ALBERT

Description: Idealized models or emulators of volcanic aerosol forcing have been widely used to reconstruct the spatiotemporal evolution of past volcanic forcing. However, existing models, including the most recently developed Easy Volcanic Aerosol (EVA; Toohey et al., doi: 10.5194/gmd‐2016‐83), (i) do not account for the height of injection of volcanic SO urn:x-wiley:jgrd:media:jgrd55987:jgrd55987-math-0001; (ii) prescribe a vertical structure for the forcing; and (iii) are often calibrated against a single eruption. We present a new idealized model, EVA_H, that addresses these limitations. Compared to EVA, EVA_H makes predictions of the global mean stratospheric aerosol optical depth that are (i) similar for the 1979–1998 period characterized by the large and high‐altitude tropical SO urn:x-wiley:jgrd:media:jgrd55987:jgrd55987-math-0002 injections of El Chichón (1982) and Mount Pinatubo (1991); (ii) significantly improved for the 1998–2015 period characterized by smaller eruptions with a large variety of injection latitudes and heights. Compared to EVA, the sensitivity of volcanic forcing to injection latitude and height in EVA_H is much more consistent with results from climate models that include interactive aerosol chemistry and microphysics, even though EVA_H remains less sensitive to eruption latitude than the latter models. We apply EVA_H to investigate potential biases and uncertainties in EVA‐based volcanic forcing data sets from phase 6 of the Coupled Model Intercomparison Project (CMIP6). EVA and EVA_H forcing reconstructions do not significantly differ for tropical high‐altitude volcanic injections. However, for high‐latitude or low‐altitude injections, our reconstructed forcing is significantly lower. This suggests that volcanic forcing in CMIP6 last millenium experiments may be overestimated for such eruptions.

Description: Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi-approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie-lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ. Key Points New Zealand's Neogene explosive volcanism based on the marine tephra record Geochemical fingerprinting of marine tephra layers across the study area to establish volcanic events Insights into geochemical variations with time, repose times and spatiotemporal distribution

Description: Submarine groundwater discharge (SGD) is a globally important process supplying nutrients and trace elements to the coastal environment, thus playing a pivotal role in sustaining marine primary productivity. Along with nutrients, groundwater also contains allochthonous microbes that are discharged from the terrestrial subsurface into the sea. Currently, little is known about the interactions between groundwater‐borne and coastal seawater microbial populations, and groundwater microbes' role upon introduction to coastal seawater populations. Here, we investigated seawater microbial abundance, activity and diversity in a site strongly influenced by SGD. In addition, through laboratory‐controlled bottle incubations, we mimicked different mixing scenarios between groundwater and seawater. Our results demonstrate that the addition of 0.1 μm filtered groundwater stimulated heterotrophic activity and increased microbial abundance compared to control coastal seawater, whereas 0.22 μm filtration treatments induced primary productivity and Synechococcus growth. 16S rRNA gene sequencing showed a strong shift from a SAR11‐rich community in the control samples to Rhodobacteraceae dominance in the 〈0.1 μm treatment, in agreement with Rhodobacteraceae enrichment in the SGD field site. These results suggest that microbes delivered by SGD may affect the abundance, activity and diversity of intrinsic microbes in coastal seawater, highlighting the cryptic interplay between groundwater and seawater microbes in coastal environments, which has important implications for carbon cycling. Plain Language Summary Submarine groundwater discharge (SGD) is an important process where groundwater flows into the ocean along the coast. When the groundwater mixes with seawater, the microbes from both sources interact with each other, which can impact the diversity, activity, and amount of microbes in the coastal environment. Currently, little is known about how groundwater‐borne microbes affect marine microbial populations. Our research shows that when groundwater microbes are removed before mixing groundwater with seawater, the abundance and activity of certain microbes that consume organic matter significantly increase. Additionally, we noticed a significant difference in the types of microbes present between the sites where SGD occurs versus background (uninfluenced) coastal water, especially in terms of the microbes that consume organic matter. Overall, this study suggests that there is a connection between groundwater and seawater microbes, which can influence the delicate balance between organisms that produce carbon and those that consume it. This has important implications for how carbon cycles globally. Key Points Groundwater discharge into the coastal zone delivers both nutrients and allochthonous microbes Groundwater microbes interact with seawater populations, by which affecting the delicate autotroph‐heterotroph balance Subterranean microbial processes are key drivers of food webs, potentially affecting biogenic carbon fluxes in the ocean

Description: Key Points: - A new CHBr3 emission inventory based on natural and anthropogenic sources suggests that the latter account for 12%–28% of the global emissions - In the NH, new anthropogenic estimates increase known natural CHBr3 emissions by up to 70.5%, leading to higher atmospheric CHBr3 levels - At the NH extratropical tropopause, CHBr3 is enhanced by 0.9 ppt Br due to anthropogenic sources thus doubling natural CHBr3 abundances Bromoform (CHBr3) contributes to stratospheric ozone depletion but is not regulated under the Montreal Protocol due to its short lifetime and large natural sources. Here, we show that anthropogenic sources contribute significantly to the amount of CHBr3 transported into the Northern Hemisphere (NH) extratropical stratosphere. We present a new CHBr3 emission inventory comprised of natural and anthropogenic sources, with the latter estimated from ship ballast, power plant cooling and desalination plant brine water. Including anthropogenic sources in the new inventory increases CHBr3 emissions by up to 31.5% globally and 70.5% in the NH. In consequence, atmospheric CHBr3 is also significantly higher, especially over the NH extratropics during boreal winter. Here anthropogenic sources enhance bromine at the tropopause by 0.9 ppt Br, thus doubling natural CHBr3 abundances. For some latitudes, tropopause bromine increases by 2.4 ppt Br suggesting significant contributions of anthropogenic CHBr3 to the NH lowermost stratosphere.

Description: A major stratospheric sudden warming (SSW) in January 2009 was the strongest and most prolonged on record. Aura Microwave Limb Sounder (MLS) observations are used to provide an overview of dynamics and transport during the 2009 SSW, and to compare with the intense, long-lasting SSW in January 2006. The Arctic polar vortex split during the 2009 SSW, whereas the 2006 SSW was a vortex displacement event. Winds reversed to easterly more rapidly and reverted to westerly more slowly in 2009 than in 2006. More mixing of trace gases out of the vortex during the decay of the vortex fragments, and less before the fulfillment of major SSW criteria, was seen in 2009 than in 2006; persistent well-defined fragments of vortex and anticyclone air were more prevalent in 2009. The 2009 SSW had a more profound impact on the lower stratosphere than any previously observed SSW, with no significant recovery of the vortex in that region. The stratopause breakdown and subsequent reformation at very high altitude, accompanied by enhanced descent into a rapidly strengthening upper stratospheric vortex, were similar in 2009 and 2006. Many differences between 2006 and 2009 appear to be related to the different character of the SSWs in the two years.

Description: A site at the gas hydrate stability limit was investigated offshore northwestern Svalbard to study methane transport in sediment. The site was characterized by chemosynthetic communities (sulfur bacteria mats, tubeworms) and gas venting. Sediments were sampled with in‐situ porewater collectors and by gravity coring followed by analyses of porewater constituents, sediment and carbonate geochemistry, and microbial activity, taxonomy, and lipid biomarkers. Sulfide and alkalinity concentrations showed concentration maxima in near‐surface sediments at the bacterial mat and deeper maxima at the gas vent site. Sediments at the periphery of the chemosynthetic field were characterized by two sulfate‐methane transition zones (SMTZ) at ~204 and 45 cm depth, where activity maxima of microbial anaerobic oxidation of methane (AOM) with sulfate were found. Amplicon sequencing and lipid biomarker indicate that AOM at the SMTZs was mediated by ANME‐1 archaea. A 1D numerical transport reaction model suggests that the deeper SMTZ‐1 formed on centennial scale by vertical advection of methane, while the shallower SMTZ‐2 could only be reproduced by non‐vertical methane injections starting on decadal scale. Model results were supported by age distribution of authigenic carbonates, showing youngest carbonates within SMTZ‐2. We propose that non‐vertical methane injection was induced by increasing blockage of vertical transport or formation of sediment fractures. Our study further suggests that the methanotrophic response to the non‐vertical methane injection was commensurate with new methane supply. This finding provides new information about for the response time and efficiency of the benthic methane filter in environments with fluctuating methane transport.

Description: Direct dimethyl sulfide (DMS) flux measurements using eddy covariance have shown a suppression of gas transfer at medium to high wind speed. However, not all eddy covariance measurements show evidence of this suppression. Processes, such as wave-wind interaction and surfactants, have been postulated to cause this suppression. We measured DMS and carbon dioxide eddy covariance fluxes during the Asian summer monsoon in the western tropical Indian Ocean (July and August 2014). Both fluxes and their respective gas transfer velocities show signs of a gas transfer suppression above 10 m/s. Using a wind-wave interaction, we describe a flow separation process that could be responsible for a suppression of gas transfer. As a result we provide a Reynolds number-based parameterization, which states the likelihood of a gas transfer suppression for this cruise and previously published gas transfer data. Additionally, we compute the difference in the gas transfer velocities of DMS and CO2 to estimate the bubble-mediated gas transfer using a hybrid model with three whitecap parameterizations.

Description: Oceanic dimethyl sulfide (DMS) is of interest due to its critical influence on atmospheric sulfur compounds in the marine atmosphere and its hypothesized significant role in global climate. High-resolution shipboard underway measurements of surface seawater DMS and the partial pressure of carbon dioxide (pCO2) were conducted in the Atlantic Ocean and Indian Ocean sectors of the Southern Ocean (SO), the southeast Indian Ocean, and the northwest Pacific Ocean from February to April 2014 during the 30th Chinese Antarctic Research Expedition. The SO, particularly in the region south of 58°S, had the highest mean surface seawater DMS concentration of 4.1 ± 8.3 nM (ranged from 0.1 to 73.2 nM) and lowest mean seawater pCO2 level of 337 ± 50 μatm (ranged from 221 to 411 μatm) over the entire cruise. Significant variations of surface seawater DMS and pCO2 in the seasonal ice zone (SIZ) of SO were observed, which are mainly controlled by biological process and sea ice activity. We found a significant negative relationship between DMS and pCO2 in the SO SIZ using 0.1° resolution, [DMS] seawater = -0.160 [pCO2] seawater + 61.3 (r2 = 0.594, n = 924, p 〈 0.001). We anticipate that the relationship may possibly be utilized to reconstruct the surface seawater DMS climatology in the SO SIZ. Further studies are necessary to improve the universality of this approach. Key Points: • The characteristics of surface water DMS and pCO2 distributions from the Southern Ocean to northwest Pacific Ocean are investigated • The correlations between DMS, pCO2, and environmental parameters are analyzed • Anticorrelation between DMS and pCO2 is found in the seasonal ice zone of the Southern Ocean

Description: Monthly zonal mean climatologies of atmospheric measurements from satellite instruments can have biases due to the non-uniform sampling of the atmosphere by the instruments. We characterize potential sampling biases in stratospheric trace gas climatologies of the Stratospheric Processes and their Role in Climate (SPARC) Data Initiative using chemical fields from a chemistry climate model simulation and sampling patterns from 16 satellite-borne instruments. The exercise is performed for the long-lived stratospheric trace gases O3 and H2O. Monthly sample biases for O3 exceed 10% for many instruments in the high latitude stratosphere and in the upper troposphere/lower stratosphere, while annual mean sampling biases reach values of up to 20% in the same regions for some instruments. Sampling biases for H2O are generally smaller than for O3, although still notable in the upper troposphere/lower stratosphere and Southern Hemisphere high latitudes. The most important mechanism leading to monthly sampling bias is the non-uniform temporal sampling of many instruments, i.e., the fact that for many instruments, monthly means are produced from measurements which span less than the full month in question. Similarly, annual mean sampling biases are well explained by non-uniformity in the month-to-month sampling by different instruments. Non-uniform sampling in latitude and longitude are shown to also lead to non-negligible sampling biases, which are most relevant for climatologies which are otherwise free of sampling biases due to non-uniform temporal sampling.

Description: In the framework of the European Project STAR the Mobile Aerosol Raman Lidar (MARL) of the Alfred Wegener Institute (AWI) was operated in Paramaribo, Suriname (5.8°N, 55.2°W), and carried out extensive observations of tropical cirrus clouds during the local dry season from 28 September 2004 to 16 November 2004. The coverage with ice clouds was very high with 81% in the upper troposphere (above 12 km). The frequency of occurrence of subvisual clouds was found to be clearly enhanced compared to similar observations performed with the same instrument at a station in the midlatitudes. The extinction-to-backscatter ratio of thin tropical cirrus is with 26 ± 7 sr significantly higher than that of midlatitude cirrus (16 ± 9 sr). Subvisual cirrus clouds often occur in the tropical tropopause layer (TTL) above an upper tropospheric inversion. Our observations show that the ice-forming ability of the TTL is very high. The transport of air in this layer was investigated by means of a newly developed trajectory model. We found that the occurrence of clouds is highly correlated with the temperature and humidity history of the corresponding air parcel. Air that experienced a temperature minimum before the measurement took place was generally cloud free, while air that was at its temperature minimum during the observation and thus was saturated contained ice. We also detected extremely thin cloud layers slightly above the temperature minimum in subsaturated air. The solid particles of such clouds are likely to consist of nitric acid trihydrate (NAT) rather than ice.

Description: Simplified representations of spatially inhomogeneous (three-dimensional (3-D)) clouds in radiative transfer models provide systematic errors when calculating solar broadband radiative fluxes. An example is the neglect of horizontal photon transports as it is the case for the independent column approximation (ICA). The present work tries to quantify and interpret these errors on the basis of a large set of 3-D mixed phase cloud scenarios with 3-D varying extinction coefficients, scattering phase functions, and single-scattering albedos. The cloud cases result from a mesoscale atmospheric circulation model with detailed cloud microphysics. Domain-averaged cloud radiative fluxes are calculated by means of a Monte Carlo radiative transfer model. Depending on cloud type and solar zenith angle (SZA) the differences between 3-D and ICA results range from +20 W m−2 to −30 W m−2 for the upward reflected fluxes and from +10 W m−2 to −7 W m−2 for the absorbed fluxes. The mean (averaged over all cloud realizations) errors of the ICA-based upward fluxes vary between 5 W m−2 overestimation at 15°SZA and 6 W m−2 underestimation at 75°SZA. The ICA underestimates the absorbed flux by ∼1–2 W m−2 for most SZA except for 75°. It is found that neglecting the horizontal variability of the absorption and scattering properties of the cloud hydrometeors leads to a general underestimation of solar broadband absorption by as much as 15 W m−2 with average values between 4 W m−2 at small SZA and 1 W m−2 at large SZA.

Description: Submarine groundwater discharge (SGD) into coastal areas is a common global phenomenon and is rapidly gaining scientific interest due to its influence on marine ecology, the coastal sedimentary environment and its potential as a future freshwater resource. We conducted an integrated study of hydroacoustic surveys combined with geochemical porewater and water column investigations at a well‐known groundwater seep site in Eckernförde Bay (Germany). We aim to better constrain the effects of shallow gas and SGD on high frequency multibeam backscatter data and to present acoustic indications for submarine groundwater discharge. Our high‐quality hydroacoustic data reveal hitherto unknown internal structures within the pockmarks in Eckernförde Bay. Using precisely positioned sediment core samples, our hydroacoustic‐geochemical approach can differentiate intra‐pockmark regimes that were formerly assigned to pockmarks of a different nature. We demonstrate that high‐frequency multibeam data, in particular the backscatter signals, can be used to detect shallow free gas in areas of enhanced groundwater advection in muddy sediments. Intriguingly, our data reveal relatively small (typically 〈15 m across) pockmarks within the much larger, previously mapped, pockmarks. The small pockmarks, which we refer to as “intra‐pockmarks”, have formed due to the localized ascent of gas and groundwater; they manifest themselves as a new type of ‘eyed’ pockmarks, revealed by their acoustic backscatter pattern. Our data suggest that, in organic‐rich muddy sediments, morphological lows combined with a strong multibeam backscatter signal can be indicative of free shallow gas and subsequent advective groundwater flow.

Description: The Los Chocoyos (14.6°N, 91.2°W) supereruption happened ∼75,000 years ago in Guatemala and was one of the largest eruptions of the past 100,000 years. It emitted enormous amounts of sulfur, chlorine, and bromine, with multi‐decadal consequences for the global climate and environment. Here, we simulate the impact of a Los Chocoyos‐like eruption on the quasi‐biennial oscillation (QBO), an oscillation of zonal winds in the tropical stratosphere, with a comprehensive aerosol chemistry Earth System Model. We find a ∼10‐year disruption of the QBO starting 4 months post eruption, with anomalous easterly winds lasting ∼5 years, followed by westerlies, before returning to QBO conditions with a slightly prolonged periodicity. Volcanic aerosol heating and ozone depletion cooling leads to the QBO disruption and anomalous wind regimes through radiative changes and wave‐mean flow interactions. Different model ensembles, volcanic forcing scenarios and results of a second model back up the robustness of our results.

Description: We show that inflows of oxygenated waters into sulfidic layers have a strong impact on biogeochemical transformation at oxic/anoxic transition zones. Taking the pelagic methane dynamics in the Gotland Basin as an example, we performed our studies when one of the largest inflows ever recorded entered the Baltic Sea in March 2015. An inflowing gravity current transported oxic waters into the sulfidic deep layers and freshly generated a near-bottom secondary redox interface. At the upper slope, where the inflowing water masses were vigorously turbulent and the main and secondary redox interfaces in close contact to each other, methane oxidation rates inside the transition zone were found to be higher compared to the weakly turbulent basin interior. At the main redox interface in the basin center, lateral intrusions of oxygenated waters into intermediate water depth may have stimulated the growth of the methanotrophic community and their activity.

Description: Mesoscale eddies are frequently observed in the Eastern Tropical North Atlantic (ETNA), yet their effects on the transport and distribution of biogeochemical solutes, and specifically on the production and remineralization of dissolved organic matter (DOM) remain difficult to elucidate. Here, we investigated the submesoscale variability of chromophoric DOM (CDOM) and fluorescent DOM (FDOM) together with microbial production and remineralization processes in two cyclonic eddies (CEs) in the ETNA during summer and winter 2019. One CE, formed near the coast off Mauritania during the post-upwelling season, was sampled along a ∼900 km zonal corridor between Mauritania and the Cape Verde Islands. The other CE, formed nearby Brava Island, was out of coastal influence. Four fluorescent components were identified with parallel factor analysis, two humic-like, and two protein-like components. Humic-like FDOM components correlated to optode-based community respiration and were also good indicators of upwelling associated with the Brava Island CE as they correlated to physical parameters (e.g., temperature) and to dissolved inorganic nitrogen. The tryptophan-like FDOM components correlated with the carbon and nitrogen content of semi-labile DOM, phytoplankton biomass, community respiration, and bacterial production. Overall, our study revealed that DOM optical properties are suitable for tracing freshly produced organic matter and the transport of remineralized DOM within offshore eddies. Key Points: - Four fluorescent dissolved organic matter (FDOM) components were studied in two cyclonic eddies (CEs) in the Eastern Tropical North Atlantic - Tryptophan-like FDOM was an indicator of the CEs' productivity as it correlated with semi-labile dissolved organic matter and microbial metabolic activities - Humic-like FDOM was a by-product of microbial respiration; its distribution within an offshore CE covaried with nutrient upwelling

Description: This study performed the first assessment of the volcanic gas output from the Central Volcanic Zone (CVZ) of northern Chile. We present the fluxes and compositions of volcanic gases (H2O, CO2, H2, HCl, HF, and HBr) from five of the most actively degassing volcanoes in this region—Láscar, Lastarria, Putana, Ollagüe, and San Pedro—obtained during field campaigns in 2012 and 2013. The inferred gas plume compositions for Láscar and Lastarria (CO2/Stot = 0.9–2.2; Stot/HCl = 1.4–3.4) are similar to those obtained in the Southern Volcanic Zone of Chile, suggesting uniform magmatic gas fingerprint throughout the Chilean arc. Combining these compositions with our own UV spectroscopy measurements of the SO2 output (summing to ~1800 t d−1 for the CVZ), we calculate a cumulative CO2 output of 1743–1988 t d−1 and a total volatiles output of 〉20,200 t d−1.

Description: Acetone is one of the most abundant oxygenated volatile organic compounds (VOCs) in the atmosphere. The oceans impose a strong control on atmospheric acetone, yet the oceanic fluxes of acetone remain poorly constrained. In this work, the global budget of acetone is evaluated using two global models: CAM‐chem and GEOS‐Chem. CAM‐chem uses an online air‐sea exchange framework to calculate the bidirectional oceanic acetone fluxes, which is coupled to a data‐oriented machine‐learning approach. The machine‐learning algorithm is trained using a global suite of seawater acetone measurements. GEOS‐Chem uses a fixed surface seawater concentration of acetone to calculate the oceanic fluxes. Both model simulations are compared to airborne observations from a recent global‐scale, multiseasonal campaign, the NASA Atmospheric Tomography Mission (ATom). We find that both CAM‐chem and GEOS‐Chem capture the measured acetone vertical distributions in the remote atmosphere reasonably well. The combined observational and modeling analysis suggests that (i) the ocean strongly regulates the atmospheric budget of acetone. The tropical and subtropical oceans are mostly a net source of acetone, while the high‐latitude oceans are a net sink. (ii) CMIP6 anthropogenic emission inventory may underestimate acetone and/or its precursors in the Northern Hemisphere. (iii) The MEGAN biogenic emissions model may overestimate acetone and/or its precursors, and/or the biogenic oxidation mechanisms may overestimate the acetone yields. (iv) The models consistently overestimate acetone in the upper troposphere‐lower stratosphere over the Southern Ocean in austral winter. (v) Acetone contributes up to 30–40% of hydroxyl radical production in the tropical upper troposphere/lower stratosphere.

Description: “Flip‐flop” detachment mode represents an endmember type of lithosphere‐scale faulting observed at almost amagmatic sections of ultraslow‐spreading mid‐ocean ridges. Recent numerical experiments using an imposed steady temperature structure show that an axial temperature maximum is essential to trigger flip‐flop faults by focusing flexural strain in the footwall of the active fault. However, ridge segments without significant melt budget are more likely to be in a transient thermal state controlled, at least partly, by the faulting dynamics themselves. Therefore, we investigate which processes control the thermal structure of the lithosphere and how feedbacks with the deformation mechanisms can explain observed faulting patterns. We present results of 2‐D thermo‐mechanical numerical modeling including serpentinization reactions and dynamic grain size evolution. The model features a novel form of parametrized hydrothermal cooling along fault zones as well as the thermal and rheological effects of periodic sill intrusions. We find that the interplay of hydrothermal fault zone cooling and periodic sill intrusions in the footwall facilitates the flip‐flop detachment mode. Hydrothermal cooling of the fault zone pushes the temperature maximum into the footwall, while intrusions near the temperature maximum further weaken the rock and promote the formation of new faults with opposite polarity. Our model allows us to put constraints on the magnitude of two processes, and we obtain most reasonable melt budgets and hydrothermal heat fluxes if both are considered. Furthermore, we frequently observe two other faulting modes in our experiments complementing flip‐flop faulting to yield a potentially more robust alternative interpretation for existing observations. Plain Language Summary At mid‐ocean ridges, two plates diverge and new seafloor is created. The nature and appearance of this new seafloor strongly depend on spreading velocity and the availability of magmatic melts. At one of the melt‐poorest and slowest‐spreading ridges, a special form of large‐scale tectonic faults, so‐called flip‐flop detachments, can be observed. Tectonic faults can act as pathways for fluids circulating through the seafloor, which provides a significant cooling effect for the young plate. The interplay of magmatic activity, faulting and fluid circulation is evident at many different ridges with different magmatic activity and spreading rates. Flip‐flop faulting is restricted to only a few ridge sections worldwide, and we here investigate the prerequisites for this special spreading mode. To do so, we set up a computer model of an ultraslow‐spreading mid‐ocean ridge including the effects of sparse magmatism as well as the cooling effect associated with fluid circulation. We find that feedbacks between faulting dynamics, hydrothermal cooling and magmatic activity control the magnitude and spatial location of each individual process. Seafloor and subsurface observations are best explained by calculations with moderate melt input and hydrothermal circulation acting together. Key Points We implemented hydrothermal cooling and magmatic intrusion in a thermo‐mechanical model to explain detachment faulting at ultraslow ridges Stable flip‐flop detachment faulting is observed for setups considering both melt input and hydrothermal heat fluxes at realistic magnitudes Two other faulting modes frequently observed in our model offer potential alternative interpretations for existing seafloor observations

Description: An array of broadband seismometers transecting the Talamanca Range in southern Costa Rica was operated from 2005 until 2007. In combination with data from a short‐period network near Quepos in central Costa Rica, this data is analyzed by the receiver function method to image the crustal structure in south‐central Costa Rica. Two strong positive signals are seen in the migrated images, interpreted as the Moho (at around 35 km depth) and an intra‐crustal discontinuity (15 km depth). A relatively flat crustal and Moho interface underneath the north‐east flank of the Talamanca Range can be followed for a lateral distance of about 50 km parallel to the trench, with only slight changes in the overall geometry. Closer to the coast, the topography of the discontinuities shows several features, most notably a deeper Moho underneath the Talamanca Mountain Range and volcanic arc. Under the highest part of the mountain ranges, the Moho reaches a depth of about 50 km, which indicates that the mountain ranges are approximately isostatically compensated. Local deviations from the crustal thickness expected for isostatic equilibrium occur under the active volcanic arc and in south Costa Rica. In the transition region between the active volcanic arc and the Talamanca Range, both the Moho and intracrustal discontinuity appear distorted, possibly related to the southern edge of the active volcanic zone and deformation within the southern part of the Central Costa Rica Deformed Belt. Near the volcanoes Irazu and Turrialba, a shallow converter occurs, correlating with a low‐velocity, low‐density body seen in tomography and gravimetry. Applying a grid search for the crustal interface depth and vp/vs ratio cannot constrain vp/vs values well, but points to generally low values (〈1.7) in the upper crust. This is consistent with quartz‐rich rocks forming the mountain range.

Description: Forecasting and early warning systems are important investments to protect lives, properties and livelihood. While early warning systems are frequently used to predict the magnitude, location and timing of potentially damaging events, these systems rarely provide impact estimates, such as the expected amount and distribution of physical damage, human consequences, disruption of services or financial loss. Complementing early warning systems with impact forecasts has a two‐fold advantage: it would provide decision makers with richer information to take informed decisions about emergency measures, and focus the attention of different disciplines on a common target. This would allow capitalizing on synergies between different disciplines and boosting the development of multi‐hazard early warning systems. This review discusses the state‐of‐the‐art in impact forecasting for a wide range of natural hazards. We outline the added value of impact‐based warnings compared to hazard forecasting for the emergency phase, indicate challenges and pitfalls, and synthesize the review results across hazard types most relevant for Europe. Plain language summary Forecasting and early warning systems are important investments to protect lives, properties and livelihood. While such systems are frequently used to predict the magnitude, location and timing of potentially damaging events, they rarely provide impact estimates, such as the expected physical damage, human consequences, disruption of services or financial loss. Extending hazard forecast systems to include impact estimates promises many benefits for the emergency phase, for instance, for organising evacuations. We review and compare the state‐of‐the‐art of impact forcasting across a wide range of natural hazards, and outline opportunities and key challenges for research and development of impact forecasting.

Description: A one‐dimensional reaction‐transport model is used to investigate the dynamics of methane gas in coastal sediments in response to intra‐annual variations in temperature and pressure. The model is applied to data from two shallow water sites in Eckernförde Bay (Germany) characterized by low and high rates of upward fluid advection. At both sites, organic matter is buried below the sulfate‐reducing zone to the methanogenic zone at sufficiently high rates to allow supersaturation of the pore water with dissolved methane and to form a free methane gas phase. The methane solubility concentration varies by similar magnitudes at both study sites in response to bottom water temperature changes and leads to pronounced peaks in the gas volume fraction in autumn when the methanic zone temperature is at a maximum. Yearly hydrostatic pressure variations have comparatively negligible effects on methane solubility. Field data suggest that no free gas escapes to the water column at any time of the year. Although the existence of gas migration cannot be substantiated by direct observation, a speculative mechanism for slow moving gas is proposed here. The model results reveal that free gas migrating upward into the undersaturated pore water will completely dissolve and subsequently be consumed above the free gas depth (FGD) by anaerobic oxidation of methane (AOM). This microbially mediated process maintains methane undersaturation above the FGD. Although the complexities introduced by seasonal changes in temperature lead to different seasonal trends for the depth‐integrated AOM rates and the FGD, both sites adhere to previously developed prognostic indicators for methane fluxes based on the FGD.

Description: Along ultraslow spreading ridges melt is distributed unequally, but melt focusing guides melt away from amagmatic segments toward volcanic centers. An interplay of tectonism and magmatism is thought to control melt ascent, but the detailed process of melt extraction is not yet understood. We present a detailed image of the seismic velocity structure of the Logachev volcanic center and adjacent region along the Knipovich Ridge. With travel times of P- and S-waves of 3,959 earthquakes we performed a local earthquake tomography. We simultaneously inverted for source locations, velocity structure and the Vp/Vs-ratio. An extensive low velocity anomaly coincident with high Vp/Vs-ratios 〉1.9 lies underneath the volcanic center at depths of 10 km below sea level in an aseismic area. More shallow, tightly clustered earthquake swarms connect the anomaly to a shallow anomaly with high Vp/Vs-ratio beneath the basaltic seafloor. We consider the deep low-velocity anomaly to represent an area of partial melt from which melts ascent vertically to the surface and northwards into the adjacent segment. By comparing tomographic studies of the Logachev and Southwest Indian Ridge Segment-8 volcano we conclude that volcanic centers of ultraslow spreading ridges host spatially confined, circular partial melt areas below 10 km depth, in contrast to the shallow extended melt lenses along fast spreading ridges. Lateral feeding over distances of 35 km is possible at orthogonal spreading segments, but limited at the obliquely spreading Knipovich Ridge. Key Points - Active volcanic centers at ultraslow spreading ridges host deeper and more confined partial melt areas than faster spreading ridges - Earthquake swarms delineate melt ascent paths from the partial melt area to the surface - Lateral feeding at shallow depths into subordinate segments is prevented by ridge obliquity

Description: Spreading centers in the proximity of back‐rolling subduction zones constitute an ideal natural laboratory to investigate the interaction of magmatism and tectonism during the early evolution of back‐arc basins. Using 32 days of ocean bottom seismometer data, we located 697 microeathquakes at the southern Fonualei Rift and Spreading Center (S‐FRSC). The majority of epicenters concentrate along the central region of the axial valley, marking the active ridge axis. Only odd events were associated with the prominent faults bounding the axial valley. About 450 events are spatially clustered around 17°42’S and their waveforms show a pronounced similarity. Most of these events are associated with a 138 hours lasting earthquake swarm. The tectonic structure of the ridge axis in the S‐FRSC resembles a series of left‐stepping en echelon segments, expressed at the seafloor by numerous volcanic ridges. The recorded earthquake swarm is located at the stepover of two en echelon segments suggesting that the earthquake swarm is mainly tectonically driven. The events directly beneath our seismic network indicate a maximum depth of brittle faulting down to about 14 km below the seafloor. This is within the maximum depth range of brittle faulting at ultraslow mid‐ocean ridges. Since the thickness of the brittle lithosphere is mainly controlled by temperature, our results suggest a sub‐axial thermal structure similar to that of ultraslow mid‐ocean ridges of similar opening rates.

Description: The stratospheric climate and variability from simulations of sixteen chemistryclimate models is evaluated. On average the polar night jet is well reproduced though its variability is less well reproduced with a large spread between models. Polar temperature biases are less than 5 K except in the Southern Hemisphere (SH) lower stratosphere in spring. The accumulated area of low temperatures responsible for polar stratospheric cloud formation is accurately reproduced for the Antarctic but underestimated for the Arctic. The shape and position of the polar vortex is well simulated, as is the tropical upwelling in the lower stratosphere. There is a wide model spread in the frequency of major sudden stratospheric warnings (SSWs), late biases in the breakup of the SH vortex, and a weak annual cycle in the zonal wind in the tropical upper stratosphere. Quantitatively, “metrics” indicate a wide spread in model performance for most diagnostics with systematic biases in many, and poorer performance in the SH than in the Northern Hemisphere (NH). Correlations were found in the SH between errors in the final warming, polar temperatures, the leading mode of variability, and jet strength, and in the NH between errors in polar temperatures, frequency of major SSWs, and jet strength. Models with a stronger QBO have stronger tropical upwelling and a colder NH vortex. Both the qualitative and quantitative analysis indicate a number of common and long‐standing model problems, particularly related to the simulation of the SH and stratospheric variability.

Description: Continuous high-resolution underway measurements of dimethyl sulfide (DMS) and isoprene in the ocean surface were conducted from Germany to South Africa in November 2008. DMS, total dimethylsulfoniopropionate (DMSPt), isoprene and 19'-hexanoyloxyfucoxanthin (19'-hex) correlated in nitrogen-depleted regions when they were clustered by nitrogen to phosphorous ratio (N:P). The 19'-hex-containing algae groups might be a common source of DMS, DMSPt, and isoprene in the low N: P regions. Additionally, DMS and isoprene correlated in nitrate-depleted regions when they were clustered against nitrate concentrations. Correlations between DMS and isoprene were also found within nitrate-depleted eddies encountered along the cruise track. Eddies with N: P of similar to 2.8 showed the highest positive correlations between DMS and isoprene. We conclude that the DMS/isoprene relationships in the eastern Atlantic Ocean were influenced by nutrient availability, with implications for using nutrients to predict the DMS and isoprene concentrations over a range of oceanographic areas depleted in nitrogen

Description: Stratospheric sudden warmings (SSWs) are extreme events in the polar stratosphere that are both caused by and have effects on the tropospheric flow. This means that SSWs are associated with changes in the angular momentum of the atmosphere, both before and after their onset. Because these angular momentum changes are transferred to the solid Earth, they can be observed in the rate of the Earth's rotation and the wobble of its rotational pole. By comparing observed Earth rotation variations to reanalysis data, we find that an anomaly in the orientation of the Earth's rotational pole, up to 4 times as large as the annual polar wobble, typically precedes SSWs by 20-40 days. The polar motion signal is due to pressure anomalies that are typically seen before SSW events and represents a new type of observable that may aid in the prediction of SSWs. A decline in the length of day is also seen, on average, near the time of the SSW wind reversal and is found to be due to anomalous easterly winds generated in the tropical troposphere around this time, though the structure and timing of this signal seems to vary widely from event to event.

Description: Since 2009, unprecedented comprehensive long-term gas hydrate observations have become available from Ocean Networks Canada's NEPTUNE cabled ocean observatory at the northern Cascadia margin. Several experiments demonstrate the scientific importance of permanent power and Internet connectivity to the ocean floor as they have advanced the field of gas hydrate related research. One example is the cabled crawler Wally at Barkley Canyon, enabling live in situ exploration of the hydrate mounds and its associated benthic communities through the crawler's mobility and permanent accessibility throughout the year. Another example is a bubble-imaging sonar at Clayoquot Slope, revealing the strong relationship between ebullition of natural gas and tidal pressure, without apparent correlation to earthquakes, storms, or temperature fluctuations, in year-long continuous recordings. Finally, regular observatory maintenance cruises allow additional science sampling including echo-sounder surveys to extend the observatory footprint. Long-term trends in the data are not yet apparent but can also become evident from continuous measurements, as ocean observatories such as NEPTUNE are built for a 25-year lifetime, and expansion of the observatory networks makes these findings comparable and testable. Plain Language Summary Natural gas near the ocean floor creates a rapidly changing environment where it is important to collect data continuously in order to determine the magnitude, speed, and potential mechanism of change. This long-standing challenge of year-round access to the deep ocean has been tackled by Ocean Networks Canada through cabling the northern Cascadia seafloor, providing power and Internet communication-ideal for power-hungry instruments, large data volumes, and real-time access. The presence of gas influences the shape of the seafloor, animal activity, and potential escape of methane, a potent greenhouse gas. A seafloor crawler Wally was operated around deep canyon mounds of gas hydrate (a solid gas-water composite) since 2009 and helped discover environmental changes influencing sea life. Further along the continental slope, an acoustic sonar monitored rising methane bubbles where the bubbling appears to be controlled neither by earthquakes, winter storms, nor subtle temperature changes but actually strongly by tidal pressure. Regular maintenance of the observatory by ship allows more data to be collected near the cabled seafloor sites, extending the observations to a larger area. Ocean observatories are built to last decades and therefore more data for more research can be collected, potentially detecting relatively slow processes as well.

Description: In order to investigate the accuracy of simplification in modeling the radiative transfer in those solar spectral regions with major impacts on bio-organisms, i.e., the UVA (0.32–0.4 μm), the UVB (0.28–0.32 μm), and the photosynthetically active radiation (PAR, 0.4–0.7 μm), radiative transfer calculations with varying treatments of cloud geometries (plane-parallel homogeneous (PPHOM), independent column approximation (ICA), and three-dimensional (3-D) inhomogeneous) have been performed. The complete sets of atmospheric information for 133 cloud realizations are taken from the three-dimensional nonhydrostatic mesoscale atmospheric model (GESIMA). A Monte Carlo radiative transfer model (GRIMALDI) has been developed that simulates scattering and absorption for arbitrarily three-dimensional distributions of cloud hydrometeors, air molecules, and water vapor. Results are shown for domain-averaged direct and total transmission (and so, implicitly, diffuse transmission) at the ground surface. In the UVA the PPHOM assumption leads to an underestimation in direct (total) downward flux by as much as 43 (28) W m−2, which is about 49% (32%) of the incoming irradiation, whereas results based on the ICA are almost identical to the 3-D case, except for convective clouds where the error in the UVA for direct (total) downward flux reaches 5 (2) W m−2, or 6% (2%) of the incoming solar irradiation.

Description: We describe the main differences in simulations of stratospheric climate and variability by models within the fifth Coupled Model Intercomparison Project (CMIP5) that have a model top above the stratopause and relatively fine stratospheric vertical resolution (high-top), and those that have a model top below the stratopause (low-top). Although the simulation of mean stratospheric climate by the two model ensembles is similar, the low-top model ensemble has very weak stratospheric variability on daily and interannual time scales. The frequency of major sudden stratospheric warming events is strongly underestimated by the low-top models with less than half the frequency of events observed in the reanalysis data and high-top models. The lack of stratospheric variability in the low-top models affects their stratosphere-troposphere coupling, resulting in short-lived anomalies in the Northern Annular Mode, which do not produce long-lasting tropospheric impacts, as seen in observations. The lack of stratospheric variability, however, does not appear to have any impact on the ability of the low-top models to reproduce past stratospheric temperature trends. We find little improvement in the simulation of decadal variability for the high-top models compared to the low-top, which is likely related to the fact that neither ensemble produces a realistic dynamical response to volcanic eruptions

Description: Recent winters have been unique due to the rapid and extreme cooling of the subpolar North Atlantic. Here, we present a novel view on its causes and consequences. Combining in-situ observations with remote sensing and atmospheric reanalysis data, we show that increased freshening of the subpolar region gives rise to a faster surface cooling in fall and winter. Large freshwater events, in particular, result in pronounced cold anomalies with sharp temperature gradients that promote an enhanced storminess. The storms reinforce the cooling by driving stronger heat losses and modulating the surface flow. Consistent with this mechanism, past freshwater events have been followed by cold anomalies in winter of approximately −2°C and increases in the North Atlantic Oscillation index of up to ∼0.6 within 3 years. We expect that future freshwater discharges into the North Atlantic will amplify the cold anomaly and trigger an enhanced wintertime storminess with far-reaching climatic implications.

Description: We present the first complete budget of the interannual variability in Arctic springtime ozone taking into account anthropogenic chemical and natural dynamical processes. For the winters 1991/1992 to 2003/2004 the Arctic chemical ozone loss is available from observations. This work investigates the dynamical supply of ozone to the Arctic polar vortex due to mean transport processes for the same winters. The ozone supply is quantified in a vortex-averaged framework using estimates of diabatic descent over winter. We find that the interannual variability of both dynamical ozone supply and chemical ozone loss contribute, in equal shares, to the variability of the total ozone change. Moreover, together they explain nearly all of the interannual variability of Arctic springtime column ozone. Variability in planetary wave activity, characterized by the Eliassen-Palm flux at 100 hPa, contributes significantly to the variability of ozone supply, chemical ozone loss and total springtime ozone.

Description: What controls subduction megathrust seismogenesis downdip of the mantle wedge corner (MWC)? We propose that, in the region of the 2010 Mw=8.8 Maule, Chile, earthquake, serpentine minerals derived from the base of the hydrated mantle wedge exert a dominant control. Based on modeling, we predict that the megathrust fault zone near the MWC contains abundant lizardite/chrysotile‐rich serpentinite that transforms to antigorite‐rich serpentinite at greater depths. From the MWC at 32–40 km depth to at least 55 km, the predominantly velocity‐strengthening megathrust accommodated dynamic propagation of the 2010 rupture but with small slip and negative stress drop. The downdip distribution of interplate aftershocks exhibits a gap around the MWC that can be explained by the velocity‐strengthening behavior of lizardite/chrysotile. Interspersed velocity‐weakening and dynamic weakening antigorite‐rich patches farther downdip may be responsible for increased abundance of aftershocks and possibly for some of the high‐frequency energy radiation during the 2010 rupture.

Description: The postseismic deformation captured with continuous Global Positioning System (cGPS) monitoring following many recent mega-thrust events has been shown to be a signal composed of two dominant processes: afterslip on the plate interface and viscoelastic relaxation of the continental and oceanic mantles in response to the coseismic stress perturbation. Following the south-central Chile 2010 Maule Mw 8.8 earthquake, the time series from the regional cGPS network show a distinct curvature in the pathway of the horizontal motion that is not easily fit by a stationary decaying pattern of afterslip in combination with viscoelastic relaxation. Here we show that with realistic assumptions about the long-term decay of the afterslip signal, the postseismic signal can be decomposed into three first-order contributing processes: plate interface re-locking, plate interface afterslip, and mantle viscoelastic relaxation. From our analyses we conclude that the plate interface recovers its interseismic locking state rapidly (model space ranges between an instant recovery and a period of 1 year); a finding that supports laboratory experimental evidence as well as some recent studies of aftershocks and postseismic surface deformation. Furthermore, re-locking is the main cause of the curvature in the cGPS signal, and this study presents a plausible range of geodetic re-locking rates following a megathrust earthquake.

Description: Interest in stratospheric aerosol and its role in climate have increased over the last decade due to the observed increase in stratospheric aerosol since 2000 and the potential for changes in the sulfur cycle induced by climate change. This review provides an overview about the advances in stratospheric aerosol research since the last comprehensive assessment of stratospheric aerosol was published in 2006. A crucial development since 2006 is the substantial improvement in the agreement between in situ and space-based inferences of stratospheric aerosol properties during volcanically quiescent periods. Furthermore, new measurement systems and techniques, both in situ and space based, have been developed for measuring physical aerosol properties with greater accuracy and for characterizing aerosol composition. However, these changes induce challenges to constructing a long-term stratospheric aerosol climatology. Currently, changes in stratospheric aerosol levels less than 20% cannot be confidently quantified. The volcanic signals tend to mask any nonvolcanically driven change, making them difficult to understand. While the role of carbonyl sulfide as a substantial and relatively constant source of stratospheric sulfur has been confirmed by new observations and model simulations, large uncertainties remain with respect to the contribution from anthropogenic sulfur dioxide emissions. New evidence has been provided that stratospheric aerosol can also contain small amounts of nonsulfate matter such as black carbon and organics. Chemistry-climate models have substantially increased in quantity and sophistication. In many models the implementation of stratospheric aerosol processes is coupled to radiation and/or stratospheric chemistry modules to account for relevant feedback processes

Description: Receiver functions (RF) have been used for several decades to study structures beneath seismic stations. Although most available stations are deployed on-shore, the number of ocean bottom station (OBS) experiments has increased in recent years. Almost all OBSs have to deal with higher noise levels and a limited deployment time (∼1 year), resulting in a small number of usable records of teleseismic earthquakes. Here, we use OBSs deployed as mid-aperture array in the deep ocean (4.5-5.5 km water depth) of the eastern mid-Atlantic. We use evaluation criteria for OBS data and beam forming to enhance the quality of the RFs. Although some stations show reverberations caused by sedimentary cover, we are able to identify the Moho signal, indicating a normal thickness (5-8 km) of oceanic crust. Observations at single stations with thin sediments (300-400 m) indicate that a probable sharp lithosphere-asthenosphere boundary (LAB) might exist at a depth of ∼70-80 km which is in line with LAB depth estimates for similar lithospheric ages in the Pacific. The mantle discontinuities at ∼410 km and ∼660 km are clearly identifiable. Their delay times are in agreement with PREM. Overall the usage of beam formed earthquake recordings for OBS RF analysis is an excellent way to increase the signal quality and the number of usable events.

Description: Large explosive volcanic eruptions can inject massive amounts of sulfuric gases into the Earth's atmosphere and, in so doing, affect global climate. The January 1835 eruption of Cosigüina volcano, Nicaragua, ranks among the Americas’ largest and most explosive historical eruptions, but whether it had effects on global climate remains ambiguous. New petrologic analyses of the Cosigüina deposits reveal that the eruption released enough sulfur to explain a prominent ca. AD 1835 sulfate anomaly in ice cores from both the Arctic and Antarctic. A compilation of temperature-sensitive tree-ring chronologies indicates appreciable cooling of the Earth's surface in response to the eruption, consistent with instrumental temperature records. We conclude that this eruption represents one of the most important sulfur-producing events of the last few centuries and had a sizable climate impact rivaling that of the 1991 eruption of Mount Pinatubo.

Description: In this study, results from the Baltic Sea Tracer Release Experiment (BATRE) are described, in which deep water mixing rates and mixing processes in the central Baltic Sea were investigated. In September 2007, an inert tracer gas (CF3SF5) was injected at approximately 200 m depth in the Gotland Basin, and the subsequent spreading of the tracer was observed during six surveys until February 2009. These data describe the diapycnal and lateral mixing during a stagnation period without any significant deep water renewal due to inflow events. As one of the main results, vertical mixing rates were found to dramatically increase after the tracer had reached the lateral boundaries of the basin, suggesting boundary mixing as the key process for basin-scale vertical mixing. Basin-scale vertical diffusivities were of the order of 10−5 m2 s−1 (about 1 order of magnitude larger than interior diffusivities) with evidence for a seasonal and vertical variability. In contrast to tracer experiments in the open ocean, the basin geometry (hypsography) was found to have a crucial impact on the vertical tracer spreading. The e-folding time scale for deep water renewal due to mixing was slightly less than 2 years, the time scale for the lateral homogenization of the tracer patch was of the order of a few months. Key Points: Mixing rates in the Gotland Basin are dominated by boundary mixing processes; The time scale for Gotland Basin deep water renewal is approximately 2 years; Mixing rates determined from the tracer CF3SF5

Description: The early major warming in December 2001 is described and compared to the two other December major warmings in 1998 and 1987, showing a strong tropospheric-stratospheric coupling in all three cases. We argue that the occurrence of free westward propagating Rossby waves interacting with a forced quasi-stationary wave number 1 led to these three early events. The possible excitation of these waves is discussed with respect to the tropospheric circulation, which showed strong blockings over the northern Atlantic prior to the early major warmings.

Description: Microwave Limb Sounder and Sounding of the Atmosphere with Broadband Emission Radiometry data provide the first opportunity to characterize the four-dimensional stratopause evolution throughout the life-cycle of a major stratospheric sudden warming (SSW). The polar stratopause, usually higher than that at midlatitudes, dropped by ∼30 km and warmed during development of a major “wave 1” SSW in January 2006, with accompanying mesospheric cooling. When the polar vortex broke down, the stratopause cooled and became ill-defined, with a nearly isothermal stratosphere. After the polar vortex started to recover in the upper stratosphere/lower mesosphere (USLM), a cool stratopause reformed above 75 km, then dropped and warmed; both the mesosphere above and the stratosphere below cooled at this time. The polar stratopause remained separated from that at midlatitudes across the core of the polar night jet. In the early stages of the SSW, the strongly tilted (westward with increasing altitude) polar vortex extended into the mesosphere, and enclosed a secondary temperature maximum extending westward and slightly equatorward from the highest altitude part of the polar stratopause over the cool stratopause near the vortex edge. The temperature evolution in the USLM resulted in strongly enhanced radiative cooling in the mesosphere during the recovery from the SSW, but significantly reduced radiative cooling in the upper stratosphere. Assimilated meteorological analyses from the European Centre for Medium-Range weather Forecasts (ECMWF) and Goddard Earth Observing System Version 5.0.1 (GEOS-5), which are not constrained by data at polar stratopause altitudes and have model tops near 80 km, could not capture the secondary temperature maximum or the high stratopause after the SSW; they also misrepresent polar temperature structure during and after the stratopause breakdown, leading to large biases in their radiative heating rates. ECMWF analyses represent the stratospheric temperature structure more accurately, suggesting a better representation of vertical motion; GEOS-5 analyses more faithfully describe stratopause level wind and wave amplitudes. The high-quality satellite temperature data used here provide the first daily, global, multiannual data sets suitable for assessing and, eventually, improving representation of the USLM in models and assimilation systems.

Description: The formation of a subsurface anticyclonic eddy in the Peru-Chile Undercurrent (PCUC) in January and February 2013 is investigated using a multi-platform four-dimensional observational approach. Research vessel, multiple glider and mooring-based measurements were conducted in the Peruvian upwelling regime near 12°30'S. The dataset consists of 〉 10000 glider profiles and repeated vessel-based hydrography and velocity transects. It allows a detailed description of the eddy formation and its impact on the near-coastal salinity, oxygen and nutrient distributions. In early January, a strong PCUC with maximum poleward velocities of ∼ 0.25 m/s at 100 to 200 m depth was observed. Starting on January 20 a subsurface anticyclonic eddy developed in the PCUC downstream of a topographic bend, suggesting flow separation as the eddy formation mechanism. The eddy core waters exhibited oxygen concentrations 〈 1μmol/kg, an elevated nitrogen-deficit of ∼ 17μmol/l and potential vorticity close to zero, which seemed to originate from the bottom boundary layer of the continental slope. The eddy-induced across-shelf velocities resulted in an elevated exchange of water masses between the upper continental slope and the open ocean. Small scale salinity and oxygen structures were formed by along-isopycnal stirring and indications of eddy-driven oxygen ventilation of the upper oxygen minimum zone were observed. It is concluded that mesoscale stirring of solutes and the offshore transport of eddy core properties could provide an important coastal open-ocean exchange mechanism with potentially large implications for nutrient budgets and biogeochemical cycling in the oxygen minimum zone off Peru.

Description: The current generation of Earth system models that participate in the Coupled Model Intercomparison Project phase 5 (CMIP5) does not, on average, produce a strengthened Northern Hemisphere (NH) polar vortex after large tropical volcanic eruptions as suggested by observational records. Here we investigate the impact of volcanic eruptions on the NH winter stratosphere with an ensemble of 20 model simulations of the Max Planck Institute Earth system model. We compare the dynamical impact in simulations of the very large 1815 Tambora eruption with the averaged dynamical response to the two largest eruptions of the CMIP5 historical simulations (the 1883 Krakatau and the 1991 Pinatubo eruptions). We find that for both the Tambora and the averaged Krakatau-Pinatubo eruptions the radiative perturbation only weakly affects the polar vortex directly. The position of the maximum temperature anomaly gradient is located at approximately 30°N, where we obtain significant westerly zonal wind anomalies between 10hPa and 30hPa. Under the very strong forcing of the Tambora eruption, the NH polar vortex is significantly strengthened because the subtropical westerly wind anomalies are sufficiently strong to robustly alter the propagation of planetary waves. The average response to the eruptions of Krakatau and Pinatubo reveals a slight strengthening of the polar vortex, but individual ensemble members differ substantially, indicating that internal variability plays a dominant role. For the Tambora eruption the ensemble variability of the zonal mean temperature and zonal wind anomalies during midwinter and late winter is significantly reduced compared to the volcanically unperturbed period.

Description: During the summer monsoon, the western tropical Indian Ocean is predicted to be a hot spot for dimethylsulfide emissions, the major marine sulfur source to the atmosphere, and an important aerosol precursor. Other aerosol relevant fluxes, such as isoprene and sea spray, should also be enhanced, due to the steady strong winds during the monsoon. Marine air masses dominate the area during the summer monsoon, excluding the influence of continentally derived pollutants. During the SO234-2/235 cruise in the western tropical Indian Ocean from July to August 2014, directly measured eddy covariance DMS fluxes confirm that the area is a large source of sulfur to the atmosphere (cruise average 9.1 μmol m−2 d−1). The directly measured fluxes, as well as computed isoprene and sea spray fluxes, were combined with FLEXPART backward and forward trajectories to track the emissions in space and time. The fluxes show a significant positive correlation with aerosol data from the Terra and Suomi-NPP satellites, indicating a local influence of marine emissions on atmospheric aerosol numbers.

Description: The preconditioning of major sudden stratospheric warmings (SSWs) is investigated with two long time series using reanalysis (ERA-40) and model (MAECHAM5/MPI-OM) data. Applying planetary wave analysis, we distinguish between wavenumber-1 and wavenumber-2 major SSWs based on the wave activity of zonal wavenumbers 1 and 2 during the prewarming phase. For this analysis an objective criterion to identify and classify the preconditioning of major SSWs is developed. Major SSWs are found to occur with a frequency of six and seven events per decade in the reanalysis and in the model, respectively, thus highlighting the ability of MAECHAM5/MPI-OM to simulate the frequency of major SSWs realistically. However, from these events only one quarter are wavenumber-2 major warmings, representing a low (similar to 0.25) wavenumber-2 to wavenumber-1 major SSW ratio. Composite analyses for both data sets reveal that the two warming types have different dynamics; while wavenumber-1 major warmings are preceded only by an enhanced activity of the zonal wavenumber-1, wavenumber-2 events are either characterized by only the amplification of zonal wavenumber-2 or by both zonal wavenumber-1 and zonal wavenumber-2, albeit at different time intervals. The role of tropospheric blocking events influencing these two categories of major SSWs is evaluated in the next step. Here, the composite analyses of both reanalysis and model data reveal that blocking events in the Euro-Atlantic sector mostly lead to the development of wavenumber-1 major warmings. The blocking-wavenumber-2 major warming connection can only be statistical reliable analyzed with the model time series, demonstrating that blocking events in the Pacific region mostly precede wavenumber-2 major SSWs.

Description: A comprehensive quality assessment of the ozone products from 18 limb-viewing satellite instruments is provided by means of a detailed inter-comparison. The ozone climatologies in the form of monthly zonal mean time series covering the upper troposphere to lower mesosphere are obtained from LIMS, SAGE I, SAGE II, UARS-MLS, HALOE, POAM II, POAM III, SMR, OSIRIS, SAGE III, MIPAS, GOMOS, SCIAMACHY, ACE-FTS, ACE-MAESTRO, Aura-MLS, HIRDLS, and SMILES within 1978-2010. The inter-comparisons focus on mean biases based on monthly and annual zonal mean fields, on inter-annual variability and on seasonal cycles. Additionally, the physical consistency of the data sets is tested through diagnostics of the quasi-biennial oscillation and the Antarctic ozone hole. The comprehensive evaluations reveal that the uncertainty in our knowledge of the atmospheric ozone mean state is smallest in the tropical middle stratosphere and in the midlatitude lower/middle stratosphere, where we find a 1σ multi-instrument spread of less than ±5%. While the overall agreement among the climatological data sets is very good for large parts of the stratosphere, individual discrepancies have been identified including unrealistic month-to-month fluctuations, large biases in particular atmospheric regions, or inconsistencies in the seasonal cycle. Notable differences between the data sets exist in the tropical lower stratosphere and at high latitudes, with a multi-instrument spread of ±30% at the tropical tropopause and ±15% at polar latitudes. In particular, large relative differences are identified in the Antarctic polar cap during the time of the ozone hole, with a spread between the monthly zonal mean fields of ±50%. Differences between the climatological data sets are suggested to be partially related to inter-instrumental differences in vertical resolution and geographical sampling. The evaluations as a whole provide guidance on what data sets are the most reliable for applications such as studies of ozone variability, model-measurement comparisons and detection of long-term trends. A detailed comparison versus SAGE II data is presented, which can help identify suitable candidates for long-term data merging studies.