ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
As in our previous studies, 0(3P), generated by titration with NO of microwave discharged N2 (He carrier), was mixed with B10H14 vapor (Ar carrier) in a flow-tube reactor. Levels of product OH were determined via LIF on an absolute basis, for dwell times 4 to 18 ms. The system was calibrated with C2H6, run under identical conditions. The reactants comprised approximately 1% of the flowing mixture. OH production is ≈62 greater from B10H14 than from B5H9 (under similar conditions but at somewhat lower temperature). FTIR analyses of a solid product that condensed downstream on cold surfaces showed the presence of —B—O—H⃜O—B— hydrogen bonds and matched (but not perfectly) the calculated frequencies of HB(OH)2. © 1994 John Wiley & Sons, Inc.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550260206
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