ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (92,449)
  • Springer  (74,662)
  • Nature Publishing Group  (17,787)
  • 1990-1994  (92,449)
  • Physics  (92,449)
Collection
  • Articles  (92,449)
Years
Year
Journal
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 44 (1990), S. 167-194 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Low-frequency modes of the monsoon are examined in the context of their radiation balance and diagnosed for the 13-month period between May 1979 and May 1980 using Earth radiation budget and cloud measurements taken by experiments carried on board the Nimbus-7 satellite. Simultaneous observations of the albedo, longwave radiation, absorbed shortwave radiation, and net radiation at the top of the atmosphere (TOA), and the total cloud fraction and cloud-top temperature are considered. The use of broad-band radiation budget measurements permits a description of the observed longwave, shortwave, and net radiative energy exchange by the low-frequency modes. When wavenumber one fields are considered, the entire morphology of the 1979 summer monsoon (pre-onset, onset, break, re-intensification, and withdrawal) can be fully explained in terms of an eastward propagating mode. Ridge passages occurred over the Arabian Sea and India in June prior to onset, during the July break, and during the retreat of the monsoon. Trough passages occurred prior to the onset during a period of increased tropical cyclone activity, at the time of the onset, and immediately following the break. These low-frequency waves can be unambiguously tracked around the world over extended time periods. The latitudinal structure of the waves indicated that a thermally direct Hadley Cell perturbation propagated eastward with the oscillation. These cells were evident from extratropical extensions of the oscillation, each about 180° of longitude out-of-phase with the tropical oscillation. Because the absorbed shortwave and emitted longwave radrative components are in phase and of nearly identical amplitudes, the net radiative effect of the low-frequency mode is small in general. However, in certain latitudinal belts, the passage of the waves induced perturbations in the net radiation. Because longwave cloud-radiative forcing acts in the same direction as latent heat release, it is able to contribute to the diabatic energetics maintaining the structure and propagation of the eastward propagating 30- to 60-day waves. Between trough and ridge, the TOA longwave flux varies in a coherent manner by on the order of 50 to 60 Wm−2.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 44 (1990), S. 153-165 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The interannual variability of the monthly mean upper layer thickness for the central Arabian Sea (5°N-15° N and 60° E-70° E) from a numerical model of the Indian Ocean during the period 1954–1976 is investigated in relation to Indian monsoon rainfall variability. The variability in the surface structure of the Somali Current in the western Arabian Sea is also briefly discussed. It is found that these fields show a great deal of interannual variability that is correlated with variability in Indian monsoon rainfall. Model upper layer thickness (H) is taken as a surrogate variable for thermocline depth, which is assumed to be correlated with sea surface temperature. In general, during the period 1967 to 1974, which is a period of lower than normal monsoon rainfall, the upper ocean warm water sphere is thicker (deeper thermocline which implies warmer surface water); in contrast, during the period 1954–1966, which is a period of higher than normal monsoon rainfall, the upper warm water sphere is thinner (shallower thermocline which implies cooler surface water). The filtered time series of uppper layer thickness indieates the presence of a quasi-biennial oscillation (QBO) during the wet monsoon period, but this QBO signal is conspicuously absent during the dry monsoon period. Since model H primarily responds to wind stress curl, the interannual variability of the stress curl is investigated by means of an empirical orthogonal function (EOF) analysis. The first three EOF modes represent more than 72% of the curl variance. The spatial patterns for these modes exhibit many elements of central Arabian Sea climatology. Features observed include the annual variation in the intensity of the summer monsoon ridge in the Arabian Sea and the annual zonal oscillation of the ridge during pre- and post-monsoon seasons. The time coefficients for the first EOF amplitude indicate the presence of a QBO during the wet monsoon period only, as seen in the ocean upper layer thickness. The variability in the model upper layer thickness is a passive response to variability in the wind field, or more specifically to variability in the Findlater Jet. When the winds are stronger, they drive stronger currents in the ocean and have stronger curl fields associated with them, driving stronger Ekman pumping. They transport more moisture from the southern hemisphere toward the Indian subcontinent, and they also drive a greater evaporative heat flux beneath the Findlater Jet in the Arabian Sea. It has been suggested that variability in the heat content of the Arabian Sea drives variability in Indian monsoon rainfall. The results of this study suggest that the opposite is true, that the northern Arabian Sea responds passively to variability in the monsoon system.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The role of organized tropical storms and typhoons within the West Pacific-Indian Ocean dipole of low frequency activity is examined with the aid of INSAT satellite observations. Two Asian summer monsoon seasons-1984 and 1987-are analyzed in conjunction with a satellite derived convective index. The former year was noted as an above average Indian monsoon; the latter year as an extreme Indian monsoon failure. The analysis demonstrates that the dipole region is actually an organized collection of seven smaller scale high amplitude, low frequency centers which blur together to form the semblance of a dipole which had been originally identified in 2.5° resolution outgoing Longwave Radiation (OLR) data derived from NOAA satellite measurements. The centers are basically situated over oceanic regions in the eastern and western sectors of the dipole, although, an isolated high amplitude center is also found over central Tibet. Of considerable interest is that the locations of the seven centers, whereas not equivalent, are very similar for both the 1984 and 1987 seasonsinar. The analysis indicates that there are coherent phase relationships between the eastern sector of the dipole and the western sector, but that it is not a simple dipole-like process. Rather, the four high amplitude centers, within the western sector, all fall within a longitudinal channel in which the well known, northward propagating behavior of Monsoon convection anomalies serves to modulate the east-west phase lag along the meridional channel. The result is that the western paelfic phase lags the equatorial Indian Ocean center whereas it generally phase leads the more northern centers within the Arabian Sea and Bay of Bengal. In the two years studied here, there is little evidence of east-west propagation of anomalies between he two centers. The contribution of organized tropical storms and cyclones to the amplitude and phase characteristics of the high amplitude centers is irregular but important, particularly in the eastern sector of the dipole, where up to 50% of the variance can be explained by organized storms. It is also shown that the influence of storms on the phase propagation characteristics of convective anomalies is irregular but significant.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 44 (1990), S. 219-250 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary In this paper we have studied the low frequency variability of the sensible and latent heat flux over the Indian monsoon area. We have used an atmospheric energy budget (vertical integrated heat sources and moisture sinks), as well as the similarity theory in order to compute the surface fluxes on a darly basis. Mainly, the three following data sets were used: the First GARP Global Experiment analyzed data, the TIROS-N outgoing longwave radiation data and the Monsoon Experiment precipitation data. Our three main findings are the following. First, the variability of the temperature and the specific humidity at the surface is more important over the land than over the sea on the intraseasonal time scale (30% over land, but 20% over sea). For the wind an energy peak appears clearly around 30–40 days. The surface fluxes show an uneven variance percentage field (10% to 40%); the energy peaks stretch from 10 to 40 days. Second, the wind has a significant influence on the surface fluxes, except at some locations exclusively over the land areas. Of the temperature and the specific humidity, the temperature is the one which influences the fluxes the most. (This influence may be very strong over land.) The specific humidity may have a significant influence, over the land and sea, at the same time. Thus, one cannot neglect the influence of temperature and specific humidity over land on the intraseasonal time scale. Third, we have found a close relation between the propagation of low frequency waves and the propagation of surface flux patterns. This may suggest a feedback mechanism which relates surface processes to the northward propagation of these waves over India.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 44 (1990), S. 265-279 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Using a General Circulation Model developed at FSU (FSUGCM), the role of the diabatic heating on the 30–60-day oscillation is investigated. To concentrate on the radiation and the moist convection processes, an aqua planet model is employed in this paper. We have obtained a 40-day oscillation with relatively lower frequency than other GCMs without strong heating in the lower troposphere. Unlike some GCMs and simple models, the convective area does not move eastward along with the oscillation. Adiabatic cooling due to the upward motion is mostly compensated by diabatic heating. This implies that Kelvin CISK theory might not explain our 40-day oscillation. We have also examined the impact of radiative heating on the low frequency oscillation. When we reduce the radiative cooling rate, our 40-day mode does not appear and a Kelvin CISK mode appears with a faster phase speed. The impact of the different convection schemes is also investigated. With an enhanced convection scheme, zonal wave number two with a 40-day period is generated.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 44 (1990), S. 281-292 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The present paper discusses the build-up, the air mass transformation and the propagation of the Siberian high as well as its relations to the development of cold surges in East Asia. It has been found that (1) the genesis and development of the Siberian high result from the combined effects of the mass convergence at middle and upper-level and the radiative cooling; (2) the apparent transformation of the Siberian high over land is observed in winter, which is caused by the upward sensible heat and latent heat flux from the underlying surface; (3) the Siberian high and its attendant cold air outbreaks usually undergo a marked low-frequency, southward propagation with the period of 10–20 days; (4) activity of cold surge over the East China Sea and the South China Sea is closely related to the intensity of the Siberian high. The active cold surge occurs when the Siberian high is usually strong.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 44 (1990), S. 251-263 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The Indian summer monsoon, one of the earth's most vigorous and energetic seasonally occurring weather events, influences the global atmospheric circulation. Its onset, duration, and intensity are governed by large- and meso-scale geophysical processes, such as surface solar heating and air-sea interactions. In this paper, using innovative combinations of satellite sensor data, we investigate some of these fundamental processes which are closely tied to clouds and control the monsoon system's evolution. The study, which focuses on the monsoon period of June, 1979, examines the low-frequency variability of clouds and their effects on air-sea processes through an analysis of the complex influence clouds play on the surface heat and water budgets. First, the effects of clouds on both the solar and longwave components of the surface radiation budget are assessed using a cloud radiative forcing parameter. While the effects of clouds on the long-wave irradiance act in a manner opposite to their effects on the shortwave irradiance, only a partial compensation is found to take place and the net effect results in a maximum cloud forcing of 60 Wm−2 in the southwestern Arabian Sea. Second, employing satellite-derived precipitation and evaporation estimates, the paper analyzes the net surface fresh water budget variability around the monsoon onset. This budget is important in that fresh water affects the upper ocean density distribution and, consequently, the thermohaline circulation. Two regions are found to dominate the analysis: the western Arabian Sea, where evaporation is dominant by more than 10 mm day−1, and the eastern Arabian Sea, where precipitation is dominant by more than 10 mm day−1. Thus, a strong zonal gradient of fresh water at the surface is established during the monsoon. The last topic investigated is the intraseasonal variability of convection as analyzed using a cloud parameter indicative of deep convection. Cloud oscillations of 30–50 days, associated with the different phases of the monsoon, are found to propagate northward in the eastern Indian Ocean and eastward in the Bay of Bengal. Our analysis not only supports the hypothesis that the 30–50-day oscillation is driven by deep convection but also, and more importantly, suggests that the ocean thermal forcing is modulated by 30–50-day oscillations through cloud-induced surface radiative forcing. Although the results presented are limited in scope and preliminary because of the diffculty in quantifying the accuracy of the parameters examined, they do demonstrate: 1) the role of clouds in modulating the surface heat and water budgets, 2) the advantage of using combinations of multi-sensor and multi-platform satellite observations to quantify interrelated surface heat/water budget processes, and 3) the potential to examine the intraseasonal variability of air-sea interaction processes associated with the monsoon, even though these processes are not directly measurable from space.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 45 (1991), S. 1-13 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The monthly mean Outgoing Long wave Radiation (OLR) data from June 1974 to May 1988 (Fourteen year period) derived from the NOAA polar orbiter are analysed to examine the inter-annual variability in OLR fluxes over the indian sub-continent and adjoining Seas. The monthly mean OLR data are further analysed to observe the seasonal and annual OLR variations among the specified regions over the sub-continent. Linear and multiple correlation statistics have been applied to explain the homogeneities among the various regions in terms of long term annual as well as seasonal OLR means. Derived results show close links between selected regions where as poor and, in few cases, even negative correlations exist between some regions. Considerable differences have been observed between the regions in annual and in seasonal OLR variances. Similar analysis has been done for rainfall of the subcontinent based on fourteen year's data. The rainfall analyses for the selected regions over India illustrate a rather poor association between OLR and rainfall distribution variability. On the basis of our results discussed in this paper, it is viewed that Satellite-Derived OLR could be treated only as of marginal use for space-time precipitation analyses.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 46 (1991), S. 205-210 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 47 (1991), S. 83-84 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 107-115 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A number of cut-off processes are investigated, with the Alpine region in most cases lying at the margins of these upper lows. Our aim was to determine whether the thermal front parameter (TFP) can be used to objectively define the areas of bad weather from analysis charts and prognostic charts. An attempt is made to formulate two synoptic “guidelines”, for the eastern Alpine region, on front-sides and northern margins of upper lows, into objective synoptic rules.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 127-144 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary This study examined ECMWF operational analyses of the outflow layer of two tropical cyclones (Allen, 1980; Elena, 1985) during their passage across the Atlantic and Caribbean. Wind fields and related derived quantities were compared to those from objective analyses of specialized data sets. Errors in center position and storm motion from the ECMWF analyses were also evaluated. Analyses of wind and angular momentum flux in 1985, subsequent to upgrading of the operational model, were superior to those from 1980. High-resolution, uninitialized analyses from 1985, however, provided no advantages over lower resolution, initialized analyses for the same time period. For all ECMWF analyses, azimuthally averaged (mean) tangential velocity, and thus mean vorticity, were well represented. Mean radial velocity and mean divergence were poorly represented. Problems with the latter arose primarily due to underestimation of outflow, especially in the 1980 analyses. Azimuthaleddy fluxes of angular momentum in the ECMWF analyses quantitatively differed from but qualitatively resembled, the control analyses. Vorticity maxima at 850 mb in the operational analyses most accurately defined the center position of the storms, with a mean error less than or equal to one grid point. In contrast, surface pressure minima failed to provide reliable estimates. Over open ocean and at early stages of storms, analysis quality was uneven, with occasional large position errors and widely varying locations of vorticity maxima in the vertical. Nevertheless, in regions surrounded by even a few rawinsondes, such as the Caribbean or Gulf of Mexico, ECMWF analyses contained sufficient information to allow individual case studies of the tropical cyclone environment. In the same regions, estimates of the eddy flux convergence of angular momentum were found to be accurate enough to aid in operational hurricane intensity prediction. Enhancements in resolution and model initialization at ECMWF since 1985 should further improve operational analyses of the tropical cyclone environment.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 205-227 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary This paper describes the evolution of two thunderstorms which developed over northeastern Colorado on 23 July 1983, and more significantly discusses the possible causal relationship between them. In particular, a disturbance apparently created by the first thunderstorm, which developed over the eastern slopes of the Rocky mountains, seems to have triggered the second thunderstorm, which developed further east over the high plains. We present evidence that suggests that the disturbance is a rapidly propagating gravity wave (possibly a solitary wave of depression) that occupied most of the troposphere and was generated by the explosive convective development of the first thunderstorm. Detailed observations of the interactions between these two storms were possible because both storms developed over a dense network of automated weather stations that provided high temporal and spatial resolution surface measurements of pressure, temperature, precipitation, and horizontal wind velocity. Also located within this mesonetwork was a high power 915 MHz wind profiler that provided radial velocities throughout most of the troposphere. These measurements were supplemented with GOES visible and infrared satellite imagery and operational data from National Weather Service rawinsondes and weather radars.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 237-245 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Problems of turbulent dissipation of a cold air lake (CAL) and the inversion layer bordering CAL on the upper boundary are presented and studied with the compound model. In wintertime such cold air lakes can persist for days even if rather strong winds are blowing above them. The required conditions for CAL dissipation are removed processes of its formation or maintenance, as well as a sufficiently strong invasion of turbulence in the inversion layer from above down-wards. By this, the inversion layer at first becomes stronger and dissipation is stopped, until the increase of turbulent kinetic energy of the upper flow enables further dissipation. Such turbulent dissipation process is shown by the model for typical conditions and for different initial values of the relevent variables.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 259-265 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary THETAPLOT is a diagram useful for the display and analysis of atmospheric thermodynamic soundings, particularly in relation to conditionally and convectively instable summertime weather situations. The basic coordinates of THETAPLOT are the equivalent potential temperature and the negative logarithm of pressure. The body of the diagram contains families of curves of constant potential temperature, mixing ratio and temperature. From any given sounding, three curves are plotted on the diagram: 1) Theta-ed, the equivalent potential temperature of air saturated at its dew point temperature; 2) Theta-e, equivalent potential temperature; and 3) Theta-es, the saturated equivalent potential temperature. The winds are plotted along the margin of the diagram.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 49 (1992), S. 187-207 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary This paper is concerned with the simulation of deep convection for the CCOPE 19 July 1981 case study. Clark's three-dimensional (3D) cloud model modified to use the bulk water parameterization scheme of Lin et al. has been used in the simulation of the CCOPE 19 July 1981 case in coarse mesh, fine mesh, and interactive grid nested schemes, respectively. Comparisons with observations show this 3D grid nested cloud model is capable of both capturing both the dynamic and microphysical properties of the cloud. In the nested grid fine mesh model simulation, the timing and mode of cloud growth, the diameter of liquid cloud, the cloud top rate of rise, the maximum cloud water content, and the altitude of first radar echo are consistent with observations. The simulated thunderstorm begins to dissipate, after precipitation reaches the ground as indicated by the decreasing values of maximum updraft and maximum liquid cloud water content, and ends as a precipitating anvil as was observed in the actual thunderstorm. The model precipitation developed through ice phase processes consistent with the analysis of observations from the actual thunderstorm. Qualitative comparisons of the actual radar RHIs with simulated reflectively patterns from the 3D model show remarkable similarity, especially after the mature stage is reached. Features of the actual RHI patterns, such as the weak echo region, upshear anvil bulge, strong upwind reflectivity gradients, and the upwind outflow region near the surface are reproduced in the simulation. Comparison of the actual radar PPIs with horizontal cross sections of radar reflectivity simulated by the 3D model, however, show modest differences in the storm size with the 3D simulated thunderstorm being 1–2 km longer in the west-east direction than the actual thunderstorm. The model-predicted maximum updraft speed is smaller than the 2D model-predicted maximum updraft speed, but still greater than what was observed. Comparisons among the nested grid fine mesh model (MB), nested grid coarse mesh model (MA), fine mesh model (FM), coarse mesh model (CM), and 2D model results previously published show that the nested grid fine mesh model (MB) gives the best simulation result. The various 3D model simulation results are generally similar to each other except for the difference in the domain maximum values. The domain maximum values in the fine mesh models (MB and FM) are generally higher than the coarse mesh models as a result of averaging over a smaller area.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The Penn State University/National Center for Atmospheric Research (PSU/NCAR) mesoscale model is a widely used research tool that has been applied in a wide variety of real-data, mesoalpha-scale applications. Recently a nonhydrostatic version of this model has been developed by Dudhia (1993). It is the purpose of this paper to illustrate the capabilities of this modeling system by describing four examples of mesobeta-scale simulations: two of the cases involve maritime processes and two deal with continental weather events. All utilize fully three-dimensional sets of initial conditions that are based on real data, both standard data and from special measurements programs. One case employs the model in a data-assimilation configuration, wherein Newtonian relaxation terms are used in the equations to assimilate data from a variety of platforms. This example of nonhydrostatic four-dimensional data assimilation (FDDA) is performed for the purpose of generating a dynamically consistent four-dimensional data-set, however the same procedure can be used for model initialization. The first case, described in section 2, involves the simulation of a coastal front that forms offshore near the western edge of the Gulf Stream. In the second case, described in section 3, the model is used in the FDDA mode to define the mesobeta-scale windfield over the complex terrain of the region around Grand Canyon, Arizona. In sections 4 and 5 will be described the mesobeta-scale structure of cold fronts, one within a marine cyclone, and another near the Rocky Mountains.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Hydrostatic and nonhydrostatic simulation models are employed to study the intensification of a terrain drag-induced dryline. The study develops a multi-stage theory for the evolution of the dryline including the concentration of potential vorticity accompanying meso-gamma scale dryline “bulges”. The numerical simulations indicate three fundamental stages of dryline intensification all of which are either directly or indirectly a result of the terrain-drag on the mid/upper-tropospheric jet stream by the Front Range of the Colorado Rocky Mountains. The first stage involves the downward momentum flux accompanying a large amplitude hydrostatic mountain wave which induces a downslope windstorm along the lee slopes. The surge of momentum (i.e., the dry, warm air associated with the downslope windstorm) propagates down the leeslope and modifies an existing weak dryline boundary. As the downslope windstorm initiates an undular bore along the lee slopes, the high momentum gradient which propagates downstream accompanying the bore, as well as the strong lower tropospheric sinking motions ahead of the bore, contract the scale of the surface moisture boundary between the dry air from above the leeslope and the moist air over the High Plains. This process further strengthens the dryline. The second stage involves the coupling of the terrain drag-induced along-stream ageostrophic front within the midtroposphere to the boundary layer through a thermally-indirect circulation. As the along-stream ageostrophic circulation intensifies within the middle troposphere down-stream from the mountain wave, sinking air parcels originating above 40 kPa descend to below 60 kPa over the High Plains where surface pressures are, only ∼85 kPa. These descending air parcels within the upstream branch of the along-stream ageostrophic thermally-indirect circulation contain high values of momentum and very low dewpoint values. As the planetary boundary layer (PBL) deepens due to surface warming during the morning hours, momentum and dry air from the midtropospheric along-stream ageostrophic front are entrained into the PBL. This process amplifies the bore-induced hydrostatic dryline bulge via low-level ageostrophic confluence. Finally, regions of low Richardson number (arising from strong vertical shears) within the amplifying midtropospheric along-stream ageostrophic thermally-indirect circulation become preferred regions for the development of non-hydrostatic evanescent internal gravity waves. These waves are embedded within the hydrostatic along-stream front above the low-level dryline and are accomapanied by very significant values of vertical momentum flux which act to focus the meso-gamma scale structure of the dryline into smaller scale bulges where low-level winds and vorticities are very high. This meso-gamma scale process follows the hydrostatic tilting and vortex tube stretching which creates meso-beta scale maxima of mid-lower tropospheric vorticity. The turbulent momentum fluxes accompanying wavebreaking within the nonhydrostatic dryline bulge create very large (i.e., stratospheric values of) potential vorticity near 70 kPa due to the nonconservation of potential vorticity on isentropic surfaces.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 49 (1992), S. 229-254 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A nonhydrostatic numerical simulation of a tropical cyclone is performed with explicit representation of cumulus on a meso-β scale grid and for a brief period on a meso-γ scale grid. Individual cumulus plumes are represented by a combination of explicit resolution and a 1.5 level closure predicting turbulent kinetic energy (TKE). The results demonstrate a number of expected and unexpected important scale interaction processes. Within the central core of the developing cyclone, meso-β convective regions grow and breakdown into propagating inertiagravity waves throughout the lifecycle of the cyclone. In the early stages, the amplitude of pressure fluctuations associated with the meso-β scale convection exceed the central pressure of the cyclone and strongly modulate its intensity. With each meso-β scale pulsation, the cyclone core increases in strength, measured by the central pressure deficit. The increasingly strong inertial frequency of the storm core acts to increasingly trap the convection induced heating within the core by balancing the tangential wind against the low central pressure, before the meso-β scale convection breaks down and sends the warmth away as a propagating wave. Eventually, the slow manifold's amplitude exceeds the amplitude of the meso-β scale oscillations and a stable eye region is formed. As inertial instability increases, increasingly high thermal warmth can be protected in the core, allowing persistent subsidence to form and to clear out the cyclone eye. On the outside of the eye wall, strong inertial stability gradients in the troposphere cause convective warming to split the inflow to the eye wal! and spawn outwardly propagating inertia gravity waves. These waves carry away all of the heating forced by convection that is not inertially trapped by the eye wall and act as a moderating influence on storm intensity. Inertia gravity waves are also spawned in the stratosphere at the top of the eye wall by the revolution of asymmetric cumulus structures. In all instances, the tropospheric waves are coupled to the propagating stratospheric waves which both move at 35 ms−1, although there are many instances where the stratospheric waves seem to have no tropospheric counterpart. Hence the anvil top forcing and low level breakdown are linked. The outwardly propagating inertia gravity waves act to initiate outer bands of convection. This initiation is with the assistance of low level boundary layer variations of density related to previous convection and to virga falling from the anvil which moistens and destabilizes the mid levels ofθ e minimum. The convection initiated by these waves does not move substantially outward with the wave, although may appear to develop outward discontinuously.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 75-88 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The set of fully compressible nonhydrostatic equations governing a broad spectrum of atmospheric motion was transformed fromz coordinates to sigma coordinates under a hydrostatic base state. The hydrostatic base state may be either time-independent, such as a hydrostatic balance with-out motion or with motion such as a thermal wind balance, or time-dependent such as might be obtained from the result of integrating a hydrostatic model. The transformed set of equations can be used to predict and study all scales of at mospheric phenomena. The set of perturbation equations was also derived under the same condition. The computational sensitivity in computation of pressure gradient force in sigma coordinate can be improved by computing the pressure gradient interms of perturbations under a certain hydrostatic state. The hydrostatic regional spectral model developed by Juang and Kanamitsu (1991) was modified to be a nonhydrostatic spectral model based on the nonhydrostatic equations in sigma coordinates with time-dependent hydrostatic base states. A semi-implicit time integration scheme was used. Two experiments were performed to test this nonhydrostatic spectral model with acceptable results.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 61-73 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Most finite-difference numerical weather prediction models employ vertical discretizations that are staggered, and are low-order (usually second-order) approximations for the important terms such as the derivation of the geopotential from the hydrostatic equation, and the calculation of the vertically integrated divergence. In a sigma-coordinate model the latter is used for computing both the surface pressure change and the vertical velocity. All of the above-mentioned variables can diminish the accuracy of the forecast if they are not calculated accurately, and can have an impact on related quantities such as precipitation. In this study various discretization schemes in the vertical are compared both in theory and in practice. Four different vertical grids are tested: one unstaggered and three staggered (including the widely-used “Lorenz” grid). The comparison is carried out by assessing the accuracy of the grids using vertical numerics that range from second-order up to sixth-order. The theoretical part of the study examines how faithfully each vertical grid reproduces the vertical modes of the governing equations linearized with a basic state atmosphere. The performance of the grids is evaluated for 2nd, 4th and 6th-order numerical schemes based on Lagrange polynomials, and for a 6th-ordercompact scheme. Our interpretation of the results of the theoretical study is as follows. The most important result is that the order of accuracy employed in the numerics seems to be more significant than the choice of vertical grid. There are differences between the grids at second-order, but these differences effectively vanish as the order of accuracy increases. The sixth-order schemes all produce very accurate results with the grids performing equally well, and with the compact scheme significantly outperforming the Lagrange scheme. A second major result is that for the number of levels typically used in current operational forecast models, second-order schemes (which are used almost universally) all appear to be relatively poor, for other than the lowest modes. The theoretical claims were confirmed in practice using a large number (100) of forecasts with the Australian Bureau of Meteorology Research Centre's operational model. By comparing “test” model forecasts using the four grids and the different orders of numerics with very high resolution “control” model forecasts, the results of the theoretical study seem to be corroborated.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 127-142 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Convective to planetary scale processes govern the motion and structure of tropical storms. A model with a high resolution and a large domain is required for accurate prediction of a storm's track and intensity. A series of integrations are performed using a primitive equation model and an initial state that defines a tropical storm that later developed into a hurricane in the real atmosphere. Increasing the horizontal resolution or domain of the model improves the forecast track. However only the increase in the horizontal resolution produces a better hurricane structure. Banded structure in the vertical motion field, asymmetries in the low tropospheric winds similar to those observed and upper tropospheric cyclonic outflow develop in high horizontal resolution experiments. It is shown that horizontal advection and pressure gradient terms produce wind tendencies in the low troposphere that displace the vortex in the observed direction. A high pressure area surrounding the central low pressure area appears in the upper troposphere. Around this high pressure area large pressure gradients develop that induce outflow winds in the distal storm area.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 105-126 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary In this paper we present some recent work on typhoon prediction with a high resolution global model. The emphasis of this paper is on typhoon recurvature. Here we include examples of successful typhoon recurvature track forecasts made from a very high resolution global spectral model. The main objective of this study however is to go beyond the forecasts, i.e. to interrogate the history tapes and to diagnose residue-free budgets of the divergence and vorticity. The premise of this paper is that the recurvature of the typhoons depends on both the usual advection of vorticity by the layer mean winds and the advection of divergence in the outflow layers of the storm. The region immediately outside the heavy rain area of the storm experiences large values of divergent outflows which contribute a significant advection of divergence. Through the Dine's compensation this region must, in consort, experience an enhancement of low level convergence and of deep convection, thus contributing to the storm motion. We distinguish two facets of storm motion and recurvature, one based on the conventional steering that invokes the advection of vorticity by a vertical integrated flow, the other is the generation mechanism proposed here. During recurvature the storm appears to move in a direction which is influenced by the rotational and the divergent flow dynamics. Increased vertical resolution in the outflow layer is shown to resolve stronger amplitudes in the outflow layer divergence and thus to contribute to improved forecasts of recurvature. A number of processes seem to simultaneously evolve, these include the strong advection of divergence part of the wind, enhancement of cumulus convection over this region, an enhancement of lower tropospheric convergence, generation of vorticity of the lower troposphere and the attendant recurvature.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 143-163 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A number of forecast experiments were performed in order to assess the capability of reproducing, by means of a limited-area numerical model, the highly structured mesoscale circulations occurring in the Po Valley of Northern Italy during a north-westerly cold front passage across the Alpine chain, with particular attention to the modelling of the effects of organized convection. The case-study occurred during summer 1987 and the model used throughout was the 1989 version of the UB/NMC Limited Area Model (University of Belgrade, National Meteorological Centre of Washington). The model was integrated both with eta, η, and sigma, ϑ, as vertical coordinates and ECMWF initialized analyses were always used as initial conditions. ECMWF initialized analysis or operational forecast fields were also used for updating in time the lateral boundary conditions. Experiments show qualitative and quantitative agreement with observations, both in upper-air geopotential height fields, in MSLP and in cumulated precipitation. Several modelling issues were also investigated, e.g. sensitivity of the results to horizontal and vertical model resolution and to the influence of the lateral boundaries poitioning, finding large effects of the latter on quantitative precipitation fields. Difficulties in modelling very localized mesoscale phenomena, e.g. organized convective thunderstorms in the Po Valley and Alpine North Foehn in the Milan area, were generally encounted.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 165-174 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary In this paper we present a methodology for evaluating rain rates from a mix of satellite and surface based observations. The component data sets include the outgoing longwave radiation (OLR), microwave radiometric data from the special sensor microwave imager (SSM/I) and surface raingauge data from the World Weather Watch. We have noted some deficiencies in the SSM/I algorithm-based rain rate over land areas; the OLR-based rain rates exhibit a larger lateral spread and lower intensities than the observed rainfall structures. The proposed combined method assimilates these three data sets to provide improved fields of global tropical rainfall.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 175-187 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The Kuo-type cumulus parameterization and rainfall rate scheme is extended by including the outgoing longwave radiation (OLR), the local time rate of change of OLR, and the horizontal Laplacian of OLR to include the additional source of mesoscale moisture supply. The extended scheme remains simple and efficient. A series of 5-day forecasts of the 1979 monsoon for the tropical belt between the Arabian Sea and the western Pacific Ocean show improvement in the 3-day forecast in the daily accumulated precipitation in both the amount and location. Further RMS error analyses indicate that using OLR and the Laplacian of OLR also produces a significant improvement in a 3-day forecast. Additional tests of the extended scheme for the 1987 and 1988 monsoons produced consistent and characteristic areal rainfall rates in the tropics. The improvement in the “OLR model” forecasts is attributed to the improved skill of OLR forecast in the forecast model as the RMS errors for 5 consecutive days in the 6 experimental forecasts are smaller than those of the 3 control forecasts.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 28
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 189-195 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A special analytical solution is derived for the classical orographic configuration of two-dimensional, stratified, linear, non-hydrostatic and dry model (without friction and Coriolis force). The well-known differential equation for the vertical velocity involves the vertical distribution of the Scorer parameterl 2(z) and in this casel 2 is specified such that the lower atmosphere has a stable duct near the surface and is capped by a layer which acts as a good reflector. Examination of the solution for the vertical amplitude in the vicinity of singularities indicates the dominant lee wavelength and observations confirm that in comparable settings resonant trapped gravity waves develop in the lee of mountains. Comparison with a real atmospheric lee-wave events gives good predictions for the wavelength and wave drag, but, as in other linear models, the amplitude is underestimated.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 237-238 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 231-236 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary In this paper we combine chaotic theory with statistics to present three forecast models: a model of equal distance ind-dimensional phase space, a mode regression model of twelve units and a model of neighborhood model regression. Many experiments show that all these models can generate accurate forcasts.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 51 (1993), S. 1-24 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Nonlinear interactions and feedbacks in frontal dynamics are studied with two-dimensional quasigeostrophic, semigeostrophic and primitive equation models for given cases of moderate surface cold fronts. According to the degree of approximation these feedbacks are in effect as a result of geostrophic and ageostrophic advection configuring the further frontal development and the associated energy-transfers between the geostrophic and the ageostrophic scales. The most prominent feedback processes, including the feedback connected with the ageostrophic along-front windv ag , are theoretically reviewed. In cases of smallv ag values, their effects on form and horizontal scale of the frontal secondary circulation are discussed by comparing the products of different model versions and the cross-frontal spectral analysis of the ageostrophic wind fields. To scrutinize the role played by thev ag -field, further experiments were based on a hierarchy ofv ag -substitutes parameterized by the momentum equation of the crossfrontal winddu/dt=fv ag . Tentative results show the tendency towards very localized effects.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    ISSN: 1435-604X
    Keywords: Photodynamic therapy ; Superficial bladder tumours ; Dosimetry ; Isotropic light sensors ; Photosensitizers ; Wavelength of irradiation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract The use of photodynamic therapy (PDT) for the treatment of superficial tumours on the bladder wall is described. Details are given on the laser, methods of delivering light into the bladder, suitable commercial dosimetry systems and instrumentation suitable for making light measurements on the bladder wall during therapy. New alternative photosensitizers are discussed in some detail. Some early clinical results are presented and the current problems with this type of therapy are highlighted.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 43-49 
    ISSN: 1435-604X
    Keywords: Copper vapour laser ; Argon ion laser ; Port wine stains ; Telangiectasia ; Spider naevi ; Questionnaire
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract A questionnaire was sent to 242 patients who had undergone treatment with yellow light (578 nm) from a copper vapour laser for a port wine stain (PWS), for facial telangiectasia (FT), or for a spider naevus (SN). The questionnaire covered the social implications of the lesion, the physical appearance of the lesion after treatment and the patient's judgement of how the treatment has affected them. Replies were received from 73% of the patients. The replies revealed that 83% PWS, 74% FT, and 81% SN patients felt there had been an improvement in their appearance compared with 2.5% PWS, 14% FT, and 7.5% SN patients who felt that their appearance had changed for the worse. The overall impression of the treatment was also very positive, especially with PWS patients, 91% would recommend the treatment to others, 84% would have the treatment again and 60% indicated their feelings regarding their overall treatment and the effect it had on their lives was very good.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    ISSN: 1435-604X
    Keywords: Biliary calculi ; Laser lithotripsy ; Pulsed 504 nm dye laser ; Salivary calculi ; Urinary calculi
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Biliary, urinary and salivary stones were fragmented in vitro with a flashlamp-pumped dye laser operating at 504 nm. A clinical fragmentation criterion was formulated; fragmentation was continued until all fragments had passed through a sieve with holes of 1.5×1.5 mm2. The number of shots of 50 mJ necessary for total fragmentation appeared to be proportional to the stone mass. The three types of stones showed statistically significant differences in the number of shots per unit mass, necessary for fragmentation. On biliary calculi we investigated the influence of the energy per laser pulse. For pulse energies of 32 mJ and larger, the energy necessary for fragmentation appeared to be proportional to the initial stone mass, but did not depend on the energy per pulse.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 121-128 
    ISSN: 1435-604X
    Keywords: Hyperthermia ; Tissue optics ; Thermal properties ; Lasers ; Cancer therapy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract The rationale of hyperthermic treatment of tumours is based on the phenomenon that several tumours have a reduced tolerance for exposure to temperatures in the region 42–47 °C for 20–30 min. Hyperthermia may also be used as an adjunct to other modalities such as chemotherapy, conventional radiation therapy or photodynamic therapy. Methods for introducing hyperthermia include electromagnetic radiation in the radiofrequency and microwave region as well as ultrasonic waves. The use of lasers emitting within the visible and near infrared part of the spectrum has the potential to initiate a local elevation of the temperature. The extension of the heated region will depend on optical wavelength, tissue composition and blood perfusion. Typical linear dimensions of the 42–47 °C temperature region will range from 2–3 mm and up to about 10 mm. Superficial tumours may be heated by direct irradiation whereas deeper lying tumours or lesions of large extent may require light delivered by one or several inserted optical fibres. Laser-induced hyperthermia may be of particular relevance in the treatment of retinal or choroidal tumours. Visible and near infrared radiation can be transmitted through the cornea, the lens and the vitreous with negligible loss. The absorption in the tumour is, however, significantly larger and the main part of the optical power will be absorbed within 0.5–5 mm into the neoplastic tissue. This paper emphasizes a discussion of the basic principles.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 137-141 
    ISSN: 1435-604X
    Keywords: Retinal epiblastic tumours ; Uveal tumours ; Photocoagulation therapy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Two kinds of tumours are of particular importance in ophthalmology: the retinal epiblastic tumours, like the retinoblastoma and uveal tumours, like the uveal melanoma and the metastatic tumours. The photocoagulation therapy is sometimes used as a first treatment or as the only treatment, and this kind of therapy is useful according to our experience to complete conservative tumour therapy with radioactivity or cytostatic chemistry. A review of literature is done and we present several clinical examples from our own experience in the Lisbon Institute of ophthalmology and in the University Eye Clinic, Santa Maria Hospital, Lisbon.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    ISSN: 1435-604X
    Keywords: Bladder tumour ; Diagnosis ; Fluorescence ; Photodynamic therapy ; Photosensitization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Most methods of modern laser tumour therapy are physically based on the conversion of light to heat. Recently tumours have also been treated using ionizing processes for tissue ablation. Photodynamic laser therapy (PDT), however, involves light-induced non-thermal biochemical processes and the use of a photosensitizer. Several drugs are known to be stored selectively in tumours after systemic application. This transient marking can be used for diagnostic and therapeutic procedures. The marker most commonly used is dihaematoporphyrin ether/ester (DHE) intravenously injected at doses of 0.2–3.0 mg/kg bodyweight for diagnosis and therapy, respectively. The corresponding clearance intervals after injection of DHE range from 3–48 h to 25–75 h. Detection of photosensitized tumours might offer great advantages. The highly sensitive two-wavelength laser excitation method with computerized fluorescence imaging recently has been transferred to the hospital for clinical tests. Photoinduced production of singlet oxygen is claimed to be the initial process which leads to later tumour destruction and therapy. PDT has been applied to 20 patients suffering from superficial tumours (TIS GII–III) recurred after application of other treatments. The results after PDT were evaluated by three-monthly check-ups (endoscopy, cytology, bladder mapping, renal ultrasonography) as well as by computed tomography (CT) examination at 8–13 month intervals. In six patients treated by PDT no tumour recurrence has been found over the whole observation period of up to 5 years. Four patients have remained free of tumour (12 and 14 months) after repeated transurethral resection (TUR) and Nd-YAG laser therapy following PDT. Due to an initial application of insufficient irradiation four patients required a second PDT. In one patient a circumscribed dysplasia appeared at the left ostium 26 months following PDT and was treated successfully by means of thermal Nd-YAG laser irradiation following TUR. In six patients slight mucosal atypia persisted for a period of at least 2.5 years. One cystectomy had to be performed because of bladder shrinkage. The dissected bladder, however, was free of tumour. These preliminary results suggest that PDT is justified in patients who are in a worst-case situation with cystectomy recommended in case of recurrent superficial TIS bladder carcinoma and indicate the future potential of photodynamic therapy of tumours. Homogeneous irradiation of the area to be treated and a reliable light dosimetry are prerequisites for an effective tumour therapy. Standard instruments for a routine application do not exist, but are under development.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 213-215 
    ISSN: 1435-604X
    Keywords: Gynaecological tumours ; Endometriosis ; Haematoporphyrin derivative
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 217-221 
    ISSN: 1435-604X
    Keywords: Oesophageal cancer ; Nd-YAG laser ; Endoscopic treatment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Over a 10 year period, 149 non-surgical patients were treated for palliation of an oesophageal cancer. One hundred and twenty-nine patients had an advanced cancer; 20 had a small cancer. The initial success rate was 81% and the complications rate was 3.1% for advanced cancers. Average duration of improvement after initial improvement was 138 days. Location was the only factor affecting the initial results in advanced cancers. Improvement duration was affected by the reason for treatment and an association of treatments during follow up. A complete local destruction of the small cancers was obtained in 18 patients. Three patients had a local recurrence during follow up.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 253-269 
    ISSN: 1435-604X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Laser applications are developing rapidly in medicine. Virtually every specialty of surgery, and a number of medical specialties, are using the laser for several conditions, and the number of conditions treated seems to grow every day. This fact is of concern to policy-makers in a time of limited resources for health care. Increasingly, health policy decisions are guided by costeffectiveness studies of medical applications. This paper reviews evidence of cost-effectiveness for a number of relatively mature laser applications. In general, although available studies are suggestive of benefit, effectiveness has been demonstrated for relatively few laser applications. Little reliable cost information has been developed, although out-patient therapy and shortened length of stay in hospital seem to be demonstrated for several conditions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 289-292 
    ISSN: 1435-604X
    Keywords: Cancer ; Laser ; Chromophores ; Photodynamic therapy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Chromophores in tissue are of considerable interest for the tissue interactions with lasers in the visible light range. The natural chromophores in man are essentially melanin and red cell haemoglobin. With the development of Photodynamic Therapy (PDT) in the treatment of human cancer, the new technology of exogenous chromophores was developed and continues to expand both in laser medicine and laser surgery. This technology relates specific chromophores to specific wavelengths for the destruction of tumours and has been very effective for PDT in those instances where there is accessibility to the tumour mass by the laser beam. The problems today are concerned with how to mark these malignant foci deep in the tissue, how to detect them, and how to direct selected laser beams to the marked carcinomatous tissue. In laser medicine, the field is expanding especially for tissue and laboratory diagnostics.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    ISSN: 1435-604X
    Keywords: Photodynamic therapy ; PDT ; Fluorescence ; Haematoporphyrin derivative ; HPD ; Diagnosis ; Murine tumour ; Laser ; Pharmacodynamic ; Pharmacokinetic ; Regrowth delay
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Eight commercially available HPD-photosensitizers intended for photodynamic therapy were tested in a murine tumour model with regard to their therapeutic efficacy. The regrowth delay of the fibrosarcoma SSK-2 on the mouse C3H, Neuherberg-line, was determined 3, 24, 48 and 72 h after injection of the drugs (dose: 9 mg kg−1 body weight). The corresponding pharmacodynamics, as measured by regrowth delay, were approximated by an exponential function and the characterizing coefficients derived. These coefficients served to quantify the photodynamic properties of the drugs. The pharmacodynamics of five substances were compared with those obtained fluorometrically. The latter showed shorter decay constants than the therapy-correlated substances which indicates different metabolic behaviour of the therapeutic and diagnostically useful fluorescent components of haematoporphyrin-derived photosensitizers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 337-337 
    ISSN: 1435-604X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 381-386 
    ISSN: 1435-604X
    Keywords: HeNe laser irradiation ; Biostimulation ; Wound healing ; Capillary regeneration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Laser light of low energy is discussed to have an accelerating effect on wound healing. The aim of the present study was to proof whether HeNe laser irradiations have a positive effect on regeneration of capillaries. For this purpose aluminium chambers were implanted in the dorsal skin flap of Syrian hamsters. After coagulation of blood vessels by means of an argon laser the tissue was irradiated daily with the low energy light of a HeNe laser. Regeneration of capillaries was studied by means of intravital microscopy. The results of the study revealed a positive effect of low dose HeNe laser irradiation on the regeneration of capillaries at day 5 after the coagulation. The measurable part of the capillaries was about 27% higher for the irradiated animals compared to controls.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 5 (1990), S. 411-413 
    ISSN: 1435-604X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 15-21 
    ISSN: 1435-604X
    Keywords: Laser ; Platelets ; Aspirin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Laser angioplasty involves intravascular laser irradiation which may affect platelets and aggregation. In this study we examined the in vitro effects of different energy doses and modes of CO2 laser irradiation on the platelet number, function and ultrastructure. Since aspirin is used in many patients suffering from coronary artery disease, the consequences of laser irradiation on aspirin-treated platelets were studied as well. We found that CO2 laser irradiation causes a dose-response reduction of the platelet number that is most pronounced with high energy-short duration irradiation, and a dose-response reduction in platelet aggregation which is independent of the mode of irradiation. Pretreatment with aspirin does not change the effects of laser irradiation on platelet number, while aggregation is reduced only at relatively high energy doses. Electron microscopy revealed significant intracellular injury following low energy irradiation, while progressive damage to membranes occurred in a dose-response mode, both in untreated and aspirin-treated platelets. The clinical application of our findings should be done cautiously since important in vivo factors, such as the effect of laser irradiation on the vessel wall and coagulation system, were not studied.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 53-53 
    ISSN: 1435-604X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    ISSN: 1435-604X
    Keywords: Atherosclerosis ; Peripheral arteries ; Laser angioplasty ; Pulsed Nd-YAG laser ; Sapphire tips
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Percutaneous transluminal laser angioplasty with a pulsed Nd-YAG laser (1064 nm wavelength, 100μs pulse duration, up to 0.4 J per pulse, 10 Hz repetition rate) coupled to optical fibres with sapphire tips of 1.8 and 2.2 mm diameter was performed under experimental conditions and then in 30 chronic occlusions of femoral and popliteal arteries in 22 patients. The experimental study in 11 human cadaverous arteries revealed that this laser system was effective in the recanalization of seven femoropopliteal occlusions, but the relative rigidity of the sapphire-tipped contact probe prevented its access to two infrapopliteal vessels. Two perforations occurred after the recanalization of 18 and 15 cm, respectively. Clinically the procedure was successful in 17 out of 25 sessions (68%). The probe formed a primary channel of at least 2.0 mm width which was further dilated by conventional balloon catheter. Ankle/brachial systolic pressure index (ABPI) increased from 0.43±0.13 to 0.79±0.21 after the procedure. In eight cases complications occurred. Two reocclusions were treated by Streptokinase infusion, two procedures were repeated 2 months later, one patient was referred to elective bypass surgery, and three patients were treated conservatively. Six patients were followed-up for more than 6 months. In one patient claudication of 400 m reappeared. ABPI showed a moderate decrease from 0.84±0.20 to 0.69±0.19. These first results are encouraging and it is likely that this method could become an important adjunct to balloon angioplasty.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    ISSN: 1435-604X
    Keywords: Laser angioplasty ; Coronary artery disease ; Nitrogen laser ; Tissue fluorescence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract To determine the fluorescence pattern for distinguishing normal (N) from calcified and fibrous plaque (P), fluorescence spectra of cadaveric aorta were measured with a spectrofluorometer. Emission (Em) and excitation (Ex) spectra corrected for instrumental response were obtained from 200 to 1000 nm. Specimens from 50 patients were measured less than 24 h after autopsy and then examined histologically. Spectra from 25 specimens demonstrated that the ratio of fluorescence intensity 460 nm/385 nm with Ex=337 nm provided separation of N from P (1.53±29 vs 0.82±0.25,p〈0.01) and that a ratio of 1.25 correctly identified all N and P. A prospective test of this ratio on an additional 25 specimens yielded a significant difference between N and P (1.70±0.37 vs 0.87±0.23,p〈0.0001) with a value of 1.25 correctly identifying all (10/10) N and 93% (14/15) P. Prospective analysis of previously proposed fluorescence ratios (600 nm/580 nm at Ex=480 nm; 530 nm/550 nm at Ex=459 nm; 448 nm/514 nm and 538 nm/514 nm at Ex=337 nm) all resulted in poor separation of N from P. The ratio of 460 nm/385 nm with Ex=337 nm is superior to previously reported criteria for distinguishing N from P and may be useful for guiding laser angioplasty systems.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    ISSN: 1435-604X
    Keywords: Photodynamic therapy ; Skin photosensitivity ; Antihistamines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract We have investigated the incidence of cutaneous phototoxicity in 47 patients who received photodynamic therapy between April 1988 and March 1990. Of these, 15 patients received antihistamines as part of a pilot study to evluate their photoprotective role. Patients were followed-up for a minimum of 8 weeks. One out of the fifteen who received antihistamines and 15 out of the 32 patients who did not (p〈0.005), developed cutaneous phototoxicity. On the basis of these results we have initiated a randomized double-blind trial to evaluate the role of antihistamines in haematoporphyrin derivative-induced cutaneous phototoxicity.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    ISSN: 1435-604X
    Keywords: Atherosclerosis ; Alexandrite ; Angioplasty
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Pulsed ultra-violet excimer laser radiation is capable of tissue ablation with only minimal thermal injury of adjacent tissue structures. Since difficult fibre optic coupling of energy was observed, alternative Q-switched laser sources capable of ablation of atherosclerotic plaque are under current investigation. To evaluate tissue effects of Alexandrite laser radiation, 160 arterial segments with macroscopic evidence of atherosclerotic disease were treated. The laser light was transmitted via silica based quartz fibres with different diameters. Using the Q-switched Alexandrite laser at the fundamental wavelength (748 nm) with a pulse duration of 300 ns the energy density threshold for tissue ablation was found to be in the range of 63 to 126 J cm−2 using a 300μm fibre. On macroscopic examination only limited thermal and acoustic injury was found in crater adjacent tissue structures. Crater edges were even and did not reveal signs of crater charring or debris in the crater lumen. However, the histological cross-sections revealed thermal injury extending from 100 up to 200μm lateral into adjacent tissue. The crater margins revealed fissuring as a result of shock wave injury. Thermal damage was most evident if irradiation of atherosclerotic tissue was performed in blood.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 215-215 
    ISSN: 1435-604X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 223-233 
    ISSN: 1435-604X
    Keywords: Angioplasty ; Recanalization ; Laser ; Balloon ; Intravascular ultrasound ; Restenosis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract The current state of clinical laser angioplasty is reviewed. Compared to balloon dilation at the beginning of the past decade, both peripheral and coronary laser angioplasty devices produce better results. Compared to current balloon angioplasty techniques, however, laser angioplasty does not seem to offer improved initial or long term results. Intravascular ultrasound imaging may help to improve laser ablation of atherosclerotic plaque. It remains to be established, however, whether precise debulking of the obstruction will result in a reduced restenosis rate compared to balloon angioplasty.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 241-254 
    ISSN: 1435-604X
    Keywords: Laser angioplasty ; Photoablation ; Photohydraulic effect ; Fast thermal explosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Besides the coagulation, where the body digests the necrotic tissue and direct evaporation of tissue, the photoablation effect turns out to be very important in tissue removal. In the case of high tissue absorption the process channels in photoablation can either be photochemical (bond breaking) or fast thermal. In the case of transparent media, a plasma formation due to high irradiances and an optical breakdown is necessary for ablation or photodisruption. All the process channels lead to a fast microscale explosion and to Shockwaves. For soft tissue the main process channel is the fast thermal explosion. Assuming that tissue will be disintegrated, if the energy deposited within a single laser pulse is larger than a material specific threshold, the thresholds for the radiant exposure and ablation rates respectively can be calculated. There is a large difference, whether the laser radiation is applied to the tissue surface in noncontact or through a fibre in contact. In contact the ‘fast thermal explosion’ happens in a closed chamber and hence the photohydraulic effect will support the photoablation. The thermally damaged zone in the surrounding tissue depends on the optical penetration depth mainly in cases that the pulse duration is shorter than a critical time given by the heat conductivity. Pulsed lasers can be used ‘non-thermally’ only if the average power is less than a tenth of a watt. With a higher amount of average power a pulsed laser will act comparable to a cw laser.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 289-296 
    ISSN: 1435-604X
    Keywords: Atherosclerosis ; Dihaematoporphyrin ether/ester, DHE ; Haematoporphyrin derivative, HPD ; Laser angioplasty ; Laser-induced fluorescence ; Plaque
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Selective fluorescence-marking of plaque offers new possibilities in cardiovascular diagnosis and therapy. Angioscopic investigations and spectrometry-assisted laser angioplasty will be simplified and more effective as compared with methods of today. It might help to make laser angioplasty a further promising interventional method to overcome, at least partially, the problems caused by atheromatous or atherosclerotic changes in the cardiovascular system. Fluorescence detection and imaging of markers is usually limited by the intrinsic fluorescence of tissue. Optical differential methods in combination with two-wavelength laser excitation and computer-assisted image processing, however, allow for discrimination of background-related signals and enable plaque detection and imaging at a high contrast. Plaque consists of either fibrotic, lipoid, or calcified depositions and is rather bradytrophic. For that reason in vitro experiments on human specimens post mortem seem to be justified and of clinical evidence. Due to intrinsically different fluorometric properties of plaque and normal vascular tissue imaging of marker-free plaque areas is possible. Additionally the specimens have been incubated with a haematoporphyrin-containing fluorescence marker at concentrations of 10–40μg ml−1 and incubation times of 60 min in order to obtain a corresponding increase in contrast. Lipoid depositions show the highest contrast because of lipophilic properties of the marker, while fibrotic and calcified plaque is slightly less effectively marked. The results, however, so far obtained indicate that fluorescence detection of plaque promises further progress in diagnosis and therapy of cardiovascular diseases.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 317-321 
    ISSN: 1435-604X
    Keywords: Laser angioplasty ; Coronary artery disease ; PTCA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Excimer laser angioplasty is an alternative method for the treatment of obstructive coronary lesions. Initial clinical results demonstrated the safety and feasibility of the procedure. However, efficacy was limited by low catheter flexibility and unreliable energy transmission. Advanced transmission devices were used in 80 interventions in 79 patients. The catheter diameter is 1.3, 1.5 or 1.8 mm, the catheters consist of 20, 30 or 35 quartz fibres (100 μm) respectively. The mean energy density was 55 ±18 mJ mm−2, mean loss of energy transmission was 20%. The pulse width was 60 ns and 115 ns in 40 interventions each. The target vessel was the LAD in 53, the LCX in 6 and the RCA in 21 interventions. Failure of laser angioplasty occurred in 10 patients due to failed guidewire placement (N=6), failed catheter placement (N=3) or impossibility to cross the lesion with the catheter (N=1). Stand-alone laser angioplasty was performed in 43/70 procedures. Additional balloon angioplasty was necessary due to an unsatisfactory result (N=10) or due to complications (N=17) in 27 patients. Vessel occlusion occurred in 18 patients (25%) and could be successfully resolved by balloon dilatation (N=16) or additional laser angioplasty (N=1) in 17 patients. Two early occlusions were found at the 24-h control angiography. The incidence of myocardial infarction and in-hospital death (N=1) was 1.4%. Conclusion: The use of an advanced energy delivery system with trusted energy transmission and higher energy density increased the primary success rate of stand-alone excimer laser angioplasty. However, further improvement of catheter flexibility and reduction of dead space at the catheter tip is necessary to optimize ablation efficacy.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 339-347 
    ISSN: 1435-604X
    Keywords: Xenon chloride ; Excimer laser ; Coronary angioplasty
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Photochemical ablation of coronary artery atheroma using pulsed xenon-chloride excimer laser has, over the past 18 months produced promising results. Worldwide experience amounts to some 2000 cases. In the first 6 months following installation of the Dymer 200+ laser (Advanced Interventional Systems, Irvine, California, USA) at St. Thomas' Hospital, 53 procedures have been performed in 49 patients. Of these, 52.8% were ‘high risk’ (triple vessel disease, unstable angina, LV ejection fraction 〈35%, need to treat sole remaining coronary conduit). Complications were two in hospital deaths (18 and 48 h post-procedure-3.8%); one ELCA related myocardial infarct (1.9%); two haemorrhage requiring transfusion (3.8%); no emergency bypass graft surgery (0%). Current indications for the use of laser include: (1) long-segment diffuse disease; (2) proximal or ostial stenoses in coronary artery or graft; (3) restenosis after balloon angioplasty; (4) total occlusions crossed by a guidewire; (5) severe stenoses crossed by guidewire but not balloon; and (6) bifurcation lesions or stenoses compromising an important side-branch. Potential complications include: arterial perforation; aneurysm formation; peripheral embolization by plaque material; abrupt thrombotic closure; dissection; late sudden occlusion; spasm; and restenosis. Minor problems at the start of the programme involved: modifications to the machine to meet local laser safety requirements; special gases required for the machine; supply and design of fibre optic catheters; guiding catheters; heparin dose; dissection of the coronary artery (major and minor); and selection of patients.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 371-371 
    ISSN: 1435-604X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 429-435 
    ISSN: 1435-604X
    Keywords: TEA CO2 laser ; Ablation ; Thermal modelling ; Pulse width ; Gelatin ; Absorption coefficient
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Ablation of gelatin samples was performed by using a semiconductively preionized TEA CO2 laser, emitting pulses of the lower TEM mode, 100 ns duration, at a repetition rate of 2.4Hz. Ablation rate experiments were performed at a range of fluences from 2J cm−2 to 10J cm−2. Assuming that the absorption coefficient is much larger than the scattering coefficient, experimental data were explained by simple models of ablation. The ablation depth per pulse and the specific absorption depth were calculated from the experimental data.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    ISSN: 1435-604X
    Keywords: Photodynamic therapy ; Tumour ; Haematopor-phyrin derivative ; Photoproduct ; Laser illumination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Illumination of haematoporphyrin derivative in phosphate-buffered solutions causes the formation of a stable photoproduct with new absorption and fluorescence bands. We report data showing photodynamic activity of the photoproduct. Praestomic tumour OJ-5, carcinosarcoma W-256 (mice) and adenocarcinoma Akatol of colon (rats) have been used. Dynamics of tumour growth, life span of animals and morphological changes of tumour tissues have been the main criteria used to show the photoproduct activity.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    ISSN: 1435-604X
    Keywords: Tissue optics ; Absorption ; Scattering ; Fluence distribution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract This paper is the second of two reviewing the propagation of electromagnetic radiation of wavelength 0.25–10μm in tissue. This part begins with a discussion of how the fundamental optical interaction coefficients of tissue may be measured. Both direct methods, in which the coefficients are measured for optically thin samples, and indirect methods, in which the coefficients are inferred from measurements on bulk samples are described. The difficulties inherent in both types of measurement are outlined. Next the wavelength dependence of the scattering and absorption coefficient is discussed, both from a heuristic point of view and by illustration from current literature. We illustrate how the optical spectrum can be divided into regions where the propagation of light is dominated by absorption or scattering effects. Finally we show how the distribution of light fluence in these spectral regions is dramatically different and illustrate the important features of these distributions.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
    ISSN: 1435-604X
    Keywords: Laser bronchoscopy ; 1.32μm Nd-YAG laser
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Endoscopic laser treatment for tracheobronchial malignancy is usually given with the neodymium-YAG laser using the 1.064μm output beam. However, recent experimental work suggests that the 1.32μm output beam of this laser has more desirable tissue effects. We have now treated 55 patients with the 1.32μm Nd-YAG laser (MBB-Medizintechnic) under general anaesthesia, using power settings of 10–20 W and pulse durations of up to 1 s. The indications for treatment were localized airway obstruction in each case. Airway calibre was improved in 46 (84%) patients and this was associated with an improvement in symptoms of cough and breathlessness. Patients with tracheal and carinal obstruction exhibited the most striking clinical improvements with up to four-fold increases in peak expiratory flow. In patients with more peripheral endobronchial obstruction, treatment improved airway calibre less frequently and resulted in a smaller clinical improvement. Of 11 patients with obstruction of a main bronchus and lung collapse, treatment led to partial or complete re-expansion in 10 cases (91%). The 1.32μm wavelength allows treatment to be conducted efficiently and safely but at a considerably lower power than is required for the 1.064μmwavelength. The ability to use low powers has the apparent advantage of generating only negligible quantities of smoke. Our experience with this new laser system demonstrates its considerable potential in the management of tracheobronchial malignancy.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 63
    ISSN: 1435-604X
    Keywords: Autofluorescence ; Fluorescence ; Laser spectroscopy ; Tumour detection ; Tumour diagnosis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract Laser-induced autofluorescence spectra from humans were recorded in vivo at three different clinics in a study aimed at investigating the capability of this method to discriminate between malignant tumours and normal surrounding tissues. For the recordings a mobile trolley with the necessary equipment was constructed for use in an examination room or in an operating theatre environment. Laser light was guided through a 600μm optical fibre to the target tissue. The fluorescence from the excited tissue was collected with the same fibre and was fed to an optical multichannel analyser. Two excitation wavelengths were used (337 and 405 nm) in order to optimize the fluorescence signals in two interesting wavelength regions (380–500 and 550–700 nm). Oral and oropharyngeal tumours excited with 405 nm light contained detectable endogenous porphyrins and were in this way discriminated from the normal mucosa. Astrocytoma grade III–IV fluorescence different from that of normal brain tissue, while tumours in the bronchial tree were not detectable using the spectral shape of the pure tissue autofluorescence.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    Electronic Resource
    Electronic Resource
    Springer
    Lasers in medical science 6 (1991), S. 451-455 
    ISSN: 1435-604X
    Keywords: Larynx ; Endoscopic microlaryngeal surgery ; CO2 laser
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Physics , Technology
    Notes: Abstract The value of functional and reconstructive surgery to the larynx in the treatment of malignant tumours to preserve residual function as far as possible has been clearly demonstrated. A further step in the development of ‘functional surgery’ is classical microsurgery of the larynx which facilitates diagnosis and endoscopic microsurgical treatment of benign tumours. However, recently following the introduction of the carbon dioxide (CO2) laser it has been shown that it is possible to treat also malignant tumours of the larynx by endoscopic microsurgery. An incision made by the photo-thermal CO2 laser scalpel is characterized by the relative absence of bleeding, lack of post-operative oedema, rapid epithelialization without associated infection or cicatrization and this results in optimal post-operative laryngeal function. This paper presents the results of treatment of selected cases of T1 and T2 carcinoma of the glottis treated by CO2 laser excision under microlaryngoscopic control. In this series healing was rapid with minimal hospitalization and without a tracheostomy. Excellent functional results were achieved and the patient was able to return rapidly to his original occupation. It is our opinion that at present this treatment modality represents the optimal treatment for T1 and T2 carcinoma of the glottis.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 33-40 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Substituted poly(cyclohexene)s, used as poly(phenylene) precursors, have been prepared by radical polymerization of cyclohexadiene-1,2-diol derivatives containing various leaving groups. The precursors were converted into poly(phenylene) either by curing at elevated temperatures or by deep-UV exposure in the presence of a photoacid generator. These reactions were investigated by both IR and UV analysis. Our results with the conversion of precursors into poly(phenylene) via photoaromatization suggest that polyphenylene precursors can be imaged by deep-UV microlithography (as a new class of photoimageable thermally stable polymers).
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 117-122 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The cationic polymerization of various α- and β-substituted vinyl ethers, initiated by 1-iodo-1-(2-methylpropyloxy)ethane 1 and tetrabuty lammonium perchlorate (TBAP) was investigated. The polymerization of 2,3-dihydrofuran (DHF, 3a) in CH2Cl2 at -40°C proceeds via opening of the ethylenic double bond and yields polymers with narrow molar mass distributions and high glass transitions. The number average of molar mass increased linearly with conversion. Under these conditions, a controlled polymerization of two propenyl ethers (1-ethoxypropene 2a and 2-methoxypropene 2b) and two other cyclic unsaturated ethers (3,4-dihydro-2H-pyran 3b and 5-methyl-2,3-dihydrofuran 3c) could not be achieved. Either transfer reactions or the decomposition of 1 prevented the formation of high molar mass polymers of these vinyl ethers.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 555-560 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary 3-Vinylbenzothiophene was synthesized and its copolymerization with methyl methacrylate and n-butyl acrylate was investigated. The copolymerizations were performed according to an experimental design scheme and the results were analyzed using a nonlinear error-in-variables method. The 3-vinylbenzothiophene was found to be a reactive monomer with reactivity ratio values similar to those of 2-vinyl thiophene.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 561-568 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Isotactic (it-) and syndiotactic (st-) MMA oligomers from 19-mer to 29-mer could be isolated efficiently from it-PMMA ( $$\overline {DP}$$ = 28.6) and st-PMMA ( $$\overline {DP}$$ = 28.6) (sample load: 50 mg) by the SFC using a 10 mm i. d. x 250 mm column packed with silica gel. DP of each isolated oligomer was determined by FD mass spectroscopy, and the values agreed well with those calculated from the relative intensity of 1H NMR signals due to CH3O- and the terminal t-C4H9-groups. Glass transition temperature (T g) of the it-28-mer measured by DSC was 34.5°C, which was higher than that of the it-PMMA by 6.5°C. T g of both the it-and st-oligomers increased linearly with DP in the range of DP=20∼29. A 1: 1 mixture of the it- and st-27-mers annealed at 140°C showed an endothermic transition at 102.3°C which was attributable to melting of stereocomplex, whereas an annealed 1: 1 mixture of the it- and st-PMMAs had a much broader endotherm around 80∼140°C.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The coordination structures of Cu(II) complexes of amino functions supported on polyacrylamides with varying extents of NNMBA-crosslinks were followed by EPR techniques. The geometry of the Cu(II) complexes changes with increasing crosslinking. The covalency of the Cu-N bond also depends on the extent of the NNMBA-crosslinking in the polymer-support.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 601-606 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The sorption behaviour of copper (II) and uranium (VI) ions on branched poly(ethylenimine) (BPEI) bridged with bifunctional crosslinkers (CR), 1-chloro-2,3-epoxypropane, 1,3-dibromopropane and 1,2-dibromoethane with various degress of crosslinks has been examined. The effect of crosslinking on the extent of sorption and thermal stability is reported.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The mesophase formation was observed from the system of mixed organic polymer (hydroxypropyl cellulose) and inorganic polymer (imogolite) in acetic acid aqueous solution. The phase diagram of the mesophase formation was drawn as a function of imogolite content. The mesophase structure was found to change from the helicoidall arrangement of nematic sheets to the pile of pleated nematic sheets with increasing imogolite content.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary First unsaturated polyester fibers were prepared starting from stereoregular, macromolecular poly(octamethylene fumarate). Fibers obtained from octamethylene copolyesters of fumaric and terephthalic acids manifested improved mechanical properties and higher melting points. All unsaturated polyester fibers prepared in the study, based on the homopolymer and on copolymers of fumaric acid, even those containing as low as 10% of fumaric acid residues, are able to be covalently bonded to an unsaturated polyester matrix.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 633-638 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Propylene oligomers containing isopropenyl end group have been prepared by thermolysis of atactic polypropylene. The chain-end structures and the number-avarage isopropenyl chain end functionality was determined in the product by C-13 NMR spectroscopy. Molecular weight of the oligomers were between 300 and 1000, as characterized by GPC. Conditions leading to the formation of propylene oligomers with number-average isopropenyl chain end functionality of 1.0, have been worked out.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 653-656 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The photoaddition of aromatic dithiols (1) onto aliphatic alkenes (2a-2c) yielding polysulfides is studied. Polysulfides having anti-Markownikow and Markownikow moieties in the main chain are obtained by the reaction of dithiols (1) with ethyleneglycoldivinylether (2a). The unusual Markownikow orientation is explained on the basis of a radical cation intermediate.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Radical polymerizations of vinyl monomers using a initiator of 2,2′-azobis(2-amidinopropane) dihydrochloride on monodispersed silica colloid led to formation of spherical polymer/SiO2 composites, retained particle size. Addition of hydroxypropyl cellulose to the reaction system resulted in yielding excellent dispersible composites into ethanol by short period ultrasonic irradiation. The polymerization of styrene in the presence of mercapto-amine or carboxylic acid derivatives could successfully introduce amino or carboxyl group on the Poly(styrene)/SiO2 composite.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 689-695 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The interrelation between the electrical conductance, σ and some chemically modified cellulose molecule produced through partial substitution of the hydroxyl groups by different groups namely, acetate, methoxyl, carboxymethyl and sodium carboxymethyl has been studied in the temperature ranges 283–333 k. The results show that σ of the examined samples change in the descending order: sodium carboxymethyl cellulose 〉carboxymethyl cellulose 〉methyl cellulose〉cotton cellulose〉cellulose acetate. The variable response of σ to the chemical modification and the physical changes of cellulose accompanying such modification has been discussed in terms of the molecular structure, chain flexibility and degree of polymerization of the examined samples.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 697-702 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Acidic parameters according to the GUTMANN's acceptor numbers (AN) of cellulose acetates and unmodified cellulose have been determined by means of the negatively solvatochromic probe dye Fe(phen)2(CN)2. Unmodified cellulose possesses a relatively high acceptor strength due to cooperative hydrogen bonds while increasing acetate contents in the polymer chain lower the acceptor strength. The dependence of AN on the acetate content can be used to estimate the degree of substitution (DS). Pecularities in the substitution interval (DS=0 to DS=1.5) are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 677-681 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The complex forming poly[(ethylene glycol-co-proplene glycol)-g-acrylamide]: polyacrylic acid interpenetrating polymer network hydrogel is able to bend under electric field “stimuli”. pH, ionic strength gradients and voltage can influence it's bending degree. So we may improve the sample' “responsive” speed through manipulating those factor in the further study in order to put it into the biomedical application.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 449-450 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary An original way of reducing composition heterogeneity has been proposed for copolymers obtained at high conversions. The main idea underlying this method consists in application as initiators of special compounds (iniferters) leading to alteration of the mechanism of polymer chain growth.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A reaction scheme based on propagation and intramolecular chain transfer steps is proposed for the anionic homopolymerization of epoxides initiated by tertiary amines. Chain transfer regenerates a living chain and gives a dead chain with terminal vinilydene unsaturations and hydroxy groups. The possibility of generating phenols or substituted phenols is also considered. Molecular-mass distributions were predicted as a function of conversion by both kinetic and Monte Carlo methods. Predictions were compared with experimental results reported in the literature. The evolution of the number-average degree of polymerization could be reasonably predicted.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 481-487 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The coefficient of thermal expansion is measured for irradiated Polyvinyl Chloride (PVC) from 10K to 340K. The samples of PVC are irradiated, up to 500 Mrad in steps of 100 Mrad, in air at room temperature by using Co gamma rays with a dose rate of 0.3 Mrad/h. The PVC is an amorphous sample which is confirmed by X-ray diffraction. The coefficient of thermal expansion is found to decrease with radiation dose from 10K to 110K and it increaseswith radiation dose from 110K to 340K. The results are explained on the basis of radiation induced degradation of the sample.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. A4 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 497-503 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The synthesis of telechelic monodispersed diols produced from the radical telomerization of an excess of undecylenol with commercialy available α, ω-dithiols HSC2H4XC2H4SH (X=0, S or CH2) initiated by peroxides is presented. In each case, the diols were obtained selectively and quantitatively and they were characterized by both 1H and 13C NMR. Their physical characteristics (Tg, Tm and decomposition temperatures) were determined. Such compounds are thermally more stable than polydispersed telechelic commercially available diols.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 505-509 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The anionic polymerization of dimethylphenylvinylsilane with sec-butyllithium/N,N,N′,N′-tetramethylethylenediamine (TMEDA) was investigated. The polymerization proceeded up to 100% yield and afforded the polymer having isomerized-structure units. The polymerization was accompanied by chain transfer reaction to the monomer and the polymerization rate in the presence of TMEDA was much lower than in the absence of TMEDA.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Methacrylation of triglycidyl triphenyl methane (via methacrylic acid) has been done using three catalysts: dimethyl dodecyl amine (DMDA), tetrabutyl ammonium bromide (TBAB) and chromium (III) diisopropyl salicylate (Cr Dips). The reaction has been followed by epoxy colorimetric titration, CPG and 1H NMR. This study has shown the superiority of chromium catalysis because of its rapidity and ease of process. Then, these cured products (TACTIX and methacrylated TACTIX) show homogeneous Tg values which are higher than 200°C.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 639-644 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polyesters from 3,3′-bis(chloromethyl)oxacyclobutane and dipotassium isophthalate were obtained by phase transfer catalysis using different catalysts and solvents. The products were characterised by IR,1H-NMR and DSC.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 645-652 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polycarbonates, polythiocarbonates, and polyesters from 1,1,3-trimethyl-3-(4′-hydroxy-phenyl)-4-indanol were synthesized using phase transfer conditions. THe effects of several catalysts and reactions times were evaluated by the yields and inherent viscosities. Phase transfer catalysis was not an efficient technique due to the rigid structure of the diphenol with the indanic group. The results were compared with that obtained with a diphenol having the same number of carbon atoms but forming an aliphatic side chain.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 657-662 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary 1,2,3-Triphenylcyclopropene (TPCP) is a powerful retarder for polymerizations of methyl methacrylate (MMA) and styrene initiated by benzoyl peroxide or azobisisobutyronitrile. End-groups in polymers of MMA were studied by 13C-NMR spectroscopy and also, in the case of the peroxide, by using radioactive initiator. It was shown that, towards the benzoyloxy and 1-cyano-1-methylethyl radicals, the reactivity of TPCP exceeds that of MMA by factors of about 60 and three respectively at 60°C. TPCP can be used to introduce into polymers end-groups of special types.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The influence of solvent on polyvinylpyrrolidone (PVP) and polyitaconic acid monomethylester (PMMI) sterecomplex formation was studied by means of laser light scattering and viscometry. Several phase changes were observed, from homogeneous solution to precipitates and gels. Responsible of this behaviour are hydrogen bonding, Coulombic forces, or hydrophobic interaction in aqueous medium.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 28 (1992), S. 703-707 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The Lewis and Mayo's rule, used so far for the determination of r1 and r2, is presently applied for the simultaneous determination of partial monomers conversions α1 and α2; whereas the integration of the Skeist's rule gave global conversion α only. An experimental verification is performed for the cotelomerization of MMA and maleic anhydride with dodecyl mercaptan as telogen, and it gives a very good correlation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract An anomalous effect on the twisted intramolecular charge transfer (TICT) phenomenon of 4-(N,N-dimethylamino) benzonitrile (DMABN) dissolved in elastomers such as poly(propylene oxide), poly(ethylene oxide) has been observed. Under irradiation, the normal fluorescence of DMABN in these matrices has been found to increase strongly while the emission arising from the TICT state decreases slightly.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 23 (1990), S. 35-42 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Active centers have been studied in the polymerization of propylene using highly active Mg(OEt)2/Benzoyl chloride/TiCl4 catalysts activated with AlEt3. The method for the measurement of active centers is based on the inhibiting effect of CO on polymerization. The activity of the present catalysts, which is higher than that of TiCl3 or MgCl2-supported catalyst, is mainly due to the higher concentration of active centers by one order of magnitude. In order to investigate the stability of active centers during polymerization the number of active centers are compared at various polymerization times.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The influence of the total monomer concentration on the radical reactivity ratio r1 of butyl methacrylate (BMA) (M1)-ω-(p-vinylbenzyl ether) macromonomer of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO-VBE) (M2) monomer pair was investigated. For two different molecular weights of the PPO-VBE macromonomer ( $$\bar M_n = 14,000$$ , $${{\bar M_w } \mathord{\left/ {\vphantom {{\bar M_w } {\bar M_n }}} \right. \kern-\nulldelimiterspace} {\bar M_n }} = 1.25$$ and $$\bar M_n = 5,300$$ $${{\bar M_w } \mathord{\left/ {\vphantom {{\bar M_w } {\bar M_n }}} \right. \kern-\nulldelimiterspace} {\bar M_n }} = 1.26$$ ), the determined reactivity ratio r1 decreases with the increase of the macromonomer concentration. Therefore, the reactivity of the macromonomer, 1/r1, follows the opposite trend. This dependence is due to micelles formation during copolymerization. This microsegregation process partitionates the comonomer concentrations between the bulk of solvent and around the growing chain and therefore, the experimental r1 is actually a product of the true reactivity ratio r1 0 and a partition coefficient k.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 23 (1990), S. 7-12 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The 2,2 bis(4-ethynylphenyl)hexafluoropropane is prepared via an original synthesis's process using a substitution of 2,2 bis(4-triflatephenyl) hexafluoropropane by trimethylsilyl acetylene. In this process ZnO is used to remove the triflate anion formed during the reaction. This diacetylenic compound melts at 37–38°C, exhibits an onset of polymerization at 120°C. After thermal treatment at 250°C, the obtained network shows a softening point at 300°C. This network remains stable in air up to 435°C.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 23 (1990), S. 89-94 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The DC conductivity of two networks — a poly(N,N-diethylacrylamide) network (N1) and a network prepared by the copolymerization of N,N-diethylacrylamide with 3 mol.% of sodium methacrylate (N2) — in deionized water in the temperature range 10–55°C was measured. While in the low-temperature range (expanded gel state) the volt-ampere (V-A) behaviour of both networks shows a semiconductive character (conductivity increases with increasing temperature), in the high-temperature range (collapsed gel state) the conductivity of the network N1 rapidly decreases with increasing temperature (metallic character). The presence of charges on the chain raises the conductivity and shifts the temperature of the change in conductivity to higher values. In the collapse region of the ionized network N2 anomalies were observed on the V-A characteristics.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Packed column SFC has been found suitable for the rapid and detailed analysis of the isotactic and syndiotactic oligomers of MMA, when the temperature gradient technique was applied and the modifier was employed. Oligomer components from trimer to 20-mer separated completely. The heptamer fraction collected three times by SFC gave the 1H NMR spectrum of satisfactorily high S/N ratio; the spectrum agreed well with that of the standard sample. Separation by tacticity as well as by molecular weight was observed for the SFC of a mixture of the isotactic and syndiotactic oligomers. The isotactic oligomers had longer retention time than the syndiotactic oligomers of the corresponding degree of polymerization.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 23 (1990), S. 177-184 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary 1,4-Bis[2-(4′,4″-diheptyloxyphenyl)ethynyl]benzene and 1,4-bis[2-(3′,3″-dimethyl-4′,4″-diheptyloxyphenyl)ethynyl]benzene were synthesized by a one pot phase transfer Pd(O)/Cu(I) catalyzed three step coupling of 1,4-diiodobenzene with 2-methyl-3-butyn-2-ol and the appropriate aryl halide. Both compounds display mesomorphic behavior similar to that of the analogous 1,2-(4,4′-dialkoxyaryl)acetylenes, except that the temperature window of each phase is stabilized, such that an enantiotropic mesophase is even observed in the derivative containing a methyl branch in the mesogen. Both compounds form mesomorphic EDA complexes with p-chloranil as electron acceptor, and display a depression of the nematic-isotropic transition temperature.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The reaction of trimethylsilyl iodide (TMSI) with 1,3-dioxolane (DXL) leads to the formation of 1-trimethylsiloxy-4-iodo-3-oxabutane. In combination with tetrabutyl ammonium triflate this compound can be used as an initiator for the polymerization of vinyl ethers. According to a living polymerization mechanism, the polymers are characterized by controlled molecular weights and narrow molecular weight distributions. The trimethylsiloxy head group originating from the initiation reaction is easily transformed into a primary hydroxyl function by hydrolysis.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 23 (1990), S. 525-527 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Some three years ago in a preliminary report from this laboratory we have proposed that the polymerization of isobutylene (IB) by the γ-tolyl-γ-valerolactone/BCl3 initiating system in CH3Cl or CH2Cl2 diluents at-30°C proceeds in a living manner by an unusual ring expansion mechanism and produces macrocyclic polyisobutylenes (PIBs) [1]. Extensive follow-up research confirmed the living nature of the polymerization, however, has failed to confirm the results of a key preliminary experiment upon which the proposition of macrocyclic polymer structure was based. Thus the results of a comparative hydrolysis/GPC experiment carried out with a relatively low molecular weight (Mn=5,400) PIB at -30°C under a blanket of N2 which gave a lower apparent molecular weight after hydrolysis than the original sample before hhydrolysis, could not be confirmed with higher molecular weight samples, i.e., with Mn=12,000, 17,000 and 30,000. As a consequence we wish to retract our earlier claim in regard to the synthesis of macrocyclic PIBs by certain lactone/BCl3 initiating systems but maintain that these polymerizations proceed in a living manner and yield asymmetric telechelic PIBs, e.g.,α-chloro-ε-carboxyl-PIBs [2].
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 23 (1990), S. 555-562 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The experimental results obtained by scanning tunneling microscopy (STM) studies of different carbon fibres are presented and discussed. The comparative analysis of the STM images at scales from hundreds of nanometers down to atomic scale reveals the differences of surface features for carbon fibres processed from different precursors, polyacrylonitrile fibres and pitch. The high temperature treatment of carbon fibres — the so-called graphitization process — as used to improve the stress modulus induces drastically increased ordering phenomena at the atomic level. Structural information obtained by STM on the surface of the fibres as well as in their cross sectional areas is discussed in comparison with known results of diffraction studies. STM appears to be the new powerfull technique for the detailed structural studies of surfaces of carbon fibres. The perspectives of these studies are under discussion.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...