ALBERT

Beschreibung: The spatial variability in the mix of species making up Cold-water coral reef communities is not well known. In this study abundances of a selection of megafauna (Lophelia pertusa, Madrepora oculata, Paragorgia arborea, Primnoa resedaeformis, Mycale lingua, Geodia baretti, Acesta excavata and fish) were quantified throughout 9 manned submersible video transects from 3 reef complexes (Røst Reef, Sotbakken Reef and Traena Reef) on the Norwegian margin. Substrate type (coral structure, rubble, exposed hardground or soft sediment) was also recorded. Variations in the densities of these fauna (with respect to both reef complex and substrate type) were investigated, with spatial covariance between species assessed. For the majority of fauna investigated, densities varied by both reef and substrate. Spatial covariance indicated that some species may be utilising similar habitat niches, but that minor environmental differences may favour colonisation by one or other at a particular reef. Fish densities were generally higher in regions with biogenic substrate (coral structure and coral rubble substrates) than in areas of soft or hardground substrate. Further, fish were more abundant at the northerly Sotbakken Reef at time of study than elsewhere. Community structure varied by reef, and therefore management plans aimed at maintaining the biodiversity of reef ecosystems on the Norwegian margin should take this lack of homogeneity into account.

Beschreibung: Solid-solution partitioning of Ra determines the dissolved Ra composition of porewater in marine sands. Therefore, sorption controls also influence the endmember concentration of Ra in submarine groundwater discharge (SGD). Ra is widely used as a tracer of SGD, and constraining sorption controls in permeable sands is necessary to evaluate spatial and temporal variation in Ra groundwater activities. This work presents Ra distribution coefficients measured in seawater (salinity 35) for some common solid sorbents as well as different solution compositions relevant to permeable marine sands and the subterranean estuary. There was a strong correlation of Ra distribution coefficient (Kd = solid-phase Ra/solution Ra) with surface area for size-fractionated sediments (log Kd (L/g) = 0.77 [log S.A. (m2/g)] + 0.73; r2 = 0.76). Ra sorption showed no direct relationship with solid-phase Fe or Mn content of the sands, although removal of visible surficial oxide coatings with dilute acid reduced Kd by a factor of 2 to 3. Synthetic Fe-oxides showed nearly two orders of magnitude difference in Ra sorption. Ferrihydrite had the highest Ra sorption coefficient at 1535 ± 410 L kg− 1, followed by lepidocrocite (174 ± 21 L kg− 1), hematite (75 ± 17 L kg− 1), and goethite (20 ± 8 L kg− 1). A marked increase in Ra adsorption was observed with increasing pH, with the sorption edge of natural sands falling within the pH range of 5–8. The extent of Ra sorption at a given pH varied among different substrates. No effect of dissolved Fe was observed on Ra partitioning. A large increase in Ra Kd was evident with increasing Ba concentration when seawater contained sulfate, opposite the effect that would be expected for sorption competition. No effect of Ba concentration was observed when sulfate was excluded from the ASW, indicating that barite precipitation caused the Kd increase. There was no clear effect of temperature on Ra sorption between 2 and 60 °C. Results of this study show that minor solid-phase components increase the Ra sorption capacity of bulk sands and buffer the dissolved Ra concentration (i.e., the SGD endmember). Solution controls on Ra sorption have the potential to greatly alter the Ra composition of discharging groundwater. Given that high-salinity, high-pH conditions probably prevail in porewater below the sediment–water interface, the actual SGD Ra endmember may be less variable than suggested by compilations that include groundwater from deep and fresh groundwater. Highlights ► Variable Ra partitioning to size-fractionated and diverse sediments was primarily controlled by specific surface area. ► Ra displayed pH-dependent sorption to sands, with a sorption edge between pH 5 and 8. ► No effect on Ra partitioning was observed for temperature or competition by dissolved Fe and Ba.

Beschreibung: There is mounting evidence that driving on the beach has a significant biophysical impact, and it has been suggested in a number of recent studies that driving on the beachface leads to a net loss of sediment from the beach-dune system. Identifying a conclusive link between beach driving and beach erosion is, however, complicated by the natural variability of the environment in both space and time, and it has proven difficult to distinguish the driving signal from this background noise. In this respect, the impacts of beach driving are not clear, making it difficult to develop appropriate management strategies to reduce the impact in either degree or extent. LiDAR data from both Padre Island National Seashore and Assateague Island National Seashore are used in the present study to determine if the differences in beach and dune morphology between restricted and open access sections of the beach are associated with beach driving. Results from Padre Island National Seashore suggest that beach driving does not affect the height and volume of the foredunes, but is responsible for a statistically significant decrease in the elevation of the dune crest and base compared to the control section of beach. The decrease in elevation is ascribed to the compaction and pulverization of seaweed wrack that accumulates along the Texas coast in the spring and summer months, and is responsible for the anchoring of sediment for the growth of new vegetation seaward of the foredune. At Assateague Island National Seashore, driving on the beach is shown to cause a statistically significant change in the beach-dune morphology, with smaller dunes set further back from the shoreline within the open access sections of the beach. Despite the changes in dune morphology at both sites, there is no statistically significant difference in beach-dune volume on either side of the beach access road, which suggests that driving on the beach does not lead to a net loss of sediment from the beach-dune system. Driving on the beach does, however, make the foredune at both sites susceptible to scarping and overwash during tropical storms and hurricanes.

Beschreibung: Digital macro photography and settling tests were carried out to investigate the morphological and settling characteristics of ANAMMOX granules in a high-rate reactor. The ANAMMOX granules could be divided into settling and floating granules. The settling granules with an average diameter of 2.96 ± 0.99 mm were smaller than the floating granules with an average diameter of 4.58 ± 1.22 mm. A settling model was established and validated to correlate the settling velocity with the density (ρG), mass shape factor (ψmass), shape-correction factor (characterized by sphericity (Φ′) or roundness (ξ)) and projected area equivalent sphere diameter (dP) of ANAMMOX granules. The sphericity was more suitable than the roundness for describing the settling behavior. The sensitivity of four parameters was in the order of ρG, ψmass, dP and Φ′. Based on the settling model, ANAMMOX granules with diameter of 1.75–4.00 mm were supposed to be optimal for the ANAMMOX process.

Beschreibung: A chemical study of the lichen Ramalina siliquosa complex found in Brittany was conducted. Eight chemotypes were considered and their chemical composition was elucidated for the first time by LC–MS analysis. Ten main compounds were identified: conhypoprotocetraric acid (1), salazinic acid (2), peristictic acid (3), cryptostictic acid (4), protocetraric acid (5), stictic acid (6), norstictic acid (7), hypoprotocetraric acid (8), 4-O-demethylbarbatic acid (9), (+)-usnic acid (10) and 22 minor compounds were reported. The MS/MS fragmentation patterns of each compound of R. siliquosa complex were determined and proposed.

Beschreibung: The coral species Paragorgia arborea and Primnoa resedaeformis are abundant and widely distributed gorgonians in North Atlantic waters. Both species add significant habitat complexity to the benthic environment, and support a host of invertebrate species. Mapping their distribution is an essential step in conservation and resource management, but challenging as a result of their remoteness. In this study, three predictive models — Ecological Niche Factor Analysis, Genetic Algorithm for Rule-set Production and Maximum Entropy modeling (MaxEnt) were applied to predict the distribution of species' suitable habitat across a region of Røst Reef (Norwegian margin) based on multiscale terrain variables. All three models were successful in predicting the habitat suitability for both gorgonian species across the study area, and the MaxEnt predictions were shown to outperform other predictions. All three models predicted the most suitable habitats for both species to mainly occur along the ridges and on the upper section of the large slide, suggesting both species preferentially colonize topographic highs. Jackknife tests for MaxEnt predictions highlighted the seabed aspect in relation to P. arborea distribution, and the seabed relative position (curvature) in relation to the distribution of both species. Given the vulnerability of deep-water corals to anthropogenic impacts, further comparative study over a wider study area would be particularly beneficial for the management of the species.

Beschreibung: Oil derived from photosynthetic microalgae is a potential major source of renewable energy, but while industrial-scale efforts to grow algal biomass are underway, it remains an expensive process. The cost of biomass production may be offset by using the algae to simultaneously remediate chemical contaminants from wastewater or natural surface waters. This work examines trace metal accumulation and cycling in algae grown for biofuel use, and evaluates the potential of this approach for remediation purposes. In the system studied, a natural, mixed-species algal community was allowed to develop on a shallow floway fed with water from the York River estuary (VA, USA). Accumulation of metals ranged widely in the algal biomass (Fe 〉 Mn 〉 〉Pb 〉 Cu 〉 V 〉 Cd) and represented removal from the dissolved phase of between 1 and 87% (for Cd and Pb, respectively). These metals were selected for analysis because of their differing geochemical behavior, as well as their importance as micronutrients (Fe, Mn, Cu, V) and toxicants (Pb, Cu, Cd). Most of the algal metal inventory was partitioned in the intracellular fraction (∼30% for Mn, 50–90% for other metals; operationally defined using a chemical wash technique), indicating accumulation due to biochemical demand, not adsorption to cell surfaces. Although algal community composition was similar on the upstream and downstream ends of the floway, the metal inventory was two-fold higher on the downstream end. Differences in metal accumulation may have been related to algal physiology or to pronounced cycles of water pH and dissolved oxygen driven by algal photosynthesis and respiration. Differences in metal removal efficiency and biomass inventory indicate that algal floway systems may be manipulated to optimize remediation of metal-contaminated water.

Beschreibung: Submarine groundwater discharge (SGD) to the ocean supplies Sr with less radiogenic 87Sr/86Sr than seawater, and thus constitutes an important term in the Sr isotope budget of the modern ocean. However, few data exist for Sr in coastal groundwater or in the geochemically dynamic subterranean estuary (STE). We examined Sr concentrations and isotope ratios from nine globally-distributed coastal sites and characterized the behavior of Sr in the STE. Dissolved Sr generally mixed conservatively in the STE, although large differences were observed in the meteoric groundwater end-member Sr concentrations among sites (0.1–24 μM Sr). Strontium isotope exchange was observed in the STE at five of the sites studied, and invariably favored the meteoric groundwater end-member signature. Most of the observed isotope exchange occurred in the salinity range 5–15, and reached up to 40% exchange at salinity 10. Differences in fresh groundwater Sr concentrations and isotope ratios (87Sr/86Sr = 0.707–0.710) reflected aquifer lithology. The SGD end-member 87Sr/86Sr must be lower than modern seawater (i.e., less than 0.70916) in part because groundwater Sr concentrations are orders of magnitude higher in less-radiogenic carbonate and volcanic island aquifers. A simple lithological model and groundwater Sr data compiled from the literature were used to estimate a global average groundwater end-member of 2.9 μM Sr with 87Sr/86Sr = 0.7089. This represents a meteoric-SGD-driven Sr input to the ocean of 0.7–2.8 × 1010 mol Sr y−1. Meteoric SGD therefore accounts for 2–8% of the oceanic Sr isotope budget, comparable to other known source terms, but is insufficient to balance the remainder of the budget. Using reported estimates for brackish SGD, the estimated volume discharge at salinity 10 (7–11 × 1015 L y−1) was used to evaluate the impact of isotope exchange in the STE on the brackish SGD Sr flux. A moderate estimate of 25% isotope exchange in the STE gives an SGD Sr end-member 87Sr/86Sr of 0.7091. The brackish SGD Sr flux thus accounts for 11–23% of the marine Sr isotope budget, but does not appear sufficient to balance the ∼40% remaining after other known sources are included. Substantial uncertainties remain for estimating the SGD source of Sr to the global ocean, especially in the determination of the volume flux of meteoric SGD, and in the paucity of measurements of groundwater Sr isotope composition in major SGD regions such as Papua New Guinea, the South America west coast, and West Africa. Consequently, our global estimate should be viewed with some caution. Nevertheless, we show that the combined sources of meteoric SGD and brackish SGD coupled with isotope exchange in the STE may constitute a substantial component (∼13–30%) of the modern oceanic 87Sr/86Sr budget, likely exceeding less radiogenic Sr inputs by sedimentary diagenesis and hydrothermal circulation through the mid-ocean ridge system. Temporal variation in SGD Sr fluxes and isotope composition may have contributed to fluctuations in the oceanic 87Sr/86Sr ratio over geologic time.

Beschreibung: The Gaoligongshan metamorphic belt, located east of the Eastern Himalayan Syntaxis (EHS) in the Yunnan province, southwestern China, is a compelling region in which to determine temporal constrains on crustal dynamic processes related to the Himalayan orogeny. We applied multi-system geo- and thermochronology (900 °C to 〈50 °C) to orthogneiss and mylonites from a major shear zone in the southern Gaoligongshan in order to elucidate the magmatic, cooling and exhumation history of this belt. Zircon U/Pb data reveal three magmatic events at ∼486 Ma, ∼136 Ma and ∼76 Ma. Similar ages are found in orthoderivative rocks of the neighboring Tengchong and Baoshan blocks, and the Gangdese batholith, suggesting that the southern Gaoligongshan is composed of an assemblage of Lhasa and Qiangtang terrane derived rocks. Muscovite Rb/Sr ages of 35–21 Ma are coeval with the onset of lateral crustal displacement along major shear zones in Eastern Tibet and Indochina, and with the post-collision volcanic activity in western Yunnan. Biotite Rb/Sr and mica 40Ar/39Ar ages provide evidence that mylonitization along the Gaoligongshan shear zone and crustal rotation of the Tengchong and Baoshan blocks proceeded during the Miocene, between 19 and 12 Ma, when the rocks rapidly cooled through the 350–280 °C temperature range. Almost identical 40Ar/39Ar ages reported for the Karakorum–Jiali–Parlung Fault system in Western Tibet suggest that the Gaoligongshan shear zone is the southeastern continuation of this fault, recording the eastward extrusion of Tibet and crustal movement around the EHS. The final stage of exhumation of the Gaoligongshan occurred between 8 and 5 Ma at an average exhumation rate of ∼3 km/Ma as documented by apatite fission-track and apatite (U–Th–Sm)/He data. This rapid exhumation was triggered by crustal root delamination and opening of the Andaman sea. Our results clearly show that the complex tectonothermal evolution of the Gaoligongshan was influenced by Tibetan extrusion and escape tectonics associated with lower crustal flow around the EHS and the southeastward movement of Indochina and back-arc extension in response to Andaman seafloor spreading.

Beschreibung: Benthic habitat mapping is an important first step towards ecosystem-based management. In a top-down approach, benthic mapping of a semi-enclosed bay in south-eastern Brazil was performed using a combined approach of acoustic RoxAnn survey and benthic samples. An inventory of the benthic macrofauna as well as unsupervised classifications of the acoustic data provided information about sediment patterns and potential areas of ecological importance, and a new zoning scheme is suggested based on the macrofauna analysis. The RoxAnn survey proved suitable to determine sediment characteristics, however, species–environment relationships cannot be revealed by acoustic techniques only. Based on the data presented here, acoustic surveys could become an important tool in future monitoring programmes following the bottom-up approach of seabed classification protocols for an ecosystem-based management to improve existing coastal ecosystem management strategies in Brazil. A combined approach of benthic mapping of Caraguatatuba Bay, Brazil, with recommendations for management practices (PDF Download Available). Available from: https://www.researchgate.net/publication/257423766_A_combined_approach_of_benthic_mapping_of_Caraguatatuba_Bay_Brazil_with_recommendations_for_management_practices [accessed Jun 6, 2017].