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  • Elsevier  (5,804,724)
  • American Chemical Society  (2,084,048)
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  • 1
    Publication Date: 2024-05-08
    Description: In the last few years, several works have analyzed rainfall regime changes with the increase of temperature as a result of global warming. These changes, documented mainly in northern Europe, still need to be clarified in the Mediterranean area. Many studies have identified sometimes contradictory trends according to the type of data used, the methodology, and the daily or subdaily types of events. Therefore, an in-depth investigation of the Mediterranean area is required for the definition of more certain future scenarios. In this study, we examined a very large database including 〉1000 raingauges and thermometers in northern and central Italy to analyze the relationship between temperature and rainfall using the relation Clausius-Clapeyron. Furthermore, we analyzed the relationship between temperature and extreme precipitation events (EPEs, defined as the events higher than the 95th percentile) calculating the temperature anomalies occurred during these events. This large database covers a low rainfall accumulation period (RAP) that allowed us to study the relationship between temperature and rainfall and to distinguish rapid from long events related to rainfall intensity. The results show different relationships between rainfall and temperature in relation to seasons, RAPs, rainfall intensity, and geographical factors. The high spatial density of the database made it possible to identify spatial clusters with homogenous characteristics mainly influenced by geographical factors. With an increase in temperature, the wet season is characterized by a general increase in rainfall with a higher surge for intense and fast events. Instead, the dry season shows a general rainfall decrease for less intense and longer events, but an increase in rapid and more intensive rainfall events. This outcome has further implications involving a future decrease in water availability and an increase of the EPEs, causing an extremization of the climate during the dry season for northern and central Italy.
    Description: Published
    Description: 163368
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Keywords: Current global warming; Extreme precipitation events; Italy; Mediterranean; Temperature increase
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2024-05-07
    Description: Active volcanoes often discharge hot (T ≫ 100 °C) magmatic gases whose original composition has been modified through partial interaction with an externally fed hydrothermal system. The study of methane (CH4) in these volcanic discharges may provide useful information on the interplay between deep magmatic gases and shallow circulation of hydrothermal fluids. However, the origin of CH4 in high-temperature volcanic gases and the factors exerting control on its abundance and stable isotope composition are still largely unknown. Here, we present the abundances and stable isotopic composition of CH4 in hot (99–387 °C) volcanic gases from the La Fossa volcanic crater of Vulcano Island (Southern Italy). Our investigation revealed low (〈1.5 μmol/mol) CH4 concentrations and an extraordinarily large variability in CH4 stable isotopic composition, with δ13C and δ2H values being positively correlated and varying from −35 to −9.2 ‰ and −670 to −102 ‰, respectively. Notably, CH4 isotopes measured at Vulcano almost encompasses the global-scale variability observed in natural fluids, with δ2H values ≤ −500 ‰ being the first ever reported in nature. Gases showing extremely negative δ13C-CH4 and δ2H-CH4 values systematically display higher CH4 abundances. We propose two possible scenarios in order to explain the observed huge variation in δ13C and δ2H: (1) mixing of 13C- and 2H-depleted CH4 with 13C- and 2H-enriched CH4 of thermogenic origin formed under hydrothermal conditions; (2) post-genetic removal and isotopic alteration of 13C- and 2H-depleted CH4 occurring during the ascent of volcanic gases. Comparing our dataset with available isotopic data from naturally occurring and artificially produced CH4, a thermogenic origin for the isotopically light CH4 seems unlikely. We postulate that the 13C- and 2H-depleted CH4 may have formed via kinetically-controlled abiotic synthesis through CO (or CO2) hydrogenation reactions in the hot ascending gas phase, possibly at temperatures intermediate between those typical of magmatic and hydrothermal conditions. Further investigations of methane in high-temperature volcanic gases are necessary to test this hypothesis.
    Description: Published
    Description: 148-165
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Elsevier
    In:  EPIC3Elsevier, ISBN: 9780128220146
    Publication Date: 2024-05-07
    Description: Marine Neurotoxins, Volume Five provides comprehensive information on marine toxins present in the human food chain and the affecting targets relevant for the functioning of the brain and our nervous system, covering all the information ...
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
    Format: application/pdf
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  • 4
    Publication Date: 2024-05-07
    Description: Subduction zone volcanoes may show irregular bursts of high-frequency or high-magnitude activity. The andesitic Mt. Tongariro (New Zealand) experienced an unusual 〈200 year-long magmatic flare-up at ~11 ka that produced seven eruption episodes of a higher magnitude (M = 4–5) than seen before or since. This brief sequence produced a total of 4.5 km3 of dominantly tephra fall (Mangamate Formation) sourced by multiple vents aligned along the NNE trending axis of the tectonic Tongariro Graben. The magmatic system responsible for sporadic M = 1–2 eruptions underwent extensive change to feed the flare-up. Petrography and phase equilibria suggest that a coalesced network of magma mush zones formed along the N-S graben axis extending down to ~11 km during the episode. Recharge, mingling and mixing of formerly isolated heterogenous magmas within the plumbing system well before these eruptions is indicated by crystal zonation patterns. Mafic end members are evidenced by Fo86–89 olivine, clinopyroxene with Mg# 〉 85 and calcic plagioclase (An73–89), while evolved magma end members contained Mg# 〈 75 clinopyroxene and An56–63 plagioclase. Rim-zoning of these phases reflect timespans for equilibration of evolved and mafic crystals to a hybrid melt. The whole-rock compositions of lapilli reflect the hybrid basaltic andesite to andesite, but show diverse glass compositions (56–72 wt% SiO2) implying that magma homogenisation was incomplete before eruption. Crystal-melt equilibria of olivine and clinopyroxene rims reveal polybaric crystallisation, showing mean depths of ~8.5 km (230 ± 70 MPa) at temperatures between 1000 and 1150 °C. At the northern margins of the system, volatile-rich amphibole-bearing magmas were erupted for the first and last eruption of the series, creating stable Plinian eruption styles. This flare-up was previously interpreted as tectonically controlled, however, there were low tectonic extension rates at that time. Hence, we propose instead that magma pressure build-up and recharge beneath Mt. Tongariro drove the inflation and homogenisation of the magma system, fueling the ~200 year-long flare-up. Subsequently, the magma supply system returned to pre-Mangamate activity levels, so that vigorous recharge would be required for a return to 〉M 4 eruptions.
    Type: Article , PeerReviewed
    Format: text
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  • 5
    Publication Date: 2024-05-06
    Description: Here, we characterize the temporal evolution of volatiles during the Tajogaite eruption by analyzing the elemental (He-Ar-CO2-N2) and isotopic (He-Ar-Ne) composition of fluid inclusions (FI) in phenocrysts (olivine+ pyroxene) identified in erupted lavas. Our 2021 lava samples identify substantial temporal variations in volatile composition. We show that, during the 2021 Tajogaite eruption, the He-CO2-N2 concentrations in FI increased since October 15th; this increase was accompanied by increasing 40Ar/36Ar ratios (from ~300 to 〉500), and paralleled a major shift in bulk lava chemistry, with increasing Mg contents (Mg#, from 47 to 52 to 55–59), CaO/Al2O3 (from 0.65 to 0.74 to 0.75–0.90), Ni and Cr, and decreasing TiO2, P2O5 and incompatible elements. The olivine core composition also became more forsteritic (from Mg# = 80–81 to Mg# = 84–86). Mineral thermobarometry and FI barometry results indicate that the eruption was sustained by magmas previously stored in at least two magma accumulation zones, at respectively ~6–12 km and 15–30 km, corroborating previous seismic and FI evidence. We therefore propose that the compositional changes seen throughout the eruption can be explained by an increased contribution - since early/mid-October - of more primitive, less degassed magma from the deeper (mantle) reservoir. Conversely, Rc/Ra values (3He/4He ratios corrected for atmospheric contamination) remained constant throughout the whole eruption at MORB-like values (7.38 ± 0.22 Ra, 1σ), suggesting an isotopically homogeneous magma feeding source. The Tajogaite He isotope signature is within the range of values observed for the 1677 San Antonio lavas (7.37 ± 0.17Ra, 1σ), but is more radiogenic than the 3He/4He values (〉9 Rc/Ra) observed in the Caldera de Taburiente to the north. The 3He/4He ratios (6.75 ± 0.20 Ra, 1σ) measured in mantle xenoliths from the San Antonio volcano indicate a relatively radiogenic nature of the mantle beneath the Cumbre Vieja ridge. Based on these results and mixing modeling calculations, we propose that the homogeneous He isotopic signatures observed in volatiles from the Tajogaite/San Antonio lavas reflect three component mixing between a MORB-like source, a radiogenic component and small additions (6–15%) of a high 3He/4He reservoir-derived (〉9Ra) fluid components. The simultaneous occurrence of high 3He/4He (〉9Ra)- and MORB-like He signatures in northern and southern La Palma is interpreted to reflect small-scale heterogeneities in the local mantle, arising from spatially variable proportions of MORB, radiogenic, and high 3He/4He components.
    Description: Published
    Description: 107928
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: La Palma ; 2021 Tajogaite eruption ; Fluid inclusions ; Noble gas ; Magma feeding system ; Mantle source heterogeneity ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2024-05-06
    Description: Mantle volatiles are transported to Earth’s crust and surface by basaltic volcanism. During subaerial eruptions, vast amounts of carbon, sulfur and halogens can be released to the atmosphere during a short time-interval, with impacts ranging in scale from the local environment to the global climate. By contrast, passive volatile release at the surface originating from magmatic intrusions is characterized by much lower flux, yet may outsize eruptive volatile quantities over long timescales. Volcanic hydrothermal systems (VHSs) act as conduits for such volatile release from degassing intrusions and can be used to gauge the contribution of intrusive magmatism to global volatile cycles. Here, we present new compositional and isotopic (δD and δ18O-H2O, 3He/4He, δ13C-CO2, Δ33S- δ34S-H2S and SO4) data for thermal waters and fumarole gases from the Askja and Kverkfj¨oll volcanoes in central Iceland. We use the data together with magma degassing modelling and mass balance calculations to constrain the sources of volatiles in VHSs and to assess the role of intrusive magmatism to the volcanic volatile emission budgets in Iceland. The CO2/ΣS (10􀀀 30), 3He/4He (8.3–10.5 RA; 3He/4He relative to air), δ13C-CO2 (􀀀 4.1 to 􀀀 0.2 ‰) and Δ33S- δ34S-H2S (􀀀 0.031 to 0.003 ‰ and 􀀀 1.5 to +3.6‰) values in high-gas flux fumaroles (CO2 〉 10 mmol/mol) are consistent with an intrusive magmatic origin for CO2 and S at Askja and Kverkfj¨oll. We demonstrate that deep (0.5–5 kbar, equivalent to ~2–18 km crustal depth) decompression degassing of basaltic intrusions in Iceland results in CO2 and S fluxes of 330–5060 and 6–210 kt/yr, respectively, which is sufficient to account for the estimated CO2 flux of Icelandic VHSs (3365–6730 kt/yr), but not the VHS S flux (220–440 kt/yr). Secondary, crystallization-driven degassing from maturing intrusions and leaching of crustal rocks are suggested as additional sources of S. Only a minor proportion of the mantle flux of Cl is channeled via VHSs whereas the H2O flux remains poorly constrained, because magmatic signals in Icelandic VHSs are masked by a dominant shallow groundwater component of meteoric water origin. These results suggest that the bulk of the mantle CO2 and S flux to the atmosphere in Iceland is supplied by intrusive, not eruptive magmatism, and is largely vented via hydrothermal fields.
    Description: Published
    Description: 107776
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2024-05-03
    Description: Although many studies have demonstrated that arc magmas are more oxidized than mid-ocean ridge (MORB) and oceanic island basalts (OIB), the oxidation state of their mantle source is still debated. This ongoing debate is mainly due to contradictory fO2 values obtained from different proxies (e.g., Fe3+/ΣFe of olivine-hosted melt inclusions and glasses; Zn/ΣFe, V/Sc, V/Ga of lavas). On the one hand, some studies using V/Sc, V/Ga and Zn/ ΣFe of lavas tend to show that the oxidation state of the mantle beneath arcs cannot be distinguished from that of the MORB mantle. On the other, Fe3+/ΣFe of glasses and olivine-hosted melt inclusions suggest that the sub-arc mantle is more oxidized than the mantle beneath ridges. Here, we estimate the oxygen fugacity of high-Mg olivine-hosted melt inclusions from various mid-ocean ridges and arcs, from one hot spot (Reunion Island) and Mount Etna using two fO2 proxies: the Fe3+/ΣFe of melts and the partition coefficient of V between olivine and melt (Dv Ol/Melt). After assessing the role of secondary processes such as volatile degassing and fractional crystallization on the fO2 of melts and reconstructing primary melt compositions, we show that (1) fO2 values derived from Fe3+/ΣFe and Dv Ol/Melt are comparable and (2) arc and Mount Etna primary melts are more oxidized than mid-ocean ridge and Reunion Island primary melts. We then demonstrate, from Zr/Nb, that the observed variability in primary melt fO2 is not due to chemical variability of the mantle source. Finally, the correlations between incompatible trace element ratios such as Th/La, Ba/La, Ba/Th and La/Yb and the fO2 of primary melts reveal a link between the oxidized nature of arc and Mount Etna primary magmas to slab fluid and/or sediment melt influence. Our arc dataset displays a variety of subduction influences, from fluid-dominated (Aoba and Mount Meager) to sediment melt-dominated (La Sommata) influences. The origin of the oxidation of Mount Etna magmas is more complicated to identify and the nature of the oxidized metasomatic fluids that likely percolated through the mantle source before magma generation is yet to be determined. 1.
    Description: Published
    Description: 121701
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2024-05-03
    Description: Radon is a radioactive gas and a major source of ionizing radiation exposure for humans. Consequently, it can pose serious health threats when it accumulates in confined environments. In Europe, recent legislation has been adopted to address radon exposure in dwellings; this law establishes national reference levels and guidelines for defining Radon Priority Areas (RPAs). This study focuses on mapping the Geogenic Radon Potential (GRP) as a foundation for identifying RPAs and, consequently, assessing radon risk in indoor environments. Here, GRP is proposed as a hazard indicator, indicating the potential for radon to enter buildings from geological sources. Various approaches, including multivariate geospatial analysis and the application of artificial intelligence algorithms, have been utilised to generate continuous spatial maps of GRP based on point measurements. In this study, we employed a robust multivariate machine learning algorithm (Random Forest) to create the GRP map of the central sector of the Pusteria Valley, incorporating other variables from census tracts such as land use as a vulnerability factor, and population as an exposure factor to create the risk map. The Pusteria Valley in northern Italy was chosen as the pilot site due to its well-known geological, structural, and geochemical features. The results indicate that high Rn risk areas are associated with high GRP values, as well as residential areas and high population density. Starting with the GRP map (e.g., Rn hazard), a new geological-based definition of the RPAs is proposed as fundamental tool for mapping Collective Radon Risk Areas in line with the main objective of European regulations, which is to differentiate them from Individual Risk Areas.
    Description: Published
    Description: 169569
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Keywords: Collective Radon Risk Areas; Geogenic Radon Potential; Machine learning; Pusteria Valley; Radon risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2024-05-03
    Description: Uncertainty concerning the processes responsible for slip-rate fluctuations associated with temporal clustering of surface faulting earthquakes is a fundamental, unresolved issue in tectonics, because strain-rates accommodated by fault/shear-zone structures are the key to understanding the viscosity structure of the crust and seismic hazard. We constrain the timing and amplitude of slip-rate fluctuations that occurred on three active normal faults in central Italy over a time period of 20–30 kyrs, using in situ 36Cl cosmogenic dating of fault planes. We identify five periods of rapid slip on individual faults lasting a few millennia, separated time periods of up to 10 millennia with low or zero slip-rate. The rapid slip pulses migrated across the strike between the faults in two waves from SW to NE. We replicate this migration with a model where rapid slip induces changes in differential stress that drive changes in strain-rate on viscous shear zones that drive slip-rate variability on overlying brittle faults. Earthquakes increase the differential stress and strain-rate on underlying shear zones, which in turn accumulate strain, re-loading stress onto the overlying brittle fault. This positive feedback produces high strain-rate episodes containing several large magnitude surface faulting earthquakes (earthquake clusters), but also reduce the differential stress on the viscous portions of neighbouring fault/shear-zones slowing the occurrence of large-magnitude surface faulting earthquakes (earthquake anticlusters). Shear-zones on faults experiencing anticlusters continue to accumulate viscous strain at a lowered rate, and eventually this loads the overlying brittle fault to failure, initiating a period of rapid slip through the positive feedback process described above, and inducing lowered strain-rates onto neighbouring fault/shear-zones. We show that these patterns of differential stress change can replicate the measured earthquake clustering implied by the 36Cl data. The stress changes are related to the fault geometry in terms of distance and azimuth from the slipping structure, implying that (a) strain-rate and viscosity fluctuations for studies of continental rheology, and (b) slip-rates for seismic hazard purposes are to an extent predictable given knowledge of the fault system geometry.
    Description: Published
    Description: 105096
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Active Faults ; Central Apennines ; Fault interaction
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2024-05-03
    Description: Identifying potential dust sources of Loess-Paleosol-Sequences (LPS) is important to understand past climatic and environmental conditions. For loess deposits of Central Italy different hypothesis on particle sources have been proposed, but none of them has been tested using a comprehensive geochemical approach yet. Here we present geochemical, mineralogical and grain-size data from selected deposits of a LPS situated at Ponte Crispiero (Marche, Central Italy) to obtain first insights on the provenance of particles deposited here. Loess deposits within the Ponte Crispiero succession are rather coarse (mostly coarse silt and fine sand) indicating a dominance of proximal dust sources. Applied geochemical indices suggest the alluvial plains of the Po River (Northern Italy) and its discharging area as major particle sources. According to these findings, the so-called “Great Po Plain” hypothesis, that claims the presence of a vast alluvial landscape related to the sea-level drop of the Adriatic Sea during the Pleniglacial (i.e. Marine Isotope Stage MIS 4–2), may be considered as a realistic scenario. Such a considerable alluvial plain would have the potential as major source for silt and sand particles not only for the Ponte Crispiero LPS, but also for the loess on the Adriatic side of Central Italy. The main geochemical characteristics of Ponte Crispiero loess are the low concentrations of Zr and Hf and the high contents of carbonate and transition elements compared to the Upper Continental Crust and other European loess sections. Overall, this study contributes towards a better understanding of the provenance and origin of Italian loess. However, for further testing the “Great Po Plain” hypothesis, more (geochemical) investigations need to be conducted, especially in the surrounding areas of the Po plain.
    Description: Published
    Description: 107064
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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