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  • Inorganic Chemistry  (83,671)
  • Organic Chemistry  (68,964)
  • GEOPHYSICS  (21,936)
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  • 1
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    Frontiers in Chemistry: Rising Stars (2021)
    Frontiers Media SA
    Details
    Publication Date: 2024-04-04
    Description: The Frontiers in Chemistry Editorial Office team are delighted to present the inaugural “Frontiers in Chemistry: Rising Stars” article collection, showcasing the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers featured within this collection were individually nominated by the Journal’s Chief Editors in recognition of their potential to influence the future directions in their respective fields. The work presented here highlights the diversity of research performed across the entire breadth of the chemical sciences, and presents advances in theory, experiment and methodology with applications to compelling problems. This Editorial features the corresponding author(s) of each paper published within this important collection, ordered by section alphabetically, highlighting them as the great researchers of the future. The Frontiers in Chemistry Editorial Office team would like to thank each researcher who contributed their work to this collection. We would also like to personally thank our Chief Editors for their exemplary leadership of this article collection; their strong support and passion for this important, community-driven collection has ensured its success and global impact.
    Keywords: Green and Sustainable Chemistry ; Analytical Chemistry ; Theoretical and Computational Chemistry ; Polymer Chemistry ; Medicinal and Pharmaceutical Chemistry ; Organic Chemistry ; Nanoscience ; Catalysis and Photocatalysis ; Supramolecular Chemistry ; Electrochemistry ; Inorganic Chemistry ; Chemical Biology ; thema EDItEUR::P Mathematics and Science::PD Science: general issues
    Language: English
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    E-BOOK
  • 2
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    [Editors' Choice] Carboxylating stubborn alkyl chlorides (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-07-08
    Description: Author: Phil Szuromi
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    [This Week in Science] Olefins enlisted to attack ketones (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-07-08
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
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    [This Week in Science] A radical route to ophiobolin rings (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-05-27
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
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    [This Week in Science] A light approach to C-N bond formation (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-07-15
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
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    [Editors' Choice] Iron takes alcohols to carboxylic acids (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-07-22
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    [This Week in Science] Catalysis gets all tied up in knots (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-06-24
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
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    [This Week in Science] Adding two fluorines to just one carbon (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-07-01
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 9
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    [Perspective] Three catalysts for activating carbon-hydrogen bonds (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-06-10
    Description: Transition metal–catalyzed arylation of C–H bonds has been intensively studied for forming C–C bonds in complex-molecule synthesis (1). An acidic C–H bond (for example, one near a double bond or an O atom) is cleaved to form a carbon–metal bond, which then couples to arene. Many of these organometallic species can be generated catalytically. Much less research has dealt with unreactive nonacidic sp3 C–H bond functionalization (3). On page 1304 of this issue, Shaw et al. (3) report an efficient and general method that focuses on arylation of sp3 C–H bonds at carbon atoms adjacent to amines and to cyclic ethers by combining nickel, visible-light photoredox, and hydrogen-atom transfer (HAT) catalysis. Author: Corinne Fruit
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
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    [This Week in Science] A tip of the HAT to C-C bond formation (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-06-10
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 11
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    [This Week in Science] A rhodium route from C-H to C-N bonds (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-09
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 12
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    [This Week in Science] Copper-catalyzed radical relay (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-07
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 13
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    [In Depth] A modular route to new antibiotics (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-05-20
    Description: Antibiotics have been taking it on the chin lately. Not only has resistance to the anti-infective medications been growing, but drug companies have been dropping antibiotic research programs, because the drugs are difficult and expensive to make. Now, new help is on the way. Researchers report this week that they've found a way to churn out new members of one of the most widely used classes of antibiotics. These drugs, called macrolides, were first developed in the 1950s and now represent a major bulwark against infections. A bevy of possible new drugs in this class could lead to new weapons against antibiotic-resistant infections, and possibly save millions of lives. Author: Robert F. Service
    Keywords: Organic Chemistry
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  • 14
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    [This Week in Science] Copper adds alkyls asymmetrically (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-04-22
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 15
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    [This Week in Science] EZ catalyst control in olefin metathesis (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-04-29
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 16
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    [This Week in Science] Carbon links without helpful neighbors (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-05-13
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 17
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    [Perspective] Rethinking the SN2 reaction (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-04-01
    Description: The SN2 nucleophilic substitution reaction, X− + RY → XR + Y−, is a paradigm reaction in organic chemistry (1). The modern understanding of the SN2 reaction mechanism is based on work of Hughes and Ingold (2), who proposed that the nucleophile (X−) approaches the carbon atom that bears the leaving group (Y−). As a result, the bond between the carbon atom and the leaving group becomes weakened. As this bond breaks and a new bond forms between the nucleophile and the carbon atom, the configuration of the carbon atom is inverted. Analyses of gas-phase reaction rates led to the suggestion of a potential energy surface (PES) with two wells connected by a central barrier transition state (3). Electronic structure calculations have confirmed this picture for some SN2 reactions (4), but recent studies have shown that the actual reaction dynamics may be considerably more complex (see the figure) (5–8). Authors: Jing Xie, William L. Hase
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
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  • 18
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    [This Week in Science] Beyond textbook SN2 chemistry (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-04-01
    Description: Author: Julia Fahrenkamp-Uppenbrink
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 19
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    [This Week in Science] CO takes the lead to make β-lactam rings (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-18
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 20
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    [This Week in Science] Pluses and minuses of BTX behavior (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-18
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 21
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    [Editors' Choice] Lighting the way to fluorine placement (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-03-03
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 22
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    [Editors' Choice] A pair of tablemates for aromatic benzene (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-09
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 23
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    [This Week in Science] Catching a break in polyphenol synthesis (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-12-09
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 24
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    [This Week in Science] How to turn olefins into nucleophiles (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-10-21
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 25
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    [Editors' Choice] Fluorine frolicking with eight friends (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-02-10
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 26
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    [This Week in Science] Stitching a belt out of carbon rings (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-04-14
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 27
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    [Perspective] Allotropy by design—Carbon nanohoops (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-04-14
    Description: The allotropes formed by carbon reflect differences in its bonding: single bonds in diamond, double bonds in graphite and graphene, and triple bonds in polyynes. Fashioning graphene sheets into bowls, monkey saddles, balls, and tubes has led to a number of molecular allotropes of carbon or carbon-rich quasi-allotropes with novel topologies and shapes. A simple ring of carbon can be reduced to practice in various forms (1): a cyclic array of carbon atoms, a “pearl necklace” of benzene rings, or a cylindrical hoop of flank-fused benzenes, just to name a few. On page 172 of this issue, Povie et al. (2) report on the synthesis of an angular-fused hoop structure, which has been a long-standing target. Author: Jay S. Siegel
    Keywords: Organic Chemistry
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  • 28
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    [This Week in Science] Stitching one alkyl group to another (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-04-14
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 29
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    [This Week in Science] Coordinated scission of N–H or O–H bonds (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-11
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 30
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    [This Week in Science] A salty route to an all-nitrogen ring (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-01-27
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 31
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    [This Week in Science] Boron choreographs a double reaction (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
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    Publication Date: 2017-03-03
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 32
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    [This Week in Science] Turning benzene into a C–H bond cleaver (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
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    Publication Date: 2017-04-01
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 33
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    [Perspective] Polynitrogen chemistry enters the ring (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-01-27
    Description: Polynitrogens have the potential for ultrahigh-performing explosives or propellants because singly or doubly bonded polynitrogens can decompose to triply bonded dinitrogen (N2) with an extraordinarily large energy release. The large energy content and relatively low activation energy toward decomposition makes the synthesis of a stable polynitrogen allotrope an extraordinary challenge. Many elements exist in different forms (allotropes)—for example, carbon can exist as graphite, diamond, buckyballs, or graphene. However, no stable neutral allotropes are known for nitrogen, and only two stable homonuclear polynitrogen ions had been isolated until now—namely, the N3− anion (1) and the N5+ cation (2). On page 374 of this issue, Zhang et al. (3) report the synthesis and characterization of the first stable salt of the cyclo-N5− anion, only the third stable homonuclear polynitrogen ion ever isolated. Author: Karl O. Christe
    Keywords: Inorganic Chemistry
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  • 34
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    [This Week in Science] A cyclic catalyst to pair up sugars (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
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    Publication Date: 2017-01-13
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 35
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    Evaluation of thermal radiation at high temperatures (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Emittance measuring apparatus for temperatures up to 4000-deg f
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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    NASA TECHNICAL REPORTS
  • 36
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    A very rapid 3000 deg f technique for measuring emittance of opaque solid materials (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Total normal emittance measurement technique for opaque solid materials over 1000- to 3000-deg f range
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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    NASA TECHNICAL REPORTS
  • 37
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    Pitfalls in thermal emission studies (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Pitfalls in thermal emission studies - terminology, experimental procedure, and physical standards
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
    Format: text
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  • 38
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    Periodic heat flow in a hollow cylinder rotating in a furnace with a viewing port (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Rotating-specimen furnace for use in determining spectral & total emittance of materials from measurement of radiant flux from specimen surface
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 39
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    The total hemispherical emittance of platinum, columbium-1 percent zirconium, and polished and oxidized inor-8 in the range 100 deg to 1200 deg c (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Temperature dependence of hemispherical emittance of metal and alloy strips in 100- to 1200-deg c range using blackbody vacuum chamber
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 40
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    Measurement of spectral normal emittance of materials under simulated spacecraft powerplant operating conditions (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Spectral normal emittance of materials under simulated space environment
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 41
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    Heated cavity reflectometer modifications (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Heated cavity reflectometer for thermal reflectance measurements of opaque surface
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 42
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    Inspection tool for measurement of the radiation properties of satellite temperature control surfaces (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Apparatus for measuring emittance and absorptivity of satellite temperature control surfaces
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 43
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    An apparatus for measuring total hemispherical emittance between ambient and liquid nitrogen temperatures (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Apparatus for measuring hemispherical emittance of solids in ambient & liquid nitrogen temperature range, with copper & aluminum foil data
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 44
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    Thermocouple and radiation thermometry above 900 deg k (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Thermocouple and radiation thermometry above 900 deg k
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 45
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    Measurement of total hemispherical emittance of structural materials and coatings under simulated spacecraft conditions (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Hemispherical emittance of structural materials & coatings under simulated spacecraft conditions over wide temperature range
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 46
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    The measurement of total normal emittance of three nuclear reactor materials (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Measurement of total normal emittance of nuclear reactor materials - carbon steel, boron steel, & borated graphite
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 47
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    Radiative property measurements of thermal control coatings for spacecraft (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Solar absorptance, emittance, & transmittance of thermal control coating for spacecraft
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 48
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    Spectral emittance measurements from 40 deg c to 200 deg c (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Spectral emittance of opaque and transparent materials from 40- to 200-deg c
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 49
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    Hemispheric spectral reflectance of solids (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Hemispheric spectral reflectance of opaque solids
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 50
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    Calorimetric determination of infrared emittance and the absorptance/emission ratio (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Calorimetric device for determination of solar absorption & infrared emittance ratio of materials at room temperature
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 51
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    Thermal radiation properties of solids at low temperatures (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: Thermal radiation properties of solids at cryogenic temperatures
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 52
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    Temperature measurements below 1000 deg k 〈an abstract〈 (1963)
    In:  CASI
    Details
    Publication Date: 2009-12-28
    Description: International practical temperature scale for temperature measurements below 1000-deg k using platinum resistance thermometers
    Keywords: GEOPHYSICS
    Type: Measurement of Thermal Radiation Properties of Solids; NASA-SP-31
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  • 53
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    Global and local current sheet thickness estimates during the late growth phase (1992)
    In:  CASI
    Details
    Publication Date: 2004-12-03
    Description: The thinning and intensification of the cross tail current sheet during the substorm growth phase are analyzed during the CDAW 6 substorm (22 Mar. 1979) using two complementary methods. The magnetic field and current sheet development are determined using data from two spacecraft and a global magnetic field model with several free parameters. These results are compared with the local calculation of the current sheet location and structure previously done by McPherron et al. Both methods lead to the conclusion that an extremely thin current sheet existed prior to the substorm onset, and the thicknesses estimated by the two methods at substorm onset agree relatively well. The plasma data from the ISEE 1 spacecraft at 13 R(sub E) show an anisotropy in the low energy electrons during the growth phase which disappears just before the substorm onset. The global magnetic model results suggest that the field is sufficiently stretched to scatter such low energy electrons. The strong stretching may improve the conditions for the growth of the ion tearing instability in the near Earth tail at substorm onset.
    Keywords: GEOPHYSICS
    Type: ESA, Substorms 1; p 131-135
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  • 54
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    Magnetic cloud passage at Earth and associated substorm activity (1992)
    In:  CASI
    Details
    Publication Date: 2004-12-03
    Description: An approach to the study of the solar wind-magnetosphere interaction by signal type, that is, by examining the effect in the magnetosphere of well defined interplanetary structures, is presented. Focus is on the response of the magnetosphere to interplanetary magnetic clouds. Among their properties are: the slow and smooth variation of the magnetic field vector, with fluctuation level well below common interplanetary values; the similarly well behaved bulk flow; the wide range of field and flow parameters; and the longevity of passage (1 to 2 days). If the magnetic cloud is oriented such that a long period of uninterruptedly northward pointing field is followed by a long interval of continuously southward pointing field, then the transition of the magnetosphere from a quiescent state (the 'ground state') to a very active state can be studied, the latter being sustained by continued forcing from the magnetic cloud. A synopsis of the main findings of a recent study in such an interaction is given, concentrating on the substorm activity attending the second part of cloud passage.
    Keywords: GEOPHYSICS
    Type: ESA, Substorms 1; p 371-376
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  • 55
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    Magnetotail instability (1992)
    In:  CASI
    Details
    Publication Date: 2004-12-03
    Description: The stability of the geomagnetic tail is investigated on the basis of three dimensional resistive magnetohydrodynamic simulations, using different dynamic constraints and different initial equilibria. Different forms of the energy equation for isotropic pressure are found to have no significant effect on the dynamic growth of a resistive tearing instability, which is responsible for near Earth reconnection, plasmoid formation and ejection, and the generation of fast plasma flows. The constraints of a modified double adiabatic approach, however, can quench the tearing instability through the development of large, mirror type, anisotropies in the boundary regions of the plasma sheet, unless isotropization occurs on fast, nearly Alfvenic, time scales. The presence of a net cross tail magnetic field component B(sub yN) can reduce the growth of the instability without complete stabilization. An increase of B(sub z) from midnight toward the tail flanks, however, by more than a factor of about 3, apparently completely stabilizes the tearing mode. Stabilization and destabilization thus may depend on properties and constraints (and their release) in regions other than the neutral sheet where reconnection is initiated.
    Keywords: GEOPHYSICS
    Type: ESA, Substorms 1; p 225-230
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  • 56
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    Driven and unloading aspects of magnetospheric substorms (1992)
    In:  CASI
    Details
    Publication Date: 2004-12-03
    Description: Issues concerning the 'driven' versus 'unloading' nature of substorms are presented. The original concepts attendant to this debate are presented and substorms are concluded to inextricably combine aspects that are driven with aspects that represent a loading-unloading system. For isolated substorms, the magnetosphere-ionosphere system is shown to exhibit a bimodal response to solar wind changes. A 20 min response characteristic is associated with the driven aspect of substorms, while a 1 hr response time is associated with unloading. It is found that for strong solar wind input conditions, the magnetospheric response becomes more nearly unimodal. This is interpreted in terms of a nonlinear dynamical evolution of the system. Simple analog models are described which capture the essence of the nonlinear magnetospheric behavior. These models exhibit chaotic transitions for strong driving conditions: this may explain the observed behavior of the magnetosphere during strong geomagnetic activity.
    Keywords: GEOPHYSICS
    Type: ESA, Substorms 1; p 185-191
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  • 57
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    Characteristics of pseudobreakups (1992)
    In:  CASI
    Details
    Publication Date: 2004-12-03
    Description: A pseudobreakup is a phenomenon similar to the substorm expansive phase onset, including an activation of an auroral arc, a burst of Pi2 micropulsations, and enhancement of the westward electrojet. However, these effects are weak and a pseudobreak is generally assumed to be very localized. The pseudobreakups are discussed based on simultaneous observations made in space and on the ground during the substorm growth phase. In the events studied the main features listed above are found, but the significance of the localization is unclear. The optical pseudobreakup, with associated magnetic perturbations, is highly localized, but simultaneously a wide local time sector of the auroral oval may be activated. The major differences between pseudobreakups and substorm expansive phase onsets are concluded to be the intensity and the development that follows. Careful study of pseudobreakups may help to determine phase initiation, and the role of the ionosphere-magnetosphere coupling in the substorm process.
    Keywords: GEOPHYSICS
    Type: ESA, Substorms 1; p 111-116
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  • 58
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    Evolution of the Pinatubo volcanic cloud over Hampton, Virginia (1995)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: The eruption of Mt. Pinatubo in June 1991 produced the largest enhancement of stratospheric aerosol loading ever observed by lidar over Hampton, Virginia. Low altitude layers (less than 20 km) were the first to arrive over Hampton in early August, the result of transport associated with a tropospheric anticyclonic cell over North America. The maximum peak scattering ratio, 34 at 22.4 km, and the maximum stratospheric integrated backscatter of 0.0053 sr(exp -1), both at 694 nm, observed since the eruption were measured on February 20, 1992. After decreasing during the spring and summer of 1992, the aerosol burden increased significantly during the winter of 1992-93, evidence of a poleward winter transport from the equatorial reservoir. Over the period from February 1992 to February 1994, the stratospheric aerosol loading decreased with an average 1/e decay time of 10.1 months. The vertical distribution, intensity, and transport of Pinatubo aerosols over this site are described and compared with similar measurements after El Chichon.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 9; p. 1101-1104
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  • 59
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    Nonsphericity of dust-like tropospheric aerosols: Implications for aerosol remote sensing and climate modeling (1995)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: T-matrix computations of light scattering by polydispersions of randomly oriented nonspherical aerosols and Mie computations for equivalent spheres are compared. Findings show that even moderate nonsphericity results in suubstantial errors in the retrieved aerosol optical thickness if satellite reflectance measurements are analyzed using Mie theory. On the other hand, the use of Mie theory for nonspherical aerosols produces negligible errors in the computation of albedo and flux related quantities, provided that the aerosol size distribution and optical thickness are known beforehand. The first result can be explained by large nonspherical-spherical differences in scattering phase function, while the second result follows from small nonspherical-spherical differences in single-scattering albedo and asymmetry parameter. No cancellation of errors occurs if one consistently uses Mie theory in the retrieval algorithm and then in computing the albedo for the retrieved aerosol optical thickness.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 9; p. 1077-1080
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  • 60
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    Atmospheric gradients from very long baseline interferometry observations (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Azimuthal asymmetries in the atmospheric refractive index can lead to errors in estimated vertical and horizontal station coordinates. Daily average gradient effects can be as large as 50 mm of delay at a 7 deg elevation. To model gradients, the constrained estimation of gradient paramters was added to the standard VLBI solution procedure. Here the analysis of two sets of data is summarized: the set of all geodetic VLBI experiments from 1990-1993 and a series of 12 state-of-the-art R&D experiments run on consecutive days in January 1994. In both cases, when the gradient parameters are estimated, the overall fit of the geodetic solution is improved at greater than the 99% confidence level. Repeatabilities of baseline lengths ranging up to 11,000 km are improved by 1 to 8 mm in a root-sum-square sense. This varies from about 20% to 40% of the total baseline length scatter without gradient modeling for the 1990-1993 series and 40% to 50% for the January series. Gradients estimated independently for each day as a piecewise linear function are mostly continuous from day to day within their formal uncertainties.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 9; p. 1041-1044
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  • 61
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    Observations of Pc5 micropulsation-related electric field oscillations in equatorial ionosphere (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: A 54.95-MHz coherent backscatter radar, an ionosonde and the magnetometer located at Trivandrum in India (8.5 deg N, 77 deg E, 0.5 deg N dip angle) recorded large-amplitude ionospheric fluctuations and magnetic field fluctuations associated with a Pc5 micropulsation event, which occurred during an intense magnetic storm on 24 March 1991 (A(sub p) = 161). Simultaneous 100-n T-level fluctuations are also observed in the H-component at Brorfelde, Denmark (55.6 deg N gm) and at Narsarsuaq, Greenland (70.6 deg N gm). Our study of the above observations shows that the E-W electric field fluctuations in the E- and F-regions and the magnetic field fluctuations at Thumba are dominated by a near-sinusoidal oscillation of 10 min during 1730-1900 IST (1200-1330 UT), the amplitude of the electric field oscillation in the equatorial electrojet (EEJ) is 0.1-0.25 mV/m and it increases with height, while it is about 1.0 mV/m in the F-region, the ground-level H-component oscillation can be accounted for by the ionospheric current oscillation generated by the observed electric field oscillation in the EEJ and the H-component oscillations at Trivandrum and Brofelde are in phase with each other. The observations are interpreted in terms of a compressional cavity mode resonance in the inner magnetosphere and the assoicated ionospheric electric field penetrating from high latitudes to the magnetic equator.
    Keywords: GEOPHYSICS
    Type: Annales Geophysicae (ISSN 0992-7689); 12; 6; p. 565-573
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  • 62
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    Centrifugal trapping in the magnetotail (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Particles leving the neutral sheet in the distant magnetotail at times display adiabatic trajectory sequences characterized by an inflection toward the equator and subsequent mirroring in its vicinity. We demonstrate that this low-latitude mirroring results primarily from a centrifugal deceleration due to the fast direction-changing E x B drift. This effect which we refer to as 'centrifugal trapping' appears both in guiding centre and full particle treatments. It thus does not directly relate to nonadiabatic motion. However, pitch angle scattering due to nonadiabatic neutral sheet interaction does play a role in reducing the parallel speed of the particles. We show that centrifugal trapping is an important mechanism for the confinement of the slowest (typically below the equatorial E x B drift speed) plasma sheet populations to the midplane vicinity.
    Keywords: GEOPHYSICS
    Type: Annales Geophysicae (ISSN 0992-7689); 13; 3; p. 242-246
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  • 63
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    Topographic form of the Coast Ranges of the Cascadia Margin in relation ot coastal uplift rates and plate subduction (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The Coast Ranges of the Cascadia margin are overriding the subducted Juan de Fuca/Gorda plate. We investigate the extent to which the latitudinal change in attributes related to the subduction process. These attributes include the varibale age of the subducted slab that underlies the Coast Ranges and average vertical crustal velocities of the western margin of the Coast Rnages for two markedly different time periods, the last 45 years and the last 100 kyr. These vertical crustal velocities are computed from the resurveying of highway bech marks and from the present elevation of shore platforms that have been uplifted in the late Quaternary, respectively. Topogarphy of the Coast Ranges is in part a function of the age and bouyancy of the underlying subducted plate. This is evident in the fact that the two highest topographic elements of the Coast Rnages, the Klamath Mountains and the Olympic Mountains, are underlain by youngest subducted oceanic crust. The subducted Blanco Fracture Zone in southernmost Oregon is responsible for an age discontinuity of subducted crust under the Klamath Mountains. The norhtern terminus of hte topographically higher Klamaths is offset to the north relative to the position of the underlying Blanco Fracture Zone, teh offset being in the direction of migration of the farcture zone, as dictated by relative plate motions. Vertical crustal velocities at the coast, derived from becnh mark surveys, are as much as an order of magnitude greater than vertical crustal velocities derived from uplifted shore platforms. This uplift rate discrepancy indicates that strain is accumulating on the plate margin, to be released during the next interplate earthquake. In a latitudinal sense, average Coast Rnage topography is relatively high where bench mark-derived, short-term vertical crustal velocities are highest. Becuase the shore platform vertical crustal velocities reflect longer-term, premanent uplift, we infer that a small percentage of the interseismic strain that accumulates as rapid short-term uplift is not recovered by subduction earthquakes but rather contributes to rock uplift of the Coast Ranges. The conjecture that permanent rock uplift is related to interseismic uplift is consistent with the observation that those segments of the subduction zone subject to greater interseismic uplift rates are at approximately the same latitudes as those segments of the Coast Ranges that have higher magnitudes of rock uplift over the long term.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; B6; p. 12,245-12,255
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    The art of mapping the magnetosphere (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: A comprehensive review is presented of the mathematical models used to represent magnetic fields in the Earth's magnetosphere, of the way existing data-based models use these methods and of the associated problems and concepts. The magnetic field has five main components: the internal field, the magnetopause, the ring current, the tail and Birkeland currents. Methods of representing separately each of these are discussed, as is the deformation of magnetic fields; Appendix B traces the connection between deformations and the Cauchy integral. A summary section lists the uses of data-based models and their likely future evolution, and Appendix A supplements the text with a set of problems.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; A9; p. 17,169-17,198
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  • 65
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    On the derivation of coseismic displacement fields using differential radar interferometry: The Landers earthquake (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: We present a map of the coseimic displacement field resulting from the Landers, California, June 28, 1992, earthquake derived using data acquired from an orbiting high-resolution radar system. We achieve results more accurate than previous space studies and similar in accuracy to those obtained by conventional field survey techniques. Data from the ERS 1 synthetic aperture radar instrument acquired in April, July, and August 1992 are used to generate a high-resolution, wide area map of the displacements. The data represent the motion in the direction of the radar line of sight to centimeter level precision of each 30-m resolution element in a 113 km by 90 km image. Our coseismic displacement contour map gives a lobed pattern consistent with theoretical models of the displacement field from the earthquake. Fine structure observed as displacement tiling in regions several kilometers from the fault appears to be the result of local surface fracturing. Comparison of these data with Global Positioning System and electronic distance measurement survey data yield a correlation of 0.96; thus the radar measurements are a means to extend the point measurements acquired by traditional techniques to an area map format. The technique we use is (1) more automatic, (2) more precise, and (3) better validated than previous similar applications of differential radar interferometry. Since we require only remotely sensed satellite data with no additioanl requirements for ancillary information. the technique is well suited for global seismic monitoring and analysis.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; B10; p. 19,617-19,635
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    Birkeland currents in the plasma sheet (1993)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: A search was conducted for the signatures of Birkeland currents in the Earth's magnetic tail, using observed values of B(sub x) and B(sub y) from large sets of spacecraft data. The data were binned by x and y for -10 greater than x(sub GSM) greater than -35 and absolute value of y(sub GSM) less than or equal to 20 R(sub E) (less than or equal to 30 R(sub E) for x(sub GSM) less than or equal to -25 R(sub E)) and in each bin their distribution in the (B(sub x), B(sub y)) plane was fitted by least squares to a piecewise linear function. That gave average x-y distributions of the flaring angle between B(sub xy) and the x direction, as well as that angle's variation across the thickness of the plasma sheet. Angles obtained in the central plasma sheet differed from those derived near the lobe boundary. That is the expected signature if earthward or tailward Birkeland current sheets are embedded in the plasma sheet, and from this dfiference we derived the dawn-dusk profiles of the tail Birkeland currents for several x(sub GSM) intervals. It was found that (1) the Birkeland currents have the sense of region 1 currents, when mapped to the ionosphere; (2) both the linear current density (kiloamperes/R(sub E)) and the net magnitude of the field-aligned currents decrease rapidly down the tail; (3) the total Birkeland current at x approximately equals -10 R(sub E) equals approximately equals 500-700 kA, which is approx. 30% of the net region 1 current observed at ionospheric altitudes, in agreement with model mapping results; and (4) the B(sub z) and B(sub y) components of the interplanetary magnetic field influence the distribution of Birkeland currents in the tail.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 98; A11; p. 19,455-19,464
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    Three-dimensional magnetic reconnection and the magnetic topology of coronal mass ejection events (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Measurements of superthermal electron fluxes in the solar wind indicate that field lines within coronal mass ejections, CMEs, near and beyond 1 AU are normally connected to the Sun at both ends. However, on occasion some field lines embedded deep within CMEs appear to be connected to the Sun at only one end. Here we propose an explanation for how such field lines arise in terms of 3-dimensional reconnection close to the Sun. Such reconnection also provides a natural explanation for the flux rope topology characteristic of many CMEs as well as the coronal loops formed during long-duration, solar X-ray events. Our consideration of the field topologies resulting from 3-dimensional reconnection indicates that field lines within and near CMEs may on occasion be connected to the outer heliosphere at both ends.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 8; p. 869-872
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    The efficiency of 'viscous interaction' between the solar wind and the magnetosphere during intense northward IMF events (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: We examined 11 cases when the interplanetary magnetic field (IMF) was intensely northward (greater than 10 nT) for long durations of time (greater than 3 hours), to quantitatively determine an uppler limit on the efficiency of solar wind energy injection into the magnetosphere. We have specifically selected these large B(sub N) events to minimize the effects of magnetic reconnection. Many of these cases occurred during intervals of high-speed streams associated with coronal mass ejections when viscous interaction effects might be at a maximum. It is found that the typical efficiency of solar wind energy injection into the magnetosphere is 1.0 x 10(exp -3) to 4.0 x 10(exp -3), 100 to 30 times less efficient than during periods of intense southward IMFs. Other energy sinks not included in these numbers are discussed. Estimates of their magnitudes are provided.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 6; p. 663-666
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    High resolution studies of heacy NO(y) molecules in atmospheric spectra (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: New line parameters for two heavy odd nitrogen molecules HNO3 in the nu(sub 5)/2nu(sub 9) region, and ClONO2 in the nu(sub 4) region are incorporated in the analysis of high resolution i.r. atmospheric spectra. The line parameters are tested and renormalized vs laboratory spectra, and then applied to retrievals from balloon-borne and ground-based solar absorption spectra.
    Keywords: GEOPHYSICS
    Type: Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073); 52; 3-4; p. 367-377
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    The Earth's magnetosphere is 165 R(sub E) long: Self-consistent currents, convection, magnetospheric structure, and processes for northward interplanetary magnetic field (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The subject of this paper is a self-consistent, magnetohydrodynamic numerical realization for the Earth's magnetosphere which is in a quasi-steady dynamic equilibrium for a due northward interplanetary magnetic field (IMF). Although a few hours of steady northward IMF are required for this asymptotic state to be set up, it should still be of considerable theoretical interest because it constitutes a 'ground state' for the solar wind-magnetosphere interaction. Moreover, particular features of this ground state magnetosphere should be observable even under less extreme solar wind conditions. Certain characteristics of this magnetosphere, namely, NBZ Birkeland currents, four-cell ionospheric convection, a relatively weak cross-polar potential, and a prominent flow boundary layer, are widely expected. Other characteristics, such as no open tail lobes, no Earth-connected magnetic flux beyond 155 R(sub E) downstream, magnetic merging in a closed topology at the cusps, and a 'tadpole' shaped magnetospheric boundary, might not be expected. In this paper, we will present the evidence for this unusual but interesting magnetospheric equilibrium. We will also discuss our present understanding of this singular state.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A3; p. 3623-3635
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    Localized tearing modes in the magnetotail driven by curvature effects (1995)
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    Publication Date: 2011-08-24
    Description: The stability of collisionless tearing modes is examined in the presence of curvature drift resonances and the trapped particle effects. A kinetic description for both electrons and ions is employed to investigate the stability of a two-dimensional equilibrium model. The main features of the study are to treat the ion dynamics properly by incorporating effects associated with particle trajectories in the tail fields and to include the linear coupling of trapped particle modes. Generalized dispersion relations are derived in several parameter regimes by considering two important sublayers of the reconnecting region. For a typical choice of parameters appropriate to the current sheet region, we demonstrate that localized tearing modes driven by ion curvature drift resonance effects are excited in the current sheet region with growth time of the order of a few seconds. Also, we examine nonlocal characteristics of tearing modes driven by curvature effects and show that modes growing in a fraction of a second arise when mode widths are larger than the current sheet width. Further, we show that trapped particle effects, in an interesting frequency regime, significantly enhance the growth rate of the tearing mode. The relevance of this theory for substorm onset phase and other features of the substorms is briefly discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A3; p. 3563-3572
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  • 72
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    Identification of the HNO3 3 nu(sub 9) - nu(sub 9) band Q branch in stratospheric solar occultation spectra (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The spectroscopic identification for the HNO3 3 nu(sub 9) - nu(sub 9) band Q branch at 830.4/cm is reported based on 0.01/cm resolution solar occultation spectra of the lower stratosphere recorded by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier transform spectrometer and a recent analysis of this band. Least-squares fits to 0.0025/cm resolution laboratory spectra in the Q branch region indicate an integrated intensity of 0.529 x 10(exp -18)/cm/mol/sq cm at 296 K for this weak band. Stratospheric HNO3 retrievals derived from the ATMOS data are consistent with this value within its estimated uncertainty of about +/- 30%. A set of spectroscopic line parameters suitable for atmospheric studies has been generated.
    Keywords: GEOPHYSICS
    Type: Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073); 52; 3-4; p. 319-322
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  • 73
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    Infrared spectroscopic measurements of the ethane (C2H6) total column abundance above Mauna Loa, Hawaii -- seasonal variations (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: About 200 i.r. solar spectra recorded at 0.01/cm resolution on 71 days between November 1991 and July 1993 at the Network for the Detection of Stratospheric Change (NDSC) station at Mauna Loa, Hawaii (latitude 19.53 deg N, longitude 155.58 deg W, elevation 3.459 km) have been analyzed with a nonlinear least-squares spectral fitting technique to study temporal variations in the total column of atmospheric ethane (C2H6) above the site. The results were derived from the analysis of the unresolved nu(sub 7) band (P)Q(sub 3) subbranch at 2976.8/cm. A distinct seasonal cycle is observed with a factor of 2 variation, a maximum total column of 1.16 x 10(exp 16) mol/sq cm at the end of winter, and a minimum total column of 0.53 x 10(exp 16) mol/sq cm at the end of summer. Our measurements are compared with previous observations and model predictions.
    Keywords: GEOPHYSICS
    Type: Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073); 52; 3-4; p. 273-279
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    Mid-infrared extinction by sulfate aerosols from the Mt. Pinatubo eruption (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Quantitative measurements of the wavelength dependence of aerosol extinction in the 750-3400/cm spectral region have been derived from 0.01/cm resolution stratospheric solar occultation spectra recorded by the ATMOS (Atmospheric Trace Molecule Spectroscopy) Fourier transform spectrometer about 9 1/2 months after the Mt Pinatubo volcanic eruption. Strong, broad aerosol features have been identified near 900, 1060, 1190, 1720, and 2900/cm below a tangent height of approximately 30 km. Aerosol extinction measurements derived from approximately 0.05/cm wide microwindows nearly free of telluric line absorption in the ATMOS spectra are compared with transmission calculations derived from aerosol size distribution profiles retrieved from correlative SAGE (Stratospheric Aerosol and Gas Experiment) II visible and near i.r. extinction measurements, seasonal and zonally averaged H2SO4 aerosol weight percentage profiles, and published sulfuric acid optical constants derived from room temperature laboratory measurements. The calculated shapes and positions of the aerosol features are generally consistent with the observations, thereby confirming that the aerosols are predominantly concentrated H2SO4-H2O droplets, but there are significant differences between the measured and calculated wavelength dependences of the aerosol extinction. We attribute these differences as primarily the result of errors in the calculated low temperature H2SO4-H2O optical constants. Errors in both the published room temperature optical constants and the limitations of the Lorentz-Lorenz relation are likely to be important.
    Keywords: GEOPHYSICS
    Type: Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073); 52; 3-4; p. 241-252
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    Latitude variations of stratospheric trace gases (1994)
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    Publication Date: 2011-08-24
    Description: We present vertical column abundances of H2O, N2O, HNO3, NO2, O3, HF, HCl, and ClNO3, determined from solar absorption spectra measured by the JPL MkIV interferometer from the NASA DC-8 aircraft. These observations, taken in 1987 and 1992, covered latitudes ranging from 85 deg S to 85 deg N. Although most gases display latitude symmetry, large asymmetries in H2O, HNO3, and O3 are apparent, which can be ascribed to processes enhanced by the colder Antarctic winter temperatures.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 21; 23; p. 2599-2602
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    In situ measurements of the NO2/NO ratio for testing atmospheric photochemical models (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Simultaneous in situ measurements of NO2, NO, O3, ClO, pressure and temperature have been made for the first time, presenting a unique opportunity to test our current understanding of the photochemistry of the lower stratospere. Data were collected from several flights of the ER-2 aircraft at mid-latitudes in May 1993 during NASA's Stratospheric Photochemistry, Aerosols and Dynamics Expedition (SPADE). The daytime ratio of NO2/NO remains fairly constant at 19 km with a typical value of 0.68 and standard deviation of +/- 17. The ratio observations are compared with simple steady-state calculations based on laboratory-measured reaction rates and modeled NO2 photolysis rates. At each measurement point the daytime NO2/NO with its measurements uncertainty overlap the results of steady-state caculations and associated uncertainty. Possible sources of error are examined in both model and measurements. It is shown that more accurate laboratory determinations of the NO + 03 reaction rate and of the NO2 cross-sections in the 200-220 K temperature range characteristic of the lower stratosphere would allow for a more robust test of our knowledge of NO(X) phtochemistry by reducing significant sources if uncertainties in the interpretation of statospheric measurements.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 21; 23; p. 2555-2558
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    The short-term prediction of universal time and length of day using atmospheric angular momentum (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The ability to predict short-term variations in the Earth's rotation has gained importance in recent years owing to more precise spacecraft tracking requirements. Universal time (UT1), that component of the Earth's orientation corresponding to the rotation angle, can be measured by number of high-precision space geodetic techniques. A Kalman filter developed at the Jet Propulsion Laboratory (JPL) optimally combines these different data sets and generates a smoothed times series and a set of predictions for UT1, as well as for additional Earth orientation components. These UT1 predictions utilize an empirically derived random walk stochastic model for the length of the day (LOD) and require frequent and up-to-date measurements of either UT1 or LOD to keep errors from quickly accumulating. Recent studies have shown that LOD variations are correlated with changes in the Earth's axial atmospheric angular momentum (AAM) over timescales of several years down to as little as 8 days. AAM estimates and forecasts out to 10 days are routinely available from meteorological analysis centers; these data can supplement geodetic measurements to improve the short-term prediction of LOD and have therefore been incorporated as independent data types in the JPL Kalman filter. We find that AAM and, to a lesser extent, AAM forecast data are extremely helpful in generating accurate near-real-time estimates of UT1 and LOD and in improving short-term predictions of these quantities out to about 10 days.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; B4; p. 6981-6996
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    Analytical models of the magnetic field of disk-shaped current sheets (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Disk-shaped current distributions are useful tools in modeling the magnetospheres of Earth and other planets and have also been adapted for modeling the geotail. Such models usually start with an axisymmetric vector potential but may be modified to account for observed asymmetries, variable thickness, and warping in response to an inclined orientation of the planetary dipole axis. Models of this type until now either have lacked the ability to simulate a sharp inner edge of the current and to control accurately its falloff with distance or did not allow a simple analytical representation. Here existing methods will be reviewed, after which a new class of models which overcomes the above deficiencies and also allows the modeling of current disks of finite thickness flanked by current-free regions will be presented.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; A1; p. 199-205
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    A geopotential model from satellite tracking, altimeter, and surface gravity data: GEM-T3 (1994)
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    Publication Date: 2011-08-24
    Description: An improved model of Earth's gravitational field, Goddard Earth Model T-3 (GEM-T3), has been developed from a combination of satellite tracking, satellite altimeter, and surface gravimetric data. GEM-T3 provides a significant improvement in the modeling of the gravity field at half wavelengths of 400 km and longer. This model, complete to degree and order 50, yields more accurate satellite orbits and an improved geoid representation than previous Goddard Earth Models. GEM-T3 uses altimeter data from GEOS 3 (1975-1976), Seasat (1978) and Geosat (1986-1987). Tracking information used in the solution includes more than 1300 arcs of data encompassing 31 different satellites. The recovery of the long-wavelength components of the solution relies mostly on highly precise satellite laser ranging (SLR) data, but also includes Tracking Network (TRANET) Doppler, optical, and satellite-to-satellite tracking acquired between the ATS 6 and GEOS 3 satellites. The main advances over GEM-T2 (beyond the inclusion of altimeter and surface gravity information which is essential for the resolution of the shorter wavelength geoid) are some improved tracking data analysis approaches and additional SLR data. Although the use of altimeter data has greatly enhanced the modeling of the ocean geoid between 65 deg N and 60 deg S latitudes in GEM-T3, the lack of accurate detailed surface gravimetry leaves poor geoid resolution over many continental regions of great tectonic interest (e.g., Himalayas, Andes). Estimates of polar motion, tracking station coordinates, and long-wavelength ocean tidal terms were also made (accounting for 6330 parameters). GEM-T3 has undergone error calibration using a technique based on subset solutions to produce reliable error estimates. The calibration is based on the condition that the expected mean square deviation of a subset gravity solution from the full set values is predicted by the solutions' error covariances. Data weights are iteratively adjusted until this condition for the error calibration is satisfied. In addition, gravity field tests were performed on strong satellite data sets withheld from the solution (thereby ensuring their independence). In these tests, the performance of the subset models on the withheld observations is compared to error projections based on their calibrated error covariances. These results demonstrate that orbit accuracy projections are reliable for new satellites which were not included in GEM-T3.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; B2; p. 2815-2839
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    Low and middle altitude cusp particle signatures for general magnetopause reconnection rate variations. 1: Theory (1994)
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    Publication Date: 2011-08-24
    Description: We present predictions of the signatures of magnetosheath particle precipitation (in the regions classified as open low-latitude boundary layer, cusp, mantle and polar cap) for periods when the interplanetary magnetic field has a southward component. These are made using the 'pulsating cusp' model of the effects of time-varying magnetic reconnection at the dayside magnetopause. Predictions are made for both low-altitude satellites in the topside ionosphere and for midaltitude spacecraft in the magnetosphere. Low-altitude cusp signatures, which show a continuous ion dispersion signature, reveal 'quasi-steady reconnection' (one limit of the pulsating cusp model), which persists for a period of at least 10 min. We estimate that 'quasi-steady' in this context corresponds to fluctuations in the reconnection rate of a factor of 2 or less. The other limit of the pulsating cusp model explains the instantaneous jumps in the precipitating ion spectrum that have been observed at low altitudes. Such jumps are produced by isolated pulses of reconnection: that is, they are separated by intervals when the reconnection rate is zero. These also generate convecting patches on the magnetopause in which the field lines thread the boundary via a rotational discontinuity separated by more extensive regions of tangential discontinuity. Predictions of the corresponding ion precipitation signatures seen by midaltitude spacecraft are presented. We resolve the apparent contradiction between estimates of the width of the injection region from midaltitude data and the concept of continuous entry of solar wind plasma along open field lines. In addition, we reevaluate the use of pitch angle-energy dispersion to estimate the injection distance.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); p. 8531-8553
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    Multi-wavelength profiles of aerosol backscatter over Lauder, New Zealand, 24 November 1992 (1994)
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    Publication Date: 2011-08-24
    Description: Simultaneous profiles of aerosol backscatter ratio were measured over Lauder, New Zealand (45 deg S, 170 deg E) on the night of November 24, 1992. Instrumentation comprised two complementary lidar systems and a backscattersonde, to give measurements at wavelengths 351, 490, 532, and 940 nm. The data from the lidars and the backscattersonde were self-consistent, enabling the wavelength dependence of aerosol backscatter to be determined as a function of altitude. This wavelength-dependence is a useful parameter in radiative transfer calculations. In the stratosphere, the average wavelength exponent between 351 and 940 nm was -1.23 +/- 0.1, which was in good agreement with values derived from measured physical properties of aerosols.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 21; 9; p. 789-792
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    Relativistic electron acceleration and decay time scales in the inner and outer radiation belts: SAMPEX (1994)
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    Publication Date: 2011-08-24
    Description: High-energy electrons have been measured systematically in a low-altitude (520 x 675 km), nearly polar (inclination = 82 deg) orbit by sensitive instruments onboard the Solar, Anomalous, and Magnetospheric Particle Explorer (SAMPEX). Count rate channels with electron energy thresholds ranging from 0.4 MeV to 3.5 MeV in three different instruments have been used to examine relativistic electron variations as a function of L-shell parameter and time. A long run of essentially continuous data (July 1992 - July 1993) shows substantial acceleration of energetic electrons throughout much of the magnetosphere on rapid time scales. This acceleration appears to be due to solar wind velocity enhancements and is surprisingly large in that the radiation belt 'slot' region often is filled temporarily and electron fluxes are strongly enhanced even at very low L-values (L aprroximately 2). A superposed epoch analysis shows that electron fluxes rise rapidly for 2.5 is approximately less than L is approximately less than 5. These increases occur on a time scale of order 1-2 days and are most abrupt for L-values near 3. The temporal decay rate of the fluxes is dependent on energy and L-value and may be described by J = Ke-t/to with t(sub o) approximately equals 5-10 days. Thus, these results suggest that the Earth's magnetosphere is a cosmic electron accelerator of substantial strength and efficiency.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 21; 6; p. 409-412
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    Energy deposition and middle atmosphere electrodynamic response to a highly relativistic electron precipitation event (1994)
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    Publication Date: 2011-08-24
    Description: Rocket data have been used to evaluate the characteristics of precipitating relativistic electrons and their effects on the electrodynamic structure of the middle atmosphere. These data were obtained at Poker Flat, Alaska, on May 13 and 14, 1990, during a midday, highly relativistic electron (HRE) precipitation event. Solid state detectors were used to measure the electron fluxes and their energy spectra. An X ray scintillator was included on each flight to measure bremsstrahlung X rays produced by energetic electrons impacting on the upper atmosphere. However, these were found the be of negligible importance for this particular event. The energy deposition by the electrons has been determined from the flux measurements and compared with in situ measurements of the atmospheric electrical response. The electrodynamic measurements were obtained by the same rockets and additionally on May 13, with an accompanying rocket. The impact flux was highly irregular, containing short-lived bursts of relativistic electrons, mainly with energies below 0.5 MeV and with fluxes most enhanced between pitch angles of 0 deg - 20 deg. Although the geostationary counterpart of this measured event was considered to be of relatively low intensity and hardness, energy deposition peaked near 75 km with fluxes approaching an ion pair production rate in excess of 100/cu cm s. This exceeds peak fluxes in relativistic electron precipitation (REP) events as observed by us in numerous rocket soundings since 1976. Conductivity measurements from a blunt probe showed that negative electrical conductivities exceeded positive conductivities down to 50 km or lower, consistent with steady ionization by precipitating electrons above 1 MeV. These findings imply that the electrons from the outer radiation zone can modulate the electrical properties of the middle atmosphere to altitudes below 50 km. During the decline and activity minimum of the current solar cycle, we anticipate the occurence of similar events but with fluxes 1-2 orders of magnitude above that reported here, based on studies of earlier solar cycles (e.g., Baker et al., 1993).
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D10; p. 21,071-21,081
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    Evolution of the 1991-1992 Arctic vortex and comparison with the Geophysical Fluid Dynamics Laboratory SKYHI general circulation model (1994)
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    Publication Date: 2011-08-24
    Description: Nitrous oxide (N2O) measured on board the ER-2 aircraft during the Airborne Arctic Stratospheric Expedition 2 (AASE 2) has been used to monitor descent of air inside the Arctic vortex between October 1991 and March 1992. Monthly mean N2O fields are calculated from the flight data and then compared with mean fields calculated from the high-resolution Geophysical Fluid Dynamics Laboratory general circulation model SKYHI in order to evaluate the model's simulation of the polar vortex. From late fall through winter the model vortex evolves in much the same way as the 1991-1992 vortex, with N2O gradients at the edge becoming progressively steeper. The October to March trends in N2O profiles inside the vortex are used to verify daily net heating rates in the vortex that were computed from clear sky radiative heating rates and National Meteorological Center temperature observations. The computed heating rates successfully estimate the descent of vortex air from December through February but suggest that before December, air at high latitudes may not be isolated from the midlatitudes. SKYHI heating rates are in good agreement with the computed rates but tend to be slightly higher (i.e., less cooling) due to meteorological differences between SKYHI and the 1991-1992 winter. Three ER-2 flights measured N2O just north of the subtropical jet. These low-midlatitude profiles show only slight differences from the high-midlatitude profiles (45 deg - 60 deg N), indicating strong meridional mixing in the midlatitude 'surf zone.' Mean midwinter N2O profiles inside and outside the vortex calculated from AASE 2 data are shown to be nearly identical to 1989 AASE profiles, pointing to the N2O/potential temperature relationship as an excellent marker for vortex air.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D10; p. 20,713-20,723
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    The solar cycle variation of ozone in the stratosphere inferred from Nimbus 7 and NOAA 11 satellites (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The combined Nimbus 7 solar backscattered ultraviolet (SBUV) and NOAA 11 SBUV/2 ozone data, covering a period of more than a solar cycle (about 15 years), are used to study the UV response of ozone in the stratosphere. The study shows that about 2% change in total column ozone and about 5-7% change in ozone mixing ratio in the upper stratosphere (0.7 to 2 hPa) may be attributed to the change in the solar UV flux over a solar cycle. In the upper stratosphere, where photochemical processes are expected to play a major role, the measured solar cycle variation of ozone is significantly larger than inferred either from the photochemical models or from the ozone response to the 27-day solar UV modulation. For example, the observed solar cycle related change in ozone mixing ratio at 2 hPa is about 1% for 1% change in the solar UV flux near 200 nm. The inferred change in ozone from either the photochemical models or from the 27-day ozone-UV response is about a factor of 2-3 lower than this value.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D10; p. 20,665-20,671
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    Spread of denitrification from 1987 Antarctic and 1988-1989 Arctic stratospheric vortices (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: Vertical profiles of N2O and NO(y) taken by the ER-2 outside the vortex are used to construct average vertical profiles of F(NO(y)) = NO(y)/(A-N2O), where A is the tropospheric content of N2O three years prior to the measurements. The southern hemisphere had less nitrous oxide in the range 400 less than Theta less than 470 K, by up to 25% relative to the northern hemisphere. F(NO(y)) is the ratio of NOy produced to N2O lost in a stratospheric air mass since entry from the troposphere. The profiles of F(NO(y)) have the following characteristics: (1) Relative to 1991-1992, a year without denitrification inside or outside the vortex, the northern hemisphere in 1988-1989 showed denitrification outside the vortex ranging up to 25% and averaging 17% above Theta = 425 K. (2) Relative to the northern hemisphere in 1991-1992, the southern hemisphere in 1987 showed denitrification outside the vortex ranging up to 32% and averaging 20% above Theta = 400 K. (3) Below Theta = 400 K the southern hemisphere showed enhancements of F(NO(y)) relative to the northern hemisphere in 1991-1992 ranging up to 200% at Theta = 375 K, outside the vortex. Corresponding profiles of residual water, R(H2O) = H2O - 2(1.6 - CH4), are considered and shown to be consistent with those of F(NO(y)) in the sense that they show deficits outside the Antarctic vortex, which was both dehydrated and denitrified, but not outside the 1988-1989 Arctic vortex, which was denitrified but not dehydrated. R(H2O) is the water content of stratospheric air with the contribution from methane oxidation subtracted. Comparison of F(NO(y)) and R(H2O) below 400 K outside the Antarctic vortex leads to the suggetion that dehydration in the Antarctic vortex occurs by the sedimentation of ice crystals large enough to fall out of the stratosphere, whereas denitrification occurs mainly on mixed nitric acid-water crystals which evaporate below the base of the vortex at Theta = 400 K but above the tropopause.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D10; p. 20,573-20,583
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    Limb-darkening models from along-track operation of the ERBE scanning radiometer (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: During January and August 1985, the scanning radiometers of the Earth Radiation Budget Experiment(ERBE) aboard the Earth Radiation Budget Satellite (ERBS) and the NOAA-9 satellite were operated in along-track scanning modes. Along-track scanning permits the study of many measurement problems. It provides the data for developing a limb-darkening model for a single site over a short period of time and also permits the indentification of the scene from data taken at smaller nadir angles. The earth-emitted radiation measured by the scanners has been analyzed to produce limb-darkening models for a variety of scene types. Limb-darkening models relate the radiance in any given direction to the radiant flux. The scene types were computed using measurements within 10 deg of zenith. The models have values near zenith of 1.02-1.09. The typical zenith values of the model are 1.06 for both day and night for ERBS, and for NOAA-9, 1.06 for day and 1.05 for night. Mean models are formed for the ERBS and NOAA-9 results and are found to differ less than 1%, the ERBS results being the higher. The models vary about 1% with latitude near zenith and agree with earlier models that were used to analyze ERBE data typically to 2%.
    Keywords: GEOPHYSICS
    Type: Journal of Applied Meteorology (ISSN 0894-8763); 33; 1; p. 74-84
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  • 88
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    PULSAUR 2: Rocket and groundbased measurements in a pulsating aurora (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The second pulsating aurora rocket (PULSAUR 2) rocket was launched into a pulsating aurora on 9 February 1994 and carried a broad range of instruments in order to perform a study of this type of aurora. The rocket measurements were complemented with a set of ground-based measurements. The particle measurements performed in the rocket are related to the ground-based optical measurements performed along the rocket trajectory. It is found that the high energy electrons are largely in phase with the measured luminosity. The EISCAT measurements carried out during the flight are reviewed. The PULSAUR 2 campaign is described. Results concerning the auroral conditions and the particle measurements are presented.
    Keywords: GEOPHYSICS
    Type: ESA, Proceedings of 12th ESA Symposium on European Rocket and Balloon Programmes and Related Research; p 233-237
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  • 89
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    The causes of geomagnetic storms during solar maximum (1994)
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    Publication Date: 2011-08-24
    Description: One of the oldest mysteries in geomagnetism is the linkage between solar and geomagnetic activity. In investigating the causes of geomagnetic storms occurring during solar maximum, the following topics are discussed: solar phenomena; types of solar wind; magnetic reconnection and magnetic storms; an interplanetary example; and future space physics missions.
    Keywords: GEOPHYSICS
    Type: EOS (ISSN 0096-3941); 75; 5; p. 49, 51-53
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  • 90
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    High-speed correction factor to the O(+)-O resonance charge exchange collision frequency (1995)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The high-speed correction factor to the O(+)-O collision frequency, resulting from drift velocities between ions and neutrals, is calculated by solving the integral expression in this factor both numerically and analytically. Although the analytic solution is valid for either small or large drift velocities between ions and neutrals, for temperatures of interest and all drift velocities considered, agreement is found between analytic and detailed numerical integration results within less than 1% error. Let T(sub r) designate the average of the ion and neutral temperatures in K, and u = nu(sub d)/alpha, where nu(sub d) is the relative drift velocity in cm/s, and alpha = 4.56 x 10(exp 3) square root of T(sub r) cm/s is the thermal velocity of the O(+)-O system. Then, as u ranges from 0 to 2, the correction factor multiplying the collision frequency increases monotonically from 1 to about 1.5. An interesting result emerging from this calculation is that the correction factor for temperatures of aeronomical interest is to a good approximation independent of the temperature, depending only on the scaled velocity u.
    Keywords: GEOPHYSICS
    Type: Annales Geophysicae (ISSN 0992-7689); 13; 3; p. 253-255
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  • 91
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    Atmospheric pressure loading parameters from very long baseline interferometry observations (1994)
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    Publication Date: 2011-08-24
    Description: Atmospheric mass loading produces a primarily vertical displacement of the Earth's crust. This displacement is correlated with surface pressure and is large enough to be detected by very long baseline interferometry (VLBI) measurements. Using the measured surface pressure at VLBI stations, we have estimated the atmospheric loading term for each station location directly from VLBI data acquired from 1979 to 1992. Our estimates of the vertical sensitivity to change in pressure range from 0 to -0.6 mm/mbar depending on the station. These estimates agree with inverted barometer model calculations (Manabe et al., 1991; vanDam and Herring, 1994) of the vertical displacement sensitivity computed by convolving actual pressure distributions with loading Green's functions. The pressure sensitivity tends to be smaller for stations near the coast, which is consistent with the inverted barometer hypothesis. Applying this estimated pressure loading correction in standard VLBI geodetic analysis improves the repeatability of estimated lengths of 25 out of 37 baselines that were measured at least 50 times. In a root-sum-square (rss) sense, the improvement generally increases with baseline length at a rate of about 0.3 to 0.6 ppb depending on whether the baseline stations are close to the coast. For the 5998-km baseline from Westford, Massachusetts, to Wettzell, Germany, the rss improvement is about 3.6 mm out of 11.0 mm. The average rss reduction of the vertical scatter for inland stations ranges from 2.7 to 5.4 mm.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; B9; p. 18,081-18,087
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  • 92
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    Ifluence of crystallization and entrainment of cooler material on the emplacement of basaltic aa lava flows (1994)
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    Publication Date: 2011-08-24
    Description: A theoretical model is used to describe and investigate the effects of simultaneous crystallization, radiation loss, and entrainment of cooler material on the temperature of a well-mixed core of an active aa lava flow. Entrainment of crust, levee debris, and base material into the interior of active flows has been observed, but the degree of assimilation and the thermal consequences are difficult to quantify. The rate of entrainment can be constrained by supplementing the theoretical model with information on the crystallization along the path of the flow and estimation of the radiative loss from the flow interior. Application of the model is demonstrated with the 1984 Mauna Loa flow, which was erupted about 30 C undercooled. Without any entrainment of cooler material, the high crystallization rates would have driven temperatures in the core wall above temperatures measured by thermocouple and estimated from glass geothermometry. One plausible scenario for this flow, which agrees with available temperature and crystallinity measurements, has a high initial rate of entrainment during the first 8 hours of travel (a mass ratio of entrained material to fluid core of about 15% if the average temperature of the entrained material was 600 C), which counterbalances the latent heat from approximately 40% crystallization. In this scenario, the model suggests an additional 5% crystallization and a 5% entrainment mass ratio over the subsequent 16-hour period. Measurements of crystallization, radiative losses, and entrainment factors are necessary for understanding the detailed thermal histories of active lava flows.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; B6; p. 11,819-11,831
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  • 93
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    Excitation of the low lying vibrational levels of H2O by O(3P) as measured on Spacelab 2 (1994)
    In:  Other Sources
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    Publication Date: 2011-08-24
    Description: The data from the infrared telescope (IRT), which was flown on space shuttle Challenger Spacelab 2 mission (July 1985), were originally reported by Koch et al. (1987) as originating from near orbital emissions, primarily H2O. In this study, analysis of this data was extended to determine the collisional cross sections for the excitation of the low lying vibrational levels of H2O, present in the orbiter cloud, by atmospheric O(3P). The evaluation of the contribution to the measured signal from solar excitation and ram O excitation of outgassing H2O permits the determination of the H2O column density and the excitation cross section of the (101) level at an O(3P) velocity of approximately 7.75 km/s. Contributions to the radiation in the 1.7-3.0 micron band by transitions from the (100), (001), and multiquantum excited levels are discussed. The findings of the study are (1) the IRT data for the 4.5-9.5 micron and the nighttime data for the 1.7-3.0 micron sensors are consistent with being explained by collision excitation of H2O by O(3P), (2) diurnal variations of 4.5-9.5 micron intensities follow the model predicted O density for a full orbit, (3) daytime increases in the H2O cloud density were not evident, (4) the cross sections for the collisional excitation process are derived and compared to values computated by Johnson (1986) and Redmon et al. (1986), (5) theoretical investigation suggests greater than 60% of the radiation from H2O is a result of multiphoton emission resulting from collisional multiquanta excitation, and (6) the large daytime increase in the 1.7-3.0 micron intensity data suggests that O(+) may likely be instrumental in producing excited H2O(+) through charge exchange.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; A9; p. 17,559-17,575
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  • 94
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    An efficient algorithm for choosing scattering directions in Monte Carlo work with arbitrary phase functions (1995)
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    Publication Date: 2011-08-24
    Description: This paper describes an efficient Monte Carlo algorithm for choosing a new direction of a photon after a scattering interaction. The algorithm chooses a scattering angle by linear interpolation in a table of the inverse cumulative scattering probability. A Legendre expansion of the phase function makes it easy to apply Clenshaw's algorithm to build the interpolation table. The points in the table are close enough together that linear interpolation is accurate. With a table of 100,000 entries, we can keep the absolute and relative errors in matching the probability distribution below 10(exp -5).
    Keywords: GEOPHYSICS
    Type: Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073); 53; 1; p. 23-38
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  • 95
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    On the uniqueness of linear moving-average filters for the solar wind-auroral geomagnetic activity coupling (1995)
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    Publication Date: 2011-08-24
    Description: The relation between the solar wind input to the magetosphere, VB(sub South), and the auroral geomagnetic index AL is modeled with two linear moving-average filtering methods: linear prediction filters and a driven harmonic oscillator in the form of an electric circuit. Although the response of the three-parameter oscillator is simpler than the filter's, the methods yield similar linear timescales and values of the prediction-observation correlation and the prediction Chi(exp 2). Further the filter responses obtained by the two methods are similar in their long-term features. In these aspects the circuit model is equivalent to linear prediction filtering. This poses the question of uniqueness and proper interpretation of detailed features of the filters such as response peaks. Finally, the variation of timescales and filter responses with the AL activity level is discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A4; p. 5637-5641
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  • 96
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    Modeling the Earth's magnetospheric magnetic field confined within a realistic magnetopause (1995)
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    Publication Date: 2011-08-24
    Description: Empirical data-based models of the magnetosphereic magnetic field have been widely used during recent years. However, the existing models (Tsyganenko, 1987, 1989a) have three serious deficiencies: (1) an unstable de facto magnetopause, (2) a crude parametrization by the K(sub p) index, and (3) inaccuracies in the equatorial magnetotail B(sub z) values. This paper describes a new approach to the problem; the essential new features are (1) a realistic shape and size of the magnetopause, based on fits to a large number of observed crossing (allowing a parametrization by the solar wind pressure), (2) fully controlled shielding of the magnetic field produced by all magnetospheric current systems, (3) new flexible representations for the tail and ring currents, and (4) a new directional criterion for fitting the model field to spacecraft data, providing improved accuracy for field line mapping. Results are presented from initial efforts to create models assembled from these modules and calibrated against spacecraft data sets.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A4; p. 5599-5612
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  • 97
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    The middle atmospheric response to short and long term solar UV variations: analysis of observations and 2D model results (1995)
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    Publication Date: 2011-08-24
    Description: We have investigated the middle atmospheric response to the 27-day and 11-yr solar UV flux variations at low to middle latitudes using a two-dimensional photochemical model. The model reproduced most features of the observed 27-day sensitivity and phase lag of the profile ozone response in the upper stratosphere and lower mesosphere, with a maximum sensitivity of +0.51% per 1% change in 205 nm flux. The model also reproduced the observed transition to a negative phase lag above 2 mb, reflecting the increasing importance with height of the solar modulated HO(x) chemistry on the ozone response above 45 km. The model revealed the general anti-correlation of ozone and solar UV at 65-75 km, and simulated strong UV responses of water vapor and HO(x) species in the mesosphere. Consistent with previous 1D model studies, the observed upper mesospheric positive ozone response averaged over +/- 40 was simulated only when the model water vapor concentrations above 75 km were significantly reduced relative to current observations. In agreement with observations, the model computed a low to middle latitude total ozone phase lag of +3 days and a sensitivity of +0.077% per 1% change in 205 nm flux for the 27-day solar variation, and a total ozone sensitivity of +0.27% for the 11-yr solar cycle. This factor of 3 sensitivity difference is indicative of the photochemical time constant for ozone in the lower stratosphere which is comparable to the 27-day solar rotation period but is much shorter than the 11-yr solar cycle.
    Keywords: GEOPHYSICS
    Type: Journal of Atmospheric and Terrestrial Physics (ISSN 0021-9169); 57; 4; p. 333-365
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  • 98
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    Accuracy of satellite altimeter elevations over the Greenland ice sheet (1995)
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    Publication Date: 2011-08-24
    Description: The accuracy of Geosat satellite altimetry over the Greenland ice sheet is evaluated by comparing the measured heights to radar elevations from the airborne Greenland Aerogeophysics Project. At the center of the ice sheet where the ice surface is nearly level, surface comparisons show a fit at the 1 to 3 m level as expected, but even at moderately sloping ice regions (0.3 deg-0.6 deg), satellite altimetry mean errors in the range of 10 to 35 m are observed. These errors are found for slope-corrected and waveform-retracked data, so most previous accuracy estimates of current satellite altimetry ice sheet elevations in regions of slopping or undulating ice appear to be too optimistic.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; C2; p. 2687-2696
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  • 99
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    Satellite observations of zonal electric fields near sunrise in the equatorial ionosphere (1995)
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    Publication Date: 2011-08-24
    Description: We report here on a number of examples of anomalous enhancements of eastward electric fields near sunrise in the equatorial ionospheric F-region. These examples were selected from the data base of the equatorial satellite, San Marco D (1988), which measured ionospheric electric fields during a period of solar minimum. The eastward electric fields reported correspond to vertical plasma drifts. The examples studied here are similar in signature and polarity to the pre-reversal electric field enhancements seen near sunset from ground-based radar systems. The morphology of these sunrise events, which are observed on about 14% of the morning-side satellite passes, are studied as a function of local zonal velocity, magnetic activity, geographic longitude and altitude. The nine events studied occur at locations where the zonal plasma flow is generally measured to be eastward, but reducing as a function of local time and at satellite longitudes where the magnetic declination has the opposite polarity as the declination of the sunrise terminator.
    Keywords: GEOPHYSICS
    Type: Journal of Atmospheric and Terrestrial Physics (ISSN 0021-9169); 57; 1; p. 19-24
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  • 100
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    Observations of the loss of stratospheric NO2 following volcanic eruptions (1993)
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    Publication Date: 2011-08-24
    Description: Observations of stratospheric column amounts of nitrogen dioxide (NO2), nitric oxide (NO) and nitric acid (HNO3) have been made following major eruptions of the El Chichon and Mt. Pintatubo volcanoes. Midlatitude abundances of NO2 and NO were reduced by as much as 70% in the months following the appearance of the volcanic aerosols as compared to volcanically quite periods. There are heterogeneous reactions which could occur on the volcanic aerosols to convert NO2 into HNO3 but no commensurate increase in HNO3 column amounts was observed at the times of NO2 decrease.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 20; 24; p. 2873-2876
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