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  • Elsevier  (517,599)
  • 2005-2009  (517,599)
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  • 1
    Publication Date: 2024-05-09
    Description: A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.
    Description: Published
    Description: 246-254
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: low-pH waters; shallow submarine hydrothermal springs; Panarea Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2023-12-12
    Description: Carbon dioxide capture and storage (CCS) involves the capture of CO2 at a large industrial facility, such as a power plant, and its transport to a geological (or other) storage site where CO2 is sequestered. Previous work has identified pipeline transport of liquid CO2 as the most economical method of transport for large volumes of CO2. However, there is little published work on the economics of CO2 pipeline transport. The objective of this paper is to estimate total cost and the cost per tonne of transporting varying amounts of CO2 over a range of distances for different regions of the continental United States. An engineering-economic model of pipeline CO2 transport is developed for this purpose. The model incorporates a probabilistic analysis capability that can be used to quantify the sensitivity of transport cost to variability and uncertainty in the model input parameters. The results of a case study show a pipeline cost of US$ 1.16 per tonne of CO2 transported for a 100 km pipeline constructed in the Midwest handling 5 million tonnes of CO2 per year (the approximate output of an 800 MW coal-fired power plant with carbon capture). For the same set of assumptions, the cost of transport is US$ 0.39 per tonne lower in the Central US and US$ 0.20 per tonne higher in the Northeast US. Costs are sensitive to the design capacity of the pipeline and the pipeline length. For example, decreasing the design capacity of the Midwest US pipeline to 2 million tonnes per year increases the cost to US$ 2.23 per tonne of CO2 for a 100 km pipeline, and US$ 4.06 per tonne CO2 for a 200 km pipeline. An illustrative probabilistic analysis assigns uncertainty distributions to the pipeline capacity factor, pipeline inlet pressure, capital recovery factor, annual O&M cost, and escalation factors for capital cost components. The result indicates a 90% probability that the cost per tonne of CO2 is between US$ 1.03 and US$ 2.63 per tonne of CO2 transported in the Midwest US. In this case, the transport cost is shown to be most sensitive to the pipeline capacity factor and the capital recovery factor. The analytical model elaborated in this paper can be used to estimate pipeline costs for a broad range of potential CCS projects. It can also be used in conjunction with models producing more detailed estimates for specific projects, which requires substantially more information on site-specific factors affecting pipeline routing.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2023-09-21
    Description: Three pockmarks named "Hydrate Hole", "Black Hole", and "Worm Hole" were studied in the northern Congo Fan area at water depths around 3100 m. The cross-disciplinary investigations include seafloor observations by TV-sled, sampling by TV-guided grab and multicorer as well as gravity coring, in addition to hydroacoustic mapping by a swath system, a parametric sediment echosounder and a deep-towed sidescan sonar. The pockmarks are morphologically complex features consisting of one or more up to 1000 m wide and 10-15 m deep depressions revealed by swath-mapping. High reflection amplitudes in the sediment echosounder records indicate the presence of a 25-30 m thick shallow sediment section with gas hydrates, which have been recovered by gravity corer. Hydrates, chemosynthetic communities, and authigenic carbonates clearly indicate fluid flow from depths, which we propose to be mainly in the form of ascending gas bubbles rather than advection of methane-rich porewater. Evidence for seepage at the seafloor is confined to small areas within the seafloor depressions and was revealed by characteristic backscatter facies. Small meter-scale sized depressions signified as "pits" exist in or close to the pockmarks but seafloor observations did not reveal evidence for the presence of typical seep organisms or authigenic carbonates. Areas of intermediate back-scatter were inhabited by vesicomyid clams in soft sediments. High backscatter was associated with vestimentiferan tubeworms (Siboglinidae) and authigenic carbonates. We discuss the three different environments "pits", "vesicomyid clams", "vestimentifera/carbonate" in the light of differences in the geochemical setting. Pits are probably formed by escaping gas bubbles but seepage is too transient to sustain chemosynthetic life. Vesicomyid clams are present in sediments with gas hydrate deposits. However, the hydrates occur several meters below the surface indicating a lower flux compared to the vestimentifera/carbonate environment. In the latter environment, accumulated carbonates and clam shells indicate that fine grained particles have been eroded away. Gas hydrates were found in this environment at depths below about 50 cm suggesting the highest supply with methane compared to the other environments. (C) 2007 Elsevier B.V. All rights reserved.
    Type: Article , PeerReviewed
    Format: text
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  • 4
    Publication Date: 2023-06-08
    Description: Supercritical fluid extraction (SFE) offers an alternative method to conventional extraction of fatty acids. SFE was developed for analytical application in the mid-1980s in response to the desire to reduce the use of organic solvents in the laboratory environment, and it is now becoming a standard method for the extraction, fractionation, refinement and deodorization of lipids or essential oils containing sample matrices at the industrial scale. This paper reviews applications of supercritical fluid technology in fatty acid/lipid extraction using carbon dioxide. Carbon dioxide is an ideal supercritical fluid because of its environmentally benign, non-toxic, non-flammable, non-polluting, recoverable characteristics and its ability to solubilise lipophilic substances. A summary of commercial applications and examples of recent developments of SFE in the food processing industry are also reviewed.
    Type: Article , PeerReviewed
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  • 5
    Publication Date: 2023-06-05
    Description: We are presenting an attempt to evaluate the spatial variability of geotechnical parameters in the upper Pleistocene–Holocene alluvial deposits of Roma (Italy) by means of multivariate geostatistics. The upper Pleistocene–Holocene alluvial deposits of Roma are sensitive to high levels of geohazard. They occupy a sizable and significant part of the city, being the foundation for many monuments, historical neighborhoods, and archaeological areas, and the main host of the present and future subway lines. We have stored information from more than 2000 geotechnical boreholes crossing the alluvial deposits into a relational database. For the present study, only the boreholes with lithologic/textural interpretation and geotechnical information were selected. The set includes 283 boreholes and 719 samples, which have a set of geotechnical information comprising physical properties and mechanical parameters. Techniques of multivariate statistics and geostatistics were combined and compared to evaluate the estimation methods of the mechanical parameters, with special reference to the drained friction angle from direct shear test (φ′). Principal Component Analysis was applied to the dataset to highlight the relationships between the geotechnical parameters. Through cross-validation analysis, multiple linear regression, kriging, and cokriging were tested as estimators of φ′. Cross-validation demonstrates that the cokriging with granulometries as auxiliary variables is the most suitable method to estimate φ′. In addition to proving that cokriging is a good estimator of φ′, cross-validation demonstrates that input data are coherent and this allows us to use them for estimation of geotechnical parameters, although they come from different laboratories and different vintages. Nevertheless, to get the same good results of cross-validation in estimation, it is necessary for granulometries to be available at grid points. Since this information being not available at all grid points, it is expected that, in the future, textural information can be derived in an indirect way, i.e., from lithologic/textural spatial reconstructions.
    Description: Published
    Description: 251-268
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: open
    Keywords: Alluvial deposits ; Geotechnical properties ; Principal Component Analysis ; Multivariate geostatistics ; Roma ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2023-05-16
    Description: In this work, the popular CAS assay for siderophore detection, based on the utilization of chrome azurol S, was redesigned and optimized to produce a new, fast, non-toxic, and easy method to determine a wide variety of microorganisms capable of siderophore production on a solid medium. Furthermore, this specific bioassay allows for the identification of more than one single siderophore-producing microorganism at the same time, using an overlay technique in which a modified CAS medium is cast upon culture agar plates (thus its name “O-CAS”, for overlaid CAS). Detection was optimized through adjustments to the medium's composition and a quantifying strategy. Specificity of the bioassay was tested on microorganisms known for siderophore production. As a result, a total of 48 microorganisms were isolated from three different types of samples (fresh water, salt water, and alkaline soil), of which 36 were determined as siderophore producers. The compounds identified through this method belonged to both hydroxamate and catechol-types, previously reported to cause color change of the CAS medium from blue to orange and purple, respectively. Some isolated microorganisms, however, caused a color change that differed from previous descriptions.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2023-04-25
    Description: Arabidopsis genes encoding enzymes for each of the eight steps in l-arginine (Arg) synthesis were identified, based upon sequence homologies with orthologs from other organisms. Except for N-acetylglutamate synthase (NAGS; EC 2.3.1.1), which is encoded by two genes, all remaining enzymes are encoded by single genes. Targeting predictions for these enzymes, based upon their deduced sequences, and subcellular fractionation studies, suggest that most enzymes of Arg synthesis reside within the plastid. Synthesis of the l-ornthine (Orn) intermediate in this pathway from l-glutamate occurs as a series of acetylated intermediates, as in most other organisms. An N-acetylornithine:glutamate acetyltransferase (NAOGAcT; EC 2.3.1.35) facilitates recycling of the acetyl moiety during Orn formation (cyclic pathway). A putative N-acetylornithine deacetylase (NAOD; EC 3.5.1.16), which participates in the “linear” pathway for Orn synthesis in some organisms, was also identified. Previous biochemical studies have indicated that allosteric regulation of the first and, especially, the second steps in Orn synthesis (NAGS; N-acetylglutamate kinase (NAGK), EC 2.7.2.8) by the Arg end-product are the major sites of metabolic control of the pathway in organisms using the cyclic pathway. Gene expression profiling for pathway enzymes further suggests that NAGS, NAGK, NAOGAcT and NAOD are coordinately regulated in response to changes in Arg demand during plant growth and development. Synthesis of Arg from Orn is further coordinated with pyrimidine nucleotide synthesis, at the level of allocation of the common carbamoyl-P intermediate.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2023-03-30
    Description: This paper presents seasonal variations of the wind characteristics and wind turbine characteristics in the regions around Elazig, namely Maden, Agin and Keban. Mean wind speed data in measured hourly time series format is statistically analyzed for the six year period 1998–2003. The probability density distributions are derived from the time series data and their distributional parameters are identified. Two probability density functions are fitted to the measured probability distributions on a seasonal basis. The wind energy characteristics of all the regions is studied based on the Weibull and Rayleigh distributions. Energy calculations and capacity factors for the wind turbine characteristics were determined for wind machines of different sizes between 300 and 2300 kW. It was found that Maden is the best region, among the regions analyzed, for wind characteristics and wind turbine characteristics.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2023-03-30
    Description: Energy is an essential ingredient of socio-economic development and economic growth. Renewable energy sources like wind energy is indigenous and can help in reducing the dependency on fossil fuels. Wind is the indirect form of solar energy and is always being replenished by the sun. Wind is caused by differential heating of the earth's surface by the sun. It has been estimated that roughly 10 million MW of energy are continuously available in the earth's wind. Wind energy provides a variable and environmental friendly option and national energy security at a time when decreasing global reserves of fossil fuels threatens the long-term sustainability of global economy. This paper reviews the wind resources assessment models, site selection models and aerodynamic models including wake effect. The different existing performance and reliability evaluation models, various problems related to wind turbine components (blade, gearbox, generator and transformer) and grid for wind energy system have been discussed. This paper also reviews different techniques and loads for design, control systems and economics of wind energy conversion system.
    Type: Article , PeerReviewed
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  • 10
    Publication Date: 2023-03-10
    Description: A series of idealised numerical simulations of dense water flowing down a broad uniform slope are presented, employing both a z-coordinate model (the MIT general circulation model) and an isopycnal coordinate model (the Hallberg Isopycnal Model). Calculations are carried out at several different horizontal and vertical resolutions, and for a range of physical parameters. A subset of calculations are carried out at very high resolution using the non-hydrostatic variant of the MITgcm. In all calculations dense water descends the slope while entraining and mixing with ambient fluid. The dependence of entrainment, mixing and down-slope descent on resolution and vertical coordinate are assessed. At very coarse resolutions the z-coordinate model generates excessive spurious mixing, and dense water has difficulty descending the slope. However, at intermediate resolutions the mixing in the z-coordinate model is less than found in the high-resolution non-hydrostatic simulations, and dense water descends further down the slope. Isopycnal calculations show less resolution dependence, although entrainment and mixing are both reduced slightly at coarser resolution. At intermediate resolutions the z-coordinate and isopycnal models produce similar levels of mixing and entrainment. These results provide a benchmark against which future developments in overflow entrainment parameterizations in both z-coordinate and isopycnal models may be compared.
    Type: Article , PeerReviewed
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