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  • Institute of Physics  (1,082,725)
  • American Geophysical Union  (232,449)
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  • 1
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    January 2002 volcano-tectonic eruption of Nyiragongo volcano, Democratic Republic of Congo (2007)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: In January 2002, Nyiragongo volcano erupted 14–34 × 106 m3 of lava from fractures on its southern flanks. The nearby city of Goma was inundated by two lava flows, which caused substantial socioeconomic disruption and forced the mass exodus of the population, leaving nearly 120,000 people homeless. Field observations showed marked differences between the lava erupted from the northern portion of the fracture system and that later erupted from the southern part. These observations are confirmed by new 238U and 232Th series radioactive disequilibria data, which show the presence of three different phases during the eruption. The lavas first erupted (T1) were probably supplied by a residual magma batch from the lava lake activity during 1994–1995. These lavas were followed by a fresh batch erupted from fissure vents as well as later (May–June 2002) from the central crater (T2). Both lava batches reached the surface via the volcano's central plumbing system, even though a separate flank reservoir may also have been involved in addition to the main reservoir. The final phase (T3) is related to an independent magmatic reservoir located much closer (or even beneath) the city of Goma. Data from the January 2002 eruption, and for similar activity in January 1977, suggest that the eruptive style of the volcano is likely to change in the future, trending toward more common occurrence of flank eruptions. If so, this would pose a significant escalation of volcanic hazards facing Goma and environs, thus requiring the implementation of different volcano-monitoring strategies to better anticipate where and when future eruptions might take place.
    Description: Published
    Description: B09202
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Nyiragongo ; forecasting ; volcanic hazard ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Geogenic and atmospheric sources for volatile organic compounds in fumarolic emissions from Mt. Etna and Vulcano Island (Sicily, Italy) (2012)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: In this paper, fluid source(s) and processes controlling the chemical composition of VOCs (Volatile Organic Compounds) in gas discharges from Mt. Etna and Vulcano Island (Sicily, Italy) were investigated. The main composition of the Etnean and Volcano gas emissions is produced by mixing, to various degrees, of “magmatic” and “hydrothermal” components. VOCs are dominated by alkanes, alkenes and aromatics, with minor, though significant, concentrations of O-, S- and Cl(F)-substituted compounds. The main mechanism for the production of alkanes is likely related to pyrolysis of organic matter-bearing sediments that interact with the ascending magmatic fluids. Alkanes are then converted to alkene and aromatic compounds via catalytic reactions (dehydrogenation and dehydroaromatization, respectively). Nevertheless, an abiogenic origin for the light hydrocarbons cannot be ruled out. Oxidative processes of hydrocarbons at relatively high temperatures and oxidizing conditions, typical of these volcanic-hydrothermal fluids, may explain the production of alcohols, esters, aldehydes, as well as O- and S-bearing heterocycles. By comparing the concentrations of hydrochlorofluorocarbons (HCFCs) in the fumarolic discharges with respect to those of background air, it is possible to highlight that they have a geogenic origin likely due to halogenation of both methane and alkenes. Finally, CFC (chlorofluorocarbon) abundances appear to be consistent with background air, although the strong air contamination that affects the Mt. Etna fumaroles may mask a possible geogenic contribution for these compounds. On the other hand, no CFCs were detected in the Vulcano gases, which are characterized by low air contribution. Nevertheless, a geogenic source for these compounds cannot be excluded on the basis of the present data.
    Description: Published
    Description: D17305
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: etna, vulcano, VOC ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Gas seepage and seismogenic structures along the North-Anatolian Fault in the eastern Sea of Marmara (2012)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: We carried out a combined geophysical and gas-geochemical survey on an active fault strand along the North-Anatolian Fault (NAF) system in the Gulf of İzmit (eastern Sea of Marmara), providing for the first time in this area data on the distribution of methane (CH4) and other gases dissolved in the bottom seawater, as well as the CH4 isotopic composition. Based on high-resolution morphobathymetric data and chirp-sonar seismic reflection profiles we selected three areas with different tectonic features associated to the NAF system, where we performed visual and instrumental seafloor inspections, including in-situ measurements of dissolved CH4, and sampling of the bottom water. Starting from background values of 2-10 nM, methane concentration in the bottom seawater increases abruptly up to 20 nM over the main NAF trace. CH4 concentration peaks up to ~120 nM were detected above mounds related probably to gas and fluids expulsion. Methane is microbial (δ13CCH4: -67.3 and -76 ‰ vs. VPDB), and was found mainly associated with pre- Holocene deposits topped by a 10-20 m thick draping of marine mud. The correlation between tectonic structures and gas-seepages at the seafloor suggests that the NAF in the Gulf of İzmit could represent a key site for long-term combined monitoring of fluid exhalations and seismicity to assess their potential as earthquake precursors.
    Description: Published
    Description: Q10018
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: submarine ; gas seepage ; active fault ; Marmara sea ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Intense magmatic degassing through the lake of Copahue volcano, 2013-2014 (2016)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d−1 of SO2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H2O ~ 10989 t d−1, CO2 ~ 638 t d−1, HCl ~ 66 t d−1, H2 ~ 3.3 t d−1, and HBr ~ 0.05 t d−1). These levels of degassing, comparable to those seen at many open-vent degassing arc volcanoes, were surprisingly high for a volcano hosting a crater lake. Copahue's unusual degassing regime was also confirmed by the chemical composition of the plume that, although issuing from a hot (65°C) lake, preserves a close-to-magmatic signature. EQ3/6 models of gas-water-rock interaction in the lake were able to match observed compositions and demonstrated that magmatic gases emitted to the atmosphere were virtually unaffected by scrubbing of soluble (S and Cl) species. Finally, the derived large H2O flux (10,988 t d−1) suggested a mechanism in which magmatic gas stripping drove enhanced lake water evaporation, a process likely common to many degassing volcanic lakes worldwide.
    Description: Published
    Description: 6071–6084
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: water/rock interaction ; volcanic lakes ; volcanic/hydrothermal gases ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Carbon Stocks and Potential Greenhouse Gas Production of Permafrost-Affected Active Floodplains in the Lena River Delta (2024)
    American Geophysical Union
    In:  EPIC3Journal of Geophysical Research (JGR): Biogeosciences, American Geophysical Union, 129, ISSN: 2169-8953
    Details
    Publication Date: 2024-04-19
    Description: Arctic warming increases the degradation of permafrost soils but little is known about floodplain soils in the permafrost region. This study quantifies soil organic carbon (SOC) and soil nitrogen stocks, and the potential CH4 and CO2 production from seven cores in the active floodplains in the Lena River Delta, Russia. The soils were sandy but highly heterogeneous, containing deep, organic rich deposits with 〉60% SOC stored below 30 cm. The mean SOC stocks in the top 1 m were 12.9 ± 6.0 kg C m−2. Grain size analysis and radiocarbon ages indicated highly dynamic environments with sediment re-working. Potential CH4 and CO2 production from active floodplains was assessed using a 1-year incubation at 20°C under aerobic and anaerobic conditions. Cumulative aerobic CO2 production mineralized a mean 4.6 ± 2.8% of initial SOC. The mean cumulative aerobic:anaerobic C production ratio was 2.3 ± 0.9. Anaerobic CH4 production comprised 50 ± 9% of anaerobic C mineralization; rates were comparable or exceeded those for permafrost region organic soils. Potential C production from the incubations was correlated with total organic carbon and varied strongly over space (among cores) and depth (active layer vs. permafrost). This study provides valuable information on the carbon cycle dynamics from active floodplains in the Lena River Delta and highlights the key spatial variability, both among sites and with depth, and the need to include these dynamic permafrost environments in future estimates of the permafrost carbon-climate feedback.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 6
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    Constraints on the Cryohydrological Warming of Firn and Ice in Greenland From Rayleigh Wave Ellipticity Data (2024)
    American Geophysical Union
    Details
    Publication Date: 2024-04-05
    Description: Rayleigh wave ellipticity measurements from seismic ambient noise recorded on the Greenland Ice Sheet (GrIS) show complex and anomalous behavior at wave periods sensitive to ice (T 〈 3–4 s). To understand these complex observations, we compare them with synthetic ellipticity measurements obtained from synthetic ambient noise computed for various seismic velocity and attenuation models, including surface wave overtone effects. We find that in dry snow conditions within the interior of the GrIS, to first order the anomalous ellipticity observations can be explained by ice models associated with the accumulation and densification of snow into firn. We also show that the distribution of ellipticity measurements is strongly sensitive to seismic attenuation and the thermal structure of the ice. Our results suggest that Rayleigh wave ellipticity is well suited for monitoring changes in firn properties and thermal composition of the Greenland and Antarctic ice sheets in a changing climate.
    Description: Published
    Description: e2023GL103673
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: JCR Journal
    Keywords: 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    North Pacific Mid-Depth and Deep Water Ventilation During the Last Glacial Cycle: Ventilation Patterns and Source Variations (2019)
    American Geophysical Union
    In:  EPIC3AGU Centennial Fall Meeting, San Francisco, CA, USA, 2019-12-09-2019-12-13American Geophysical Union
    Details
    Publication Date: 2023-06-21
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
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    Drifter observations reveal intense vertical velocity in a surface ocean front (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-03-11
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tarry, D., Ruiz, S., Johnston, T., Poulain, P., Özgökmen, T., Centurioni, L., Berta, M., Esposito, G., Farrar, J., Mahadevan, A., & Pascual, A. Drifter observations reveal intense vertical velocity in a surface ocean front. Geophysical Research Letters, 49(18), (2022): e2022GL098969, https://doi.org/10.1029/2022gl098969.
    Description: Measuring vertical motions represent a challenge as they are typically 3–4 orders of magnitude smaller than the horizontal velocities. Here, we show that surface vertical velocities are intensified at submesoscales and are dominated by high frequency variability. We use drifter observations to calculate divergence and vertical velocities in the upper 15 m of the water column at two different horizontal scales. The drifters, deployed at the edge of a mesoscale eddy in the Alboran Sea, show an area of strong convergence (urn:x-wiley:00948276:media:grl64766:grl64766-math-0001(f)) associated with vertical velocities of −100 m day−1. This study shows that a multilayered-drifter array can be an effective tool for estimating vertical velocity near the ocean surface.
    Description: This research was supported by the Office of Naval Research (ONR) Departmental Research Initiative CALYPSO under program officers Terri Paluszkiewicz and Scott Harper. The authors' ONR Grant No. are as follows: DT, SR, AM, and AP N000141613130, TMSJ N000146101612470, PP N000141812418, TO N000141812138, LRC N000141712517, and N00014191269, MB and GE N000141812782 and N000141812039, and JTF N000141812431.
    Keywords: Drifters ; Vertical velocity ; Submesoscale ; Kinematic properties ; Fronts ; Alboran Sea
    Repository Name: Woods Hole Open Access Server
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  • 9
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    Volcano monitoring with magnetic measurements: a simulation of eruptions at axial seamount, Kilauea, Baroarbunga, and Mount Saint Helens (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-03-11
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Biasi, J., Tivey, M., & Fluegel, B. Volcano monitoring with magnetic measurements: a simulation of eruptions at axial seamount, Kilauea, Baroarbunga, and Mount Saint Helens. Geophysical Research Letters, 49(17), (2022): e2022GL100006, https://doi.org/10.1029/2022GL100006.
    Description: Monitoring of active volcanic systems is a challenging task due in part to the trade-offs between collection of high-quality data from multiple techniques and the high costs of acquiring such data. Here we show that magnetic data can be used to monitor volcanoes by producing similar data to gravimetric techniques at significantly lower cost. The premise of this technique is that magma and wall rock above the Curie temperature are magnetically “transparent,” but not stationary within the crust. Subsurface movements of magma can affect the crustal magnetic field measured at the surface. We construct highly simplified magnetic models of four volcanic systems: Mount Saint Helens (1980), Axial Seamount (2015–2020), Kīlauea (2018), and Bárðarbunga (2014). In all cases, observed or inferred changes to the magmatic system would have been detectable by modern magnetometers. Magnetic monitoring could become common practice at many volcanoes, particularly in developing nations with high volcanic risk.
    Description: This work was supported by the NSF Grant No 2052963 to J. Biasi and an internal Woods Hole Oceanographic Institution grant to M. Tivey.
    Keywords: Magnetism ; Volcanic hazards ; Hawaii ; Iceland ; Volcanology ; Monitoring
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  • 10
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    Radium inputs into the Arctic Ocean from rivers a basin‐wide estimate (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-03-11
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Bullock, E., Kipp, L., Moore, W., Brown, K., Mann, P., Vonk, J., Zimov, N., & Charette, M. Radium inputs into the Arctic Ocean from rivers a basin‐wide estimate. Journal of Geophysical Research: Oceans, 127(9), (2022): e2022JC018964, https://doi.org/10.1029/2022jc018964.
    Description: Radium isotopes have been used to trace nutrient, carbon, and trace metal fluxes inputs from ocean margins. However, these approaches require a full accounting of radium sources to the coastal ocean including rivers. Here, we aim to quantify river radium inputs into the Arctic Ocean for the first time for 226Ra and to refine the estimates for 228Ra. Using new and existing data, we find that the estimated combined (dissolved plus desorbed) annual 226Ra and 228Ra fluxes to the Arctic Ocean are [7.0–9.4] × 1014 dpm y−1 and [15–18] × 1014 dpm y−1, respectively. Of these totals, 44% and 60% of the river 226Ra and 228Ra, respectively are from suspended sediment desorption, which were estimated from laboratory incubation experiments. Using Ra isotope data from 20 major rivers around the world, we derived global annual 226Ra and 228Ra fluxes of [7.4–17] × 1015 and [15–27] × 1015 dpm y−1, respectively. As climate change spurs rapid Arctic warming, hydrological cycles are intensifying and coastal ice cover and permafrost are diminishing. These river radium inputs to the Arctic Ocean will serve as a valuable baseline as we attempt to understand the changes that warming temperatures are having on fluxes of biogeochemically important elements to the Arctic coastal zone.
    Description: This study was a broad, collaborative effort that would not have been possible without contributions from numerous funding sources, including the National Science Foundation (NSF-0751525, NSF-1736277, NSF-1458305, NSF-1938873, NSF-2048067, NSF-2134865), the NERC-BMBF project CACOON [NE/R012806/1] (UKRI NERC) and BMBF-03F0806A, and an EU Starting Grant (THAWSOME-676982).
    Keywords: Radium isotopes ; Arctic Ocean ; River fluxes
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  • 11
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    Accuracy and reproducibility of coral Sr/Ca SIMS timeseries in modern and fossil corals (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-03-08
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Sayani, H., Cobb, K., Monteleone, B., & Bridges, H. Accuracy and reproducibility of coral Sr/Ca SIMS timeseries in modern and fossil corals. Geochemistry, Geophysics, Geosystems, 23(9), (2022): e2021GC010068, https://doi.org/10.1029/2021gc010068.
    Description: Coral strontium-to-calcium ratios (Sr/Ca) provide quantitative estimates of past sea surface temperatures (SST) that allow for the reconstruction of changes in the mean state and climate variations, such as the El Nino-Southern Oscillation, through time. However, coral Sr/Ca ratios are highly susceptible to diagenesis, which can impart artifacts of 1–2°C that are typically on par with the tropical climate signals of interest. Microscale sampling via Secondary Ion Mass Spectrometry (SIMS) for the sampling of primary skeletal material in altered fossil corals, providing much-needed checks on fossil coral Sr/Ca-based paleotemperature estimates. In this study, we employ a set modern and fossil corals from Palmyra Atoll, in the central tropical Pacific, to quantify the accuracy and reproducibility of SIMS Sr/Ca analyses relative to bulk Sr/Ca analyses. In three overlapping modern coral samples, we reproduce bulk Sr/Ca estimates within ±0.3% (1σ). We demonstrate high fidelity between 3-month smoothed SIMS coral Sr/Ca timeseries and SST (R = −0.5 to −0.8; p 〈 0.5). For lightly-altered sections of a young fossil coral from the early-20th century, SIMS Sr/Ca timeseries reproduce bulk Sr/Ca timeseries, in line with our results from modern corals. Across a moderately-altered section of the same fossil coral, where diagenesis yields bulk Sr/Ca estimates that are 0.6 mmol too high (roughly equivalent to −6°C artifacts in SST), SIMS Sr/Ca timeseries track instrumental SST timeseries. We conclude that 3–4 SIMS analyses per month of coral growth can provide a much-needed quantitative check on the accuracy of fossil coral Sr/Ca-derived estimates of paleotemperature, even in moderately altered samples.
    Description: We'd also like to thank Yolande Berta and Georgia Tech's Center for Nanostructure Characterization for providing access to their SEM facilities, and the Khaled bin Sultan Living Ocean Foundation and The Nature Conservancy for financial and logistical support for field excursions to Palmyra. Funding for this work was provided by the National Science Foundation (Award Numbers 1502832 and 2002458 to K.M.C) and the National Oceanic and Atmospheric Administration (Award Number: NA11OAR4310165 to K.M.C).
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  • 12
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    Observational and modeling evidence of seasonal trends in sediment-derived material inputs to the Chukchi Sea (2020)
    American Geophysical Union
    Details
    Publication Date: 2023-03-08
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC016007, doi:10.1029/2019JC016007.
    Description: Benthic inputs of nutrients help support primary production in the Chukchi Sea and produce nutrient‐rich water masses that ventilate the halocline of the western Arctic Ocean. However, the complex biological and redox cycling of nutrients and trace metals make it difficult to directly monitor their benthic fluxes. In this study, we use radium‐228, which is a soluble radionuclide produced in sediments, and a numerical model of an inert, generic sediment‐derived tracer to study variability in sediment inputs to the Chukchi Sea. The 228Ra observations and modeling results are in general agreement and provide evidence of strong benthic inputs to the southern Chukchi Sea during the winter, while the northern shelf receives higher concentrations of sediment‐sourced materials in the spring and summer due to continued sediment‐water exchange as the water mass traverses the shelf. The highest tracer concentrations are observed near the shelfbreak and southeast of Hanna Shoal, a region known for high biological productivity and enhanced benthic biomass.
    Description: This study presents data from multiple Arctic expeditions over the past two decades, and we are indebted to the captains, crews, and scientific parties that made this data collection possible. This work was funded by NSF awards OCE‐1458305 to M. Charette, OCE‐1458424 to W. Moore, OCE‐1434085 to D. Kadko, PLR‐1504333 to R. Pickart, and OPP‐1822334 to M. Spall. Funding was also provided by National Oceanic and Atmospheric Administration Grant NA14‐OAR4320158 to R. Pickart. L. Kipp was supported by an Ocean Frontier Institute Postdoctoral Fellowship. Radium data used in this manuscript are available in Table S1.
    Description: 2020-10-27
    Keywords: Chukchi Sea ; Benthic flux ; Radium‐228 ; GEOTRACES
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  • 13
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    Can we estimate air‐sea flux of biological O2 from total dissolved oxygen? (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-03-02
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 36(9), (2022): e2021GB007145, https://doi.org/10.1029/2021gb007145.
    Description: In this study, we compare mechanistic and empirical approaches to reconstruct the air-sea flux of biological oxygen (F[O2]bio-as) by parameterizing the physical oxygen saturation anomaly (ΔO2[phy]) in order to separate the biological contribution from total oxygen. The first approach matches ΔO2[phy] to the monthly climatology of the argon saturation anomaly from a global ocean circulation model's output. The second approach derives ΔO2[phy] from an iterative mass balance model forced by satellite-based physical drivers of ΔO2[phy] prior to the sampling day by assuming that air-sea interactions are the dominant factors driving the surface ΔO2[phy]. The final approach leverages the machine-learning technique of Genetic Programming (GP) to search for the functional relationship between ΔO2[phy] and biophysicochemical parameters. We compile simultaneous measurements of O2/Ar and O2 concentration from 14 cruises to train the GP algorithm and test the validity and applicability of our modeled ΔO2[phy] and F[O2]bio-as. Among the approaches, the GP approach, which incorporates ship-based measurements and historical records of physical parameters from the reanalysis products, provides the most robust predictions (R2 = 0.74 for ΔO2[phy] and 0.72 for F[O2]bio-as; RMSE = 1.4% for ΔO2[phy] and 7.1 mmol O2 m−2 d−1 for F[O2]bio-as). We use the empirical formulation derived from GP approach to reconstruct regional, inter-annual, and decadal variability of F[O2]bio-as based on historical oxygen records. Overall, our study represents a first attempt at deriving F[O2]bio-as from snapshot measurements of oxygen, thereby paving the way toward using historical O2 data and a rapidly growing number of O2 measurements on autonomous platforms for independent insight into the biological pump.
    Description: N. Cassar was supported by the “Laboratoire d'Excellence” LabexMER (ANR-10-LABX-19) and co-funded by a grant from the French government under the program “Investissements d'Avenir.” Y. Huang was supported by grants from the China NSF (Nos. 42130401 and 42141002). Y. Huang was also partly supported by Chinese State Scholarship Fund to study at Duke University as a joint PhD student (No. 201806310052). R. Eveleth was supported by the NSF GRFP under grant (No. 1106401). D. Nicholson was supported by the NSF OCE-1129973 and OCE-1923915.
    Keywords: Air-sea gas biological oxygen flux ; Physical oxygen saturation anomaly ; Total dissolved oxygen ; Mechanistic and empirical models
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  • 14
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    Retrieving a “Weather Balloon” from the last Ice Age (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-28
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Seltzer, A. M., & Tyne, R. L. Retrieving a “Weather Balloon” from the last Ice Age. AGU Advances, 3(4), (2022): e2022AV000747, https://doi.org/10.1029/2022AV000747.
    Description: “How cold was the last ice age?” is a question that paleoclimate scientists have been trying to answer for decades. Constraining the magnitude of climate change since the Last Glacial Maximum (∼20,000 years ago) can help improve our understanding of Earth's climate sensitivity and, therefore enhance our ability to predict future change (Tierney et al., 2020). Of course, there is no single answer to this question: there is spatial structure to LGM temperature change that is linked to fundamental climate system properties and processes. Consequently, paleoclimate scientists have focused on variations of this question, like “What was the latitudinal gradient of LGM temperature change?” (Chiang et al., 2003), “What was the land-sea contrast?” (Rind & Peteet, 1985) or “What was the change in ocean heat content?” (Bereiter et al., 2018). These questions inform large-scale atmospheric and oceanic circulation, the intensity of the water cycle, and planetary energy balance; the answers to these questions come from proxies like planktic and benthic foraminifera, speleothems, ice cores, pollen records, ancient groundwater, lake sediments, and glacial moraines, to name a few. In short, the paleoclimate community has developed a proxy “tool kit” equipped to map changes across the Earth's surface and into the ocean interior; but, until now, no “tool” existed for the upper atmosphere.
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  • 15
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    Sediments in sea ice drive the Canada Basin surface Mn maximum: insights from an Arctic Mn Ocean model (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-28
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 36(8), (2022): e2022GB007320, https://doi.org/10.1029/2022GB007320.
    Description: Biogeochemical cycles in the Arctic Ocean are sensitive to the transport of materials from continental shelves into central basins by sea ice. However, it is difficult to assess the net effect of this supply mechanism due to the spatial heterogeneity of sea ice content. Manganese (Mn) is a micronutrient and tracer which integrates source fluctuations in space and time while retaining seasonal variability. The Arctic Ocean surface Mn maximum is attributed to freshwater, but studies struggle to distinguish sea ice and river contributions. Informed by observations from 2009 IPY and 2015 Canadian GEOTRACES cruises, we developed a three-dimensional dissolved Mn model within a 1/12° coupled ocean-ice model centered on the Canada Basin and the Canadian Arctic Archipelago (CAA). Simulations from 2002 to 2019 indicate that annually, 87%–93% of Mn contributed to the Canada Basin upper ocean is released by sea ice, while rivers, although locally significant, contribute only 2.2%–8.5%. Downstream, sea ice provides 34% of Mn transported from Parry Channel into Baffin Bay. While rivers are often considered the main source of Mn, our findings suggest that in the Canada Basin they are less important than sea ice. However, within the shelf-dominated CAA, both rivers and sediment resuspension are important. Climate-induced disruption of the transpolar drift may reduce the Canada Basin Mn maximum and supply downstream. Other micronutrients found in sediments, such as Fe, may be similarly affected. These results highlight the vulnerability of the biogeochemical supply mechanisms in the Arctic Ocean and the subpolar seas to climatic changes.
    Description: This work was funded by the Natural Sciences and Engineering Research Council of Canada (NSERC) Climate Change and Atmospheric Research Grant: GEOTRACES (RGPCC 433848-12) and VITALS (RGPCC 433898), an NSERC Discovery Grant (RGPIN-2016-03865) to SEA, and by the University of British Columbia through a four year fellowship to BR. Computing resources were provided by Compute Canada (RRG 2648 RAC 2019, RRG 2969 RAC 2020, and RRG 1541 RAC 2021).
    Keywords: GEOTRACES ; Arctic Ocean ; Trace elements ; Canadian Arctic Archipelago ; Ocean modeling ; Micronutrients
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  • 16
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    WISTFUL: whole‐rock interpretative seismic toolbox for ultramafic lithologies (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-28
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Shinevar, W., Jagoutz, O., & Behn, M. WISTFUL: whole‐rock interpretative seismic toolbox for ultramafic lithologies. Geochemistry, Geophysics, Geosystems, 23(8), (2022): e2022GC010329, https://doi.org/10.1029/2022gc010329.
    Description: To quantitatively convert upper mantle seismic wave speeds measured into temperature, density, composition, and corresponding and uncertainty, we introduce the Whole-rock Interpretative Seismic Toolbox For Ultramafic Lithologies (WISTFUL). WISTFUL is underpinned by a database of 4,485 ultramafic whole-rock compositions, their calculated mineral modes, elastic moduli, and seismic wave speeds over a range of pressure (P) and temperature (T) (P = 0.5–6 GPa, T = 200–1,600°C) using the Gibbs free energy minimization routine Perple_X. These data are interpreted with a toolbox of MATLAB® functions, scripts, and three general user interfaces: WISTFUL_relations, which plots relationships between calculated parameters and/or composition; WISTFUL_geotherms, which calculates seismic wave speeds along geotherms; and WISTFUL_inversion, which inverts seismic wave speeds for best-fit temperature, composition, and density. To evaluate our methodology and quantify the forward calculation error, we estimate two dominant sources of uncertainty: (a) the predicted mineral modes and compositions, and (b) the elastic properties and mixing equations. To constrain the first source of uncertainty, we compiled 122 well-studied ultramafic xenoliths with known whole-rock compositions, mineral modes, and estimated P-T conditions. We compared the observed mineral modes with modes predicted using five different thermodynamic solid solution models. The Holland et al. (2018, https://doi.org/10.1093/petrology/egy048) solution models best reproduce phase assemblages (∼12 vol. % phase root-mean-square error [RMSE]) and estimated wave speeds. To assess the second source of uncertainty, we compared wave speed measurements of 40 ultramafic rocks with calculated wave speeds, finding excellent agreement (Vp RMSE = 0.11 km/s). WISTFUL easily analyzes seismic datasets, integrates into modeling, and acts as an educational tool.
    Description: Funding for this study was provided by NSF Grants EAR-17-22935 (OJ) and EAR-18-44340 (MB).
    Keywords: Seismic velocity ; Seismic wave speed ; Thermodynamic modeling ; Density ; Composition ; Elastic moduli
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  • 17
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    Seismic imaging of Dante’s Domes oceanic core complex from streamer waveform inversion and reverse time migration (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-25
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 127(8), (2022): e2021JB023814, https://doi.org/10.1029/2021jb023814.
    Description: Early arrival traveltime tomography and full waveform inversion were conducted on downward continued streamer seismic data at Dante's Domes oceanic core complex (OCC), providing unprecedented details of shallow P wave velocity structure. Together with reverse time migration images, seafloor morphology, in situ geological samples, magnetic and gravity data, the seismic constraints are used to infer the lithological distribution along the seismic profiles. Based on the striking similarity in velocity structure beneath the corrugated domes with other OCCs and drilling results from Atlantis Massif, we confidently reconfirmed the Southern Dome as dominantly gabbroic rocks, and the Northern Dome as serpentinized peridotites. A series of isolated gabbroic bodies embedded in the diabase and basaltic layers is observed in the breakaway zone, suggesting that the initiation of Dante's Domes OCC occurred over a long period during which there were several failed attempts to form a long-lived detachment fault. This early development of the OCC probably occurred under a regime of alternating magma starvation and magma replenishment. The predominantly gabbroic section, beneath the Southern Dome and extending to termination, indicates the OCC has been created with relatively high magma flux. We also imaged distinct shallow subseafloor reflections which are also termed as D reflectors underneath the corrugated domes. The location of the D reflectors is similar to those in the Atlantis Massif, with depths well correlated with the top of exhumed gabbroic bodies and the discontinuities in the D reflectors between gabbroic bodies. Our findings contribute to the understanding of processes controlling the OCCs initiation and evolution at slow spreading ridges.
    Description: This research was supported by the National Natural Science Foundation of China (91858207), Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (GML2019ZD0205), and Guangdong Basic and Applied Basic Research Foundation (2021B1515020023). M. X. acknowledges support from Special Foundation for National Science and Technology Basic Research Program of China (2018FY100505), Guangdong NSF research team project (2017A030312002), K. C. Wong Education Foundation (GJTD-2018-13), and the Chinese Academy of Sciences (Y4SL021001, QYZDY-SSWDQC005, 133244KYSB20180029, 131551KYSB20200021, and ISEE2021PY03). J. P. C. acknowledges support from the Independent Research and Development Program at WHOI.
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  • 18
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    Spatial variability of movement, structure, and formation of Warm Core Rings in the Northwest Atlantic Slope Sea (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-25
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 127(8),(2022): e2022JC018737, https://doi.org/10.1029/2022jc018737.
    Description: Gulf Stream Warm Core Rings (WCRs) have important influences on the New England Shelf and marine ecosystems. A 10-year (2011–2020) WCR dataset that tracks weekly WCR locations and surface areas is used here to identify the rings' path and characterize their movement between 55 and 75°W. The WCR dataset reveals a very narrow band between 66 and 71°W along which rings travel almost due west along ∼39°N across isobaths – the “Ring Corridor.” Then, west of the corridor, the mean path turns southwestward, paralleling the shelfbreak. The average ring translation speed along the mean path is 5.9 cm s−1. Long-lived rings (lifespan 〉150 days) tend to occupy the region west of the New England Seamount Chain (NESC) whereas short-lived rings (lifespan 〈150 days) tend to be more broadly distributed. WCR vertical structures, analyzed using available Argo float profiles indicate that rings that are formed to the west of the NESC have shallower thermoclines than those formed to the east. This tendency may be due to different WCR formation processes that are observed to occur along different sections of the Gulf Stream. WCRs formed to the east of the NESC tend to form from a pinch-off mechanism incorporating cores of Sargasso Sea water and a perimeter of Gulf Stream water. WCRs that form to the west of the NESC, form from a process called an aneurysm. WCRs formed through aneurysms comprise water mostly from the northern half of the Gulf Stream and are smaller than the classic pinch-off rings.
    Description: AS and AG are grateful for financial support from NOAA (NA11NOS0120038), NSF (OCE-1851242 and OCE-2123283), SMAST, and UMass Dartmouth. GG was supported by NSF under grant OCE-1657853. MA was supported by NSF under grant OCE-2122726 and by ONR under grant N00014-22-1-2112.
    Keywords: Gulf Stream ; Warm core rings ; Trajectories ; Eddies ; Aneurysm ; Ring formation
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  • 19
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    Eruption rates, tempo, and stratigraphy of Paleocene flood basalts on Baffin Island, Canada (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-25
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Biasi, J., Asimow, P., Horton, F., & Boyes, X. Eruption rates, tempo, and stratigraphy of Paleocene flood basalts on Baffin Island, Canada. Geochemistry, Geophysics, Geosystems, 23(9), (2022): e2021GC010172, https://doi.org/10.1029/2021gc010172.
    Description: High-temperature melting in mantle plumes produces voluminous eruptions that are often temporally coincident with mass extinctions. Paleocene Baffin Island lavas—products of early Iceland mantle plume activity—are exceptionally well characterized geochemically but have poorly constrained stratigraphy, geochronology, and eruptive tempos. To provide better geologic context, we measured seven stratigraphic sections of the volcanic deposits and collected paleomagnetic data from 38 sites in the lavas and underlying Cretaceous sediments (Quqaluit Fm.). The average paleomagnetic pole from this study does not overlap with the expected pole for a stable North American locality at 60 Ma, yet the data have sufficient dispersion to average out secular variation. After ruling out other possibilities, we find that the picrites were probably erupted during a polarity transition, over less than 5 kyr. If so, the average eruption interval was ∼67 years per flow for the thickest sequence of exposed lavas. We also calculate that the flood basalts had a minimum total volume of ∼176 km3 (excluding submerged lavas in Baffin Bay). This implies a minimum eruption rate of ∼0.035 km3 yr−1, which is similar to rates found in West Greenland lavas but less than rates found in larger flood basalts. Despite this, the Baffin and West Greenland lavas temporally correlate with the “End C27n event” (a period of ∼2°C global warming) and may be its underlying cause.
    Description: his work was supported by the National Science Foundation (award #1911699 to F. Horton and award #2052963 to J. Biasi), Woods Hole Oceanographic Institution (WHOI) Andrew W. Mellon Foundation Endowed Fund for Innovative Research, a National Geographic Society grant (#CP4-144R-18), and internal funding from the Caltech Geological and Planetary Sciences Division.
    Keywords: Baffin island ; North Atlantic ; Flood basalt ; Paleomagnetism ; Volcanology ; Secular variation
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  • 20
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    Carbonation of serpentinite in creeping faults of California (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-21
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(15), (2022): e2022GL099185, https://doi.org/10.1029/2022gl099185.
    Description: Several large strike slip faults in central and northern California accommodate plate motions through aseismic creep. Although there is no consensus regarding the underlying cause of aseismic creep, aqueous fluids and mechanically weak, velocity-strengthening minerals appear to play a central role. This study integrates field observations and thermodynamic modeling to examine possible relationships between the occurrence of serpentinite, silica-carbonate rock, and CO2-rich aqueous fluids in creeping faults of California. Our models predict that carbonation of serpentinite leads to the formation of talc and magnesite, followed by silica-carbonate rock. While abundant exposures of silica-carbonate rock indicate complete carbonation, serpentinite-hosted CO2-rich spring fluids are strongly supersaturated with talc at elevated temperatures. Hence, carbonation of serpentinite is likely ongoing in parts of the San Andres Fault system and operates in conjunction with other modes of talc formation that may further enhance the potential for aseismic creep, thereby limiting the potential for large earthquakes.
    Description: This work was supported by National Science Foundation (NSF) grants NSF-EAR-1220280 to F. K. and J. L., NSF-EAR-1219908 to D. G., and NSF-OCE-2001728 to J. L.
    Keywords: Mineral carbonation ; Serpentinite ; Talc ; CO2 ; Aseismic creep ; San Andreas Fault
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  • 21
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    Does sea spray aerosol contribute significantly to aerosol trace element loading? a case study from the US GEOTRACES Pacific Meridional Transect (GP15) (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-21
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Marsay, C. M., Landing, W. M., Umstead, D., Till, C. P., Freiberger, R., Fitzsimmons, J. N., Lanning, N. T., Shiller, A. M., Hatta, M., Chmiel, R., Saito, M., & Buck, C. S. Does sea spray aerosol contribute significantly to aerosol trace element loading? a case study from the US GEOTRACES Pacific Meridional Transect (GP15). Global Biogeochemical Cycles, 36(8), (2022): e2022GB007416. https://doi.org/10.1029/2022GB007416.
    Description: Atmospheric deposition represents a major input for micronutrient trace elements (TEs) to the surface ocean and is often quantified indirectly through measurements of aerosol TE concentrations. Sea spray aerosol (SSA) dominates aerosol mass concentration over much of the global ocean, but few studies have assessed its contribution to aerosol TE loading, which could result in overestimates of “new” TE inputs. Low-mineral aerosol concentrations measured during the U.S. GEOTRACES Pacific Meridional Transect (GP15; 152°W, 56°N to 20°S), along with concurrent towfish sampling of surface seawater, provided an opportunity to investigate this aspect of TE biogeochemical cycling. Central Pacific Ocean surface seawater Al, V, Mn, Fe, Co, Ni, Cu, Zn, and Pb concentrations were combined with aerosol Na data to calculate a “recycled” SSA contribution to aerosol TE loading. Only vanadium was calculated to have a SSA contribution averaging 〉1% along the transect (mean of 1.5%). We derive scaling factors from previous studies on TE enrichments in the sea surface microlayer and in freshly produced SSA to assess the broader potential for SSA contributions to aerosol TE loading. Maximum applied scaling factors suggest that SSA could contribute significantly to the aerosol loading of some elements (notably V, Cu, and Pb), while for others (e.g., Fe and Al), SSA contributions largely remained 〈1%. Our study highlights that a lack of focused measurements of TEs in SSA limits our ability to quantify this component of marine aerosol loading and the associated potential for overestimating new TE inputs from atmospheric deposition.
    Description: This research was supported by the National Science Foundation (NSF) grants OCE-1756103 to C. S. Buck, OCE-1756104 to W. M. Landing, OCE-1737024 to A.M. Shiller, OCE-1736906 to M. Hatta, OCE-1736875 to C. P. Till, OCE-1737167 to J. N. Fitzsimmons, and OCE-1736599 to M. Saito. In addition, N. T. Lanning was supported by the NSF Graduate Research Fellowship Program award 1746932.
    Keywords: Aerosols ; Trace elements ; GEOTRACES ; Sea spray aerosol ; Pacific Ocean
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  • 22
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    Lagrangian views of the pathways of the Atlantic meridional overturning circulation (2019)
    American Geophysical Union
    Details
    Publication Date: 2023-02-21
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(8), (2019): 5313-5335, doi:10.1029/2019JC015014.
    Description: The Lagrangian method—where current location and intensity are determined by tracking the movement of flow along its path—is the oldest technique for measuring the ocean circulation. For centuries, mariners used compilations of ship drift data to map out the location and intensity of surface currents along major shipping routes of the global ocean. In the mid‐20th century, technological advances in electronic navigation allowed oceanographers to continuously track freely drifting surface buoys throughout the ice‐free oceans and begin to construct basin‐scale, and eventually global‐scale, maps of the surface circulation. At about the same time, development of acoustic methods to track neutrally buoyant floats below the surface led to important new discoveries regarding the deep circulation. Since then, Lagrangian observing and modeling techniques have been used to explore the structure of the general circulation and its variability throughout the global ocean, but especially in the Atlantic Ocean. In this review, Lagrangian studies that focus on pathways of the upper and lower limbs of the Atlantic Meridional Overturning Circulation (AMOC), both observational and numerical, have been gathered together to illustrate aspects of the AMOC that are uniquely captured by this technique. These include the importance of horizontal recirculation gyres and interior (as opposed to boundary) pathways, the connectivity (or lack thereof) of the AMOC across latitudes, and the role of mesoscale eddies in some regions as the primary AMOC transport mechanism. There remain vast areas of the deep ocean where there are no direct observations of the pathways of the AMOC.
    Description: The authors extend their thanks to Xiaobiao Xu for valuable comments on the first draft of this manuscript. A. B. (WHOI), H. F., M. S. L., N. F., and K. D. were supported by Overturning in the Subpolar North Atlantic Program grants OCE‐1259618, OCE‐1259013, and OCE‐1259102 from the U.S. National Science Foundation. S. Z. was supported by the Climate Program Office of the National Oceanic and Atmospheric Administration under award NA16OAR4310168. M. L. was supported through the MOVE project, funded by NOAA's Global Ocean Monitoring and Observing Program under award NA15OAR4320071. A. B. (GEOMAR) and S. R. received funding from the Cluster of Excellence 80 “The Future Ocean” within the framework of the Excellence Initiative by the Deutsche Forschungsgemeinschaft (DFG) on behalf of the German federal and state governments (grant CP1412) and by the German Federal Ministry of Education and Research (BMBF) for the SPACES projects AGULHAS (grant 03F0750A) and CASISAC (grant 03F0796A). No new data are reported in this project. The data mentioned in the text may be found in repositories cited in each previously published paper cited in this review manuscript.
    Keywords: Floats ; Drifters ; Lagrangian methods ; AMOC ; Atlantic Ocean ; Numerical models
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  • 23
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    Using misorientation and weighted burgers vector statistics to understand intragranular boundary development and grain boundary formation at high temperatures (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-21
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 127(8), (2022): e2022JB024497, https://doi.org/10.1029/2022JB024497.
    Description: During plastic deformation, strain weakening can be achieved, in part, via strain energy reduction associated with intragranular boundary development and grain boundary formation. Grain boundaries (in 2D) are segments between triple junctions, that connect to encircle grains; every boundary segment in the encircling loop has a high (〉10°) misorientation angle. Intragranular boundaries terminate within grains or dissect grains, usually containing boundary segments with a low (〈10°) misorientation angle. We analyze electron backscatter diffraction (EBSD) data from ice deformed at −30°C (Th≈ 0.9). Misorientation and weighted Burgers vector (WBV) statistics are calculated along planar intragranular boundaries. Misorientation angles change markedly along each intragranular boundary, linking low- (〈10°) and high-angle (10–38°) segments that exhibit distinct misorientation axes and WBV directions. We suggest that these boundaries might be produced by the growth and intersection of individual intragranular boundary segments comprising dislocations with distinct slip systems. There is a fundamental difference between misorientation axis distributions of intragranular boundaries (misorientation axes mostly confined to ice basal plane) and grain boundaries (no preferred misorientation axis). These observations suggest during progressive subgrain rotation, intragranular boundaries remain crystallographically controlled up to large misorientation angles (〉〉10°). In contrast, the apparent lack of crystallographic control for grain boundaries suggests misorientation axes become randomized, likely due to the activation of additional mechanisms (such as grain boundary sliding) after grain boundary formation, linking boundary segments to encircle a grain. Our findings on ice intragranular boundary development and grain boundary formation may apply more broadly to other rock-forming minerals (e.g., olivine, quartz).
    Description: This work was supported by a NASA fund (Grant No. NNX15AM69G) to David L. Goldsby and two Marsden Funds of the Royal Society of New Zealand (Grant Nos. UOO1116, UOO052) to David J. Prior. Sheng Fan was supported by the University of Otago doctoral scholarship, the Antarctica New Zealand doctoral scholarship, a research grant from New Zealand Ministry of Business, Innovation and Employment through the Antarctic Science Platform (ANTA1801) (Grant No. ASP-023-03), and a New Zealand Antarctic Research Institute (NZARI) Early Career Researcher Seed Grant (Grant No. NZARI 2020-1-5). Open access publishing facilitated by University of Otago, as part of the Wiley – University of Otago agreement via the Council of Australian University Librarians.
    Keywords: High temperature deformation ; Misorientation ; Weighted Burgers vector ; Intragranular boundary ; Grain boundary ; Boundary geometry
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  • 24
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    Size-differentiated export flux in different dynamical regimes in the ocean (2021)
    American Geophysical Union
    Details
    Publication Date: 2023-02-17
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(3), (2021): e2020GB006764, https://doi.org/10.1029/2020GB006764
    Description: Export of Particulate Organic Carbon (POC) is mainly driven by gravitational sinking. Thus, traditionally, it is thought that larger, faster-sinking particles make up most of the POC export flux. However, this need not be the case for particles whose sinking speeds are comparable to the vertical velocities of a dynamic flow field that can influence the descent rate of particles. Particles with different settling speeds are released in two process-oriented model simulations of an upper ocean eddying flow in the Northeast Pacific to evaluate the impact of (1) ocean dynamics on the respective contribution of the different sinking-velocity classes to POC export, and (2) the particle number size-spectrum slope. The analysis reveals that the leading export mechanism changes from gravitationally driven to advectively driven as submesoscale dynamics become more active in the region. The vertical velocity associated with submesoscale dynamics enhances the contribution of slower-sinking particles to POC export flux by a factor ranging from 3 to 10, especially where the relative abundance of small particles is large (i.e., steep particle size-spectrum slope). Remineralization generally decreases the total amount of biomass exported, but its impact is weaker in dynamical regimes where submesoscale dynamics are present and export is advectively driven. In an advectively driven export regime, remineralization processes counter-intuitively enhance the role of slower-sinking particles to the point where these slower-sinking velocity classes dominate the export, therefore challenging the traditional paradigm for POC export. This study demonstrates that slow-sinking particles can be a significant contribution, and at times, even dominate the export flux.
    Description: The work was funded by NASA grant NNX16AR48 G, to complement the EXport Processes in the global Ocean from RemoTe Sensing (EXPORTS) program.
    Description: 2021-08-17
    Keywords: Export ; Flux ; Particulate organic carbon ; Sinking rates ; Submeso-scales ; Vertical velocities
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  • 25
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    The influence of ocean topography on the upwelling of carbon in the Southern Ocean (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-17
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 48(19), (2021): e2021GL095088, https://doi.org/10.1029/2021GL095088.
    Description: The physical circulation of the Southern Ocean sets the surface concentration and thus air-sea exchange of CO2. However, we have a limited understanding of the three-dimensional circulation that brings deep carbon-rich waters to the surface. Here, we introduce and analyze a novel high-resolution ocean model simulation with active biogeochemistry and online Lagrangian particle tracking. We focus our attention on a subset of particles with high dissolved inorganic carbon (DIC) that originate below 1,000 m and eventually upwell into the near-surface layer (upper 200 m). We find that 71% of the DIC-enriched water upwelling across 1,000 m is concentrated near topographic features, which occupy just 33% of the Antarctic Circumpolar Current. Once particles upwell to the near-surface layer, they exhibit relatively uniform pCO2 levels and DIC decorrelation timescales, regardless of their origin. Our results show that Southern Ocean bathymetry plays a key role in delivering carbon-rich waters to the surface.
    Description: Riley X. Brady was supported by the Department of Energy's Computational Science Graduate Fellowship (DE-FG02-97ER25308), and particularly benefited from the fellowship's summer practicum at Los Alamos National Lab. Nicole S. Lovenduski and Riley X. Brady were further supported by the U.S. Department of Energy Biological and Environmental Research program (DE-SC0022243) and by the National Science Foundation (NSF-PLR 1543457; NSF-OCE 1924636; NSF-OCE 1752724; NSF-OCE 1558225). Mathew E. Maltrud and Phillip J. Wolfram were supported as part of the Energy Exascale Earth System Model (E3SM) project, funded by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research. This research used resources provided by the Los Alamos National Laboratory Institutional Computing Program, which is supported by the U.S. Department of Energy National Nuclear Security Administration under Contract No. 89233218CNA000001.
    Keywords: Southern Ocean ; Carbon cycle ; Upwelling ; Lagrangian modeling ; Ocean biogeochemistry ; Climate modeling
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    Relative timing of off‐axis volcanism from sediment thickness estimates on the 8°20’N seamount chain, East Pacific Rise (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-16
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fabbrizzi, A., Parnell‐Turner, R., Gregg, P., Fornari, D., Perfit, M., Wanless, V., & Anderson, M. Relative timing of off‐axis volcanism from sediment thickness estimates on the 8°20’N seamount chain, East Pacific Rise. Geochemistry, Geophysics, Geosystems, 23(9), (2022): e2022GC010335, https://doi.org/10.1029/2022gc010335.
    Description: Volcanic seamount chains on the flanks of mid-ocean ridges record variability in magmatic processes associated with mantle melting over several millions of years. However, the relative timing of magmatism on individual seamounts along a chain can be difficult to estimate without in situ sampling and is further hampered by Ar40/Ar39 dating limitations. The 8°20’N seamount chain extends ∼170 km west from the fast-spreading East Pacific Rise (EPR), north of and parallel to the western Siqueiros fracture zone. Here, we use multibeam bathymetric data to investigate relationships between abyssal hill formation and seamount volcanism, transform fault slip, and tectonic rotation. Near-bottom compressed high-intensity radiated pulse, bathymetric, and sidescan sonar data collected with the autonomous underwater vehicle Sentry are used to test the hypothesis that seamount volcanism is age-progressive along the seamount chain. Although sediment on seamount flanks is likely to be reworked by gravitational mass-wasting and current activity, bathymetric relief and Sentry vehicle heading analysis suggest that sedimentary accumulations on seamount summits are likely to be relatively pristine. Sediment thickness on the seamounts' summits does not increase linearly with nominal crustal age, as would be predicted if seamounts were constructed proximal to the EPR axis and then aged as the lithosphere cooled and subsided away from the ridge. The thickest sediments are found at the center of the chain, implying the most ancient volcanism there, rather than on seamounts furthest from the EPR. The nonlinear sediment thickness along the 8°20’N seamounts suggests that volcanism can persist off-axis for several million years.
    Description: This work was supported by National Science Foundation awards OCE-1356610, OCE-1356822, OCE-1357150, OCE-1754419, OCE-1834797, OCE-2001314, and OCE-2001331.
    Keywords: Off-axis seamounts ; East Pacific Rise ; Sediment thickness ; Seafloor morphology ; Autonomous underwater vehicle ; Eruption history
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    Monitoring volcanic activity through combined measurements of CO2 efflux and (222Rn) and (220Rn) in soil gas: an application to Mt. Etna (Italy) (2023)
    American Geophysical Union
    Details
    Publication Date: 2023-02-07
    Description: We present measurements of soil CO2 effluxes combined with soil (222Rn) and (220Rn) from two high-degassing areas on the lower flanks of Mt. Etna volcano (ZE-SV on the E flank and PAT on the SW flank). Measurements were conducted periodically from June 2006 to January 2009 in the ZE-SV area and January 2007 to January 2009 in the PAT area. The results showed significant variations in discharge activity and style. Log values of (220Rn)/(222Rn) and CO2 efflux generally follow a negative correlation, herein parameterized as the Soil Gas Disequilibrium Index (SGDI). Deviations of the SGDI from this negative correlation provide insight into variance of localized and shallow system conditions, namely rock fracturing, residual magma degassing, and near surface interactions between magmatic gases and groundwater. Statistical analysis highlighted signal anomalies, both negative and positive, that were modeled according to the physical properties and the modes of transport for each of the SGDI gas components. The revealed anomalies show correspondence with episodes of magma ascent and eruption, thereby demonstrating the potential of using the SGDI as another instrument for forecasting volcanic activity. An important strength of the SGDI, compared to other magma gas proxies like CO2 or SO2, is that the very short and very different half-lives of 222Rn (t1/2 = 3.85 days) and 220Rn (t1/2 = 55 seconds) provide unique information on the timescales of soil gas transport. Coupling the SGDI with other pre-eruptive proxies enhances the volcanological community’s response capabilities, which is critical for effective hazard mitigation.
    Description: Published
    Description: 167-202
    Description: 4V. Processi pre-eruttivi
    Keywords: Soil gases ; radon ; carbon dioxide ; volcano monitoring ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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    Submarine groundwater discharge in the northern Bohai Sea, China: Implications for coastal carbon budgets and buffering capacity (2022)
    American Geophysical Union
    Details
    Publication Date: 2023-01-20
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 127(8), (2022): e2022JG006810, https://doi.org/10.1029/2022jg006810.
    Description: Submarine groundwater discharge (SGD) has been widely recognized as an important source of dissolved nutrients in coastal waters and affects nutrient biogeochemistry. In contrast, little information is available on SGD impacts on coastal carbon budgets. Here, we assessed the SGD and associated carbon (dissolved inorganic carbon [DIC] and total alkalinity [TA]) fluxes in Liaodong Bay (the largest bay of the Bohai Sea, China) and discussed their border implications for coastal DIC budget and buffering capacity. Based on 223Ra and 228Ra mass balance models, the SGD flux was estimated to be (0.92–1.43) × 109 m3 d−1. SGD was the largest contributor of DIC, accounting for 55%–77% of the total DIC sources. The low ratio (〈1) of SGD-derived TA to DIC fluxes and negative correlation between radium isotopes and pH in seawater implied that SGD would potentially reduce seawater pH in Liaodong Bay. Combining the groundwater carbon data in Liaodong Bay with literature data, we found that the SGD-derived DIC flux off China was 4–9 times greater than those from rivers. By analyzing the TA/DIC ratios in groundwater along the Chinese coast and related carbon fluxes, SGD was thought to partially reduce the CO2 buffer capacity in receiving seawater. These results obtained at the bay scale and national scale suggest that SGD is a significant component of carbon budget and may play a critical role in modulating coastal buffering capacity and atmospheric CO2 sequestration.
    Description: his research was supported by National Natural Science Foundation of China (Grant Nos. 42130703, 42007170) and the Science, Technology and Innovation Commission of Shenzhen (Grant No. 20200925174525002.
    Description: 2023-01-20
    Keywords: Submarine groundwater discharge ; Radium isotopes ; Dissolved inorganic carbon ; Total alkalinity ; Carbon budgets ; Buffering capacity
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    Active alkaline traps to determine acidic-gas ratios in volcanic plumes: Sampling techniques and analytical methods (2015)
    American Geophysical Union
    Details
    Publication Date: 2023-01-19
    Description: In situ measurements have been the basis for monitoring volcanic gas emissions for many years and—being complemented by remote sensing techniques—still play an important role to date. Concerning in situ techniques for sampling a dilute plume, an increase in accuracy and a reduction of detection limits are still necessary for most gases (e.g., CO2, SO2, HCl, HF, HBr, HI). In this work, the Raschig-Tube technique (RT) is modified and utilized for application on volcanic plumes. The theoretical and experimental absorption properties of the RT and the Drechsel bottle (DB) setups are characterized and both are applied simultaneously to the well-established Filter packs technique (FP) in the field (on Stromboli Island and Mount Etna). The comparison points out that FPs are the most practical to apply but the results are errorprone compared to RT and DB, whereas the RT results in up to 13 times higher analyte concentrations than the DB in the same sampling time. An optimization of the analytical procedure, including sample pretreatment and analysis by titration, Ion Chromatography, and Inductively Coupled Plasma Mass Spectrometry, led to a comprehensive data set covering a wide range of compounds. In particular, less abundant species were quantified more accurately and iodine was detected for the first time in Stromboli’s plume. Simultaneously applying Multiaxis Differential Optical Absorption Spectroscopy (MAX-DOAS) the chemical transformation of emitted bromide into bromine monoxide (BrO) from Stromboli and Etna was determined to 3–6% and 7%, respectively, within less than 5 min after the gas release from the active vents.
    Description: Published
    Description: 2797–2820
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: plume ; volcano ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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    The paroxysmal event and its deposits (2008)
    American Geophysical Union
    Details
    Publication Date: 2023-01-16
    Description: The 5 April 2003 eruption of Stromboli volcano (Italy) was the most violent in the past 50 years. It was also the best documented due to the accurate geophysical monitoring of the ongoing effusive eruption. Detailed field studies carried out a few hours to a few months after the event provided further information that were coupled with visual documentation to reconstruct the explosive dynamics. The eruption consisted of an 8-min-long explosive event preceded by a short-lived precursory activity that evolved into the impulsive ejection of gas and pyroclasts. Meter-sized ballistic blocks were launched to altitudes of up to 1400 m above the craters falling on the volcano flanks and on the village of Ginostra, about 2 km far from the vent. The vertical jet of gas and pyroclasts above the craters fed a convective plume that reached a height of 4 km. The calculated erupted mass yielded values of 1.1–1.4 × 108 kg. Later explosions generated a scoria flow deposit, with an estimated mass of 1.0–1.3 × 107 kg. Final, waning ash explosions closet the event. The juvenile fraction consisted of an almost aphyric, highly vesicular pumice mingled with a shallow-derived, crystal-rich, moderately vesicular scoria. Resuming of the lava emission a few hours after the paroxysm indicate that the shallow magmatic system was not significantly modified during the explosions. Combination of volume data with duration of eruptive phases allowed us to estimate the eruptive intensity: during the climactic explosive event, the mass discharge rate was between 106 and 107 kg/s, whereas during the pyroclastic flow activity, it was 2.8–3.6 × 105 kg/s. Strong similarities with other historical paroxysms at Stromboli suggest similar explosion dynamics.
    Description: Unpublished
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: open
    Keywords: Stromboli ; paroxysm ; explosive dynamics ; pyroclastic deposits ; ballistic ejecta ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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    Tephra sedimentation during the 2010 Eyjafjallajökull eruption (Iceland) from deposit, radar, and satellite observations (2012)
    American Geophysical Union
    Details
    Publication Date: 2023-01-16
    Description: The April–May 2010 eruption of the Eyjafjallajökull volcano (Iceland) was characterized by a nearly continuous injection of tephra into the atmosphere that affected various economic sectors in Iceland and caused a global interruption of air traffic. Eruptive activity during 4–8 May 2010 was characterized based on short-duration physical parameters in order to capture transient eruptive behavior of a long-lasting eruption (i.e., total grain-size distribution, erupted mass, and mass eruption rate averaged over 30 min activity). The resulting 30 min total grain-size distribution based on both ground and Meteosat Second Generation-Spinning Enhanced Visible and Infrared Imager (MSG-SEVIRI) satellite measurements is characterized by Mdphi of about 2 and a fine-ash content of about 30 wt %. The accumulation rate varied by 2 orders of magnitude with an exponential decay away from the vent, whereas Mdphi shows a linear increase until about 18 km from the vent, reaching a plateau of about 4.5 between 20 and 56 km. The associated mass eruption rate is between 0.6 and 1.2 × 105 kg s−1. In situ sampling showed how fine ash mainly fell as aggregates of various typologies. About 5 to 9 wt % of the erupted mass remained in the cloud up to 1000 km from the vent, suggesting that nearly half of the ash 〉7 settled as aggregates within the first 60 km. Particle sphericity and shape factor varied between 0.4 and 1 with no clear correlation to the size and distance from vent. Our experiments also demonstrate how satellite retrievals and Doppler radar grain-size detection can provide a real-time description of the source term but for a limited particle-size range.
    Description: Published
    Description: B12202
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: MSG-SEVIRI, PLUDIX ; particle aggregation ; settling velocity ; tephra deposits ; weak plumes ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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    Contributions of different sea-level processes to high-tide flooding along the US coastline (2022)
    American Geophysical Union
    Details
    Publication Date: 2023-01-14
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 127(7), (2022): e2021JC018276, https://doi.org/10.1029/2021JC018276.
    Description: Coastal communities across the United States (U.S.) are experiencing an increase in the frequency of high-tide flooding (HTF). This increase is mainly due to sea-level rise (SLR), but other factors such as intra- to inter-annual mean sea level variability, tidal anomalies, and non-tidal residuals also contribute to HTF events. Here we introduce a novel decomposition approach to develop and then analyze a new database of different sea-level components. Those components represent processes that act on various timescales to contribute to HTF along the U.S. coastline. We find that the relative importance of components to HTF events strongly varies in space and time. Tidal anomalies contribute the most along the west and northeast coasts, where HTF events mostly occur in winter. Non-tidal residuals are most important along the Gulf of Mexico and mid-Atlantic coasts, where HTF events mostly occur in fall. We also quantify the minimum number of components that were required to cause HTF events in the past and how this number changed over time. The results highlight that at present, due to SLR, fewer components are needed to combine to push water levels above HTF thresholds, but tidal anomalies alone are still not sufficient to reach HTF thresholds in most locations. Finally, we explore how co-variability between different components leads to compounding effects. In some places, positive correlation between sea-level components leads to significantly more HTF events than would be expected if sea-level components were uncorrelated, whereas in other places negative correlation leads to fewer HTF events.
    Description: his work was supported by NASA's Sea Level Change Team award number 80NSSC20K1241. S.L. also acknowledges support by the China Scholarship Council (no. 201904910413) and the Ministry of Science and Technology of the People's Republic of China (grant no. 2011YQ120045).
    Description: 2023-01-14
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    Skillful long-lead prediction of summertime heavy rainfall in the US Midwest from sea surface salinity (2022)
    American Geophysical Union
    Details
    Publication Date: 2023-01-07
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(13), (2022): e2022GL098554, https://doi.org/10.1029/2022GL098554.
    Description: Summertime heavy rainfall and its resultant floods are among the most harmful natural hazards in the US Midwest, one of the world's primary crop production areas. However, seasonal forecasts of heavy rain, currently based on preseason sea surface temperature anomalies (SSTAs), remain unsatisfactory. Here, we present evidence that sea surface salinity anomalies (SSSAs) over the tropical western Pacific and subtropical North Atlantic are skillful predictors of summer time heavy rainfall one season ahead. A one standard deviation change in tropical western Pacific SSSA is associated with a 1.8 mm day−1 increase in local precipitation, which excites a teleconnection pattern to extratropical North Pacific. Via extratropical air-sea interaction and long memory of midlatitude SSTA, a wave train favorable for US Midwest heavy rain is induced. Combined with soil moisture feedbacks bridging the springtime North Atlantic salinity, the SSSA-based statistical prediction model improves Midwest heavy rainfall forecasts by 92%, complementing existing SSTA-based frameworks.
    Description: This study is supported by the NSF PREEVENTS program under ICER-1663138 (LL) and ICER-1663704 (RWS and CCU).
    Description: 2023-01-07
    Keywords: Sea surface salinity ; Midwest precipitation ; Heavy rainfall ; Long-lead prediction
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    Influence of kelp forest biomass on nearshore currents (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-12-24
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 127(7), (2022): e2021JC018333, https://doi.org/10.1029/2021JC018333.
    Description: As part of a project focused on the coastal fisheries of Isla Natividad, an island on the Pacific coast of Baja California, Mexico, we conducted a 2-1/2 year study of flows at two sites within the island's kelp forests. At one site (Punta Prieta), currents are tidal, whereas at the other site (Morro Prieto), currents are weaker and may be more strongly influenced by wind forcing. Satellite estimates of the biomass of the giant kelp (Macrocystis pyrifera) for this period varied between 0 (no kelp) and 3 kg/m2 (dense kelp forest), including a period in which kelp entirely was absent as a result of the 2014–2015 “Warm Blob” in the Eastern Pacific. During this natural “deforestation experiment”, alongshore velocities at both sites when kelp was present were substantially weaker than when kelp was absent, with low-frequency alongshore currents attenuated more than higher frequency ones, behavior that was the same at both sites despite differences in forcing. The attenuation of cross-shore flows by kelp was less than alongshore flows; thus, residence times for water inside the kelp forest, which are primarily determined by cross-shore velocities, were only weakly affected by the presence or absence of kelp. The flow changes we observed in response to changes in kelp density are important to the biogeochemical functioning of the kelp forest in that slower flows imply longer residence times, and, are also ecologically relevant in that reduced tidal excursions may lead to more localized recruitment of planktonic larvae.
    Description: The work we describe here was supported by NSF grants DEB 1212124, OCE 1416934, OCE 1736830, and OCE 2022927, by an equipment grant from the Kuwait Foundation for the Advancement of Sciences, and through grants from the Marisla Foundation, Packard Foundation, and Walton Family Foundation.
    Description: 2022-12-24
    Keywords: Kelp ; Tides ; Coastal circulation ; Mixing
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    Increasing inhomogeneity of the global ocean (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-12-23
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(12), (2022): e2021GL097598, https://doi.org/10.1029/2021GL097598.
    Description: The ocean is inhomogeneous in hydrographic properties with diverse water masses. Yet, how this inhomogeneity has evolved in a rapidly changing climate has not been investigated. Using multiple observational and reanalysis datasets, we show that the spatial standard deviation (SSD) of the global ocean has increased by 1.4 ± 0.1% in temperature and 1.5 ± 0.1% in salinity since 1960. A newly defined thermohaline inhomogeneity index, a holistic measure of both temperature and salinity changes, has increased by 2.4 ± 0.1%. Climate model simulations suggest that the observed ocean inhomogeneity increase is dominated by anthropogenic forcing and projected to accelerate by 200%–300% during 2015–2100. Geographically, the rapid upper-ocean warming at mid-to-low latitudes dominates the temperature inhomogeneity increase, while the increasing salinity inhomogeneity is mainly due to the amplified salinity contrast between the subtropical and subpolar latitudes.
    Description: This work is supported by the Strategic Priority Research Program of Chinese Academy of Sciences (grant XDB42000000 and XDB40000000), the National Key R&D Program of China (2017YFA0603200), and the Shandong Provincial Natural Science Foundation (ZR2020JQ17), and the U.S. National Science Foundation Physical Oceanography Program (OCE- 2048336).
    Description: 2022-12-23
    Keywords: Global ocean ; Temperature ; Salinity ; Spatial inhomogeneity ; Climate change
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    The role of wind stress in driving the along-shelf flow in the Northwest Atlantic Ocean (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-12-16
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 126(4), (2021): e2020JC016757, https://doi.org/10.1029/2020JC016757.
    Description: The along-shelf circulation in the Northwest Atlantic (NWA) Ocean is characterized by an equatorward flow from Greenland's south coast to Cape Hatters. The mean flow is considered to be primarily forced by freshwater discharges from rivers and glaciers while its variability is driven by both freshwater fluxes and wind stress. In this study, we hypothesize and test that the wind stress is important for the mean along-shelf flow. A two-layer model with realistic topography when forced by wind stress alone simulates a circulation system on the NWA shelves that is broadly consistent with that derived from observations, including an equatorward flow from Greenland coast to the Mid-Atlantic Bight (MAB). The along-shelf sea-level gradient is close to a previous estimate based on observations. The along-shelf flows exhibit strong seasonal variations with along-shelf transports being strong in fall/winter and weak in spring/summer, consistent with available observations. It is found that the NWA shelf circulation is affected by both wind-driven gyres through their western boundary currents and wind-stress forcing on the shelf especially along the coasts of Newfoundland and Labrador. The local wind stress forcing has more direct impacts on flows in shallower waters along the coast while the open-ocean gyres tend to affect the circulations along the outer shelf. Our conclusion is that wind stress is an important forcing of the main along-shelf flows in the NWA. One objective of this study is to motivate further examination of whether wind stress is as important as freshwater forcing for the mean flow.
    Description: Both Yang and Chen are also supported by NOAA Climate Program Office's Climate Variability and Prediction Program under grant NA20OAR4310398. JY is supported by Woods Hole Oceanographic Institution (WHOI) W. V. A. Clark Chair for Excellence in Oceanography and NSF Ocean Science Division under grant OCE1634886. Chen is supported by WHOI Independent Research and Development award.
    Description: 2021-09-30
    Keywords: Cross-shelf interactions ; Northwest Atlantic Ocean ; Numerical models ; Ocean dynamics ; Shelf flows ; Wind stress forcing
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    Closing the global marine Ra-226 budget reveals the biological pump as a dominant removal flux in the upper ocean (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-12-10
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(12), (2022): e2022GL098087, https://doi.org/10.1029/2022GL098087.
    Description: Radium isotopes are powerful proxies in oceanography and hydrology. Radium mass balance models, including assessments of submarine groundwater discharge (SGD), often overlook particle scavenging (PS) as a pathway for dissolved radium removal from the world ocean. Here, we build a global ocean 226Ra mass balance model and reevaluate the potential importance of PS. We find that PS is the major 226Ra sink for the upper ocean, removing about 96% of the total input from various sources. Aside from vertical exchange with the lower ocean, SGD is the largest 226Ra source into the upper ocean. The biological pump transfers particles to the deep ocean, resulting in a major but often overlooked impact on the global 226Ra marine budget. Our findings suggest that radium mass balance models should consider PS in systems with high siliceous algae production and export fluxes and long water residence times to prevent underestimation of large-scale SGD fluxes.
    Description: The authors are grateful to the many researchers and funding agencies responsible for the collection of data and quality control. The authors are very grateful to Jesus Gomez-Velez of Vanderbilt University for suggesting the statistical approach for distribution expansion and helping with the coding. The authors from Ocean University of China were funded by the Natural Science Foundation of China 41876075, 42130410, and 91958214, and Fundamental Research Funds for the Central Universities China 201962003 and 202072001. Funding for M.A.C. was provided by U.S. National Science Foundation OCE-1736277 and a WHOI-OUC Cooperative Research Initiative award. Valentí Rodellas acknowledges financial support from the Beatriu de Pinós postdoctoral programme of the Catalan Government (2019-BP-00241).
    Description: 2022-12-10
    Keywords: Particle scavenging ; Submarine groundwater discharge ; Siliceous algae ; Global ocean
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    Deep outer-rise faults in the Southern Mariana Subduction Zone indicated by a machine-learning-based high-resolution earthquake catalog (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-12-06
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(12), (2022): e2022GL097779, https://doi.org/10.1029/2022GL097779.
    Description: Outer-rise faults are predominantly concentrated near ocean trenches due to subducted plate bending. These faults play crucial roles in the hydration of subducted plates and the consequent subducting processes. However, it has not yet been possible to develop high-resolution structures of outer-rise faults due to the lack of near-field observations. In this study we deployed an ocean bottom seismometer (OBS) network near the Challenger Deep in the Southernmost Mariana Trench, between December 2016 and June 2017, covering both the overriding and subducting plates. We applied a machine-learning phase detector (EQTransformer) to the OBS data and found more than 1,975 earthquakes. An identified outer-rise event cluster revealed an outer-rise fault penetrating to depths of 50 km, which was inferred as a normal fault based on the extensional depth from tomographic images in the region, shedding new lights on water input at the southmost Mariana subduction zone.
    Description: This study is supported by National Natural Science Foundation of China (Nos. 91858207, 92158205, 41890813), Hong Kong Research Grant Council Grants (No. 14304820), Award from CORE (a joint research center for ocean research between QNLM and HKUST), Chinese Academy of Sciences (Nos. Y4SL021001, QYZDY-SSW-DQC005), and Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (No. GML2019ZD0205), Faculty of Science at CUHK.
    Description: 2022-12-06
    Keywords: Outer-rise fault ; Mariana Subduction Zone ; EQTransformer ; Ocean bottom seismometer
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    Increasing coral reef resilience through successive marine heatwaves (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-12-06
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 48(17), (2021): e2021GL094128, https://doi.org/10.1029/2021GL094128.
    Description: Ocean warming is causing declines of coral reefs globally, raising critical questions about the potential for corals to adapt. In the central equatorial Pacific, reefs persisting through recurrent El Niño heatwaves hold important clues. Using an 18-year record of coral cover spanning three major bleaching events, we show that the impact of thermal stress on coral mortality within the Phoenix Islands Protected Area (PIPA) has lessened over time. Disproportionate survival of extreme thermal stress during the 2009–2010 and 2015–2016 heatwaves, relative to that in 2002–2003, suggests that selective mortality through successive heatwaves may help shape coral community responses to future warming. Identifying and facilitating the conditions under which coral survival and recovery can keep pace with rates of warming are essential first steps toward successful stewardship of coral reefs under 21st century climate change.
    Description: Support was provided by the US National Science Foundation (NSF) 1737311 to A. L. Cohen; The Atlantic Donor Advised Fund to A. L. Cohen; a Woods Hole Oceanographic Institution post-doctoral scholarship to M. D. Fox; the Robertson Foundation, The Prince Albert Foundation, the New England Aquarium, and the Akiko Shiraki Dynner Fund.
    Keywords: Coral reefs ; Thermal stress ; ENSO ; Adaptation ; Oceanography ; Central Pacific
    Repository Name: Woods Hole Open Access Server
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    Krypton-81 dating constrains timing of deep groundwater flow activation (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-12-06
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(11), (2022): e2021GL097618, https://doi.org/10.1029/2021GL097618.
    Description: Krypton-81 dating provides new insights into the timing, mechanisms, and extent of meteoric flushing versus retention of saline fluids in the subsurface in response to changes in geologic and/or climatic forcings over 50 ka to 1.2 Ma year timescales. Remnant Paleozoic seawater-derived brines associated with evaporites in the Paradox Basin, Colorado Plateau, are beyond the 81Kr dating range (〉1.2 Ma) and have likely been preserved due to negative fluid buoyancy and low permeability. 81Kr dating of formation waters above the evaporites indicates topographically-driven meteoric recharge and salt dissolution since the Late Pleistocene (0.03–0.8 Ma). Formation waters below the evaporites (up to 3 km depth), in basal aquifers, contain relatively young meteoric water components (0.4–1.1 Ma based on 81Kr) that partially flushed remnant brines and dissolved evaporites. We demonstrate that recent, rapid denudation of the Colorado Plateau (〈4–10 Ma) activated deep, basinal-scale flow systems as recorded in 81Kr groundwater age distributions.
    Description: Funding for this research was provided by the W.M. Keck Foundation, CIFAR Earth 4D Subsurface Science and Exploration program, NSF EAR (#2120733), National Key Research and Development Program of China (Grant No. 2016YFA0302200), and National Natural Science Foundation of China (Grants No. 41727901). McIntosh and Ballentine are fellows of the CIFAR Earth4D Subsurface Science and Exploration program.
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    Formation of ionospheric irregularities over Southeast Asia during the 2015 St. Patrickˈs Day storm (2017)
    American Geophysical Union
    Details
    Publication Date: 2022-11-23
    Description: We investigate the geospace response to the 2015 St. Patrickˈs Day storm leveraging on instruments spread over Southeast Asia (SEA), covering a wide longitudinal sector of the low-latitude ionosphere. A regional characterization of the storm is provided, identifying the peculiarities of ionospheric irregularity formation. The novelties of this work are the characterization in a broad longitudinal range and the methodology relying on the integration of data acquired by Global Navigation Satellite System (GNSS) receivers, magnetometers, ionosondes, and Swarm satellites. This work is a legacy of the project EquatoRial Ionosphere Characterization in Asia (ERICA). ERICA aimed to capture the features of both crests of the equatorial ionospheric anomaly (EIA) and trough (EIT) by means of a dedicated measurement campaign. The campaign lasted from March to October 2015 and was able to observe the ionospheric variability causing effects on radio systems, GNSS in particular. The multiinstrumental and multiparametric observations of the region enabled an in-depth investigation of the response to the largest geomagnetic storm of the current solar cycle in a region scarcely reported in literature. Our work discusses the comparison between northern and southern crests of the EIA in the SEA region. The observations recorded positive and negative ionospheric storms, spread F conditions, scintillation enhancement and inhibition, and total electron content variability. The ancillary information on the local magnetic field highlights the variety of ionospheric perturbations during the different storm phases. The combined use of ionospheric bottomside, topside, and integrated information points out how the storm affects the F layer altitude and the consequent enhancement/suppression of scintillations.
    Description: Published
    Description: 12211–12233
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 2A. Fisica dell'alta atmosfera
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: 5IT. Osservazioni satellitari
    Description: JCR Journal
    Description: open
    Keywords: Saint Patrickˈs Day storm ; scintillation enhancement/suppression ; equatorial ionospheric anomaly ; positive and negative ionospheric storms ; spread F ; total electron content variability ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.02. Dynamics ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.07. Scintillations ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous ; 01. Atmosphere::01.03. Magnetosphere::01.03.02. Magnetic storms ; 01. Atmosphere::01.03. Magnetosphere::01.03.03. Magnetospheric physics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Shallow calcium carbonate cycling in the North Pacific Ocean (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-11-06
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 36(5), (2022): e2022GB007388, https://doi.org/10.1029/2022gb007388.
    Description: The cycling of biologically produced calcium carbonate (CaCO3) in the ocean is a fundamental component of the global carbon cycle. Here, we present experimental determinations of in situ coccolith and foraminiferal calcite dissolution rates. We combine these rates with solid phase fluxes, dissolved tracers, and historical data to constrain the alkalinity cycle in the shallow North Pacific Ocean. The in situ dissolution rates of coccolithophores demonstrate a nonlinear dependence on saturation state. Dissolution rates of all three major calcifying groups (coccoliths, foraminifera, and aragonitic pteropods) are too slow to explain the patterns of both CaCO3 sinking flux and alkalinity regeneration in the North Pacific. Using a combination of dissolved and solid-phase tracers, we document a significant dissolution signal in seawater supersaturated for calcite. Driving CaCO3 dissolution with a combination of ambient saturation state and oxygen consumption simultaneously explains solid-phase CaCO3 flux profiles and patterns of alkalinity regeneration across the entire N. Pacific basin. We do not need to invoke the presence of carbonate phases with higher solubilities. Instead, biomineralization and metabolic processes intimately associate the acid (CO2) and the base (CaCO3) in the same particles, driving the coupled shallow remineralization of organic carbon and CaCO3. The linkage of these processes likely occurs through a combination of dissolution due to zooplankton grazing and microbial aerobic respiration within degrading particle aggregates. The coupling of these cycles acts as a major filter on the export of both organic and inorganic carbon to the deep ocean.
    Description: This work was funded by NSF OCE-1220301 to W.B., NSF OCE-1220600 to J.F.A., and startup funding for A.V.S.
    Description: 2022-11-06
    Keywords: Calcium carbonate ; Dissolution ; Carbon cycle
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  • 43
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    Hydroacoustic monitoring of seafloor spreading and transform faulting in the equatorial Atlantic Ocean (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-11-04
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Parnell-Turner, R., Smith, D. K., & Dziak, R. P. Hydroacoustic monitoring of seafloor spreading and transform faulting in the equatorial Atlantic Ocean. Journal of Geophysical Research: Solid Earth, 127(7), (2022): e2022JB024008, https://doi.org/10.1029/2022JB024008.
    Description: Seismicity along mid-ocean ridges and oceanic transform faults provides insights into the processes of crustal accretion and strike-slip deformation. In the equatorial Atlantic ocean, the slow-spreading Mid-Atlantic Ridge is offset by some of the longest-offset transform faults on Earth, which remain relatively poorly understood due to its remote location far from land-based teleseismic receivers. A catalog of T-phase events detected by an array of 10 autonomous hydrophones deployed between 2011 and 2015, extending from 20°N to 10°S is presented. The final catalog of 6,843 events has a magnitude of completeness of 3.3, compared to 4.4 for the International Seismic Center teleseismic catalog covering the same region, and allows investigation of the dual processes of crustal accretion and transform fault slip. The seismicity rate observed at asymmetric spreading segments (those hosting detachment faults) is significantly higher than that of symmetric spreading centers, and 74% of known hydrothermal vents along the equatorial Mid-Atlantic Ridge occur on asymmetric spreading segments. Aseismic patches are present on nearly all equatorial Atlantic transform faults, including on the Romanche transform where regional rotation and transpression could explain both bathymetric uplift and reduction in seismic activity. The observed patterns in seismicity provide insight into the thermal and mechanical structure of the ridge axis and associated transform faults, and potentially provide a method for investigating the distribution of hydrothermal vent systems.
    Description: This research was supported by National Science Foundation Grants EAR-1062238, EAR-1062165, and OCE-1839727. This paper is NOAA Pacific Marine Environmental Laboratory contribution 5323.
    Keywords: Mid-ocean ridge ; Oceanic transform fault ; T-phase ; Earthquake ; Hydrothermal vent
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    A century of observed temperature change in the Indian Ocean (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-11-04
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Wenegrat, J. O., Bonanno, E., Rack, U., & Gebbie, G. A century of observed temperature change in the Indian Ocean. Geophysical Research Letters, 49(13), (2022): e2022GL098217, https://doi.org/10.1029/2022GL098217.
    Description: The Indian Ocean is warming rapidly, with widespread effects on regional weather and global climate. Sea-surface temperature records indicate this warming trend extends back to the beginning of the 20th century, however the lack of a similarly long instrumental record of interior ocean temperatures leaves uncertainty around the subsurface trends. Here we utilize unique temperature observations from three historical German oceanographic expeditions of the late 19th and early 20th centuries: SMS Gazelle (1874–1876), Valdivia (1898–1899), and SMS Planet (1906–1907). These observations reveal a mean 20th century ocean warming that extends over the upper 750 m, and a spatial pattern of subsurface warming and cooling consistent with a 1°–2° southward shift of the southern subtropical gyre. These interior changes occurred largely over the last half of the 20th century, providing observational evidence for the acceleration of a multidecadal trend in subsurface Indian Ocean temperature.
    Description: GG is supported by U.S. NSF-OCE 82280500.
    Keywords: Historical temperature observations ; Indian Ocean ; Ocean warming ; Ocean heat content ; Antarctic circumpolar current
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  • 45
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    Fluid‐mediated mass transfer between mafic and ultramafic rocks in subduction zones (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-11-04
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Codillo, E., Klein, F., Dragovic, B., Marschall, H., Baxter, E., Scambelluri, M., & Schwarzenbach‬, E. Fluid‐mediated mass transfer between mafic and ultramafic rocks in subduction zones. Geochemistry Geophysics Geosystems, 23, (2022): e2021GC010206, https://doi.org/10.1029/2021gc010206.
    Description: Metasomatic reaction zones between mafic and ultramafic rocks exhumed from subduction zones provide a window into mass-transfer processes at high pressure. However, accurate interpretation of the rock record requires distinguishing high-pressure metasomatic processes from inherited oceanic signatures prior to subduction. We integrated constraints from bulk-rock geochemical compositions and petrophysical properties, mineral chemistry, and thermodynamic modeling to understand the formation of reaction zones between juxtaposed metagabbro and serpentinite as exemplified by the Voltri Massif (Ligurian Alps, Italy). Distinct zones of variably metasomatized metagabbro are dominated by chlorite, amphibole, clinopyroxene, epidote, rutile, ilmenite, and titanite between serpentinite and eclogitic metagabbro. Whereas the precursor serpentinite and oxide gabbro formed and were likely already in contact in an oceanic setting, the reaction zones formed by diffusional Mg-metasomatism between the two rocks from prograde to peak, to retrograde conditions in a subduction zone. Metasomatism of mafic rocks by Mg-rich fluids that previously equilibrated with serpentinite could be widespread along the subduction interface, within the subducted slab, and the mantle wedge. Furthermore, the models predict that talc formation by Si-metasomatism of serpentinite in subduction zones is limited by pressure-dependent increase in the silica activity buffered by the serpentine-talc equilibrium. Elevated activities of aqueous Ca and Al species would also favor the formation of chlorite and garnet. Accordingly, unusual conditions or processes would be required to stabilize abundant talc at high P-T conditions. Alternatively, a different set of mineral assemblages, such as serpentine- or chlorite-rich rocks, may be controlling the coupling-decoupling transition of the plate interface.
    Description: M. Scambelluri acknowledges the Italian Ministry of Research MUR for granting the PRIN project n. 2017ZE49E7. This research was funded by NSF-OISE (Office of International Science & Engineering, Petrology & Geochemistry) PIRE, Award #1545903, and the WHOI Ocean Ventures Fund.
    Keywords: Fluid-rock interactions ; Magnesium metasomatism ; Subduction zones ; Voltri Massif
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    The roles of heat and gas in a mushy magma chamber (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-11-03
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 127(7),(2022): e2022JB024357, https://doi.org/10.1029/2022jb024357.
    Description: Crustal magmatic systems likely consist of magmatic reservoirs dominated by crystal mush. Recent studies suggest that the physical processes occurring in crystal mush could alter the response of magmatic reservoirs during volcanic unrest. Here, we present a magma chamber deformation model that incorporates two new aspects in crystal mush: heat and exsolved gas. The model is based on earlier studies by Liao et al. (2021, https://doi.org/10.1029/2020JB019395) with additional processes including thermal-mechanical coupling, dependence of material properties on gas content, and temperature evolution following an injection of hotter magma. The post-injection time-dependent evolution of the system can be grouped into three periods, which are dominated by poroelastic diffusion (short term), viscoelastic relaxation (mid term), and thermal equilibration (long term). All three time-regimes are strongly affected by gas distribution, which alters the relative compressibility of the crystal-rich and crystal-poor regions in the chamber. The contribution of thermal evolution emerges during the mid-term evolution. The time-dependent evolution of the system highlights the intrinsic ability of a gas-bearing mushy magma chamber to generate non-monotonic time series of stresses, deformation, and magma transport.
    Keywords: Crystal mush ; Magma chamber ; Exsolved volatiles
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    Xenon hydrate as an analog of methane hydrate in geologic systems out of thermodynamic equilibrium (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(5), (2019):2462-2472, doi:10.1029/2019GC008250.
    Description: Methane hydrate occurs naturally under pressure and temperature conditions that are not straightforward to replicate experimentally. Xenon has emerged as an attractive laboratory alternative to methane for studying hydrate formation and dissociation in multiphase systems, given that it forms hydrates under milder conditions. However, building reliable analogies between the two hydrates requires systematic comparisons, which are currently lacking. We address this gap by developing a theoretical and computational model of gas hydrates under equilibrium and nonequilibrium conditions. We first compare equilibrium phase behaviors of the Xe·H2O and CH4·H2O systems by calculating their isobaric phase diagram, and then study the nonequilibrium kinetics of interfacial hydrate growth using a phase field model. Our results show that Xe·H2O is a good experimental analog to CH4·H2O, but there are key differences to consider. In particular, the aqueous solubility of xenon is altered by the presence of hydrate, similar to what is observed for methane; but xenon is consistently less soluble than methane. Xenon hydrate has a wider nonstoichiometry region, which could lead to a thicker hydrate layer at the gas‐liquid interface when grown under similar kinetic forcing conditions. For both systems, our numerical calculations reveal that hydrate nonstoichiometry coupled with hydrate formation dynamics leads to a compositional gradient across the hydrate layer, where the stoichiometric ratio increases from the gas‐facing side to the liquid‐facing side. Our analysis suggests that accurate composition measurements could be used to infer the kinetic history of hydrate formation in natural settings where gas is abundant.
    Description: This work was funded in part by the U.S. Department of Energy, DOE [awards DE‐FE0013999 and DE‐SC0018357 (to R. J.) and DOE Interagency Agreement DE‐FE0023495 (to W. F. W.)]. X. F. acknowledges support by the Miller Research Fellowship at the University of California Berkeley. W. F. W. acknowledges support from the U.S. Geological Survey's Gas Hydrate Project and the Survey's Coastal, Marine Hazards and Resources Program. L. C. F. acknowledges funding from the Spanish Ministry of Economy and Competitiveness (grants RYC‐2012‐11704 and CTM2014‐54312‐P). L. C. F. and R. J. acknowledge funding from the MIT International Science and Technology Initiatives, through a Seed Fund grant. The simulation data are available on the UC Berkeley Dash repository at https://doi.org/10.6078/D1G67B.
    Description: 2019-11-06
    Keywords: Methane hydrates ; Xenon hydrates ; Phase behavior ; Growth kinetics ; Nonstoichiometry
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  • 48
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    Nitrogen cycle patterns during forest regrowth in an African Miombo woodland landscape (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Biogeosciences, 124(6), (2019): 1591-1603, doi:10.1029/2018JG004803.
    Description: Tropical dry forests in eastern and southern Africa cover 2.5 × 106 km2, support wildlife habitat and livelihoods of more than 150 million people, and face threats from land use and climate change. To inform conservation, we need better understanding of ecosystem processes like nutrient cycling that regulate forest productivity and biomass accumulation. Here we report on patterns in nitrogen (N) cycling across a 100‐year forest regrowth chronosequence in the Tanzanian Miombo woodlands. Soil and vegetation indicators showed that low ecosystem N availability for trees persisted across young to mature forests. Ammonium dominated soil mineral N pools from 0‐ to 15‐cm depth. Laboratory‐measured soil N mineralization rates across 3‐ to 40‐year regrowth sites showed no significant trends and were lower than mature forest rates. Aboveground tree N pools increased at 6 to 7 kg N·ha−1·yr−1, accounting for the majority of ecosystem N accumulation. Foliar δ15N 〈0‰ in an N‐fixing canopy tree across all sites suggested that N fixation may contribute to ecosystem N cycle recovery. These results contrast N cycling in wetter tropical and Neotropical dry forests, where indicators of N scarcity diminish after several decades of regrowth. Our findings suggest that minimizing woody biomass removal, litter layer, and topsoil disturbance may be important to promote N cycle recovery and natural regeneration in Miombo woodlands. Higher rates of N mineralization in the wet season indicated a potential that climate change‐altered rainfall leading to extended dry periods may lower N availability through soil moisture‐dependent N mineralization pathways, particularly for mature forests.
    Description: This study depended on the knowledge, insights, and cooperation of many people and institutions. We thank the Millennium Villages Project‐Mbola site for providing introductions to the landscape and village headmen in many regions. We thank the ARI‐Tumbi staff (now TARI‐Tumbi) in Tabora, Tanzania for providing invaluable logistical support in identifying forest regrowth sites and help with labwork in Tabora, Tanzania. We thank other key local organizations, including Tabora Development Foundation Trust (Dick Mlimuka, Oscar Kisanji) and Tanzania Forest Service (Bw. Relingo), for logistical support and transportation. We thank many village headmen and farmers for access to forest sites within their lands for sampling. Finally, we would like to thank the MBL Stable Isotope laboratory and Dr. Marshall Otter for his expertise with producing and interpreting soil and leaf C, N and stable isotope data. This study was funded in part by NSF PIRE Grant OISE 0968211, a Dissertation Support Grant to Marc Mayes from Brown University (2015–2016), and completed with permission and cooperation from the Tanzania Commission on Science and Technology (COSTECH permits 2013‐261‐NA‐2014‐199 and 2015‐183‐ER‐2014‐199). Data and code for analyses can be accessed at a Github repository: https://github.com/mtm17/MiomboN.git.
    Description: 2019-11-08
    Keywords: Nitrogen ; Africa ; Miombo ; Tropical dry forest ; Carbon ; Secondary forest regrowth
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  • 49
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    Mature diffuse tectonic block boundary revealed by the 2020 southwestern Puerto Rico seismic sequence (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: This paper is not subject to U.S. copyright. The definitive version was published in ten Brink, U. S., Vanacore, E. A., Fielding, E. J., Chaytor, J. D., Lopez-Venegas, A. M., Baldwin, W. E., Foster, D. S., & Andrews, B. D. Mature diffuse tectonic block boundary revealed by the 2020 southwestern Puerto Rico seismic sequence. Tectonics, 41(3), (2022): e2021TC006896, https://doi.org/10.1029/2021TC006896.
    Description: Distributed faulting typically tends to coalesce into one or a few faults with repeated deformation. The progression of clustered medium-sized (≥Mw4.5) earthquakes during the 2020 seismic sequence in southwestern Puerto Rico (SWPR), modeling shoreline subsidence from InSAR, and sub-seafloor mapping by high-resolution seismic reflection profiles, suggest that the 2020 SWPR seismic sequence was distributed across several short intersecting strike-slip and normal faults beneath the insular shelf and upper slope of Guayanilla submarine canyon. Multibeam bathymetry map of the seafloor shows significant erosion and retreat of the shelf edge in the area of seismic activity as well as slope-parallel lineaments and submarine canyon meanders that typically develop over geological time. The T-axis of the moderate earthquakes further matches the extension direction previously measured on post early Pliocene (∼〉3 Ma) faults. We conclude that although similar deformation has likely taken place in this area during recent geologic time, it does not appear to have coalesced during this time. The deformation may represent the southernmost part of a diffuse boundary, the Western Puerto Rico Deformation Boundary, which accommodates differential movement between the Puerto Rico and Hispaniola arc blocks. This differential movement is possibly driven by the differential seismic coupling along the Puerto Rico—Hispaniola subduction zone. We propose that the compositional heterogeneity across the island arc retards the process of focusing the deformation into a single fault. Given the evidence presented here, we should not expect a single large event in this area but similar diffuse sequences in the future.
    Description: 2022-08-08
    Keywords: Rupture of multiple faults ; Intra-arc deformation ; Earthquake-generated submarine canyon ; Anisotropic arc composition ; Caribbean seismic hazard
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    Dynamics of marsh-derived sediments in lagoon-type estuaries (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Donatelli, C., Kalra, T. S., Fagherazzi, S., Zhang, X., & Leonardi, N. Dynamics of marsh-derived sediments in lagoon-type estuaries. Journal of Geophysical Research: Earth Surface, 125(12), (2020): e2020JF005751, doi:10.1029/2020JF005751.
    Description: Salt marshes are valuable ecosystems that must trap sediments and accrete in order to counteract the deleterious effect of sea level rise. Previous studies have shown that the capacity of marshes to build up vertically depends on both autogenous and exogenous processes including ecogeomorphic feedbacks and sediment supply from in‐land and coastal ocean. There have been numerous efforts to quantify the role played by the sediments coming from marsh edge erosion on the resistance of salt marshes to sea level rise. However, the majority of existing studies investigating the interplay between lateral and vertical dynamics use simplified modeling approaches, and they do not consider that marsh retreat can affect the regional‐scale hydrodynamics and sediment retention in back‐barrier basins. In this study, we evaluated the fate of the sediments originating from marsh lateral loss by using high‐resolution numerical model simulations of Jamaica Bay, a small lagoonal estuary located in New York City. Our findings show that up to 42% of the sediment released during marsh edge erosion deposits on the shallow areas of the basin and over the vegetated marsh platforms, contributing positively to the sediment budget of the remaining salt marshes. Furthermore, we demonstrate that with the present‐day sediment supply from the ocean, the system cannot keep pace with sea level rise even accounting for the sediment liberated in the bay through marsh degradation. Our study highlights the relevance of multiple sediment sources for the maintenance of the marsh complex.
    Description: This study was supported by the Department of the Interior Hurricane Sandy Recovery program (ID G16AC00455, subaward to University of Liverpool). S. F. was partly supported by NSF awards 1637630 (PIE LTER) and 1832221 (VCR LTER). We thank Robert Chant from Rutgers University for sharing the hydrodynamic measurements in Jamaica Bay.
    Keywords: Marsh erosion ; Sediment recycling ; Sea level rise ; Jamaica Bay
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    Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ruppel, C. D., & Waite, W. F. Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems. Journal of Geophysical Research: Solid Earth, 125(8), (2020): e2018JB016459, doi:10.1029/2018JB016459.
    Description: Gas hydrate is an ice‐like form of water and low molecular weight gas stable at temperatures of roughly −10°C to 25°C and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one sixth of Earth's methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean‐atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean‐atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth's near‐surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some field studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.
    Description: Both authors have received nearly two decades of support from the U.S. Geological Survey's (USGS's) Energy Resources Program and the Coastal/Marine Hazards and Resources Program and from numerous DOE‐USGS Interagency Agreements, most recently DE‐FE0023495. C. R. acknowledges support from NOAA's Office of Ocean Exploration and Research (OER) under NOAA‐USGS Interagency Agreement 16‐01118.
    Keywords: Gas hydrate ; Hydrate breakdown ; Hydrate formation ; Permafrost hydrate ; Geologic systems ; Marine hydrate
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    Emerging wetlands from river diversions can sustain high denitrification rates in a Coastal Delta (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 126(5), (2021): e2020JG006217, https://doi.org/10.1029/2020JG006217.
    Description: It is assumed that to treat excess NO3− high soil organic matter content (%OM) is required to maintain high denitrification rates in natural or restored wetlands. However, this excess also represents a risk by increasing soil decomposition rates triggering peat collapse and wetland fragmentation. Here, we evaluated the role of %OM and temperature interactions controlling denitrification rates in eroding (Barataria Bay-BLC) and emerging (Wax Lake Delta-WLD) deltaic regions in coastal Louisiana using the isotope pairing (IPT) and N2:Ar techniques. We also assessed differences between total (direct denitrification + coupled nitrification-denitrification) and net (total denitrification minus nitrogen fixation) denitrification rates in benthic and wetland habitats with contrasting %OM and bulk density (BD). Sediment (benthic) and soil (wetland) cores were collected during summer, spring, and winter (2015–2016) and incubated at close to in-situ temperatures (30°C, 20°C, and 10°C, respectively). Denitrification rates were linearly correlated with temperature; maximum mean rates ranged from 40.1–124.1 μmol m−2 h−1 in the summer with lower rates (〈26.2 ± 5.3 μmol m−2 h−1) in the winter seasons. Direct denitrification was higher than coupled denitrification in all seasons. Denitrification rates were higher in WLD despite lower %OM, lower total N concentration, and higher BD in wetland soils. Therefore, in environments with low carbon availability, high denitrification rates can be sustained as long as NO3− concentrations are high (〉30 μM) and water temperature is 〉10°C. In coastal Louisiana, substrates under these regimes are represented by emergent supra-tidal flats or land created by sediment diversions under oligohaline conditions (〈1 ppt).
    Description: This study was supported by the NOAA-Sea Grant Program-Louisiana (Grant 2013R/E-24) to Victor H. Rivera-Monroy and Kanchan Maiti. Victor H. Rivera-Monroy was also supported by the Department of the Interior South-Central Climate Adaptation Science Center (Cooperative Agreement #G12AC00002).
    Keywords: Coastal Louisiana ; Deltaic system ; Denitrification ; Nitrate loading ; Organic matter ; Seasonal change ; Sediment and freshwater diversions
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    Modeling the dynamics of salt marsh development in coastal land reclamation (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(6), (2022): e2021GL095559, https://doi.org/10.1029/2021GL095559.
    Description: The valuable ecosystem services of salt marshes are spurring marsh restoration projects around the world. However, it is difficult to determine the final vegetated area based on physical drivers. Herein, we use a 3D fully coupled vegetation-hydrodynamic-morphological modeling system to simulate the final vegetation cover and the timescale to reach it under various forcing conditions. Marsh development in our simulations can be divided in three distinctive phases: A preparation phase characterized by sediment accumulation in the absence of vegetation, an encroachment phase in which the vegetated area grows, and an adjustment phase in which the vegetated area remains relatively constant while marsh accretes vertically to compensate for sea level rise. Sediment concentration, settling velocity, sea level rise, and tidal range each comparably affect equilibrium coverage and timescale in different ways. Our simulations show that the Unvegetated-Vegetated Ratio also relates to sediment budget in marsh development under most conditions.
    Description: This study was supported by the Department of the Interior Hurricane Sandy Recovery program (ID G16AC00455), NSF awards 1637630 (PIE LTER) and 1832221 (VCR LTER), and China Scholarship Council.
    Description: 2022-09-16
    Keywords: Marsh restoration ; Land reclamation ; COAWST ; Vegetation dynamics ; Phases of marsh development ; Expectance of marsh coverage
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  • 54
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    Introduction to special issue on gas hydrate in porous media: linking laboratory and field-scale phenomena (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124(8), (2019): 7525-7537, doi: 10.1029/2019JB018186.
    Description: The proliferation of drilling expeditions focused on characterizing natural gas hydrate as a potential energy resource has spawned widespread interest in gas hydrate reservoir properties and associated porous media phenomena. Between 2017 and 2019, a Special Section of this journal compiled contributed papers elucidating interactions between gas hydrate and sediment based on laboratory, numerical modeling, and field studies. Motivated mostly by field observations in the northern Gulf of Mexico and offshore Japan, several papers focus on the mechanisms for gas hydrate formation and accumulation, particularly with vapor phase gas, not dissolved gas, as the precursor to hydrate. These studies rely on numerical modeling or laboratory experiments using sediment packs or benchtop micromodels. A second focus of the Special Section is the role of fines in inhibiting production of gas from methane hydrate, controlling the distribution of hydrate at a pore scale, and influencing the bulk behavior of seafloor sediments. Other papers fill knowledge gaps related to the physical properties of hydrate‐bearing sediments and advance new approaches in coupled thermal‐mechanical modeling of these sediments during hydrate dissociation. Finally, one study addresses the long‐standing question about the fate of methane hydrate at the molecular level when CO2 is injected into natural reservoirs under hydrate‐forming conditions.
    Description: C. R. was supported by the U.S. Geological Survey's Energy Resources Program and the Coastal/Marine Hazards and Resources Program, as well as by DOE Interagency Agreement DE‐FE0023495. C. R. thanks W. Waite and J. Jang for discussions and suggestions that improved this paper and L. Stern for a helpful review. J. Y. Lee was supported by the Ministry of Trade, Industry, and Energy (MOTIE) through the Project “Gas Hydrate Exploration and Production Study (19‐1143)” under the management of the Gas Hydrate Research and Development Organization (GHDO) of Korea and the Korea Institute of Geoscience and Mineral Resources (KIGAM). Any use of trade, firm, or product name is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Keywords: Gas hydrate ; Methane ; Reservoir properties ; Multiphase flow
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  • 55
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    Surface methane concentrations along the mid-Atlantic bight driven by aerobic subsurface production rather than seafloor gas seeps. (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015989, doi:10.1029/2019JC015989.
    Description: Relatively minor amounts of methane, a potent greenhouse gas, are currently emitted from the oceans to the atmosphere, but such methane emissions have been hypothesized to increase as oceans warm. Here, we investigate the source, distribution, and fate of methane released from the upper continental slope of the U.S. Mid‐Atlantic Bight, where hundreds of gas seeps have been discovered between the shelf break and ~1,600 m water depth. Using physical, chemical, and isotopic analyses, we identify two main sources of methane in the water column: seafloor gas seeps and in situ aerobic methanogenesis which primarily occurs at 100–200 m depth in the water column. Stable isotopic analyses reveal that water samples collected at all depths were significantly impacted by aerobic methane oxidation, the dominant methane sink in this region, with the average fraction of methane oxidized being 50%. Due to methane oxidation in the deeper water column, below 200 m depth, surface concentrations of methane are influenced more by methane sources found near the surface (0–10 m depth) and in the subsurface (10–200 m depth), rather than seafloor emissions at greater depths.
    Description: This research was supported by DOE Grant (DE‐FE0028980) to J. K. and by DOE‐USGS Interagency Agreement DE‐FE0026195.
    Description: 2020-10-04
    Keywords: Methane ; Ocean ; Isotopes ; Gas seeps ; Mid Atlantic bight ; Oxidation
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  • 56
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    Enhanced carbon uptake and reduced methane emissions in a newly restored wetland (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005222, doi:10.1029/2019JG005222.
    Description: Wetlands play an important role in reducing global warming potential in response to global climate change. Unfortunately, due to the effects of human disturbance and natural erosion, wetlands are facing global extinction. It is essential to implement engineering measures to restore damaged wetlands. However, the carbon sink capacity of restored wetlands is unclear. We examined the seasonal change of greenhouse gas emissions in both restored wetland and natural wetland and then evaluated the carbon sequestration capacity of the restored wetland. We found that (1) the carbon sink capacity of the restored wetland showed clear daily and seasonal change, which was affected by light intensity, air temperature, and vegetation growth, and (2) the annual daytime (8–18 hr) sustained‐flux global warming potential was −11.23 ± 4.34 kg CO2 m−2 y−1, representing a much larger carbon sink than natural wetland (−5.04 ± 3.73 kg CO2 m−2 y−1) from April to December. In addition, the results showed that appropriate tidal flow management may help to reduce CH4 emission in wetland restoration. Thus, we proposed that the restored coastal wetland, via effective engineering measures, reliably acted as a large net carbon sink and has the potential to help mitigate climate change.
    Description: We would like to thank Yangtze Delta Estuarine Wetland Ecosystem Ministry of Education & Shanghai Observation and Research Station for providing sites during our research. This research was supported by the National Key Research and Development Program of China (Grant 2017YFC0506002), the National Natural Science Foundation of China Overseas and Hong Kong‐Macao Scholars Collaborative Research Fund (Grant 31728003), the China Postdoctoral Science Foundation (Grant 2018M640362), the Shanghai University Distinguished Professor (Oriental Scholars) Program (Grant JZ2016006), the Open Fund of Shanghai Key Lab for Urban Ecological Processes and Eco‐Restoration (Grant SHUES2018B06), and the Scientific Projects of Shanghai Municipal Oceanic Bureau (Grant 2018‐03). The complete data set is available at https://data.4tu.nl/repository/uuid:536b2614‐c4ca‐43d2‐84dd‐6180fd859544.
    Keywords: Blue carbon ; Restored wetland ; Sustained‐flux global warming potential (SGWP) ; Greenhouse gas (GHG) ; Carbon sequestration capacity
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  • 57
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    Sediment delivery to a tidal marsh platform is minimized by source decoupling and flux convergence (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 125(8),(2020): e2020JF005558, doi:10.1029/2020JF005558.
    Description: Sediment supply is a primary factor in determining marsh response to sea level rise and is typically approximated through high‐resolution measurements of suspended sediment concentrations (SSCs) from adjacent tidal channels. However, understanding sediment transport across the marsh itself remains limited by discontinuous measurements of SSC over individual tidal cycles. Here, we use an array of optical turbidity sensors to build a long‐term, continuous record of SSC across a marsh platform and adjacent tidal channel. We find that channel and marsh concentrations are correlated (i.e., coupled) within tidal cycles but are largely decoupled over longer time scales. We also find that net sediment fluxes decline to near zero within 10 m of the marsh edge. Together, these results suggest that large sections of the marsh platform receive minimal sediment independent of flooding frequency or channel sediment supply. Marsh‐centric, as opposed to channel‐centric, measures of sediment supply may better characterize marsh platform vulnerability.
    Description: This work was funded by NSF Awards 1529245, 1654374, 1426981, 1637630, and 1832221, the NSF Graduate Research Fellowship Program, and the USGS Climate and Land Use Research and Development program. We thank D. Walters, J. Himmelstein, D. Nicks, R. Walker, T. Messerschmidt, and the Plum Island Ecosystems LTER, especially S. Kelsey for laboratory and field assistance. Additionally, we thank C. Friedrichs, G. Guntenspergen, and O. Duran Vinent for contributing ideas that helped develop the work, and the reviewers who helped improve the manuscript. This work is Contribution Number 3928 of the Virginia Institute of Marine Science. In memoriam of David Nicks.
    Description: 2021-01-27
    Keywords: Salt marsh ; Sediment transport ; Turbidity ; Flux convergence ; Decoupling
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    Focused fluid flow along the Nootka fault zone and continental slope, explorer-Juan de Fuca Plate Boundary (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Riedel, M., Rohr, K. M. M., Spence, G. D., Kelley, D., Delaney, J., Lapham, L., Pohlman, J. W., Hyndman, R. D., & Willoughby, E. C. Focused fluid flow along the Nootka fault zone and continental slope, explorer-Juan de Fuca Plate Boundary. Geochemistry Geophysics Geosystems, 21(8), (2020): e2020GC009095, doi:10.1029/2020GC009095.
    Description: Geophysical and geochemical data indicate there is abundant fluid expulsion in the Nootka fault zone (NFZ) between the Juan de Fuca and Explorer plates and the Nootka continental slope. Here we combine observations from 〉20 years of investigations to demonstrate the nature of fluid‐flow along the NFZ, which is the seismically most active region off Vancouver Island. Seismicity reaching down to the upper mantle is linked to near‐seafloor manifestation of fluid flow through a network of faults. Along the two main fault traces, seismic reflection data imaged bright spots 100–300 m below seafloor that lie above changes in basement topography. The bright spots are conformable to sediment layering, show opposite‐to‐seafloor reflection polarity, and are associated with frequency reduction and velocity push‐down indicating the presence of gas in the sediments. Two seafloor mounds ~15 km seaward of the Nootka slope are underlain by deep, nonconformable high‐amplitude reflective zones. Measurements in the water column above one mound revealed a plume of warm water, and bottom‐video observations imaged hydrothermal vent system biota. Pore fluids from a core at this mound contain predominately microbial methane (C1) with a high proportion of ethane (C2) yielding C1/C2 ratios 〈500 indicating a possible slight contribution from a deep source. We infer the reflective zones beneath the two mounds are basaltic intrusions that create hydrothermal circulation within the overlying sediments. Across the Nootka continental slope, gas hydrate‐related bottom‐simulating reflectors are widespread and occur at depths indicating heat flow values of 80–90 mW/m2.
    Description: This study represents data from numerous cruises acquired over more than two decades. We would like to thank all the scientific personnel and technical staff involved in data acquisition, processing of samples, and making observations during the ROV dives, as well as the crews and captains of the various research vessels involved. This is contribution #5877 from the University of Maryland Center for Environmental Science. This is NRCan contribution number / Numéro de contribution de RNCan: 20200324.
    Keywords: Fluid flow ; Nootka transform fault ; Gas hydrate ; Intrusion ; Heat flow
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    Submarine permafrost map in the arctic modeled using 1-D transient heat flux (SuPerMAP) (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(6), (2019): 3490-3507, doi:10.1029/2018JC014675.
    Description: Offshore permafrost plays a role in the global climate system, but observations of permafrost thickness, state, and composition are limited to specific regions. The current global permafrost map shows potential offshore permafrost distribution based on bathymetry and global sea level rise. As a first‐order estimate, we employ a heat transfer model to calculate the subsurface temperature field. Our model uses dynamic upper boundary conditions that synthesize Earth System Model air temperature, ice mass distribution and thickness, and global sea level reconstruction and applies globally distributed geothermal heat flux as a lower boundary condition. Sea level reconstruction accounts for differences between marine and terrestrial sedimentation history. Sediment composition and pore water salinity are integrated in the model. Model runs for 450 ka for cross‐shelf transects were used to initialize the model for circumarctic modeling for the past 50 ka. Preindustrial submarine permafrost (i.e., cryotic sediment), modeled at 12.5‐km spatial resolution, lies beneath almost 2.5 ×106km2 of the Arctic shelf. Our simple modeling approach results in estimates of distribution of cryotic sediment that are similar to the current global map and recent seismically delineated permafrost distributions for the Beaufort and Kara seas, suggesting that sea level is a first‐order determinant for submarine permafrost distribution. Ice content and sediment thermal conductivity are also important for determining rates of permafrost thickness change. The model provides a consistent circumarctic approach to map submarine permafrost and to estimate the dynamics of permafrost in the past.
    Description: Boundary condition data are available online via the sources referenced in the manuscript. This work was partially funded by a Helmholtz Association of Research Centres (HGF) Joint Russian‐German Research Group (HGF JRG 100). This study is part of a project that has received funding from the European Unions Horizon 2020 research and innovation program under grant agreement 773421. Submarine permafrost studies in the Kara and Laptev Seas were supported by Russian Foundation for Basic Research (RFBR/RFFI) grants 18‐05‐60004 and 18‐05‐70091, respectively. The International Permafrost Association (IPA) and the Association for Polar Early Career Scientists (APECS) supported research coordination that led to this study. We acknowledge coordination support of the World Climate Research Programme (WCRP) through their core project on Climate and Cryosphere (CliC). Thanks to Martin Jakobsson for providing a digitized version of the preliminary IHO delineation of the Arctic seas and to Guy Masters for access to the observational geothermal database. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Description: 2019-10-17
    Keywords: Submarine permafrost ; Arctic ; Cryosphere ; Sea level
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    Estimating the impact of seep methane oxidation on ocean pH and dissolved inorganic radiocarbon along the US Mid-Atlantic Bight (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 126(1), (2021): e2019JG005621, https://doi.org/10.1029/2019JG005621.
    Description: Ongoing ocean warming can release methane (CH4) currently stored in ocean sediments as free gas and gas hydrates. Once dissolved in ocean waters, this CH4 can be oxidized to carbon dioxide (CO2). While it has been hypothesized that the CO2 produced from aerobic CH4 oxidation could enhance ocean acidification, a previous study conducted in Hudson Canyon shows that CH4 oxidation has a small short‐term influence on ocean pH and dissolved inorganic radiocarbon. Here we expand upon that investigation to assess the impact of widespread CH4 seepage on CO2 chemistry and possible accumulation of this carbon injection along 234 km of the U.S. Mid‐Atlantic Bight. Consistent with the estimates from Hudson Canyon, we demonstrate that a small fraction of ancient CH4‐derived carbon is being assimilated into the dissolved inorganic radiocarbon (mean fraction of 0.5 ± 0.4%). The areas with the highest fractions of ancient carbon coincide with elevated CH4 concentration and active gas seepage. This suggests that aerobic CH4 oxidation has a greater influence on the dissolved inorganic pool in areas where CH4 concentrations are locally elevated, instead of displaying a cumulative effect downcurrent from widespread groupings of CH4 seeps. A first‐order approximation of the input rate of ancient‐derived dissolved inorganic carbon (DIC) into the waters overlying the northern U.S. Mid‐Atlantic Bight further suggests that oxidation of ancient CH4‐derived carbon is not negligible on the global scale and could contribute to deepwater acidification over longer time scales.
    Description: This study was sponsored by U.S. Department of Energy (DE‐FE0028980, awarded to J. D. K; DE‐FE0026195 interagency agreement with C. D. R.). We thank the crew of the R/V Hugh R. Sharp for their support, G. Hatcher, J. Borden, and M. Martini of the USGS for assistance with the LADCP, and Zach Bunnell, Lillian Henderson, and Allison Laubach for additional support at sea.
    Description: 2021-06-23
    Keywords: Radiocarbon ; Methane ; DIC ; Ocean acidification ; Climate change ; U.S Mid-Atlantic Bight
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    Earthquake magnitude distributions on northern Caribbean faults from combinatorial optimization models (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 126(10),(2021): e2021JB022050, https://doi.org/10.1029/2021JB022050.
    Description: On-fault earthquake magnitude distributions are calculated for northern Caribbean faults using estimates of fault slip and regional seismicity parameters. Integer programming, a combinatorial optimization method, is used to determine the optimal spatial arrangement of earthquakes sampled from a truncated Gutenberg-Richter distribution that minimizes the global misfit in slip rates on a complex fault system. Slip rates and their uncertainty on major faults are derived from a previously published GPS block model for the region, with fault traces determined from offshore geophysical mapping and previously published onshore studies. The optimal spatial arrangement of the sampled earthquakes is compared with the 500-year history of earthquake observations. Rupture segmentation of the subduction interface along the Hispaniola-Puerto Rico Trench (PRT) fault and seismic coupling on the PRT fault appear to exert the primary control over this spatial arrangement. Introducing a rupture barrier for the Hispaniola-PRT fault northwest of Mona Passage, based on geophysical and seismicity observations, and assigning a low slip rate of 2 mm/yr on the PRT fault are most consistent with historical earthquakes in the region. The addition of low slip-rate secondary faults as well as segmentation of the Hispaniola and Septentrional strike-slip fault improves the consistency with historical seismicity. An important observation from the modeling is that varying the slip rate on the PRT fault and different segmentation scenarios result in significant changes to the optimal magnitude distribution on faults farther away. In general, optimal on-fault magnitude distributions are more complex and inter-dependent than is typically assumed in probabilistic seismic hazard analysis and probabilistic tsunami hazard analysis.
    Description: Funding for this study is from the U.S. Geological Survey Coastal and Marine Hazards and Resources Program.
    Description: 2022-04-11
    Keywords: Northern Caribbean ; Rupture forecast ; Combinatorial optimization ; Integer programming
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    Hurricanes enhance labile carbon export to the deep ocean (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 46 (2019): 10484–10494, doi:10.1029/2019GL083719.
    Description: Tropical cyclones (hurricanes) generate intense surface ocean cooling and vertical mixing resulting in nutrient upwelling into the photic zone and episodic phytoplankton blooms. However, their influence on the deep ocean remains unknown. Here we present evidence that hurricanes also impact the ocean's biological pump by enhancing export of labile organic material to the deep ocean. In October 2016, Category 3 Hurricane Nicole passed over the Bermuda Time Series site in the oligotrophic NW Atlantic Ocean. Following Nicole's passage, particulate fluxes of lipids diagnostic of fresh phytodetritus, zooplankton, and microbial biomass increased by 30–300% at 1,500 m depth and 30–800% at 3,200 m depth. Mesopelagic suspended particles following Nicole were also enriched in phytodetrital material and in zooplankton and bacteria lipids, indicating particle disaggregation and a deepwater ecosystem response. Predicted climate‐induced increases in hurricane frequency and/or intensity may significantly alter ocean biogeochemical cycles by increasing the strength of the biological pump.
    Description: This work and the Oceanic Flux Program time series were supported by the National Science Foundation Chemical Oceanography Program Grant OCE 1536644. The Bermuda Atlantic Time Series and Hydrostation S time series were supported by NSF Grants OCE 1756105 and OCE 1633125, respectively. We acknowledge the contributions of BATS technicians with CTD and pigment analyses. We sincerely thank the officers and crew of R/V Atlantic Explorer (Bermuda Institute of Ocean Sciences) for their expert assistance on the cruises. The data used in this study are listed in the figures, tables, and references, and are also available in the NSF's Biological and Chemical Oceanography Data Management Office (BCO‐DMO, https://doi.org/10.1575/1912/bco‐dmo.775902.1).
    Description: 2020-02-16
    Keywords: Hurricanes ; Carbon cycle ; North Atlantic Ocean ; Deep ocean ; Particle fluxes ; Lipid biomarkers
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    Hydrate formation on marine seep bubbles and the implications for water column methane dissolution (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fu, X., Waite, W. F., & Ruppel, C. D. Hydrate formation on marine seep bubbles and the implications for water column methane dissolution. Journal of Geophysical Research: Oceans, 126(9), (2021): e2021JC017363, https://doi.org/10.1029/2021JC017363.
    Description: Methane released from seafloor seeps contributes to a number of benthic, water column, and atmospheric processes. At seafloor seeps within the methane hydrate stability zone, crystalline gas hydrate shells can form on methane bubbles while the bubbles are still in contact with the seafloor or as the bubbles begin ascending through the water column. These shells reduce methane dissolution rates, allowing hydrate-coated bubbles to deliver methane to shallower depths in the water column than hydrate-free bubbles. Here, we analyze seafloor videos from six deepwater seep sites associated with a diverse range of bubble-release processes involving hydrate formation. Bubbles that grow rapidly are often hydrate-free when released from the seafloor. As bubble growth slows and seafloor residence time increases, a hydrate coating can form on the bubble's gas-water interface, fully coating most bubbles within ∼10 s of the onset of hydrate formation at the seafloor. This finding agrees with water-column observations that most bubbles become hydrate-coated after their initial ∼150 cm of rise, which takes about 10 s. Whether a bubble is coated or not at the seafloor affects how much methane a bubble contains and how quickly that methane dissolves during the bubble's rise through the water column. A simplified model shows that, after rising 150 cm above the seafloor, a bubble that grew a hydrate shell before releasing from the seafloor will have ∼5% more methane than a bubble of initial equal volume that did not grow a hydrate shell after it traveled to the same height.
    Description: X. Fu acknowledges support from the Miller Fellowship during her time at U.C. Berkeley. W. Waite and C. Ruppel are supported by the United States Geological Survey (USGS) Coastal/Marine Hazards and Resources Program and the Energy Resources Program, with research conducted under USGS-Department of Energy interagency agreements DE-FE0023495 and 89243320SFE000013.
    Keywords: Gas and hydrate systems ; Oceanography: biological and chemical ; Carbon cycling ; Biogeochemical cycles, processes, and modeling
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    Building a global ecosystem research infrastructure to address global grand challenges for macrosystem ecology (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Loescher, H., Vargas, R., Mirtl, M., Morris, B., Pauw, J., Yu, X., Kutsch, W., Mabee, P., Tang, J., Ruddell, B., Pulsifer, P., Bäck, J., Zacharias, S., Grant, M., Feig, G., Zheng, L., Waldmann, C., & Genazzio, M. Building a global ecosystem research infrastructure to address global grand challenges for macrosystem ecology. Earth’s Future, 10(5), (2022): e2020EF001696, https://doi.org/10.1029/2020ef001696.
    Description: The development of several large-, “continental”-scale ecosystem research infrastructures over recent decades has provided a unique opportunity in the history of ecological science. The Global Ecosystem Research Infrastructure (GERI) is an integrated network of analogous, but independent, site-based ecosystem research infrastructures (ERI) dedicated to better understand the function and change of indicator ecosystems across global biomes. Bringing together these ERIs, harmonizing their respective data and reducing uncertainties enables broader cross-continental ecological research. It will also enhance the research community capabilities to address current and anticipate future global scale ecological challenges. Moreover, increasing the international capabilities of these ERIs goes beyond their original design intent, and is an unexpected added value of these large national investments. Here, we identify specific global grand challenge areas and research trends to advance the ecological frontiers across continents that can be addressed through the federation of these cross-continental-scale ERIs.
    Description: This manuscript is in part the product of several workshops and ongoing GERI development. The first workshop was the Terrestrial Ecosystem Research Network (TERN) sponsored and entitled: “Towards a Global Ecosystem Observatory”, 5–7 March 2017, University of Queensland, Brisbane Australia. Another workshop was sponsored by Chinese Academy of Sciences (CAS) and entitled: “Global Integrated Research Infrastructure component in Next Generation ILTER”, 17–20 April, 2018, South China Botanical Garden, Zhaoqing, Guangdong Province, China. The National Science Foundation (NSF) supported two workshops. The first was entitled: ‘Building a Global Ecological Understanding’ held at the University of Delaware, Newark Delaware, 3–6 June, 2016 (NSF 1347883) and the second entitled: “Global Environmental Research Infrastructure (GERI) Planning Workshop”, held at NEON HQ, Boulder Colorado, 25–27 June 2019 (NSF 1917180). The authors wish to thank the workshop attendees for their thoughtful contributions. NEON is a project sponsored by the NSF and managed under cooperative support agreement (DBI-1029808) to Battelle.
    Keywords: Environmental research infrastructure ; Macrosystem science ; Interoperability ; Societal benefit ; New capabilities ; Federating infrastructure
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    Modeling of barrier breaching during hurricanes Sandy and Matthew (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Hegermiller, C. A., Warner, J. C., Olabarrieta, M., Sherwood, C. R., & Kalra, T. S. Modeling of barrier breaching during hurricanes Sandy and Matthew. Journal of Geophysical Research: Earth Surface, 127(3), (2022): e2021JF006307, https://doi.org/10.1029/2021JF006307.
    Description: Physical processes driving barrier island change during storms are important to understand to mitigate coastal hazards and to evaluate conceptual models for barrier evolution. Spatial variations in barrier island topography, landcover characteristics, and nearshore and back-barrier hydrodynamics can yield complex morphological change that requires models of increasing resolution and physical complexity to predict. Using the Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST) modeling system, we investigated two barrier island breaches that occurred on Fire Island, NY during Hurricane Sandy (2012) and at Matanzas, FL during Hurricane Matthew (2016). The model employed a recently implemented infragravity (IG) wave driver to represent the important effects of IG waves on nearshore water levels and sediment transport. The model simulated breaching and other changes with good skill at both locations, resolving differences in the processes and evolution. The breach simulated at Fire Island was 250 m west of the observed breach, whereas the breach simulated at Matanzas was within 100 m of the observed breach. Implementation of the vegetation module of COAWST to allow three-dimensional drag over dune vegetation at Fire Island improved model skill by decreasing flows across the back-barrier, as opposed to varying bottom roughness that did not positively alter model response. Analysis of breach processes at Matanzas indicated that both far-field and local hydrodynamics influenced breach creation and evolution, including remotely generated waves and surge, but also surge propagation through back-barrier waterways. This work underscores the importance of resolving the complexity of nearshore and back-barrier systems when predicting barrier island change during extreme events.
    Description: C. A. Hegermiller is grateful to the U.S. Geological Survey (USGS) Mendenhall Research Fellowship Program for support. This project was supported by the USGS Coastal and Marine Geology Program and the Office of Naval Research, Increasing the Fidelity of Morphological Storm Impact Predictions Project. M. Olabarrieta acknowledges support from the NSF project OCE-1554892.
    Description: 2022-07-26
    Keywords: Breach ; Barrier island ; Hurricane
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    Predicted sea-level rise-driven biogeomorphological changes on Fire Island, New York: implications for people and plovers (2022)
    American Geophysical Union
    Details
    Publication Date: 2022-10-27
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zeigler, S. L., Gutierrez, B. T., Lentz, E. E., Plant, N. G., Sturdivant, E. J., & Doran, K. S. Predicted sea-level rise-driven biogeomorphological changes on Fire Island, New York: implications for people and plovers. Earth’s Future, 10(4), (2022): e2021EF002436, https://doi.org/10.1029/2021EF002436.
    Description: Forecasting biogeomorphological conditions for barrier islands is critical for informing sea-level rise (SLR) planning, including management of coastal development and ecosystems. We combined five probabilistic models to predict SLR-driven changes and their implications on Fire Island, New York, by 2050. We predicted barrier island biogeomorphological conditions, dynamic landcover response, piping plover (Charadrius melodus) habitat availability, and probability of storm overwash under three scenarios of shoreline change (SLC) and compared results to observed 2014/2015 conditions. Scenarios assumed increasing rates of mean SLC from 0 to 4.71 m erosion per year. We observed uncertainty in several morphological predictions (e.g., beach width, dune height), suggesting decreasing confidence that Fire Island will evolve in response to SLR as it has in the past. Where most likely conditions could be determined, models predicted that Fire Island would become flatter, narrower, and more overwash-prone with increasing rates of SLC. Beach ecosystems were predicted to respond dynamically to SLR and migrate with the shoreline, while marshes lost the most area of any landcover type compared to 2014/2015 conditions. Such morphological changes may lead to increased flooding or breaching with coastal storms. However—although modest declines in piping plover habitat were observed with SLC—the dynamic response of beaches, flatter topography, and increased likelihood of overwash suggest storms could promote suitable conditions for nesting piping plovers above what our geomorphology models predict. Therefore, Fire Island may offer a conservation opportunity for coastal species that rely on early successional beach environments if natural overwash processes are encouraged.
    Description: Funding for this work was provided by the U.S. Geological Survey's Coastal and Marine Hazards and Resources Program, with supplemental funding through the Disaster Relief Act.
    Keywords: Sea level rise ; Erosion ; Coastal habitats ; Barrier island ; Shorebirds
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    Sea ice meltwater and Circumpolar Deep Water drive contrasting productivity in three Antarctic polynyas (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(5), (2019): 2943-2968, doi:10.1029/2019JC015071.
    Description: In the Southern Ocean, polynyas exhibit enhanced rates of primary productivity and represent large seasonal sinks for atmospheric CO2. Three contrasting east Antarctic polynyas were visited in late December to early January 2017: the Dalton, Mertz, and Ninnis polynyas. In the Mertz and Ninnis polynyas, phytoplankton biomass (average of 322 and 354 mg chlorophyll a (Chl a)/m2, respectively) and net community production (5.3 and 4.6 mol C/m2, respectively) were approximately 3 times those measured in the Dalton polynya (average of 122 mg Chl a/m2 and 1.8 mol C/m2). Phytoplankton communities also differed between the polynyas. Diatoms were thriving in the Mertz and Ninnis polynyas but not in the Dalton polynya, where Phaeocystis antarctica dominated. These strong regional differences were explored using physiological, biological, and physical parameters. The most likely drivers of the observed higher productivity in the Mertz and Ninnis were the relatively shallow inflow of iron‐rich modified Circumpolar Deep Water onto the shelf as well as a very large sea ice meltwater contribution. The productivity contrast between the three polynyas could not be explained by (1) the input of glacial meltwater, (2) the presence of Ice Shelf Water, or (3) stratification of the mixed layer. Our results show that physical drivers regulate the productivity of polynyas, suggesting that the response of biological productivity and carbon export to future change will vary among polynyas.
    Description: This work was cofunded by the Australian Antarctic Division research projects AAS 4131 and 4291. This project was also supported by the Australian Government Cooperative Research Centres Programme through the Antarctic Climate & Ecosystems (ACE CRC). S. Moreau and C. Genovese were supported by the Australian Research Council's Special Research Initiative for Antarctic Gateway Partnership (project ID SR140300001). V. Puigcorbé and M. Roca‐Martí are grateful for the support from Pere Masque and Edith Cowan University. M.C. Arroyo was supported by the Dickhut Fellowship, administered by the Virginia Institute of Marine Science. The authors would like to thank the officers and crew of the R/V Aurora Australis for their logistic support, the CSIRO hydrochemists for their analyses of nutrient concentrations, and E. J. Yang for her microscope analysis of phytoplankton species. We also want to thank two anonymous reviewers for their very good comments on this study. The data presented in this paper are available on the Australian Antarctic Division (AAD) Data Centre at https://data.aad.gov.au/aadc/metadata/metadata_by_parameter.cfm.
    Description: 2019-09-28
    Keywords: Polynyas ; Primary productivity ; Phytoplankton biomass ; Ice shelves ; Sea ice ; Iron
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    Unabated bottom water warming and freshening in the south Pacific Ocean. (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(3), (2019): 1778-1794, doi:10.1029/2018JC014775.
    Description: Abyssal ocean warming contributed substantially to anthropogenic ocean heat uptake and global sea level rise between 1990 and 2010. In the 2010s, several hydrographic sections crossing the South Pacific Ocean were occupied for a third or fourth time since the 1990s, allowing for an assessment of the decadal variability in the local abyssal ocean properties among the 1990s, 2000s, and 2010s. These observations from three decades reveal steady to accelerated bottom water warming since the 1990s. Strong abyssal (z 〉 4,000 m) warming of 3.5 (±1.4) m°C/year (m°C = 10−3 °C) is observed in the Ross Sea, directly downstream from bottom water formation sites, with warming rates of 2.5 (±0.4) m°C/year to the east in the Amundsen‐Bellingshausen Basin and 1.3 (±0.2) m°C/year to the north in the Southwest Pacific Basin, all associated with a bottom‐intensified descent of the deepest isotherms. Warming is consistently found across all sections and their occupations within each basin, demonstrating that the abyssal warming is monotonic, basin‐wide, and multidecadal. In addition, bottom water freshening was strongest in the Ross Sea, with smaller amplitude in the Amundsen‐Bellingshausen Basin in the 2000s, but is discernible in portions of the Southwest Pacific Basin by the 2010s. These results indicate that bottom water freshening, stemming from strong freshening of Ross Shelf Waters, is being advected along deep isopycnals and mixed into deep basins, albeit on longer timescales than the dynamically driven, wave‐propagated warming signal. We quantify the contribution of the warming to local sea level and heat budgets.
    Description: S. G. P. was supported by a U.S. GO‐SHIP postdoctoral fellowship through NSF grant OCE‐1437015, which also supported L. D. T. and S. M. and collection of U.S. GO‐SHIP data since 2014 on P06, S4P, P16, and P18. G. C. J. is supported by the Global Ocean Monitoring and Observation Program, National Oceanic and Atmospheric Administration (NOAA), U.S. Department of Commerce and NOAA Research. B. M. S and S. E. W. were supported by the Australian Government Department of the Environment and CSIRO through the Australian Climate Change Science Programme and by the National Environmental Science Program. We are grateful for the hard work of the science parties, officers, and crew of all the research cruises on which these CTD data were collected. We also thank the two anonymous reviewers for their helpful comments that improve the manuscript. This is PMEL contribution 4870. All CTD data sets used in this analysis are publicly available at the website (https://cchdo.ucsd.edu).
    Description: 2019-08-20
    Keywords: Abyssal warming ; Pacific deep circulation ; Deep steric sea level ; Deep warming variability ; Antarctic Bottom Water
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    Characterizing the transition from balanced to unbalanced motions in the Southern California Current (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(3), (2019): 2088-2109, doi:10.1029/2018JC014583.
    Description: As observations and models improve their resolution of oceanic motions at ever finer horizontal scales, interest has grown in characterizing the transition from the geostrophically balanced flows that dominate at large‐scale to submesoscale turbulence and waves that dominate at small scales. In this study we examine the mesoscale‐to‐submesoscale (100 to 10 km) transition in an eastern boundary current, the southern California Current System (CCS), using repeated acoustic Doppler current profiler transects, sea surface height from high‐resolution nadir altimetry and output from a (1/48)° global model simulation. In the CCS, the submesoscale is as energetic as in western boundary current regions, but the mesoscale is much weaker, and as a result the transition lacks the change in kinetic energy (KE) spectral slope observed for western boundary currents. Helmholtz and vortex‐wave decompositions of the KE spectra are used to identify balanced and unbalanced contributions. At horizontal scales greater than 70 km, we find that observed KE is dominated by balanced geostrophic motions. At scales from 40 to 10 km, unbalanced contributions such as inertia‐gravity waves contribute as much as balanced motions. The model KE transition occurs at longer scales, around 125 km. The altimeter spectra are consistent with acoustic Doppler current profiler/model spectra at scales longer than 70/125 km, respectively. Observed seasonality is weak. Taken together, our results suggest that geostrophic velocities can be diagnosed from sea surface height on scales larger than about 70 km in the southern CCS.
    Description: This research was funded by NASA (NNX13AE44G, NNX13AE85G, NNX16AH67G, NNX16AO5OH, and NNX17AH53G). We thank Sung Yong Kim for providing the high‐frequency radar spectral estimates and the two anonymous reviewers for providing useful comments and suggestions that greatly improved the manuscript. High‐frequency ALES data for Jason‐1 and Jason‐2 altimeters are available upon request (https://openadb.dgfi.tum.de/en/contact/ALES). Both AltiKa and Sentinel‐3 altimeter products were produced and distributed by the Copernicus Marine and Environment Monitoring Service (CMEMS; http://www.marine.copernicus.eu). D. M. worked on the modeling component of this study at the Jet Propulsion Laboratory (JPL), California Institute of Technology, under a contract with the National Aeronautics and Space Administration (NASA). High‐end computing resources were provided by the NASA Advanced Supercomputing (NAS) Division of the Ames Research Center. The LLC output can be obtained from the ECCO project (ftp://ecco.jpl.nasa.gov/ECCO2/LLC4320/). The ADCP data are available at the Joint Archive for Shipboard ADCP data (JASADCP; http://ilikai.soest.hawaii.edu/sadcp).
    Description: 2019-08-21
    Keywords: Mesoscale ; Submesoscale ; Internal gravity waves
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    "Petit spot" rejuvenated volcanism superimposed on plume-derived Samoan shield volcanoes: Evidence from a 645-m drill core from Tutuila Island, American Samoa (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(3), (2019): 1485-1507, doi:10.1029/2018GC007985.
    Description: In 2015 a geothermal exploration well was drilled on the island of Tutuila, American Samoa. The sample suite from the drill core provides 645 m of volcanic stratigraphy from a Samoan volcano, spanning 1.45 million years of volcanic history. In the Tutuila drill core, shield lavas with an EM2 (enriched mantle 2) signature are observed at depth, spanning 1.46 to 1.44 Ma. These are overlain by younger (1.35 to 1.17 Ma) shield lavas with a primordial “common” (focus zone) component interlayered with lavas that sample a depleted mantle component. Following ~1.15 Myr of volcanic quiescence, rejuvenated volcanism initiated at 24.3 ka and samples an EM1 (enriched mantle 1) component. The timing of the initiation of rejuvenated volcanism on Tutuila suggests that rejuvenated volcanism may be tectonically driven, as Samoan hotspot volcanoes approach the northern terminus of the Tonga Trench. This is consistent with a model where the timing of rejuvenated volcanism at Tutuila and at other Samoan volcanoes relates to their distance from the Tonga Trench. Notably, the Samoan rejuvenated lavas have EM1 isotopic compositions distinct from shield lavas that are geochemically similar to “petit spot” lavas erupted outboard of the Japan Trench and late stage lavas erupted at Christmas Island located outboard of the Sunda Trench. Therefore, like the Samoan rejuvenated lavas, petit spot volcanism in general appears to be related to tectonic uplift outboard of subduction zones, and existing geochemical data suggest that petit spots share similar EM1 isotopic signatures.
    Description: Reviews from Kaj Hoernle and three anonymous reviewers are gratefully acknowledged. M. G. J. acknowledges support from the American Samoa Power Authority and National Science Foundation grants OCE‐1736984 and EAR‐1624840. The Tutuila drill core was the brainchild of Tim Bodell, without whom we would still have no stratigraphic record of Tutuila volcanism. The support of Utu Abe Malae and Matamua Katrina Mariner was instrumental to the project's success. We dedicate this paper to the memory of Abe Malae and his efforts to support science and education in American Samoa. Images of the entire drill core are available online (escholarship.org/uc/item/6gg6p61w). All data presented are either part of this study or previously published and are referenced in text.
    Description: 2019-08-13
    Keywords: Samoa ; Mantle geochemistry ; Petit spot ; EM1 ; Rejuvenated volcanism
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    Deepening of the winter mixed layer in the Canada Basin, Arctic Ocean over 2006-2017 (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(7), (2019): 4618-4630, doi: 10.1029/2019JC014940.
    Description: The Arctic Ocean mixed layer interacts with the ice cover above and warmer, nutrient‐rich waters below. Ice‐Tethered Profiler observations in the Canada Basin of the Arctic Ocean over 2006–2017 are used to investigate changes in mixed layer properties. In contrast to decades of shoaling since at least the 1980s, the mixed layer deepened by 9 m from 2006–2012 to 2013–2017. Deepening resulted from an increase in mixed layer salinity that also weakened stratification at the base of the mixed layer. Vertical mixing alone can explain less than half of the observed change in mixed layer salinity, and so the observed increase in salinity is inferred to result from changes in freshwater accumulation via changes to ice‐ocean circulation or ice melt/growth and river runoff. Even though salinity increased, the shallowest density surfaces deepened by 5 m on average suggesting that Ekman pumping over this time period remained downward. A deeper mixed layer with weaker stratification has implications for the accessibility of heat and nutrients stored in the upper halocline. The extent to which the mixed layer will continue to deepen appears to depend primarily on the complex set of processes influencing freshwater accumulation.
    Description: We gratefully acknowledge J. Toole for helpful conversations. S. Cole was supported by the National Science Foundation under grant PLR‐1602926 and J. Stadler by the Woods Hole Oceanographic Institution Summer Student Fellowship program. Profile data are available via the Ice‐Tethered Profiler program website: http://whoi.edu/itp. SSM/I ice concentration data were downloaded from the National Snow and Ice Data Center.
    Description: 2019-12-22
    Keywords: Arctic Ocean ; Mixed layer ; Freshwater
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    Recent contributions of theory to our understanding of the Atlantic Meridional Overturning Circulation (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Johnson, H. L., Cessi, P., Marshall, D. P., Schloesser, F., & Spall, M. A. Recent contributions of theory to our understanding of the Atlantic Meridional Overturning Circulation. Journal of Geophysical Research-Oceans, 124(8), (2019): 5376-5399, doi: 10.1029/2019JC015330.
    Description: Revolutionary observational arrays, together with a new generation of ocean and climate models, have provided new and intriguing insights into the Atlantic Meridional Overturning Circulation (AMOC) over the last two decades. Theoretical models have also changed our view of the AMOC, providing a dynamical framework for understanding the new observations and the results of complex models. In this paper we review recent advances in conceptual understanding of the processes maintaining the AMOC. We discuss recent theoretical models that address issues such as the interplay between surface buoyancy and wind forcing, the extent to which the AMOC is adiabatic, the importance of mesoscale eddies, the interaction between the middepth North Atlantic Deep Water cell and the abyssal Antarctic Bottom Water cell, the role of basin geometry and bathymetry, and the importance of a three‐dimensional multiple‐basin perspective. We review new paradigms for deep water formation in the high‐latitude North Atlantic and the impact of diapycnal mixing on vertical motion in the ocean interior. And we discuss advances in our understanding of the AMOC's stability and its scaling with large‐scale meridional density gradients. Along with reviewing theories for the mean AMOC, we consider models of AMOC variability and discuss what we have learned from theory about the detection and meridional propagation of AMOC anomalies. Simple theoretical models remain a vital and powerful tool for articulating our understanding of the AMOC and identifying the processes that are most critical to represent accurately in the next generation of numerical ocean and climate models.
    Description: H. L. J. and D. P. M. are grateful for funding from the U.K. Natural Environment Research Council under the UK‐OSNAP project (NE/K010948/1). P. C. gratefully acknowledges support by the National Science Foundation through OCE‐1634128. M. A. S. was supported by the National Science Foundation Grants OCE‐1558742 and OCE‐1634468. We are also grateful to Eli Tziperman and an anonymous reviewer whose comments helped us to improve the manuscript. The Estimating the Circulation and Climate of the Ocean state estimate (ECCO version 4 release 3) used to produce Figure 2 is available online (https://ecco.jpl.nasa.gov). Please refer to the original papers reviewed here for access to any other data discussed.
    Keywords: Atlantic ; Overturning circulation
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    Effects of oceanic mesoscale and submesoscale frontal processes on the vertical transport of phytoplankton (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(8), (2019): 5999-6014, doi: 10.1029/2019JC015034.
    Description: Oceanic fronts are dynamically active regions of the global ocean that support upwelling and downwelling with significant implications for phytoplankton production and export. However (on time scales urn:x-wiley:jgrc:media:jgrc23568:jgrc23568-math-0001 the inertial time scale), the vertical velocity is 103–104 times weaker than the horizontal velocity and is difficult to observe directly. Using intensive field observations in conjunction with a process study ocean model, we examine vertical motion and its effect on phytoplankton fluxes at multiple spatial horizontal scales in an oligotrophic region in the Western Mediterranean Sea. The mesoscale ageostrophic vertical velocity (∼10 m/day) inferred from our observations shapes the large‐scale phytoplankton distribution but does not explain the narrow (1–10 km wide) features of high chlorophyll content extending 40–60 m downward from the deep chlorophyll maximum. Using modeling, we show that downwelling submesoscale features concentrate 80% of the downward vertical flux of phytoplankton within just 15% of the horizontal area. These submesoscale spatial structures serve as conduits between the surface mixed layer and pycnocline and can contribute to exporting carbon from the sunlit surface layers to the ocean interior.
    Description: The AlborEx experiment was conducted in the framework of PERSEUS EU‐funded project (Grant 287600) and was led by the Spanish National Research Council (CSIC) and involved other national and international partners: Balearic Islands Coastal Observing and Forecasting System (SOCIB, Spain); Consiglio Nazionale delle Ricerche (CNR, Italy); Istituto Nazionale di Oceanografia e di Geofisica Sperimentale (OGS, Italy); and Woods Hole Oceanographic Institution (WHOI, ONR Grant N00014‐16‐1‐3130). Glider operations were partially funded by JERICO FP7 project. Part of this work has been carried out as part of the Copernicus Marine Environment Monitoring Service (CMEMS) MedSUB project. CMEMS is implemented by Mercator Ocean in the framework of a delegation agreement with the European Union. S. R. and A. P. acknowledge support from WHOI Subcontract A101339. Data available from authors: Ship CTDs, glider and VM‐ADCP data files are available in the SOCIB data catalog (https://doi.org/10.25704/z5y2-qpye); model data are available at IMEDEA data catalog https://ide.imedea.uib-csic.es/thredds/catalog/data/projects/alborex/catalog.html. We thank all the crew and participants on board R/V SOCIB for their collaboration and Marc Torner and the SOCIB glider Facility for their efficient cooperation. We also thank B. Mourre for numerical data from the Western Mediterranean Operational Model to initialize the Process Study Ocean Model. Figures were created using the cmocean colormaps package (Thyng et al., 2016).
    Keywords: Vertical motion ; Ocean front ; Mesoscale ; Submesoscale ; Transport ; Phytoplankton
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    The relationship between U.S. East Coast sea level and the Atlantic Meridional Overturning Circulation: a review (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Little, C. M., Hu, A., Hughes, C. W., McCarthy, G. D., Piecuch, C. G., Ponte, R. M., & Thomas, M. D. The relationship between U.S. East Coast sea level and the Atlantic Meridional Overturning Circulation: a review. Journal of Geophysical Research-Oceans, 124(9), (2019): 6435-6458, doi:10.1029/2019JC015152.
    Description: Scientific and societal interest in the relationship between the Atlantic Meridional Overturning Circulation (AMOC) and U.S. East Coast sea level has intensified over the past decade, largely due to (1) projected, and potentially ongoing, enhancement of sea level rise associated with AMOC weakening and (2) the potential for observations of U.S. East Coast sea level to inform reconstructions of North Atlantic circulation and climate. These implications have inspired a wealth of model‐ and observation‐based analyses. Here, we review this research, finding consistent support in numerical models for an antiphase relationship between AMOC strength and dynamic sea level. However, simulations exhibit substantial along‐coast and intermodel differences in the amplitude of AMOC‐associated dynamic sea level variability. Observational analyses focusing on shorter (generally less than decadal) timescales show robust relationships between some components of the North Atlantic large‐scale circulation and coastal sea level variability, but the causal relationships between different observational metrics, AMOC, and sea level are often unclear. We highlight the importance of existing and future research seeking to understand relationships between AMOC and its component currents, the role of ageostrophic processes near the coast, and the interplay of local and remote forcing. Such research will help reconcile the results of different numerical simulations with each other and with observations, inform the physical origins of covariability, and reveal the sensitivity of scaling relationships to forcing, timescale, and model representation. This information will, in turn, provide a more complete characterization of uncertainty in relevant relationships, leading to more robust reconstructions and projections.
    Description: The authors acknowledge funding support from NSF Grant OCE‐1805029 (C. M. L.) and NASA Contract NNH16CT01C (C. M. L. and R. M. P.), the Regional and Global Model Analysis (RGMA) component of the Earth and Environmental System Modeling Program of the U.S. Department of Energy's Office of Biological & Environmental Research Cooperative Agreement DE‐FC02‐97ER62402 (A. H.), Natural Environment Research Council NE/K012789/1 (C. W. H.), Irish Marine Institute Project A4 PBA/CC/18/01 (G. D. M.), and NSF Awards OCE‐1558966 and OCE‐1834739 (C. G. P.). The National Center for Atmospheric Research is sponsored by National Science Foundation. The authors thank the two reviewers for their comments, and CLIVAR and the U.S. AMOC Science Team for inspiration and patience. All CMIP5 data used in Figures 4-6 are available at http://pcmdi9.llnl.gov/ website; the AMOC strength fields were digitized from Chen et al. (2018, supporting information Figure S3).
    Keywords: Sea level ; AMOC ; United States ; Coastal ; Climate model ; Review
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  • 75
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    Long-term evolution of nontransform discontinuities at the Mid-Atlantic Ridge, 24°N–27°30′N (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124 (2019): 10023–10055, doi: 10.1029/2019JB017648.
    Description: We studied long‐term evolution of nontransform discontinuities (NTDs) on the Mid‐Atlantic Ridge from 0‐ to ~20‐ to 25‐Ma crust using plate reconstructions of multibeam bathymetry, long‐range HMR1 sidescan sonar, residual mantle Bouguer gravity anomaly (RMBA), and gravity‐derived crustal thickness. NTDs have propagated north and south with respect to flowlines of relative plate motion and both rapidly and slowly compared to the half spreading rate; at times they have been quasi‐stable. Fast, short‐term (〈2 Myr) propagation is driven by reduced magma supply (increased tectonic extension) in the propagating ridge tip when NTD ridge‐axis offsets are small (≲5 km). Propagation at larger offsets generally is slower and longer term. These NTDs can show classic structures of rift propagation including inner and outer pseudofaults and crustal blocks transferred between ridge flanks by discontinuous jumps of the propagating ridge tip. In all cases crustal transfer occurs within the NTD valley. Aside from ridge‐axis offset, the evolution of NTDs appears to be controlled by three factors: (1) gross volume and distribution of magma supplied to ridge segments as controlled by 3‐D heterogeneities in mantle fertility and/or dynamic upwelling; this controls fundamental ridge segmentation. (2) The lithospheric plumbing system through which magma is delivered to the crust. (3) The consequent focusing of tectonic extension in magma‐poor parts of spreading segments, typically at segment ends, which can drive propagation. We also observe long‐wavelength (5‐10 Myr) RMBA asymmetry between the conjugate ridge flanks, and we attribute this to asymmetric distribution of density anomalies in the upper mantle.
    Description: We thank Tingting Wang for providing plate‐reconstruction codes, Ross Parnell‐Turner for technical support, and Anouk Beniest and an anonymous reviewer for comments that helped to improve the manuscript. We benefited greatly from discussion with the Deep Sea Geodynamics Group of the South China Sea Institute of Oceanology. Figures were drawn using the GMT software of Wessel and Smith (1998). This study was supported by National Natural Science Foundation of China (91628301, 41890813, and U1606401), Chinese Academy of Sciences (Y4SL021001, QYZDY‐SSW‐DQC005, and 133244KYSB20180029), Chinese National 985 Project (1350141509), International Exchange Program for Graduate Students of Tongji University (2016020006), China Scholarship Council (201706260034), and Woods Hole Oceanographic Institution. We thank the crews and science parties of the ARSRP, MAREAST, MODE94, and MODE98 expeditions for their contributions to data acquisition. ARSRP and MAREAST data acquisition was funded by Office of Naval Research grant N00014‐90‐J‐6121 and by U.S. National Science Foundation grant OCE‐9503561, respectively. Access to the original data used in this study is available at https://doi.org/10.26025/z2z7‐kd89.
    Description: 2020-03-11
    Keywords: Mid‐Atlantic Ridge ; Nontransform discontinuity ; Plate reconstruction ; Propagating rift
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    Shelfbreak downwelling in the Alaskan Beaufort Sea (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124 (2019): 7201-7225, doi: 10.1029/2019JC015520.
    Description: The oceanographic response and atmospheric forcing associated with downwelling along the Alaskan Beaufort Sea shelf/slope is described using mooring data collected from August 2002 to September 2004, along with meteorological time series, satellite data, and reanalysis fields. In total, 55 downwelling events are identified with peak occurrence in July and August. Downwelling is initiated by cyclonic low‐pressure systems displacing the Beaufort High and driving westerly winds over the region. The shelfbreak jet responds by accelerating to the east, followed by a depression of isopycnals along the outer shelf and slope. The storms last 3.25 ± 1.80 days, at which point conditions relax toward their mean state. To determine the effect of sea ice on the oceanographic response, the storms are classified into four ice seasons: open water, partial ice, full ice, and fast ice (immobile). For a given wind strength, the largest response occurs during partial ice cover, while the most subdued response occurs in the fast ice season. Over the two‐year study period, the winds were strongest during the open water season; thus, the shelfbreak jet intensified the most during this period and the cross‐stream Ekman flow was largest. During downwelling, the cold water fluxed off the shelf ventilates the upper halocline of the Canada Basin. The storms approach the Beaufort Sea along three distinct pathways: a northerly route from the high Arctic, a westerly route from northern Siberia, and a southerly route from south of Bering Strait. Differences in the vertical structure of the storms are presented as well.
    Description: The authors thank Paula Fratantoni and Dan Torres for processing the moored profiler and ADCP data, respectively. Data from the SBI mooring array can be found at https://archive.eol.ucar.edu/projects/sbi/all_data.shtml. Funding for the analysis was provided by the following grants: National Science Foundation Grants OCE‐1259618 (N. F. and R. P.), OCE‐1756361 (N. F.), and PLR‐1504333 (N. F. and R. P.); National Oceanic and Atmospheric Administration Grant NA14‐OAR4320158 (R. P. and P. L.); and the Natural Sciences and Engineering Research Council of Canada (K. M.).
    Description: 2020-04-16
    Keywords: Downwelling ; Beaufort Sea ; Shelfbreak ; North Slope ; Arctic cyclone
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  • 77
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    Magnetic mineral populations in lower oceanic crustal gabbros (Atlantis Bank, SW Indian Ridge): implications for marine magnetic anomalies (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 21(3), (2020): e2019GC008847, doi:10.1029/2019GC008847.
    Description: To learn more about magnetic properties of the lower ocean crust and its contributions to marine magnetic anomalies, gabbro samples were collected from International Ocean Discovery Program Hole U1473A at Atlantis Bank on the Southwest Indian Ridge. Detailed magnetic property work links certain magnetic behaviors and domain states to specific magnetic mineral populations. Measurements on whole rocks and mineral separates included magnetic hysteresis, first‐order reversal curves, low‐temperature remanence measurements, thermomagnetic analysis, and magnetic force microscopy. Characteristics of the thermomagnetic data indicate that the upper ~500 m of the hole has undergone hydrothermal alteration. The thermomagnetic and natural remanent magnetization data are consistent with earlier observations from Hole 735B that show remanence arises from low‐Ti magnetite and that natural remanent magnetizations are up to 25 A m−1 in evolved Fe‐Ti oxide gabbros, but are mostly 〈1 A m−1. Magnetite is present in at least three forms. Primary magnetite is associated with coarse‐grained oxides that are more frequent in the upper part of the hole. This magnetic population is linked to dominantly “pseudo‐single‐domain” behavior that arises from fine‐scale lamellar intergrowths within the large oxides. Deeper in the hole the magnetic signal is more commonly dominated by an interacting single‐domain assemblage most likely found along crystal discontinuities in olivine and/or pyroxene. A third contribution is from noninteracting single‐domain inclusions within plagioclase. Because the concentration of the highly magnetic, oxide‐rich gabbros is greatest toward the surface, the signal from coarse oxides will likely dominate the near‐bottom magnetic anomaly signal at Atlantis Bank.
    Description: This work used samples and data provided by the International Ocean Discovery Program. Funding was provided by the U.S. Science Support Program (J.B.). I.L. has benefited from a Smithsonian Edward and Helen Hintz Secretarial Scholarship. We thank the members of the IODP Expedition 360 Science Party, and the captain and crew of the JOIDES Resolution. Part of this work was done as a Visiting Fellow at the Institute for Rock Magnetism (IRM) at the University of Minnesota. The IRM is made possible through the Instrumentation and Facilities program of the National Science Foundation, Earth Sciences Division, and by funding from the University of Minnesota. We would like to thank IRM staff M. Jackson, P. Solheid, and D. Bilardello for their generous assistance. Many thanks to A. Butula, K. Vernon, and J. Marquardt for their assistance with rock magnetic measurements at UWM and to L. McHenry for assistance with XRD. We also thank two anonymous reviewers for their thoughtful comments that improved the manuscript. Magnetic data associated with this manuscript are available in the Magnetics Information Consortium (MagIC) database at https://www.earthref.org/MagIC/doi/10.1029/2019GC008847. XRD data are available at https://zenodo.org/record/3611642.
    Description: 2020-08-28
    Keywords: Marine magnetic anomalies ; Ocean crust magnetization ; Magnetic mineralogy ; IODP ; Expedition 360 ; JOIDES Resolution
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    Impact of current-wind interaction on vertical processes in the Southern Ocean (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 125(4), (2020): e2020JC016046, doi:10.1029/2020JC016046.
    Description: Momentum input from westerly winds blowing over the Southern Ocean can be modulated by mesoscale surface currents and result in changes in large‐scale ocean circulation. Here, using an eddy‐resolving 1/20 degree ocean model configured near Drake Passage, we evaluate the impact of current‐wind interaction on vertical processes. We find a reduction in momentum input from the wind, reduced eddy kinetic energy, and a modification of Ekman pumping rates. Wind stress curl resulting from current‐wind interaction leads to net upward motion, while the nonlinear Ekman pumping term associated with horizontal gradients of relative vorticity induces net downward motion. The spatially averaged mixed layer depth estimated using a density criteria is shoaled slightly by current‐wind interaction. Current‐wind interaction, on the other hand, enhances the stratification in the thermocline below the mixed layer. Such changes have the potential to alter biogeochemical processes including nutrient supply, biological productivity, and air‐sea carbon dioxide exchange.
    Description: The MITgcm can be obtained online (http://mitgcm.org). The geostrophic current product derived from the sea level anomaly can be downloaded in the Copernicus Marine and Environment Monitoring Service of Ssalto/Duacs gridded “allsat” series and along‐track Sea Level Anomalies, Absolute Dynamic Topographies and Geostrophic velocities over the Global Ocean, Mediterranean Sea, Black Sea, European Seas and Acrtic Ocean areas, in Delayed‐Time and in Near‐Real‐Time. Resources supporting this work were provided by the NASA High‐End Computing (HEC) Program through the NASA Advanced Supercomputing (NAS) Division at Ames Research Center with the award number SMD‐15‐5752. H. S., J. M., and D. J. M. were supported by the NSF MOBY project (OCE‐1048926 and OCE‐1048897). H. S. acknowledges the support by National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (NRF‐2019R1C1C1003663) and Yonsei University Research Fund of 2018‐22‐0053. D. J. M. also gratefully acknowledges NSF and NASA support, along with the Holger W. Jannasch and Columbus O'Donnell Iselin shared chairs for Excellence in Oceanography. H. Seo acknowledges the support from the ONR (N00014‐17‐1‐2398), NOAA (NA10OAR4310376), and the Andrew W. Mellon Foundation Endowed Fund for Innovative Research at WHOI. We also thank two anonymous referees whose comments significantly improved the presentation of results.
    Description: 2020-09-17
    Keywords: Southern Ocean ; Eddy-wind interaction ; Ekman pumping ; Stratification ; Eddy kinetic energy ; Mixed layer depth
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    What caused recent shifts in tropical pacific decadal sea-level trends? (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124 (2019): 7575-7590, doi: 10.1029/2019JC015339.
    Description: Satellite altimetry reveals substantial decadal variability in sea level 𝜁 across the tropical Pacific during 1993–2015. An ocean state estimate that faithfully reproduces the observations is used to elucidate the origin of these low-frequency tropical Pacific 𝜁 variations. Analysis of the hydrostatic equation reveals that recent decadal 𝜁 changes in the tropical Pacific are mainly hermosteric in nature, related to changes in upper-ocean heat content. A forcing experiment performed with the numerical model suggests that anomalous wind stress was an important driver of the relevant heat storage and thermosteric variation. Closed budget diagnostics further clarify that the wind-stress-related thermosteric 𝜁 variation resulted from the joint actions of large-scale ocean advection and local surface heat flux, such that advection controlled the budget over shorter, intraseasonal to interannual time scales, and local surface heat flux became increasingly influential at longer decadal periods. In particular, local surface heat flux was important in contributing to a recent reversal of decadal 𝜁 trends in the tropical Pacific. Contributions from local surface heat flux partly reflect damping latent heat flux tied to wind-stress-driven sea-surface-temperature variations.
    Description: This work was supported by NSF Awards OCE‐1558966 and OCE‐1834739. Support of the ECCO project by the NASA Physical Oceanography, Cryospheric Science, and Modeling, Analysis and Prediction programs is also acknowledged. We thank Ou Wang (NASA JPL) for performing the forcing perturbation experiment. Comments from two anonymous reviewers were helpful. Altimetry observations used in Figures 1 and 2 were downloaded from CSIRO (http://www.cmar.csiro.au/sealevel/sl_data_cmar.html). ECCOv4 output is available on the group website (https://ecco.jpl.nasa.gov/).
    Description: 2020-04-30
    Keywords: Sea‐level change ; Sea‐level variability ; Decadal variability ; Tropical Pacific ; State estimation
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    Coral records of temperature and salinity in the tropical western Pacific reveal influence of the Pacific Decadal Oscillation since the late nineteenth century (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ramos, R. D., Goodkin, N. F., Siringan, F. P., & Hughen, K. A. Coral records of temperature and salinity in the tropical western Pacific reveal influence of the Pacific Decadal Oscillation since the late nineteenth century. Paleoceanography and Paleoclimatology, 34(8), (2019): 1344-1358, doi: 10.1029/2019PA003684.
    Description: The Pacific Decadal Oscillation (PDO) is a complex aggregate of different atmospheric and oceanographic forcings spanning the extratropical and tropical Pacific. The PDO has widespread climatic and societal impacts, thus understanding the processes contributing to PDO variability is critical. Distinguishing PDO‐related variability is particularly challenging in the tropical Pacific due to the dominance of the El Niño–Southern Oscillation and influence of anthropogenic warming signals. Century‐long western Pacific records of subannual sea surface temperature (SST) and sea surface salinity (SSS), derived from coral Sr/Ca and δ18O profiles, respectively, allow for evaluating different climatic sensitivities and identifying PDO‐related variability in the region. The summer Sr/Ca‐SST record provides evidence of a significant SST increase, likely tied to greenhouse gas emissions. Anthropogenic warming is masked in the winter Sr/Ca‐SST record by interannual to multidecadal scale changes driven by the East‐Asian Winter Monsoon and the PDO. Decadal climate variability during winter is strongly correlated to the PDO, in agreement with other PDO records in the region. The PDO also exerts influence on the SSS difference between the dry and wet season coral δ18O (δ18Oc)‐SSS records through water advection. The PDO and El Niño–Southern Oscillation constructively combine to enhance/reduce advection of saline Kuroshio waters at our site. Overall, we are able to demonstrate that climate records from a tropical reef environment significantly capture PDO variability and related changes over the period of a century. This implies that the tropical western Pacific is a key site in understanding multifrequency climate variability, including its impact on tropical climate at longer timescales.
    Description: The authors would like to thank J. Ossolinski, J. Aggangan, J. Quevedo, R. Lloren, G. Albano, J. Perez, and A. Bolton for their help in acquiring core samples in the field. The detailed comments and suggestions of two anonymous reviewers significantly improved the original manuscript. This research was funded by the National Research Foundation Singapore under its Singapore NRF Fellowship scheme awarded to N. F. Goodkin (National Research Fellow award NRF‐RF2012‐03), as administered by the Earth Observatory of Singapore and the Singapore Ministry of Education under the Research Centers of Excellence initiative and by the Ministry of Education, Singapore through its Academic Research Fund Tier 2 (Project MOE2016‐T2‐1‐016). The coral Sr/Ca and δ18O data generated in this study are available in the supporting information Data Set S1 and are archived at the NOAA NCDC World Data Center for Paleoclimatology (https://www.ncdc.noaa.gov/paleo/study/27271). Other data and resources used in this study were sourced from the following sites: PDO index (http://research.jisao.washington.edu/pdo/PDO.latest); IPO index (https://www.esrl.noaa.gov/psd/data/timeseries/IPOTPI/ipotpi.hadisst2.data); NP index (https://www.esrl.noaa.gov/psd/data/correlation/np.data); PDO and North Pacific SST reconstructions (https://www.ncdc.noaa.gov/data‐access/paleoclimatology‐data); and MTM coherence and phase analysis MATLAB® code (https://www.mathworks.com/matlabcentral/fileexchange/22551‐multi‐taper‐coherence‐method‐with‐bias‐correction).
    Keywords: Coral proxies ; PDO ; ENSO ; EAWM ; Western Pacific
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    Dissolved organic radiocarbon in the central Pacific Ocean (2019)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Druffel, E. R. M., Griffin, S., Wang, N., Garcia, N. G., McNichol, A. P., Key, R. M., & Walker, B. D. Dissolved organic radiocarbon in the central Pacific Ocean. Geophysical Research Letters, 46(10), (2019):5396-5403, doi:10.1029/2019GL083149.
    Description: We report marine dissolved organic carbon (DOC) concentrations, and DOC ∆14C and δ13C values in seawater collected from the central Pacific. Surface ∆14C values are low in equatorial and polar regions where upwelling occurs and high in subtropical regions dominated by downwelling. A core feature of these data is that 14C aging of DOC (682 ± 86 14C years) and dissolved inorganic carbon (643 ± 40 14C years) in Antarctic Bottom Water between 54.0°S and 53.5°N are similar. These estimates of aging are minimum values due to mixing with deep waters. We also observe minimum ∆14C values (−550‰ to −570‰) between the depths of 2,000 and 3,500 m in the North Pacific, though the source of the low values cannot be determined at this time.
    Description: We thank Jennifer Walker, Xiaomei Xu, and Dachun Zhang for their help with the stable carbon isotope measurements; John Southon and staff of the Keck Carbon Cycle AMS Laboratory for their assistance and advice; the support of chief scientists Samantha Siedlecki, Molly Baringer, Alison Macdonald, and Sabine Mecking; the guidance of Jim Swift and Dennis Hansell for shared ship time; and Sarah Bercovici for collecting water on the GoA cruise. We appreciate the comments of Christian Lewis and Niels Hauksson on this manuscript. This work was supported by NSF (OCE‐141458941 to E. R. M. D. and OCE‐0824864, OCE‐1558654, and Cooperative Agreement OCE1239667 to R. M. K. and A. P. M.), the Fred Kavli Foundation, the Keck Carbon Cycle AMS Laboratory, and the NSF/NOAA‐funded GO‐SHIP Program. This research was undertaken, in part, thanks to funding from the Canada Research Chairs program (to B. D. W.) and an American Chemical Society Petroleum Research Fund New Directions grant (55430‐ND2 to E. R. M. D. and B. D. W.). Data from the P16N cruises are available in Table S2 in the Supporting Information and at the Repeat Hydrography Data Center at the CCHDO website (http://cdiac.esd.ornl.gov/oceans/index.html) using the expo codes 3RO20150329, 3RO20150410, and 3RO20150525. There are no real or perceived financial conflicts of interests for any author.
    Description: 2019-11-02
    Keywords: Dissolved organic carbon ; Radiocarbon ; Pacific Ocean ; Dissolved inorganic carbon ; Deep ocean circulation ; AABW
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    Silica-rich vein formation in an evolving stress field, Atlantis Bank Oceanic Core Complex (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ma, Q., Dick, H. J. B., Urann, B., & Zhou, H. Silica-rich vein formation in an evolving stress field, Atlantis Bank Oceanic Core Complex. Geochemistry Geophysics Geosystems, 21(7), (2020): e2019GC008795, doi:10.1029/2019GC008795.
    Description: Drilling 809‐m Hole U1473A in the gabbro batholith at the Atlantis Bank Oceanic Core Complex (OCC) found two felsic vein generations: late magmatic fractionates, rich in deuteric water, hosted by oxide gabbros, and anatectic veins associated with dike intrusion and introduction of seawater‐derived volatiles. Microtextures show a change from compressional to tensional stress during vein formation. Temperatures and oxidation state were obtained from amphibole‐plagioclase and oxide pairs in the adjacent gabbros. Type I veins generally have reverse shear‐sense, with restricted ΔFMQ, high Mt/Ilm ratios, and low‐amphibole Cl/F indicating deuteric fluids. They formed during percolation and fractionation of Fe‐Ti‐rich melts into the primary olivine gabbro. Type II veins are usually hosted by olivine gabbro, occur at dike contacts and the margins of normal‐sense shear zones. They are undeformed or weakly deformed, with highly variable ΔFMQ, low Mt/Ilm ratios, and high‐amphibole Cl/F, indicating seawater‐derived fluids. The detachment fault on which the gabbro massif was emplaced rooted near the base of the dike‐gabbro transition beneath the rift valley. The ingress of seawater volatiles began at 〉800°C and penetrated at least ~590 m into the lower crust during extensional faulting in the rift valley and adjacent rift mountains. The sequence of the felsic vein formation likely reflects asymmetric diapiric flow, with a reversal of the stress regime, and a transition from juvenile to seawater‐derived volatiles. This, in turn, is consistent with fault capture leading to the large asymmetries in spreading rates during OCC formations and heat flow beneath the rift mountains.
    Description: This study was supported by the Chinese National Key Basic Research Program (Grant 2012CB417300). H. Dick and B. Urann were supported by U.S. National Science Foundation (Grant OCE‐MG&G 8371300). Emmanuel Codillo provided numerous useful comments and moral support. We thank N. Chatterjee for assistance in analyzing major element mineral composition in the MIT Electron Microprobe Laboratory. The great contributions of 360 Scientific Party for their initial shipboard description and interpretations of the Hole U1473A cores made this work possible. Special thanks go to C. J. MacLeod, Expedition cochief scientist, and Peter Blum, staff scientist, Stephen Midgley, IODP operations superintendent, and Siem Offshore James Samuel McLelland, offshore installation manager, ship's master Terry Skinner, and the crew and drillers on the JOIDES Resolution.
    Keywords: Felsic veins ; Magma chambers ; Ocean ridge ; Geothermometry ; Flourine‐chlorine ; Dynamics
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    Exceptional 20th century ocean circulation in the Northeast Atlantic (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Spooner, P. T., Thornalley, D. J. R., Oppo, D. W., Fox, A. D., Radionovskaya, S., Rose, N. L., Mallett, R., Cooper, E., & Roberts, J. M. Exceptional 20th century ocean circulation in the Northeast Atlantic. Geophysical Research Letters, 47(10), (2020): e2020GL087577, doi:10.1029/2020GL087577.
    Description: The North Atlantic subpolar gyre (SPG) connects tropical and high‐latitude waters, playing a leading role in deep‐water formation, propagation of Atlantic water into the Arctic, and as habitat for many ecosystems. Instrumental records spanning recent decades document significant decadal variability in SPG circulation, with associated hydrographic and ecological changes. Emerging longer‐term records provide circumstantial evidence that the North Atlantic also experienced centennial trends during the 20th century. Here, we use marine sediment records to show that there has been a long‐term change in SPG circulation during the industrial era, largely during the 20th century. Moreover, we show that the shift and late 20th century SPG configuration were unprecedented in the last 10,000 years. Recent SPG dynamics resulted in an expansion of subtropical ecosystems into new habitats and likely also altered the transport of heat to high latitudes.
    Description: We thank Janet Hope and UCL laboratory staff, colleagues who sailed on EN539, Kathryn Pietro‐Rose, Sean O'Keefe and Henry Abrams, Sara Chipperton, Tanya Monica, Laura Thrower and Kitty Green for sediment processing, Miles Irving for artwork assistance, James Rolfe for nitrogen isotope measurement, Maryline Vautravers and Michael Kucera for guidance, Arne Biastoch and Christian Mohn for discussion of VIKING20, and Chris Brierley, Meric Srokosz, and Jon Robson for comments. Funding was provided by National Science Foundation (NSF) grant OCE‐1304291 to D.W.O. and D.J.R.T., the Leverhulme Trust, National Environment Research Council (NERC) grant NE/S009736/1, and the ATLAS project to D.J.R.T. This project has received funding from the European Union's Horizon 2020 research and innovation program under grant agreement 678760 (ATLAS). This paper reflects only the authors views and the European Union cannot be held responsible for any use that may be made of the information contained herein.
    Keywords: Foraminifera ; Subpolar gyre ; North Atlantic ; Ocean circulation ; Industrial era
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    Equatorial circulation in the western Indian Ocean during onset of the 2018 summer monsoon and links to the Bay of Bengal (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(10), (2020): e2020GL087215, doi:10.1029/2020GL087215.
    Description: Cross‐equator transects occupied by an underwater glider and a research vessel in the western Indian Ocean captured the evolution of equatorial circulation during onset of the boreal summer monsoon in 2018. At the end of the winter monsoon in March, surface currents were westward, while the equatorial undercurrent carried salty Arabian Sea High‐Salinity Water eastward. As winds transitioned from westward to eastward during April, an eastward near‐surface Wyrtki Jet developed, while the equatorial undercurrent weakened, vanishing by May. A first‐mode baroclinic Kelvin wave propagated through the survey region after westward winds relaxed. However, the vertical structure of the evolving circulation was inconsistent with the first baroclinic mode, suggesting the influence of higher modes in setting observed vertical structure. The strong equatorial undercurrent at the end of the winter monsoon allowed high‐salinity waters from the western equatorial Indian Ocean to reach the southern Bay of Bengal in summer 2018.
    Description: This work was supported by the Office of Naval Research as part of the NASCar DRI under Grant N000141512632 and as part of the MISO‐BOB DRI under Grant N000141712968.
    Keywords: Monsoon ; Indian Ocean ; Equatorial ; Underwater glider ; Equatorial undercurrent
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  • 85
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    Observations and a model of net calcification declines in Palau's largest coral reef lagoon between 1992 and 2015 (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016147, doi:10.1029/2020JC016147.
    Description: Net ecosystem calcification (NEC) rates of Palau's largest lagoon and barrier reef system between 1992 and 2015 are estimated from sparse total alkalinity (TA) and salinity measurements and a tidal exchange model in which surface lagoon water transported offshore on the ebb tide is replaced by saltier (denser) ocean water that sinks to the bottom after entering the lagoon on the flood tide. Observed lagoon salinities are accurately reproduced by the model with no adjustable parameters. To accurately reproduce observed lagoon TA, NEC for the lagoon‐barrier reef system was 70 mmols m−2 day−1 from 1992 to 1998, 35 mmols m−2 day−1 from 1999 to 2012, and 25 mmols m−2 day−1 from 2013 to 2015. This indicates that Palau's largest lagoon and barrier reef system has not recovered, as of 2015, from the 50% decline in NEC in 1998 caused by the loss of coral cover following a severe bleaching event. The cause of the further decline in NEC in 2012–2013 is unclear. Lagoon residence times vary from 8 days during spring tides to 14 days during neap tides and drive substantial spring‐neap variations in lagoon TA (~25% of the mean salinity‐normalized ocean‐lagoon TA difference). Sparse measurements that do not resolve these spring‐neap variations can exhibit apparent long‐term variations in alkalinity that are not due to changes in NEC.
    Description: This work was partially supported by NSF award 1220529 to A.L.C., S.J.L., and K.E.F.S and NSF award 1737311 to A.L.C. and the Oceanography Department, Texas A&M University K.E.F.S.
    Description: 2021-01-06
    Keywords: Coral reef ; Calcification ; Bleaching ; Residence time ; Net ecosystem calcification ; Palau
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  • 86
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    Intercomparison of XRF core scanning results from seven labs and approaches to practical calibration (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Dunlea, A. G., Murray, R. W., Tada, R., Alvarez-Zarikian, C. A., Anderson, C. H., Gilli, A., Giosan, L., Gorgas, T., Hennekam, R., Irino, T., Murayama, M., Peterson, L. C., Reichart, G., Seki, A., Zheng, H., & Ziegler, M. Intercomparison of XRF core scanning results from seven labs and approaches to practical calibration. Geochemistry Geophysics Geosystems, 21(9), (2020): e2020GC009248, doi:10.1029/2020GC009248.
    Description: X‐ray fluorescence (XRF) scanning of marine sediment has the potential to yield near‐continuous and high‐resolution records of elemental abundances, which are often interpreted as proxies for paleoceanographic processes over different time scales. However, many other variables also affect scanning XRF measurements and convolute the quantitative calibrations of element abundances and comparisons of data from different labs. Extensive interlab comparisons of XRF scanning results and calibrations are essential to resolve ambiguities and to understand the best way to interpret the data produced. For this study, we sent a set of seven marine sediment sections (1.5 m each) to be scanned by seven XRF facilities around the world to compare the outcomes amidst a myriad of factors influencing the results. Results of raw element counts per second (cps) were different between labs, but element ratios were more comparable. Four of the labs also scanned a set of homogenized sediment pellets with compositions determined by inductively coupled plasma‐optical emission spectrometry (ICP‐OES) and ICP‐mass spectrometry (MS) to convert the raw XRF element cps to concentrations in two ways: a linear calibration and a log‐ratio calibration. Although both calibration curves are well fit, the results show that the log‐ratio calibrated data are significantly more comparable between labs than the linearly calibrated data. Smaller‐scale (higher‐resolution) features are often not reproducible between the different scans and should be interpreted with caution. Along with guidance on practical calibrations, our study recommends best practices to increase the quality of information that can be derived from scanning XRF to benefit the field of paleoceanography.
    Description: Funding for this research was provided by the U.S. National Science Foundation to R. W. M. (Grant 1130531). USSSP postcruise support was provided to Expedition 346 shipboard participants A. G. D., R. W. M., L. G., C. A. Z., and L. P. Portions of this material are based upon work supported while R. W. M. was serving at the National Science Foundation.
    Keywords: XRF scanning ; Quantitative XRF ; Paleoceanography ; Sedimentary geochemistry ; XRF calibration ; XRF intercomparison
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  • 87
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    Enormous lithium isotopic variations of abyssal peridotites reveal fast cooling and Melt/Fluid-rock interactions (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 125(9),(2020): e2020JB020393, doi:10.1029/2020JB020393.
    Description: Fast diffusing Li isotopes provide important insights into the “recent” transient events or processes for both modern and ancient times, but questions remain concerning the large Li isotopic variations of mantle peridotites, which greatly hampers their usage as a geochemical tracer. This study investigates in situ Li content and isotopic profiles of the constituent minerals of abyssal peridotites from the Gakkel Ridge and Southwest Indian Ridge. The complicated and large variations of Li isotopic profiles in Clinopyroxene (Cpx) and Orthopyroxene (Opx) indicate Li isotopic disequilibrium at millimeter scale. The negative correlations of a wide range of Li contents (0.5 to 6.5 ppm) and δ7Li values (−10 to +20‰) of olivine, Opx and Cpx grains/relicts, trace element zoning of Cpx, the occurrence of plagioclase, olivine serpentinization along cracks, together with numerical modeling demonstrate the observed Li characteristics to be a manifestation of high‐temperature mineral‐melt Li diffusion during melt impregnation overprinted by low‐temperature mineral‐fluid Li diffusion during dissolution and serpentinization. The preservation of the Li isotopic diffusion profiles requires rapid cooling of 0.3–5°C/year after final‐stage melt impregnation at the Moho boundary, which is consistent with the low temperature at very slow spreadin g ridges caused by conductive cooling. Compared with the well‐studied melt‐rock interaction process, our study indicates that low‐temperature fluid‐rock interaction can induce Li diffusion even in the visibly unaltered mineral relicts of partially altered rocks.
    Description: This study was financially supported by the National Science Foundation of China (grant no. 41872058) and the U.S. National Science Foundation grant.
    Description: 2021-03-07
    Keywords: Li isotope ; Abyssal peridotite ; Isotope diffusion ; Melt‐rock interaction ; Fluid‐rock interaction
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    Ocean circulation and variability beneath Nioghalvfjerdsbrae (79 North Glacier) ice tongue (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016091, doi:10.1029/2020JC016091.
    Description: The floating ice tongue of 79 North Glacier, a major outlet glacier of the Northeast Greenland Ice Stream, has thinned by 30% since 1999. Earlier studies have indicated that long‐term warming of Atlantic Intermediate Water (AIW) is likely driving increased basal melt, causing the observed thinning. Still, limited ocean measurements in 79 North Fjord beneath the ice tongue have made it difficult to test this hypothesis. Here we use data from an Ice Tethered Mooring (ITM) deployed in a rift in the ice tongue from August 2016 to July 2017 to show that the subannual AIW temperature variability is smaller than the observed interannual variability, supporting the conclusion that AIW has warmed over the period of ice tongue thinning. In July 2017, the AIW at 500 m depth in the ice tongue cavity reached a maximum recorded temperature of 1.5°C. Velocity measurements reveal weak tides and a mean overturning circulation, which is likely seasonally enhanced by subglacial runoff discharged at the grounding line. Deep inflow of AIW and shallow export of melt‐modified water persist throughout the record, indicating year‐round basal melting of the ice tongue. Comparison with a mooring outside of the cavity suggests a rapid exchange between the cavity and continental shelf. Warming observed during 2016–2017 is estimated to drive a 33 ± 20% increase in basal melt rate near the ice tongue terminus and a 14 ± 2% increase near the grounding line if sustained.
    Description: Funding for the ITM was provided by the Grossman Family Foundation through the WHOI Development Office. M. R. L. is supported by a National Defense Science and Engineering Graduate Fellowship. N. L. B. is supported by a grant from the National Science Foundation (NSF OCE‐1536856).
    Description: 2021-02-10
    Keywords: 79 North ; Basal melt ; Fjord ; Greenland ; Ice ocean interaction ; Ice shelf
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    The air-sea response during Hurricane Irma's (2017) rapid intensification over the Amazon-Orinoco River plume as measured by atmospheric and oceanic observations (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Atmospheres 125(18), (2020): e2019JD032368, doi:10.1029/2019JD032368.
    Description: Hurricane Irma (2017) underwent rapid intensification (RI) while passing over the Amazon‐Orinoco River plume in the tropical Atlantic. The freshwater discharge from the plume creates a vertical salinity gradient that suppresses turbulent heat flux from the cool, ocean subsurface. The stability within the plume reduces sea surface temperature (SST) cooling and promotes energetic air‐sea fluxes. Hence, it is hypothesized that this ocean feature may have facilitated Irma's RI through favorable upper ocean conditions. This hypothesis is validated using a collection of atmospheric and oceanic observations to quantify how the ocean response influences surface flux and atmospheric boundary layer thermodynamics during Hurricane Irma's RI over the river plume. Novel aircraft‐deployed oceanic profiling floats highlight the detailed evolution of the ocean response during Irma's passage over the river plume. Analyses include quantifying the ocean response and identifying how it influenced atmospheric boundary layer temperature, moisture, and equivalent potential temperature (θE). An atmospheric boundary layer recovery analysis indicates that surface fluxes were sufficient to support the enhanced boundary layer θE (moist entropy) observed, which promotes inner‐core convection and facilitates TC intensification. The implicit influence of salinity stratification on Irma's intensity during RI is assessed using theoretical intensity frameworks. Overall, the findings suggest that the salinity stratification sustained SST during Irma's passage, which promoted energetic air‐sea fluxes that aided in boundary layer recovery and facilitated Irma's intensity during RI. Examination of the air‐sea coupling over this river plume, corresponding atmospheric boundary layer response, and feedback on TC intensity was previously absent in literature.
    Description: This research was performed while the corresponding author held an NRC Research Associateship Award at the U.S. Naval Research Lab, Monterey. Chen is supported by Office of Naval Research (ONR) grant N0001416WX00470. Sanabia is sponsored by ONR grants N0001416WX01384 and N0001416WX01262. Jayne is supported by National Oceanic and Atmospheric Administration (NOAA) grant NA13OAR4830233.The authors gratefully acknowledge the HRD scientists, NOAA AOC crews, U.S. Air Force crews, and U.S. Navy crews who were involved in the collection of both atmospheric and oceanic data. This research would not be possible without your efforts. We are thankful for helpful discussion and pre‐RI AXBT data provided by Jun Zhang (NOAA/HRD).
    Description: 2020-12-12
    Keywords: Hurricane Irma ; Air-sea interaction ; Atmospheric boundary layer ; River plume ; Tropical cyclone ; Upper ocean response
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    Understanding of contemporary regional sea-level change and the implications for the future (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Reviews of Geophysics 58(3), (2020): e2019RG000672, doi:10.1029/2019RG000672.
    Description: Global sea level provides an important indicator of the state of the warming climate, but changes in regional sea level are most relevant for coastal communities around the world. With improvements to the sea‐level observing system, the knowledge of regional sea‐level change has advanced dramatically in recent years. Satellite measurements coupled with in situ observations have allowed for comprehensive study and improved understanding of the diverse set of drivers that lead to variations in sea level in space and time. Despite the advances, gaps in the understanding of contemporary sea‐level change remain and inhibit the ability to predict how the relevant processes may lead to future change. These gaps arise in part due to the complexity of the linkages between the drivers of sea‐level change. Here we review the individual processes which lead to sea‐level change and then describe how they combine and vary regionally. The intent of the paper is to provide an overview of the current state of understanding of the processes that cause regional sea‐level change and to identify and discuss limitations and uncertainty in our understanding of these processes. Areas where the lack of understanding or gaps in knowledge inhibit the ability to provide the needed information for comprehensive planning efforts are of particular focus. Finally, a goal of this paper is to highlight the role of the expanded sea‐level observation network—particularly as related to satellite observations—in the improved scientific understanding of the contributors to regional sea‐level change.
    Description: The research was carried out in part at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration. The authors acknowledge support from the National Aeronautics and Space Administration under Grants 80NSSC17K0565, 80NSSC170567, 80NSSC17K0566, 80NSSC17K0564, and NNX17AB27G. A. A. acknowledges support under GRACE/GRACEFO Science Team Grant (NNH15ZDA001N‐GRACE). T. W. acknowledges support by the National Aeronautics and Space Administration (NASA) under the New (Early Career) Investigator Program in Earth Science (Grant: 80NSSC18K0743). C. G. P was supported by the J. Lamar Worzel Assistant Scientist Fund and the Penzance Endowed Fund in Support of Assistant Scientists at the Woods Hole Oceanographic Institution.
    Keywords: Sea level ; Satellite observations ; Remote sensing
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    The rheological behavior of CO2 ice: application to glacial flow on Mars (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(22), (2020): e2020GL090431, doi:10.1029/2020GL090431.
    Description: Vast quantities of solid CO2 reside in topographic basins of the south polar layered deposits (SPLD) on Mars and exhibit morphological features indicative of glacial flow. Previous experimental studies showed that CO2 ice is 1–2 orders of magnitude weaker than water ice under Martian polar conditions. Here we present data from deformation experiments on pure, fine‐grained CO2 ice, over a broader range of temperatures than previously explored (158–213 K). The experiments confirm previous observations of highly nonlinear power law creep at larger stresses, but also show a transition to a previously unseen linear‐viscous creep regime at lower stresses. We examine the viscosity of CO2 within the SPLD and predict that the CO2‐rich deposits are modestly stronger than previously thought. Nevertheless, CO2 ice flows much more readily than H2O ice, particularly on the steep flanks of SPLD topographic basins, allowing the CO2 to pond as observed.
    Description: This work was funded by NASA grant NNH16ZDA001N‐SSW awarded to Smith and Goldsby. Additional salary support for Cross was provided by the WHOI Investment in Science Fund.
    Description: 2021-04-29
    Keywords: SPLD ; Mars ; Glacier ; Carbon dioxide ; Flow law ; Creep
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  • 92
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    Fate of internal waves on a shallow shelf (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015377, doi:10.1029/2019JC015377.
    Description: Internal waves strongly influence the physical and chemical environment of coastal ecosystems worldwide. We report novel observations from a distributed temperature sensing (DTS) system that tracked the transformation of internal waves from the shelf break to the surf zone over a narrow shelf slope region in the South China Sea. The spatially continuous view of temperature fields provides a perspective of physical processes commonly available only in laboratory settings or numerical models, including internal wave reflection off a natural slope, shoreward transport of dense fluid within trapped cores, and observations of internal rundown (near‐bed, offshore‐directed jets of water preceding a breaking internal wave). Analysis shows that the fate of internal waves on this shelf—whether transmitted into shallow waters or reflected back offshore—is mediated by local water column density structure and background currents set by the previous shoaling internal waves, highlighting the importance of wave‐wave interactions in nearshore internal wave dynamics.
    Description: We are grateful for the support of the Dongsha Atoll Research Station (DARS) and the Dongsha Atoll Marine National Park, whose efforts made this research possible. The authors would also like to thank A. Hall, S. Tyler, and J. Selker from the Center for Transformative Environmental Monitoring Programs (CTEMPs) funded by the National Science Foundation (EAR awards 1440596 and 1440506), G. Lohmann from WHOI, A. Safaie from UC Irvine, G. Wong, L. Hou, F. Shiah, and K. Lee from Academia Sinica for providing logistical and field support, as well as E. Pawlak, S. Lentz, B. Sanders, and S. Grant for equipment, and B. Raubenheimer, S. Elgar, R. Walter and D. Lucas for informative discussions that improved this work. We acknowledge the US Army Research Laboratory DoD Supercomputing Resource Center for computer time on Excalibur, which was used for the numerical simulations in this work. Funding for this work supported by Academia Sinica and for K.D. and E.R. from NSF‐OCE 1753317 and for O.F., J.R., and R.A. from ONR Grant 1182789‐1‐TDZZM. A portion of this work (R.A.) was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE‐AC52‐07NA27344.
    Description: 2020-10-21
    Keywords: Internal waves ; Distributed temperature sensing ; Coral reef ; Internal wave reflection
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    From Andes to Amazon: assessing branched tetraether lipids as tracers for soil organic carbon in the Madre de Dios River system (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kirkels, F. M. S. A., Ponton, C., Galy, V., West, A. J., Feakins, S. J., & Peterse, F. From Andes to Amazon: assessing branched tetraether lipids as tracers for soil organic carbon in the Madre de Dios River system. Journal of Geophysical Research-Biogeosciences, 125(1), (2020): e2019JG005270, doi:10.1029/2019JG005270.
    Description: We investigate the implications of upstream processes and hydrological seasonality on the transfer of soil organic carbon (OC) from the Andes mountains to the Amazon lowlands by the Madre de Dios River (Peru), using branched glycerol dialkyl glycerol tetraether (brGDGT) lipids. The brGDGT signal in Andean soils (0.5 to 3.5 km elevation) reflects air temperature, with a lapse rate of −6.0 °C/km elevation (r 2 = 0.89, p 〈 0.001) and −5.6 °C/km elevation (r 2 = 0.89, p 〈 0.001) for organic and mineral horizons, respectively. The same compounds are present in river suspended particulate matter (SPM) with a lapse rate of −4.1 °C/km elevation (r 2 = 0.82, p 〈 0.001) during the wet season, where the offset in intercept between the temperature lapse rates for soils and SPM indicates upstream sourcing of brGDGTs. The lapse rate for SPM appears insensitive to an increasing relative contribution of 6‐methyl isomer brGDGTs produced within the river. River depth profiles show that brGDGTs are well mixed in the river and are not affected by hydrodynamic sorting. The brGDGTs accumulate relative to OC downstream, likely due to the transition of particulate OC to the dissolved phase and input of weathered soils toward the lowlands. The temperature‐altitude correlation of brGDGTs in Madre de Dios SPM contrasts with the Lower Amazon River, where the initial soil signature is altered by changes in seasonal in‐river production and variable provenance of brGDGTs. Our study indicates that brGDGTs in the Madre de Dios River system are initially soil derived and highlights their use to study OC sourcing in mountainous river systems.
    Description: The brGDGT analyses were supported by NWO‐Veni grant 863.13.016 to F.P. This material is based upon work supported by the US National Science Foundation under grant EAR‐1227192 to A. J. W. and S. J. F. for the river fieldwork and lipid purification. In Perú, we thank the Servicio Nacional de Áreas Naturales Protegidas por el Estado (SERNANP) and personnel of Manu and Tambopata National Parks for logistical assistance and permission to work in the protected areas. We thank the Explorers' Inn and the Pontifical Catholic University of Perú (PUCP), as well as the Amazon Conservation Association for the use of the Tambopata and Wayqecha Research Stations, respectively. For river fieldwork assistance, we thank M. Torres, A. Robles, and A. Cachuana. Soil samples were contributed by Andrew Nottingham and Patrick Meir. Logistical support was provided by Y. Malhi, J. Huaman, W. Huaraca Huasco, and other collaborators as part of the Andes Biodiversity and Ecosystems Research Group ABERG (www.andesresearch.org). We thank Dominika Kasjaniuk for technical support at Utrecht. Two anonymous reviewers have provided valuable comments that have helped to improve this manuscript. Geochemical and brGDGT data are available in the PANGAEA Data Repository (Kirkels et al., 2019) and can be accessed at https://doi.pangaea.de/10.1594/PANGAEA.906170
    Keywords: Bacterial membrane lipids (brGDGTs) ; Altitude‐temperature relations ; Amazon headwaters ; Soil‐river connectivity ; Riverine organic carbon transport, brGDGT proxy signal
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  • 94
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    How does viscosity contrast influence phase mixing and strain localization? (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 125 (2020): e2020JB020323, doi: 10.1029/2020JB020323.
    Description: Ultramylonites—intensely deformed rocks with fine grain sizes and well‐mixed mineral phases—are thought to be a key component of Earth‐like plate tectonics, because coupled phase mixing and grain boundary pinning enable rocks to deform by grain‐size‐sensitive, self‐softening creep mechanisms over long geologic timescales. In isoviscous two‐phase composites, “geometric” phase mixing occurs via the sequential formation, attenuation (stretching), and disaggregation of compositional layering. However, the effects of viscosity contrast on the mechanisms and timescales for geometric mixing are poorly understood. Here, we describe a series of high‐strain torsion experiments on nonisoviscous calcite‐fluorite composites (viscosity contrast, ηca/ηfl ≈ 200) at 500°C, 0.75 GPa confining pressure, and 10−6–10−4 s−1 shear strain rate. At low to intermediate shear strains (γ ≤ 10), polycrystalline domains of the individual phases become sheared and form compositional layering. As layering develops, strain localizes into the weaker phase, fluorite. Strain partitioning impedes mixing by reducing the rate at which the stronger (calcite) layers deform, attenuate, and disaggregate. Even at very large shear strains (γ ≥ 50), grain‐scale mixing is limited, and thick compositional layers are preserved. Our experiments (1) demonstrate that viscosity contrasts impede mechanical phase mixing and (2) highlight the relative inefficiency of mechanical mixing. Nevertheless, by employing laboratory flow laws, we show that “ideal” conditions for mechanical phase mixing may be found in the wet middle to lower continental crust and in the dry mantle lithosphere, where quartz‐feldspar and olivine‐pyroxene viscosity contrasts are minimized, respectively.
    Description: This work was funded through a National Science Foundation grant (EAR‐1352306) awarded to P. S., with additional support for A. J. C. provided by the McDonnell Center for the Space Sciences (Washington University in St. Louis), the J. Lamar Worzel Assistant Scientist Fund (WHOI), and the Penzance Endowed Fund in Support of Assistant Scientists (WHOI). Partial support for electron microscopy was provided by the Institute of Materials Science and Engineering (Washington University in St. Louis).
    Description: 2021-02-04
    Keywords: Ultramylonite ; Geometric mixing ; Strain partitioning ; Shear zone ; Calcite ; Torsion
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  • 95
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    Changes in the arctic ocean carbon cycle with diminishing ice cover (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in DeGrandpre, M., Evans, W., Timmermans, M., Krishfield, R., Williams, B., & Steele, M. Changes in the arctic ocean carbon cycle with diminishing ice cover. Geophysical Research Letters, 47(12), (2020): e2020GL088051, doi:10.1029/2020GL088051.
    Description: Less than three decades ago only a small fraction of the Arctic Ocean (AO) was ice free and then only for short periods. The ice cover kept sea surface pCO2 at levels lower relative to other ocean basins that have been exposed year round to ever increasing atmospheric levels. In this study, we evaluate sea surface pCO2 measurements collected over a 6‐year period along a fixed cruise track in the Canada Basin. The measurements show that mean pCO2 levels are significantly higher during low ice years. The pCO2 increase is likely driven by ocean surface heating and uptake of atmospheric CO2 with large interannual variability in the contributions of these processes. These findings suggest that increased ice‐free periods will further increase sea surface pCO2, reducing the Canada Basin's current role as a net sink of atmospheric CO2.
    Description: This research was made possible by grants from the NSF Arctic Observing Network program (ARC‐1107346, PLR‐1302884, PLR‐1504410, and OPP‐1723308). In addition, M. S. was supported by ONR (Grant 00014‐17‐1‐2545), NASA (Grant NNX16AK43G), and NSF (Grants PLR‐1503298 and OPP‐1751363).
    Keywords: Arctic Ocean ; Ice concentration ; Seawater CO2 ; Interannual variability ; Canada Basin ; Shipboard CO2 measurements
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  • 96
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    Using the sigma-pi diagram to analyze water masses in the northern South China Sea in spring (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(7), (2020): e2019JC015676, doi:10.1029/2019JC015676.
    Description: The temperature‐salinity (T‐S) diagram is widely used in water mass analysis, but the boundaries between water masses are vaguely distinguished by conventional T‐S‐based methods. Herein, we propose a new method based on the potential density‐potential spicity (sigma‐pi) diagram. The new method has been applied to the conductivity‐temperature‐depth data collected in the northern South China Sea during a spring cruise in 2011. The water masses in the study region are classified into 13 types according to both the standard deviation of potential spicity in each potential density layer and the water volumetric distribution in the sigma‐pi space. The results suggest that this new method is reasonable and robust for classifying water masses in the sigma‐pi space as compared to previous methods based on the traditional T‐S space. In addition, the westward intrusion of the West Pacific Ocean water to the northern South China Sea can be clearly detected by the tongue‐like potential spicity structure and relatively high potential spicity patches on potential density layers, further verifying the robustness and efficiency of our method in the water mass analysis.
    Description: This work was supported by the National Natural Science Foundation of China (91958203, 41776027, and 11732010) and the National Basic Research Program of China (2015CB954004 and 2009CB421208). Funding of Y.G.'s cotutelle doctoral research project by Région Hauts‐de‐France and Xiamen University is acknowledged. All the cruise participants are appreciated. We also thank the editor and anonymous reviewers for their valuable comments.
    Description: 2020-12-20
    Keywords: Water mass ; Spicity ; Northern South China Sea
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  • 97
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    Sea-level rise will drive divergent sediment transport patterns on fore reefs and reef flats, potentially causing erosion on Atoll Islands (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 125 (2020): e2019JF005446, doi: 10.1029/2019JF005446.
    Description: Atoll reef islands primarily consist of unconsolidated sediment, and their ocean‐facing shorelines are maintained by sediment produced and transported across their reefs. Changes in incident waves can alter cross‐shore sediment exchange and, thus, affect the sediment budget and morphology of atoll reef islands. Here we investigate the influence of sea level rise and projected wave climate change on wave characteristics and cross‐shore sediment transport across an atoll reef at Kwajalein Island, Republic of the Marshall Islands. Using a phase‐resolving model, we quantify the influence on sediment transport of quantities not well captured by wave‐averaged models, namely, wave asymmetry and skewness and flow acceleration. Model results suggest that for current reef geometry, sea level, and wave climate, potential bedload transport is directed onshore, decreases from the fore reef to the beach, and is sensitive to the influence of flow acceleration. We find that a projected 12% decrease in annual wave energy by 2100 CE has negligible influence on reef flat hydrodynamics. However, 0.5–2.0 m of sea level rise increases wave heights, skewness, and shear stress on the reef flat and decreases wave skewness and shear stress on the fore reef. These hydrodynamic changes decrease potential sediment inputs onshore from the fore reef where coral production is greatest but increase potential cross‐reef sediment transport from the outer reef flat to the beach. Assuming sediment production on the fore reef remains constant or decreases due to increasing ocean temperatures and acidification, these processes have the potential to decrease net sediment delivery to atoll islands, causing erosion.
    Description: This study was supported by the Strategic Environmental Research and Development Program through awards SERDP: RC‐2334, and RC‐2336. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Description: 2021-03-25
    Keywords: Coral atolls ; Fringing reefs ; Sediment transport ; Wave model ; Wave climate ; Sea level rise
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  • 98
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    The value of initial condition large ensembles to robust adaptation decision-making (2020)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Mankin, J. S., Lehner, F., Coats, S., & McKinnon, K. A. The value of initial condition large ensembles to robust adaptation decision-making. Earth's Future, 8(10), (2020): e2012EF001610, doi:10.1029/2020EF001610.
    Description: The origins of uncertainty in climate projections have major consequences for the scientific and policy decisions made in response to climate change. Internal climate variability, for example, is an inherent uncertainty in the climate system that is undersampled by the multimodel ensembles used in most climate impacts research. Because of this, decision makers are left with the question of whether the range of climate projections across models is due to structural model choices, thus requiring more scientific investment to constrain, or instead is a set of equally plausible outcomes consistent with the same warming world. Similarly, many questions faced by scientists require a clear separation of model uncertainty and that arising from internal variability. With this as motivation and the renewed attention to large ensembles given planning for Phase 7 of the Coupled Model Intercomparison Project (CMIP7), we illustrate the scientific and policy value of the attribution and quantification of uncertainty from initial condition large ensembles, particularly when analyzed in conjunction with multimodel ensembles. We focus on how large ensembles can support regional‐scale robust adaptation decision‐making in ways multimodel ensembles alone cannot. We also acknowledge several recently identified problems associated with large ensembles, namely, that they are (1) resource intensive, (2) redundant, and (3) biased. Despite these challenges, we show, using examples from hydroclimate, how large ensembles provide unique information for the scientific and policy communities and can be analyzed appropriately for regional‐scale climate impacts research to help inform risk management in a warming world.
    Description: F. L. has been supported by the Swiss NSF (grant no. PZ00P2_174128), the NSF Division of Atmospheric and Geospace Sciences (grant no. AGS‐0856145, Amendment 87), and the Regional and Global Model Analysis (RGMA) component of the Earth and Environmental System Modeling Program of the U.S.Department of Energy’s Office of Biological & Environmental Research (BER) via NSF IA 1844590. This is SOEST publication no. 11115.
    Keywords: Large ensembles ; Robust decision‐making ; Internal variability ; Initial conditions ; Climate adaptation
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  • 99
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    Nitrate supply routes and impact of internal cycling in the North Atlantic Ocean inferred from nitrate isotopic composition (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(4), (2021): e2020GB006887, https://doi.org/10.1029/2020GB006887.
    Description: In this study we report full-depth water column profiles for nitrogen and oxygen isotopic composition (δ15N and δ18O) of nitrate (NO3−) during the GEOTRACES GA01 cruise (2014). This transect intersects the double gyre system of the subtropical and subpolar regions of the North Atlantic separated by a strong transition zone, the North Atlantic Current. The distribution of NO3− δ15N and δ18O shows that assimilation by phytoplankton is the main process controlling the NO3− isotopic composition in the upper 150 m, with values increasing in a NO3− δ18O versus δ15N space along a line with a slope of one toward the surface. In the subpolar gyre, a single relationship between the degree of NO3− consumption and residual NO3− δ15N supports the view that NO3− is supplied via Ekman upwelling and deep winter convection, and progressively consumed during the Ekman transport of surface water southward. The co-occurrence of partial NO3− assimilation and nitrification in the deep mixed layer of the subpolar gyre elevates subsurface NO3− δ18O in comparison to deep oceanic values. This signal propagates through isopycnal exchanges to greater depths at lower latitudes. With recirculation in the subtropical gyre, cycles of quantitative consumption-nitrification progressively decrease subsurface NO3− δ18O toward the δ18O of regenerated NO3−. The low NO3− δ15N observed south of the Subarctic Front is mostly explained by N2 fixation, although a contribution from the Mediterranean outflow is required to explain the lower NO3− δ15N signal observed between 600 and 1500 m depth close to the Iberian margin.
    Description: The GEOVIDE project was co-funded by the French national program LEFE/INSU (GEOVIDE), ANR Blanc (GEOVIDE) and RPDOC, LabEX MER and IFREMER. F. Deman was supported by the Belgian Federal Science Policy Office (Belspo contract BL/12/C63) while writing the manuscript. This work was financed by Flanders Research Foundation (FWO contract G0715.12N) and Vrije Universiteit Brussel, R&D, Strategic Research Plan “Tracers of Past & Present Global Changes”. During the preparation of the manuscript, Debany Fonseca-Batista was supported by funding from the Canada First Research Excellence Fund, through an International Postdoctoral Fellowship of the Ocean Frontier Institute (OFI) at Dalhousie University.
    Description: 2021-10-02
    Keywords: Atlantic ; Isotopy ; Nitrate
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  • 100
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    Continental interior and edge breakup at convergent margins induced by subduction direction reversal: a numerical modeling study applied to the South China Sea margin (2021)
    American Geophysical Union
    Details
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Tectonics 39(11), (2020): e2020TC006409, doi:10.1029/2020TC006409.
    Description: The dynamics of continental breakup at convergent margins has been described as the results of backarc opening caused by slab rollback or drag force induced by subduction direction reversal. Although the rollback hypothesis has been intensively studied, our understanding of the consequence of subduction direction reversal remains limited. Using thermo‐mechanical modeling based on constraints from the South China Sea (SCS) region, we investigate how subduction direction reversal controls the breakup of convergent margins. The numerical results show that two distinct breakup modes, namely, continental interior and edge breakup (“edge” refers to continent above the plate boundary interface), may develop depending on the “maturity” of the convergent margin and the age of the oceanic lithosphere. For a slab age of ~15 to ~45 Ma, increasing the duration of subduction promotes the continental interior breakup mode, where a large block of the continental material is separated from the overriding plate. In contrast, the continental edge breakup mode develops when the subduction is a short‐duration event, and in this mode, a wide zone of less continuous continental fragments and tearing of the subducted slab occur. These two modes are consistent with the interior (relic late Mesozoic arc) and edge (relic forearc) rifting characteristics in the western and eastern SCS margin, suggesting that variation in the northwest‐directed subduction duration of the Proto‐SCS might be a reason for the differential breakup locus along the strike of the SCS margin. Besides, a two‐segment trench associated with the northwest‐directed subduction is implied in the present‐day SCS region.
    Description: This research was supported by the Guangdong NSF research team project (2017A030312002), the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (GML2019ZD0205), the K. C. Wong Education Foundation (GJTD‐2018‐13), the Strategic Priority Research Program of the Chinese Academy of Science (XDA13010303), the Chinese Academy of Sciences (Y4SL021001, QYZDY‐SSWDQC005, 133244KYSB20180029, and ISEE2019ZR01), the NSFC project (41606073, 41890813, and 41576070), the IODP‐China Foundation, the OMG Visiting Fellowship (OMG18‐15), and the Hong Kong Research Grant Council Grants (Nos. 14313816 and 14304820).
    Description: 2021-04-06
    Keywords: Continental breakup ; Convergent margins ; Edge breakup ; Subduction direction reversal ; Proto‐South China Sea ; Numerical modeling
    Repository Name: Woods Hole Open Access Server
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