ALBERT

Description: Sediments and rocks recovered in CRP-1 coring operations contain relatively little organic matter (average 0.4% TOC) and very small amounts of solvent-soluble organic matter ( average 60 µg bitumen/g rock). The kerogen recovered from these rocks has atomic H:C ratios that range from 0.7 to 1.0 and atomic O:C ratios that range from 0.14-0.22. This range of values could be produced by mixing coal detritus with aquatic organic matter. Coal with the O:C ratios necessary to produce the kerogen present in the CRP-1 samples occurs in outcrops of the Permian Beacon Supergroup proximal to the drillsite.

Description: Stable isotope records, and sedimentological and organic-geochemical investigations of marine sediments from the east Greenland Sea at 70°N provide important information about glacial-interglacial variations of paleoenvironments through the last 225 kyr. The oxygen isotope records established on the planktonic foraminifer N. pachyderma sin. show some excursions from the global climate pattern, probably due to local/regional overprint by meltwater supply. The cold, low-saline East Greenland Current and fluctuations in sea-ice covering were a crucial element controlling the carbonate production in the subsurface/surface water column in the east Greenland Sea over the last 225 kyr. The beginning of Termination Ia is AMS 14C dated at about 15.8 kyr B.P. and interpreted as a Greenland Ice Sheet meltwater signal. The stage 2/3 boundary is dated at about 25 kyr B.P. The timing of the onset of the last deglacial meltwater event is about 800 years earlier than that of the Barents Shelf Ice Sheet meltwater signal recorded in the Fram Strait. Several major pulses of increased supply of coarse-grained terrigenous material by glacio-marine processes occurred during the last 225 kyr. The supply of coarse-grained ice-rafted debris at the East Greenland continental slope reached maximum values during the last glacial maximum (stage 2/Weichselian, 15-19 kyr B.P.). The drastic climatic change and the gradual retreat of continental ice masses/glaciers during the last deglaciation (Termination I) are clearly documented in the marine sedimentary sequences from shelf and upper slope environments. This process resulted in distinctly decreased supply and deposition of ice-rafted debris in the open shelf-upper slope environments. During Termination I, the sea-ice cover also decreased, causing an increase in surface-water productivity, indicated by increased organic carbon and biogenic opal deposition.

Description: High-resolution stable oxygen and carbon isotope and sedimentological investigations were carried out on four west-east profils at the East Greenland continental margin between 68° and 75°. The sediment cores represent distinct flacial/interglacial palaeoclimatic episodes over the past 190 ka. Based on oxygen isotope stratigraphy and AMS 14C dating, our data can be well correlated with the global climate record. However, there are some excursions from the global climate curve suggesting a local/regional overprint by meltwater events of the Greenland Ice Sheet, especially at the beginning of isotope stage 3 and during Termination I. Distinct high-amplitude variations in supply of ice-rafted debris (IRD) indicate repeated advances and retreats of the Greenland Ice Sheet, causing fluctiations in the massive production and transport of icebergs into the Greenland Sea. During the last 190 ka, a number of IRD peaks appear to be correlated with cooling cycles observed in the GRIP Greenland Ice Core. Drastic events in iceberg discharge along the East Greenland continental margin recurred at very short intervals of 100-300 years (i.e. much more frequently than the about 10 000 years associated with Heinrich events), suggesting short-term collapses of the Greenland Ice Sheet on these time-scales. These late Weichselian Greenland Ice Sheet oscillations appear to be in phase with those in the Barents Sea area. Maximum flux rates of terrigenous (ice-rafted) material were recorded at the continental slope between about 21 and 16 ka, which may correspond to the maximum (stage 2) extension of glaciers on Greenland. The beginning ot Termination I is documented by a distinct shift in the oxygen isotopes and a most prominent decrease in flux of IRD at the continental slope caused by the retreat of continental ice masses.

Description: Samples of Quaternary through Miocene diatomaceous sediment and siliceous sedimentary rock from the Japan Sea (ODP Leg 128, Site 799) were examined to determine the origin of bitumen encountered during drilling, whether previously published studies using Rock-Eval pyrolysis have accurately assessed organic matter type and maturity, and if evidence exists to postulate the presence of a Kuroko-type massive sulfide deposit at depth or along depositional strike. Whole-rock total organic carbon:total nitrogen ratios have values ranging from 31 to 4. Elemental atomic H:C and O:C kerogen ratios decrease from ca 1.3 and 0.3, respectively, in Quaternary and Pliocene samples to 1.2 and 0.1, respectively, in samples obtained from the bottom of the hole. The bitumen ratio of these rocks increases from 50 mg bitumen/g OC at 700 mbsf to 150 mg bitumen/g at 1000 mbsf. The kerogen in these samples comprises a mixture of marine and terrigenous organic material that reaches the earliest stages of catagenesis in the bottom part of this hole. The bitumen is dominated by asphaltenes, resins and polar components. Because these compounds have very high boiling points, Rock-Eval pyrolysis does not assess the thermal maturity, or organic matter type accurately in the early stages of catagenesis. The bitumens have a very low thermal maturity and the observed degree of thermal alteration is consistent with the modern geothermal gradient in the Kita-Yamato trough.