ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(+)-(1S, 3S, 6S, 8S)-and (-)-(1R, 3R, 6R, 8R)-4, 9-Twistadiene: Synthesis and Absolute ConfigurationA synthesis and the determination of the absolute configuration of (+)-(1S, 3S, 6S, 8S)- and (-)-(1R, 3R, 6R, 8R)-4, 9-twistadiene ((+)- and (-)-4, respectively) is described. Their chiroptical properties are compared with those of saturated twistane ((+)- and (-)-5) as well as with those of the unsaturated and saturated 2, 7-dioxatwistane analogs (+)- and (-)-9, and (+)- and (-)-10, respectively, which also are compounds of known absolute configurations.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19800630526
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