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  • Chemistry  (13,362)
  • Aircraft Propulsion and Power  (40)
  • Fisheries
  • LUNAR AND PLANETARY EXPLORATION
  • 1955-1959  (13,402)
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  • 1
    Publication Date: 2015-04-01
    Description: Afterburners for turbojet engines have, within the past decade, found increasing application in service aircraft. Practically all engines manufactured today are equipped with some form of afterburner, and its use has increased from what was originally a short-period thrust-augmentation application to an essential feature of the turbojet propulsion system for flight at supersonic speeds. The design of these afterburners has been based on extensive research and development effort in expanded laboratory facilities by both the NACA and the American engine industry. Most of the work of the engine industry, however, has either not been published or is not generally available owing to its proprietary nature. Consequently, the main bulk of research information available for summary and discussion is of NACA origin. However, because industrial afterburner development has closely followed NACA research, the omission is more one of technical detail than method or concept. One principal difficulty encountered in summarizing the work in this field is that sufficient knowledge does not yet exist to rationally or directly integrate the available background of basic combustion principles into combustor design. A further difficulty is that most of the experimental investigations that have been conducted were directed chiefly toward the development of specific afterburners for various engines rather than to the accumulation of systematic data. This work has, nonetheless, provided not only substantial improvements in the performance of afterburners but also a large fund of experimental data and an extensive background of experience in the field. Consequently, it is the purpose of the present chapter to summarize the many, and frequently unrelated, experimental investigations that have been conducted rather than to formulate a set of design rules. In the treatment of this material an effort has been made, however, to convey to the reader the "know how" acquired by research engineers in the course of afterburner studies.
    Keywords: Aircraft Propulsion and Power
    Type: Adaptation of Combustion Principles to Aircraft Propulsion. Volume II - Combustion in Air-Breathing Jet Engines
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  • 2
    Publication Date: 2015-04-01
    Description: In the early development of jet engines, it was occasionally found that excessive amounts of coke or other carbonaceous deposits were formed in the combustion chamber. Sometimes a considerable amount of smoke was noted in the-exhaust gases. Excessive coke deposits may adversely affect jet-engine performance in several ways. The formation of excessive amounts of coke on or just downstream of a fuel nozzle (figs. 116(a) and (b)) changes the fuel-spray pattern and possibly affects combustor life and performance. Similar effects on performance can result from the deposition of coke on primary-air entry ports (fig. 116(c)). Sea-level or altitude starting may be impaired by the deposition of coke on spark-plug electrodes (fig. 116(b)), deposits either grounding the electrodes completely or causing the spark to occur at positions other than the intended gap. For some time it was thought that large deposits of coke in turbojet combustion chambers (fig. 116(a)) might break away and damage turbine blades; however, experience has indicated that for metal blades this problem is insignificant. (Cermet turbine blades may be damaged by loose coke deposits.) Finally, the deposition of coke may cause high-temperature areas, which promote liner warping and cracking (fig. 116(d)) from excessive temperature gradients and variations in thermal-expansion rates. Smoke in the exhaust gases does not generally impair engine performance but may be undesirable from a tactical or a nuisance standpoint. Appendix B of reference 1 and references 2 to 4 present data obtained from full-scale engines operated on test stands and from flight tests that indicate some effects on performance caused by coke deposits and smoke. Some information about the mechanism of coke formation is given in reference 5 and chapter IX. The data indicate that (1) high-boiling fuel residuals and partly polymerized products may be mixed with a large amount of smoke formed in the gas phase to account for the consistency, structure, and chemical composition of the soft coke in the dome and (2) the hard deposits on the liner are similar to petroleum coke and may result from the liquid-phase thermal cracking of the fuel. During the early development period of jet engines, it was noted that the excessive coke deposits and exhaust smoke were generally obtained when fuel-oil-type fuels were used. Engines using gasoline-type fuels were relatively free from the deposits and smoke. These results indicated that some type of quality control would be needed in fuel specifications. Also noted was the effect of engine operating conditions on coke deposition. It is possible that, even with a clean-burning fuel, an excessive amount of coke could be formed at some operating conditions. In this case, combustor redesign could possibly reduce the coke to a tolerable level. This chapter is a summary of the various coke-deposition and exhaust-smoke problems connected- with the turbojet combustor. Included are (1) the effect of coke deposition on combustor life or durability and performance; (2) the effect of combustor design, operating conditions, inlet variables, and fuel characteristics on coke deposition; (3) elimination of coke deposits; (4) the effect of operating conditions and fuel characteristics on formation of exhaust smoke; and (5) various bench test methods proposed for determining and controlling fuel quality.
    Keywords: Aircraft Propulsion and Power
    Type: Adaptation of Combustion Principles to Aircraft Propulsion. Volume II - Combustion in Air-Breathing Jet Engines
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  • 3
    Publication Date: 2015-04-01
    Description: Combustion must be maintained in the turbojet-engine combustor over a wide range of operating conditions resulting from variations in required engine thrust, flight altitude, and flight speed. Furthermore, combustion must be efficient in order to provide the maximum aircraft range. Thus, two major performance criteria of the turbojet-engine combustor are (1) operatable range, or combustion limits, and (2) combustion efficiency. Several fundamental requirements for efficient, high-speed combustion are evident from the discussions presented in chapters III to V. The fuel-air ratio and pressure in the burning zone must lie within specific limits of flammability (fig. 111-16(b)) in order to have the mixture ignite and burn satisfactorily. Increases in mixture temperature will favor the flammability characteristics (ch. III). A second requirement in maintaining a stable flame -is that low local flow velocities exist in the combustion zone (ch. VI). Finally, even with these requirements satisfied, a flame needs a certain minimum space in which to release a desired amount of heat, the necessary space increasing with a decrease in pressure (ref. 1). It is apparent, then, that combustor design and operation must provide for (1) proper control of vapor fuel-air ratios in the combustion zone at or near stoichiometric, (2) mixture pressures above the minimum flammability pressures, (3) low flow velocities in the combustion zone, and (4) adequate space for the flame.
    Keywords: Aircraft Propulsion and Power
    Type: Adaptation of Combustion Principles to Aircraft Propulsion. Volume II - Combustion in Air-Breathing Jet Engines
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  • 4
    Publication Date: 2015-04-01
    Description: From considerations of safety and reliability in performance of gas-turbine aircraft, it is clear that engine starting and acceleration are of utmost importance. For this reason extensive efforts have been devoted to the investigation of the factors involved in the starting and acceleration of engines. In chapter III it is shown that certain basic combustion requirements must be met before ignition can occur; consequently, the design and operation of an engine must be tailored to provide these basic requirements in the combustion zone of the engine, particularly in the vicinity of the ignition source. It is pointed out in chapter III that ignition by electrical discharges is aided by high pressure, high temperature, low gas velocity and turbulence, gaseous fuel-air mixture, proper mixture strength, and-an optimum spark. duration. The simultaneous achievement of all these requirements in an actual turbojet-engine combustor is obviously impossible, yet any attempt to satisfy as many requirements as possible will result in lower ignition energies, lower-weight ignition systems, and greater reliability. These factors together with size and cost considerations determine the acceptability of the final ignition system. It is further shown in chapter III that the problem of wall quenching affects engine starting. For example, the dimensions of the volume to be burned must be larger than the quenching distance at the lowest pressure and the most adverse fuel-air ratio encountered. This fact affects the design of cross-fire tubes between adjacent combustion chambers in a tubular-combustor turbojet engine. Only two chambers in these engines contain spark plugs; therefore, the flame must propagate through small connecting tubes between the chambers. The quenching studies indicate that if the cross-fire tubes are too narrow the flame will not propagate from one chamber to another. In order to better understand the role of the basic factors in actual engine operation, many investigations have been conducted in single combustors from gas-turbine engines and in full-scale engines in altitude tanks and in flight. The purpose of the present chapter is to discuss the results of such studies and, where possible, to interpret these results qualitatively in terms of the basic requirements reported in chapter III. The discussion parallels the three phases of turbojet engine starting: (1) Ignition of the fuel-air mixture (2) Propagation of flame throughout the combustion zone (3) Acceleration of the engine to operating speed.
    Keywords: Aircraft Propulsion and Power
    Type: Adaptation of Combustion Principles to Aircraft Propulsion. Volume II - Combustion in Air-Breathing Jet Engines
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  • 5
    Publication Date: 2015-04-01
    Description: Studies of the fundamental processes of combustion are usually concerned with wide ranges of investigation of individual processes. In general, each fundamental combustion process may be studied in an environment that is most suited to its evaluation and possibly unrelated basically to any practical application. The majority of the data presented in volume I of this series concern the fundamental aspects of combustion as functions of the individual occurrence of various contributing processes. In a jet engine, however, the various fundamental combustion processes may occur simultaneously and may interact. Furthermore, the engine environment usually does not permit independent variation of single combustion parameters, since specified operating conditions impose specific values on the parameters. In volume II, data are presented to show the effect of operating conditions on the over-all combustion process in different combustion components. To show the effect of operating conditions, it is necessary to specify the range of these conditions within which combustion components may operate. Therefore, this chapter presents only the operating conditions that might be required in the primary combustors and afterburners of typical current turbojet engines. (Corresponding information on ram-jet engines is presented in ch. xisi.) This chapter is not intended to serve as an explanation of engine operation. The operating conditions of the combustion components are presented in terms of total pressures and temperatures at the primary-combustor and afterburner inlets, reference velocities and outlet total temperatures of the primary combustors, and velocities at the plane of the flameholder in the afterburners. The data are presented to relate the operating regions of typical current turbojet combustion components to flight altitudes, Mach numbers, and modes of engine operation. Specifically, data are presented for the combustion parameters of the primary combustor and afterburner of three turbojet engines having rated compressor total-pressure ratios of 5, 8, and 12 under full-throttle conditions. Operational data for the primary combustor also include part-throttle operation at 70, 80, and 90 percent of rated engine speed and windmifling operation. The range of flight conditions includes altitudes from sea level to 65,000 feet and flight Mach numbers from zero to 1.6.
    Keywords: Aircraft Propulsion and Power
    Type: Adaptation of Combustion Principles to Aircraft Propulsion. Volume II - Combustion in Air-Breathing Jet Engines
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  • 6
    Publication Date: 2019-05-11
    Description: Three highly polished 15- included- angle cone- cylinders with hemispherical tips of several diameters ( 2, 3, and 4 in.) have been flown in order to obtain boundary- layer transition data at very low wall to local stream temperature ratios, and heat- transfer data. All surfaces had a 2-microinch average roughness height. Laminar flow existed over the entire hemispherical nose of the 2- and 3-inch-tip- diameter models throughout the complete flight history. Extreme cooling to wall to local stream temperature ratios at the sonic point as low as 0.20 did not cause transition on the nose for diameters as large as 3 inches. However, extreme cooling did cause early transition on the 4-inch model where it appears probable that transition occurred forward of the 45 station at a wall to local stream temperature ratio of about 0.26. Variations in tip diameter influenced transition downstream of the nose under conditions of extreme cooling. The 2-inch- tip model was laminar at all cone- cylinder stations at temperature ratios as low as 0.32 whereas the 3- and 4-inch-tip models were turbulent at the same local flow conditions but at higher wall to local temperature ratios. Transition on the cone and cylinder of the 3- and 4-inch- tip bodies appeared to be sensitive to local Mach number, and occurred at higher local temperature ratios when values of local Mach number were higher. Increasing the nose diameter from 2 to 3 inches significantly changed the local flow conditions for which laminar flow existed on the cone- cylinder afterbody. However, a further increase in tip size t o a 4-inch diameter had no discernable effect on the local flow conditions at transition. The transition results of the 3- and 4-inch-nose-diameter smooth bodies are similar to those observed on a 7/8-inch-nose-diameter body with roughened surfaces. Turbulent boundary layers resulted in both cases at very low wall to local stream temperature ratios. Both laminar and turbulent heat-transfer data were in good agreement with theoretical Stanton numbers when heat-transfer reduction due to tip blunting was considered.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-3-4-59E , GRC-E-DAA-TN65086
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  • 7
    Publication Date: 2019-06-28
    Description: Average spanwise blade temperatures and cooling-air pressure losses through a small (1.4-in, span, 0.7-in, chord) air-cooled turbine blade were calculated and are compared with experimental nonrotating cascade data. Two methods of calculating the blade spanwise metal temperature distributions are presented. The method which considered the effect of the length-to-diameter ratio of the coolant passage on the blade-to-coolant heat-transfer coefficient and assumed constant coolant properties based on the coolant bulk temperature gave the best agreement with experimental data. The agreement obtained was within 3 percent at the midspan and tip regions of the blade. At the root region of the blade, the agreement was within 3 percent for coolant flows within the turbulent flow regime and within 10 percent for coolant flows in the laminar regime. The calculated and measured cooling-air pressure losses through the blade agreed within 5 percent. Calculated spanwise blade temperatures for assumed turboprop engine operating conditions of 2000 F turbine-inlet gas temperature and flight conditions of 300 knots at a 30,000-foot altitude agreed well with those obtained by the extrapolation of correlated experimental data of a static cascade investigation of these blades.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E58E20
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  • 8
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    Unknown
    In:  CASI
    Publication Date: 2019-06-28
    Description: Some of the considerations involved in the design of aircraft fuel tanks for liquid hydrogen are discussed herein. Several of the physical properties of metals and thermal insulators in the temperature range from ambient to liquid-hydrogen temperatures are assembled. Calculations based on these properties indicate that it is possible to build a large-size liquid-hydrogen fuel tank which (1) will weigh less then 15 percent of the fuel weight, (2) will have a hydrogen vaporization rate less than 30 percent of the cruise fuel-flow rate, and (3) can be held in a stand-by condition and readied for flight in a short time.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E55F22
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  • 9
    Publication Date: 2019-06-28
    Description: The report summarizes source material on combustion for flight-propulsion engineers. First, several chapters review fundamental processes such as fuel-air mixture preparation, gas flow and mixing, flammability and ignition, flame propagation in both homogenous and heterogenous media, flame stabilization, combustion oscillations, and smoke and carbon formation. The practical significance and the relation of these processes to theory are presented. A second series of chapters describes the observed performance and design problems of engine combustors of the principal types. An attempt is made to interpret performance in terms of the fundamental processes and theories previously reviewed. Third, the design of high-speed combustion systems is discussed. Combustor design principles that can be established from basic considerations and from experience with actual combustors are described. Finally, future requirements for aircraft engine combustion systems are examined.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E54I07
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  • 10
    Publication Date: 2019-06-27
    Description: Two short turbojet combustors designed for use with vaporized hydrocarbon fuels were tested in a one-quarter annular duct. The experimental combustors consisted of many small "swirl-can" combustor elements manifolded together. This design approach allowed the secondary mixing zone to be considerably reduced over that of conventional combustors. The over-all combustion lengths, for the two configurations were 13.5 and 11.0 inches, approximately one-half the length of the shortest conventional combustors. These short combustors did not provide combustion efficiencies as high as those for conventional combustors at low pressures. However, over the range of combustor-inlet total-pressures expected in aircraft capable of flight at Mach numbers of 2.5 and above, these short combustors gave very high efficiencies. A combustion efficiency of 97 percent was obtained at a combustor-inlet total-pressure of 25.0 inches of mercury absolute, reference velocity of 120 feet per second, and inlet-air total temperature of 1160 deg R. By proportioning the fuel flow between the manifold rows of can combustor elements, control of the combustor-outlet radial total-temperature profile was demonstrated. Combustor totalpressure loss varied from 0.75 percent of the inlet total pressure at isothermal conditions and a reference velocity of 75 feet per second to 5.5 percent at a total-temperature ratio of 1.8 and a reference velocity of 180 feet per second.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E57J03
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  • 11
    Publication Date: 2019-06-27
    Description: This analysis investigates the application of gas turbine engines at a cruise Mach number of 4.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-TM-X-60935 , NACA-C-8548
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  • 12
    Publication Date: 2019-07-11
    Description: A program was conducted in an altitude facility at the NACA Lewis laboratory to investigate the effects of rapid inlet pressure oscillations on the operation of a current turbo jet engine. These pressure oscillations were approximately sinusoidal in form and were generated to cover a frequency range of 2 to 75 cycles per second and an amplitude range of 10 to 70 percent of the free-stream total pressure. As the oscillation progressed through the compressor, the amplitude was attenuated considerably and a relatively large phase shift (lag) occurred. Engine stall limits obtained during pressure oscillations differed from quasi-steady-state stall limits as defined by over-all compressor pressure ratio.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E58A03
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  • 13
    Publication Date: 2019-07-11
    Description: The multistage turbine from the J73 turbojet engine has previously been investigated with standard and with reduced-chord rotor blading in order to determine the individual performance characteristics of each configuration over a range of over-all pressure ratio and speed. Because both turbine configurations exhibited peak efficiencies of over 90 percent, and because both units had relatively wide efficient operating ranges, it was considered of interest to determine the performance of the first stage of the turbine as a separate component. Accordingly, the standard-bladed multistage turbine was modified by removing the second-stage rotor disk and stator and altering the flow passage so that the first stage of the unit could be operated independently. The modified single-stage turbine was then operated over a range of stage pressure ratio and speed. The single-stage turbine operated at a peak brake internal efficiency of over 90 percent at an over-all stage pressure ratio of 1.4 and at 90 percent of design equivalent speed. Furthermore, the unit operated at high efficiencies over a relatively wide operating range. When the single-stage results were compared with the multistage results at the design operating point, it was found that the first stage produced approximately half the total multistage-turbine work output.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E53L28A
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  • 14
    Publication Date: 2019-07-11
    Description: The steady-state over-all performance characteristics of the J65-B3 turbojet engine were determined in an altitude test chamber for four exhaust-nozzle areas at Reynolds number indices of 0.8, 0.4, and 0.2. This range of Reynolds number indices corresponds to a range of altitudes from about sea level to 51,500 feet at a flight Mach number of 0.8. Generalized data are presented to allow calculation of engine performance at any flight condition corresponding to a Reynolds number index within the range investigated. Engine performance calculated from these generalized data is presented for seven altitudes over a range of flight speeds from zero to about 1100 knots. The use of an exhaust nozzle sized to give rated perforce at sea level would permit operation near the point of minimum specific fuel consumption for a wide range of flight conditions and engine speeds.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-SE55C08
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  • 15
    Publication Date: 2019-07-11
    Description: Internal performance of an XJ79-GE-1 variable ejector was experimentally determined with the primary nozzle in a representative nonafterburning position. Jet-thrust and air-handling data were obtained in quiescent air for 11 selected ejector configurations over a wide range of operation. Additional data, at specific operating conditions, were obtained which indicate the ejector diameter ratio for peak jet-thrust performance. The experimental ejector data are presented in both graphical and tabulated form.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E56E23
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  • 16
    Publication Date: 2019-07-12
    Description: An investigation was conducted in an altitude test chamber at the NACA Lewis laboratory to determine the effect of a revision of the rated engine operating conditions and modifications to the afterburner fue1 system, flameholder, and shell cooling on the augmented performance of the J71-A-2 (x-29) turbo jet engine operating at altitude . The afterburner modifications were made by the manufacturer to improve the endurance at sea-level, high-pressure conditions and to reduce the afterburner shell temperatures. The engine operating conditions of rated rotational speed and turbine-outlet gas temperature were increased. Data were obtained at conditions simulating flight at a Mach number of 0.9 and at altitudes from 40,000 to 60,000 feet. The afterburner modifications caused a reduction in afterburner combustion efficiency. The increase in rated engine speed and turbine-outlet temperature coupled with the afterburner modifications resulted in the over-all thrust of the engine and afterburner being unchanged at a given afterburner equivalence ratio, while the specific fuel consumption was increased slightly. A moderate shift in the range of equivalence ratios over which the afterburner would operate was encountered, but the maximum operable altitude remained unaltered. The afterburner-shell temperatures were also slightly reduced because of the modifications to the afterburner.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-SE55D12
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  • 17
    Publication Date: 2019-07-12
    Description: Annular blade-element data obtained primarily from single-stage compressor installations are correlated over a range of inlet Mach numbers and cascade geometry. The correlation curves are presented in such a manner that they are related directly to the low-speed two-dimensional-cascade data of part VI of this series. Thus, the data serve as both an extension and a verification of the two-dimensional-cascade data. In addition, the correlation results are applied to compressor design.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E55G02
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  • 18
    Publication Date: 2019-07-12
    Description: An investigation of the endurance characteristics, at high Mach number, of the J65-W-7 engine was made in an altitude chamber at the Lewis laboratory. The investigation was made to determine whether this engine can be operated at flight conditions of Mach 2 at 35,000-feet altitude (inlet temperature, 250 F) as a limited-service-life engine Failure of the seventh-stage aluminum compressor blades occurred in both engines tested and was attributed to insufficient strength of the blade fastenings at the elevated temperatures. For the conditions of these tests, the results showed that it is reasonable to expect 10 to 15 minutes of satisfactory engine operation before failure. The high temperatures and pressures imposed upon the compressor housing caused no permanent deformation. In general, the performance of the engines tested was only slightly affected by the high ram conditions of this investigation. There was no discernible depreciation of performance with time prior to failure.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-SE55B07
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  • 19
    Publication Date: 2019-08-17
    Description: The effect of stator and rotor aspect ratio on transonic-turbine performance was experimentally investigated. The stator aspect ratios covered were 1.6. 0.8, and 0.4, while the rotor aspect ratios investigated were 1.46 and 0.73. It was found that the observed variation in turbine design-point efficiency was negligible. Thus, within the range of aspect ratio investigated, these results verify for turbines operating in the transonic flow range the finding of a reference report, which showed analytically that, if blade shape and solidity are held constant, the aspect ratio may be varied over a wide range without appreciable change in turbine efficiency.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-2-11-59E , E-177
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  • 20
    Publication Date: 2019-08-17
    Description: The suitability of cermets for turbine stator blades of a modified turbojet engine was determined at an average turbine-inlet-gas temperature of 2000 F. Such an increase in temperature would yield a premium in thrust from a service engine. Because the cermet blades require no cooling, all the available compressor bleed air could be used to cool a turbine made from conventional ductile alloys. Cermet blades were first run in 100-hour endurance tests at normal gas temperatures in order to evaluate two methods for mounting them. The elevated gas-temperature test was then run using the method of support considered best for high-temperature operation. After 52 hours at 2000 F, one of the group of four cermet blades fractured probably because of end loads resulting from thermal distortion of the spacer band of the nozzle diaphragm. Improved design of a service engine would preclude this cause of premature failure.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-2-13-59E , E-147
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  • 21
    Publication Date: 2019-08-17
    Description: An investigation was conducted in a modified turbojet engine to determine the cooling characteristics of the semistrut corrugated air- cooled turbine blade and to compare and evaluate a leading-edge tip cap as a means for improving the leading-edge cooling characteristics of cooled turbine blades. Temperature data were obtained from uncapped air-cooled blades (blade A), cooled blades with the leading-edge tip area capped (blade B), and blades with slanted corrugations in addition to leading-edge tip caps (blade C). All data are for rated engine speed and turbine-inlet temperature (1660 F). A comparison of temperature data from blades A and B showed a leading-edge temperature reduction of about 130 F that could be attributed to the use of tip caps. Even better leading-edge cooling was obtained with blade C. Blade C also operated with the smallest chordwise temperature gradients of the blades tested, but tip-capped blade B operated with the lowest average chordwise temperature. According to a correlation of the experimental data, all three blade types 0 could operate satisfactorily with a turbine-inlet temperature of 2000 F and a coolant flow of 3 percent of engine mass flow or less, with an average chordwise temperature limit of 1400 F. Within the range of coolant flows investigated, however, only blade C could maintain a leading-edge temperature of 1400 F for a turbine-inlet temperature of 2000 F.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-2-9-59E
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  • 22
    Publication Date: 2019-08-16
    Description: A lightweight turbine rotor assembly was devised, and components were evaluated in a full-scale jet engine. Thin sheet-metal airfoils were brazed to radial fingers that were an integral part of a number of thin disks composing the turbine rotor. Passages were provided between the disks and in the blades for air cooling. The computed weight of the assembly was 50 percent less than that of a similar turbine of normal construction used in a conventional turbojet engine. Two configurations of sheet-metal test blades simulating the manner of attachment were fabricated and tested in a turbojet engine at rated speed and temperature. After 8-1/2 hours of operation pieces broke loose from the tip sections of the better blades. Severe cracking produced by vibration was determined as the cause of failure. Several methods of overcoming the vibration problem are suggested.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-10-5-58E
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  • 23
    Publication Date: 2019-08-16
    Description: The design and experimental investigation of a 4.5-inch-mean-diameter two-stage turbine are presented herein and used to study the effect of size on the efficiency of turbines in the auxiliary power drive class. The results of the experimental investigation indicated that design specific work was obtained at design speed at a total-to-static efficiency of 0.639. At design pressure ratio, design static-pressure distribution through the turbine was obtained with an equivalent specific work output of 33.2 Btu per pound and an efficiency of 0.656. It was found that, in the design of turbines in the auxiliary power drive class, Reynolds number plays an important part in the selection of the design efficiency. Comparison with theoretical efficiencies based on a loss coefficient and velocity diagrams are presented. Close agreement was obtained between theory and experiment when the loss coefficient was adjusted for changes in Reynolds number to the -1/5 power.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-4-6-59E
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  • 24
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    Unknown
    In:  CASI
    Publication Date: 2019-08-14
    Description: The ram jet is basically one of the most dimple types of aircraft engine. It consists only of an inlet diffuser, a combustion system, and an exit nozzle. A typical ram-jet configuration is shown in figure 128. The engine operates on the Brayton cycle, and ideal cycle efficiency depends only on the ratio of engine to ambient pressure. The increased, engine pressures are obtained by ram action alone, and for this reason the ram jet has zero thrust at zero speed. Therefore, ram-jet-powered aircraft must be boosted to flight speeds close to a Mach number of 1.0 before appreciable thrust is generated by the engine. Since pressure increases are obtained by ram action alone, combustor-inlet pressures and temperatures are controlled by the flight speed, the ambient atmospheric condition, and by the efficiency of the inlet diffuser. These pressures and temperatures, as functions of flight speed and altitude, are shown in figure 129 for the NACA standard atmosphere and for practical values of diffuser efficiency. It can be seen that very wide ranges of combustor-inlet temperatures and pressures may be encountered over the ranges of flight velocity and altitude at which ram jets may be operated. Combustor-inlet temperatures from 500 degrees to 1500 degrees R and inlet pressures from 5 to 100 pounds per square inch absolute represent the approximate ranges of interest in current combustor development work. Since the ram jet has no moving parts in the combustor outlet, higher exhaust-gas temperatures than those used in current turbojets are permissible. Therefore, fuel-air ratios equivalent to maximum rates of air specific impulse or heat release can be used, and, for hydrocarbon fuels, this weight ratio is about 0.070. Lower fuel-air ratios down to about 0.015 may also be required to permit efficient cruise operation. This fuel-air-ratio range of 0.015 to 0.070 used in ram jets can be compared with the fuel-air ratios up to 0.025 encountered in current turbojets. Ram-jet combustor-inlet velocities range from 150 to 400 feet per second. These high linear velocities combined with the relatively low pressure ratios obtainable in ram jets require that the pressure drop through the combustor be kept low to avoid excessive losses in cycle efficiency. It has been estimated that, for a long-range ram-jet engine, an increase in pressure loss of one dynamic head would require a compensating 1-percent increase in combustion efficiency. Therefore, combustor pressure-loss coefficients (pressure drop/impact pressure) of the order of 1 to 4 are found in most current engines. The operating conditions described impose major problems in the design of stable and efficient ram-jet combustion systems. This chapter presents a survey of ram-jet combustor research and, where possible, points out criteria that may be useful in the design of ram-jet combustion systems.
    Keywords: Aircraft Propulsion and Power
    Type: Adaptation of Combustion Principles to Aircraft Propulsion. Volume II - Combustion in Air-Breathing Jet Engines
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  • 25
    Publication Date: 2019-08-15
    Description: The performance of turbine-engine combustors usually is given in terms of operating limits and combustion efficiency. The latter property is determined most often by measuring the increase in enthalpy across the combustor through the use of thermocouples. This investigation was conducted to determine the ability of gas-analytical techniques to provide additional information about combustor performance. Gas samples were taken at the outlet and two upstream stations and their compositions determined. In addition to over-all combustion efficiency, estimates of local fuel-air ratios, local combustion efficiencies, and heat-release rates can be made. Conclusions can be drawn concerning the causes of combustion inefficiency and may permit corrective design changes to be made more intelligently. The purpose of this investigation was not to present data for a given combustor but rather to show the types and value of additional information that can be gained from gas-analytical data.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-1-26-59E , E-245
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  • 26
    Publication Date: 2019-07-11
    Description: Internal performance of an XJ79-GE-1 variable ejector was experimentally determined with the primary nozzle in two representative after-burning positions. Jet-thrust and air-handling data were obtained in quiescent air for 4 selected ejector configurations over a wide range of secondary to primary airflow ratios and primary-nozzle pressure ratios. The experimental ejector data are presented in both graphical and tabulated form.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E57F25
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  • 27
    Publication Date: 2019-07-11
    Description: Nine divergent-shroud ejector configurations were investigated to determine the effect of shroud divergence angle on ejector internal performance. Unheated dry air was used for both the primary and secondary flows. The decrease in the design-point thrust coefficient with increasing flow divergence angle (angle measured from primary exit to shroud exit) followed very closely a simple relation involving the cosine of the angle. This indicates that design-point thrust performance for divergent-shroud ejectors can be predicted with reasonable accuracy within the range investigated. The decrease in design-point thrust coefficient due to increasing the flow divergence engle from 120deg to 30deg (half-singles) was approximately 6 percent. Ejector air-handling characteristics and the primary-nozzle flow coefficient were not significantly affected by change in shroud divergence angle.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E57F13
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  • 28
    Publication Date: 2019-07-11
    Description: A two-spool turbojet engine was operated in the Lewis altitude wind tunnel to study the inception of compressor surge. In addition to the usual steady-state pressure and temperature measurements, the compressors were extensively instrumented with fast-response interstage pressure transducers. Thus it was possible to obtain maps for both compressors, pressure oscillations during rotating stall, effects of stall on efficiency, and stage-loading curves. In addition, with the transient measurements, it was possible to record interstage pressures and then compute stage performance during accelerations to the stall limit. Rotating stall was found to exist at low speeds in the outer spool. Although the stall arose from poor flow conditions at the inlet-stage blade tips, the low-energy air moved through the machine from the tip at the inlet to the outer spool to the hub at the inlet to the inner spool. This tip stall ultimately resulted in compressor surge in the mid-speed region, and necessitated inter-compressor air bleed. Interstage pressure measurements during acceleration to the compressor stall limit indicated that rotating stall was not a necessary condition for compressor surge and that, at the critical stall point, the circumferential interstage pressure distribution was uniform. The exit-stage group of the inner spool was first t o stall; then, the stages upstream stalled in succession until the inlet stage of the outer spool was stalled. With a sufficiently high fuel rate, the process repeated with a cycle time of about 0.1 second. It was possible to construct reproducible stage stall lines as a function of compressor speed from the stage stall points of several such compressor surges. This transient stall line was checked by computing the stall line from a steady-state stage-loading curve. Good agreement between the stage stall lines was obtained by these two methods.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E57I27
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  • 29
    Publication Date: 2019-07-12
    Description: The performance and operational characteristics of two afterburner configurations for the Iroquois turbojet engine were evaluated in an altitude test chamber over a range of afterburner equivalence ratios at afterburner-inlet pressures from 733 to 3186 pounds per square foot absolute. These conditions correspond to an altitude range from 38,700 to 66,800 feet at a flight Mach number of 1.5. The only difference between the two afterburner configurations was in the pattern of afterburner fuel injection. At an afterburner-inlet pressure of approximately 3100 pounds per square foot absolute, corresponding to an altitude of 38,700 feet and a_ flight Mach number of 1.5, the combustion efficiency of both configurations reached peak values of 0.80 to 0.85 at equivalence ratios of 0.35 to 0.40. However, further reduction in the afterburner-inlet pressure severely affected combustion efficiency. For example, at an afterburner inlet pressure level of 700 to 1000 pounds per square foot absolute, the efficiency for both configurations was 0.20 to 0.40.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-SE58G01
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  • 30
    Publication Date: 2019-08-15
    Description: For a period of ten to fifteen years intensive research and development has been conducted on turbojet propulsion systems for aircraft. During this period much has been learned about the system both from the standpoint of current usage and of future development possibilities. It is the purpose of this report to discuss the current status of the turbojet engine as produced in the United States and to discuss the future possibilities for improvement in the engine and in the fuel. The engine and fuel improvements will be evaluated both from the standpoint of probability of success in obtaining these improvements and from the standpoint of the effects of these improvements on the airplane performance.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-54H23
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  • 31
    Publication Date: 2019-08-15
    Description: An investigation was conducted to determine the flameholding capabilities of aerodynamic jets at afterburner operating conditions. Stability data for a number of aerodynamic flameholders were obtained in a 5- by 5-inch test section at inlet-air reference velocities up to 600 feet per second, an inlet-air temperature of 1250 F, and a combustor-inlet pressure of 15 inches of mercury absolute. Combustion efficiency and stability data of the more promising combinations were then obtained in a 10- by 12-inch test section at the same test conditions. Both air and stoichiometric mixtures of fuel and air were used in the jets; mixture flow rates were approximately 1 percent by weight of the total air-flow rate. Injection pressures were limited to values that might be available from compressor-bleed air. At a reference velocity of 600 feet per second, aerodynamic flame-holders alone were unable to maintain a stable flame at injection pressures up to 70 pounds per square inches large reductions in velocity were required to achieve flame stabilization. When the aerodynamic jets were used in combination with a V-gutter flameholder with approximately a 30 percent blocked area, flame stabilization was attained at a velocity of 600 feet per second; however, the combustion efficiencies of the various combinations were no greater than that obtained with the V-gutter alone.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-4-9-59E
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  • 32
    Publication Date: 2019-08-15
    Description: Incompressible-flow calculations were performed to determine the effects of combustor geometric and operating variables on pressure loss and airflow distribution in a tubular combustor with a tapered liner. The calculations include the effects of momentum transfer between annulus and liner gas streams, annulus wall friction, heat release, and discharge coefficients of liner air-entry holes. Generalized curves are presented which show the effects of liner-wall inclination, liner open hole area, and temperature rise across the combustor on pressure loss and airflow distribution for a representative parabolic liner hole distribution. A comparison of the experimental data from 12 tapered liners with the theoretical calculations indicates that reasonable design estimates can be made from the generalized curves. The calculated pressure losses of the tapered liners are compared with those previously reported for tubular liners.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-11-26-58E , E-126
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  • 33
    Publication Date: 2019-08-15
    Description: A comparison of the performance of a single-stage rotor run at three different blade setting angles is presented. The rotor was of a design typical for a last stage of a multistage compressor. At each setting angle, the rotor blade row was operated from 53 to 100 percent of equivalent maximum speed (850 ft/sec tip speed) at constant inlet pressure. Hot-wire anemometry was used to observe rotating-stall and surge patterns in time unsteady flow. Results indicated that an increase in peak pressure ratio and an increase in maximum equivalent weight flow were obtained at each speed investigated when the blade setting angle was decreased. An increase in peak efficiency was achieved with decrease in blade setting angle for part of the range of speeds investigated. However, the peak efficiencies for the three blade setting angles were approximately the same at the maximum speed investigated. The flow ranges for all three configurations were about the same at minimum speed and decreased at almost the same rate when the rotative speed was increased through part of the range of speeds investigated. At maximum speed, the flow range for the smallest setting angle was considerably less than the flow range for the other two configurations. A decrease in efficiency and flow range for the smallest blade setting angle at maximum speed can be attributed primarily to a Mach number effect. In addition, because of the difference in projected axial chord lengths at the casing wall, some effect on performance could be expected from the change in three-dimensional flow occurring at the tip. Rotating-stall characteristics for the two smaller blade setting angles were essentially the same. Only surge could be detected for the largest blade setting angle in the unstable-flow region of operation.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-11-27-58E , E-117
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  • 34
    Publication Date: 2019-08-15
    Description: High-altitude turbojet performance is adversely affected by the effects of low air density. This performance loss is evaluated as a Reynolds number effect, which represents the increased significance of high fluid viscous forces in relation to dynamic fluid forces as the Reynolds number is decreased. An analytical and experimental investigation of the effects of low Reynolds number operation on a single-stage, high-work-output turbine with a downstream stator was carried out at Reynolds numbers of 182,500, 39,600, and 23,000, based on average rotor-design flow conditions. At low Reynolds numbers and turbulent flow conditions, increased viscous losses caused decreased effective flow area, and thus decreased weight flow, torque, and over-all efficiency at a given equivalent speed and pressure ratio. Decreasing the Reynolds number from 182,500 to 23,000 at design equivalent speed resulted in a 5.00-point loss in peak over-all turbine efficiency for both theory and experiment. The choking equivalent weight flow decreased 2.30 percent for these conditions. Limiting loading work output was reached at design equivalent speed for all three Reynolds numbers. The value of limiting loading work output at design speed decreased 4.00 percent as Reynolds number was decreased from 182,500 to 23,000. A theoretical performance-prediction method using basic boundary-layer relations gave good agreement with experimental results over most of the performance range at a given Reynolds number if the experimental and analytical design operating conditions were carefully matched at the highest Reynolds number with regard to design performance parameters. High viscous losses in the inlet stator and rotor prevented the attainment of design equivalent work output at the lowest Reynolds number of 23,000.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-TM-X-9
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  • 35
    Publication Date: 2019-07-12
    Description: The performance characteristics of the 19B-8 and 19XB-1 turbojet engines and the windmilling-drag characteristics of the 19B-6 engine were determined in the Cleveland altitude wind tunnel. The investigations were conducted on the 19B-8 engine at simulated altitudes from 5000 to 25,000 feet with various free-stream ram-pressure ratios and on the 19XB--1 engine at simulated altitudes from 5000 to 30,000 feet with approximately static free-stream conditions. Data for these two engines are presented to show the effect of altitude, free-stream ram-pressure ratio, and tail-pipe-nozzle area on engine performance. A 21-percent reduction in tail-pipe-nozzle area of the 19B-8 engine increased the let thrust 43 percent the net thrust 72 percent, and the fuel consumption 64 percent. An increase in free-stream ram-pressure ratio raised the jet thrust and the air flow and lowered the net thrust throughout the entire range of engine speeds for the 19B-8 engine. At similar operating conditions, the corrected jet thrust and corrected air flow were approximately the same for both engines, and the corrected specific fuel consumption based on jet thrust was lower for the 19XB-1 engine than for the 19B-8 engine. The thrust and air-flow data obtained with both engines at various altitudes for a given free-stream rampressure ratio were generalized to standard sea-level atmospheric conditions. The performance parameters involving fuel consumption generalized only at high engine speeds at simulated altitudes as high as 15,000 feet. The windmilling drag of the 19B-8 engine increased rapidly as the airspeed was increased.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E7C13
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  • 36
    Publication Date: 2019-07-12
    Description: The stall-limit line at low speeds was improved somewhat by closing the inlet guide vanes 6 deg, while the design-speed maximum flow and pressure ratio were reduced. The first-stage characteristic curve was moved to lower values of both flog coefficient and equivalent pressure ratio. The second-stage pressure ratio was decreased slightly at high speeds, while the later stages were unaffected.
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-SE55D11
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  • 37
    Publication Date: 2019-07-12
    Description: Good internal performance over a wide range of flight conditions can be obtained with either a plug nozzle or a variable ejector nozzle that can provide a divergent shroud at high pressure ratios. For both the ejector and the plug nozzle, external flow can sometimes cause serious drag losses and, for some plug-nozzle installations, external flow can cause serious internal performance losses. Plug-nozzle cooling and design of the secondary-air-flow systems for ejectors were also considered .
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E56A18
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  • 38
    Publication Date: 2019-07-12
    Description: The over-all component performance characteristics of the J71 Type IIA three-stage turbine were experimentally determined over a range of speed and over-all turbine total-pressure ratio at inlet-air conditions af 35 inches of mercury absolute and 700 deg. R. The results are compared with those obtained for the J71 Type IIF turbine, which was previously investigated, the two turbines being designed for the same engine application. Geometrically the two turbines were much alike, having the same variation of annular flow area and the same number of blades for corresponding stator and rotor rows. However, the blade throat areas downstream of the first stator of the IIA turbine were smaller than those of the IIF; and the IIA blade profiles were curve-backed, whereas those of the IIF were straight-backed. The IIA turbine passed the equivalent design weight flow and had a brake internal efficiency of 0.880 at design equivalent speed and work output. A maximum efficiency of 0.896 occurred at 130 percent of design equivalent speed and a pressure ratio of 4.0. The turbine had a wide range of efficient operation. The IIA turbine had slightly higher efficiencies than the IIF turbine at comparable operating conditions. The fact that the IIA turbine obtained the design equivalent weight flow at the design equivalent operating point was probably a result of the decrease in the blading throat areas downstream of the first stator from those of the IIF turbine, which passed 105 percent of design weight flow at the corresponding operating point. The third stator row of blades of the IIA turbine choked at the design equivalent speed and at an over-all pressure ratio of 4.2; the third rotor choked at a pressure ratio of approximately 4.9
    Keywords: Aircraft Propulsion and Power
    Type: NACA-RM-E55A20
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  • 39
    Publication Date: 2019-08-16
    Description: Five engine tests were conducted to definitely establish the failure mechanism of leading-edge cracking and to determine which conditions of engine operation cause the failures. Five groups of S-616 and M-252 buckets from master lots were run consecutively in the same J47-25 engine. The tests included a steady-state run at full-power conditions, rapid cycling between idle and rated speed, and three different start-stop tests. The first start-stop test consisted of cycles of start and stop with 5 minutes of idle speed before each stop; the second included cycles of start and stop but with 15 minutes of rated speed before each stop; the third consisted of cycles of gradual starts and normal stops with 5 minutes at idle speed before each stop. The test results demonstrated that the primary cause of leading-edge cracking was thermal fatigue produced by repeated engine starts. The leading edge of the bucket experiences plastic flow in compression during starts and consequently is subjected to a tensile stress when the remainder of the bucket becomes heated and expands. Crack initiation was accelerated when rated-speed operation was added to each normal start-stop cycle. This acceleration of crack formation was attributed to localized creep damage and perhaps to embrittlement resulting from overaging. It was demonstrated that leading-edge cracking can be prevented simply by starting the engine gradually.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-MEMO-4-7-59E , E-281
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  • 40
    Publication Date: 2019-08-16
    Description: In order to determine the effect of a low design diffusion factor on the performance of a transonic axial-flow compressor rotor, a high-specific-flow rotor with a 0.35 hub-tip radius ratio was designed, fabricated and tested. This rotor used a design tip diffusion factor of 0.20 with a design corrected specific weight flow of 40 pounds per second per square foot of frontal area, a total-pressure ratio of 1.27, and an adiabatic efficiency of 0.96. The design, rotor performance, and blade element performance are presented with a discussion on rotor shock losses and a comparison with a similarly designed rotor with a tip diffusion factor of 0.35. At the design corrected tip speed of 1100 feet per second, a peak rotor adiabatic efficiency of 0.88 was attained at a corrected specific weight flow of 39 pounds per second per square foot of frontal area with a mass-averaged total-pressure ratio of 1.27. The blade element tip diffusion factor was 0.281, which is 0.08 higher than the design value of 0.20. Peak efficiencies of 0.95, 0.91, 0.89, and 0.85 were obtained at 70, 80, 90, and 110 percent of design speed, respectively. Comparison of the performance of the rotor reported herein and a similarly designed rotor with increased blade loading indicates that higher blade loading results in a more desirable rotor because of a higher pressure ratio and equivalent efficiency. Computed values of shock losses at the rotor tip section indicate that the losses at peak efficiency are primarily a function of shock losses since the profile losses are only a small percentage of the total loss.
    Keywords: Aircraft Propulsion and Power
    Type: NASA-TM-X-86
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  • 41
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 10 (1959), S. 412-415 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Comparing Exposure Tests on the Corrosion Resistance of Passivated Galvanic zinc coatingsThe results of three years exposure tests on galvanic zinc coatings passivated by 15 different methods are given. The experiments were carried out under different conditions of climate: industry, urban, country and sea climate.There were big differences between the differently passivated coatings though generally a considerable increase of the corrosion resistance could be observed. The most effectfully passivating methods are named. Further result is that there is no good agreement between exposure and accelerated tests. The results show that the most intensive corrosion takes place in industrial climate and decreases in the order urban sea and country climate. It should be mentioned that fairly no dust will be deposited on some chromate coatings. Some coatings remained glittering for longer times, open, till the basic metal was corroded. A comparison of the resistances to corrosion of the differently passivated zinc coatings is given.
    Notes: Die Ergebnisse dreijähriger Feldversuche von galvanischen Zinküberzügen, die nach fünfzehn verschiedenen Verfahren passiviert worden waren, wurden bekanntgegeben. Die Versuche wurden unter verschiedenen Klimaverhältnissen: Industrie-, Stadt-, Land- und Seeklima, durchgeführt.Es wurde festgestellt, daß zwischen den in verschiedenen Bädern passiovierten Überzügen große Unterschiede bestehen in Bezug auf die Korrosionsbeständigkeit. In den meisten Fällen wurde eine bedeutende Verbesserung der Korrosions-beständigkeit beobachtet. Die Passivierungsbäder, welche die Korrosionsbeständigkeit der Zinküberzüge besonders steigern, wurden angegeben. Allgemein wurde festgestellt, daß nur ein loser Zusammenhang zwischen den Ergebnissen der Feld und Schnellversuche besteht. Die Ergebnisse zeigen, daß bei den passivierten Zinküberzügen die stärkste Korrosion im Industrieklima eintritt und dann in der Reihenfolge Stadt-, See-, und Landklima abnimmt. Man bemerkte auch, daß sich auf einigen Chromatüberzügen kaum Schmutz niederschlägt. Manche der Überzüge behielten ihren Glanz längere Zeit, oft bis zum Auftreten der Korrosion des Grundmetalls. Ein Vergleich der Korrosionsbeständigkeit der in verschiedenen Bädern passivierten Zinküberzügen wurde angegeben.
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Electro Chemical Behavior of Bimetallic Electrodes and the Application of their Overpotential Curves in Corrosion ResearchA two phase electrode with local cells on its anodic and cathodic surfaces is put into an extern circuit. The polarization voltage depends on (a)the situation and size of the local cell surfaces,(b)the anodic and cathodic processes on the local electrodes,(c)the direction and the current density of the extern current and(d)the situation of the tip of the reference electrode in the solution.The facts nzcntioned above are the basis for an investigation of current doisity-voltage curves of electrodes which are corroded by local currents.
    Notes: Eine Zweiphasenelektrode mit Lokal-elementanbildung auf ihren Anoden-und Kathodenflächen wird in einem äußeren Stromkreis eingebaut; die Messung der Polarisationsspannung hängt ab von: (a)Lage und Größe der Lokalelementflächen(b)Anoden- und Kathodenvorgängen auf den Lokalelektroden(c)Richtung und Stärke des außen angelegten Stromes und(d)Lage des Abzapfpunktes der Bezugselektrode in der Lösung.Die Erörterung der Tatsachen bildet die Grundlage zur Untersuchung von Strom. Spannungskurven von Elektroden, die bei Korrosionsvorgängen durch Lokalströme erhalten werden.
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  • 44
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 461-466 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 45
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 455-460 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 46
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 443-450 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion of Steel Pipes in Refinary Equipment by Sulfur Rich Crude OilThe crude oil of Nagylengyel contains five and six membered naphtene rings which are fused partly and heterocyclic compounds with sulfur, nitrogen resp. vanadium. The products of thermal decomposition of the crude oil and the overheated water vapor which is added to lower the partial pressure of the oil vapor attack the iron parts of the refinery severely. According to chemical and x-ray investigations the corrosion processes cause the formation of metal sulfides and sulfates as well as oxides of various degrees of oxidation. The corrosion products show differing structures according to the duration of corrosion. After some months there arc several plain covers of rust. After two years a peculiar structure of several layers appears which looks like finger prints. Under the cover the basic metal seems to be ribbed as by etching.The form of this noteworthy corrosion may be discerned by diffusion effects.
    Notes: Das Rohöl von Nagylengyel enthält Verbindungen, in welchen  -  z. T. kondensierte  -  fünf- oder sechsgliedrige Naphthenringe, außerdem Ringe mit Schwefel-, Stickstoff- bzw. Vanadin-Heteroatomen vorkommen. Bei der Verarbeitung des Rohöles greifen die therm. Zersetzungsprodukte und der  -  zwecks Erniedringung des Partialdruckes der Öldämpfe  -  eingeführte überhitzte Wasserdampf die Eisenteile der Raffinationsanlage stark an. Die Korrosionsvorgänge führen  -  nach den Daten der chem. und röntgenograph. Analyse der Korrosionsprodukte  -  zur Bildung von Metallsulfid und -sulfat-Verbindungen, ferner Metalloxyden verschiedener Oxydationsstufen.Die äußere Form und die mikrosk. Untersuchung zeigt, abhängend von der Zeitdauer der Korrosionswirkung, unterschiedliche Struktur. Bei paar Mon. Einwirkungsdauer sind mehrere glatte Rostschichten zu finden. Nach 2 Jhr. erscheint eine eigenartige „Fingerabdruck“ ähnliche, mehrschichtige Struktur. Unter dem gerippten Überzug scheint auch das Grundmetall durch Einätzung und Rippen unterteilt zu sein.Das Zustandekommen der bemerkenswerten Korrosionsformen kann mit Diffusionseffekten in Zusammenhang gebracht werden.
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  • 47
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 467-470 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 475-480 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 481-487 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 471-474 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 487-487 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 491-491 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. XXI 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 613-623 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Investigations on the Corrosion of Pressure Pipes and on the Protective MeasuresThe article presents a discussion of the general principles of galvanic cells as they cause many initial corrosion processes. This allows to understand easily the formation of rust on pipes in tunnels.The author gives a short summery of the behavior of different metal parts of a pipeline in a gallery under the influence of percolating water as well as of constant modifications of the conditions of temperature and airation.Furthermore some protective measures are described which were found to be suitable. Finally the properties of a protective coating which consists of several covers of paint, requested to guarrantee durable protection, are discussed.
    Notes: In vorliegendem Beitrag werden einige allgemeine Grundsätze der Bildung galvanischer Elemente betrachtet, da solche Elemente den Ausgangspunkt der Korrosionserscheinung darstellen; dadurch wird auch die Bildung des Rostes auf metallischen Leitungen in unterirdischen Schächten leichter verständlich.Der Verfasser gibt danach eine kurze Zusammenfassung des Verhaltens der verschiedenen metallischen Bestandteile einer in einer Galerie laufenden Leitung unter dem Einfluß von Sickerwasser sowie ständigem Wechsel der Temperatur und der Belüftung.Außerdem werden die Schutzmaßnahmen beschrieben, die zur Bekämpfung der schädlichen Einflüsse einer feuchtigkeitsgesättigten Atmosphäre erprobt wurden. Abschließend werden die wesentlichen Eigenschaften behandelt, die ein aus mehreren Anstrichschichten bestehender Überzug besitzen muß, um dauerhaften Schutz zu gewähren.
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    Description / Table of Contents: On the Importance of the Physical Properties of the Soil in Regard to the Mechanisms of the Reactions of Iron in SoilsAmong various factors controlling the velocity of the corrosion of iron in soils, as there are the soil water, the soil air, the pH-value and the electric resistance of the soil, the adhesive power of the soil to water is the most important one. The active and Passive states of iron in soil can be discerned from the theories of soil physicsBy means of model tests with glass balls of different sizes all kinds of contact corrosion can be explained. In a system unsaturated with water pitting might take place. A more uniform and weaker erosion is noticed in saturated soils.Basing on these results the experimental results of the American Bureau of Standards on the velocity of the corrosion of iron in 47 soils in the USA are represented as dependant of the average annual amount of rain.
    Notes: Unter den verschiedenen Faktoren, welche die Korrosionsgeschwindigkeit des Eisens im Erdreich regulieren, wie z. B. Bodenwasser, Bodenluft, Wasserstoffionen-Konzentration und Erdbodenwiderstand, ist das Haflvermögen des Bodens an Wasser der wichtigste Faktor. Das aktive und passive Verhalten des Eisens im Erdreich kann mit den Grundlagen der Bodenphysik erklärt werden.An Hand von Modellversuchen mit Glaskugeln verschiedener Größe werden die möglichen Arten der Kontaktkorrosion erklärt, in einem an Wasser ungesättigten System kommt es zu Lochfraß, und in einem an Wasser gesättigten Boden wird Eisen weniger und gleichmäßiger abgetragen.Auf Grund dieser Ergebnisse wurde versucht, die in der Natur erhaltenen Versuchsergebnisse des amerikanischen Bureau of Standards über die Korrosionsgeschwindigkeit des Eisens in 47 USA-Böden in Abhängigkeit von der durchschnittlichen jährlichen Regenmenge darzustellen.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 630-636 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: The Corrosion of the Tin Plate Container in Canning IndustryA large number of variables (steel, tin coating, surface treatments, can, content) play a role in the corrosion of the tin plate cans; thence its many aspects. The author treats deals special effects of corrosion on the inside and the outside of cans such as sulfide staining briefly. The usual effects of corrosion are discussed in detail: they are characterised by the tin-iron couple, in which tin is the anode (in unlacquered cans). The thickness and the porosity of the tin coating play a minor role while the type and characteristics of the steel, the presence of cathodic de-polarizers (like atmospheric oxygen), and the storage temperature, are important factors Lacquering increases corrosion by reducing the surface of the protective anode.The time dependance of the potentials of tin and steel in a couple, and of the output of the cell, seem to be the best means of studying the influences of the various factors; the most recent research is in this direction. So far, however, no laboratory test can replace practical tests.
    Notes: Zahlreiche Variabeln (Stahl, Verzinnung, Behandlung der Oberfläche, Dose, Produkt) beeinflussen die Korrosion der Konservendose; darum ist sie so verschiedenartig. Verfasser behandelt kurz die äußere Korrosion sowie bestimmte Typen von inneren Angriffen wie Sulfurierung, und bespricht eingehend die eigentliche Korrosion. Diese ist durch die Anwesenheit des Elektroelementes Zinn-Eisen charakterisiert, in welchem das Zinn als Anode wirkt (unlackierte Dose). Dicke und Porosität der Verzinnung spielen eine untergeordnete Rolle; dagegen sind Typ und Eigenschaften des Stahls, Anwesenheit von Depolarisatorer der Kathode (u. d. Luftsauerstoff) und Lagertemperatur wichtige Faktoren. Die Lackierung beschleunigt die Korrosion, da sie die Oberfläche der schützenden Anode vermindert.Die zeitliche Änderung des Potentials von Zinn und Stahl, in elektricher Berührung und der Strommenge der Zelle, scheinen der beste Weg zu sein, um den Einfluß der verschiedenen Faktoren zu untersuchen; in dieser Richtung bewegen sich die allerletzten Studien; doch bis jetzt erlaubt kein Laboratoriumversuch die praktische Probe zu ersetzen.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 645-650 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Description / Table of Contents: On the Importance of the Hydrate of Lime in Cement Mortar an Concrete against Aggression and of its Resistant Setting by Chemical Reactions during Hydration1The evaluation and interpretation of analytic and physical long term experiments with concretes made of Portland and blast furnace cements which were stored in aggressive agents, shows that the results agree to the theory of cements of the author. On this basis the hydration and cementation processes in the mortar beds as well as the causes and the mechanism of the corrosion of concrete are discerned. As the results of several testing methods and of different evaluation principles are agreeing, theoretically, the experimental results are of general and principle importance.2By means of a chemical reation a resistant setting of the hydrate of lime in the liquid phase during hydration was made possible. The so caused inhibition of the primary aggression allowed to increase the resistance of concretes of standard cements to a level never achieved before.
    Notes: 1Durch die Auswertung und Deutung von Langzeitversuchen, analytischen und physikalischen Untersuchungsergebnissen mit Beton aus Portlandzement und Hochofenzement bei Lagerung in aggressiven Medien ist es gelungen, einc neue zementtheoretische Anschauung des Verfassers zu bestätigen und davon ausgehend zur Klärung der Hydratations- und Erhärtungsvorgänge im Mörtelbett sowohl als auch der Ursachen und des Verlaufs der Betonaggression beizutragen. Die Untersuchungsergebnisse sind im Himblick auf ihre Übereinstimmung nach verschiedenen Prüfmethoden und den verschiedensten Auswertungsunterlagen nach Herstellungsart und Durchführungszeit theoretisch von allgemeingültiger und grundsätzlicher Bedeutung.2Durch die aggressionsbeständige Bindung des Kalkhydrats des Zements in der flüssigen Phase durch eine gezielte chemische Umsetzung während der Hydratation und die dadurch verursachte Hemmung bzw. Stillegung der Primäraggression wurde es möglich, Beton aus Normenzementen auf einfache Weise eine Aggressionsbeständigkeit zu geben, wie sie bisher noch nicht erreicht werden konnte.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 651-657 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 658-664 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 665-668 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 669-670 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 680-680 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958) 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 681-686 
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    Description / Table of Contents: Documentation and Protection against Corrosion by PaintsThe protection against corrosion by painsts plays an important part in the range of protective methode available.Modern paints differ considerably from those used thirty or even ten years ago.Successive developments require continuous testing. The recording and evaluation of the results of short-term tests in the laboratory, of weathering tests and practical applications are usually unsatisfactory.A significant documentation would enable a successful comparison and interpretation of results to be given. Thus, some directions on how to prepare a documentation are given.Besides the standard DIN 53210 “Determination of the Degree of Rusting” there is a draft on the determination of the quality of a paint coat. Results are collected in card index files.
    Notes: Der Korrosionsschutz durch Anstriche nimmt bei den zur Verfügung stehenden Schutzverfahren einen breiten Raum ein. Die heute verwendeten Anstrichmittel unterscheiden sich erheblich von denen, die man vor 30 Jahren benutzt hat und selbst von denen, die vor 10 Jahren in Gebrauch waren.Diese ständige Weiterentwicklung erfordert eine fortlaufende Erprobung. Die Erfassung und Auswertung von Ergebnissen bei Kurzprüfungen im Labor, Bewitterungsprüfungen und bei der Anwendung in der Praxis, ist in der Regel unbefriedigend. Aber erst durch eine sinnvolle Dokumentation der Prüfergebnisse können diese mit einander verglichen und ausgewertet werden.Nachfolgend werden Wege aufgezeigt, wie dieses erfolgen kann. Neben der DIN 53210 „Bestimmung des Rostgrades“ wird ein Schema zur Beurteilung des Zustandes des Anstriches mitgeteilt. Die Ergebnisse werden in Karteikarten erfaßt.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 690-693 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of Electro-Chemical Measurements to Find the Causes of CorrosionElectro-chemical investigations of materials under operating conditions enable the causes of corrosion damage to be ascertained.Current density voltage curves plotted on half logarithmic paper give information on the kind and the amount of the corrosion currents. There cases which could be cleared up by electro-chemical investigations are discussed.In the first case, the results show that the sensitivity of a steel section depends much more on its chemical composition than on peripheral segregation.The second case demonstrates that technical phosphoric acid weakens the passivation of V4A steel and conditions potentials at which pitting might occur if the surface is not clean.Finally the influence of atmospheric oxygen upon the corrosion current is discussed in the light of electro-chemical investigations. Intakes of air at a leaky stuffing box are considered to have caused the corrosion of a centrifugal pump.
    Notes: Eiektrochemische Messungen an Werkstoffen, die den jeweiligen Betriebsverhältnissen angeglichen werden, können oft zu wesentlichen Aussagen über die Ursachen von Korrosionsschadensfällen führen.In halblogarithmischer Darstellung aufgenommene Stromdichte-Potentialkurven sind direkten Aussagen über die Art und Größe von Korrosionsströmen zugänglich. In drei Beispielen werden die Ergebnisse von elktrochemischen Messungen diskutiert, die zur Klärung von Korrosionsschäden führten.In einem Fall geben die Versuchsergebinsse an, daß die Korrosionsanfälligkeit eines Profilstables stärker von der chemischen Zusammensetzung, als von randnaben Seigerungen bestimmt wird.Im zweiten Beispiel wird aufgezeigt, daß technische Phosphorsäure die Passivierung von V4A-Stahl abschwächt und Ruhepotentiale erreicht werden, die bei nicht sauberen Oberflächen zu Lochfraß führen können.Aus den Versuchsergebnissen elektrochemischer Messungen an Gußbronze in Kühlsole wird drittens der Einfluß von Lufltsauerstoff auf den Korrosionsstrom angeführt, so daß Lufteintritt an einer undichten Stoffbüchse für die starke Korrosion einer Kreiselpumpe verantwortlich gemacht werden muß.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 686-689 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Glossy and Thick Rhodium CoatingsRhodium has been used for twenty years to prevent the tarnishing of silver goods and silver jewellery. Today, Rhodium finds its applications in engineering too. The 'decorative' coatings are glossy but only 1 micron thick. The 'technological' coatings of thicknesses varying between 2 and 25 microns, are always dull.However, for certain purposes it is desirable to obtain both thick and glossy Rhodium coatings. The author, therefore, examines the effects of various additives: cetain metal salts delay the disappearance of the gloss with a coating thickness of up to 2 microns, but the true gloss-producing agents appear to be active only on the surface. A number of such surfaceactive materials (anion-active, cathion-active and non-ionising) were investigated. Some of these produce glossy coatings with a thickness of far more than 10 microns. In addition, the porosity of the coat and its surface tesion is greatly reduced, the porosity of the coat and its surface tension is greatly reduced and thereby the corrosion resistance of the Rhodium is significantly improved. However, results of these experiments are not entirely consistent and work in this field continues.
    Notes: Rhodium wird seit über zwei Jahrzehnten angewandt, um das Anlaufen von Silberwaren und Silberschmuck zu verhüten. Heute hat Rhodium auch in der Technik Eingang gefunden. Die „dekorativen“ Schichten sind glänzend, jedoch nicht stärker als 1 Mikron; die „technischen“ Schichten, deren Dicke zwischen 2 und 25 Mikron schwankt, sind stets matt.Für gewisse Zwecke ist es jedoch erwünscht, dicke und glänzende Rhodiumüberzüge zu erhalten. Der Verfasser hat daher die Wirkung verschiedener Zusätze geprüft: Gewisse Metallsalze verzögern das Schwinden des Glanzes bei einer Schichtdicke bis zu zwei Mikron, jedoch scheinen die ausgesprochenen glanzgebenden Produkte oberflächenaktive Stoffe zu sein. Eine Reihe synthetischer oberflächenaktiver Produkte  -  anionaktive, kationaktive und nichtionogene  -  wurde untersucht. Einige davon ergeben glänzende Überzüge bei Schichtdicken, die weit über 10 Mikron liegen. Die Porosität der Schicht und ihre Oberflächenspannung werden außerdem stark herabgesetzt und dadurch wird die Korrosionsbeständigkeit des Rhodiums deutlich verbessert. Die erhaltenen Ergebnisse sind jedoch noch nicht durchweg konstant und die Arbeiten auf diesem Gebiet werden fortgesetzt.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 715-718 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 693-698 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Causes of Stress Corrosion Cracking in Non-ferrous Metals and SteelsThe basic problems of stress corrosion are, on the one hand, the extreme localisation of the attack on the grain boundaries or on areas within the crystals; on the other hand the effect to tensile strees. The assumption that the tensile stress causes the localisation of the attack is not borne out. It is shown that a localised attack on the intergranular boundaries takes place even in homogeneous solid solution, without any tensile stress. This is traced to the increased reactivity of obtuse-angled grain boundaries due to solid solution formation, which can be proved experimentally. This solid solution effect, however, with a maximum of 50 At does not cause intercrystalline i. e. stress corrosion under the action of chemically corrosive agents alone; but only if an electrochemical process takes place at the same time. It is shown that such a porcess is possible even is homogeneous solid solution. As regards the part played by tensile stress, it is shown that its effect consists only of producing plastic deformation for, in the course of such deformation, i. e: in statu deformandi, the activity of a solid solution is increased considerably; for this, too, experimental proofs are given.
    Notes: Die Grundprobleme der Spannungskorrosion sind einerseits die extreme Lokalisierung des Angriffs auf die Korngrenzen oder auch auf Bereiche innerhalb der Kristallite, andererseits die Wirkung der Zugspannung. Die Annahme, daß durch die Zugspannung die Lokalisierung des Angriffs verursacht werden würde, wurde nicht bestätigt. Es wird nachgewiesen, daß ein lokalisierter Angriff auf die Korngrenzen auch bei homogenen Mischkristallen schon ohne Vorhandensein von Zugspannungen erfolgt. Dies wird auf eine Erhöhung des Reaktionsvermögens der Großwinkel-Korngrenzen als Folge der Mischkristallbildung zurückgeführt, die experimentell nachgewiesen wird. Dieser “Mischkristall-Effekt” mit Maximum bei 50 At.-% führt jedoch bei Einwirkung chemischer Agentien allein noch nicht zu interkristalliner bzw. Spannungskorrosion, sondern nur bei gleichzeitigem Auftreten eines elektrochemischen Prozesses. Es wird gezeigt, daß ein solcher unter gewissen Voraussetzungen auch bei homogenen Mischkristallen möglich ist. Bezüglich der Rolle der Zugspannungen wird gezeigt, daß ihre Wirkung lediglich darin besteht, plastische Verformungen hervorzurufen, denn unmittelbar während einer plastischen Verformung, d. h. “in statu deformandi”, wird das Reaktionsvermögen von Mischkristallen ganz beträchtlich erhöht, wofür ebenfalls experimentelle Beweise erbracht werden.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 719-722 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 699-715 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Galvanic Corrosion of Cast Iron and Brass Ms 60 in Acids, in the Absence and Pressence of Inhibitors II.Experiments show that the galvanic corrosion process is largely independent of corrosion caused by local cells. Inhibitors suppress only the effect of the local cells. The amount of galvanic corrosion in acid solutions is usually less than 1% of the total corrosion. The proportion of galvanic corrosion is increased only by the addition in inhibitors, because the corrosion caused by local cells is then supressed much more than the galvanic corrosion. Mixtures of inhibitors give greater protection than single substances. The nature of the charge on the inhibitor ions has little influence, because inhibition occurs both at the anode and at the cathode of the galvanic couple irrespective of the charge on the inhibitor ions. The effects observed can be explained by the theory which postulates an insulating pin-cushion inhibitor film. The results again support the inhibitor theory of W. Machu.
    Notes: Versuche zeigten, daß die galvanische Korrosion weitgehend unabhängig von der durch Lokalelemente hervorgerufenen vor sich geht. Inhibitoren hemmen praktisch nur die Tätigkeit der Lokalelemente. Der Anteil der galvanischen Korrosion an der Gesamtkorrosion ist in Säuren nur gering, meist kleiner als 1%. Nur bei guter Hemmungswirkung steigt der prozentuale Anteil der galvanischen Korrosion an, da die Korrosion durch Lokalelemente durch die Inhibitoren stärker verringert wird als die nur wenig verringerte galvanische Korrosion. Gemische von Inhibitoren schützen besser als Einzelstoffe. Der Ladungssinn der Inhibitorteilchen hat nur wenig Einfluß, da unabhängig vom Ladungssinn des Inhibitorteilchens Hemmungswirkungen sowohl an der Kathode als auch an der Anode der Metallkombination auftreten. Als Erklärung der beobachteten Erscheinungen wird die nadelkissenartige, isolierend wirkende Deckschicht der Inhibitoren herangezogen. Die Versuche stellen eine erneute Bestätigung der Inhibitortheorie von W. Machu dar.
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 723-727 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 727-728 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 729-730 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 731-731 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 733-735 
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 735-736 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 736-739 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Keywords: Chemistry ; Polymer and Materials Science
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