ALBERT

Description: A detailed geochemical-petrological examination of layer 2 basalts recovered during Leg 37 of the DSDP has revealed that the original distribution, form and abundance of igneous sulfide have been profoundly altered during low-grade oxidative diagenesis. The net result appears to have been a rather pervasive remobilization of igneous sulfide to form secondary pyrite accompanied by a bulk loss of sulfur equivalent to about 50-60% of the original igneous value, assuming initial saturation. It is suggested that during infiltration of seawater into the massive crystalline rock, igneous sulfide has experienced pervasive oxidation, under conditions of limited oxidation potential, to form a series of unstable, soluble sulfur species, primarily in the form of SO3[2-] and S2O3[2-]. Spontaneous decomposition of these intermediate compounds through disproportionation has resulted in partial reconstitution of the sulfur as secondary pyrite and the generation of SO4[2-] ion, which, due to its kinetic stability, has been lost from the basalt system and ultimately transferred to the ocean. This model not only satisfies the geochemical and petrological observations but also provides a suitable explanation for the highly variable delta34S values which characterize secondary sulfides in deep ocean floor basalts.

Description: Oceanic crustal drilling by R. V. Glomar Challenger at 15 sites in the North Atlantic has led to a complex picture of the upper half kilometer of the crust. Elements of the picture include the absence of the source for linear magnetic anomalies, marked episodicity of volcanic activity, ubiquitous low temperature alteration and evidence for large scale tectonic disturbance. Comparison sections in the Pacific and much deeper crustal drilling are needed to attack problems arising from the North Atlantic results.

Description: Miocene paleoceanographic evolution exhibits major changes resulting from the opening and closing of passages, the subsequent changes in oceanic circulation, and development of major Antarctic glaciation. The consequences and timing of these events can be observed in variations in the distribution of deep-sea hiatuses, sedimentation patterns, and biogeographic distribution of planktic organisms. The opening of the Drake Passage in the latest Oligocene to early Miocene (25-20 Ma) resulted in the establishment of the deep circumpolar current, which led to thermal isolation of Antarctica and increased global cooling. This development was associated with a major turnover in planktic organisms, resulting in the evolution of Neogene assemblages and the eventual extinction of Paleogene assemblages. The erosive patterns of two widespread hiatuses (PH, 23.0-22.5 Ma; and NH 1, 20-18 Ma) indicate that a deep circumequatorial circulation existed at this time, characterized by a broad band of carbonate-ooze deposition. Siliceous sedimentation was restricted to the North Atlantic and a narrow band around Antarctica. A major reorganization in deep-sea sedimentation and hiatus distribution patterns occurred near the early/middle Miocene boundary, apparently resulting from changes in oceanic circulation. Beginning at this time, deep-sea erosion occurred throughout the Caribbean (hiatus NH 2, 16-15 Ma), suggesting disruption of the deep circumequatorial circulation and northward deflection of deep currents, and/or intensification of the Gulf Stream. Sediment distribution patterns changed dramatically with the sudden appearance of siliceous-ooze deposition in the marginal and east equatorial North Pacific by 16.0 to 15.5 Ma, coincident with the decline of siliceous sedimentation in the North Atlantic. This silica switch may have been caused by the introduction of Norwegian Overflow Water into the North Atlantic acting as a barrier to outcropping of silica-rich Antarctic Bottom Water. The main aspects of the present oceanic circulation system and sediment distribution pattern were established by 13.5 to 12.5 Ma (hiatus NH 3), coincident with the establishment of a major East Antarctic ice cap. Antarctic glaciation resulted in a broadening belt of siliceous-ooze deposition around Antarctica, increased siliceous sedimentation in the marginal and east equatorial North Pacific and Indian Oceans, and further northward restriction of siliceous sediments in the North Atlantic. Periodic cool climatic events were accompanied by lower eustatic sea levels and widespread deep-sea erosion at 12 to 11 Ma (NH 4), 10 to 9 Ma (NH 5), 7.5 to 6.2 Ma (NH 6), and 5.2 to 4.7 Ma (NH 7).

Description: Refractory megacrysts of olivine, plagioclase, chromian diopside and Cr-Al spinel, which were not in equilibrium with the host oceanic tholeiite on eruption, are present in samples from several dredge sites and DSDP drill sites in the Atlantic and Pacific Oceans. They have multiple origins: (1) cognate or accidental mantle fragments; (2) relict fragments from fractional crystallization of parental liquids considerably more primitive than oceanic tholeiite; and most commonly (3) the fractional crystallization products of such liquids mixed with oceanic tholeiite magma. Melt inclusions in chrome-spinel phenocrysts provide evidence for this postulated Mg- and Ca-rich magma which has counterparts in the Scottish Tertiary Province and in west Greenland.

Description: Nodule samples obtained were described and studied on board for 1) observation of occurrence and morphology in and outside samplers, size classification, measurement of weight and calculation of population density (kg/m2); 2) photographing whole nodules on the plate marked with the frames of unit areas of both 0cean-70 (0.50 m2) and freefall grab (0.13 m2), and that of typical samples on the plate with a 5 cm grid scale: 3) observation of internal structures of the nodules on cut section; and 4) determination of mineral composition by X-ray diffractometer. The relation between nodule types and geological environment or chemical composition was examined by referring to other data of related studies, such as sedimentology. acoustic survey, and chemical analysis.

Description: DSDP Leg 337 was planned as an attemp at deep penetration of the igneous section of the oceanic crust on the western flank of the FAMOUS (Franco- American Mid-Ocean Undersea Study) area of the Mid-Atlantic Ridge at 36°N. Site 332 is located in Deep Drill Valley approximately 30 km west of the axis of the Mid-Atlantic Ridge at 36°52'N latitude. The principal goal at this site was deep penetration into layer 2 of the ocean crust by multiple re-entry. Site 334 was drilled on a steep east-facing slope in a small, deep basin near the middle of magnetic anomaly 5. In this area, breccias with gabbro and peridotite clasts in a nannofossil-foram ooze matrix are interlayered with the plutonic rocks and may reflect exposure of a melange in or near the Median Valley of the Mid- Atlantic Ridge prior to burial by later basaltic extrusions.

Description: Titanomagnetites separated from 15 different rock samples (including ocean-floor basalts from DSDP Legs 37, 45 and 46) were analyzed together with whole-rock samples by instrumental neutron-activation analysis for Sc, Cr, Co, Zn, Hf, Ta, Th and the REE La, Ce, Nd, Sm, Eu, Gd, Tb, Dy, Tm, Yb and Lu. In titanomagnetities from ocean-floor basalts and some other rocks, REE are enriched with respect to the whole-rock composition by factors of between 1.5 and 3 for light REE and between 1.0 and 1.9 for heavy REE; that is, REE with larger ionic radii are preferentially incorporated into the magnetite lattice. Three magnetite samples are REE depleted. Their whole-rock samples contain P in appreciable amounts, so apatite, an important REE-accumulating mineral, could have captured REE to some extent. All titanomagnetites show a marked negative Eu anomaly, this is most probably caused by discrimination of Eu(2+) from the magnetite lattice. Co, Zn, Hf and Ta are significantly enriched in magnetites. The distribution behaviour of Sc and Cr is masked chiefly by the crystallization of clinopyroxene and therefore is not easy to estimate. Ulvöspinel contents of about 70% for the titanomagnetites from ocean-floor basalts were estimated from qualitative microprobe analysis. Ulvöspinel contents of all other samples varied in a wide range from 20% to about 90%. No correlation could be observed between this and the REE contents of the magnetites. Ilmenite exsolution lamellae could only be observed in titanomagnetites from a doleritic basalt from Leg 45.

Description: Times of vein mineral deposition in the ocean crust have been determined both by Rb-Sr isochron ages of vein smectites and by comparison of 87Sr/86Sr ratios of vein calcites with the known variations of seawater 87Sr/86Sr ratio with time. Results from drilling sites 105, 332B and 418A, Atlantic Ocean, which have basement formation ages of 155 m.y., 3.5 m.y., and 110 m.y., respectively, show that vein deposition is essenrially complete within 5-10 m.y. after formation of the basaltic crust. This provids direct evidence that hydrothermal circulation of sea-water through the oceanic crust is an important process for only 5-10 m.y. after crust formation.

Description: REE abundances in gabbros and peridotites from Site 334 of DSDP Leg 37 show that these rocks are cumulates produced by fractional crystallization of a primitive oceanic tholeiite magma. They may be part of a layered oceanic complex. The REE distributions in the residual liquids left after such a fractionation are similar to those of incompatible element-depleted oceanic tholeiites. The REE data indicate that the basalts which overlie the gabbro-peridotite complex, are not genetically related to plutonic rocks.

Description: 143Nd/144Nd ratios have been determined on 37 samples of oceanic basalt, with a typical precision of +/- 2-3 * 10**-5 (2 sigma). Ocean island and dredged and cored submarine basalts are included for which reliable measurements of 87Sr/86Sr ratios exist in the literature or have been measured as part of this study. A strong negative correlation exists between 143Nd/144Nd and 87Sr/86Sr ratios in basalts from Iceland and the Reykjanes Ridge, but such a clear correlation does not exist for samples from the Hawaiian Islands. However, when other ocean island basalts from the Atlantic are included there is an overall correlation between these two parameters. Increases and decreases in Rb/Sr in oceanic basalt source regions have in general been accompanied by decreases and increases respectively in Sm/Nd ratios. The compatibility of the data with single-stage models is assessed and it is concluded that enrichment and depletion events, which are consistent with transfer of silicate melts, are responsible for the observed variation.

Description: Several amino acid diagenetic reactions, which take place in the deep-sea sedimentary environment, were investigated, using various Deep Sea Drilling Project (DSDP) cores. Initially it was found that essentially all the amino acids in sediments are bound in peptide linkages; but, with increasing age, the peptide bonds undergo slow hydrolysis that results in an increasingly larger fraction of amino acids in the free state. The hydrolysis half-life in calcareous sediments was estimated to be ~1–2 million years, while in non-carbonate sediment the hydrolysis rate may be considerably slower. The amino acid compositions and the extent of racemization of several amino acids were determined in various fractions isolated from the sediments. These analyses demonstrated that the mechanism, kinetics, and rate of amino acid diagenesis are highly dependent upon the physical state (i.e., free, bound, etc.) in which the amino acids exist in the sedimentary environment. In the free state, serine and threonine were found to decompose primarily by a dehydration reaction, while in the bound state (residue or HCl-insoluble fraction) a reversible aldol-cleavage reaction is the main decomposition pathway of these amino acids. The change in amino acid composition of the residue fraction with time was suggested to be due to the hydrolysis of peptide bonds, while in foraminiferal tests the compositional changes over geological time are the result of various decomposition reactions. Reversible first-order racemization kinetics are not observed for free amino acids in sediments. The explanation for these anomalous kinetics involves a complex reaction series which includes the hydrolysis of peptide bonds and the very rapid racemization of free amino acids. The racemization rates of free amino acids in sediments were found to be many orders of magnitude faster than those predicted from elevated temperature experiments using free amino acids in aqueous solution. The racemization rate enhancement of free amino acids in sediments may be due to the catalysis of the reaction by trace metals. Reversible first-order kinetics are followed for amino acids in the residue fraction isolated from sediments; the rate of racemization in this fraction is slower than that predicted for protein-bound amino acids. Various applications of amino acid diagenetic reactions are discussed. Racemization and the decomposition reaction of serine and threonine can both be used, with certain limitations, to make rough age estimates of deep-sea sediments back to several million years. The extent of racemization in foraminiferal tests which have been dated by some other independent technique can be used to estimate geothermal gradients, and thus heat flows, and to evaluate the bottom water temperature history in certain oceanic areas.

Description: Comparison of rates of accumulation of organic carbon in surface marine sediments from the central North Pacific, the continental margins off northwest Africa, northwest and southwest America, the Argentine Basin, and the western Baltic Sea with primary production rates suggests that the fraction of primary produced organic carbon preserved in the sediments is universally related to the bulk sedimentation rate. Accordingly, less than 0.01% of the primary production becomes fossilized in slowly accumulating pelagic sediments [(2 to 6 mm (1000 y)**-1] of the Central Pacific, 0.1 to 2% in moderately rapidly accumulating [2 to 13 cm (1000 y)**-1] hemipelagic sediments off northwest Africa, northwest America (Oregon) and southeast America (Argentina), and 11 to 18% in rapidly accumulating [66 to 140 cm (1000 y)**-1] hemipelagic sediments off southwest America (Peru) and in the Baltic Sea. The emiprical expression: %Org-C = (0.0030*R*S**0.30)/(ps(1-Theta)) implies that the sedimentary organic carbon content (% Org-C) doubles with each 10-fold increase in sedimentation rate (S), assuming that other factors remain constant; i.e., primary production (R), porosity and sediment density (ps). This expression also predicts the sedimentary organic carbon content from the primary production rate, sedimentation rate, dry density of solids, and their porosity; it may be used to estimate paleoproductivity as well. Applying this relationship to a sediment core from the continental rise off northwest Africa (Spanish Sahara) suggests that productivity there during interglacial oxygen isotope stages 1 and 5 was about the same as today but was higher by a factor of 2 to 3 during glacial stages 2, 3, and 6.

Description: Eolian dust preserved in deep-sea sediment can provide a direct historical record of global atmospheric circulation. Data from a reasonably complete Upper Cretaceous section of pelagic sediments recovered at DSDP Site 463 in the central North Pacific provides a good record of eolian activity during the time period between about 112 and 66 m.y. ago. We have isolated the eolian component from these sediments, determined its mass accumulation rate and combined these data with the mineralogy of the inorganic fraction determined by others to construct a record of eolian deposition. Volcanic input is significant during Aptian-Albian and Maastrichtian times, otherwise continentally derived minerals dominate. Mass accumulation rates of the continental eolian component range from over 500 mg/cm**2/kyr during the late Albian to a low of 5 mg/cm**2/kyr during Coniacian time. (For comparison, the upper Miocene to Pleistocene rate averages about 20 mg/cm**2/kyr). The temporal pattern of Late Cretaceous eolian accumulation of Site 463 generally matches known changes in sea level, suggesting that source availability is the dominant control of eolian sedimentation during that time.

Description: Analyses of Pb from mid-ocean ridge basalts obtained from DSDP Leg 37 lie on a line of near-zero-age slope. The data seem consistent with an evolutionary model of three stages, the beginning of the second stage being at about 600 m.y. - the model age obtained for the least radiogenic Pb. The beginning of the third stage of evolution at the time of formation of the rocks apparently did not change the average Th/U ratio since measured values are consistent with the ratio deduced from Pb isotope ratios. Ratios of U/Pb are not consistent with Pb isotope ratios, however, thus ruling out a simple two-stage evolutionary model.

Description: The Aminoil Group drilled a 10,000 ft - well a few kilometers off the Krakatau volcano in 1973. The well bottomed in Pliocene sediments after penetrating a more than 8,000 ft thick Upper Pliocene section of mainly claystones with interbedded sand-, siltstones and pyroclastics. On the basis of temperature surveys and BHT's measured during logging, a static formation temperature in excess of 450° F was extrapolated for the bottom of the hole. Tue high temperatures caused some deterioration in the mud properties, but otherwise no serious drilling problems. Owing to overpressures a high salinity oil mud and controlled drilling had to be employed. The well was P&A because no economic hydrocarbon accumulations could be expected in the high temperature regimes.

Description: research

Description: Oxygen isotopic and microfaunal analyses and shell size variations of Orbulina universa in two Indian Ocean cores indicate that the position of the Subtropical Convergence has fluctuated between a northern limit north of 31°S during glacial stages and its present, maximum southern limit. The northward displacement of the Subtropical Convergence to a position off Durban, South Africa, reflects the general weakness of the Agulhas Current during glacial stages and parts of interglacial stages, representing about 65 percent of the past 540,000 years.

Description: Three piston cores in the subarctic region of the North Pacific show consistent changes in relative abundance of diatom species throughout the Brunhes magnetic epoch. These events can be used both as stratigraphic markers to subdivide the interval and as indicators of oceanographic conditions. The stratigraphic record shows an acme for A. ochotensis from about 625-350 Kyr (Isotope Stages 15-10); a marked increase in amplitude of abundance fluctuations for R. hebetata 300-0 Kyr (Stages 8-1), the extinction of R. curvirostris at 276 Kyr (Stage 8), and abundance fluctuations of D. seminae roughly in phase with the global oxygen isotope record from 450-0 Kyr (Stages 12-1). In the subarctic Pacific, an abrupt change in species abundance is not a reliable indicator of hiatus occurrence. Although details are not clear, there appears to have been a fundamental change of the subarctic gyre during the middle Brunhes (Stages 10-8 time), with more intense glacial intervals and stronger glacial-interglacial contrast occurring after that time. Coarse clastic detritus is not restricted to glacial intervals, suggesting that ice-rafting has occurred throughout the Brunhes interval; peak levels of ice-rafting may occur during ice-growth and decay, as well as during short intervals within a stage.

Description: Gneissic granodiorite was recovered by drilling at the base of the Mazagan escarpment, 100 km west of the Casablanca, Morocco, at 4000 m water depth. Coarse, predeformative muscovite yielded dates of -515 Ma, fine-grained muscovite of -455 Ma, biotite -360 and 335 Ma, and feldspar -315 Ma. These dates are tentatively correlated with the microscopic results. We assume a minimum age of middle Cambrian for the granodiorite, an Ordovician deformation and mylonitization, and a Late Carboniferous overprint under upper greenschist facies conditions.

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Description: Die Bestimmung der Temperaturverteilung in der Erdkruste und im oberen Erdmantel ist von großer Bedeutung für die Behandlung geotektonischer Probleme. In dieser Arbeit wird die Temperaturverteilung längs eines Profils in Süditalien untersucht, das vom Südadriatischen Meer durch Kalabrien zum Tyrrhenischen Meer verläuft. Grundlage für diese Untersuchung bilden eine Anzahl publizierter Wärmeflußwerte und ein refraktionsseismisches Profil. Längs des ausgewählten geothermischen Profils sind die Temperatur-Tiefen-Funktionen für zwei Modelle der Wärmeproduktionsverteilung, Schichten- und Exponential-Modell , für den stationären Zustand berechnet worden.

Description: The determination of temperature distribution in the earth's crust and upper mantle is of great importance for geotectonic problems. The temperature distribution is discussed along a profile in southern Italy, which runs from the Adriatic to the Tyrrhenian Seas. This study is based on published heat flow values and seismic refraction data. The temperature-depth-functions are calculated for layer and exponential models for the heat production assuming a stationary state.

Description: thesis

Description: DFG, SUB Göttingen

Description: Die Toskana ist die stärkste geothermische Anomalie auf dem europäischen Kontinent. In dieser Anomalie finden sich zahlreiche lokale geothermische Felder mit hoher Enthalpie, wie z.B. das Feld von Travale. In diesem geothermischen Feld, das im Era-Graben liegt, wurden in den Jahren 1980/81 elektromagnetische Messungen durchgeführt. Es war das Ziel der Untersuchungen, die Quelle und die Ursache dieser teilweise bekannten Anomalie zu finden. Hierzu sollte die Verteilung der elektrischen Leitfähigkeit in der Erdkruste bis in Tiefen der Kruste-Mantel-Grenze mit den Methoden der Magnetotellurik und Erdmagnetischen Tiefensondierung untersucht werden. Parallel dazu wurde die geothermische Anomalie von Travale mit einer Vielzahl weiterer elektromagnetischer, seismischer und geochemischer Methoden untersucht. Das Ziel, die geothermische Anomalie in der Erdkruste zu lokalisieren, war nicht einfach zu erreichen. Deshalb war es notwendig, ein Modell der Anomalie zu erarbeiten, aus dem die Lokalität folgen sollte. Vor angegangene elektromagnetische Untersuchungen (HAAK & SCHWARZ 1981) hatten gezeigt, daß nahezu das gesamte Gebiet der Toskana als eine Anomalie der elektrischen Leitfähigkeit anzusehen ist: Gutleitende Deckschichten, mit bis zu 10 km Mächtigkeit, werden von einem hochohmigen Basement unterlagert. An einigen Meßorten deutet sich der Übergangsbereich Kruste / Mantel - in einer Tiefe zwischen 20 und 30 km - durch eine Zone hoher Leitfähigkeit an. Dieser Bereich zeichnet sich durch Lamellen hoher und extrem niedriger seismischer Wellengeschwindigkeiten aus. Petrologisch kann dieses durch eine Wechsellagerung von basischem und saurem Material gedeutet werden. Die zeitlichen Variationen des elektrischen und magnetischen Feldes wurden im geothermischen Feld von Travale in einem breiten Periodenbereich von 6 - 10.000 s registriert. Die Meßorte liegen überwiegend auf zwei Profilen, eines verläuft parallel zum Era-Graben aus der Anomalie heraus nach NW, das zweite schneidet die Anomalie senkrecht zum Graben. Der Meßpunktabstand war mit einigen hundert Metern bis zu mehreren Kilometern sehr dicht, um möglichst alle lateralen Variationen der scheinbaren spezifischen Widerstände beobachten zu können. Es zeigte sich, daß die lateralen Variationen der spezifischen Widerstände im Gebiet von Travale sehr groß waren. Bis zu Perioden von 50-100 s ist der Era-Graben die dominierende zweidimensionale Leitfähigkeitsstruktur. Die gemessenen scheinbaren spezifischen Widerstände sind bei längeren Perioden durch dreidimensionale Leitfähigkeitsstrukturen verzerrt. Die scheinbaren elektrischen Widerstände sind innerhalb der geothermischen Anomalie mit Werten bis zu 50 Qm äußerst klein, während sie nördlich des geothermischen Feldes auf 100-300 Qm ansteigen, um dann etwa 7 km NW der Anomalie wieder deutlich abzufallen. Selbst in der tieferen Kruste werden keine höheren Widerstände angetroffen. Die integrierte Leitfähigkeit weist das geothermische Feld ebenso als eine Anomalie der elektrischen Leitfähigkeit aus, während nördlich davon die "hochohmige Barriere" bestätigt wurde. Aus den Ergebnissen der Seismik und Magnetotellurik wurde ein Modell für die geothermische Anomalie von Travale und die Toskana abgeleitet, das sich in drei Stockwerke gliedert: - Das unterste Stockwerk, die Übergangszone zwischen Oberem Mantel und Unterkruste in 20-30 km Tiefe ist die Quelle auf steigender heißer Gase und Flüssigkeiten. Die Temperatur beträgt etwa 700° C. - Das mittlere Stockwerk ist von tief reichenden, vertikalen Störungen durchsetzt, die einen konvektiven Wärmetransport durch die hydrothermalen Phasen in das oberste Stockwerk erlauben. Im Gebiet von Travale hat sich durch längs- und zum Era-Graben querstreichende Störungen eine ausgeprägte Schwächezone in der Kruste gebildet, die einen besonders intensiven Wärmetransport zuläßt. Der Temperaturgradient wird mit 15° C/km angenommen. - Das oberste Stockwerk besteht aus Sedimenten und kristallinen Formationen, die im wesentlichen von horizontalen Abscherungs- und Störungsflächen durchzogen sind, in denen hydrothermale Phasen zirkulieren. Innerhalb der Basements hat sich so ein zweites Reservoir ausgebildet, welches das bekannte geothermische Reservoir in den Karbonaten in Tiefen von 1-2 km durch ein ausgeprägtes Bruchsystem speist. Die Temperatur ist in 4 km Tiefe mit 400° C sehr hoch. Die augenblicklich geförderten heißen Gase und Wässer sind meteorologischen Ursprungs und werden an der Oberkante des toskanischen Basements aufgeheizt. Aus tektonischer Sicht besteht das oberste Stockwerk aus allochthonen Decken, die während der Orogenese über die Toskana hinweggeschoben wurden. Dieser tektonischen Kompressionsphase folgte eine Phase starker lateraler Dehnungen, die bis heute andauern. Das System von Grabenbrüchen und tiefgreifenden Verwerfungen ist Ausdruck dieser Dehnungstektonik. Die damit verbundenen Störungszonen tragen zu einer Entwässerung und Entgasung der tiefen Erdkruste bei und lassen die hydrothermalen Phasen in das oberste Stockwerk aufs teigen. In ausgeprägte Schwächezonen, die die gesamte Kruste durchziehen und die durch undurchlässige Schichten nach oben abgeschlossen werden, kann sich so ein geothermisches Reservoir ausbilden.

Description: Tuscany is the strongest geothermal anomaly in continental Europe. Numerous local high enthalpy geothermal fields are to be found within this anomaly, e.g. the Travale field. Electromagnetic soundings have been carried out in this geothermal field, which lies in the Era-Graben, in the years 1980 and 1981. The aim of this study was to find the origin as well as the cause of this partly known anomaly, using the methods of magnetotelluric- and geomagnetic depth soundings to study the distribution of electrical conductivity in the earth's crust downwards to the crust/mantle boundary, at least. Parallel to this study the geothermel anomaly of Travale has been studied with the help of various other methods, including electromagnetic, seismic and geochemical surveys. To localize the geothermal anomaly in the earth's crust was not an easy task. Therefore it seemed to be necessary to develop a model of the anomaly, first, and then to localize it. Earlier electromagnetic investigations (HAAK & SCHWARZ 1981) have shown, that nearly the whole area of Tuscany corresponds to an electrical conductivity anomaly: A well conducting cover, reaching down to 10 km depth is underlain by a high resistive basement. At some places within the geothermal anomaly a zone of high conductivity has been found at the depth of the crust/mantle-boundary (between 20 and 30 km) . Seismic refraction measurements are indicating a wide transition zone between the crust und upper mantle, displayed by alternating high- und extreme low-velocity layers. The time-varying electric- and magnetic fields have been recorded in the Travale area in a broad period range from 6-10.000 s, mainly on two profiles, the one parallel, the other perpendicular to the Era-Graben. The stations have been very close to each other, spacings varied between some hundreds of meters and a few kilometers, to study lateral variations of apparent resistivities within the Graben. In deed, lateral variations of apparent resistivities have been very large in the Travale area. Up to 50-100 s the Era-Graben is the dominating 2D-structure, but for longer periods of investigation the three-dimensionality of the electrical conductivity structure has to be considered. The apparent resistivities inside the geothermal anomaly are extremely low, reaching not more than 50 Gm, even in the lower crust, whereas going up to 100-300 firn north of the geothermal field. Further to NW apparent resistivities are coming down again to 5-5o Gm. Total conductance as well indicates the geothermal field as a local conductivity anomaly, whereas more to the north the poorly conducting "barrier" has been confirmed. Based on the results of the magnetotelluic soundings and those of the seismic survey a geothermal model for the anomaly of Travale as well as for Tuscany has been developed. The crust is built up by 3 stories: - The lowermost story of the transition from the mantle to the crust at 20-30 km depth has to be regarded as the origin of hot gases and fluids. Temperature amounts to 700° C. - The central story is more or less fractured vertically so that pathways allow convective transport of heat by means of hydrothermal fluids to the upper story. In the Travale area a weak crustal zone of faults crossing over has developed, allowing the transport of heat to be very intensive. The temperature gradient is assumed to reach not more than 15° C/km. - The uppermost story consists of sediments and more or less horizontally fractured crystalline formations, filled with hot, circulating fluids. Within the basement a second reservoir has evolved, which feeds the known geothermal reservoir in the carbonate series at 1-2 km depth through fractures and cracks in the top of the basement. The temperature of about 400° C in 4 km depth is extremely high. The actually exploited hot gases and fluids are of meterological origin and heated up at the top of the basement. From the tectonic point of view, the uppermost story consists of allochthonous nappes shifted across Tuscany during orogenesis. This compressive tectonic deformation was followed by strong dilatational forces, which are still active in the whole crust, expressed by the features of graben structures and deep reaching faults. This process gives volatiles and water generated by dehydration in the deep crust the chance to rise to the uppermost story. A basement fractured at the top and an impermeable cover in the uppermost layer will then favour the development of a geothermal reservoir.

Description: thesis

Description: DFG, SUB Göttingen

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Description: research

Description: research

Description: research

Description: research

Description: research

Description: research

Description: research