ISSN:
1600-5767
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Geosciences
,
Physics
Notes:
(±)Rh(en)3(SCN)3 and (+)Rh(en)3(SCN)3, Rh(C2H8N2)3.(SCN)3, C6H24N6Rh.C3N3S3, crystallize in orthorhombic cells. The lattice constants are respectively a = 14.652 (5), b = 14.268 (6), c = 17.480 (6) Å and a = 14.711 (4), b = 13.481 (3), c = 9.166 (2) Å. They are isomorphic with their homologues (±)Co(en)3(SCN)3 and (−)Cr(en)3(SCN)3. The active racemate [(+)Rh(en)3(+)Cr(en)3](SCN)6 is isomorphic with the monoclinic form of [(+)Co(en)3(−)Cr(en)3](SCN)6. Its lattice constants are a = 15.707 (5), b = 17.739 (4), c = 9.426 (3) Å and γ = 131.04 (2)°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0021889880012526
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