ALBERT

Description: The concentrations of nine rare earth elements (REE) La, Ce, Nd, Sm, Eu, Gd, Dy, Er and Yb, have been determined in mixed species assemblages of foraminifera tests taken from Atlantic Ocean sediment core tops. Reductive cleaning techniques have revealed that REE are present in three phases in foraminifera tests collected from sea floor sediments; REE included in the foraminiferal calcite matrix (termed lattice REE), REE associated with an authigenic FeMn-rich phase adsorbed onto the surface of the test following the death of the organism (termed coating REE) and REE associated with alumino-silicate detritus (termed detrital REE) which commonly infills the test chambers after burial in the sediment. The concentrations of REE in the nondetrital (lattice plus coating) and lattice phases have been measured in this study. Approximately 90% of the REE measured in the non-detrital phase reside in the coating phase, the remainder being present in the lattice phase. These data have been used to investigate the relationship between the distribution of dissolved REE in the ocean and in the coating and lattice phases. In addition to the REE the concentrations of Mn, Fe, Cu, Al and PO4 have been measured as an aid to characterisation of the various phases.

Description: A primitive equation equatorial model has been developed to study climate variability due to wind and thermodynamic forcing in an equatorial region. The model basin extends from 30° S to 30° N and zonally over 140°, has a variable horizontal resolution (50–800 km) and 13 vertical levels. Experiments are performed with observed annual cycle as well as 32 years of observed bimonthly wind data. A preliminary analysis of these experiments shows that the model is capable of simulating the basic pattern of annual as well as interannual variability of the Pacific Ocean. In particular, the model response shows evidence of the major El Niños which occurred between 1947 and 1978.

Description: The imaging of a multichannel seismic record was improved by reprocessing using pre-stack techniques. The reprocessed record shows structures that indicate tectonic erosion and gravity collapse at the front of the Japan Trench margin. Much of the lower slope appears to be underlain by a detached, coherent block of continental crust. The lower slope has failed by mass wasting and the resulting apron of slump debris at the base of the slope has become involved in thrust faulting at the front of the subduction zone. Slumping continues as long as debris is removed from the front of the margin by subduction, and the apron cannot build up sufficiently to stabilize the failing lower slope. Truncated beds at the base of the upper plate indicate subcrustal erosion as well, this probably being the main cause of massive subsidence of the margin. Subsidence was the cause of oversteepening, destabilization and subsequent gravity collapse of the leading edge of the upper plate.

Description: Ocean crustal carbon uptake during seafloor alteration at DSDP Sites 417A, 417D, and 418A exceeds the estimated loss of carbon during magmatic ridge outgassing. If these sites are representative for oceanic crust in general, 2.2–2.9 × 1012 moles of carbon are removed from the oceans per year as a net flux of carbon between the oceanic crust and seawater. Although most of this carbon occurs as calcium carbonate, this ocean crustal carbonate probably cannot be considered part of the marine calcium carbonate sink since much of the Ca in these carbonates must be derived from basalt alteration that is not balanced by a concomitant uptake of seawater Mg. Our present estimate cannot be satisfactorily applied to global carbon budgets, because of uncertainties in the bulk budget of ocean floor alteration and because of the uniqueness of our estimate. Yet, our data document that the formation of ocean crust provides a significant sink for carbon that should be included in models of the global cycling of carbon. Furthermore, magmatic outgassing during ocean crust emplacement and seafloor basalt alteration may provide a buffering mechanism for atmospheric carbon.

Description: Seismic refraction investigations along a 440-km long profije on the northern Baltic Shield have resolved the crustal structure in this area of Archaean to Early Proterozoic lithosphere formation. The profile, called the POLAR Profile, extends approximately along a SW-NE-oriented line from the Karelian Province in northern Finland across the Lapland Granulite Belt and the Kola Peninsula Province to the Varanger Peninsula in northeastern Norway. At six shotpoints, large explosions (200–1680 kg), and at three shotpoints, small explosions (80 kg) were detonated and recorded at an average station spacing of 2 km, providing high-quality record sections. A two-dimensional cross section of the crust was obtained by forward modelling using ray-tracing techniques. High-velocity bodies are found in the upper crust related to the Karasjok-Kittilä Greenstone Belt and the Lapland Granulite Belt. They extend to a depth of 6–13 km. In the Karelian Province in the southwest, a low-velocity zone was found between the depths of 8 and 14 km. The middle crust shows a slight increase in the average velocities from the southwest to the northeast, and a small velocity jump is found along a mid-crustal boundary between 18 and 21 km. The thickness of the middle crust varies between 16 and 18 km. The lower crust and the crust-mantle boundary (Moho) show considerable lateral variation. The top of the lower crust lies between 26 and 33 km, while its thickness decreases from 21 km in the southwest to 10–14 km beneath the Lapland Granulite Belt and the Inari Terrain, reaching 20 km again in the extreme northeast. The velocities also change laterally. The thin lower crust is characterized by rather low velocities (6.8–6.9 km/s), whereas in the southwest and northeast the velocities (6.9–7.3 km/s) resemble more typical shield structures. The Moho is found at 47 km in the Karelian Province, rises to 40 km beneath the Lapland Granulite Belt and descends to 46 km in the northeastern part of the Kola Peninsula Province. The upper mantle velocities at the Moho range from 8.1 km/s in the region of the thin crust, to 8.5 km/s and more beneath the Karelian Province. It is tempting to suggest that the anomalous lower crust underlying the Lapland Granulite Belt and the Inari Terrain may represent the remnants of an Early Proterozoic back-arc basin that was active prior to the 2.0 to 1.9 Ga plate convergence event, during which the Lapland Granulite Belt was thrust onto the Archaean basement of the Karelian Province. Another explanation is to assume that the velocity reduction in the anomalous lower crust was caused by a rather pronounced uplift of this region following the 1.9-Ga collision event.

Description: Pore fluid venting associated with subduction-induced sediment deformation causes precipitation of calcium carbonate as prominent carbonate chimneys or cement in the accreted sediments across the active continental margin off Oregon and Washington. A depletion of interstitial Ca2+ with a maximum decrease of 50% relative to seawater Ca2+ over only 1.5m depth and reduction in porosity in the deformed sediments suggest that interstitial Ca2+ is removed to form calcium carbonate cement. In contrast, the pore waters of the undeformed abyssal plain sediments show no depletion in dissolved Ca2+. They are either enriched to a maximum of 5% or show no change in dissolved Ca2+. Here the background level of CaCO3 content in the sediment is only 0.1 to 1%. Calcium carbonate precipitation in the deformed sediments probably occurs as the result of upward migration and oxidation of biogenic methane and of the increase in carbonate saturation due to release of excess pore pressure during fluid venting. Upward advection of fluids at rates of 1–28 cm y−1 is predicted from diffusion-advection-reaction models applied to the downcore concentration profiles of dissolved Ca2+ and NH4+ in the tectonically-deformed sediments. The range of predicted flow rates is related to the type of calcium carbonate lithification; i.e. slow rates generate cement and fast rates generate chimneys. Carbonate mineral precipitation associated with pore fluid venting requires direct transfer of Ca2+ from the oceanic basement to the accretionary complex. Such a mechanism leads us to propose that the accretionary complexes of the global plate subduction zones are a major sink for crustal Ca2+. A global flux of crustal Ca2+ that is removed by carbonate mineral precipitation may be as muc3 as the hydrothermal Ca-input. This significant Ca-flux, not previously considered in the global geochemical budget, implies that pore fluid venting in subduction zones may also act as a global sink or source for other elements.

Description: The ice-proximal environment of the Nordaustlandet tidewater ice cap, Svalbard Archipelago, is one of the best analogues for understanding glacial geologic processes of northern continental shelves during initial Pleistocene deglaciation. Investigations of the proglacial region in 1980–1983 showed that the sedimentary environment is dominated by numerous meltwater outflows which discharge sediment-laden water from subglacial meltwater streams during the summer. Two large, stable meltwater outflows were observed in embayments along the southern part of the ice front. Landsat images show that both outflows have been in approximately the same position since at least 1976. They are located at the intersection of glacial drainage basins and centered over depressions in the underlying bedrock. An “outflow valley” extending away from the ice front was observed in front of the western meltwater outflow. Sidescan sonar profiling along the glacier front showed a 200 m wide gap in acoustic reflection at the base of the western meltwater outflow, probably caused by meltwater effluence. Enhanced sediment accumulations in this region, observed as a ≈ 3 ms sediment drape in front of the outflow, and large arcuate ridges in the outflow valley, testify to the transport efficiency of the subglacial meltwater stream. Several mounds, up to about 25 m high and 200 m wide, are observed on sidescan and 3.5 kHz profiles directly in front of the outflow. Although samples from these structures are absent, they are most likely composed of sediment and are similar to beaded eskers observed in Pleistocene glacimarine sequences indicating locally very high sedimentation rates. Fine-grained components of the subglacial discharge incorporated in the buoyant meltwater plume are usually entrained in a westerly coastal current. Elevated suspended particulate material concentrations are observed within the coastal waters in a region extending about 15 km perpendicular to the glacier front and at least 60 km along the ice front extending into the northwestern Barents Sea.

Description: Sediment fluxes were highest in the Norwegian Sea during late glacial/early deglacial periods, i.e., at oxygen isotope transition 43, below transition 65, at various levels within stage 6, and below stage 9. Dark diamictons deposited at these times reflect intense iceberg rafting in surface waters fed by surges along the front of the marine-based parts of the continental ice sheets in the southeastern sector of the Norwegian Sea. The high organic carbon content (0.5–1.3%) in these layers reflects input from erosion of terrigenious matter-rich sediments outcropping on the shelves. Partial oxidation of organic matter and decreased deep-water renewal may explain the strong carbonate dissolution observed during these periods. Interglacial environments were strongly variable throughout the last 350 ka. Circulation patterns of stage 5e best resemble modern conditions, while stage 7 and 9 sediments record a much weaker Norwegian Current.

Description: Water samples and suspended matter taken in the Atlantis-II Deep area (Red Sea) during the expedition SO-2 (with RV “Sonne”) in November 1977 were investigated for chemical composition. Only slight changes have been found for most components since 1966. A strong decrease of the Cu content (from 100–500 μg kg−1 according to Brooks et al., 1969, to values below 1 μg kg−1) has, however, become evident. Comparison between theoretical concentrations in the intermediate brine layers (resulting when using the lower or the upper homothermal layers, respectively, as end members of mixing processes with Red Sea deep water) and the concentrations measured prove that precipitation and resolution processes have considerable influence on the concentrations found in solution. Components strongly involved in such processes are: iron, manganese, copper, oxygen, sulfate, and silica, as could be shown from comparison of theoretical and measured concentration profiles along the water column. Investigations of the metals suspended in the brine confirm these processes. Compared to 1971/1972, the Cu and Zn values in suspension (preferring the southwestern basin at that time) are clearly reduced — thus being in agreement with the recently lowered hydrothermal activity. Remarks on the hypothetical composition of the unknown hydrothermal brine discharging into the deepest basin are also included.