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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (6)
  • Blackwell  (4)
  • Elsevier Science  (2)
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Years
  • 1
    Publication Date: 2020-11-16
    Description: Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140,000 years ago during Mt. Vulture volcano’s last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3He/4He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even if they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30,000 people throughout the summer, for the most part on Sundays.
    Description: In press
    Description: 83-87
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: volcanic gases ; gas hazard ; crater lakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Geochemical investigations carried out at the Campano-Lucano Apennine (Southern Italy) revealed the presence of fluids composed of a mixing between components of shallow and deep origin, where mantle-derived helium is also detectable. For the gas phase, the deep component is represented by both CH4 and CO2-rich gases, while the shallow one is N2-dominated. Coinciding with the 3 April 1996 ML = 4.9 earthquake, the CH4- rich component mixed with the shallow, NZ-dominated one at the Tramutola well (Val dfAgri), displaying wide variations in mixing proportions. In contrast, no significant modifications occurred in relation to the 1998 ML = 5.5 event. According to the collected data, an earthquake-related transient modification of local crustal permeability is suggested for the 1996 event. The different crustal response to the two events may be related to different stress distributions around the epicentres or may suggest a different tectonic connection between the Val d'Agri and the two earthquake locations.
    Description: Published
    Description: 249-257
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemistry ; Earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Geochemical investigations carried out at the Campano-Lucano Apennine (Southern Italy) revealed the presence of fluids composed of a mixing between components of shallow and deep origin, where mantle-derived helium is also detectable. For the gas phase, the deep component is represented by both CH4 and CO2-rich gases, while the shallow one is N2-dominated. Coinciding with the 3 April 1996 ML = 4.9 earthquake, the CH4- rich component mixed with the shallow, NZ-dominated one at the Tramutola well (Val dfAgri), displaying wide variations in mixing proportions. In contrast, no significant modificationsoccurred in relation to the 1998 ML = 5.5 event. According to the collected data, an earthquake-related transient modification of local crustal permeability is suggested for the 1996 event. The different crustal response to the two events may be related to different stress distributions around the epicentres or may suggest a different tectonic connection between the Val d'Agri and the two earthquake locations.
    Description: Published
    Description: 249-257
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: fluids ; seismicity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: The mephitis of Maschito, known since historical times as Lago Fetente (Smelly Lake) -although the lake is now dry-, is located twenty kilometers from the Mt. Vulture volcanic edifice (Southern Italy). It is placed along the same regional tectonic discontinuity where some maars are located, close to the boundary between the foredeep and the Apulian foreland. About 300 m2 of surface is lacking in flora, while dead animals are frequently found all around it. The smelly exhalations are mainly composed of CO2 (∼ 98 %), and, in lesser amounts, of H2S, N2, CH4 and other hydrocarbons. He, Ne and Ar occur in trace amounts. The CO2 isotopic composition is in the range of that of the main active Italian volcanic gases. The helium isotopic ratio (4.7 Ra) fits with the values measured in Mt. Vulture volcano and particularly with the olivine and pyroxene fluid inclusions of mantle xenoliths ejected during its last volcanic activity (140,000 years). The 40Ar/36Ar isotopic ratio of ∼320 supports some minor non-atmospheric contributions. The C/3He ratio (2.9x109) is in the typical range of magma released fluids, while δ13C(CH4) and δD(CH4) values fall in the field of thermogenic methane. T The amount of CO2 released is about 3200 tons/year. The flux of mantle-derived helium (〉 7 x1010 atoms m-2s-1) is at least three orders of magnitude higher than that of a stable continental crust. This study strongly supports the possibility that Maschito manifestations are fed by a geothermal system, which is powered by a degassing melt, bearing in mind that the Maschito gas emissions fall along the same fault system of the Monticchio maars, which formed during Mt. Vulture volcano’s last activity.
    Description: Published
    Description: 309-314
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Geothermal System ; Helium ; Gas flux ; tectonics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2020-02-24
    Description: Socorro Island is the exposed part of an approx. 4000-m-high volcanic edifice rising from the oceanic floor to approx. 1000 m asl at the northern part of the Mathematician Ridge, Western Pacific. The volcano is active, with the most recent basaltic eruption in 1993. Moderate fumarolic activity and diffuse degassing with a total CO2 flux of approx. 20 total day)1 are concentrated in the summit region of the volcano composed of a group of rhy- olite domes. Low-temperature, boiling point, fumaroles discharge gas with high H2 (up to 20 mol% in dry gas) and CH4 (up to 4 mol%). Both carbon and He isotopic ratios and abundances correspond to those in MORB flu- ids (d13CCO2 )5&; 3He ⁄ 4He = 7.6 Ra, CO2 ⁄ 3He = (2–3) · 109, where Ra is the atmospheric ratio 3He ⁄ 4He of 1.4 · 10)6. Light hydrocarbons (CH4, C2H6, C3H8, and C4H10) are characterized by a high C1 ⁄C2+ ratio of approx. 1000. Methane is enriched in 13C (d13CCH4 from )15 to )20&) and 2H (d2H from )80 to )120&), and hydrocarbons show an inverse isotopic trend in both d13C and d2H (ethane is isotopically lighter than methane). These isotopic and concentration features of light hydrocarbons are similar to those recently discovered in fluids from ultramafic-hosted spreading ridge vents and may be related to the serpentinization processes: H2 generation and reduction of CO2 to CH4 within high-temperature zone of volcano-seawater hydrothermal system hosted in basaltic and ultramafic rocks beneath a volcano edifice. The thermodynamic analysis of this unusual composition of the Socorro fluids and the assessment of endmember compositions are complicated by the near-surface cool- ing, condensation and mixing with meteoric water.
    Description: Published
    Description: 542-555
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: open
    Keywords: Geochemistry ; isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: The studied area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence of a subduction slab at depth responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). A high geothermal gradient is made evident by the presence of many thermal springs with temperatures from 19 to 82 C, that discharge along the normal faults bordering the graben. In the period 2004e2012, 58 gas and 69 water samples were collected and their chemical and isotopic analysis revealed a wide range of compositions. Two main groups of thermal waters can be distinguished on the basis of their chemical composition. The first, represented by dilute waters (E.C. 〈0.6 mS/cm) of the westernmost sites, is characterised by the presence of CH4-rich and mixed N2eCH4 gases. The second displays higher salinities (E.C. from 12 to 56 mS/cm) due to mixing with a modified marine component. Reservoir temperatures of 150e160 C were estimated with cationic geothermometers at the easternmost sites. Along the graben, from west to east, the gas composition changes from CH4- to CO2-dominated through mixed N2eCH4 and N2eCO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (〈0.1 R/RA) up to 0.87 R/RA, showing in the easternmost sites a small (3e11%) but significant mantle input. The d13C values of the CO2-rich samples suggest a mixed origin (mantle and marine carbonates).
    Description: Published
    Description: 295-308
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Rift zone ; geothermal activity ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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