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  • 1
    Publication Date: 2021-11-01
    Description: Fluid-rock interaction has profound effects on the dynamics of the lithosphere. This Perspectives article describes the catalytic effects of water on the kinetics of mineral reactions and on the strength of rocks in terms of coupled dissolution and precipitation mechanisms on a macro- and nano-scale. The length scale of coupling between the dissolution and precipitation steps depends on the fluid composition at the mineral-fluid interface and also on differential stress. Stress-induced mass transport, dependent on the generation of porosity by mineral reactions, results in dissolution-precipitation creep as the principal mechanism of rock deformation in the lithosphere. The heterogeneous distribution of fluid infiltration into dry, strong rocks in the deep crust leads to weak rocks within strong, stressed host rock and the possibility of significant local variations in pressure. Fluid-rock interaction mechanisms are discussed in terms of recrystallisation reactions whereby mass transport and the most favourable nucleation sites determine the distribution and texture of the resultant assemblages. Metamorphic differentiation is a natural consequence of dissolution-precipitation mechanisms under deviatoric stress and similar mechanisms may apply to general pattern formation in rocks.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 2
    Publication Date: 2021-10-27
    Description: The origin of the eclogites that reside in cratonic mantle roots has long been debated. In the classic Roberts Victor kimberlite locality in South Africa, the strongly contrasting textural and geochemical features of two types of eclogites have led to different genetic models. We studied a new suite of 63 eclogite xenoliths from the former Roberts Victor Mine. In addition to major- and trace-element compositions for all new samples, we determined 18O/16O for garnet from 34 eclogites. Based on geochemical and textural characteristics we identify a large suite of Type I eclogites (n = 53) consistent with previous interpretations that these rocks originate from metamorphosed basaltic-picritic lavas or gabbroic cumulates from oceanic crust, crystallised from melts of depleted MORB mantle. We identify a smaller set of Type II eclogites (n = 10) based on geochemical and textural similarity to eclogites in published literature. We infer their range to very low δ18O values combined with their varied, often very low Zr/Hf ratios and LREE-depleted nature to indicate a protolith origin via low-pressure clinopyroxene-bearing oceanic cumulates formed from melts that were more depleted in incompatible elements than N-MORB. These compositions are indicative of derivation from a residual mantle source that experienced preferential extraction of incompatible elements and fractionation of Zr-Hf during previous melting.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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