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  • Inorganic Chemistry  (3,865)
  • Chemical Engineering  (1,794)
  • 1970-1974  (5,659)
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  • 1
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Generalized depletion curves for desorption (and Corresponding breakthrough curves for adsorption) were calculated for systems characterized by the Langmuir-type multicomponent equilibrium equation and controlled by the film type rate model. In contrast with adsorption where the nonkey (or less strongly adsorbed) component curves display overshoots above feed concentration, in desorption the key component depletion curves exhibit the instabilities in the form of inflections and curvatures. As in the one component case, the differences in the depletion and breakthrough curves may be related to the rate phenomena. The undulations in the key component depletion curves may be characterized by derivatives of the rate data. The major significance of these instabilities is to elongate the depletion curves, which in turn requires the expenditure of added effort during regeneration. Process modifications are indicated, which could suppress the instabilities. The predicted trends were confirmed by experimental depletion curves.
    Additional Material: 12 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 1139-1147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Generalized depletion curves for desorption (and breakthrough curves for adsorption) were calculated for a system characterized by the Langmuirtype equilibria and controlled by a film type rate model. The depletion points generally appear sooner than the corresponding breakthrough points, and the desorption profiles are significantly broader than the corresponding adsorption curves. These phenomena may be best explained in terms of the prevailing driving forces. The effects of adsorbate properties and operating variables (inlet composition and flow rate) were established and experimentally substantiated.
    Additional Material: 16 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 112-119 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A modified Redlich-Kwong equation has been applied to the calculation of phase equilibria in multicomponent systems. The two parameters of the Redlich-Kwong equation are treated as temperature functions. They are obtained for each pure component from experimental vapor pressures and liquid densities with the help of a generalized fugacity coefficient correlation for saturated vapors. The need to submit coefficients for pure components is thus eliminated. At least one experimental vapor-liquid equilibrium point is required to establish an interaction constant for each binary system. Applications have been made to binary and multicomponent systems containing hydrocarbons, hydrogen, carbon dioxide, and hydrogen sulfide.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 1792-1796 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Glycosides of Amino Sugars, II. Synthesis of 2-amino-2-deoxy-α-D-glucopyranosidesThe synthesis of glycosides and disaccharides of 2-amino-2-deoxy-D-glucose has been explored using trifluoroacetyl as the N-blocking group. Because of its high tendency for neighboring group participation only β-D-glycosides were formed. The corresponding α-disaccharide could be obtained as the main product when employing 2.4-dinitrophenyl as the N-protecting group.
    Notes: Die N-Trifluoracetyl-Schutzgruppe wurde zur Synthese von Glykosiden und Disacchariden der 2-Amino-2-desoxy-D-glucose benutzt. Sie zeigte eine hohe Tendenz zur Nachbargruppen-beteiligung unter Bildung von -β-D-Glykosiden. Das entsprechende α-Disaccharid wurde als Hauptprodukt bei Verwendung der N-2.4-Dinitrophenyl-Schutzgruppe erhalten.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2424-2427 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Di- and Polyamino Sugars, XV. XIV. Mitteil.: W. Meyer zu Reckendorf, Tetrahedron Letters [London] 1970, 287. Synthese der 2.4-Diamino-1.6-anhydro-2.4-dideoxy-D-talose. Synthesis of 2,4-Diamino-1,6-anhydro-2,4-dideoxy-D-taloseDehydrogenation of the amino reductone 1 with iodine yields a triulose which is isolated as the phenylhydrazone-phenylazo derivative 2. Spontaneous cyclization of 2 forms the 1.6-anhydro compound 3. On hydrogenation 2as well as 3are transformed into the title compound.
    Notes: Die durch Dehydrierung des Aminoreduktons 1 mit Jod entstehende Triulose wird als Bis-phenylhydrazon 2 isoliert, das die Konstitution eines Phenylhydrazon-benzolazo-Derivates besitzt. 2 cyclisiert leicht zur 1.6-Anhydro-Verbindung 3, die, wie auch 2, bei der katalytischen Hydrierung die Titelverbindung liefert.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2418-2423 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Elimination Reactions of a Pyranose Enolacetate. A Pyranose Amino ReductoneThe α-azidoketone 1 is easily transformed either directly or via the enolacetate 2 into the vinylogous amide 4 which on acid treatment yields 8. 4 and 8 show the typical reactions of reductones. On reduction 8 yields derivatives of 2-amino-2-deoxy-D-allose only.
    Notes: Das α-Azido-keton 1 geht leicht direkt oder über das Enolacetat 2 in das vinyloge Säureamid 4 über, Aus dem mit Säure 8 entsteht. 4 und 8 zeigen die typischen Reaktionen von Reduktonen. Bei der Reduktion gibt 8 ausschließlich Derivate der 2-Amino-2-desoxy-D-allose.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 869-875 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Glycosides of Amino Sugars, IV. Synthesis of Disaccharides of 2-Amino-2-deoxy- and 3-Amino-3-deoxy-D-glucoseThe solvent dependency of the Koenigs-Knorr reaction between two derivatives of 2-amino-2-deoxy-D-glucose (3 and 4) was investigated. The highest yield of the α-disaccharide 5 was obtained in the system toluene/1,2-dimethoxyethane. The condensation of two derivatives of 3-amino-3-deoxy-D-glucose (11 and 13) under similar conditions yielded the 1,6-linked α-and β-disaccharides (15, 14) of this sugar which were unknown until now.
    Notes: Die Koenigs-Knorr-Reaktion zwischen zwei Derivaten der 2-Amino-2-desoxy-D-glucose (3 und 4) wurde in Abhängigkeit vom Lösungsmittel untersucht. Die höchste Ausbeute an α-Disaccharid 5 konnte in einem Gemisch von Toluol und 1,2-Dimethoxyäthan erhalten werden. Die Kondensation zweier Derivate der 3-Amino-3-desoxy-D-glucose (11 und 13) unter ähnlichen Bedingungen führte zu den bisher unbekannten 1,6-verknüpften α- und β-Disacchariden (15 bzw. 14) dieses Zuckers.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 1188-1194 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Di- and Polyamino Sugars, XX. Synthesis of 2,3,4,6-Tetraamino-2,3,4,6-tetradeoxy-D-glucoseThe title compound has been prepared by introduction of two amino functions into the molecule of 2,3-diamino-2,3-dideoxy-D-glucose. Instead of the free sugar we obtained mainly the pyrrolidine 17.
    Notes: Die Titelverbindung wurde durch Einführung von zwei Stickstoff-Funktionen in die 2,3-Diamino-2,3-didesoxy-D-glucose dargestellt. Anstelle des freien Zuckers erhielten wir hauptsächlich das Pyrrolidin 17.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 2585-2600 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Glycosides of Amino Sugars, V. Synthesis of Disaccharides of 2,3-Diamino-2,3-dideoxy-D-glucose, IOn dinitrophenylation with 1-fluoro-2,4-dinitrobenzene 2,3- diamino-2,3-dideoxy-D-glucose preponderantly yields the 1,2,3-trisubstituted derivative 5 the structure of which was proved by several methods. The N,N′-dinitrophenyl derivative 2 could be obtained from the glycoside 17 and was converted into the bromide 19. On reaction with a derivative of 3-azido-3-deoxy-D-glucose (24) 19 yielded the α- and β-disaccharides 25 and 27.
    Notes: 2,3-Diamino-2,3-didesoxy-D-glucose-dihydrochlorid liefert bei der Dinitrophenylierung mit 1-Fluor-2,4-dinitrobenzol überwiegend das 1,2,3-Trisubstitutionsderivat 5. dessen Konstitution auf mehreren Wegen bewiesen wurde. Das über das Glycosid 17 erhältliche N,N′-Dinitrophenylderivat 2 konnte in das Bromid 19 übergeführt und dieses mit einem Derivat der 3-Azido-3-desoxy-D-glucose 24 zum α- und β-Disaccharid 25 bzw. 27 verknüpft werden.
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  • 10
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 13 new complex salts of the [Cr(NCS)4(p-anisidine)2]- have been synthesized and the solvation kinetics of this anion has been studied in ethanol-water mixtures. The first two NCS- ions are exchanged for water molecules. In acid solutions the rate of this reaction is not influenced by the solvent composition.In parallel with this reaction, p-anisidine molecules are substituted, too, by ethanol molecules. (Acceleration by hydrogen ions.) In the resulting complex ion the first two NCS- ions are substituted, too, by water molecules. The rate constants of this reaction are rather close to those of the reaction which leads to the exchange of the first two NCS- ions in the initial complex. The third and fourth NCS- ions are substituted only in neutral solutions by water molecules. Kinetic parameters have been derived for the substitution of the first two NCS- ions and for the substitution of the p-anisidine molecules.
    Notes: Es wurden 13 neue Komplexsalze mit den Anion [Cr(NCS)4(p-Anisidin)2]- dargestellt und die Solvatationskinetik dieses Anions in Äthanol-Wasser-Mischungen untersucht. Danach kann man die folgende Reaktionsschemata annehmen. Die ersten zwei NCS--Ionen werden gegen Wassermolekeln ausgetauscht. In sauren Lösungen wird die Geschwindigkeit dieser Reaktion nicht von der Lösungsmittelzusammensetzung beeinflußt. Parallel zu dieser Reaktion werden die p-Anisidinmolekln gegen Äthanol ausgetauscht. Diese Reaktion wird durch Wasserstoffionen beschleunigt. In den entstehenden Komplexionen sind die ersten zwei NCS--Ionen ebenfalls gegen Wasser ausgetauscht. Die Geschwindigkeitskonstanten dieser Reaktion sind von der gleichen Größenordnung wie die Geschwindigkeitskonstanten der Reaktion, die zum Austausch der ersten zwei NCS--Ionen aus dem ursprünglichen Komplexion führt. Die dritten und vierten NCS--Ionen werden nur in neutralen Lösungen gegen Wasser ausgetauscht. Kinetische Parameter für den Austausch der ersten zwei NCS--Ionen und der p-Anisidinmolekeln wurden ermittelt.
    Additional Material: 8 Ill.
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