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  • Inorganic Chemistry  (3,415)
  • Q
  • 1985-1989  (3,420)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 125 (1987), S. 1039-1050 
    ISSN: 1420-9136
    Keywords: Q ; volcanic earthquakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract CodaQ for Etna volcano is frequency dependent and theQ frequency pattern and the numerical values ranging from about 100 at 1 Hz to about 300 at 18 Hz are similar to the values obtained for other volcanoes: Campi Flegrei, Aeolian Islands and Hawaii. Moreover the frequency pattern and the numerical values of coda quality factor, for most of the seismically active zones of Italy are very different from those of the volcanic zones. Several studies of the location of magma chambers show the presence of magma pockets beneath Lipari and Vulcano Islands of the Aeolian archipelago and an anomalous low velocity body beneath Etna. These evidences suggest that a possible interpretation of the characteristic frequency pattern ofQ on volcanic areas is that the presence of magma can modify the scattering environment and consequently the codaQ estimates.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 131 (1989), S. 703-713 
    ISSN: 1420-9136
    Keywords: Attenuation ; viscoelastic material ; rheological models ; complex modulus ; stored and dissipated energies ; Q
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The attenuation properties of eight rheological models have been studied theoretically. The expressions forQ have been obtained by using dissipated and stored energies and/or complex modulus for each model. The dependence ofQ on frequency has been demonstrated. The three-element elastic model appears to be the best one to represent the viscoelastic nature of the earth's material for a finite value ofQ.
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  • 3
    ISSN: 1420-9136
    Keywords: Q ; code waves ; volcanic earthquakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Digital recordings of three component microearthquake codas from shallow seismic events in the volcanic region of Campi Flegrei — Southern Italy — were used with an automatic technique to calculate the attenuation factorQ c (codaQ) in the hypothesis of singleS toS backscattering. Results show the same value ofQ for each of the three components. This result is interpreted as due to isotropicS wave radiation pattern. A check of the coda method was performed using a single station method based on simple assumptions on the direct SH wave spectrum. Single stationQ was averaged over the stations and over the earthquakes. Results show that the two methods lead to comparable results. A frequency dependence quite different from that evaluated in active tectonic regions was found for coda attenuation, comparable to other volcanic areas throughout the world. This is interpreted as due to the presence of magma that affects anelasticity and scattering.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 127 (1988), S. 581-605 
    ISSN: 1420-9136
    Keywords: Q ; surface waves ; crust ; upper mantle
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Fundamental-mode Rayleigh wave attenuation data for stable and tectonically active regions of North America, South America, and India are inverted to obtain several frequency-independent and frequency-dependentQ β models. Because of trade-offs between the effect of depth distribution and frequency-dependence ofQ β on surface wave attenuation there are many diverse models which will satisfy the fundamental-mode data. Higher-mode data, such as 1-Hz Lg can, however, constrain the range of possible models, at least in the upper crust. By using synthetic Lg seismograms to compute expected Lg attenuation coefficients for various models we obtained frequency-dependentQ β models for three stable and three tectonically active regions, after making assumptions concerning the nature of the variation ofQ β with frequency. In stable regions, ifQ β varies as ωξ, where ζ is a constant, models in which ζ=0.5, 0.5, and 0.75 satisfy fundamental-mode Rayleigh and 1-Hz Lg data for eastern North America, eastern South America, and the Indian Shield, respectively. IfQ β is assumed to be independent of frequency (ζ=0.0) for periods of 3 s and greater, and ζ is allowed to increase from 0.0 at 3 s to a maximum value at 1 s, then that maximum value for ζ is about 0.7, 0.6, and 0.9, respectively, for eastern North America, eastern South America, and the Indian Shield. TheQ models obtained under each of the above-mentioned two assumptions differ substantially from one another for each region, a result which indicates the importance of obtaining high-quality higher-mode attenuation data over a broad range of periods. Tectonically active regions require a much lower degree of frequency dependence to explain both observed fundamental-mode and observed Lg data. Optimum values of ζ for western North America and western South America are 0.0 if ζ is constant (Q β is independent of frequency), but uncertainty in the Lg attenuation data allows ζ to be as high as about 0.3 for western North America and 0.2 for western South America. In the Himalaya, the optimum value of ζ is about 0.2, but it could range between 0.0 and 0.5. Frequency-independent models (ζ=0.0) for these regions yield minimumQ β values in the upper mantle of about 40, 70, and 40 for western North America, western South America, and the Himalaya, respectively. In order to be compatible with the frequency dependence ofQ observed in body-wave studies,Q β in stable regions must be frequency-dependent to much greater depths than those which can be studied using the surface wave data available for this study, andQ β in tectonically active regions must become frequency-dependent at upper mantle or lower crustal depths.
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  • 5
    ISSN: 1572-9591
    Keywords: fusion plasmas ; neutral beams ; neutrons ; Q ; TFTR ; tokamaks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We report measurements of the fusion reaction rate in the Tokamak Fusion Test Reactor (TFTR) covering a wide range of plasma conditions and injected neutral-beam powers up to 6.3 MW. The fusion neutron production rate in beam-injected plasmas decreases slightly with increasing plasma density ne, even though the energy confinement parameter neτE generally increases with density. The measurements indicate and Fokker-Planck simulations show that with increasing density the source of fusion neutrons evolves from mainly beam-beam and beam-target reactions at very low ne to a combination of beam-target and thermonuclear reactions at high ne. At a given plasma current, the reduction in neutron source strength at higher ne is due to both a decrease in electron temperature and in beam-beam reaction rate. The Fokker-Planck simulations also show that at low ne, plasma rotation can appreciably reduce the beam-target reaction rate for experiments with coinjection only. The variation of neutron source strength with plasma and beam parameters is as expected for beam-dominated regimes. However, the Fokker-Planck simulations systematically overestimate the measured source strength by a factor of 2–3; the source of this discrepancy has not yet been identified.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 240-245 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Influence of Substituents on the Enthalpy, Entropy and Volume of Activation in the Decomposition of Organic PerestersThe influence of the ester group on the decomposition of organic peroxides was studied on peresters of the pivalic and neodecanoic acid with tert-butyl, tert-amyl, 1-methyl-1-propylpentyl and 1,1,4-trimethylpentyl groups at temperatures of 393 to 473 K and pressures up to 3000 bar using a flow method. As expected the half-live times decrease with increasing temperature and increase with rising pressure. With increasing bulkiness of the substituents the rates of decomposition as well as the enthalpies of activation increase. This surprising fact can be explained by the simultaneous increase of the entropies and the volumes of activation.
    Notes: Der Einfluß der Estergruppe auf den Zerfall organischer Peroxide wurde an Perestern der Pivalin- und der Neodecansäure mit tert-Butyl-, tert-Amyl-, 1-Methyl-propylpentyl- sowie 1,1,4-Trimethylpentylresten bei Temperaturen von 393 bis 473 K und Drücken bis 3000 bar in einer Strömungsapparatur untersucht. Die Zerfallshalbwertszeiten nehmen erwartungsgemäß mit steigender Temperatur stark ab und mit steigendem Druck zu. Mit zunehmender Größe der Substituenten steigen sowohl die Zerfallsgeschwindigkeiten als auch die Aktivierungsenthalpien. Dieser überraschende Effekt kann durch die Vergrößerung der Aktivierungsentropie und des Aktivierungsvolumens erklärt werden.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 313-322 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Lewis Acidity of Nickel(0), III. Alkali Metal Hydridotrialkylaluminate Complexes of Ni(CDT)Ni(CDT) reacts with hydridotrialkylaluminates of the alkali metals in ether/THF or ether/amine mixtures at temperatures below -50°C to form the temperature-sensitive compounds [MA(n-Donor)n]+[R3Al—H—Ni(CDT)]- (1-7) (MA = Li, Na; R = Me, Et, iBu). An Al—H—Ni three-centre bond is present in these complexes. On the basis of NMR data, the strength of the hydridoaluminate-nickel bond and the charge on nickel, caused by the hydridoaluminate residue, are compared with the corresponding characteristics of other ligand-Ni(CDT) complexes in which donor-acceptor σ-bonds are present.
    Notes: Ni(CDT)Abkürzungen: CDT = trans, trans, trans-1,5,9-Cyclododecatrien, COD = 1,5-Cyclooctadien, MA+ (solvatisiertes) Alkalimetall-Ion, PMDTA = N,N,N′,N″N″-Pentamethyldiethylentriamin, TMEDA = N,N,N′,N′-Tetramethylethylendiamin. reagiert mit Alkalimetall-hydridotrialkylaluminaten in Ether/THF-oder Ether/Amin-Mischungen als Lösungsmittel unterhalb von -50°C zu den thermisch labilen Verbindungen [MA(n-Donor)n]+[R3Al—H—Ni(CDT)]- (1-7) (MA = Li, Na; R = Me, Et, iBu). In diesen Komplexen liegt eine Al—H—Ni-Mehrzentrenbindung vor. Anhand NMR-spektroskopischer Daten lassen sich die Stärke der Hydridoaluminat-Nickel-Bindung und die Beladung des Nickels durch den Hydridoaluminat-Rest mit den Bindungsverhältnissen in anderen Ligand-Ni(CDT)-Komplexen mit Donor-Akzeptor-σ-Bindungen vergleichen.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 275-297 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Lewis Acidity of Nickel(0), I. Methyllithium Complexes of Nickel(0)The synthesis and properties of the methyllithium complexes of nickel(0) of the type (n-Donor)m-(LiCH3)Ni0(π-Ligand)n (1a-c, 16a-c, 20a-c) [n-Donor = chelating amine or THF; π-Ligand = CDT, ethene, or CO] are described. The structure of (PMDTA)(LiCH3)Ni(C2H4)2 (1b) has been determined by X-ray crystallography.  -  In these ate complexes, a carbanionic methyl group is σ-bonded to a nickel atom, the acceptor strength of which depend on the π-ligands. The chemical and spectroscopic properties indicate that the Ni—CH3 bond in the carbonyl complex is largely covalent whereas in the CDT and ethene compounds it is more polar. The CDT complex is thermolabile in solution. The findings are in agreement with the following series of increasing acceptor strength: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Notes: Es wird über die Synthese und Eigenschaften der Methyllithium-Komplexe von Nickel(0) (n-Donor)m(LiCH3)Ni0(π-Ligand)n Wir bezeichnen mitπ-Liganden solche Liganden, die als π-Akzeptoren mit einem Übergangsmetallatom dπ—pπ—oder dπ—dπ-Rückbindungen auszubilden vermögen (Alkene, CO, auch Phosphane);n-Donoren solche Liganden, die als „harte Basen“ (Ether, Amine) über ihre freien Elektronenpaare vornehmlich Hauptgruppenmetall-Ionen, d.h. „harte Säuren“ komplexieren;σ-Donoren solche Liganden, die  -  ohne über Akzeptororbitale zu verfügen  -  entweder polare Bindungen enthalten und Mehrzentrenbindungen eingehen können (Metallalkyle und -hydride) oder ein freies Elektronenpaar bereitstellen (Carbanionen, Phosphorane, Hydrid-Ion), wobei σ-Bindungen zu einem niederwertigen Übergangsmetallatom ausgebildet werden. (1a-c, 16a-c, 20a-c) mit Chelataminen oder THF als n-Donoren und CDTAbkürzungen: CDT = trans,trans,trans-l,5,9-Cyclooctadien; COT = Cyclooctatetraen; PMDTA = Pentamethyldiethylentriamin; TMEDA = Tetramethylethylendiamin; MA+A = Alkalimetall- bzw. quartäres Ammonium-Kation., Ethen oder CO als π-Liganden berichtet. Die Struktur von (PMDTA)(LiCH3)Ni(C2H4)2 (1b) wurde röntgenographisch bestimmt.  -  In diesen at-Komplexen ist eine carbanionische Methylgruppe über eine σ-Bindung an ein Nickelatom gebunden, dessen Akzeptorstärke von den π-Liganden abhängt. Chemische und spektroskopische Eigenschaften der Komplexe lassen für CDT oder Ethen als π-Liganden auf vergleichsweise polare, für den CDT-Komplex in Lösung dazu thermolabile Ni—CH3-Bindungen schließen, während für den Carbonyl-Komplex aufgrund von 13C-NMR-Daten eine überwiegend kovalente Ni—CH3-Bindung anzunehmen ist. Die Befunde stehen mit folgender Reihe zunehmender Akzeptorstärke im Einklang: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 620-633 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Correspondence of Heteroatom-stabilized Carbocations and the Cycloheptatriene-Norcaradiene EquilibriumThe effects of alkoxyiminium substituents on the cycloheptatriene-norcaradiene equilibria 1 ⇄ 2 have been investigated. Due to the energetics two classes of compounds were found (ΔH° 〈 0, and ΔH° 〉 0). The transfer of the substituent effect from carbocation to carbocyclus is inhibited by a p-phenylene group. From 1H and 13C NMR spectra at variable temperatures thermodynamic parameters are deduced and correlated with σR-constants obtained from 19F NMR spectroscopy. By extrapolation, the enthalpy difference for the unsubstituted cycloheptatriene and norcaradiene is calculated as 9.3 kcal/mol.
    Notes: Der Einfluß von Alkoxyiminium-Substituenten an C-7 auf die Lage des Cycloheptatrien-Norcaradien-Gleichgewichts 1 ⇄ 2 wird untersucht. Auf Grund der Energetik gibt es Verbindungen, bei denen Temperaturabsenkung eine Verschiebung des Gleichgewichts zum Norcaradien (ΔH° 〈 0) ergibt, bei anderen Beispielen ist ΔH° 〈 0. Eine p-Phenylenbrücke zwischen Kation und Carbocyclus blockiert den Substituenteneffekt. Aus den 1H- und 13C-NMR-Spektren bei verschiedenen Temperaturen wurden thermodynamische Daten ermittelt und mit den durch 19F-NMR bestimmten σR-Konstanten korreliert. Durch Extrapolation konnte die Enthalpiedifferenz des unsubstituierten Cycloheptatriens und Norcaradiens zu 9.3 kcal/mol abgeschätzt werden.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 661-669 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Hydratisierte Oxokohlenwasserstoffe, IV. Silylierung von 1,1-Dihydroxy-VerbindungenDie Anwendung von verschiedenen Silylierungsreagenzien auf mono- und polyvicinale 1,1-Di-hydroxy-Verbindungen wurde untersucht. Mit einigen dieser Reagenzien konnten aus Ninhydrin (2) und Rhodizonsäure (17) die entsprechenden geminalen Bis(trimethylsilyloxy)-Derivate 1 und 20 gewonnen werden. Während 1 leicht zu Hexamethyldisiloxan und Indantrion (4) fragmentiert, ist 20 thermisch relativ stabil, es gibt pyrolytisch bei 500°C nur Spuren des Tetraketons 21 ab. Andere Silylierungsreagenzien bewirken unerwartete C-Alkylierung oder C-Amidierung am Dihydroxykohlenstoff. Silylierungen von Perhydroxycyclobutan und -cyclohexan führen zu Ringaufspaltungs- bzw. Verengungsprodukten.
    Notes: The action of various silylating agents on mono- and polyvicinal 1,1-dihydroxy compounds has been investigated. Some of these reagents converted ninhydrin (2) and rhodizonic acid (17) into the corresponding geminal bis(trimethylsilyloxy) derivatives 1 and 20, respectively. Compound 1 readily fragments to form hexamethyldisiloxane and indantrione (4). The rhodizonic acid derivative 20 is, however, rather stable and even on pyrolysis at 500°C gives only traces of the tetraketone 21. With other silylating agents unexpected C-alkylation or C-amidation at the dihydroxy carbon is observed. Silylation of perhydroxycyclobutane and -cyclohexane leads to ring opened and contracted products.
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