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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (17)
  • ddc:551.49
  • INGV  (13)
  • Blackwell Publishing Ltd  (7)
  • American Chemical Society
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  • 1
    Publication Date: 2020-11-23
    Description: Gas data of the Los Azufres geothermal field were analyzed using a method based on equilibrium of the Fischer- Tropsch (FT) reaction: CH4 + 2H2O = 4H2 +CO2 and on the combined pyrite-hematite-magnetite (HSH2) reactions: 5/4 H2 +3/2 FeS2 +3/4 Fe2O3 + 7/4 H2O = 3 H2S +Fe3O4 in order to estimate reservoir temperature and excess steam. The solution of equilibrium equations produces a grid (FT-HSH2). This method is suitable for reservoirs with relatively high H2S but low H2 and NH3 concentrations in the fluid as is the case of the Los Azufres well discharges. Reservoir temperature and reservoir excess steam values were estimated for initial and present conditions in representative wells of the field to study the evolution of fluids, because of exploitation and waste fluids reinjection. This method was very useful in estimating reservoir temperatures in vapor wells, while in two-phase wells it was found that as the well produces a smaller fraction of water, the reservoir temperature estimation agrees qualitatively with results from cationic or silica geothermometers. For liquid-dominated wells the reservoir temperature estimations agree with temperatures obtained from the well simulator WELFLO. This indicates that FT-HSH2 results provide the temperature of the fluid entering the well where the last equilibrium occurs. Results show a decrease in reservoir temperatures in the southern zone of the field where intensive reinjection takes place. With exploitation, it was also noted that the deep liquid phase in the reservoir is changing to two-phase increasing the reservoir steam fraction and the non-condensable gases in well discharges.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Los Azufres geothermal field ; gas geochemistry ; geothermal gas equilibria ; reservoir exploitation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Le metodologie di indagine geochimica applicate ad un’ampia porzione dell’Appennino meridionale, esteso dalla Calabria settentrionale ai Monti Nebrodi, nell’ambito del progetto INGV-DPC S2, hanno consentito di valutare le caratteristiche dei fluidi emessi in coincidenza di importanti lineamenti strutturali, permettendo di evidenziare le relazioni intercorrenti tra l’assetto tettonico e la genesi, la circolazione ed il comportamento dei fluidi circolanti. L’area di studio rappresenta la porzione più meridionale dell’Arco Calabro, il cui stile deformativo dominante dal Pleistocene medio all’attuale, è caratterizzato da una estensione ESE-WNW. Nella Sicilia nord-orientale, le faglie neotettoniche dislocano i livelli crostali più superficiali e si dispongono secondo direzioni preferenziali orientati circa NW-SE con meccanismi deformativi a componente trascorrente ed estensionale e N-S/NE-SO con meccanismi deformativi trascorrenti, a tratti con componente compressiva. Le strutture crostali radicate sono rappresentate dal sistema “Patti-Eolie”, che si connette a terra con il sistema “Tindari-Letojanni” e dal “sistema di Messina”. Il primo mostra, anche a livello sismologico, caratteri deformativi transtensivi; nel secondo sistema, caratterizzato da faglie a prevalente componente distensiva del rigetto la catena presenta un tasso di sollevamento recente non uniforme, con valori massimi lungo la costa messinese ionica e tassi minori lungo quella tirrenica. L’esistenza di fenomeni attivi di sollevamento regionale è dimostrato da alcune evidenze, come la presenza di argille marine quaternarie affioranti diverse centinaia di metri al di sopra del livello del mare nonché di piattaforme di abrasione tirreniane ben sviluppate ad una altitudine di circa 130 m. nei pressi di Taormina e sul versante calabrese dello stretto di Messina. La struttura tettonica più importante che interseca il sistema Ibleo-Maltese è costituito dal sistema di faglie di Messina, orientato NNE-NNW. Il terremoto di Messina del 1908 è stato attribuito ad una “faglia cieca” nell’area di Messina. Lungo le principali strutture tettoniche, sono presenti attività idrotermali e di degassamento note da tempi storici, che dal punto di vista geochimico mostrano caratteristiche molto diverse in funzione della loro ubicazione.
    Description: Published
    Description: Reggio Calabria
    Description: 3.2. Tettonica attiva
    Description: open
    Keywords: fluidi ; Tettonica attiva ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 3
    Publication Date: 2017-04-04
    Description: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Description: Published
    Description: 539–554
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: In the past, variations in the chemical contents (SO4 2−, Cl−, cations) of crater lake water have not systematically demonstrated any relationships with eruptive activity. Intensive parameters (i.e., concentrations, temperature, pH, salinity) should be converted into extensive parameters (i.e., fluxes, changes with time of mass and solutes), taking into account all the internal and external chemical–physical factors that affect the crater lake system. This study presents a generalized box model approach that can be useful for geochemical monitoring of active crater lakes, as highly dynamic natural systems. The mass budget of a lake is based on observations of physical variations over a certain period of time: lake volume (level, surface area), lake water temperature, meteorological precipitation, air humidity, wind velocity, input of spring water, and overflow of the lake. This first approach leads to quantification of the input and output fluxes that contribute to the actual crater lake volume. Estimating the input flux of the "volcanic" fluid (Qf - kg/s) –– an unmeasurable subsurface parameter –– and tracing its variations with time is the major focus during crater lake monitoring. Through expanding the mass budget into an isotope and chemical budget of the lake, the box model helps to qualitatively characterize the fluids involved. The (calculated) Cl− content and dD ratio of the rising "volcanic" fluid defines its origin. With reference to continuous monitoring of crater lakes, the present study provides tips that allow better calculation of Qf in the future. At present, this study offers the most comprehensive and up-to-date literature review on active crater lakes.
    Description: Published
    Description: 161-173
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: Geochemical monitoring ; Active crater lakes, ; Box model ; Mass budget ; Isotope and chemical budget ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 5
    Publication Date: 2017-04-04
    Description: A periodic sampling of the groundwaters and dissolved and free gases in selected deep wells located in the area affected by the May-June 2012 southern Po Valley seismic sequence has provided insight into seismogenic-induced changes of the local aquifer systems. The results obtained show progressive changes in the fluid geochemistry, allowing it to be established that deep-seated fluids were mobilized during the seismic sequence and reached surface layers along faults and fractures, which generated significant geochemical anomalies. The May-June 2012 seismic swarm (mainshock on May 29, 2012, M 5.8; 7 shocks M 〉5, about 200 events 3 〉 M 〉 5) induced several modifications in the circulating fluids. This study reports the preliminary results obtained for the geochemical features of the waters and gases collected over the epicentral area from boreholes drilled at different depths, thus intercepting water and gases with different origins and circulation. The aim of the investigations was to improve our knowledge of the fluids circulating over the seismic area (e.g. origin, provenance, interactions, mixing of different components, temporal changes). This was achieved by collecting samples from both shallow and deep-drilled boreholes, and then, after the selection of the relevant sites, we looked for temporal changes with mid-to-long-term monitoring activity following a constant sampling rate. This allowed us to gain better insight into the relationships between the fluid circulation and the faulting activity. The sampling sites are listed in Table 1, along with the analytical results of the gas phase.
    Description: Published
    Description: 815-821
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Geochemistry ; Faults ; Temporal changes. ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2019-11-04
    Description: Radon-in-soil monitoring at the Poas volcano (Costa Rica) has been performed together with water chemistry from the hot crater lake since 1981 and 1983 respectively. The results are discussed as a function of the eruptive evolution of the volcano over a 13 years period (1981-1994). It is shown that no definitely clear precursory radon signals have been recorded. On the contrary, ionic species concentrations are likely to be considered good precursors, together with the temperature variations of the crater lake water.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Poas volcano ; geochemistry ; radon ; precursor ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 7
    Publication Date: 2019-11-04
    Description: A theoretical method for estimating the characteristics of radon transport in homogeneous soil is developed. The method allows the following characteristics to be estimated: depth distribution function of the soil gas radon concentration, equilibrium radon concentration in the soil air, depth at which the radon concentration reaches its equilibrium value, radon flux density from the Earths surface, and convective radon transport velocity. The method is based on soil gas radon concentration measurements and is appropriate in the case of relatively uniform geology.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: method ; radon ; soil ; convectiv evelocity ; radon flux density ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 8
    Publication Date: 2019-11-04
    Description: The identified emissions of abiogenic carbon dioxide, carbon monoxide and methane are generally attributed to volcanic activity or to geochemical processes associated with thermometamorphic effects. In this paper we show another possible abiogenic source of emission, induced by mechanical, and not thermal, stresses. We investigated the mechanochemical production of carbon dioxide and methane when friction is applied to marly-type rock and studied the mechanisms determining the strong CO2 and CH4 emissions observed. A ring mill was used to apply friction and oriented pressure upon a synthetic calcite-clay mixture of varying proportions. We found that the CO2 and CH4 release versus the grinding action has a non-linear trend reflecting the behaviour of decreasing crystallinity, which indicates a close link between crystallinity and gas production. For the CO2 emission, we propose a release mechanism connected with the friction-induced fractures and the increase in structural disorders induced by creep in the lattice. The CH4 emission could be explained by a Sabatier reaction in which CO2 and hydrogen are involved to form CH4 and water.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: gas geochemistry ; earthquake precursors ; greenhouse gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
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  • 9
    Publication Date: 2019-11-04
    Description: Sampled from the Gangxi oil field in the Huanghua depression, Bohaiwan Basin, the crude oil He and Ar isotopic compositions and their geochemical significance were investigated. The result shows that i) the 3He/4He values of the six oil samples free from air contamination indicate a mantle helium contribution ranging between 13.9% and 32.8% and averaging 24.1%, which means that the Gangxi oil field once had a tectonic background of the mantle-derived helium input and higher geothermal flow with an average of 75.0 mWm-2; ii) deduced from the 40Ar/36Ar aging effect the Gangxi oil should be derived from the Tertiary; iii) water injection is the main reason for the air contamination for the Gangxi oil noble gases and the relations between 3He/4He and 4He/20Ne as well as 40Ar/36Ar and 4He/20Ne are of an applicative potential in estimating the water injection effect and the connectivity of producing formations. The search for the crude oil He and Ar isotopes provides a new approach to inferring natural gas and oil sources, tectonic backgrounds, geothermal flow and water injection effect.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: crude oil ; noble gas tracing ; Gangxi oil field ; Huanghua depression ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 11
    Publication Date: 2017-04-03
    Description: (extended abstract)
    Description: INGV, Regione Sicilia, Ministero Sviluppo Economico
    Description: Published
    Description: Ettore Majorana Foundation and Centre for Scientific Culture, Erice, Sicily
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: Hydrocarbons origin ; Fold belts ; 03. Hydrosphere::03.04. Chemical and biological::03.04.99. General or miscellaneous ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2019-11-04
    Description: Long-term geochemical monitoring performed in the seismic area of the Umbria-Marche region of Italy (i.e. Central Apennines) has allowed us to create a model of the circulation of fluids and interpret the temporal chemical and isotopic variations of both the thermal springs as well as the gas vents. Coincident with the last seismic crisis, which struck the region in 1997-1998, an enhanced CO2 degassing on a regional scale caused a pH-drop in all the thermal waters as a consequence of CO2 dissolution. Furthermore, much higher 3He/4He isotope ratios pointed to a slight mantle-derived contribution. Radon activity increased to well above the ±2 sinterval of the earlier seismic period, after which it abruptly decreased to very low levels a few days before the occurrence of the single deep-located shock (March 26, 1998, 51 km deep). The anomalous CO2 discharge was closely related to the extensional movement of the normal faults responsible for the Mw 5.7, 6.0 and 5.6 main shocks that characterized the earlier seismic phase. In contrast, a clear compressive sign is recognizable in the transient disappearance of the deep-originating components related to the Mw 5.3, 51 km-deep event that occurred on March 26, 1998. Anomalies were detected concomitantly with the seismicity, although they also occurred after the seismic crisis had terminated. We argue that the observed geochemical anomalies were driven by rock permeability changes induced by crustal deformations, and we describe how, in the absence of any release of elastic energy, the detection of anomalies reveals that a seismogenic process is developing. Indeed, comprehensive, long-term geochemical monitoring can provide new tools allowing us to better understand the development of seismogenesis.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: geochemical monitoring ; seismicity ; helium ; thermal waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 14
    Publication Date: 2022-04-01
    Description: We present a workflow to estimate geostatistical aquifer parameters from pumping test data using the Python package welltestpy. The procedure of pumping test analysis is exemplified for two data sets from the Horkheimer Insel site and from the Lauswiesen site, Germany. The analysis is based on a semi‐analytical drawdown solution from the upscaling approach Radial Coarse Graining, which enables to infer log‐transmissivity variance and horizontal correlation length, beside mean transmissivity, and storativity, from pumping test data. We estimate these parameters of aquifer heterogeneity from type‐curve analysis and determine their sensitivity. This procedure, implemented in welltestpy, is a template for analyzing any pumping test. It goes beyond the possibilities of standard methods, for example, based on Theis' equation, which are limited to mean transmissivity and storativity. A sensitivity study showed the impact of observation well positions on the parameter estimation quality. The insights of this study help to optimize future test setups for geostatistical aquifer analysis and provides guidance for investigating pumping tests with regard to aquifer statistics using the open‐source software package welltestpy.
    Description: Article impact statement: We present a workflow to infer parameters of subsurface heterogeneity from pumping test data exemplified at two sites using welltestpy.
    Description: German Federal Environmental Foundation (DBU) http://dx.doi.org/10.13039/100007636
    Keywords: ddc:551.49
    Language: English
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  • 15
    Publication Date: 2019-11-04
    Description: Terrestrial heat flow density, q, is inversely correlated with the age, t, of tectono-magmatic activity in the Earth's crust (Polyak and Smirnov, 1966; etc.). «Heat flow-age dependence» indicates unknown temporal heat sources in the interior considered a priori as the mantle-derived diapirs. The validity of this hypothesis is demonstrated by studying the helium isotope ratio, 3He/4He = R, in subsurface fluids. This study discovered the positive correlation between the regionally averaged (background) estimations of R- and q-values (Polyak et al., 1979a). Such a correlation manifests itself in both pan-regional scales (Norhtern Eurasia) and separate regions, e.g., Japan (Sano et al., 1982), Eger Graben (Polyak et al., 1985) Eastern China rifts (Du, 1992), Southern Italy (Italiano et al., 2000), and elsewhere. The R-q relation indicates a coupled heat and mass transfer from the mantle into the crust. From considerations of heat-mass budget this transfer can be provided by the flux consisting of silicate matter rather than He or other volatiles. This conclusion is confirmed by the correlation between 3He/ 4He and 87Sr/86Sr ratios in the products of the volcanic and hydrothermal activity in Italy (Polyak et al., 1979b; Parello et al., 2000) and other places. Migration of any substance through geotemperature field transports thermal energy accumulated within this substance, i.e. represents heat and mass transfer. Therefore, only the coupled analysis of both material and energy aspects of this transfer makes it possible to characterise the process adequately and to decipher an origin of terrestrial heat flow observed in upper parts of the earth crust. An attempt of such kind is made in this paper.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: heat flow ; helium isotope ratio ; geothermal energy ; mass transfer ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport
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  • 16
    Publication Date: 2019-11-04
    Description: In order to obtain information on the hydrological signature of rivers during and after heavy rain events, small catchment areas are selected as experimental sites. Hydrograph separations based on environmental tracers are performed. Natural isotopic tracers such as 18O, 2H and particularly 222Rn may help to distinguish the components dominating the outflow, particularly of 'pre-event waters', 'event waters' and 'post-event waters'. Even with moderate concentrations in groundwater, radon can be a very sensitive indicator of groundwater input into rivers. The selected microbasin under investigation is situated in the western part of Luxembourg and belongs to the Attert River catchment. At chosen points at the basin's outflow radon detectors continuously measure radon activity in water. The radon monitors are installed together with high precision thermometers, conductivity meters, flow meters and automatic water samplers for chemical analysis. Besides the continuous measurements, grab water samples are taken at different locations along the stream, most of them during periods of heavy rain events. Presented are the results of a one year measurement campaign. During the dry season i.e. during more or less continuous discharge conditions, the observed mean values do not show substantial variations and can be used as reference values. Fluctuations of the measured data during rain events are discussed and the interplay between the different parameters analysed.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: radon ; hydrology ; tracer ; hydrograph separation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 17
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 18
    Publication Date: 2019-11-04
    Description: Pre-seismic related strains in the Earth s crust are the main cause of the observed geophysical and geochemical anomalies in ground waters preceding an earthquake. Posoc?je Region, situated along the Soc?a River, is one of the most seismically active areas of Slovenia. Our measuring stations close to the Posoc?je Region were installed in the thermal springs at Bled in 1998 and at Zatolmin in 1999. Since the beginning of our survey, radon concentration, electrical conductivity and water temperature have been measured continuously once every hour. In May 2002, the number of geochemical parameters monitored was extended to ionic concentration, pH and Eh, which are analysed once a month. Before seeking a correlation between geochemical and geophysical anomalies with seismic events, the influence of meteorological (atmospheric precipitation, barometric pressure) and hydrological (water table of the Tolminka River) factors on observed anomalies were studied. Results at Zatolmin showed that some radon variation during the period from June to October 2002 may be related to seismic activity and not only to meteorological effects.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: radon ; electrical conductivity ; ions ; thermal springs ; earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 1456098 bytes
    Format: application/pdf
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  • 19
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
    Type: doc-type:article
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  • 20
    Publication Date: 2024-02-28
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Hydrogeological information about an aquifer is difficult and costly to obtain, yet essential for the efficient management of groundwater resources. Transferring information from sampled sites to a specific site of interest can provide information when site‐specific data is lacking. Central to this approach is the notion of site similarity, which is necessary for determining relevant sites to include in the data transfer process. In this paper, we present a data‐driven method for defining site similarity. We apply this method to selecting groups of similar sites from which to derive prior distributions for the Bayesian estimation of hydraulic conductivity measurements at sites of interest. We conclude that there is now a unique opportunity to combine hydrogeological expertise with data‐driven methods to improve the predictive ability of stochastic hydrogeological models.〈/p〉
    Description: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉〈italic〉Article impact statement〈/italic〉: This article introduces hierarchical clustering as a method for defining a notion of site similarity; the aim of this method is to improve the derivation of prior distributions in Bayesian methods in hydrogeology.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://github.com/GeoStat-Bayesian/geostatDB
    Description: https://github.com/GeoStat-Bayesian/exPrior
    Description: https://github.com/GeoStat-Bayesian/siteSimilarity
    Keywords: ddc:551.49 ; hydrogeological sites ; hydrogeological modeling
    Language: English
    Type: doc-type:article
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