with the increase in carbon content. By raising the chlorine concentration, the order of performance was inverted gradually, while at a high chlorine concentration, the behaviour of the steels tended to be similar. The interpretation of the results is based on the consideration of cathodic reactions on the level of the cementite phase and the difference in the local chemical properties of the solution. In neutral solutions, pitting potentials were shifted cathodically, but the main observations developed for basic solutions remained valid. Originality/value - Provides further research on pitting corrosion.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590510624703
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    Corrosion effects on the electrical performance of silver metal contacts (1999)
    Bradford : Emerald
    Anti-corrosion 46 (1999), S. 85-94 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this work, commercial silver metal contacts welded on top of silver plated brass or brass substrates have been exposed to air rich in NaCl. Scanning electron microscopy and energy dispersive analysis of the exposed contact surfaces were performed to identify the corrosion by-products on top of the silver contacts, suspending wafers, and welding materials. Surface corrosion products were mainly found to consist of small spherules of Cu-Zn or Ag-Cu compounds which cover the surface of the contact proper with low adhesion properties. They mainly originate from the underplating wafer or welding materials. Electrical characterization of the contacting materials was based on dc temperature overheat tests, current switching cycle tests, and energy storage during ac current excitation. The experimental results display that the operating environment is indeed a very significant parameter determining the overall performance of the electrical contacts. New design rules as well as material selection properties may have to be systematically considered to allow for electrochemical induced degradation in saline operating environments.
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    URL: http://dx.doi.org/10.1108/00035599910263152
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    Effect of environmental factors on the atmospheric corrosion of mild steel in aggressive sea coastal environment (2000)
    Bradford : Emerald
    Anti-corrosion 47 (2000), S. 215-226 
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    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The eastern coast of Saudi Arabia has one of the most corrosive environments in the world. Dhahran is therefore an ideal location for the study of atmospheric corrosion. One out of every seven cars in the region is corroded. The atmosphere is contaminated by SO2 and a high concentration of suspended particulate matter (SPM) containing sand, salt and carbon particles, exceeding the World Health Organization (WHO) and Middle East Environmental Protection Agency (MEPA) limits most of the time. Corrosion proceeds in the Dhahran atmosphere at a R.H. as low as 40 per cent. At locations close to the sea (1.5 Km), ß-FeOOH is the major corrosion product and a- and ?-FeOOH with some aluminates, silicates and hydrocarbons the minor products. At a location remote from the sea a- and ?-FeOOH are found to be the major corrosion products as shown by XRD and FTIR spectroscopy. The concentration of hydrogen ions, chloride ions and SO2 appears to control the corrosion process during the initial exposure period up to one year and the adsorption of anions on the corrosion product films in the later period.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590010344312
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    Optimising the corrosion protective abilities of lamellar micaceous iron oxide containing primers (2000)
    Bradford : Emerald
    Anti-corrosion 47 (2000), S. 226-232 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Lamellar micaceous iron oxide paints are successfully employed to provide longlife corrosion protection for metallic structures when exposed to highly aggressive environments. The aim of this work was to formulate and manufacture lamellar micaceous iron oxide paints, able to be used on the protection of steel structures exposed to water. Several formulation and manufacture variables were taken into account. Many paint films fail when they are saturated with moisture and blistering is a common failure because primers usually are not designed to allow the liquid to dissipate back out through the film. Consequently the film can not resist the formation of projections which result in local adhesion loss. For maximum durability, primers must be properly formulated and manufactured. Film permeability, which depends on paint composition (pigment volume concentration) and micaceous iron oxide dispersion time, seems to be the key characteristic controlling subsequent coating performance. Laboratory results indicated that lamellar micaceous iron oxide is a pigment which provides an anticorrosive action by providing a barrier effect. Film permeability must be compatible so as to attain a satisfactory rusting and blistering resistance.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590010344321
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    Corrosion behaviour of Monel in phosphoric acid (2000)
    Bradford : Emerald
    Anti-corrosion 47 (2000), S. 285-287 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nickel alloys are widely used as constructional materials in chemical processing industries. They are very resistant to pitting and crevice corrosion. In the present work, the corrosion behaviour of Monel in phosphoric acid of different concentrations has been studied by weight loss and electrochemical methods. It has been observed from the polarization studies that the passivation range slightly varies with H3PO4 concentration. The nature of the passive film has been investigated using the electrochemical impedance method.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590010351521
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  • 81
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    Stress corrosion cracking behaviour of precipitation hardened stainless steels in high purity water environments (2001)
    Bradford : Emerald
    Anti-corrosion 48 (2001), S. 37-47 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The susceptibility of 17-4PH and 17-7PH stainless steels to stress corrosion cracking (SCC) is examined in the present investigation. The specimens were tested in the presence of NaCl and NaOH (20%) at 908C and various pH values. The evaluations were carried out using the CERT test, at a speed of 10-6s-1, supplemented by anodic polarisation and electrochemical noise analysis. The main objective was to identify the conditions of both susceptibility and performance of these materials. Fractographic analyses revealed both ductile and brittle fractures. Also, the presence of intergranular cracks was a clear indication of a characteristic anodic dissolution of the material. Nevertheless, the main mechanism for stress corrosion crack propagation was hydrogen embrittlement. From the experimental results, it was concluded that electrochemical noise analysis is a reliable technique for the identification of crack nucleation and growth.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590110365318
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  • 82
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    Corrosion due to AC influence of very high voltage power lines on polyethylene-coated steel pipelines: evaluation of risks - preventive measures (2001)
    Bradford : Emerald
    Anti-corrosion 48 (2001), S. 221-227 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Shows how observations (1993-1999) and on-site and laboratory measurements (1993-1996) have made it possible to define certain prevalent parameters concerning AC corrosion risks. These are from the evaluation and prevention of AC corrosion risks as practised by Gaz de France.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/EUM0000000005629
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  • 83
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    Thermodynamic parameters of electrodeposition of Zn-Co-TiO composite coatings (2001)
    Bradford : Emerald
    Anti-corrosion 48 (2001), S. 235-241 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Zinc-cobalt alloys have been electrodeposited from a sulphate bath. The effect of process variables, including temperature, time, concentration of cobalt sulfate and current density on the Zn-Co deposition was investigated from kinetic and mechanistic viewpoints. Activation energies, enthalpies and entropies were determined according to Arrhenius and absolute rate theories. The codeposition mechanism of TiO2 with cobalt-zinc in the presence of benzyl triethanol ammonium exthoxylate (BTAE) has been studied. The optimum concentration of the additive was reported. The mechanism of incorporation of TiO2 was suggested and confirmed in view of calculated free energy of adsorption of TiO2. Corrosion resistance of Zn-Co-TiO2 alloy was determined by a salt spray test under most of the plating conditions studied.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/EUM0000000005631
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  • 84
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    Nickel base alloys and newer 6Mo stainless steels meet corrosion challenges of the modern day chemical process industries (2001)
    Bradford : Emerald
    Anti-corrosion 48 (2001), S. 287-297 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The first major nickel alloy introduced to the industry, about 100 years ago, was a Ni-Cu alloy 400. This alloy is still widely used in a variety of industries and will continue to be used in this current century. Over the past 100 years, especially in the last 50 years, improvements in alloy metallurgy, melting technology, and thermo-mechanical processing, along with a better fundamental understanding of the role of various alloying elements has led to new nickel alloys. These have not only extended the range of usefulness of existing alloys by overcoming their limitations, but are reliable and cost-effective and have opened new areas of applications. This paper briefly describes the various nickel alloy systems developed during the last 100 years and comments on what the future holds for the newer alloys developed in the last 20 years and on the competition faced by these alloys in the new millennium. High-temperature alloys are not discussed in this paper.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590110403090
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  • 85
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    Synergistic inhibition of anionic and nonionic surfactants on corrosion of mild steel in acidic solution (2001)
    Bradford : Emerald
    Anti-corrosion 48 (2001), S. 309-318 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Sodium oleic sulfonate (SOS), polyoxyethylene (20) sorbitan monooleate (Tween 80 or T80) and their mixtures have been studied as acid corrosion inhibitors for mild steel in 1M HCl using adsorption and gravimetric techniques. All the data reveal that the compounds act as inhibitors in the acid environment. The adsorption and inhibition efficiency are discussed as a function of the concentration and the nature of mixing the two surfactants. T80 + aSOS mixtures show a better inhibition effect than SOS + aT80, that increases with the value of aSOS. The interaction and synergism of the investigated mixtures are studied by calculating the interaction parameters (ß) and the degree of synergism (S) from surface tension-concentration and corrosion data. The degree of synergism for T80 + aSOS is higher than that of SOS + aT80. This is believed to be due to the presence of the small amount of the co-surfactant SOS which serves as an anchor molecule for the nonionic molecules.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/EUM0000000005885
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  • 86
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    Influence of sodium sulphite on corrosion inhibition by the sodium gluconate –Zn system (2001)
    Bradford : Emerald
    Anti-corrosion 48 (2001), S. 371-375 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The inhibition efficiency of sodium gluconate (SG) in controlling corrosion of carbon steel immersed in the environment containing 60 ppm Cl– has been evaluated in the presence and absence of Zn2+ by weight loss method. SG and Zn2+ show a synergistic effect. The protective film has been analysed by FTIR and fluorescence spectra. The protective film consists of Fe2+-gluconate complex and Zn(OH)2. The film is found to be UV-fluorescent. The IE of the SG-Zn2+ system increases in the presence of Na2SO4; but decreases in the presence of Na2SO3 and also in the presence of N-cetyl-N,N,N-trimethyl ammonium bromide. This study reveals that the transporting phenomenon plays a larger role than the scavenging of dissolved oxygen.
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    URL: http://dx.doi.org/10.1108/EUM0000000006257
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  • 87
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    Poly(styrene sulphonic acid)-doped polyaniline as an inhibitor for the corrosion of mild steel in hydrochloric acid (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 19-26 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Poly(styrenesulphonic acid)-doped polyaniline has been synthesised and the influence of this polymeric compound on the inhibition of corrosion of mild steel in 1M HCl has been investigated using weight loss measurements, galvanostatic polarisation studies, electropermeation studies and a.c. impedance measurements. The polymer acts predominantly as an anodic inhibitor. Hydrogen permeation studies and a.c. impedance measurements clearly indicate a very effective performance of the compound as a corrosion inhibitor. The adsorption of the compound on the mild steel surface obeys Temkin's adsorption isotherm.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590210413566
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  • 88
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    The effect of the temperature change rate on determination of the critical pitting temperature of stainless steels (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 105-110 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results have been presented of investigations on the effect of the temperature change rate on the critical temperature of pitting corrosion. Investigations of 316L stainless steel have been conducted by cyclic thermometry. An increase has been stated of the critical pitting temperature with increase of the temperature change rate. The dependence of the pitting critical temperature is linear in character for all investigated temperature change rates. Values of the critical temperature of pitting corrosion for stationary conditions (E-ES=0) were obtained by using the extrapolation procedure. The critical pitting temperature obtained by extrapolation practically does not depend on the temperature change rate in the investigated range and is equal to 336.9?K (63.9°C).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590210419344
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  • 89
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    Inhibition of the corrosion of carbon steel in hydrochloric acid solution by bisquaternary ammonium salt (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 127-132 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effectiveness of bisquaternary ammonium salt N,N'-Bis(dodecyldimethyl)-3-oxa-1,5- pentanediammonium dichloride used as corrosion inhibitor for carbon steel in 1.0?M HCl was investigated by weight loss and electrochemical techniques. Surfaces were characterised by scanning electron microscopy. The performance of the bisquaternary ammonium salt was also compared with that of urotropine, a commercial corrosion inhibitor for acid media in industry practice. The results showed good inhibiting action of the inhibitor. The inhibition efficiency increases with the inhibitor concentration but is temperature–independent. N,N'-Bis(dodecyldimethyl)-3-oxa-1,5-pentanediammonium dichloride acts mainly as a mixed-type inhibitor. The inhibition of this bisquaternary ammonium compound was assumed to occur via adsorption of the inhibitor molecule on the metal surface without affecting the corrosion mechanisms. The adsorption of the inhibitor on the metal surface in HCl solution was found to obey Frumkin's isotherm.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590210419371
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  • 90
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    Mechanism of the action of zinc-powder in anticorrosive coatings (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 173-180 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The present work was directed to the study of mechanisms of the action of zinc powder as an anticorrosive pigment in coating compositions based on binders that are composed of a two-component epoxy, a single-component polyurethane, and epoxy-ester resins. The results of the study have shown that neutralisation and barrier mechanisms contribute more than the electrochemical mechanism to the effectiveness of the anticorrosion protection. During the investigation, the results obtained in corrosion tests were evaluated by investigating the morphology of coatings by means of electron microscopy procedures.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590210426436
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  • 91
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    Effects of plasma cleaning and conservation treatment on the corrosion layer of corroded steel - XRD evaluation (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 256-263 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The application of hydrogen plasma on corroded steel and excavated iron artefacts has been studied. Transformations of the corrosion layer due to the plasma effect were investigated by means of X-ray diffraction analysis. The reduction of iron oxides to the stable iron oxide, magnetite, was observed for all the samples. In the case of excavated objects, the reduction to magnetite did not occur throughout the whole of the bulk of the oxides, as it does (for example) in the case of steel corroded in the laboratory. Nevertheless, excavated objects, in which a metallic core remained, were stabilised against subsequent corrosion. However, objects that are completely oxidised must be treated carefully, because treatment may result in the formation of a brittle outer layer, and there is a risk of disintegration of such items, if treated using the plasma conditioning and restoration procedure.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590210431755
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  • 92
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    High temperature oxidation behaviour of CeO and LaO modified aluminide coatings on carbon steel (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 283-294 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The aluminide and CeO2 and La2O3 containing aluminide coatings on carbon steel have been prepared by a pack cementation process. The influence of CeO2 and La2O3 additions on the oxidation rates of aluminide coatings has been investigated. The performance of coatings was studied by measuring oxidation kinetics, metallography, SEM and X-ray diffraction analysis techniques. The oxidation-resistance of coated carbon steel is discussed on the basis of a decrease in oxidation rates as well as adherence of oxide scales. The oxidation rates of carbon steel and aluminide coatings were markedly reduced in the presence of CeO2 and La2O3 in the temperature range of 700-900°C. The oxidation rates were significantly affected by the morphology of oxide scales. In the case where the structure of oxides scales was not seriously disrupted due to decarburisation, the oxidation rates were significantly reduced.
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    URL: http://dx.doi.org/10.1108/00035590210439757
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  • 93
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    Study of the effect of AC-interference on the cathodic protection of a gas pipeline (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 335-345 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The aim of this fieldwork was the study of the effect of 50Hz AC, induced by high-voltage power lines, on the cathodic protection system of a natural gas pipeline. The effectiveness of cathodic protection was checked through in situ long-term monitoring and analysis of pipeline electrical parameters. The results gave an insight into the problems of the cathodic protection system operation, caused by AC interference. An AC and DC potential interdependence was observed, that previously has hardly been reported, and was scrutinized in relation to cathodically protected pipelines. The effects of the AC-interference and low frequency DC potential fluctuations, as well as the potential deviations from the protection potential, are examined. These phenomena are associated with corrosion susceptibility and difficulties in obtaining reliable cathodic protection measurements.
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    URL: http://dx.doi.org/10.1108/00035590210440728
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  • 94
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    Modelling of the effect of operational parameters and concentration of some corrosion inhibitors on the corrosion of carbon steel (2002)
    Bradford : Emerald
    Anti-corrosion 49 (2002), S. 426-432 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Several corrosion inhibitors, such as, HEDP, sodium molybdate and zinc ions, were added to an aqueous corrosive media containing different concentrations chloride ions, and the corrosion rates (CRs) of carbon steel were measured at various temperatures. It was shown that, in the presence of more than 1,200?ppm of chloride ions, and temperatures greater than or equal to 42.5°C, the combination of HEDP, molybdate and zinc could not control the corrosion in a cooling water system. Then four different models were designed to represent the CR of carbon steel in presence of various corrosive parameters.
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    URL: http://dx.doi.org/10.1108/00035590210452770
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  • 95
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    Potential changes in an electric field and electrolytic corrosion (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 25-33 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Sources have been described of corrosively hazardous electric fields and methods of determination of the corrosion hazard to metal structures caused by electrolytic corrosion. Results of potential and impedance investigations in the field of stray currents flowing out of a tram traction and in the presence of a defined electric field of low frequency have been presented. Uncertainties have been indicated relating to the generally accepted interpretation principles of measurement results in the presence of electric fields. The possibility has been indicated of incorporating the impedance spectroscopy technique to potential-voltage investigations, allowing estimation of the real corrosion interaction of stray currents on underground structures.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310456261
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  • 96
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    External corrosion protection systems for flammable and combustible liquids underground storage tanks (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 91-107 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper gives an overview on the evolution and standards development of the external corrosion protection systems used for flammable and combustible liquids underground storage tanks (USTs) in North America. The paper first describes the different types of corrosion protected USTs for flammable and combustible liquids in North America. It then reviews the advantages and disadvantages of each of the corrosion protection systems used. Finally, it looks forward to some of the technical trends in the North American UST industry and the standard certification process for underground tank external corrosion protection, with updates on the technology and standards in the international UST industry.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310698065
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  • 97
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    Corrosion characteristics of copper-based IUDs (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 129-135 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A corrosion study of the intra-uterine device, "TCu 380?A", was made using cyclic voltammetry (CV), scanning electron microscopy (SEM) and optical microscopy (OM). Blood plasma, whole blood and artificial uterine fluid were used as corrosive media in order to establish a comparative scheme of the corrosion behaviour of copper in the device. In summary, the results obtained were not only similar to work reported previously, but also provided complementary data for a better understanding of the corrosion problem.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310463993
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    The application of Gabor transformation in the harmonic analysis of corrosion processes (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 193-200 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new method of spectral analysis has been proposed for non-stationary harmonic analysis of corrosion processes. The current of a model circuit has been considered which would simulate a first-order electrode reaction proceeding in conditions of a linearly changing electrode potential with a superimposed sinusoid signal. It has been shown that the Fourier transformation approach does not reflect the amplitude changes of harmonic components as a function of constant potential. In addition, it has been shown mathematically that application of Gabor transformation in spectral analysis is a means of obtaining the correct frequency components. The Gabor transform correctly reflects amplitude changes of harmonic components as a function of potential. Digital analysis of current changes by Gabor transformation unequivocally confirmed the usability of this method for harmonic analysis of corrosion processes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310471769
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  • 99
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    The beneficial influence of halide ions on the inhibition characteristics of nitrogen-containing organic inhibitors to reduce the corrosion rate of carbon steel in HCl (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 280-285 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The beneficial effect of halide ions on the inhibition of corrosion of carbon steel in 20 per cent HCl solution in the presence of some nitrogen-containing compounds, cetyl pyridinium chloride, cetyl pyridinium bromide, and hexamine was investigated using potentiodynamic polarisation measurements. Potentiodynamic polarisation studies revealed that all the tested compounds were of anodic-type inhibitors. All of the compounds were able to reduce the corrosion of carbon steel and their performance was enhanced by the addition of iodide ions. The increase in surface coverage in the presence of the iodide ions indicated that iodide ions enhanced the absorption of inhibitor compounds on the metal surface. Auger electron spectroscopic analysis confirmed the joint absorption of the compounds with KI.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310482514
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  • 100
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    Investigation of the chemical and electrochemical behaviour of mass transfer at an archaeological bronze/soil interface (2003)
    Bradford : Emerald
    Anti-corrosion 50 (2003), S. 326-333 
    Details
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes a study on the corrosion behaviour of archaeological bronze in simulated groundwater by means of a simulated occluded cell. The study revealed migration, enrichment and deposition patterns of ions in the environment and the cations produced by anodic dissolution during localised corrosion of bronze. The cycle voltametry technique was utilised for the first time on the study of electrochemical behaviour of the bronze/simulated occluded solution interface. The potential and current peaks of oxidation-reduction at the cathode and anode in the occluded solutions at various time intervals facilitated a study of the corrosion products formation processes and their formation speeds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1108/00035590310492234
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