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  • Polymer and Materials Science  (15,307)
  • 1975-1979  (13,298)
  • 1950-1954  (2,009)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 8 (1977), S. 344-353 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Influence of Hydrostatic Pressure on the Mechanical Properties of Hardened Rolling Bearing Steel 100 Cr6The paper describes the influence of hydrostatic pressure on the mechanical properties of differently heat-treated rolling bearing steel 100Cr6 based on the triaxial stressing in elements in rolling contact. It is illustrated that hydrostatic pressure superposed on tension changes the data of the tension test depending on the state of the material. While the yield point is not influenced by the pressure, the resistance to fracture and the ductility considerably increase under pressure the increase under pressure being dependent on the heat treatment. The test results show that an optimum adjustment of the heat treatment is possible only if the test conditions reflect the real field conditions. Finally, the applicability of some of the results to the behaviour of material in rolling contact is discussed.
    Notes: Ausgehend von der mehrachsigen Beanspruchung in Wälzelementen durch den Überrollungsvorgang wird der Einfluß eines hydrostatischen Druckes auf die mechanischen Eigenschaften des unterschiedlich gehärteten Wälzlagerstahls 100Cr6 beschrieben. Es wird gezeigt, daß ein dem Zugversuch überlagerter Druck die Kenngrößen des Zugversuches je nach vorliegendem Werkstoffzustand unterschiedlich verändert. Während die Elastizitätsgrenze vom Druck unabhängig ist, steigen Bruchfestigkeit und plastische Verformbarkeit unter Druck erheblich an, wobei die Zunahme dieser Größen durch den Druck von der Wärmebehandlung abhängt. Die Versuchsergebnisse belegen, daß eine exakte Optimierung der Wärmebehandlung nur unter wirklichkeitsgleichen Versuchsbedingungen möglich ist. Abschließend wird versucht, einige der ermittelten Ergebnisse auf das Verhalten des Werkstoffs bei der Wälzbeanspruchung zu übertragen.
    Additional Material: 18 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 14 (1976), S. 339-346 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
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  • 3
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Influence of Microstructure on Mechanical Properties of (α + β)-Ti-AlloysThe amount of α- and β-phase in (α + β)-Titanium alloys for example in the alloy TiAl6 V4 may be altered to a large extend by annealing procedures. In the alloy TiAl6 V4 each temperature corresponds to a certain amount of each of these phases, the composition of which is also dependent on annealing temperature. Above about 970 °C the homogeneous β-phase appears. Additions of Iron, Oxygen, Nitrogen and Hydrogen have a great influence on the transition temperature and the distribution of the α- and β-phase. There is a great influence of the distribution of the phases on the mechanical properties. The β-phase and the α-solid solution can be quenched from high temperature and decomposed at a lower temperature, so that intermediate phases as ω from β and α2 from α may be precipitated. The α-solid solution is anisotropic so that texturized samples have different properties in various directions. Based on these fundamental aspects it is shown to what extend these microstructures may influence the mechanical properties especially the fatigue behaviour of (α + β)-Ti-alloys.
    Notes: Die Anteile des α- und β-Titanmischkristalls in (α + β)-Titanlegierungen können z. B. bei der Legierung TiAl6 V4 in großen Bereichen durch Wärmebehandlung variiert werden. Bei jeder Temperatur stellt sich z. B. bei TiAl6 V4 ein bestimmtes Verhältnis zwischen α und β ein, wobei sich die Legierungskonzentration in den einzelnen Phasenanteilen ändert, bis oberhalb etwa 970 °C die reine β-Phase vorliegt. Beimengungen wie Eisen, Sauerstoff, Stickstoff und Wasserstoff verändern die Umwandlungstemperatur und auch die Anteile der jeweiligen Phasen. Die mechanischen Eigenschaften werden durch das Gefüge entscheidend beeinflußt. Sowohl der β-Mischkristall wie auch der α-Mischkristall können von hoher Temperatur abgeschreckt und bei tiefen Temperaturen zum Zerfall gebracht werden, so daß dadurch weitere Zwischenphasen, wie die ω-Phase im β-Mischkristall und die α2-Phase im α-Mischkristall ausgeschieden werden. Der α-Mischkristall weist eine starke Anisotropie auf, so daß mit Textur behaftete Proben eine Richtungsabhängigkeit der mechanischen Eigenschaften aufweisen. Ausgehend von diesen Grundlagen wird gezeigt, wie sich diese Gefügezustände auf die mechanischen Eigenschaften insbesondere bei schwingender Beanspruchung auswirken.
    Additional Material: 22 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 49 (1977), S. 669-669 
    ISSN: 0009-286X
    Keywords: Porosimetrie ; Porenvolumen ; Zwischenkontakträume ; Porenstruktur ; vakuumdichte Keramik ; Aluminiumoxid ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 13 (1975), S. 717-736 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study designed to ascertain the role of singlet molecular oxygen in the photodegradation of plastics established that most classes of dye chromophores are sensitizers in polymer films, absorbing light and transferring the absorbed energy to ambient triplet ground state molecular oxygen, generating metastable reactive singlet molecular oxygen. Unsaturated polymers containing polybutadiene, polyisoprene, etc. are highly reactive to singlet oxygen produced through photosensitization, generating hydroxylic and carbonyl derivatives and losing their rubbery properties as consequences of such reactions. Many types of transition metal chelates are singlet oxygen quenchers. The relationships of the structures and spectroscopic properties of these chelates to their efficiency in quenching singlet oxygen are examined and discussed.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 13 (1975), S. 993-1014 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method based on infrared spectral changes in thin films was devised and used to evaluate the relative effectiveness of various types of additives on photodegradative processes in an olefinically unsaturated polymer. Nickel chelates of the thiobisphenol-amine complex type are shown to be quantitatively more effective in retarding the photodegradation of these polymers than other additives having greater singlet oxygen quenching efficiencies, ultraviolet absorption, or radical antioxidant properties. Photosensitization with a singlet oxygen sensitizer (fluoranthene) rapidly produces degradative effects in the polymer which are identical with those of its direct degradation by light. The sensitized effects are also retarded by the nickel chelates. Photosensitization by a hydrogen atom-abstracting sensitizer (a benzophenone) proved considerably less effective. The effectiveness of the nickel complexes appears to be due to a combination of their ability to quench singlet oxygen and precusor excited states and their relative stability under photoexposure conditions.
    Additional Material: 14 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 2871-2878 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of temperature on the storage modulus G′ of UV crosslinked collagen has been investigated. Collagen solutions, 0.5%, at pH 2.2 were irradiated at 4°C to a maximum modulus, after which they were stored at 4°C. In order to study the effect of temperatures above 4°C, the gels were placed in a constant-temperature bath and the change in modulus with time was recorded using a torsion pendulum. The temperatures studied ranged from 25° to 60°C. The results show an initial jump in modulus immediately on heating presumably due to the helix-coil transition. The modulus goes through a maximum value. There is then a decay of modulus with time which is linear on a semilog plot. This could indicate a first-order chain-scission reaction, since the storage modulus is directly proportional to the number of crosslinks. A simple kinetic expression can be written for which the value of the rate constant can be determined from the data.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 66 (1978), S. 75-93 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Makroporöse Perl-Terpolymere aus Methacrylaldehyd, Methylmethacrylat und äthylendimethacrylat wurden hergestellt. Die Polymerisationsbedingungen (Zusammensetzung der Monomermischung und der inerten Phase, die Konzentration an Initiator und an Suspensionsstabilisator, Rühregeschwindigkeit) werden im Hinblick auf die Eigenschaften der Terpolymeren (Porosität und Konzentration an reaktiven Aldehydgruppen) diskutiert.Die Konzentration an reaktiven Gruppen wurde durch Zugabe des dritten Monomeren variiert. Die analytisch bestimmten Unterschiede in der Konzentration an reaktiven Gruppen im Monomerengemisch und im Polymeren werden interpretiert (a) durch Unerreichbarkeit der Gruppen im Innern der Substanz, (b) durch Bildung von Tetrahydropyranringen und Acetatbin lungen zwischen den Ketten und (c) duch Bildung von extrahierbaren Polymeren und Copolymeren sowie nichtumgesetzten Anteilen an Monomeren.
    Notes: Bead macroporous terpolymers of methacrylaldehyde with methyl methacrylate and ethylene dimethacrylate were prepared. Preparation conditions (composition of the monomer mixture, of the inert components, concentration of the initiator and of the suspension stabilizer, and the rate of stirring) were discussed with respect to the properties of the terpolymers (porosity and concentration of reactive aldehyde groups).Concentration of reactive groups in the polymer was controlled by adding a third monomer. The analytically determined differences in the concentration of the reactive groups in the batch and in the polymer were interpreted (a) by the inaccessibility of the groups within the polymer bulk (for polymers with 30-50 mol-% of crosslinking agent), (b) by the presence of tetrahydropyran rings or acetate bonds between the chains, and (c) by the formation of extractable soluble polymers or copolymers, or by not reacting of parts of the monomers (observed predominantly with low-crosslinked polymers containing 10 mol-% of crosslinking agent).
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 16 (1978), S. 317-319 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 16 (1978), S. 1399-1407 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The diffusion coefficient of butane in linear polyethylene at room temperature as a function of the vapor pressure of butane was measured by the spin-echo method with a pulsed magnetic field gradient. For the Special morphology of randomly oriented stacks of parallel lamellas the detour factor is 1/3. As long as the blocking factor and migration through the lamellas can be neglected, the local diffusion coefficient Da of the small molecules through the amorphous layers in the direction parallel to the lamellas is three times the apparent diffusion coefficient D derived from the decay of the amplitude of the spin echo under the assumption of an infinitely extended homogeneous medium. The diffusion coefficient and the spin-spin relaxation time both increase exponentially with increasing pressure, i.e., butane concentration in the polymer, while the spin-lattice relaxation time is pressure independent and seems to be determined by interaction with the amorphous polyethylene matrix.
    Additional Material: 5 Ill.
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