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  • Geophysics  (1,332)
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  • General Chemistry
  • 2000-2004  (1,711)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 27 (2000), S. 533-544 
    ISSN: 1432-2021
    Keywords: Key words High pressure ; High temperature ; DHMS ; phases A ; G
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract We conducted high-pressure phase equilibrium experiments in the systems MgSiO3 with 15 wt% H2O and Mg2SiO4 with 5 wt% and 11 wt% H2O at 20 ∼ 27 GPa. Based on the phase relations in these systems, together with the previous works on the related systems, we have clarified the stability relations of dense hydrous magnesium silicates in the system MgO-SiO2-H2O in the pressure range from 10 to 27 GPa. The results show that the stability field of phase G, which is identical to phase D and phase F, expands with increasing water contents. Water stored in serpentine in the descending cold slabs is transported into depths greater than 200 km, where serpentine decomposes to a mixture of phase A, enstatite, and fluid. Reaction sequences of the hydrous phases which appear at higher pressures vary with water content. In the slabs with a water content less than about 2 wt%, phase A carries water to a depth of 450 km. Hydrous wadsleyite, hydrous ringwoodite, and ilmenite are the main water reservoirs in the transition zone from 450 to 660 km. Superhydrous phase B is the water reservoir in the uppermost part of the lower mantle from 670 to 800 km, whereas phase G appears in the lower mantle only at depths greater than 800 km. In cold slabs with local water enrichment greater than 2 wt%, the following hydrous phases appear with increasing depths; phase A to 450 km, phase A and phase G from 450 km to 550 km, brucite, superhydrous phase B, and phase G from 550 km to 800 km, and phase G at depths greater than 800 km.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of engineering geology and the environment 58 (2000), S. 125-132 
    ISSN: 1435-9537
    Keywords: Key words Sand ; Fill ; Geophysics ; Nigeria ; Coastal ; Reclamation ; Mots clés Sable ; Remblai ; Geophysique ; Nigeria ; Cótier ; Assainissement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Résumé Il est prévu d'aménager une région de la péninsule de Lekki, de l'État de Lagos. Ainsi, des études ont été entreprises afin de préciser une coupe géologique et géo-électrique des terrains superficiels: identifier les séries sableuses, déterminer leurs épaisseurs et préparer une carte des caractéristiques géomorphologiques du terrain original, avant remblaiement. Des sondages électriques verticaux et des essais au pénétromètre ont été réalisés sur un secteur sableux de la péninsule de Lekki. Les données obtenues ont montré une bonne corrélation entre les caractéristiques géomorphologiques issues de photo-interprétations et celles résultant de cartes établies à partir des résultats de prospection électrique et d'essais au pénétromètre.
    Notes: Abstract  It was hoped to develop an area of reclaimed land on the Lekki Peninsula of Lagos State. An investigation was therefore carried out in order to establish the subsurface geological/geo-electrical sequence; to identify the sand columns and determine their thickness and prepare a map of the geomorphological features of the original, pre-fill terrain. Vertical electrical resistivity soundings (VES) and penetrometer tests were carried out in a sand filled segment of the Lekki Peninsula. The information obtained showed a good correlation between the geomorphological features as interpreted from the aerial photographs and those identified from maps derived from the VES/penetrometer results.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of engineering geology and the environment 59 (2000), S. 157-169 
    ISSN: 1435-9537
    Keywords: Mots clés Lyon–Turin ; Tunnel profond ; Reconnaissances géologiques ; Géophysique ; Forages ; Key words Lyons–Turin ; Deep tunnel ; Geological surveys ; Geophysics ; Boreholes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract  This article presents the evolution of a geological, geotechnical and geophysical survey system for tunnel projects, using the Ambin Tunnel as an example. After a short introduction to the Lyons–Turin project, the paper describes in chronological order the systems and methods used to obtain geological and geotechnical information. Finally, the paper examines the modifications made to this particular survey programme as a result of the data obtained. The consequences for the evolution of the provisional layout of the tunnel are examined. The project to construct a new Lyons–Turin rail connection is part of the European transport scheme and is a key element in the Trans-European Network. It is one of the 14 priority projects of the European Union. This new link is of great importance for passenger transportation between France and Italy in terms of the potential reduction in journey time; the travel time from Lyons to Turin, instead of the current 3 h 55 min, being reduced to 1 h 20 min. It will also accelerate the transportation of goods. Thus, it will provide the best solution to the problems of transalpine traffic congestion and enhance environmental protection. The key element in the international section of this new link is the Ambin Tunnel, which is over 52 km long, running between Saint Jean de Maurienne (France) and Susa-Bussoleno (Italy). The tunnel will go through the main geological units of the Western Alps from the ultra Dauphinese area (external zone) to the Piemontese area after cutting through the Brianconese reliefs (inner zone). Since 1990, an extensive site investigation survey has been conducted by the SNCF (the French national railway company) and the FS (the Italian 'Ferrovie dello Stato'). Since 1994, this survey has been undertaken by the European Group of Economic Interest, Alpetunnel GEIE. The investigation aimed to accurately define the layout of the tunnel and to reduce as many uncertainties as possible with regard to conditions, time and cost of building. The survey initially utilised information on ground conditions from detailed geological maps and air photographs, allowing the construction of a provisional geological cross section of the tunnel. This cross section highlighted a few areas that were poorly understood. These areas were then studied using seismic refraction and reflection, often in tandem with the drilling of boreholes for increased accuracy. Many boreholes have been drilled to determine the geotechnical characteristics in addition to understanding the geology. Many tests and in-situ measurements have also been undertaken to study the hydrogeological and geotechnical conditions in the mountains that will be bored through. In 1999 and 2000, further drilling will be undertaken in areas requiring more detailed study. Also two directional drilling projects will be started vertically and then run obliquely until reaching the horizontal. This will produce more than 1000 m of horizontal core, allowing a better knowledge of the nature of the ground along the axis of the tunnel to be gained, including geotechnical measurements, hydrogeological data and in-situ geotechnical conditions. Later on, these studies will be extended to allow the construction of three or four survey galleries with the same dimensions as the tunnel in order to check and test the in-situ rocks. Some surveys have been changed midstream as a result of initial results. For example, deeper drilling was undertaken following the realisation that a seismic reflector was present a few metres below . It has also proved necessary to change the layout of the survey gallery at Modane and to change its cross section after the results of the first set of boreholes were analysed. Layers of karst, water-filled cavities, soft ground and flowing water were all found. The layout of the tunnel itself has been changed in several places following the results of the boreholes, seismic data or geotechnical tests. Examples include the first mile of the French side, several miles in the Brianconese coal measures, and the underground service installations. These results have led to an increased construction of survey galleries.
    Notes: Resumé Cet article a pour but de présenter l'évolution des reconnaissances géologique, géotechnique et géophysique menées sur un projet de tunnel, à travers l'exemple concret du tunnel d'Ambin, maillon clé de la partie internationale du projet de nouvelle liaison ferroviaire transalpine Lyon-Turin. A travers la description et les commentaires des résultats obtenus par plus de 80 forages (de 50 à 1520 m de longueur), plus de 100 km de sismique de surface et de la sismique de puits réalisée dans une trentaine de forages, nous montrons la progression et l'adaptation des reconnaissances dans une suite logique d'investigations. Nous présentons également les adaptations apportées en cours d'investigation, entreprises en temps réel au vu des premiers résultats, ainsi que les conséquences sur l'évolution du tracé prévisionnel du tunnel et de certaines galeries de reconnaissances.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Surveys in geophysics 21 (2000), S. 423-448 
    ISSN: 1573-0956
    Keywords: Geophysics ; seismic ; electromagnetic ; geo-electric ; resistivity ; self-potential ; gravity ; boundary ; property ; slope stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A pre-requisite in slope stability analyses is that the internal structure and the mechanical properties of the soil or rock mass of the slope, are known or can be estimated with a reasonable degree of certainty. Geophysical methods to determine the internal structure of a soil or rock mass may be used for this purpose. Various geophysical methods and their merits for slope stability analyses are discussed. Seismic methods are often the most suitable because the measurements depend on the mechanical properties that are also important in the mechanical calculation of slope stability analyses. Other geophysical methods, such as electromagnetic, electric resistivity, self-potential, and gravity methods, may be useful to determine the internal structure, but require a correlation of found boundaries with mechanical properties.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1434-193X
    Keywords: Triplet recombination ; Electron transfer ; Radical ions ; Photochemistry ; Terpenes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The triphenypyrylium tetrafluoroborate (TPT)-sensitized reactions of several terpene donor molecules, including sabinene (1), α-phellandrene (4), α-terpinene (5) and γ-terpinene (6) give rise to significantly different products than reactions induced by other electron-transfer sensitizers, such as 1,4-dicyanobenzene (DCB). The divergent reactions require decidedly different key intermediates; the products obtained with TPT can be explained by dissociative recombination of the intermediate radical-radical cation pair in the triplet state, generating donor-derived biradicals.
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  • 6
    ISSN: 1434-193X
    Keywords: Azides ; Cleavage reactions ; Cycloadditions ; Nitrogen heterocycles ; Polycycles ; Ring expansion ; Synthetic methods ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---2-Alkyl-1-methylquinazolinium hexafluorophosphates 9 are deprotonated by sodium or potassium hydride to afford solutions of 2-alkylidenedihydroquinazolines 10, which were investigated by NMR spectroscopy. Trapping with methanesulfonyl azide (5a) of 10 in situ or subsequent treatment with trifluoromethanesulfonyl azide (5b) gives mixtures of colourless (15) and intensely yellow N-sulfonylimino-1,4-benzodiazepines 16 along with products due to cleavage of the exocyclic double bond of 10, viz. 11 and 13. The ethylidene compound 10b yields the bicyclic products 18 and 19, apparently by complex sequences of reactions that are triggered by removal of the acidic proton at C-2 of 16b and 16f. The structures of the products are based on spectroscopic evidence and X-ray diffraction analyses performed on 15b, 16d, 16e, and 19.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1589-1593 
    ISSN: 1434-193X
    Keywords: Azaallenium ions ; Azaallylium ions ; Iminium ion ; Kinetics ; Linear Free Energy Relationships ; Ab initio calculations ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The rate constants for the reactions of the 2-azaallenium ion 1b+, the 2-azaallylium ion 2a+ and the iminium ion 3+ with different nucleophiles were determined by 1H NMR spectroscopy. By correlation with the Linear Free Enthalpy Relationship (LFER) lg k20°C = s (E + N), developed by Mayr and Patz, the electrophilicity parameters E(1b+) = -3.7, E(2a+) ≍ -16 and E(3+) = -10.43 were obtained. They show that the relative reactivities of these ions are approximately 1012:1:106. Quantum chemical calculations (ab initio, DFT) of the methyl anion affinities for the ions 1b+,2a+ and3+ are in agreement with the experimental E values. The X-ray structure of 3+·CF3SO3- is reported for the first time; it shows no strong interaction between the cation and the anion.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1595-1601 
    ISSN: 1434-193X
    Keywords: Oxazoline N-oxide ; Cycloadditions ; Cycloadditions ; Lactams ; Thienamycin ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---[3+2] Cycloaddition between a camphor-derived oxazoline N-oxide 9 and the γ,δ-unsaturated enamino ester 11 afforded the single adduct 6. A stereoselective reduction of the enamino ester side chain allowed the control of the absolute configuration of the two additional asymmetric centres. Nitrogen protection and oxidative hydrolysis of the resulting product 13, followed by further functional group manipulations, led to the β-lactam derivative 1, a known precursor of the β-methylthienamycin derivative2a.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1603-1607 
    ISSN: 1434-193X
    Keywords: Boron ; Cyclotrimerizations ; Nitrogen heterocycles ; Macrocycles ; Subphthalocyanines ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The regioselective preparation of ortho-substituted subphthalocyanides was achieved employing 3-substituted phthalonitrile derivatives as starting materials. A mechanistic proposal has been outlined.Supporting information for this article is available on the WWW under //http://www.wiley-vch.de/contents/jc_2046/2000/99525_s.pdf or from the author.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1609-1615 
    ISSN: 1434-193X
    Keywords: Terpenoids ; Natural products ; Total synthesis ; Cyclizations ; Rearrangements ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---A new route for the synthesis of 2,7- and 7-functionalized labdanes starts from (R)-carvone (1). 11-Nordrim-7-en-9-one (15) is an appropriate starting material for the total synthesis of hispanone (21), a biologically active furolabdane isolated from the Mediterranean medicinal plant Ballota saxatilis.
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