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  • Articles  (163)
  • Chemistry  (163)
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  • 1995-1999  (163)
  • Architecture, Civil Engineering, Surveying  (163)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 89-94 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this study, a protocol was developed to increae accuracy, generality and efficiency when determining piloted ignition properties. A new procedure for calibrating the radiative and convective heat flux protiels on exposed speciments, such as Douglas-fir plywood, has been implemented for the lateral ignition and flame spread test (LIFT) apparatus. The boundary conditions needed for heat transfer anylysis are made unambiguous by including a simple, direct measure f surface emissivity. A new aluminum foil shutter improves accuracy for measuring ignition time. A recently developed theroy of ignitanility provides a formula to account for the transition form thick to thin thermal behaior, allowing specimens of finite thicknesses and a fuln range of test irradiances.
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  • 2
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Recent advances in passenger rail transportation, fire test methods, and hazard analysis necessitate re-examination of requirements for fire safety. Several studies have indicated nearly random ability of current bench-scale tests to predicts actual fire behavior. Fire safety in any application, including transportation, requires a multi-faceted approach. The effects of vehicle design, material selection, detection and suppression systems, and emergency egress and their interaction, on the overall fire safety of the passenger trains must all be considered. The strengths and weakness of current methods for measuring the fire performance of rail transportation systems are evaluated. A systems approach to fire safety which address typical passenger train fire scenatios is analyzed. A rationale is presented for the direction in which most fire science-oriented organizations in the world are clearly headed - the use of fire hazard and fire risk assessment methods supported by measurement methods based on heat release rate.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 253-258 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A comparison is presented of cone calorimeter heat release data between fire retardant treated and untreated wood products. The test results show significant differences between these two groups. The parameters included in the comparison are time to ignition, rate of heat release (peak and average values) and total heat release. The wood-based products were also tested in different small-scale national standard fire tests and in the full-scale room fire test. Fire retardant wood products achieve an improved classification both in present national systems and in possible new systems based on the cone calorimeter and the room fire test.
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  • 6
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 243-252 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: When a specimen is testd for its heat release rate (HRR) behaviour using a bench-scale such as ISO 5660 or equivalent, one very important test condition is not pre-standaridized and must be set: the heat flux to be imposed on the specimen by the heater. The heat flux cannot be ligitimately standardized, since the value appropriately to be used will differ according to purpose or application. The present paper sets forth the considerations which should govern the correct choice of heat flux. A discussion is given of minimum ignitiability level; statistical variability at low heat fluxes; the ranges of heat fluxes associated with small actual ignition sources; the heat fluxes associated with fires away from the ignition sources, all the way up to fully-involved room fires; the application of the product; and the needs associated with mathematical modeling of room fires. Correlational approaches are also illustrated and contrasted to physics-based ones. Finally, the empirical nature of the present situation is emphasized. Judged from first principles, it would appear that successful prediction of room fire results from bench-scale test data would require both the testing at a large number of different heat fluxes and the use of algorithms to permit time-dependent interpolation. Such algorithms have been proposed; however, some very successful predictions are noted with much simpler techniques.
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  • 7
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 283-285 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A simultaneous TG-DSC system (STA-625) has been used to investigate the suitability of using magnesium hydroxide (MH) as a flame retardant and smoke suppressant in polypropylene (PP) formulations. Several MH/PP formulations were examined at differing concentrations. The presence of MH in the system greatly alters the thermal degradation character of PP. This work forms the first in a series of application notes using various Theometric Scientific Thermal Analysis instruments.
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  • 8
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 265-273 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Forest fires involve a wide range of unknown variables, e.g. wind flow over complex terrain, atmospheric stability, vegetation burning characteristics, location and fuel type, etc. The main objective of the present work is to incorporate the Rothermel simplified combustible model into a 3D unsteady flow solver appropriated for convective atmospheric flows over complex terrain. The released combustion energy is taken into account in the enthalpy equation. The unsteady byouant plume strongly influences the local wind speed direction and magnitude. A speical interactive coupling procedure was developed that links the calculated location of fire front and fire energy release to the momentum and energy transport for each time step. The general computer algorithm includes several other features such as the effect-drag of trees on the momentum transport and the consequent modifications in the k and ε turbulence model employed. The results include the prediction of fire development in flat terrain and in a valley and over hills covered by vegetation. A parametric study was conducted to detect the influence of wind speed, vegetation and fuel content on burning area, burning speed and wind speed direction.
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  • 9
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 275-281 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The flame spread process is driven by the net heat flux to the specimen surface, including the flux from the flame itself. This flame flux is important since it comprises a major part of the driving force causing flame fluxes were obtained. The values which are reported do not appear consistent and show more deviation among materials than would be anticipated. The most common fire test used for obtaining engineering data on flame spread (ASTM E 1321) also is not formulated in terms of flame flux as a driving force. This motivated an experimental programme, whereby six materials have been studied using the flame spread geometry of the ASTM E 1321 test, but with additional instrumentation for recording heat fluxes. The flame fluxes obtained experimentally in this study show much less variation among materials than the comparable data from the literature survey.
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  • 10
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Addition of natural clay materials in intumescent polypropylene-based formulations (additive: ammonium polyphosphate and pentaerythritol) leads either to a decrease or to an increase of their fire retardant performances versus the chemical or the physical characteristics of the clay materials. A study of the factors affecting these performances has been carried out using linear and principal components analysis. This analysis shows that the results of the evaluation tests (LOI and UL 94) are affected in different ways by the adduct of the different clay material and that an increase in the LOI is not necessarily related to an increase in the UL 94 classification. LOI values are improved by the presence of the montmorillonite and of illite clay minerals which may react with acidic phosphate to form active carbonization catelysts, in addition, the results of the LOI test are improved by the presence of quartz and other foreign minerals in the clay materials. This study discusses the part played by the different constitutive minerals in the formation of defects in the polymer chain during the mixing process. It is proposed that the presence of these defects leads to a change in fire retardant performance.
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  • 11
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 12
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 111-111 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No Abstract
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  • 13
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A total of 21 electrical cables were made, all with essentially identical construction but differing in the chemical composition of sheath and/or insulatiòn, which were all commercially available materials, both halogenated and non-halogenated. All cables were tested in two large-scale cable tray tests, ASTM D5424 (CSA FT-4 protocol), with a total length of 2.44 m and IEC 332-3, with a total length of 3.5 m. The cables were also tested in a number of small- and medium-scale tests for flame spread (IEC 695-2-2, IEC 332-1, UL 1581 Part VW1, BS 476 Part 12E, DIN 4102 Part 16), temperature increase (DIN 4102 Part 16) and smoke obscuration (IEC 1034-2, BS 476 Part 12E). Finally, all cables were tested in the cone calorimeter (ISO 5660), horizontally, at incident fluxes of 20, 40 and 70 kW m-2. All the cables passed the mild flammability tests, but distinctions could be made based on the afterflame time observed, where halogenated cables outperformed non-halogenated cables by a significant margin. It was also possible to distinguish between the halogenated and non-halogenated cables on the basis of the cable length charred in some tests. In terms of smoke obscuration, it was found that the rankings offered by the various tests were very different. While non-halogenated cables had improved smoke performance over traditional vinyl types, fluorinated cables performed very well. This confirms the importance of material selection by performance rather than by chemical composition. Almost all cables performed sufficiently well that they generated relatively limited amounts of smoke under realistic end-use fire test conditions. The peak heat release rate in the large-scale cable tray test (ASTM D5424) served as an excellent criterion for discriminating between the fire performance of the various cables (the traditional criterion being char length). The average rate of heat released also served to distinguish between different levels of cable fire performance. Moreover, cables passing the test tended to release less heat and smoke than those that failed. The trends observed in the cone calorimeter heat release test were similar to those in the large-scale test and show good correlation between cable tray char length and cone calorimeter heat release. It was observed that the halogenated cables tested performed better than the non-halogenated cables in terms of heat release rate by factors ranging from two to greater than five. The results indicate that cables with excellent fire performance can be constructed by using a variety of materials. It is thus important to specify fire performance and leave material choice to manufacturers.
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  • 14
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 107-109 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper a possible explanation is presented for the differences found between the fire behaviour of materials in small-scale cone calorimeter tests and the large-scale furniture calorimeter. The results obtained with cone calorimeter/FTIR equipment at 35 kW m-2 will show that the early flash ignitions of typical materials like cotton and wool are due to the liberation of flammable gases during the pyrolysis phase and the typical ignition situation on the cone calorimeter, that is, the presence of a sparking igniter above the sample. This fast flash ignition and the early heat release behaviour on the cone calorimeter may be in contradiction to the early fire growth in other fire tests where the ignition conditions are clearly different from pyrolysis circumstances, that is, ignition via a burning newspaper, match, gas flame, etc.
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  • 15
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 61-67 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: When measuring the production rates of heat and smoke of upholstered furniture the ignition source must not influence the test results. In this paper variations in the strength, application time and geometry of the ignition burner used in the furniture calorimeter are studied. Results from replicate furniture calorimeter chair test show that the burning behaviour is almost independent of the burner intensity in the applied regime.Tests on six different furniture items were performed in the furniture calorimeter. The test objects were exposed to three intensity levels of ignition source. The sources were: a large propane burner giving 30 kW during 120 s and a smaller propane burner used at two levels of heat output, 1.7 and 5.8 kW during 90 s. The results showed that the burning behaviour of the furniture was very similar regardless of which burner was used. This was especially evident when the time regime between 50 and 400 kW was studied. The length of this period is a measurement on how quick untenable conditions are developing in a single, well-ventilated compartment.
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  • 16
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 17
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 79-96 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Light steel-frame building systems are becoming more prevalent in commercial, industrial and residential construction in New Zealand. Tested fire resistance ratings are generally available for non-load-bearing systems, but not for load-bearing applications. This study investigates the performance of load-bearing light steel-frame systems exposed to fire. Methods are presented for calculating the reduction of steel strength and stiffness at elevated temperatures, and for predicting the deflections resulting from temperature gradients and P-Δ effects. Heat transfer modelling by computer is used to predict steel framing temperatures for systems exposed to the standard ISO 834 time-temperature curve and real fires. Three full-scale furnace tests were carried out to evaluate analytical predictions. A design procedure is proposed.
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  • 18
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    Fire and Materials 20 (1996), S. 133-143 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nailed joints with wood members were exposed simultaneously to standard fire and constant load. Different loads were applied in the range of 0.1 to 0.6 of the estimated failure load at normal temperature. Measurements of the rate of charring and the temperature were used to determine the temperature profiles and further to estimate the reduction in the strength properties. The test results are compared with calculations based on the theory of K. W. Johansen. Three different relations between the reduction of embedding strength and the temperature were investigated. For one of these relations, the theory agrees well with the results obtained in the fire tests. The results of the calculations also show that there is a considerable reduction of the embedding strength during the first period of fire.
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  • 19
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 161-166 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An estimate of the annual generation of polychlorodibenzodioxins and furans (PCDD/F) in the United States as a result of PVC burning in house fires is made using building data and fire loss statistics and soot and ash samples obtained from laboratory experiments and building fires involving PVC. Using conservative estimates for construction, fire involvement and formation, dioxin generation from PVC in house fires is estimated to be in the range of 0.074 to 8.6g TEQ yr-1 as soot, 0.4 to 14g TEQ yr-1 as ash, and thus 0.47 to 23g TEQ yr-1 total. The maximum likelihood estimate is approximately 0.3g TEQ yr-1 as soot and 1g TEQyr-1 as ash. Any of these estimates constitutes a minuscule fraction of the 9300g annual air emissions or the 20000-50000g (TEQ) annual deposition from the air estimated by EPA.
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  • 20
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 167-172 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The purpose of this study is to evaluate the effect of different oil contaminants on the spontaneous ignition behavior of cotton fabric. A series of treated fabrics with different oil contamination percentages was investigated and compared. Measurements were designed and carried out to determine the average time-to-ignition and to study the thermal behavior of systems containing cellulose. The results showed that the time-to-ignition of the contaminated samples has notably decreased, particularly at relatively low temperatures (350-450°C). However, at higher temperatures such effects became insignificant. Differential Thermal Analysis measurements were used to explain the mechanism by which the oils affect the thermal behavior of the sample. The heat evolved due to the oxidation of the oil content is sufficient to increase the rate of cotton depolymerization at the expense of the dehydration mechanism. In other words, the heat evolved promotes the formation of volatiles which are not char precursors.
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  • 21
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    Fire and Materials 20 (1996), S. 173-181 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A number of common tropical timbers have been subjected to thermal analytical investigation as part of a wider research programme under air atmospheric conditions. Thermal parameters obtained were correlated with oven-dry densities of the timbers. Two well-defined pyrolysis stages have been observed which occur over the temperature ranges 201-426°C and 397-557°C. The kinetics of the thermal degradation of the timbers were obtained using Broido's analytical procedure. These results were interpreted on the basis of the known mechanism of pyrolysis and the calculated kinetic parameters were discussed within the context of other published values for cellulose.
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  • 22
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    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 23
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    Fire and Materials 20 (1996), S. 297-299 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fire retardancy properties of hardboard treated with ammonium hydrogen carbonate (AHC) and sodium bromide were investigated by measuring their ignition time and flame temperature. An increase in ignition time and lowered flame temperature were observed with increased flame retardant (FR) concentration. AHC was found to be less effective as a fire retardant for this material. © 1996 by John Wiley & Sons, Ltd.
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  • 24
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    Fire and Materials 20 (1996), S. 305-305 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No Abstract
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  • 25
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    Fire and Materials 20 (1996), S. 301-303 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Autoignition temperature and heat of combustion are two important parameters in determining the oxygen compatibility of materials. This study investigates the autoignition temperature of 32 polymers at an elevated oxygen pressure of 10.3 MPa and reports their heat of combustion. © 1996 by John Wiley & Sons, Ltd.
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  • 26
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    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 27
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The philosophy behind research into personal protection from flame and intense heat for UK military personnel is addressed. The threat is examined as are methods of measurement and assessment. Finally an overview of the novel techniques which are being pursued at the Science and Technology Division is given. © British Crown Copyright 1996/MOD.
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  • 28
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    Fire and Materials 21 (1997), S. 7-16 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The modelling of the spread of fire and its extinguishment still represents a significant challenge. As part of a combined experimental and computational study of fires we have developed a general Computational Fluid Dynamics (CFD) model of fire spread and extinguishment. The primary objective was to produce a flexible computational tool which can be used by engineers and scientists for design or research purposes. The present paper deals with the description and validation of a solid pyrolysis model which has been applied, as a sub-model, in this general computer fire code. The pyrolysis model has been formulated using the heat-balance integral method. The model can be applied to slabs of char forming solids, such as wood, as well as non-charring thermoplastic materials, such as PMMA. Results are compared with analytical solutions, numerical simulations and experimental data. In all cases the integral model performs well. © 1997 by John Wiley & Sons, Ltd.
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  • 29
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    Fire and Materials 21 (1997), S. 17-22 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation of cone calorimeter test procedures was performed using two types of mattress composites with various specimen preparations and equipment configurations. The objective was to discover suitable procedures for testing mattress composites. Concurrent with this work a much larger and more sophisticated project known as CBUF was underway in Europe. One of CBUF's secondary objectives was to provide an appropriate test protocol for testing upholstered furniture composites, including mattresses. Most of the CBUF protocol was available at the time of this study and a modified form of the specimen preparation technique was used in this investigation. Preliminary tests found unacceptable test performance with some configurations. Subsequent testing examined variations of the established test protocols and other test procedures. The data sample was small, but observations of the data indicate trends that might be attributable to the use of the different procedures. Significantly it was determined that the edge frame used to hold specimens in place during the test does affect the test results. A modified CBUF protocol proved to be the best procedure, but it requires extensive experience with the CBUF specimen preparation method in order to be able to produce satisfactory specimens. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 261-271 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reviews the past research, experimental techniques and scaling relationships used in the studies of oscillatory buoyant diffusion flames and reports an experimental investigation conducted to determine the pulsating characteristics of such flames. The experimental data were obtained by using three techniques, namely, pressure fluctuation measurements, thermal imaging and high-speed video photography. Present findings are compared with data sets reported in the literature and correlations for pulsation frequency suggested by previous studies are independently verified. Analysis of the experimental data on frequency of pulsations in different burners shows that for a fixed-diameter flame the pulsation frequency is almost independent of fuel flow rate. The equation f=1.68D-0.5 gives the best approximation for the relationship between pulsating frequency and diameter over a wide range of data. An alternative way of expressing the relationship between the key variables is St=0.52*(1/Fr)0.505. This proves to be a better way of expressing the relationship since it can include the effect of the fuel flow rate. Slight modifications to this expression allows prediction of flame oscillations under elevated/reduced gravity and isothermal buoyant plumes. This relationship and the observations of the present study confirm the hydrodynamic nature of flame puffing: interplay of buoyancy and fluid motion. © 1996 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 273-291 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper an overview is given of several methods for quantitative analysis of FTIR spectra. Each method has its particular advantages and disadvantages. Therefore, depending on the gas component to be analysed in smoke gas spectra, an optimal choice of method has to be made. This choice depends on several different aspects:• Is the spectral band of interest free of interfering components?• Does the absorption-concentration relation show strong deviations from Beer's law?• Are significant baseline corrections necessary?• Does the applied model need to warn for the presence of unexpected components?• Is it sufficient to use only a few wavenumbers or is a full-spectrum method necessary?It will not be easy to make the appropriate choice. However, in some cases, statistics can help, in others, a good rule of thumb is to keep the choice as simple as possible. © 1996 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 306-306 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 33
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    Fire and Materials 21 (1997), S. 1-6 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The effect of melting behaviour on upward flame spread of thermoplastic materials when subjected to small ignition sources and considered to suffer no external flux was studied using large-scale tests. For moderate fire conditions the cone calorimeter was utilized, with the sample set in a vertical orientation to study the melting behaviour of the specimens. Under these conditions the results indicate that the melting behaviour significantly affects upward flame spread behaviour. A pool of the melt which formed at the base of the vertically oriented sample tested creates a pool fire which then controls the fire growth and flame spread. In contrast, it was found that some thermoplastic materials which have higher glass transition temperatures or undergo a special pyrolysis process such as depolymerization, intumescing or charring do not experience significant melting behaviour when exposed to the same thermal insult. As a result, they behave very differently in terms of upward flame spread. The study also indicates that the melting behaviour of thermoplastic materials is an important characteristic in fires which should be taken into account in the development of modelling, in particular for upward flame spread models. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 51-51 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No Abstract
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    Fire and Materials 21 (1997), S. 33-39 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of 37 cigarettes were analysed to develop a model, based on cigarette physical properties, to predict the ignition propensity of the cigarettes towards cellulosic fabrics. The properties used were: cigarette circumference (in mm), tobacco packing density (in g cm-2), paper permeability (in CORESTA units) and the presence or absence of citrate additives in the paper (used independent of concentration, although typical additions range from 0.5 to 0.8 wt%). Two empirical models were developed, one for low and medium paper permeabilities, and one for very high paper permeabilities (above 50 CORESTA units). The latter exceed the paper permeability of most commercial cigarettes, and have medium to high ignition propensities. Thus, they are probably only of interest from the point of view of a mathematical curiosity. The former model, however, addresses cigarettes in the range where commercial cigarettes are potentially viable. The resulting ignition propensities exhibited cover the entire feasible range, from 0% to 100%. Both models predicted the ignition propensities of the tested cigarettes quite well, within an error range which did not exceed 30% for any cigarette. Physical rationales are presented for the effects of the variables used. However, the rationale for the discontinuity in ignition propensity found for the cigarettes with extremely high paper permeability is less clear. One explanation is that there is probably excess oxygen present so that a fuel/oxygen mixture is obtained with a ratio which is less than the lower flammability limits and is too lean to support combustion. However, further analysis of this issue is warranted. The empirical model for low and medium paper permeability cigarettes is potentially useful for developing cigarettes with lower ignition propensity, since it is a practical way of combining the individual properties that most heavily affect cigarette ignition propensity. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 53-65 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire hazard assessments must be primarily driven by life safety variables. Concern is often highly focused on toxicity issues, since fire deaths, in the majority of cases, are found (in whole or in part) to be due to toxic gas inhalation. Procedures have recently been published by ISO, wherein the toxicity assessment of fire products is focused primarily on bench-scale testing for toxic potency (the ‘per-gram toxicity’). Yet hazards of products with regards to fire toxicity may be determined much more by their differences in burning rates than by any differences in toxic potency. Burning rates are not assessed in the pertinent standards (ISO 13344 and ISO TR 9122). For most product categories, techniques for predicting full-scale burning rates from bench-scale data are not yet in hand. Thus, today the best means of comparing actual, full-scale toxic fire hazards is the full-scale fire test, equipped with additional gas measuring instrumentation. Such an approach is not among the recommended methods of the international standards, yet it is the only one with innate validity. In the present work, a series of sandwich panel products were tested in a full-scale room configuration. Bench-scale comparison was made to the ISO 5660 Cone Calorimeter and the DIN 53436 tube furnace. The toxic gases were quantified in all cases by chemical analysis. The product which showed the best performance in the full-scale tests (rock wool insulated sandwich panel) did not achieve a good fire toxicity performance due to minimization of toxic potency. Instead, the successful performance was attributed wholly to reduction of burning rate. Bench-scale measurements of toxic potency were shown to lack relevance to reality in such cases where even the full-scale toxic potency is not a determining factor. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 179-185 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Zinc hydroxystannate (ZHS), at levels of 2-5 phr, and the hydrated fillers, magnesium hydroxide (MH) and alumina trihydrate (ATH), at levels of 20-50 phr, are effective flame retardants and smoke suppressants for flexible PVC. Novel ZHS-coated hydrated fillers are found to exhibit markedly improved fire-retardant properties, particularly with regard to increasing LOI values, reducing heat release rates and suppressing smoke generation, when compared with conventional uncoated forms. The ZHS coating appears to change the filler particle morphology and there is evidence that the coating is largely retained on the filler surface after melt processing into the PVC. The improved dispersion of the active tin compound in the polymer matrix leads to enhanced fire retardancy and this, in turn, allows significant reductions to be made in overall filler loading, with no loss in flame-retardant or smoke-suppressant performance. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 95-105 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the EC-sponsored CBUF (Combustion Behaviour of Upholstered Furniture) study three different models were developed for using Cone Calorimeter results to predict full-scale furniture burning. Model I is a correlation-based approach and has the most comprehensive coverage of styles and furniture types. Model II is based on area-convolution. It has been developed, so far, for several of the common upholstered furniture styles. Model III is based on an extension of a thermal flame spread model and is here developed only for mattresses. Models II and III offer the prediction of the burning item's time history, while Model I computes the peak HRR, the time to peak, and several other primary characteristics. The predictability of all three models is good. At present, the models presented do not consider furniture with plastic frames, and only a limited predictability is offered for office-type furnitures items which contain a hard-plastic shell. The models offer a very significant improvement over the existing state of the art. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 277-282 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A correlation has been developed between closed-cup flash points and normal boiling points for silicone compounds. In addition, a more general correlation has been developed between these two properties for the general organic compounds, including silicone compounds. The closed-cup flash points can be predicted using empirical equations. The standard errors of estimate are 11.06 and 11.66°C for silicone compounds and general organic compounds (including silicone compounds), respectively. © 1997 John Wiley & Sons, Ltd.
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    Notes: The incorporation of two brominated compounds/antimony trioxide blends into a PP-PE copolymer were studied. Both brominated trimethylphenyl indane (FR 1808) and poly(pentabromobenzyl acrylate) (FR 1025) confer good flame retardancy at 40% loading. A comparison was made with the incorporation of magnesium hydroxide at higher loadings (up to 64%) in the same copolymer. The mineral filler improves both fire resistance and stiffness of the copolymer, nevertheless the high loading causes a dramatic decrease in impact resistance. Moreover, the necessary surface treatment of the filler significantly lowers the maximal tensile strength. In order to maximize both fire resistance and mechanical properties, we combined each brominated flame-retardant system (20% in weight) with magnesium hydroxide or talc (20% in weight). Talc is used as reference. These composites show interesting fire-retardant properties in comparison with the copolymers containing only 40% of the brominated flame-retardant systems. In addition, the mechanical properties are on the whole improved. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 271-276 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results are presented of a project to evaluate the combustibility and surface flammability of building interior finish materials commonly used in Taiwan. The project was conducted at the Fire Laboratory of the Architecture and Building Research Institute in Taipei. Eighteen different wall-covering materials were tested according to Chinese National Standard (CNS) 6532, which is equivalent to Japanese Industry Standard (JIS) 1321, and according to ASTM E 1354-92 (Cone calorimeter). A comparison of test results is presented, and a qualitative relationship is developed between the performance in the two methods. The classification system for degrees of combustibility developed in Canada by Richardson and Brooks was hereby used to group materials based in performance in the ASTM test method. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 43-43 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 44-44 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 39-42 
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    Notes: Heat Release Rates of organic materials are studied in many countries, but there is no mathematical formula to represent their shape. We considered a mathematical expression of the Heat Release Rate Curve by a simple equation. And we also derived the index of degree of combustibility, named ‘Burning Index (BI)’. The Heat Release Rate Curve is expressed by the derivative of a probability function of maximum value and has three parameters; an amplitude coefficient, a time width coefficient and an ignition index. BI is in proportion to an amplitude and a time width and in inverse proportion to an ignition index. BI values of cable plastic compounds with flame-retardant material had good relations with the quantity of non-organic ingredients. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 47-54 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: High-temperature pyrolysis of various classes of polymers have been discussed. For the non-carbonizing polymers it was shown that polymer structure can affect the pyrolysis characteristics. Data on the high-temperature pyrolysis of some polypropylene samples with different crystallinity have been presented. Modification of the standard method allowing one to obtain kinetic data from the single experiment was discussed. A kinetic model for the degradation of char-forming polymers in conditions of high-temperature pyrolysis has been suggested. It has been supposed that pyrolysis of carbonizing polymers proceeds in some (two in present work) parallel stages with different activation energies, temperatures and pyrolysis rates. Questions of the applicability of the suggested model to describe the various types of charring systems have been discussed. High-temperature pyrolysis for a number of epoxy resin-based polymeric compositions have been investigated. Kinetic parameters of the pyrolysis have been computed. © 1998 John Wiley & Sons Ltd.
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    Fire and Materials 22 (1998), S. 77-83 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fire-retardant wood treatment with fire-retardant chemicals consisting of basic nitrogen compounds and phosphoric acid have been thoroughly examined. The fire retardance and endurance of wood were influenced by the treatment method. Here two treatment methods were compared, heat-pressed treatment method improved these qualities more than heat-dried treatment method. Furthermore, to gain lasting fire retardance, it was considered necessary to react basic nitrogen compounds and phosphoric acid with formaldehyde as in the dicyandiamide-formaldehyde-phosphoric acid or melamine-dicyandiamide-formaldehyde-phosphoric acid system. In the treated wood, the concentration of chemicals gradually decreased as it approached the center. The functional fire retardance could be graded in accordance with the chemical content. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 103-108 
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    Notes: The thermal decomposition of six different samples of wood and leaves in nitrogen has been studied by using dynamic thermogravimetry. In the experiments two main weight loss processes took place and the total weight loss at 500°C was over 95% in all six cases. By means of the Doyle method, the two processes were found to fit most closely the plot for the second-order equation in the form dα/dt=k(1-α)2, and each of the weight loss processes was found to be controlled, respectively, by two dominant reactions as the temperature increases. It was inferred that competing reactions occur during the overall temperature interval for all the six samples. By comparing the activation energies using this model with those by the method of Moll et al., and by comparing the experimental and theoretical thermogravimetric curves, the ‘second-order’ model was tested to be able to predict the weight loss processes of the samples with very good accuracy. It can be concluded that the ‘second-order’ kinetic model acts much better than the conventionally adopted first-order model. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 119-128 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: This work compares the fire degradation of ethylene-vinyl acetate 8% copolymer (EVA8) with two flame-retarded formulations, using the cone calorimeter. The first one, EVA8/ammonium polyphosphate (APP) leads to the protection of the material, in the conditions of a fire, by means of blowing up and weak carbonization. The addition of polyamide-6 (PA-6) in EVA8/APP improves the protection by forming an intumescent carbonaceous shield. The fire hazard of the virgin polymer and of the FR systems are quantified, in terms of rate of heat release, weight loss, effective heat of combustion, volume of smoke production and CO and CO2 production. It assesses the effectiveness of the fire retardant additives APP and APP/PA-6 in EVA8-based materials under simulated real fire test conditions.The respective temperatures of the degradation front are deduced from the weight loss data recorded in the course of the cone calorimeter experiments and the results of the invariant kinetic parameters method applied to the different specimens. The addition of APP/PA-6 in EVA8 leads to a superficial phenomenon; the degradation zone is thus located on the upper volume of the specimen during all the exposure to the heat flux. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 155-165 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A set of small-scale experiments was carried out to study the effects of material structural properties on the re-ignition characteristics of solid fuels. The influence of other key parameters, such as the incident heat flux and pre-burn, was also carefully investigated. The experiments were conducted on specimens of wood and PMMA using a cone calorimeter. As expected, the effect of water on the re-ignition time was found to be significant. It was also found that the re-ignition characteristics of charring materials, such as wood, are quite different from non-charring materials, mainly due to the structural differences. Based on the experimental observations two different mathematical models were developed to analyse the data for both wood and PMMA samples. Calculations of the re-ignition time made using these models agree generally well with the measurements and confirm that the material structure plays a vital role in its re-ignition behaviour. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 44-44 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 25-37 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An analysis has been made to compare the repeatability and reproducibility of three tests for cigarette ignition of upholstered furniture composites: ASTM E1352, ASTM E1353 and NIST 851 mock-up. The first two of these tests are traditional methods designed to assess the potential of upholstered furniture components to being ignited by cigarettes while the last one, NIST 851 mock-up, is a new method designed to assess the propensity of cigarettes to ignite upholstered furniture composites. The traditional methods, ASTM E1352 and ASTM E1353 use a single cigarette for each determination and can be run in two ways: to obtain a numerical output of char length on the substrate (following the standard) or to obtain a pass/fail result for the substrate (practical use); the precision was analysed in both fashions. The new method, NIST 851 mock-up, uses 144 cigarettes for each determination (48 each on three substrate composites), and assesses the fraction of substrates that have been ignited (char length exceeding 10 mm), i.e. by a combination of pass/fail data. The analysis for actual char length was made according to ASTM E691 guidelines, while the analysis of the pass/fail was made according to a modification applicable to binary data. The precision of the test methods was as follows (in descending order):NIST 851〉ASTM E1353 P/F〉ASTM E1352 P/F〉ASTM E1353〉ASTM E1352© 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 19 (1995) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 19 (1995), S. 1-10 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Comparison of oxygen and nitrous oxide indices indicates that ammonium polyphosphate (APP) should act in the condensed phase when added to nylon 6 (PA-6). A detailed study of the thermal degradation mechanism of PA-6/APP mixtures is carried out. A polyphosphate ester is formed on heating, which is the precursor of an intumescent char. Evidence is given of the thermal insulating action of the intumescent char which slows down the rate of combustion of the polymer.
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  • 55
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    Fire and Materials 19 (1995), S. 35-41 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The behaviour of concrete structures under fire can be improved by adding fibers. However, relatively little is known of the details of the possible beneficial features of the fibre addition. The aim of this study was to compare the effects of different wood-based fibres on the thermal properties of a standard laboratory cement mortar at conditions of a developing fire. The cone calorimeter heating method was used, and the sample thickness and heat flux were varied (25 mm or 50 mm, 25 kWm-2 or 50 kWm-2) to compare test conditions. The fibres comprised chemical pulp, chemi-thermomechanical pulp, recycled fibres and viscose fibres. The fibre content in the mortar was 0.15-0.5% by weight. Temperature and mass loos measurements of oven-dried specimens (moisture content 〈0.1%) showed no differences between different wood-based fibre mortars and plain mortar. With increasing moisture content (about 5%), however, the presence of fibres affected the release of moisture from the fibre mortar material. With rapid heating of mortars, which have a moisture content of about 5%, local pressures are easily built up. These pressures are mainly caused by free water vaporization. The rear surface temperature measurements indicate that in mortars containing wood-based fibres (0.15-0.5% by weight) the vaporization temperatures may be 20 -25% lower than in the reference mortar. Some effects on heat transfer can also be observed due to differences in water vaporization and movement processes.
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    Fire and Materials 19 (1995), S. 65-70 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Notes: A computer model was developed to calculate the heat release rate of aircraft cabin panels in the OSU calorimeter based on their thermophysical, thermochemical and geometrical properties. It calculates the temperature profile through the panel as a function of time and uses the measured kinetic constants of the individual materials to deduce the mass loss rate. The mass loss rate is multiplied by the heat of combustion of the volatiles to obtain the heat release rate which would be measured in the Cone calorimeter. This heat release rate is used in an energy balance at the surface of the specimen to calculate the rise in enthalpy of the flue gases in the OSU calorimeter and thus the specimen's heat release rate in that apparatus. The calculated heat release rates are in reasonable agreement with measurements in the Cone and OSU calorimeters.
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    Fire and Materials 19 (1995), S. 61-64 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of experiments involving the combustion of inherently fire-retarded compounds has been performed using the DIN 53 436 furnace. Six chlorinated compounds comprising four pesticides, an organic solvent, and polyvinyl chloride (PVC) have been investigated with the focus on the combustion efficiency expressed as the CO2/CO ratio in the fire effluent. It was found that increased chloride content in a compound resulted in decreased CO2/CO ratio. The correlation was found to be \documentclass{article}\pagestyle{empty}\begin{document}$ \sqrt {{\rm CO}_{\rm 2} /{\rm CO}} = 0.61 \times ({\rm Cl/C)}^{- {\rm 1}} + 0.13 $\end{document}. The results indicate higher concentrations of CO in the fire effluent from chlorinated compounds than from wood. Together with a release of HCI this could result in an increased toxic potency. The overall toxic hazard may or may not be increased, since (inherently) fire-retarded materials tend to have an improved fire performance.
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    Fire and Materials 19 (1995), S. 95-96 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 60
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    Fire and Materials 19 (1995), S. 99-99 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 61
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    Fire and Materials 19 (1995), S. 101-108 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Performance of three fire zone models BR12, CCFM.VENTS and CFAST in simulating forced ventilation fires with low heat release and high ventilation rates were studied experimentally. A fire chamber of length 4.0 m, width 3.0 m height 2.8 m with adjustable ventilation rates was used. Burning tests were carried out with wood cribs and methanol to study the preflashover stage of a compartmental fire and the effect of ventilation. The mass loss rate of fuel, temperature distribution of the compartment and the air intake rate were measured. The heat release rates of the fuel were calculated from the measured mass loss rate. The smoke temperature was used as the validation parameter. A scoring system is proposed to compare the results predicted by the three models. An empirical expression for calculating the smoke temperature is assessed. Lastly, the Computational Fluid Dynamics technique is also used for comparing the simulated fire environment.
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  • 62
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    Fire and Materials 19 (1995), S. 109-118 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fire-retardant performances of various surface coatings for naval ship interior applications have been evaluated by a number of small-scale fire test methods. The coatings were eveluated as topcoats by cone calorimetry and limiting oxygen index methods and as primer/topcoat systems by radiat heating, direct flame impingement and reverse panel heating procedures. The coatings investigated were (1) a solvent-based epoxy polyester, (2) a solvent-based fireretardant alkyd,(3) a solvent-based chlorimated alkyd and (4) a water-based acrylic. In terms of the measured parameters, the chlorinated alkyd has superior fire properties while the epoxy polyserter, the fire-retardant alkyd and parameters, the chlorinated alkyd has superior fire properties while the epoxy polyester, the fire-retardant alkyd and the acrylic have significat disadvantages in relation to fire propagation. The relatively low amount of hydrogen chloride (∼ 0.3% - mass per initial mass) evolved by the chlorinated alkyd during cone calorimetric combustion and its outstanding fire-retardant properties have resulted in it being considered acceptable for naval ship interior applications.
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    Fire and Materials 19 (1995), S. 127-132 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: New Zealand Building Code Performance requirements relating to fire performance of external walls are considered and methods of evaluating the potential for vertical fire spread are discussed. Classifying external wall claddings on the basis of performance in the ‘combustibility’ test has proved overly restrictive where some external cladding materials are concerned. Performance criteria based on heat relase or ‘degree of combustibility’ are proposed and they seem to provide a better classification scheme for external wall cladding materials. Heat release test data for ten different external wall cladding materials are presented.
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    Fire and Materials 19 (1995), S. 119-126 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Two experiments were performed on board an aircraft flying repeated parabolic trajectories to generate free-fal conditions. The first experiment investigates the way in which rate of heat release (RHR) varies with gravity for a candle flame under an imposed low-speed flow. In line with previous studies of flame spread rate it has been shown that rate of heat release drops significantly in imcrogravity. The heat loss due to radiation decreases by a larger proportion than that due to non-radiative processes indicating a lower flame temperature. The RHR from a microgravity flame is flow rate dependent, increasing for increased flow rate at air speeds under 0.03 ms-1. For the geometry used in this experiment hypergravity caused only a small increase in RHR. The second experiment studied the ignitability of thermoplastics under an imposed radiant heat flux. The ignition test apparatus consists of a conical spiral heating element positioned horizontally above the sample, a continuous spark ignition source and a removable heat shield. Experiments were conducted in a sealed pressure chamber on samples of either PMMA or POM, 1.5 mm thick, with a ceramic backing. There is some indication that gravity influences the time to ignition for some materials.
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  • 65
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    Notes: The behaviour of three typical thermoplastic polymers - polypropylene (PP), polyamide 6 (PA-6), ABS and PP mixed with inert talc or fire retardant magnesium hydroxide or melamine - was assessed in the Cone Calorimeter and in traditional widely used tests. It is seen that the evaluation of the relative fire hazard of the materials, based on simple parameters, can be very different depending on the test used, particularly in the presence of additives. From this point of view, the Cone Calorimeter introduces an additional evaluation which might be as arbitrary as that obtained with any other test. For example, melamine, which is currently used as a fire retardant in several polymers, may be considered as a fire-hazardous additive in PP burned in the Cone Calorimeter if only the maximum of rate of heat release is considered. The data discussed here indicate that the use of the Cone Calorimeter for simple evaluation of materials requires further investigation. It is hown that the Cone Calorimeter is a very promising tool for mechanistic studies on combustion and fire retardance, when its potential in terms of quantitative description of the whole combustion is fully used.
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    Fire and Materials 19 (1995), S. 153-153 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 19 (1995), S. 143-151 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This paper presents the results of full-scale fires in two private motor vehicles conducted under insturmented calorimeter hoods for the Channel Tunnel Safety Unit, Department of Transport. Measurements of heat release rate, temperatures and other parameters of fire severity are given. The results were used for the assessment of the specification and design of the shuttle wagons and in the subsequent computer modelling calculations to analyse the impact of such a fire within a shuttle wagon. The fires were well ventilated and allowed to develop fully before firefighting intervention. Of the two tests the first burned for 17 min with the gas temperature in the rig reaching 1250°C and with a peak total heat output of at least 7½ MW before being extinguished. The other burned for 57 min, with gas temperatures reaching 1125°C and a pead heat output of 4½ MW.
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    Fire and Materials 19 (1995), S. 205-213 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Carbon monoxide (CO) is the single most important factor associated with deaths in fires; thus, predictions of CO developed in fires is an essential aspect of fire quantification. It is considered crucial to have correct CO prediction methods for post-flashover fire stages, since, in the United States at least, the majority of fire deaths are associated with fires which have gone to flashover. In this paper it is shown that the yiels of CO observed in real-scale fires are generally not related to either the chemical nature of the material being burned nor to the yield observed for the same material in bench-scale testing. Instead, the generation of CO in real-scale fires is determined largely according to the oxygen available for combustion, with thermal conditions of the fire plume also playing a significant role. This behavior is in sharp contrast to many other material fire properties, including yields of gases such as CO2 and HCI, which can be predicated for real-scale fires from bench-scale results. Finally, results from various studies completed thus far indicate how effective prediction of real-scale CO yields may be accomplished. While bench-scale measurements are not necessary to predict real-scale CO, bench-scale toxic potency measurements can be in error if the CO component in them does not reflect on the real-scale CO yield. Thus, a method is developed whereby the bench-scale toxic potency measurements can be computationally corected to better approximate the toxic potencies measured in real-scale, post-flashover room fires. These techniques will, undobtedly, be further refined as additional experimental results become available.
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    Fire and Materials 19 (1995), S. 241-241 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 19 (1995), S. 221-231 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fourier transform infrared spectroscopy ca be used for on-line smoke gas analysis of burning textile materials for several gases simultaneously. The technique is sensitive enough for the determination of the concentrations of compounds like H2O, CO2, Co, NO, NO2, SO2, C3H4O, HCI, HBr, HCN and HF. Quantitative analysis is, however, sometimes difficult to perform due to spectral interferences of two or more components. Simple mathematical techniques based on the direct relation between concentration and peak height or peak height or peak area then becomes impossible since they cannot be completely assigned to one component. Spectral subtraction can then be used but the results are sometimes unsatisfactory. Alternative techniques, like Partial Least Squares (PLS), Provide excellent possibilities to overcome the problems due to overlapping spectral features, without making use of spectral concentrations of different compounds in smoke gases. The use of PLS as a tool to overcome the problem of interfering of different compounds in smoke gases. The use of PLS as a tool to overcome the problem of interfering components is demonstrated by application to the overlapping spectral bands of H2O/CO2 and of H2O/NO. PLS calibration curves for other interfering components can be constructed in an analogous way.
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    Fire and Materials 19 (1995) 
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    Fire and Materials 19 (1995), S. 233-239 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A Controlled-atomosphere cone calorimeter was used to investigate the burning of pure and flame retardant-treated cotton fabrics. The condensed-phase flame retardants used were Morguard (containing ammonium dihydrogen phosphate and diammonium hydrogen phoisphate) and Nochar (containing ammonium sulfate and a sodium salt). The fabrics were tested at 25 kW m-2 incident heat flux in environments containing 15-30% oxygen. The flame retardants increased the time to ignition, residue yield, and CO and CO2 yields. The flame retardants decreased the peak and average mass loss rates, the peak and average heat release rates, the effective heat of combustion at peak heat release rate, and the propensity to flashover. The effect of oxygen concentration on the burning of pure and flame retardant-treated cotton fabrics has also been investigated. The flame retardants had better performance when the treated fabrics burned in the lower oxyge concentrations. The result of this study indicate that the controlled-atmosphere cone calorimeter is a good tool for studying the effect of flame retardant and oxygen concentration on the burning of materials.
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    Fire and Materials 22 (1998), S. 149-154 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Ion exchangers prepared from beech sawdust by introduction of weak and strong basic ion-exchanging groups were analysed with thermogravimetry, differential scanning calorimetry and limited oxygen index methods to evaluate their thermal stability and flame-retarding properties. By cross-linking with epichlorohydrin in the presence of NH4OH, ion exchangers in free form or in H3BO3 or H3PO4 form were obtained with increased thermal stability in comparison to the starting material. By cross-linking and quaternization of sawdust in one step with 1,3-bis(3-chloro-2-hydroxypropyl)imidazolium hydrogen sulfate, a material with better thermal stability and flame-retarding properties was obtained than by the previous procedure. This resulted in greater residues at higher temperatures as measured by dynamic thermogravimetry. The values of rate constants and activation energies of gasification calculated from isothermal thermogravimetric measurements decreased with improved thermal resistance similar to heat effects observed with differential scanning calorimetry. Limited oxygen index values up to 35.6% were obtained. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 179-185 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Silicones comprise a wide variety of materials such as fluids, elastomers, resins, and foams. This paper reports the ignitability of some typical silicones under various external radiant heat fluxes. The ignitability of silicones was studied using a cone calorimeter under radiant heat flux levels of 0.5-60 kW m-2. The time to ignition of the silicones was found to be proportional to a power of the incident heat flux that varies from -1.33 to -2.84. For silicone fluids, viscosity (or molecular size) is the key variable in controlling the ignitability. For silicone elastomers, the fillers play an important role in controlling the ignitability, especially at incident heat fluxes lower than 35 kW m-2. The ignitability of silicone resins depends on the chemical structure of the resins: the pure trifunctional resin has the lowest ignitability. The ignitability of the silicone foams having the same density depends on the foam thickness, especially at incident heat fluxes lower than 30 kW m-2. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 199-206 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The behaviour of wood with the heat-compressed treatment method was evaluated. Fire retardance and endurance of wood treated with basic nitrogen compounds and phosphoric acid were much improved by the compressed method using a hot press. In this way, the concentration of chemical contents and the density of wood were raised at the surface of the treated wood and it increased the specific gravity of the treated wood as a whole. It was recognized that the increase of specific gravity improved fire retardance and endurance, and fire endurance of wood was indicated by the equation of addition of chemicals and specific gravity. It is more effective to increase the specific gravity of wood at the surface to improve fire endurance. Wood treated with chemicals showed a high limiting oxygen index in proportion to the increase in the addition of chemicals regardless of the treatment method, and high fire endurance was not always accompanied by a high limiting oxygen index. © 1998 John Wiley & Sons, Ltd.
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    Notes: Fire retardant fast-growing wood product was developed by coating with fire retardant and densifying the surface of wood. Trimethylol melamineformaldehyde resin mixed with phosphoric acid was coated on the wood surface, preheated and followed by hot pressing. Effects of the amount of coating, preheating temperature, and densifying ratio on the fire retardancy of sugi (Cryptomeria japonica D. Don) wood, and pressing temperature and pressing time on that of albizia (Paraserianthes falcataria Becker) wood were discussed. Bending strength, creep performance under fire and fire retardancy were evaluated. The results showed that the treatments improved the fire retardancy of woods without reduction in the bending strength. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 155-157 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Samples of unscoured, scoured, bleached and mercerized cellulosic fabrics were treated with dimethylol urea (DMU). It was observed that this treatment imparted to the fabrics flame retardant (FR) characteristics. These observations were interpreted in terms of the fact that DMU reacts bifunctionally with glucopyronosyl hydroxyls in such a way that a three-dimensional (hence more stable) structure develops in addition to the possibility of release of acid residues within the flaming zone.
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    Fire and Materials 20 (1996), S. 115-121 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reports on the ignitability of common siding materials that could be exposed to wildland fires. When exposed to brands or fires, structures will experience piloted ignition, which is requisite for sustained ignition involving burn-through and surface flame spread in various directions. In this study, the Lateral Ignition and Flame Spread Test (LIFT) apparatus (ASTM E1321 and E1317) was used to test various siding materials (plywoods, softwoods, and vinyl), some of which were painted, humidified, or sawed. A recently developed protocol provided useful, accurate values of the following thermophysical properties: surface emissivity, surface ignition temperature, thermal conductivity, and thermal diffusivity. Full consistency was achieved with independent literature values of these properties and can be used directly in the database of fire growth models.
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    Fire and Materials 20 (1996), S. 159-159 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: No Abstract
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    Fire and Materials 20 (1996) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: The adduct of zeolites in intumescent formulations of thermoplastic polymers (additives: ammonium polyphosphate and pentaerythritol) leads to a great improvement in their fire retardant performance. A classification of different groups (A, X, Y, Mordenite and ZSM-5) is presented. The influence of the physicochemical properties of the zeolites is discussed. TG analyses reveal that the zeolite may act as a catalyst for the development of the intumescent carbonaceous material and stabilize the carbonaceous residue resulting in the degradation of the intumescent shield. Characterized by MAS-NMR 27Al and 29Si, it is proposed that alumino- and silicophosphate species formed are catalysts active for the synthesis of a protective carbon-based material.
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  • 82
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    Fire and Materials 20 (1996), S. 205-211 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper gives an overview of the Combustion Behaviour of Upholstered Furniture (CBUF) project. The work described is the collective effort of 11 CBUF partners, laboratories, universities, industries, in eight countries. It became possible to do this research thanks to the European Commission's interest in the burning behaviour of upholstered furniture and their willingness to sponsor this effort. The opportunity to work with many of the most prominent fire researchers and furniture experts has been extremely rewarding. All the expertise of these scientists has resulted in many research results that are presented here. The article only gives the main findings and conclusions of the project, namely the presentation of the fire safety design procedure of the CBUF project. Other articles will deal with specific modelling topics and an extensive description of the project can be found in the final CBUF report EUR 16477 EN.
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  • 83
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    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 84
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    Fire and Materials 20 (1996), S. 213-213 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 85
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    Fire and Materials 20 (1996), S. 253-259 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The thermal decomposition of azobisisobutyronitrile (AIBN) has been studied under fully adiabatic conditions in a sealed bomb using an accelerating rate calorimetry technique (ARC). Data relating to temperature, pressure and time have been discussed. AIBN decomposes exothermally and the onset of decomposition occurs at 56.19°C. The reaction reaches its maximum at 112.28°C. During this temperature range, the self-heat rate, and the time to maximum rate of the reaction were evaluated. The experimental data have been also treated to evaluate the activation energy of the potential runaway reaction.
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  • 86
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    Fire and Materials 20 (1996), S. 215-224 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Based on the CFAST model, this paper describes a two-layer zone model developed to predict the environment in a multi-compartment structure subjected to a fire. The predictive equations, fire sub-processes and algorithm are concisely described. In order to validate the model and program a series of experimental data obtained from Cooper's work at NIST were selected for comparison with numerical results, and the comparison is fundamentally favourable. This paper presents an example of this comparison, including the results simulated by the CFAST zone model (Version 1.6). It is shown from the comparison that this model predicts better results than that of the CFAST for these cases, and convection heat transfer may be underestimated in the two models. It is also shown that C.W. Gear's stiffly stable method is feasible in numerically integrating the governing equation set. Additionally, this model is applied to conduct a parameter sensitivity analysis for a two-room fire, and some informative results are given and discussed.
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  • 87
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    Fire and Materials 20 (1996), S. 225-233 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Fourier Transform infrared spectrometer method is developed by VTT Fire Technology in Finland, and is described by NORDTEST as NT FIRE 047. The method takes gas samples from the ventilation duct of a cone calorimeter, and is used to perform dynamic quantitative or qualitative measurements. This is an important step in the direction of continuous measurements of gas components in fire smoke. A lot of effort, knowledge and funds are required for a proper calibration and use of this equipment. The experience with application and interpretation of the test method is reviewed in regard to mounting, calibration and use of the equipment. The work concludes that the NORDTEST NT FIRE 047 test method needs to be revised and completed in the sections on apparatus, calibration routines, analysis procedure and expression of results. The missing information and details can lead to differences in application of the method. Until a revised document appears, frequent communication between laboratories can eliminate these differences.
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    Fire and Materials 20 (1996), S. 235-243 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire prevention, detection, and suppression requirements for spacecraft are based on those established for terrestrial and aircraft systems. In the weightless (or microgravity) environment of an orbiting spacecraft, however, the buoyant upward flow typical of fires in terrestrial environments is nearly absent; and this feature profoundly influences fire characteristics and responsive safety strategies. This paper reviews the findings of microgravity-combustion research that are relevant to techniques of spacecraft fire safety. These practical applications are further illustrated by descriptions of some fire-safety requirements and design features of the Shuttle and those in progress for the International Space Station.
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  • 89
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    Fire and Materials 20 (1996), S. 245-252 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper discusses the predicted results obtained from models developed to determine the effects of furnace depth (2.5 m and 0.5 m), type of furnace lining material type (fireclay brick, insulating firebrick and ceramic fibre insulation) and type of fuel (gas or liquid) on fire severity in fire resistance test furnaces using the CAN/ULC-S101, ASTM E119 and ISO 834 time-temperature relationships. The type of fuel used in the furnace and the type of furnace wall lining material significantly affected the heat absorbed by the test specimen while the furnace depth effect was minimal when the furnace was lined with ceramic fibre insulation. Factors to improve the repeatability and reproducibility of the fire severity in fire resistance test furnaces are provided.
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  • 90
    ISSN: 0308-0501
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Silica gel combined with potassium carbonate is an effective fire retardant for a wide variety of common polymers (at mass fraction of only 10% total additive) such as polypropylene, nylon, polymethylmethacrylate, poly(vinyl alcohol), cellulose, and to a lesser extent polystyrene and styrene-acrylonitrile. The peak heat release rate is reduced by up to 68% without significantly increasing the smoke or carbon monoxide levels during the combustion. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 41-49 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Flame-retarded epoxy composites and phenolic composites containing fiberglass, aramid (Kevlar® 49), and graphite fiber-reinforcements were tested using the NASA upward flame propagation test, the controlled-atmosphere cone calorimeter test, and the liquid oxygen (LOX) mechanical impact test. The upward flame propagation test showed that phenolic/graphite had the highest flame resistance and epoxy/graphite had the lowest flame resistance. The controlled-atmosphere cone calorimeter was used to investigate the effect of oxygen concentration and fiber reinforcement on the burning behavior of composites. The LOX mechanical impact test showed that epoxy/fiberglass had the lowest ignition resistance and phenolic/aramid had the highest ignition resistance in LOX. The composites containing epoxy resin and/or aramid fiber reinforcement reacted very violently in LOX upon mechanical impact. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 75-83 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Melamine and its salts added to polyamide 6 (PA-6, nylon 6) improve its fire retardancy as measured by oxygen index and UL94 tests. The mechanism of the fire-retardant action of the additives was studied using thermogravimetry, kinetics of thermal decomposition and characterization of solid residues and evolved high-boiling products. It was found that melamine, melamine oxalate, melamine phthalate and melamine cyanurate facilitate thermal decomposition of PA-6 with increasing evolution of oligomeric chain fragments instead of caprolactam, which is the principal product evolved from the nonfire-retarded PA-6. These additives promote non-combustible flow dripping and help extinguishment of the flame. The observed increase in solid residue from the thermal decomposition of the formulations or the endothermic cooling due to melamine evaporation might give an additional but less important contribution to fire retardancy. In the case of dimelamine phosphate and melamine pyrophosphate, PA-6 reacts with liberated phosphoric acids producing phosphoric esters which give char upon further thermal decomposition. The fire-retardant effect of these two salts is mostly attributed to polymer mass retention and intumescent layer protection mechanisms. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 107-114 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The National Building Code of Canada provides architects, engineers and builders with a simple, practical calculation method for assigning fire-resistance ratings to wood-frame and steel-frame wall, floor and roof-ceiling assemblies. It was originally devised in the early 1960s and is commonly known as the Component Additive Method (CAM). A collaborative industry-government research program was carried out recently at the National Research Council Canada to develop new fire-resistance ratings for gypsum-board protected walls. Forintek Canada Corp. and the Canadian Wood Council participated in that program on behalf of Canada's wood industry. As part of the research program, a number of full-size fire-endurance tests were carried out on wood-frame and steel-frame walls. The results of those fire tests have allowed us to revisit those sections of the Component Additive Method which are applicable to light-frame walls lined with gypsum board. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 115-121 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Tests were conducted on two fabrics intended for use in protective clothing: an aramid (used extensively in firefighter gear) and a modified viscose cellulosic fabric. Both were exposed to very high heat (temperatures above 400°C) and their performance as thermal insulators was assessed by the temperature transmitted through the fabric, both in their dry state and after being exposed to a water spray. Both fabrics performed satisfactorily, but the modified viscose fabric improved its thermal insulation properties when damp, while the aramid fabric remained unaffected (or perhaps negatively affected) by the water spray. Overall, the modified viscose fabric seemed a better thermal insulator than the aramid. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 123-141 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The present study investigates the validity of a test method for smoldering cigarette ignition propensity of upholstery fabrics based on using ‘cotton duck’ fabrics, and proposed by NIST. A comparison was made between the ignition propensity of cigarettes as assessed by (1) a set of 500 upholstery fabrics (chosen at random among typical upholstery fabrics) and (2) a test method proposed by NIST (NIST 851), and based on ‘cotton duck’ fabrics. The set of 500 fabrics can be assumed to be a representative cross-section of the upholstery fabrics available in the early 1990s, while the ‘cotton duck’ fabrics are not typical upholstery fabrics, and it was unclear whether they would behave similarity or differently from upholstery fabrics. Of the 500 fabrics tested, only 145 fabrics were ignitable by cigarettes, all of them predominantly (or completely) cellulosic. This study found that the overall results obtained from the 500-upholstery fabric study correlate well with those of the ‘cotton duck’ study. Therefore, the ‘cotton ducks’ can be considered, as a whole, to behave similarly to the majority (estimated at perhaps 80%) of the upholstery fabrics available at the time of the study, and the test is valid. In this study it was also found that the ‘cotton duck’ test method correlated well with an earlier cigarette ignition test method, shown to be a good predictor of full-scale upholstered furniture cigarette ignition results, when using a set of five cigarettes. Finally, a fabric density threshold was found, above which the percentage of ignitions of cellulosic fabrics, the percentage of cellulosic fabrics that are ignitable and the flame spread rate of fabrics in a flaming ignition test are all unaffected. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 187-189 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fire standard for aircraft interior panels has been compared to the corresponding marine standard with respect to smoke emission and heat release rate. This has been performed by testing an aircraft panel approved by the Federal Aviation Administration according to one of the International Maritime Organization standards for High-Speed Craft, according to the full-scale room fire test, ISO 9705. The test showed that even if the panel met the strict requirements of the Federal Aviation Administration it did not fulfil the apparently even stricter requirements of the International Maritime Organization. The panel failed on several accounts, including smoke production, heat release and structural integrity. © 1997 John Wiley & Sons, Ltd.
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  • 97
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    Notes: The fire response of a potassium aluminosilicate (Geopolymer) matrix carbon fiber composite was measured and the results compared to organic matrix composites being used for transportation, military, and infrastructure applications. At irradiance levels of 50 kWm-2 typical of the heat flux in a well-developed fire, glass- or carbon-reinforced polyester, vinylester, epoxy, bismaleimde, cyanate ester, polyimide, phenolic, and engineering thermoplastic laminates ignited readily and released appreciable heat and smoke, while carbon-fiber reinforced Geopolymer composites did not ignite, burn, or release any smoke even after extended heat flux exposure. The Geopolymer matrix carbon fiber composite retains 67% of its original flexural strength after a simulated large fire exposure. © 1997 US Government
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    Fire and Materials 21 (1997), S. 191-194 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The study presented here was designed to provide information on the nature of fibres subjected to the action of raised temperature and on the possibility of determination of the incinerated material. X-ray powder diffraction was used as the most reliable method of identifying the composition of crystalline substances. The subject of study was natural and synthetic fibres, the most frequently used in Poland in recent years; for the simulation of phenomena caused by the action of raised temperature the fibres were incinerated in a muffle furnace. The samples of analyzed incinerated fibres were of different chemical species, and those differences were more evident for natural fibres, where from five to seven chemical species or minerals were detected. In specific forensic cases related to incinerated fibres FTIR, SEM/EDX, polarized light microscope and X-ray powder diffraction techniques should be used simultaneously to give full results. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 205-211 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The contrast attenuation coefficient characterizes smoke production properties of a material. These properties are closely connected with a contrast of luminance of a scene observed in a smoky medium, the range of visibility, and mass concentration in an environment volume. The range of visibility determines a person's chances of moving about in a fire zone. This paper presents considerations on conditions of visibility in smoky compartments, a method of the contrast attenuation measurement and test results for some materials. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 161-168 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A mathematical and computational model simulating the coupled heat and mass transfer and related processes in porous media exposed to elevated temperatures has been developed. Taking into account the conservation of mass, momentum and energy, and including the effects of evaporation and dehydration processes on the transport phenomena, a set of three coupled nonlinear differential equations is obtained. Siliceous aggregate concrete slabs subjected to the ASTM E119 standard fire exposure are modeled and validated against test data. Output depicts the coupled relationships between the material's temperature, moisture content, and pore pressure histories and distributions. © 1997 John Wiley & Sons, Ltd.
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