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  • 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution
  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
  • 1
    Publication Date: 2020-12-15
    Description: A burning peat site in the Po Valley (Italy) has been investigated for the first time. Beyond the smoke from the smoldering combustion of peat, there are carbonatic concretions and huge amounts of methane in the soil (〉60% by vol.), leading to fluxes to the atmosphere of the order of 10 to the power of 2/10 to the power of 3 mg m to the power of -2 d to the power of -1. A wide range of analyses (gas composition, stable isotopes of CH4 and CaCO3, methane radiocarbon) were performed in order to understand whether methane is produced by peat layers or seeps from deeper natural gas reservoirs. The quasi-fossil character of CH4, methane-derived carbonates, methane-stable isotopic compositions related to marine carbonates reduction, the presence of helium, and a fault corresponding to the burning site all converge to indicate that the major part of the methane ascends from deep horizons. Such methane seepage is likely to feed the peat combustion, explaining the observed phenomena and the large outbursts of historical gas-emission events.
    Description: Published
    Description: 401-413
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; seep ; peat ; gas flux ; Po plain ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-12-09
    Description: Climate change negotiations aim to reduce net greenhouse-gas emissions by encouraging direct reductions of emissions and crediting countries for their terrestrial greenhouse-gas sinks. Ecosystem carbon dioxide uptake has offset nearly 10% of Europe’s fossil fuel emissions, but not all of this may be creditable under the rules of the Kyoto Protocol. Although this treaty recognizes the importance of methane and nitrous oxide emissions, scientific research has largely focused on carbon dioxide. Here we review recent estimates of European carbon dioxide, methane and nitrous oxide fluxes between 2000 and 2005, using both top-down estimates based on atmospheric observations and bottom-up estimates derived from ground-based measurements. Both methods yield similar fluxes of greenhouse gases, suggesting that methane emissions from feedstock and nitrous oxide emissions from arable agriculture are fully compensated for by the carbon dioxide sink provided by forests and grasslands. As a result, the balance for all greenhouse gases across Europe’s terrestrial biosphere is near neutral, despite carbon sequestration in forests and grasslands. The trend towards more intensive agriculture and logging is likely to make Europe’s land surface a significant source of greenhouse gases. The development of land management policies which aim to reduce greenhouse-gas emissions should be a priority.
    Description: Published
    Description: 842-850
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon budget ; carbon dioxide ; methane ; greenhouse gas emission ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2020-12-09
    Description: We report a new case of methane (CH4) of apparent abiotic origin in continental serpentinized ultramafic rocks. Multiple analytical techniques, on-site and in the laboratory, revealed methane and ethane degassing from hyperalkaline (pH 〉 11) Ca2þ eOH mineral waters in boreholes drilled in the Alter-do- Chão igneous intrusion, at Cabeço de Vide, in mainland Portugal. The C and H isotopic composition of CH4 (d13C w 20&; d2H: 283&) suggests a dominant abiotic origin, although minor thermogenic contributions cannot be excluded. Similarly, low methane-to-ethane ratios suggest a predominantly nonmicrobial source, consistent with previous microbiological data showing the lack of methanogenic archaea in these waters. Heavier hydrocarbons, CO2 and H2 are below detection limits. This case study confirms that CH4 from serpentinized ultramafic rocks can be transported by hyperalkaline fluids linked to deep circulation of meteoric waters. Maximum depth of Cabeço de Vide serpentinized rocks is less than 1 km, and present temperatures are likely lower than 50 C. Serpentinization and related gas formation may have occurred at any time during thermal evolution of the igneous intrusion, so gas formation temperature cannot be easily determined. This case is an opportunity to test thermometry provided by CH4 isotopologue analyses. The existence of methane in continental serpentinized igneous rocks is more widespread than previously thought and petroleum systems with similar serpentinized ultramafics in reservoir rocks may have traces of the observed 13C-enriched CH4
    Description: Published
    Description: 12-16
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Abiotic methane, serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-01-07
    Description: The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO2-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO2 discharge through soils of 1.8 109 mol a 1 shows that large amounts of CO2 move from the deep reservoir to the surface. A large range in d13CTDIC ( 21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 109 mol a 1 of deeply sourced CO2 in spring waters. The total natural CO2 discharge (2.1 109 mol a 1) is slightly less than minimum CO2 output estimated by an indirect method (2.8 109 mol a 1), but present-day release of 5.8 109 mol a 1 CO2 from deep geothermal wells may have reduced natural CO2 discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (〉200 mWm 2) and reaches extremely high values (up to 2700mWm 2) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO2 flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO2 degassing and heat transfer patterns.
    Description: Published
    Description: 860–875
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide degassing ; Monte Amiata ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-06-15
    Description: Twenty-two gas samples were collected in August 2012 in the area of Amik basin (Turkey). Two samples were collected from gas seeps, one was a bubbling gas in a thermal spring, while the remaining were dissolved gases from cold and thermal groundwaters (T 16-43 °C). All gases were analysed for their chemical composition (He, H2, O2, N2, CH4 and CO2) and for their He isotopic composition. Dissolved gases were also analysed for the carbon isotopic composition of the total dissolved carbon (TDC), while free gases also for their higher hydrocarbon (C1 – C5) content and for D of H2 and CH4, 13C of CH4 Basing on their chemical composition, the gases can be roughly subdivided in three groups. Most of the dissolved gases (16) belonging to the first group were collected from springs or shallow wells (〈 150 m depth). All these samples contain mainly atmospheric gasses with very limited H2 (〈 80 ppm) and CH4 (1 – 2700 ppm) contents and minor concentrations of CO2 (0.5 – 11.2 %). The isotopic composition of TDC evidences an almost organic contribution. The only exception is represented by the CO2-richest sample where a small but significant mantle contribution is found. Such contribution can also be evidenced in its 3He rich isotopic composition. Further three samples of this group evidence a small mantle contribution. These samples were collected in the northern part of the basin along the main tectonic structures delimiting the basin and close to areas with quaternary volcanic activity. A second group is composed by two dissolved gases collected from deep boreholes (〉 1200 m depth). Their composition is typical of hydrocarbon reservoirs being very rich in CH4 (〉 78 %) and N2 (〉 13%). Also the water composition is typical of saline connate waters (Cl- and B-rich, SO4-poor). C-isotopic composition of methane ( 13C -65% ) points to a biogenic origin while He-isotopic composition indicates a prevailing crustal signature for one (R/Ra 0.16) of the sites and small mantle contribution for the other (R/Ra 0.98). To the last group belong four gas samples taken at two sites within the ophiolitic basement that crops out west of the basin. These gases have the characteristic composition of gas generated by low temperature serpentinisation processes with high hydrogen (37 – 50 %) and methane (10 – 61 %) concentrations. While all gases show an almost identical D-H2 of -750h those of one of the two sites display an isotopic composition of methane ( 13C -5h D -105% ) and a C1/[C2+C3] ( 100) ratio typical of abiogenic hydrocarbons and mantle-type helium (R/Ra: 1.33), while those of the other site evidence a contribution of a crustal (thermogenic) component ( 13C-CH4 -30h D -325h C1/[C2+C3] 3000). Such crustal contribution is also supported by higher N2 contents (40% instead of 2%) and lower He-isotopic composition (R/Ra 0.07). The preliminary results highlight contributions of mantle-derived volatiles to the fluids vented along the Amik Basin. The main tectonic structure of the area, the Death Sea Fault, and other parallel structures crossing the basin seem to be the responsible for deep-originated volatiles drainage towards shallow levels.
    Description: Submitted
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: gas geochemistry ; water chemistry ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 6
    Publication Date: 2020-11-26
    Description: The volcano–hydrothermal system of El Chichón volcano, Chiapas, Mexico, is characterized by numerous thermal manifestations including an acid lake, steam vents and boiling springs in the crater and acid and neutral hot springs and steaming ground on the flanks. Previous research on major element chemistry reveals that thermal waters of El Chichón can be divided in two groups: (1) neutral waters discharging in the crater and southern slopes of the volcano with chloride content ranging from 1500 to 2200 mg/l and (2) acid-toneutral waters with Cl up to 12,000 mg/l discharging at the western slopes. Our work supports the concept that each group of waters is derived from a separate aquifer (Aq. 1 and Aq. 2). In this study we apply Sr isotopes, Ca/Sr ratios and REE abundances along with the major and trace element water chemistry in order to discriminate and characterize these two aquifers. Waters derived from Aq. 1 are characterized by 87Sr/86Sr ratios ranging from 0.70407 to 0.70419, while Sr concentrations range from 0.1 to 4 mg/l and Ca/Sr weight ratios from 90 to 180, close to average values for the erupted rocks. Waters derived from Aq. 2 have 87Sr/86Sr between 0.70531 and 0.70542, high Sr concentrations up to 80 mg/l, and Ca/Sr ratio of 17–28. Aquifer 1 is most probably shallow, composed of volcanic rocks and situated beneath the crater, within the volcano edifice. Aquifer 2 may be situated at greater depth in sedimentary rocks and by some way connected to the regional oil-gas field brines. The relative water output (l/s) from both aquifers can be estimated as Aq. 1/Aq. 2– 30. Both aquifers are not distinguishable by their REE patterns. The total concentration of REE, however, strongly depends on the acidity. All neutral waters including high-salinity waters from Aq. 2 have very low total REE concentrations (b0.6 μg/l) and are characterized by a depletion in LREE relative to El Chichón volcanic rock, while acid waters from the crater lake (Aq. 1) and acid AS springs (Aq. 2) have parallel profile with total REE concentration from 9 to 98 μg/l. The highest REE concentration (207 μg/l) is observed in slightly acid shallow cold Ca-SO4 ground waters draining fresh and old pyroclastic deposits rich in magmatic anhydrite. It is suggested that the main mechanism controlling the concentration of REE in waters of El Chichón is the acidity. As low pH results from the shallow oxidation of H2S contained in hydrothermal vapors, REE distribution in thermal waters reflects the dissolution of volcanic rocks close to the surface or lake sediments as is the case for the crater lake.
    Description: -
    Description: Published
    Description: 55-66
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrogeochemistry ; geothermal systems ; Sr isotopes ; REE ; El Chichón Volcano ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2021-01-27
    Description: Graciosa island is located in the Azores Archipelago, along the so-called Terceira Rift, a major tectonic structure that makes the NE boundary of the Azores Plateau. In general terms, it includes a basaltic plataform on the NW and a silicic poligenetic volcano with caldera on the SE, the Graciosa Caldera Volcano. This volcano has produced significant tephra falls, pyroclastic flows, lahars, and lava flows, both of basaltic s.l. and trachitic s.l. composition. The hydrothermal system shows fumarolic emissions inside the volcano caldera and thermal springs located along the shoreline. This system is exploitated in a thermal building through shallow and deep (110 m) boreholes, near the coast. In Graciosa two types of Na-Cl groundwater systems can be identified: 1) a cold one emerging at springs and exploited by wells for public water supply, and 2) a hydrothermal system with temperatures around 40-44 °C. The cold groundwaters have pH higher than 7 and different degree of mineralization, according to the proximity to the sea. The thermal waters show mixing with seawater, pH varying between 6.20 and 6.94, 166 mg/L of SiO2, and significant concentration of metals, such as Mn, Fe, Co, Ni, Cu and Zn. The thermal water mineralization varies strongly, showing EC from 8.87 mS/cm (shallow water) to 47.4 mS/cm (deeper water). The higher mineralized water is rich in CO2(g), with 2130 mg/L of total dissolved CO2. Geothermometers application reveals aquifer temperature around 167 °C and immature/mixed waters, not reaching complete equilibrium with reservoir rock. The geochemistry of the thermal waters indicates the occurrence of seawater/host rock interaction processes at high temperature and slightly acid conditions, favored by CO2(g) input, and a different degrees of mixing with cold and shallow groundwaters.
    Description: Published
    Description: Prague, Czech Republic
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Hydrothermal systems ; Graciosa Island, Azores ; Grondwater chemistry ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
    Publication Date: 2021-01-27
    Description: In this work we report new data on He abundances and isotope ratios (3He/4He) from gas associated to some thermal and CO2-rich mineral waters in N-Portugal. Collected gas samples are mainly CO2-dominant except two sites where gas is N2-rich. All the sampling sites are characterized by exceptionally high helium contents with 3He/4He ratios, corrected for air contamination, varying considerably from 0.09 to 2.68 Ra. In all sites, the 3He/4He ratios are higher than that typical for stable continental areas thus indicating a variable but not-negligible (up to 30%) contribution of mantle-derived primordial He. In all the CO2-rich waters, CO2/3He ratios and 13CCO2 are comparable with mantle values, thus suggesting a magmatic origin also for CO2. On the contrary, in the N2-rich waters He is mainly radiogenic, and CO2 is organic in origin. Since no recent volcanic activity is observed in NW Iberia, high 3He/4He values could be due, at least, to three processes: a) releasing of gas from the local upper mantle through deep extensional fault systems; b) releasing of magmatic volatiles from crustal reservoir(s) formed during past volcanic activity; c) degassing of a subsurface emplaced magma body. Mantle He flux in N-Portugal has been estimated to be up to 3 orders of magnitude higher than that typical for stable continental areas, thus suggesting, in this area, the presence of a tensional tectonic regime. This implies that mantle gases could migrate upward probably through inherited tectonic structures reactivated by neotectonic activity. The third possible scenario seems to be less plausible since seismic surveys carried out in NW Iberian did not find any significant evidence of mantle intrusion in the crust. The observed spatial variability in mantle-derived contribution could reflect the geometry of the granitic plutons in this area, thus supporting the hypotheses of an upper mantle degassing. Alternatively, it could be the result of a lateral migration of magmatic volatiles stored in a crustal reservoir.
    Description: Published
    Description: Budapest, Hungary
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Helium isotopes ; NW Iberian peninsula ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 9
    Publication Date: 2021-03-01
    Description: Between 1994 and 1995, gas samples from fumaroles and thermal waters were collected on Ischia Island. The chemical composition of the shallow and deep natural hydrothermal fluids discharged is related to the main hydrological and lithological characteristics of the rock formations present in the reservoir. A biphase reservoir (liquid 1 gas) is identified, where the dominant liquid has a temperature of about 2808C. On the basis of d 13CTDC values it was possible to hypothesize a deep source characterised by carbon isotopic values varying from 0 to 23d‰. These values are noticeably more positive with respect to those attributed to magmatic CO2 d13CCO2 ranging from 25 to 28d ‰), thus suggesting a magmatic source modified by crustal contamination. This hypothesis is supported by the carbon isotopic composition of CO2 in sampled gases, which varied from 0 to 25d‰. The inferred isotopic value of carbon of magmatic CO2 would then be about 22d‰. The observed differences in C isotopic composition between fumarolic and magmatic gases would be caused by kinetic and/or equilibrium fractionation processes. These processes would cause a fractionation of d 13C of deep CO2 towards more negative values (down to 25‰). Actually, CO2 removal or addition processes caused by the interaction between deep gases and shallow hydrothermal waters are likely to be responsible for the different chemical and isotopic compositions of gaseous emissions. For these reasons, and on the basis of the homogeneity of geothermometric values, the existence of a single, large reservoir that feeds all of the fluids discharged at Ischia Island can be hypothesised. Based on acquired data, a new geochemical model of the geothermal system of Ischia Island is proposed.
    Description: Published
    Description: 151-178
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: gas thermometers; water geothermometer; dissolved gases; geothermal system; Ischia Island ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2021-03-24
    Description: Several models which could be useful to estimate pollutant concentrations as a function of the emission distribution and the attendant meteorological conditions, have been investigated. Up to now a lot of them have been based upon physical principles. In this work an alternative block box approach, in air pollution modelling have been proposed. The main target of this approach is the prediction, on the basis of meteorological prevision, the air pollution concentration as a function of the expected number of vehicles. The integration of this model in an emission control scheme, for the control of the motor vehicle flux, may represent a very useful approach to the urban air quality problem.
    Description: Published
    Description: Ottawa, Canada.
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: open
    Keywords: Model, Pollution, Neural Model ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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