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  • Biochemistry and Biotechnology  (3,415)
  • Inorganic Chemistry  (2,355)
  • Geophysics  (1,233)
  • 1995-1999  (6,425)
  • 1945-1949  (578)
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  • 1
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    Developments in Petrophysics (1997)
    London : The Geological Society
    Details
    Keywords: Petrophysik ; Geophysics ; Petroleum - Geology ; Petroleum engineering ; Rocks
    Description / Table of Contents: P. D. Jackson, D. G. Gunn, R. C. Flint, D. Beamish, P. I. Meldrum, M. A. Lovell, P. K. Harvey, and A. Peyton: A non-contacting resistivity imaging method for characterizing whole round core while in its liner / Geological Society, London, Special Publications, 122:1-10, doi:10.1144/GSL.SP.1997.122.01.01 --- D. J. Prosser, A. Hurst, and M. R. Wilson: One-man-operable probe permeameters / Geological Society, London, Special Publications, 122:11-18, doi:10.1144/GSL.SP.1997.122.01.02 --- S. R. McDougall, A. B. Dixit, and K. S. Sorbie: Network analogues of wettability at the pore scale / Geological Society, London, Special Publications, 122:19-35, doi:10.1144/GSL.SP.1997.122.01.03 --- S. Pugliese and N. Petford: Pore-structure visualization in microdioritic enclaves / Geological Society, London, Special Publications, 122:37-46, doi:10.1144/GSL.SP.1997.122.01.04 --- Paul B. Basan, Ben D. Lowden, Peter R. Whattler, and John J. Attard: Pore-size data in petrophysics: a perspective on the measurement of pore geometry / Geological Society, London, Special Publications, 122:47-67, doi:10.1144/GSL.SP.1997.122.01.05 --- M. S. King, A. Shakeel, and N. A. Chaudhry: Acoustic wave propagation and permeability in sandstones with systems of aligned cracks / Geological Society, London, Special Publications, 122:69-85, doi:10.1144/GSL.SP.1997.122.01.06 --- Shiyu Xu, Just Doorenbos, Sue Raikes, and Roy White: A simple but powerful model for simulating elastic wave velocities in clastic Silicate rocks / Geological Society, London, Special Publications, 122:87-105, doi:10.1144/GSL.SP.1997.122.01.07 --- T. Apuani, M. S. King, C. Butenuth, and M. H. De Freitas: Measurements of the relationship between Sonic wave velocities and tensile strength in Anisotropic rock / Geological Society, London, Special Publications, 122:107-119, doi:10.1144/GSL.SP.1997.122.01.08 --- C. McCann, J. Sothcott, and S. B. Assefa: Prediction of petrophysical properties from seismic quality factor measurements / Geological Society, London, Special Publications, 122:121-130, doi:10.1144/GSL.SP.1997.122.01.09 --- Y. F. Sun and D. Goldberg: Estimation of aspect-ratio changes with pressure from seismic velocities / Geological Society, London, Special Publications, 122:131-139, doi:10.1144/GSL.SP.1997.122.01.10 --- P. K. Harvey, M. A. Lovell, J. C. Lofts, P. A. Pezard, and J. F. Bristow: Petrophysical estimation from downhole Mineralogy logs / Geological Society, London, Special Publications, 122:141-157, doi:10.1144/GSL.SP.1997.122.01.11 --- Paul F. Worthington: Petrophysical estimation of permeability as a function of scale / Geological Society, London, Special Publications, 122:159-168, doi:10.1144/GSL.SP.1997.122.01.12 --- C. A. Gonçalves, P. K. Harvey, and M. A. Lovell: Prediction of petrophysical parameter logs using a multilayer backpropagation neural network / Geological Society, London, Special Publications, 122:169-180, doi:10.1144/GSL.SP.1997.122.01.13 --- Brian P. Moss: The partitioning of petrophysical data: a review / Geological Society, London, Special Publications, 122:181-252, doi:10.1144/GSL.SP.1997.122.01.14 --- A. Revil, P. A. Pezard, and M. Darot: Electrical conductivity, spontaneous potential and ionic diffusion in porous media / Geological Society, London, Special Publications, 122:253-275, doi:10.1144/GSL.SP.1997.122.01.15 --- Brígida Ramati P. Da Rocha and Tarek M. Habashy: Fractal Geometry, porosity and complex resistivity: from rough pore interfaces to hand specimens / Geological Society, London, Special Publications, 122:277-286, doi:10.1144/GSL.SP.1997.122.01.16 --- Brígida Ramati P. Da Rocha and Tarek M. Habashy: Fractal Geometry, porosity and complex resistivity: from hand specimen to field data / Geological Society, London, Special Publications, 122:287-297, doi:10.1144/GSL.SP.1997.122.01.17 --- M. Ben Clennell: Tortuosity: a guide through the maze / Geological Society, London, Special Publications, 122:299-344, doi:10.1144/GSL.SP.1997.122.01.18 --- J. C. Lofts, J. Bedford, H. Boulton, J. A. van Doorn, and P. Jeffreys: Feature recognition and the interpretation of images acquired from horizontal wellbores / Geological Society, London, Special Publications, 122:345-365, doi:10.1144/GSL.SP.1997.122.01.19 --- D. Goldberg and Y. F. Sun: Scattering attenuation as a function of depth in the Upper Oceanic Crust / Geological Society, London, Special Publications, 122:367-375, doi:10.1144/GSL.SP.1997.122.01.20 --- N. Passas, C. Butenuth, and M. H. De Freitas: An application of the Moiré Method to a study of local strains during rock failure in tension / Geological Society, London, Special Publications, 122:377-388, doi:10.1144/GSL.SP.1997.122.01.21
    Pages: Online-Ressource (VII, 393 Seiten) , Illustrationen, Diagramme, Karten
    ISBN: 1897799810
    URL: http://sp.lyellcollection.org/content/122/1
    Language: English
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  • 2
    Electronic Resource
    Electronic Resource
    The importance of radioactivity in geoscience and mining (1995)
    Springer
    Cellular and molecular life sciences 51 (1995), S. 703-709 
    Details
    ISSN: 1420-9071
    Keywords: Geophysics ; geology ; natural radioactivity ; radiometry ; mining ; uranium ores ; radon ; disposal of radioactive waste
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Almost simultaneously with Roentgen rays, natural radioactivity was discovered. Its investigation led to important fundamentals of the geosciences: petrophysics, terrestrial heat flow, isotope geology, and absolute geological chronology. In applied geophysics and geology, exploration of radioactive ores and of tectonic faults, and radiometric well loggings, are used. Production of radioactive water and mining for uranium ores are discussed, including their development (especially in the Saxon ore mountains) and the consequences on health (radon in underground air and houses). Disposal of radioactive waste is touched on briefly.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01941267
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  • 3
    Electronic Resource
    Electronic Resource
    The role of the Hermanus Magnetic Observatory in geomagnetic field research (1995)
    Springer
    Astrophysics and space science 230 (1995), S. 439-456 
    Details
    ISSN: 1572-946X
    Keywords: Geophysics ; geomagnetic field
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Geomagnetic field research carried out at the Hermanus Magnetic Observatory over the past decade is reviewed. An important aspect of this research has been the study of geomagnetic field variations, with particular emphasis on ULF geomagnetic pulsations. Features of geomagnetic pulsations which are unique to low latitude locations have been investigated, such as the cavity mode nature of low latitude Pi 2 pulsations and the role played by ionosphericO + ions in the field line resonances responsible for Pc 3 pulsations. A theoretical model has been developed which is able to account for the observed relationships between geomagnetic pulsations and oscillations in the frequency of HF radio waves traversing ionospheric paths. Other facets of the research have been geomagnetic field modelling, aimed at improving the accuracy and resolution of regional geomagnetic field models, and the development of improved geomagnetic activity indices.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00658201
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  • 4
    Electronic Resource
    Electronic Resource
    An Approach to a Visual Language for Convective Fluid Flows: Visualization of Geophysical Simulations (1998)
    Springer
    Visual geosciences 3 (1998), S. 1-19 
    Details
    ISSN: 1610-2924
    Keywords: Geophysics ; Numerical modelling ; Visualization ; Language ; Convection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract It was known that deep within numbers and binary data from simulations of geophysical convective flows resided various patterns. Two models of convective fluid flows were being considered. One was a model of two-dimensional (768 × 256) air convection with finite Prandtl number of one and Rayleigh number of 108−1010, and another was a model of three-dimensional (up to 120 × 120 × 90) mantle convection with infinite Prandtl number and Rayleigh number of 106−108. Clearly, phenomena existed which superceded each individual dimensionless computer model to provide a piece of information regarding actual fluid flows. The problem was how to find, prove, and communicate these patterns and phenomena for convection simulations with gigabytes of data. In a search for such an analytical and communicative tool, the alternative of visualization was considered. The need for visualization was recognized and discussed. Then, utilizing both two- and three-dimensional models of high Rayleigh number convection, basic techniques of style and content were developed. Applications of the visualization techniques were designed utilizing IBM’s Data Explorer in order to create communicative images and movies, and after the applications, the problems of data storage and transfer became apparent. Throughout the process though, it became clear how important the language of vision actually could be in the geophysics community. In a field in which words such as plumes and internal waves have in ways replaced mathematics as the basic language for science, there is a need for another resource, another language-the visualization of convective fluid flows.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s10069-998-0001-3
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  • 5
    Electronic Resource
    Electronic Resource
    Masthead (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995) 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280101
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  • 6
    Electronic Resource
    Electronic Resource
    Tripodal Triamidostannates as Building Blocks in the Generation of Sn - M-Bonded Heterobimetallics (M = Fe, Ru) (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 29-34 
    Details
    ISSN: 0009-2940
    Keywords: Tripodal ligands ; Triamidostannates ; Metal-metal bonds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: By in situ lithiation of the trifunctional amines H3CC(CH2NHSiMe3)3, PhC(CH2NHSiMe3)3, and HC{SiMe2NH(p-Tolyl)}3 and subsequent reaction with SnCl2 the corresponding triamidostannates were obtained. These were coupled with CpM(CO)2Cl (M = Fe, Ru) to yield the M - Sn-bonded heterobimetallics 9-14 of which H3CC(CH2NSiMe3)3SnFe(CO)2Cp (9) was characterized by a single-crystal X-ray structure analysis. Of the in situ-generated amidostannates only [HC{SiMe2N(p-Tolyl)}3Sn][Li(THF)3] (8) could be isolated as a uniform product and characterized analytically and spectroscopically.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280105
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  • 7
    Electronic Resource
    Electronic Resource
    The Structures of [X2Y—N—YX2]+ Cations (X = F, Cl; Y = S, Se). A Comparison of X-ray and ab Initio Studies[1] (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 35-40 
    Details
    ISSN: 0009-2940
    Keywords: Selenium-nitrogen compounds ; Sulfur-nitrogen compounds ; Calculations, ab initio ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The structures of cationic species of the series [X2Y—N—YX2]+ (X = F, Cl; Y = S, Se) have been computed ab initio using all electron treatments for first-row elements and sulfur and quasi-relativistic pseudopotentials for Se and Cl. Splitvalence basis sets with polarization and diffuse functions were employed. The MP2 results for the (non-isostructural!) cations [Cl2Se—N—SeCl2]+ (1: Cs) and [F2S—N—SF2]+ (2: C2v) are in excellent agreement with the experimental (X-ray) observations. Both structures represent local minima. A deeper minimum for either of the cations is represented by another C2v isomer which for crystal lattice energy reasons is stable in the isolated state only. The geometries of the hitherto unknown species [Cl2S—N—SCl2]+ (3) and [F2Se—N—SeF2]+ (4) have been assessed by ab initio HF calculations. In analogy to 2, cations 3 and 4 are predicted to prefer C2v symmetry. Therefore, 1 exhibits unusual structural features. According to strictly localized natural bond orbital analysis (NBO), the central nitrogen atoms in 1 and 2 possess two lone pairs of electrons (LP: one sp hybrid and one p orbital). The relatively short Se—N and S—N bond distances in 1 (1.741-1.760 Å) and 2 (1.551 Å) can best be attributed to LP(N)→s̰*(Y—X) negative hyperconjugation (1: Y = Se, X = Cl; 2: Y = S, X = F).
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280106
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  • 8
    Electronic Resource
    Electronic Resource
    Die fördernde Rolle von Phosphinoester-Liganden bei der Synthese neutraler Carben-, Vinyliden- und Allenyliden-Ruthenium(II)-KomplexeHerrn Professor Hubert Schmidbaur zum 60. Geburtstag gewidmet. (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 49-62 
    Details
    ISSN: 0009-2940
    Keywords: Ruthenium(II) complexes, octahedral ; Phosphino esters as mono- and bidentate ligands ; Fluxional behaviour ; Carbene complexes ; Vinylidene complexes ; Allenylidene complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vinylidene Transition-Metal Complexes, XXXV[1].  -  The Supporting Role of Phosphino Ester Ligands for the Synthesis of Neutral Carbene, Vinylidene and Allenylidene Ruthenium(II) ComplexesThe reaction of [RuCl2(PPh3)3] (1) with the phosphino esters iPr2P(CH2)nCO2R (2-4) leads to complete (n = 1; R = CH3, C2H5) or partial (n = 2; R =CH3) displacement of the PPh3 ligands and formation of the octahedral ruthenium(II) complexes [RuCl2{k2(P,O)-iPr2PCH2CO2R}2] (5, 6) and [RuCl2(PPh3){k(P)-iPr2PCH2CH2CO2Me}{k2(P,O)-iPr2PCH2CH2CO2Me}] (7). Treatment of 5 with LiBr and LiI affords the dibromo- and diiodoruthenium derivatives 8 and 9. While compound 5 reacts with CO and SO2 by cleavage of one Ru - O bond to yield the 1:1 adducts [RuCl2(L){k(P)-iPr2PCH2CO2Me}{k2(P,O)-iPr2PCH2CO2Me}] (10, 11), the reaction of the dibromo derivative 8 with CO in solution gives the dicarbonyl complex [RuBr2(CO)2{k(P)-iPr2PCH2CO2Me}2](13). If CO is passed over 8 in the solid state, the corresponding monocarbonyl compound 14 is formed. The hydridoruthenium(II) complex 16, which is obtained from equimolar amounts of [RuHCl(CO)(PiPr3)2] (15) and 2, reacts with HC≡CMe by insertion to give the vinyl derivative [RuCl{E - CH=CHMe}(CO)(PiPr3){k2(P,O)-iPr2CH2CO2Me}] (17). Treatment of 5 with HC̊' (R' = H, Me, tBu, Ph) and of 6, 8, 9 with HC≡CPh affords upon photochemical activation the octahedral vinylidene complexes [RuX2-(=C=CHR){k(P)-iPr2PCH2CO2R}{k2(P,O)-iPr2PCH2CO2R}] (18-21 and 23-25) in good to excellent yield. At room temperature, these compounds (with the exception of 25) are highly fluxional in solution. From 31P-NMR measurements, the free energies of activation ΔG
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280108
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  • 9
    Electronic Resource
    Electronic Resource
    Reaktionen von R2Al—AlR2 (R = CH(SiMe3)2) mit Trimethylsilylazid  -  Insertion in die Al—Al-Bindung und Abbau zum trimeren Dialkylaluminiumazid (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 81-85 
    Details
    ISSN: 0009-2940
    Keywords: Aluminium-aluminium bond ; Insertion of trimethylsilyl azide ; Trimeric dialkylaluminium azide ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions of R2Al—AlR2 (R = CH(SiMe3)2) with Trimethylsilyl Azide  -  Insertion into the Al—Al Bond and Formation of a Trimeric Dialkylaluminium AzideTetrakis[bis(trimethylsilyl)methyl]dialuminium(4) (1) reacts with trimethylsilyl azide under insertion of one nitrogen atom into the Al—Al bond. As shown by NMR spectra and crystal structure the product contains three and four coordinated Al atoms due to the coordination of the α-nitrogen atom of the azide group to one of the Al atoms. An electronically delocalized N3-system is formed with a N—N bond length of 132.0 pm and a bond order of 1.5 for both N—N bonds. With an excess of trimethylsilyl azide further reaction is observed only under mild irradiation conditions with an exchange of the azide group between Si and Al and formation of Me6Si2 and the dialkylaluminium azide 3, which is better synthesized by the reaction of Me3Si—N3 with Cl—Al[CH(SiMe3)2]2. The sterically highly shielded aluminium azide 3 is a trimer in the solid state showing a non-planar 12-membered Al3N9 heterocycle with short N—N bonds (114 pm).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280112
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  • 10
    Electronic Resource
    Electronic Resource
    Transition-Metal Complexes with the Novel Scorpionate Ligand Dihydrobis-(tetrazolyl)borate: Synthesis and Characterization of Infinite Two-Dimensional Metal-Ligand Frameworks and One-Dimensional Water SubstructuresDedicated to Professor Dr. Herbert Schumann on the occassion of his 60th birthday. (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 323-328 
    Details
    ISSN: 0009-2940
    Keywords: Poly(azolyl)borates, metal complexes of ; Bis(tetrazolyl)borate, metal complexes of ; Metal-nitrogen coordination ; Coordination polymers ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dihydrobis(tetrazolyl)borate metal compounds of the composition [M(L)2{μ-H2B(CHN4)2}2]n for M = Mn, Fe, Co, Zn, Cd with L = H2O and for M = Cu with L = NH3 are obtained from metal salts and K[H2B(CHN4)2]. Single-crystal X-ray studies reveal the formation of two-dimensional rhombic grid sheets through the bridging action of the bis(tetrazolyl)borate ligands. Each metal atom is octahedrally coordinated with two trans L ligands and four H2B(CHN4)-2 nitrogen donors. Two additional, hydrogen-bonded water molecules occupy the rhombic openings in the compounds with M = Mn, Fe, Co, Zn, and Cd. The water of crystallization is held in place through hydrogen bonding from the water ligands and to the nitrogen atoms to give a substructure of parallel kinked water chains. Temperature-variable magnetic measurements show a Curie-Weiss behavior for the paramagnetic complexes with M = Mn, Fe, Co, and Cu.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280402
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