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  • Polymer and Materials Science  (16,437)
  • Wiley-Blackwell  (16,437)
  • 1985-1989  (16,437)
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  • Wiley-Blackwell  (16,437)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Copolymerization of cationic monomers with acrylamide in an aqueous solution (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 29-36 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The radical copolymerizations of commercially available cationic monomers (M1) with acrylamide (M2) have been investigated at pH 6.1 in aqueous solutions. The cationic groups in copolymers were analyzed by a colloid titration method and the reactivity ratios were determined by the Fineman-Ross method. The values of r1 and r2 were 1.71 and 0.25 for methacryloyloxyethyltrimethylammonium chloride—M2, 1.68 and 1.26 for N,N-dimethylaminoethylmethacrylate—M2, 1.13 and 0.57 for methacrylamidopropyltrimethylammonium chloride—M2, 1.10 and 0.47 for N,N-dimethylaminopropylmethacrylate—M2, 0.47 and 0.95 for N,N-dimethylaminopropylacrylamide—M2, 0.48 and 0.64 for acryloyloxyethyltrimethylammonium chloride-M2, and 0.58 and 6.7 for dimethyldiallylammonium chloride-M2 systems. The Alfrey-Price Q and e values were calculated and the linear relationship between log Q and ultraviolet absorption maxima of cationic monomers was found.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240103
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  • 2
    Electronic Resource
    Electronic Resource
    Functional polymers and sequential copolymers by phase-transfer catalysis. 16. Influence of sequence distribution on the mesomorphic properties of thermotropic copolyethers containing 4,4′-dihydroxybiphenyl (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 15-27 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Random and alternating thermotropic liquid-crystalline copolyethers have been synthesized from 4,4′-dihydroxybiphenyl and a 1/1 mol ratio of 1,5-dibromopentane and α,ω-dibromoalkanes by a two-phase (organic solvent-aqueous NaOH) phase-transfer-catalyzed polyetherification. Random copolyethers were prepared from α,ω-dibromoalkanes having six to twelve methylene units. Their phase behavior was compared with those of the perfectly alternating copolyethers containing five methylene units in one spacer and eight, nine, or eleven methylene units in the other, respectively. An odd-even dependence in thermal transitions has been observed in both oligomeric systems. In all cases, alternating copolyethers, even though comparatively lower in molecular weight, have given rise to higher melting and isotropization temperatures. Since the increase in the melting temperature is larger than the increase in the isotropization temperature, the thermal stability range of the mesophase has narrowed for alternating copolyethers with respect to their random copolyether counterparts.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240102
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  • 3
    Electronic Resource
    Electronic Resource
    Chemistry of alkenyl azlactones. VII. Preparation and properties of multiazlactones derived from mercaptan-functional compounds and oligomers (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1-14 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of polymercaptans and 2-alkenyl azlactones has been further investigated, and several new multiazlactones which are liquids at room temperature have been prepared and characterized. Michael addition yielding the multiazlactones was found to take place slowly in the absence of and rapidly in the presence of acid catalysts. If basic impurities capable of forming mercaptide ion were present, however, the reaction underwent a substantially different course producing primarily ring-opened products. A source of these basic impurities was determined to be the method of preparation of the alkenyl azlactone itself. When the azlactone was prepared from its acyclic N-substituted aminoacid precursor by cyclodehydration by use of ethyl chloroformate and triethylamine, a small amount of triethylamine remained that dramatically altered the course of reaction. Nonbasic cyclodehydration agents such as dicyclohexylcarbodiimide were effective at eliminating this side reaction, as well as was the practice of adding excess acid to the reaction system to neutralize the basic impurities.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240101
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  • 4
    Electronic Resource
    Electronic Resource
    Carbazole substituted N-acylated linear polyethylenimines (PEI). synthesis and characterization of poly[N-(9-carbazolyl)acetylethylenimine] and poly[N-(2-(9-carbazolyl))propanoylethylenimine] (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 37-60 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of carbazola substituted N-acylated polyethylenimines, namely, poly[N-(9-carbazolyl)acetylethylenimine] 20 and poly[N-(2-(9-carbazolyl))propanoylethylenimine] 21 by a grafting reaction onto PEI and isomerization polymerization of the carbazole substituted 2-oxazolines is reported. A complete acylation of amino groups in PEI by the 9-carbazolylacetyl groups was achieved by the p-nitrophenyl active ester method but PEI was only partially N-acylated by the 2-(9-carbazolyl)propanoyl groups under similar reaction conditions. The carbazole substituted 2-oxazolines, namely, 2-(9-carbazolyl)methyl-2-oxazoline 18 and (R,S)-2-[1-(9-carbazolyl)]ethyl-2-oxazoline 19, were prepared by a base induced cyclization of ß-chloroamides. The ring-opening isomerization polymerization of 18 and 19 in the molten state with a cationic initiator (dimethyl sulfate, methyl triflate, or ethylene glycol ditosylate) gave 20 and 21. Gel permeation chromatography of 20 and 21 obtained with different monomerto-initiator ratios gave evidence of a chain transfer reaction with the monomer. The polymers were characterized by elemental analyses, IR, and 1H-NMR spectroscopy.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240104
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  • 5
    Electronic Resource
    Electronic Resource
    Syntheses of stereoregular and optically active polyamides from active 4-chloro-1-benzotriazolyl diesters and diamines (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 75-85 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new route to prepare optically active polyamides was established, based on the polycondensation of two new active diesters: the active diesters of 4-chloro-1 hydroxybenzotriazole, such as 1,1'-(terephthaloyldioxy)bis(4-chloro-benzotriazole), and 1,1'-(isophthaloyldioxy)bis(4-chlorobenzotriazole), with optically active isomers of 2,4-diaminopentane. Dipolar aprotic solvents such as N,N-dimethylformamide and dimethyl sulfoxide were used as reaction solvents. The solution polycondensation carried out in solution at room temperature afforded optically active polyamides. The aminolysis of the two active diesters was carried out as a model reaction study.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240106
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  • 6
    Electronic Resource
    Electronic Resource
    Permeation control of ionic fluorescent probes by ambient pH changes from nylon capsule membranes depending on their microstructuresPreliminary report: T. Seki and Y. Okahata, Macromolecules, 17, 1880 (1984). Functional Capsule Membranes 20. Part 19 of this series: Y. Okahata, K. Ariga and T. Seki, J. Chem. Soc., Chem. Commun., 920 (1985). (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 61-73 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Permeations of water-soluble, ionic fluorescent probes from a large, ultrathin nylon-2,12 capsule membrane were largely affected by the ambient pH of the outer medium; permeations of cationic and anionic probes were accelerated by a factor of 50-100 in the basic and acidic medium, respectively, relative to that in the neutral-pH region. The permeation of NaCl and nonionic fluorescent probes was hardly affected by the ambient pH. The nylon capsule membrane was elucidated to have an asymmetrical structure: the dense-thin inner layer and the porous-thick outer part. The pH-sensitive permeation could be explained due to the ionization of a small amount of residual end-groups (COOH and NH2) existing in the dense-thin inner layer of the nylon capsule membrane.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240105
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  • 7
    Electronic Resource
    Electronic Resource
    Cationic polymerization of p-methylstyrene initiated by acetyl perchlorate: An approach to living polymerization (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 87-96 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The cationic polymerization of p-methylstyrene initiated by acetyl perchlorate at -78°C led to long-lived (living-like) polymers with a narrow molecular weight distribution (M̄w/M̄n = 1.1-1.4) in methylene chloride containing a common ion salt (n-Bu4NClO4) or in a less polar solvent (CH2Cl2/toluene, 1/4v/v). Under these conditions, the number-average molecular weight (M̄n) of the polymers increased in proportion to monomer conversion and was regulated by the monomer-to-initiator ratio. When fresh feeds of the monomer were repeatedly added to a completely polymerized solution, the polymerization ensued at the same rate as before and the linear increase in M̄n with monomer conversion continued. The effects of solvent polarity and the common ion salt on the polymerization showed the suppression of the ionic dissociation of the propagating species, resulting in a “nondissociated species,” to be the key factor for the formation of the long-lived polymers.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240107
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  • 8
    Electronic Resource
    Electronic Resource
    Preparation of aromatic polyesters by direct polycondensation with thionyl chloride in pyridine (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 97-102 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mechanistic features of the reaction with thionyl chloride in pyridine were studied in a model reaction of benzoic acid with p-chlorophenol or aniline. The yields were significantly affected by the amounts of pyridine, favorably by four equivalents, and the nature of pyridine, suggesting that pyridines are not only HCl scavengers, but are also involved in the reaction itself. The reaction was assumed to proceed via a carboxylic sulfinic-anhydride intermediate different from acyl chloride, and the intermediate was found to be not so reactive that it was completely alcoholyzed by the phenol at high temperatures of more than 60°C. The reaction was successfully applied to the preparation of aromatic polyesters of high molecular weights by the direct polycondensation of aromatic dicarboxylic acids and bisphenols in pyridine at 80°C.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240108
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  • 9
    Electronic Resource
    Electronic Resource
    Preparation of silicon-containing polymers IV. Thermally stable organosilicon poly-1,2,4-triazoles (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 103-107 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Novel silicon-containing poly-1,2,4-triazoles have been synthesized by the reaction of polyhydrazide precursors and aniline in polyphosphoric acid (PPA) at 260°C. The polyhydrazide intermediates were prepared from aromatic dihydrazides and silicon-containing acid dichlorides via interfacial polycondensation. These polymers and their intermediates were characterized by infrared spectroscopy (IR), solubility, and by solution viscosity. The thermal behavior of these polytriazoles has been studied by dynamic thermogravimetry.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240109
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  • 10
    Electronic Resource
    Electronic Resource
    Determination of molecular weight distribution of nylon 12 by gel permeation chromatography (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 109-118 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Molecular weight distribution of Nylon 12 was determined with hexafluoroisopropanol/toluene mixture as eluent by gel permeation chromatography. Calibration curve for Nylon 12 was easily obtained from that of polystyrene because the method of universal calibration was applicable among these polymers. The molecular weight distributions of Nylon 12 were always broader than expected by the theory of polymerization, i.e., most probable distribution. This result was not caused by broadening effect in gel permeation chromatography, but by polymerization itself.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240110
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  • 11
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    Electronic Resource
    Functional monomers and polymers. CXIX.For part CXVIII, see J, Liu, K. Kondo, and K. Takemoto, Makromol. Chem., 185, 2125 (1984). Synthesis and photochemical reaction of polymethacrylate derivative containing 6-cyanouracil (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 119-132 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A polymethacrylate derivative containing 6-cyanouracil was prepared, and its photochemical reaction was studied. The 6-cyanouracil derivative was found to show high reactivity for the photochemiccal reaction. The photochemical-reaction product was identified as a cyclobutanetype photodimer, and the photodimer was formed in high yield even from the monomeric compound of 6-cyanouracil under UV irradiation in low concentration. The quantum yield of the photodimerization of the 6-cyanouracil derivative was greater than that of the thymine derivative. The photodimerization of the 6-cyanouracil derivative could not be quenched by usual triplet quenchers, but was found to be quenched by the polymeric derivative of adenine, suggesting a specific interaction.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240111
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  • 12
    Electronic Resource
    Electronic Resource
    Synthesis of poly dithioesters and cyclization to 1, 3-dithiolium (dithiafulvenium) salts (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 147-153 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Piperidinium dithiobenzoate and piperidinium tetrathioterephthalate react with α-halo carbonyl compounds to give small molecules and polymers which, upon dehydrative cyclization with H2SO4, yield materials containing the 1,3-dithiolium ring. Maximum yields are obtained by use of phase-transfer techniques and the solvent system H2O/CH2Cl2. The cyclized polymers are soluble in sulfuric acid, and films can be made from (CF3)2 CHOH solutions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240113
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  • 13
    Electronic Resource
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    Polymers of ortho-vinylbenzaldehyde (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 133-145 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ortho-vinylbenzaldehyde has been prepared in a three-step synthesis. Vacuum-degassed monomer was polymerized with azodiisobutyronitrile initiator in bulk and in solution in 2-butanone. The kp/kt1/2 value at 60°C is 4.7 × 10-2 L1/2 mol-1/2s-1/2. This is about twice the ratio for styrene. Chain transfer to monomer appears to be significant. Insoluble, crosslinked products were produced at high conversions, because of chain transfer to polymer. Tg of poly(ortho-vinylbenzaldehyde) was found to be 142°C.Polymers made under N2 atmosphere often contained acetal groups. These can be produced by acid catalysis in the presence of small concentrations of ortho-vinylbenzyl alcohol. A laddertype structure is produced.The monomer is capable of photoinitiation. Insoluble gels were produced in bulk monomer at all conversions. The initiation rate was very high and crosslinking resulted from combination of radicals produced from photolysis of the pendant 0-benzaldehyde groups in the macromolecules.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240112
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  • 14
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    Novel optical resolution of an unprotected adenine derivative followed by grafting the pendant onto polyethylenimine (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 167-171 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240115
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  • 15
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    Cationic polymerization initiated by intercalation compounds of lewis acids. II. Initiating ability and mechanism of action of the initiatorsFor the first article of the series see Ref. 7. (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 155-165 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The initiating ability of the graphite intercalation compounds (GICs) of SbCl5, FeCl3, and AlBr3 was investigated. It was found that GICs were able to initiate the polymerization of monomers of different types-cyclosiloxanes, 1,2-epoxides, vinyl ethers, lactones, and vinyl monomers. GICs of SbCl5 initiated also the polymerization of tetrahydrofuran. The interaction of the monomers (with the exception of the lactones) caused a size increase of the GICs and deformations in their lamellar structure. Relatively high-molecular poly(vinyl ethers) and polydimethylcyclosiloxanes were obtained. The mechanism of action of GICs was discussed.
    Additional Material: 4 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240114
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  • 16
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    Boron-nitrogen polymers. I. Mechanistic studies of borazine pyrolyses (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 173-185 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Pyrolyses of B-triamino-N-triphenyl-, B-triamino-N-trimethyl-, and B-trianilino-borazines were performed between 150 and 300°C. Initial stages of degradation were accompanied by liberation of ammonia in addition to the expected aniline or methylamine; this was most pronounced for the methyl borazine. Aniline elimination proceeded more readily with the B-anilino than the B-amino isomer. Data obtained support a ring opening mechanism resulting in telomerizaton accompanied by aniline liberation and formation first of singly then doubly bridged dimers and finally doubly bridged tetramers. Thermal exposure up to 1000°C failed to give pure boron nitride; carbon was invariably retained.
    Additional Material: 4 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240116
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  • 17
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    Preparation of polyamides and polyesteramides by the direct polycondensation with tosyl chloride and N-methylimidazole (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 187-189 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240117
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  • 18
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    Radical grafting from carbon black by carbon black having hydroxy methyl group/ceric ion redox system (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 191-194 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240118
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  • 19
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    Radical copolymerization of γ-methylene-Δα,β-butenolide derivative: ethyl(E)-5-OXO-2,5-dihydrofuran-2-ylidene-acetate (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 197-202 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Radical polymerications including co- and terpolymerizations of a γ-methylene-Δα,β-butenolide derivative, ethyl (E)-5-oxo-2,5-dihydrofuran-2-ylideneacetate(EODY) was investigated. The monomer had no homopolymerizability but copolymerized with styrene (ST) and 1,3-cyclohexadiene to yield alternating copolymers. From IR and 1H-NMR spectra of the copolymers, the 1,4-addition was confirmed to exclusively occur for the conjugated double bond of EODY. Terpolymerization for the system involving an acceptor monomer such as maleic anhydride, α-chloromaleic anhydride, or 7,7,8,8-tetracyanoquinodimethane in addition to ST and EODY gave the terpolymer containing about 50 mol% of ST, in spite of a high fraction of ST in the feed. It was inferred that such an apparent behavior of EODY as an acceptor monomer could be due to a resonance-stabilization of the propagating radical having EODY as a terminal unit, which is also responsible for the poor yields of the copolymers and terpolymers.
    Additional Material: 3 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240201
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  • 20
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    Synthesis and characteristics of microspheres of polystyrene derivatives (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 203-213 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two sytrene derivatives formylstyrene and styrene sulfonylcholoride, were synthesized. Polymeric microspheres in diameters ranging from 0.1 to 2 μm were synthesized by polymerization of chlormoethylstyrene, formylstyrene, and styrene sulfonylcholoride in organic solvents, in the presence of appropriate surfactants. The kinetics of microsphere formation were studied. The molecular weight distribution of the products was determined by gel permeation chromatography. Conditions for binding various amino ligands to the microspheres were also established.
    Additional Material: 4 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240202
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  • 21
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    Photolabeling studies of polymer-cell surface interaction. Evaluation of 3-[(4-azidophenyl)dithio]propionic acid as a polymer-bound photolabel (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 241-253 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-[(4-Azidophenyl)dithio]propionic acid (1a) was prepared in four steps from 4,4′-diamino-diphenyldisulfide. Attachment of 1a to poly[(3-hydroxypropyl)oxirane] was accomplished under very mild conditions via an acid-catalyzed caarbodiimide coupling. Photolysis of polymer-bound 1a with an electronic flash unit proceeded without detectable disulfide bond cleavage. Mild reduction of the disulfide bond of an analogue of 1a which carried no azido group confirmed that 1a should be useful in photolabeling studies of polymer-cell surface interaction.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240204
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    Synthesis of polyamide containing optically active thymine derivative as a grafted pendant (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 269-278 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new route to polyamides containing optically active thymine groups as pendants has been established. The method is based on the grafting of (-) and (±)-2-(thymin-1-yl)propionic acid [(-) and (±) TPA] onto a polyamide containing hydroxyl groups. The hydroxy polyamide was prepared by selective N-acylation of an active diester of N-hydroxy-5-norborene-2,3-dicarboxamide (HONB), N,N'-(isophthaloyl-dioxy)-bis(5-norbornene-2,3-dicarboximide) (IPBONB), with 1,3-diamino-2-hydroxypropane (AHP). Model compounds (-) and (±)-(1,3-dibenzoylamino-2-propyl)2-(thymin-1-yl)propionate[(-) and (±) (BAPTP)] were prepared by direct, low-temperature esterification before synthesizing the polymer.
    Additional Material: 5 Ill.
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    Polymerization of para-xylylene derivatives (parylene polymerization). III. Heat effects during deposition of parylene N at different temperatures (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 215-240 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal effects accompanying the vacuum deposition of poly-para-xylene (Parylene N) at different temperatures have been studied by following the changes in the temperature of the substrate. Similarly to the case of polychloro-para-xylylene (Parylene C), two distinct exothermic effects were observed; one discrete, resulting in sharp exothermic spikes and the other continuous, resulting in the shift of the baseline. The spike effect, attributed to the solid-state polymerization of para-xylylene, is observed at the low-temperature range, the upper limit of which moves higher for higher deposition rates. The shift of a baseline as a function of deposition temperature exhibits two maxima, one independent of deposition rate and the second moving toward higher temperatures (that is, toward the first maximum) for higher deposition rates. First maximum falls at about —72°C and is attributed to the melting point of para-xylylene crystals. X-ray diffraction studies of polymer samples have shown that the existence of the second maximum is always followed by the appearance of an additional crystalline phase in the respective range of deposition temperatures. When the deposition rate is high enough, the second maximum merges with the first one, or virtually disappears. Under such conditions the new crystalline phase is no more detectable. It is postulated that the evolution of the additional amount of heat resulting in the appearance of the second maximum is due to the cyclization reaction and the formation of cyclic oligomers. This reaction very likely requires a particular spatial arrangement of monomer molecules and, therefore, it is suggested to take place in certain domains of the crystalline lattice.
    Additional Material: 10 Ill.
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    Polynuclear and halogenated structures in polyphenylenes synthesized from benzene, biphenyl, and p-terphenyl under various conditions: Characterization by laser desorption/fourier transform mass spectrometry (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 255-267 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyphenylenes made by reaction of benzene, biphenyl, or p-terphenyl with metal halide catalyst-oxidant systems are complex mixtures of dissimilar oligomers, which include halogenated and polynuclear structures, according to positive and negative-ion laser desorption/Fourier transform mass-spectral analyses. Polymerization of benzene with metal-chloride salts that terminate chain elongation by chlorination of the end rings appears to decrease formation of polynuclear structures by providing a competing pathway for chain termination. Polynuclear structures occur to a greater extent with oligomerization of biphenyl than with benzene, presumably because of isomerization and increased opportunity for π overlap during propagation. Electrical conductivities of polyphenylenes made by various routes should not be discussed solely in terms of the linear poly(p-phenylene) structure.
    Additional Material: 6 Ill.
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    An ESCA and plasma emission study of the plasma polymerization of 1-fluoronaphthalene and octafluoronaphthalene (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 279-286 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240207
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    Correlation of thermal degradation mechanisms: Polyacetylene and vinyl and vinylidene polymers (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 301-316 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The thermal degradation of poly(vinyl bromide) (PVB), poly(vinyl chloride) (PVC), poly(vinyl alcohol) (PVA), poly(vinyl acetate) (PVAc), poly(vinyl fluoride) (PVF), poly(vinylidene chloride) (PVC2), and poly(vinylidene fluoride) (PVF2) has been studied by direct pyrolysis-mass spectrometry (DP-MS) and flash pyrolysis-gas chromatography-mass spectrometry techniques. Vinyl and vinylidene polymers exhibit two competitive thermal degradation processes: (1) HX elimination with formation of polyene sequences which undergo further moleculaar rearrangements, and (2) main-chain cleavage with formation of halogenated or oxigenated compounds. The overall thermal degradation process depends on the prevailing decomposition reaction in each polymer; therefore, different behaviors are observed. The thermal degradation of polyacetylene (PA) has also been studied and found important for the elucidation of the thermal decomposition mechanism of the title polymers.
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    Preparation and structural characterization of poly(4-vinylphenylacetate-co-maleic anhydride) (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1487-1495 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(4-vinylphenylacetate-co-maleic anhydride) was synthesized by free-radical initiation to yield a 1:1 copolymer over a 0.2-0.8 mole fraction range of monomer feed in maleic anhydride. Evidence of 1:1 charge transfer complex between 4-vinylphenylacetate and maleic anhydride was obtained in the UV region at 355 nm. The 13C NMR chemical shifts and 1H NMR integration data indicate that poly(4-vinylphenylacetate-co-maleic anhydride) has an alternating and stereoregular structure. The molecular weight of poly(4-vinylphenylacetate-co-maleic anhydride) was controlled by using specific solvents and initiator concentrations.
    Additional Material: 3 Ill.
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    Monomer-isomerization polymerization. XXI.Part XX of this series is ref. 14.. Monomer-isomerization copolymerization of 3-methyl-1-butene and 2-pentene with ziegler-natta catalyst (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1505-1510 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-Methyl-1-butene (3M1B) was found to undergo monomer-isomerization copolymerization with 2-pentene (2P) in the presence of Ziegler-Natta catalyst to give a copolymer exclusively consisting of 3M1B and 1-pentene (1P) units, the same as that obtained from copolymerization of 3M1B and 1P. The apparent copolymerization parameters were determined. The amount of 3M1B unit incorporated in the copolymers was found to increase in the copolymerization system of 3M1B-2P more than in that of 3M1B-1P. The polymers consisting of nearly complete 3M1B units were produced at a rapid rate through monomer-isomerization copolymerization of 3M1B with 2P in the presence of TiCl3 - (C2H5)3Al catalyst.
    Additional Material: 2 Ill.
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    URL: http://dx.doi.org/10.1002/pola.1986.080240708
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    Preparation of conducting copolymers by oxidative electropolymerization of 2,2′-bithiophene with pyrrole (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1529-1537 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Various feed ratios of 2,2′-bithiophene (BT) and pyrrole (PY) were electropolymerized to low conversion and the polymers analyzed for their mer ratios. The polymeric product was rich in polypyrrole (PPY), but the composition could be varied by control of the electrode potential. The increase in BT content is not linear with composition, and the physical evidence indicates oxidative copolymerization and not the formation of the two homopolymers. The data can be interpreted on a copolymerization equation despite the absence of steady state conditions. Sets of reactivity ratios were determined for the polymers formed at two potentials. The electrical efficiencies for polymer formation approach stoichiometric values for oxidative polymerization.
    Additional Material: 3 Ill.
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    Synthesis of N-substituted phenoxazine polymers bearing vinyl backbone (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1565-1575 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vinyl monomers bearing N-substituted phenoxazine or 2,8-dimethylphenoxazine units were synthesized starting with the corresponding phenoxazines. N-substituents were 2-vinylbenzyl-oxycarbonylethyl group prepared via 2-carboxyethyl group, 3-methacrylamido-, 3-acrylamido-, or 3-(4-styrenesulfonamido)-propyl group prepared via 3-aminopropyl group, vinylbenzyl, or 2-vinyloxyethyl group attached by the displacements of sodium salts of the phenoxazines to the chlorides, and 2-methacryloyl- or 2-acryloyl-oxyethyl group prepared via 2-hydroxyethyl group. Free-radical polymerixations of these novel monomers proceeded smoothly, except those with 2-vinyloxyethyl group, which were susceptible to BF3-etherate. Changes of the visible absorption spectrum of iodine in THF with addition of the monomers and polymers were considerable, with the appearance of new absorption peaks or shoulders in major cases.
    Additional Material: 2 Tab.
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    Selective separation of water-ethanol mixture through synthetic polymer membranes having carboxylic acid as a functional group (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1585-1597 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Separation of water-ethanol mixture through a membrane was carried out by pervaporation using a membrane which provided a hydrogen-bonding interaction. A membrane obtained from poly(acrylic acid-co-acrylonitrile) was effective for a selective separation of water from aqueous ethanol solution by pervaporation technique. Spectroscopic and flux analyses verified that this high selectivity toward water was attributed to the hydrogen-bonding interaction between water and acrylic acid (carboxylic acid) unit in the membrane. On the other hand, a membrane from poly(acrylic acid-co-styrene) preferentially permeated ethanol in the low water feed concentration region.
    Additional Material: 9 Ill.
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    Thermal properties of nylons containing carbonyl groups (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1657-1674 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nylons containing carbonyl groups in backbone chains were prepared and their response to heat was studied. The carbonyl groups were introduced using either HOOC(CH2)4CO(CH2)4COOH or H2N(CH2)5CO(CH2)5NH2 in the initial monomer compositions. In addition to pyrolysis of these polyamides, the progress of chemical and physical changes as a function of temperature was continuously monitored and analyzed by FT-IR spectroscopy on cast films placed in an environmental chamber. Introduction of the carbonyl groups into the polymer backbone resulted in a significant reduction of the thermal stability of the corresponding polyamide. Possible mechanisms for the thermal degradation entailing these carbonyl groups and N-acylamide compounds are discussed.
    Additional Material: 14 Ill.
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    Synthesis and properties of semiconducting aromatic polyquinonediimines (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1703-1716 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new class of poly-conjugated polymers has been obtained by condensation of anthraquinones with aromatic diamines in polyphosphoric acid. The polymers are black, intractable powders. Toward obtaining tractable materials, the effect of monomer structure on polymer tractability has been studied. Copolymerizations were also carried out to “soften” these materials. Electrical conductivities in the semiconducting range, 10-4- 10-8 (ohm cm)-1 were observed. Doping with iodine showed small increases.
    Additional Material: 1 Ill.
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    Evolution of H2O and CO2 during the copper-catalyzed oxidation of isotactic polypropylene (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 389-403 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics and mechanism of H2O and CO2 evolution during uncatalyzed and copper(oxide)-catalyzed (Cu, CuO, CuO0.67) oxidation of isotactic polypropylene have been investigated in detail for various catalysts over a range of temperatures (90-150°C). These volatiles were determined chromatographically; H2O and CO2 represent the main volatiles of the oxidation, comprising about 80 mol % of all volatiles. Uncatalyzed oxidation evolves ca. 1 mol of H2O and 1 mol of CO2 for each unit mole of polymer oxidized, while catalyzed oxidation produces 2 mol of H2O and ca. 1.2 mol of CO2 for each unit mole of polymer. These results indicate that secondary as well as tertiary H atoms on the polymer chains are involved in hydroperoxide formation and decay. The oxidation mechanism has been formulated and evaluated on this basis. It consists essentially of two parallel oxidation reactions involving tertiary and secondary groups (H atoms and hydroperoxides), respectively. The mechanism can be represented by first- and pseudo-first-order reactions in series: (1) oxygen absorption showing induction periods; (2) hydroperoxide formation and decay (plateaus are reached); (3) H2O evolution from the decay of hydroperoxides; and (4) subsequent CO2 production involving chain scission. Arrhenius parameters for all oxidation reactions (uncatalyzed and catalyzed) are also presented. It appears that CuO0.67 is the most efficient catalyst of those investigated.
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    Kinetics of reaction of methyl α-eleostearate with phenol (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 469-481 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of addition reactions between methyl α-eleostearate which forms the main chain of tung oil and phenol when catalyzed by an acid, p-toluene sulfonic acid, have been studied. The addition reactions, carried out with phenol was shown to be second order with regard to methyl α-eleostearate concentration and first order with regard to phenol concentration. The reactions were additions of two phenol molecules to one methyl α-eleostearate molecule, and it was presumed that they proceed in the two steps given below in which the first step is rate determining: (1)\documentclass{article}\pagestyle{empty}\begin{document}$ 2{\rm E} + {\rm P} \to [{\rm X}]({\rm intermediate}) $\end{document} (2)\documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} [{\rm X}] + 3{\rm P} \to 2{\rm P - E - P} \\ \left( {_{{\rm P : phenol}}^{{\rm E : methyl }\alpha {\rm - eleostearate}} } \right) \\xb \end{array} $$\end{document} The apparent reaction rate constant (l/mol min) was found to be 0.036 and its value was nearly equal to that in the case of m-cresol. The apparent activation energie (kcal/mol) was found to be 4.76 and its value was larger than that in the case of m-cresol.
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    Monomer-isomerization polymerization. XXIII.For Part XXII of this series see Ref. 1.. Monomer-isomerization polymerization of 5-phenyl-2-pentene with ziegler-natta catalysts (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1633-1642 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5-Phenyl-2-pentene (5Ph2P) was found to undergo monomer-isomerization polymerization with TiCl3-R3Al (R = C2H5 or i-C4H9, Al/Ti 〉 2) catalysts to give a polymer consisting of exclusively 5-phenyl-1-pentene (5Ph1P) unit. The geometric and positional isomerizations of 5Ph2P to its terminal and other internal isomers were observed to occur during polymerization. The catalyst activity of alkylaluminum examined to TiCl3 was in the following order: (C2H5)3Al 〉 (i-C4H9)3Al 〉 (C2H5)2AlCl. The rate of monomer-isomerization polymerization of 5Ph2P with TiCl3-(C2H5)3Al catalyst was influenced by both the Al/Ti molar ratio and the addition of nickel acetylacetonate [Ni(acac)2], and the maximum rate was observed at Al/Ti = 2.0 and Ni/Ti = 0.4 in molar ratios.
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    Semiconducting polymers via the high temperature free radical polymerization of multinitriles (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1675-1683 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerizability of a variety of mono- and multi- nitriles in the presence of free radical initiators at high temperature is determined by the concentration of available cyano-groups. Mononitriles do not polymerize, but multinitriles do so readily. If alkyl substituents are introduced in a molecule that easily polymerizes, this concentration and the ability to polymerize are lowered; if several or bulky substituents are introduced, the polymerization is completely prevented. Multinitriles containing ester groups undergo decarbomethoxylation in these polymerizations. The polymers are black and highly insoluble. From the few reactions that were attempted on these polymers, we can conclude that the structure is probably not the simple conjugated imine structure proposed by earlier investigators, but more experiments are needed to prove this point. The black polymers had conductivities less than 10-9 Ω-1 but, after heating at 700°C, conductivities in the range from 10-3 to 10-6 Ω-1 are observed.
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    Polymerization of 1-(trimethylsilyl)-1-propyne homologs containing two silicon atoms by tantalum- and niobium-based catalystsPart 6 of “Polymerization of Heteroatom-Containing Acetylenes.” For part 5, see ref 1. (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1839-1848 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymerization of new 1-(trimethylsilyl)-1-propyne homologs containing two silicon atoms [CH3C≡CSi(CH3)2CH2Si(CH3)3 and CH3C≡CSi(CH3)2CH2CH2Si(CH3)3] was investigated by use of Ta and Nb catalysts. CH3C≡CSi(CH3)2CH2Si(CH3)3 was polymerized quantitatively by TaCl5 alone to provide a polymer having molecular weight over 106. CH3C≡CSi(CH3)2CH2CH2Si(CH3)3 was polymerized in good yield by an equimolar mixture of TaCl5 with an appropriate organometallic cocatalyst such as Ph4Sn to give a polymer with molecular weight of ca. 4 X 105. Nb catalysts were less active toward these monomers than the corresponding Ta catalysts. These two kinds of polymers had alternating double bonds along the main chain according to IR and 13C-NMR spectra. Both polymers were white solids completely soluble in low-polarity solvents like toluene, and solution casting afforded uniform, tough films. These polymers were thermally fairly stable, and their softening points were above 350°C. Films of these polymers showed smaller oxygen permeability coefficients [Po2 = 4 × 10-9 - 8 × 10-9 cm3(STP) · cm/(cm2·sec·cmHg)] but larger separation factors [(Po2/Po2) = 3.4 - 3.6] than a poly[1-(trimethylsilyl)-1-propyne] film.
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    Photolysis of aromatic diisocyanate-based polyurethanes in solution (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1879-1894 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fluorescence analysis has been employed as an analytical technique to elucidate the photolysis mechanism of several aromatic diisocyanate-based polyurethanes in solution. Based on a comparison with model arylmonocarbamates and arylbiscarbamates, the photo-Fries rearrangement and cleavage-type products found for the small-model arylcarbamates were also identified for the photolyzed polyurethanes in solution. Viscosity and absorbance change results for photolysis of both air and nitrogen-saturated polyurethane solutions are consistent with a general two-step mechanism for the photolysis of aromatic diisocyanate-based polyurethanes.
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    Synthesis of polyurea by direct polycondensation of 4-aminophenyl ether with lithium carbonate (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1915-1921 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyureas of high molecular weight were obtained by the direct polycondensation of 4-aminophenyl ether with lithium carbonate in the presence of triphenylphosphine (Ph3P), hexachloroethane (C2Cl6), and pyridine. Reaction conditions, such as the molar ratios of Ph3P and C2Cl6 to the monomers, monomer concentrations, reaction temperatures, reaction times, and kind of solvents, had a significant effect on the yield and the molecular weight of the resulting polyureas. The polyurea having the highest solution viscosity of 0.91 dL/g was obtained with the molar ratio of Ph3P/C2Cl6/monomers = 2.4/2/1 in the mixed solvent of N-methyl-2-pyrrolidone and pyridine at 80°C.
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    Characterization of large water-soluble macromolecules by size exclusion chromatography (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1829-1838 
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    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method for characterizing very large, water-soluble polymers by size exclusion chromotography (SEC) has been developed. Sephacryl S1000 packing material, a precision syringe pump, and an eluent pressure detector have been utilized to produce highly accurate chromatograms of polymers having molecular hydrodynamic diameters up to 250 nm. Previous SEC analysis has been limited to polymers having hydrodynamic diameters of less than 120 nm.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240807
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  • 42
    Electronic Resource
    Electronic Resource
    FT-IR study of the stabilization reaction of polyacrylonitrile in the production of carbon fibers (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1989-1995 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The stabilized fibers prepared by heating PAN and a PAN copolymer in air and under reduced pressure have been examined by FT-IR spectroscopy in order to determine their chemical structures. Three kinds of reactions, cyclization, dehydrogenation, and oxygen uptake are found to occur almost simultaneously in the stabilization process in air by digital difference spectrum method. The effect of the comonomer is confirmed to accelate the dehydrogenation reaction and also the formation of acridone ring in the thermal stabilization in air by kinetic study.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240819
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  • 43
    Electronic Resource
    Electronic Resource
    Effect of a graft polymerized graft as a spacer for an insoluble polymer ligand (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 2027-2031 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240823
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  • 44
    Electronic Resource
    Electronic Resource
    Synthesis of acryloyl-type polymer fixing 5-fluorouracil residues through D-glucofuranoses and its antitumor activity (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 2059-2074 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acryloyl-type polymer fixing 1-β-carbonylethyl-5-fluorouracil residues through D-glucofuranoses via ester bonds was synthesized by means of polymerization of the corresponding monomer and polymer reaction. In order to provide the water-soluble objective polymer, the copolymerization of the acryloyl-type monomer with acrylamide was carried out. The extent of release of 5-FU residues from the copolymer was investigated in the enzyme or nonenzyme system in vitro. Furthermore, the antitumor activities of the water-insoluble homopolymer and water-soluble copolymer obtained were tested in vivo.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240903
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  • 45
    Electronic Resource
    Electronic Resource
    Resolution of wide-angle x-ray scattering from a thermoplastic composite (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 2101-2105 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wide-angle x-ray scattering from a polyetheretherketone/carbonaceous fiber composite has been resolved using a curve-fit procedure. This resolution yielded under curve areas for crystalline, amorphous, and fiber scatter which could be used as the basis for an estimation of crystallinity.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240906
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  • 46
    Electronic Resource
    Electronic Resource
    Synthesis and characterization of fluorescently labelled poly(vinyl acetate) particles (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1895-1913 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nonaqueous dispersions of poly(vinyl acetate) particles stabilized with poly(2-ethylhexyl methacrylate) and labelled with fluorescent dyes in the core and stabilizer polymer phases were prepared. The materials were characterized using a broad range of techniques (NMR, UV, and fluorescence spectroscopy. GPC, particle sizing, and DSC). The data show that dispersion polymerization of vinyl acetate in the presence of stabilizers containing certain fluorescent dye derivatives, instead of unlabelled stabilizer, results in changes in the mean particle size, size distribution, composition, and molecular weights of the colloidal polymer particles. It was found that increasing the amounts of fluorescent groups in the stabilizer resulted in smaller mean particle sizes and larger amounts of irreversibly attached stabilizer. When the average number of labels in stabilizer exceeded one per chain, a new ultra-high molecular weight polymer fraction appeared. The fluorescence spectra for several of these materials are reported. We describe how fluorescence decay curves can be used to assess block formation and local phase separation in particles labelled with phenanthrene groups. These materials are intended to be used for more detailed studies by fluorescence spectroscopy. Those results will be published in due course.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240812
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  • 47
    Electronic Resource
    Electronic Resource
    Radiation-induced graft polymerization of acrylamide I. Preparation conditions and gel determination for polyethylene-grafted films (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1933-1942 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Radiation-induced graft polymerization of acrylamide (AAm) onto low-density polyethylene(LDPE) film has been investigated. The appropriate reaction conditions at which the graft polymerization was carried out successfully were selected. It was observed that the grafting process was enhanced remarkably by using distilled water as diluent. In this grafting system ammonium ferrous sulphate (Mohr's salt) was used as inhibitor to minimize the homopolymerization of AAm and the suitable concentration of such inhibitor was found to be 3 wt %. The dependence of the grafting rate on the monomer concentration was calculated to be 2.9 order, regardless of the irradiation atmosphere (N2 gas or under vacuum). When the radiation grafting process was carried out under vacuum, higher degrees of grafting were obtained as compared to those in nitrogen gas or in air atmosphere. Network structure was formed in the graft copolymer and the gel formation was determined in the p-xylene-extracted grafted films. Results showed good evidence that the grafting process takes place by the front mechanism.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240815
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  • 48
    Electronic Resource
    Electronic Resource
    Synthesis of dihydroxamic acid chelating polymers and the adsorptive property for uranium in sea water (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1953-1966 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preparation of new chelating polymers bearing dihydroxamic acid groups and the adsorptive ability for uranium in sea water are described. Chloromethylated polystyrene crosslinked with divinylbenzene was treated with diethyl malonate in N, N-dimethylformamide to give the polymer having diethyl malonate groups. This polymer was then treated with hydroxylamine in methanol to afford the dihydroxamic acid polymer. The presence of hydroxamic acid groups was confirmed by the appearance of IR absorption band at 1680 cm-1. The dihydroxamic acid polymer contained carboxylic acid groups as well as hydroxamic acid ones, and the contents of carboxylic acid and hydroxamic acid groups were estimated from elemental analysis to be 2-3 and 2-4 mmol/g, respectively. The polymer showed the adsorptive ability of 40 μg-U/g in 8 days for uranium in sea water. In addition, the polymer showed the selective adsorptivity for iron, nickel, copper, and zinc as well as uranium. The macroreticular-type polymer showed much higher adsorption rate for uranium in sea water than the gel-type ones did, suggesting that the rate depends on the diffusion of the uranium in the polymer support.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240817
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  • 49
    Electronic Resource
    Electronic Resource
    Interchain EDA complexes: A model for LCST? (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 579-587 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240316
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  • 50
    Electronic Resource
    Electronic Resource
    Precipitation polymerization of acrylamide using vazo-33 as an initiator and acetonitrile/water mixtures as the solvent (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 567-577 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Precipitation polymerization of acrylamide initiated by a thermal initiator, Vazo-33 (DuPont Vazo Initiator), was achieved at a solvent composition of acetonitrile/water = 4/6 (vol/vol). The polymerization kinetics were investigated in the acrylamide [M] concentration range 0.86-2.27M, Vazo-33 [I] concentration range 1.4-11.0 × 10-4M, and temperature range 30-40°C. Polymerization was carried out in reaction ampules and the rate was determined gravimetrically. Number-average molecular weight was obtained from intrinsic viscosity. The precipitation polymerization rate varied as [M]2.16 and [I]0.44. Number-average molecular weight was proportional to [M]1.22 and inversely proportional to [I]0.31. The overall reaction activation energy was calculated as 17.3 kcal/mol in the temperature range studied. The optimal reaction conditions studied were: acetonitrile/water = 4/6, temperature = 40°C, [M] = 1.95M and [I] = 2.8 × 10-4M. One hundred percent conversion was achieved in 90 min and a polymer with a number-average molecular weight of 1,200,000 was obtained.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240315
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