ALBERT

Description: The exchange of trace gases across the ocean/atmosphere interface, as well as the deposition of atmospheric pollutants and aerosols, are key processes linking the biogeochemical cycles and biological processes in the ocean with atmospheric chemistry and climate. Here we summarize our knowledge about the distributions of long-lived trace gases (CO2, CH4, N2O), short-lived trace gases, and pollutants (dimethyl sulfide (DMS), isoprene, halocarbons, NOx, SO2, O3, and others), and aerosols in the Indian Ocean. In general, dissolved trace gases show a pronounced temporal and spatial variability, which is caused by the variability of both physical processes (e.g., coastal upwelling) and biological productivity. The distributions of pollutants and aerosols and their depositions to the sea surface are mainly driven by the monsoon system and the variability of their land sources. Nitrogen and iron-containing aerosols can significantly affect biological production in the surface layer of the open Indian Ocean.

Description: Neomphaloidean gastropods are endemic to chemosynthesis-based ecosystems ranging from hot vents to organic falls, and their diversity and evolutionary history remain poorly understood. In the southwestern Pacific, deep-sea hydrothermal vents on back-arc basins and volcanic arcs are found in three geographically secluded regions: a western region around Manus Basin, an eastern region around North Fiji and Lau Basins, and the intermediate Woodlark Basin where active venting was confirmed only recently, on the 2019 R/V L’Atalante CHUBACARC expedition. Although various lineages of neomphaloidean snails have been detected, typically restricted to one of the three regions, some of these have remained without names. Here, we use integrative taxonomy to describe three of these species: the neomphalid Symmetromphalus mithril sp. nov. from Woodlark Basin and the peltospirids Symmetriapelta becki sp. nov. from the eastern region and Symmetriapelta radiata sp. nov. from Woodlark Basin. A combination of shell sculpture and radular characters allow the morphological separation of these new species from their described congeners. A molecular phylogeny reconstructed from 570 bp of the mitochondrial cytochrome c oxidase subunit I gene confirmed the placement of the three new species in their respective genera and the superfamily Neomphaloidea. The finding of these new gastropods, particularly the ones from the Woodlark Basin, provides insights and implications on the historical role of Woodlark as a dispersing centre, in addition to highlighting the uniqueness of the Woodlark faunal community.

Description: The Indian Ocean is an important conduit for the exchange of physical and biogeochemical properties through many distinct interbasin oceanic connections. The Indonesian archipelago provides a gappy pathway for warm tropical waters to enter the Indian Ocean from the Pacific. South of Australia, a complex circulation transports cooler subtropical waters from the Pacific while Indian Ocean waters from within the Leeuwin Current feed a series of currents along the southern Australian continental margin. Southern Ocean waters source both the deep and shallow overturning circulations into the Indian Ocean. The westward leakage of eddies spawned from the Agulhas Current off South Africa returns warm and salty Indian Ocean waters into the Atlantic and plays a significant role in the upper branch of the global meridional overturning circulation. This chapter discusses these pathways and highlights how they change with time and influence the circulation and properties of the Indian and global oceans.

Description: The cruise took place from 14.8.2005 (Akureyri) – 22.8.2005 (Akureyri) Research subject: ROV studies, mapping and sampling of the Tjörnes Offset (Storagrunn, Hollinn, Nafir) Chief Scientist: Prof. Dr. Colin W. Devey, IFM-GEOMAR, Kiel Number of Scientists: 10 Project: DFG De572/13-1 Fracture Zone

Description: Air-sea interaction in late boreal winter is studied over the extratropical North Atlantic (NA) during 1960–2020 by examining the relationship between sea-surface temperature (SST) and total turbulent heat flux (THF). The two quantities are positively correlated on interannual timescales over the central-midlatitude and subpolar NA, suggesting the atmosphere on average drives SST and THF variability is independent of SST. On decadal timescales and over the central-midlatitude NA the correlation is negative, suggesting ocean processes on average drive SST and THF variability is sensitive to SST. The correlation is positive over the subpolar NA. There, interannual and decadal THF variability is governed by the North Atlantic Oscillation (NAO). During the major late 20th and early 21st century SST increase in the subpolar NA diminishing oceanic heat loss associated with a weakening NAO was observed. This study suggests that the atmosphere is more sensitive to SST over the central-midlatitude than subpolar NA. Key Points: - Regional variation in the nature of air-sea interaction over the extratropical North Atlantic (NA) north of 35°N - Timescale dependence in relationship between sea-surface temperature (SST) and turbulent heat flux over the central-midlatitude NA - The atmosphere is more sensitive to SST variability over the central-midlatitude than subpolar NA

Description: The eastern boundary regions of the Atlantic and Pacific oceans host highly productive ecosystems. These upwelling systems play a key role in supporting marine biodiversity, local and global fisheries, and biogeochemical cycles. Consequently, it is of high interest to understand the processes driving these systems. This thesis focuses on one of these highly productive ecosystems - the tropical Angolan upwelling system (tAUS). Conditions in the tAUS undergo strong seasonal modulations, where many characteristics exhibit variability on semi-annual and annual time scales. The lowest sea surface temperature (SST), highest primary productivity, and lowest along-shore wind are found in austral winter during the main upwelling season. Interestingly, and in contrast to other upwelling systems, the productivity signal cannot be explained by local wind-driven upwelling. Possible forcing mechanisms of the productivity signal are connected to equatorial dynamics via the propagation of coastal trapped waves (CTWs). The tAUS is thus an ecosystem influenced by both remote and local processes. This thesis focuses on understanding the physical drivers of the seasonal and interannual variability in the tAUS, particularly in SST and primary productivity. The analyses conducted within this thesis are mostly based on observational datasets. Additionally, the results are compared with output of a regional ocean model. The observational data includes shipboard measurements as well as satellite products. The shipboard measurements comprise an extensive ocean turbulence dataset. This dataset provides, for the first time, insights into turbulent heat and nitrate fluxes in the tAUS. In the tAUS, waters are colder directly at the coast than further offshore. Both SST and the crossshore SST gradient exhibit a seasonal cycle. A seasonal mixed layer heat budget is calculated to identify atmospheric and oceanic causes for heat content variability. The results show that the seasonal cycle in SST is mainly controlled by surface heat fluxes and turbulent heat loss at the base of the mixed layer. The net surface heat flux warms the coastal ocean more strongly than the offshore region and thus acts to dampen cross-shore SST differences. Ocean turbulence data shows that turbulent mixing across the base of the mixed layer is an important cooling term. This turbulent cooling, being strongest in the shallow shelf regions, explains the observed negative cross-shore temperature gradient. The seasonal cycle of the cross-shore SST gradient exhibits semi-annual variability, likely linked to tidal mixing acting on changing background stratification associated with the passage of CTWs. The primary productivity in the tAUS peaks in late austral winter. Analyses of observational data and the output of a regional ocean model reveal that the seasonal productivity maximum is due to the combined effect of CTWs and elevated tidal mixing on the shelf. During austral winter, the passage of an upwelling CTW displaces the nitracline upward by more than 50 m. Thereby, nitrate-rich waters spread onto the shelf, where elevated vertical mixing causes a nitrate flux into the surface mixed layer. High-mode CTWs play an important role in the upward and onshore transport of nitrate-rich waters. The interannual variability of the productivity maximum in the tAUS is strongly correlated with the amplitude of the upwelling CTW. Consequently, it is of high interest to investigate dynamical factors controlling the characteristics of the CTW as their strength controls the amount of primary production in the tAUS. Regression analyses suggest that the timing and amplitude of the austral winter upwelling CTW in tAUS are influenced by variability in different regions. The timing of the CTW is mostly influenced by variability in the equatorial region and along the southern African coast. Here. weaker equatorial easterlies from April to July lead to a late arrival of the upwelling CTW. The amplitude of the CTW is influenced by variability in the eastern equatorial Atlantic and in the central South Atlantic, a region characterizing the strength of the South Atlantic anticyclone. A cooling in the eastern equatorial Atlantic four to three months before the arrival of the CTW causes stronger zonal winds, leading to a stronger austral winter upwelling CTW. In general, the results suggest that the timing and amplitude of the upwelling CTW in the tAUS during austral winter are predictable on seasonal time scales. Overall, this thesis enhances our understanding of the seasonal to interannaul dynamics in the tAUS. The results of this thesis show that CTWs, near-coastal mixing, and surface heat fluxes are essential processes to explain the seasonal variability of SST and productivity in the tAUS. A key result is the proposed mechanism explaining the austral winter productivity peak, based on the combined effect of CTWs and near-coastal mixing. This result not only advances process understanding in the tAUS but also suggests a potential predictability of productivity in the region.

Description: A stratigraphic complex composed of mass transport deposits (MTDs), where the gas occurrence allows for the formation of a gas chimney and pipe structure, is identified based on seismic interpretation in the QiongDongNan area of the northern South China Sea. During the Fifth Gas Hydrate Drilling Expedition of the Guangzhou Marine Geological Survey, this type of complex morphology that has close interaction with local gas hydrate (GH) distribution was eventually confirmed. A flow-reaction model is built to explore the spatial–temporal matching evolution process of massive GH reservoirs since 30 kyr before the present (BP). Five time snapshots, including 30, 20, 10, and 5 kyr BP, as well as the present, have been selected to exhibit key strata-evolving information. The results of in situ tensile estimation imply fracturing emergence occurs mostly at 5 kyr BP. Six other environmental scenarios and three cases of paleo-hydrate existence have been compared. The results almost coincide with field GH distribution below the bottom MTD from drilling reports, and state layer fracturing behaviors always feed and probably propagate in shallow sediments. It can be concluded that this complex system with 10% pre-existing hydrates results in the exact distribution and occurrence in local fine-grained silty clay layers adjacent to upper MTDs.

Description: Key Points: - We reconstruct the temporal evolution of seawater isotope ratios of boron, strontium, lithium, and osmium over the last 65 million years - The evolution of seawater boron isotope ratio shows similarity to the evolution of strontium, lithium and osmium isotope ratios - Randomly drawn, smooth time series are provided for use in uncertainty propagation in calculation of palaeo pH The boron isotope ratio of seawater (δ11Bsw) is a parameter which must be known to reconstruct palaeo pH and CO2 from boron isotope measurements of marine carbonates. Beyond a few million years ago, δ11Bsw is likely to have been different to modern. Palaeo δ11Bsw can be estimated by simultaneously constraining the vertical gradients in foraminiferal δ11B (Δδ11B) and pH (ΔpH). A number of subtly different techniques have been used to estimate ΔpH in the past, all broadly based on assumptions about vertical gradients in oxygen, and/or carbon, or other carbonate system constraints. In this work we pull together existing data from previous studies, alongside a constraint on the rate of change of δ11Bsw from modeling. We combine this information in an overarching statistical framework called a Gaussian Process. The Gaussian Process technique allows us to bring together data and constraints on the rate of change in δ11Bsw to generate random plausible evolutions of δ11Bsw. We reconstruct δ11Bsw, and by extension palaeo pH, across the last 65Myr using this novel methodology. Reconstructed δ11Bsw is compared to other seawater isotope ratios, namely ,87/86 Sr, 187/188 Os , and δ7Li, which we also reconstruct with Gaussian Processes. Our method provides a template for incorporation of future δ11Bsw constraints, and a mechanism for propagation of uncertainty in δ11Bsw into future studies.

Description: What role do socio-demographic and local environmental factors play in the perception of climate change? The article of Landwehr et al. to be discussed here presents interdisciplinary findings on this question, which are particularly interesting regarding the group of farmers. However, the findings also raise questions about the degree of abstraction of climate perception, the rigidity of social identity, the role of the media and the strategy of targeting. In the context of recent “farmer protests” and populist narratives, the author of this response concludes that future interdisciplinary research projects on climate perceptions should also analyse political variables and the relevance of populist discourses.

Description: Welche Rolle spielen sozio-demografische und lokale Umweltfaktoren für die Klimawandelwahrnehmung? Der hier besprochene Artikel von Landwehr et al. stellt interdisziplinäre Befunde zu dieser Frage vor, die besonders mit Blick auf die Gruppe der Landwirt(inn)e(n) interessant sind. Die Befunde werfen aber auch Fragen zum Abstraktionsgrad der Klimawahrnehmung, der Rigidität sozialer Identität, der Rolle der Medien und der Zielgruppenstrategie auf. Im Kontext der jüngsten ,,Bauernproteste“ und populistischer Narrative folgert der Autor dieser Reaktion, dass in künftigen interdisziplinären Forschungsprojekten zur Klimawahrnehmung auch politische Variablen und die Relevanz populistischer Diskurse untersucht werden sollten.