ALBERT

Description: Vertical phytoplankton distribution, temperol fluctuations and sedimentation rates were studied in the central Baltic Sea during the "Baltic Sea Patchiness Experiment 1986" (PEX'86). Vertical particle flux was measured with free sediment traps deployed at 30 and 60m depth for ten April/May 1986 within the PEX grid (20 x 40 nautical drifting days in miles). In the vicinity of one drifting trap water samples were collected in 10-12 depths down to 70m and vertical profiles of temperature, salinity, beam attenuation and light intensity were measured at three hour intervals. Water samples were analyzed for Chl.a, POC and PON content, dry weight and nutrients. Particulate parameters including the activity of 137 Cs were measured in trap samples. Suspended and sedimented particulates were counted under an inverted microscope. Precision and accuracy of the microscopical counts are discussed and confidence limits are calculated for different spec1es and applied counting schemes. Errors in all cases were smaller than the observed in situ variability. A general description of spring blooms in the central Baltic is given and the particular situation of spring 1986 is summarized. Within the station grid of PEX'86 an anticyclonic eddy was observed in which this study was conducted. Here the phytoplankton had reached peak concentrations and mass sedimentation of diatoms was about to start. The bloom was dominated by Thalassiosira levanderi and Chaetoceros spp. (lOµm size). Achnantes taeniata, Mesodinium rubrum, Gonyaulax catenata and an autotrophic Gymnodinium species (26-30µm) were also abundant. Horizontal patchiness and advection caused greater variability in the distribution of phytoplankton biomass blooms as well as temperature and attenuation during the first days than during the latter half of the investigation period. In four different areas within the PEX grid different developed independently. On still smaller time and space scales, the phytoplankton species composition also changed. The degree of patchiness was different for different species. General concepts explaining vertical distribution patterns of phytoplankton by physical and biological mechanisms are discussed. The species-specific distribution of selected diatoms, dinoflagellates and of the funktionally autotrophic ciliate M.rubrum are described. None of the species were homogeneously distributed although no vertical density stratification was observed. Whereas the diatoms and M.rubrum were present within the whole trophogenic layer, the dinoflagellates were only found in the upper 30m. The vertical distribution was different for concentrations were encountered each at species and different maximum depths respectively. Mechanisms affecting species-specific distribution of mobile and non-mobile phytoplankters in isopycnal layers are discussed in light of the particular situation of this study. Diurnal vertical migration is shown for two dinoflagellates and the phytociliate and triggering factors are discussed. All three species migrated upwards during the day and downwards at night. In its detail, however, the migratory behaviour differed between species and also within single populations. Different strategies of adaptation of phytoplankton to changing environmental conditions are suggested: Wheras diatoms adapt to fluctuations of the light climate by physiological adaptations, mobile organisms have the possibility to stay in an isolume layer. The significance of turbulence, of chainformation and of resting stages in the life cycles of phytoplankton is also evaluated. Trap deployments reveiled that only T.levanderi and Chaetoceros spp. sedimented. Their daily relative sedimentation rates (losses as % of standing stocks) increased over time and were species-specific (for T.levanderi max. 50%). Since part of the T.levanderi population was actively dividing (20% of the standing stock was found as paired cells) their suspended concentration decreased slower than that of Chaetoceros spp., although the daily sedimentation of the latter species was only about 30% of the standing stock. T.levanderi occured in chains in the water column but only single cells were found in sedimented material and paired cells were never found in the trap samples. Chaetoceros spores were rare in the water column and only sporadically collected by the sediment traps. The relative sedimentation rate of all other species was less than 5% per day. The settling velocity of the cells was estimated in different independent ways to be about 40-60m/d. This high sinking speed was attributed to aggregate formation. The results indicate that aggregate formation is not only species-specific but also differs between life-stages within one species. Variability of sedimentation rates on a timescale of hours was high, suggesting a diurnal pattern. Sedimentation did not change the vertical distribution patterns, indicating that cells were sinking with similar rates from all depths. The advantages of a Lagrangian sampling strategy (time series measurements 1n the vicinity of a free drifting buoy) for investigating phytoplankton development in time are evaluated and compared to a sampling at a moored station (Eulerian approach). In an environment that exhibits an intense patchiness even at spatial scales of lOOm, as encountered in this study, the influence of advection and patchiness on a time-series with a resolution of hours to days can not be neglected even if the Lagrangian approach is followed. Furthermore, in this study the variability of var1ous parameters measured in an Eulerian mode was not generally higher than that following the Lagrangian one, as one would have expected.

Description: The Owen Ridge south of Oman represents oceanic crust that was uplifted by compressional tectonic forces in the early Miocene. Build-out of the Indus Fan led to deposition of a thick sequence of turbidites over the site of the Ridge during the late Oligocene and early Miocene. Early Miocene uplift of the Ridge led to a pelagic cap of nannofossil chalks. Two short sequences of turbidites from the pre- and syn-uplift phases were chosen for detailed grain size analysis. The upper Oligocene section at Site 731 is composed of thin (centimeter-decimeter scale) graded mud turbidites separated by relatively thick (decimeter-meter scale) intervals of homogeneous, non-bioturbated clayey siltstones. These finer intervals are unusually silt-rich (about 60%) for ungraded material and were probably deposited as undifferentiated muds from a series of turbidity current tails. By contrast, the lower Miocene section at Site 722 is comprised of a sequence of interbedded turbidites and hemipelagic carbonates. Sharp-based silt turbidites are overlain by burrow-mottled marly nannofossil chalks. The Oligocene sequence may have accumulated in an overbank setting on the middle fan - the local topographic position favoring frequent deposition from turbidity current tails and occasional deposition from the body of a turbidity flow. Uplift of the Ridge in the early Miocene led to pelagic carbonate deposition interrupted only by turbidity currents capable of overcoming a topographic barrier. Further uplift eventually led to entirely pelagic carbonate deposition.

Description: Titanomagnetites separated from 15 different rock samples (including ocean-floor basalts from DSDP Legs 37, 45 and 46) were analyzed together with whole-rock samples by instrumental neutron-activation analysis for Sc, Cr, Co, Zn, Hf, Ta, Th and the REE La, Ce, Nd, Sm, Eu, Gd, Tb, Dy, Tm, Yb and Lu. In titanomagnetities from ocean-floor basalts and some other rocks, REE are enriched with respect to the whole-rock composition by factors of between 1.5 and 3 for light REE and between 1.0 and 1.9 for heavy REE; that is, REE with larger ionic radii are preferentially incorporated into the magnetite lattice. Three magnetite samples are REE depleted. Their whole-rock samples contain P in appreciable amounts, so apatite, an important REE-accumulating mineral, could have captured REE to some extent. All titanomagnetites show a marked negative Eu anomaly, this is most probably caused by discrimination of Eu(2+) from the magnetite lattice. Co, Zn, Hf and Ta are significantly enriched in magnetites. The distribution behaviour of Sc and Cr is masked chiefly by the crystallization of clinopyroxene and therefore is not easy to estimate. Ulvöspinel contents of about 70% for the titanomagnetites from ocean-floor basalts were estimated from qualitative microprobe analysis. Ulvöspinel contents of all other samples varied in a wide range from 20% to about 90%. No correlation could be observed between this and the REE contents of the magnetites. Ilmenite exsolution lamellae could only be observed in titanomagnetites from a doleritic basalt from Leg 45.

Description: Times of vein mineral deposition in the ocean crust have been determined both by Rb-Sr isochron ages of vein smectites and by comparison of 87Sr/86Sr ratios of vein calcites with the known variations of seawater 87Sr/86Sr ratio with time. Results from drilling sites 105, 332B and 418A, Atlantic Ocean, which have basement formation ages of 155 m.y., 3.5 m.y., and 110 m.y., respectively, show that vein deposition is essenrially complete within 5-10 m.y. after formation of the basaltic crust. This provids direct evidence that hydrothermal circulation of sea-water through the oceanic crust is an important process for only 5-10 m.y. after crust formation.

Description: REE abundances in gabbros and peridotites from Site 334 of DSDP Leg 37 show that these rocks are cumulates produced by fractional crystallization of a primitive oceanic tholeiite magma. They may be part of a layered oceanic complex. The REE distributions in the residual liquids left after such a fractionation are similar to those of incompatible element-depleted oceanic tholeiites. The REE data indicate that the basalts which overlie the gabbro-peridotite complex, are not genetically related to plutonic rocks.

Description: 143Nd/144Nd ratios have been determined on 37 samples of oceanic basalt, with a typical precision of +/- 2-3 * 10**-5 (2 sigma). Ocean island and dredged and cored submarine basalts are included for which reliable measurements of 87Sr/86Sr ratios exist in the literature or have been measured as part of this study. A strong negative correlation exists between 143Nd/144Nd and 87Sr/86Sr ratios in basalts from Iceland and the Reykjanes Ridge, but such a clear correlation does not exist for samples from the Hawaiian Islands. However, when other ocean island basalts from the Atlantic are included there is an overall correlation between these two parameters. Increases and decreases in Rb/Sr in oceanic basalt source regions have in general been accompanied by decreases and increases respectively in Sm/Nd ratios. The compatibility of the data with single-stage models is assessed and it is concluded that enrichment and depletion events, which are consistent with transfer of silicate melts, are responsible for the observed variation.

Description: The book is devoted to investigations of benthic fauna and geology of the Southern Atlantic Ocean. These works have been carried out in terms of exploring biological structure of the ocean and are of great importance for development of this fundamental problem. They are based on material collected during Cruise 43 of R/V Akademik Kurchatov in 1985-1986 and Cruise 43 of R/V Dmitry Mendeleev in 1989. Problems of quantitative distribution, group composition and trophic structure of benthos in the Southern Scotia Sea, along the east-west Transatlantic section along 31°30'S, and offshore Namibia in the area of the Benguela upwelling are under consideration in the book. Authors present new data on fauna of several groups of deep-sea bottom animals and their zoogeography. Much attention is paid to analysis of morphological structure of the Scotia Sea floor considered in terms of plate tectonics. Bottom sediments along the Transatlantic section and facial variation of sediments in the area of South Shetland Islands and of the continental margin of Namibia are under consideration.

Description: Comparison of rates of accumulation of organic carbon in surface marine sediments from the central North Pacific, the continental margins off northwest Africa, northwest and southwest America, the Argentine Basin, and the western Baltic Sea with primary production rates suggests that the fraction of primary produced organic carbon preserved in the sediments is universally related to the bulk sedimentation rate. Accordingly, less than 0.01% of the primary production becomes fossilized in slowly accumulating pelagic sediments [(2 to 6 mm (1000 y)**-1] of the Central Pacific, 0.1 to 2% in moderately rapidly accumulating [2 to 13 cm (1000 y)**-1] hemipelagic sediments off northwest Africa, northwest America (Oregon) and southeast America (Argentina), and 11 to 18% in rapidly accumulating [66 to 140 cm (1000 y)**-1] hemipelagic sediments off southwest America (Peru) and in the Baltic Sea. The emiprical expression: %Org-C = (0.0030*R*S**0.30)/(ps(1-Theta)) implies that the sedimentary organic carbon content (% Org-C) doubles with each 10-fold increase in sedimentation rate (S), assuming that other factors remain constant; i.e., primary production (R), porosity and sediment density (ps). This expression also predicts the sedimentary organic carbon content from the primary production rate, sedimentation rate, dry density of solids, and their porosity; it may be used to estimate paleoproductivity as well. Applying this relationship to a sediment core from the continental rise off northwest Africa (Spanish Sahara) suggests that productivity there during interglacial oxygen isotope stages 1 and 5 was about the same as today but was higher by a factor of 2 to 3 during glacial stages 2, 3, and 6.

Description: Recent studies of abyssal peridotites (Johnson et al., 1990, doi:10.1029/JB095iB03p02661), mid-ocean-ridge basalts (MORBs) (McKenzie, 1985, doi:10.1016/0012-821X(85)90001-9) and their entrained melt inclusions (Sobolev and Shimizu, 1993, doi:10.1038/363151a0; Humler and Whitechurch, 1988, doi:10.1016/0012-821X(88)90055-6) have shown that fractional melting of the upwelling sub-oceanic mantle produces magmas with a much wider range of compositions than erupted MORBs. In particular, it seems that strongly depleted primary magmas are routinely produced by melting beneath ridges (Johnson et al., 1990, doi:10.1029/JB095iB03p02661). The absence of strongly depleted melts as erupted lavas prompts the question of how long such magmas survive beneath ridges, before their distinctive compositions are concealed by mixing with more enriched magmas. Here we report mineral compositions from a unique suite of oceanic cumulates recovered from DSDP Site 334 (Aumento et al., doi:10.2973/dsdp.proc.37.1977), which indicate that the rocks crystallized from basaltic liquids that were strongly depleted in Na, Ti, Zr, Y, Sr and rare-earth elements relative to any erupted MORB. It thus appears that the magmatic plumbing system beneath the Mid-Atlantic Ridge permitted strongly depleted magmas to accumulate in a magma chamber and remain sufficiently isolated to produce cumulate rocks. Even so, spatial heterogeneity in the compositions of high-calcium pyroxenes suggests that in the later stages of solidification these rocks reacted with infiltrating enriched basaltic liquids.

Description: Refractory megacrysts of olivine, plagioclase, chromian diopside and Cr-Al spinel, which were not in equilibrium with the host oceanic tholeiite on eruption, are present in samples from several dredge sites and DSDP drill sites in the Atlantic and Pacific Oceans. They have multiple origins: (1) cognate or accidental mantle fragments; (2) relict fragments from fractional crystallization of parental liquids considerably more primitive than oceanic tholeiite; and most commonly (3) the fractional crystallization products of such liquids mixed with oceanic tholeiite magma. Melt inclusions in chrome-spinel phenocrysts provide evidence for this postulated Mg- and Ca-rich magma which has counterparts in the Scottish Tertiary Province and in west Greenland.

Description: Nodule samples obtained were described and studied on board for 1) observation of occurrence and morphology in and outside samplers, size classification, measurement of weight and calculation of population density (kg/m2); 2) photographing whole nodules on the plate marked with the frames of unit areas of both 0cean-70 (0.50 m2) and freefall grab (0.13 m2), and that of typical samples on the plate with a 5 cm grid scale: 3) observation of internal structures of the nodules on cut section; and 4) determination of mineral composition by X-ray diffractometer. The relation between nodule types and geological environment or chemical composition was examined by referring to other data of related studies, such as sedimentology. acoustic survey, and chemical analysis.

Description: Ziel dieser Arbeit war es am Beispiel zweier Schleswig-Holsteinischer Marschsedimente die Veränderungen des gestaltlichen Porengefüges bei geostatischer Kompaktion zu quantifizieren. In einem Vergleich mit Ergebnissen aus pF- und ku- Untersuchungen von Sedimenten derselben Standorte durch GUENTHER (1991) sollte überprüft werden, welche Parameter des gestaltlichen Gefüges die Veränderungen der funktionalen Eigenschaften bestimmen. Der Vergleich fand beispielhaft an unkompaktierten und kompaktierten Bodenproben statt. ff

Description: DSDP Leg 337 was planned as an attemp at deep penetration of the igneous section of the oceanic crust on the western flank of the FAMOUS (Franco- American Mid-Ocean Undersea Study) area of the Mid-Atlantic Ridge at 36°N. Site 332 is located in Deep Drill Valley approximately 30 km west of the axis of the Mid-Atlantic Ridge at 36°52'N latitude. The principal goal at this site was deep penetration into layer 2 of the ocean crust by multiple re-entry. Site 334 was drilled on a steep east-facing slope in a small, deep basin near the middle of magnetic anomaly 5. In this area, breccias with gabbro and peridotite clasts in a nannofossil-foram ooze matrix are interlayered with the plutonic rocks and may reflect exposure of a melange in or near the Median Valley of the Mid- Atlantic Ridge prior to burial by later basaltic extrusions.

Description: Analyses of Pb from mid-ocean ridge basalts obtained from DSDP Leg 37 lie on a line of near-zero-age slope. The data seem consistent with an evolutionary model of three stages, the beginning of the second stage being at about 600 m.y. - the model age obtained for the least radiogenic Pb. The beginning of the third stage of evolution at the time of formation of the rocks apparently did not change the average Th/U ratio since measured values are consistent with the ratio deduced from Pb isotope ratios. Ratios of U/Pb are not consistent with Pb isotope ratios, however, thus ruling out a simple two-stage evolutionary model.

Description: A detailed geochemical-petrological examination of layer 2 basalts recovered during Leg 37 of the DSDP has revealed that the original distribution, form and abundance of igneous sulfide have been profoundly altered during low-grade oxidative diagenesis. The net result appears to have been a rather pervasive remobilization of igneous sulfide to form secondary pyrite accompanied by a bulk loss of sulfur equivalent to about 50-60% of the original igneous value, assuming initial saturation. It is suggested that during infiltration of seawater into the massive crystalline rock, igneous sulfide has experienced pervasive oxidation, under conditions of limited oxidation potential, to form a series of unstable, soluble sulfur species, primarily in the form of SO3[2-] and S2O3[2-]. Spontaneous decomposition of these intermediate compounds through disproportionation has resulted in partial reconstitution of the sulfur as secondary pyrite and the generation of SO4[2-] ion, which, due to its kinetic stability, has been lost from the basalt system and ultimately transferred to the ocean. This model not only satisfies the geochemical and petrological observations but also provides a suitable explanation for the highly variable delta34S values which characterize secondary sulfides in deep ocean floor basalts.

Description: Oceanic crustal drilling by R. V. Glomar Challenger at 15 sites in the North Atlantic has led to a complex picture of the upper half kilometer of the crust. Elements of the picture include the absence of the source for linear magnetic anomalies, marked episodicity of volcanic activity, ubiquitous low temperature alteration and evidence for large scale tectonic disturbance. Comparison sections in the Pacific and much deeper crustal drilling are needed to attack problems arising from the North Atlantic results.