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  • 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas  (13)
  • Elsevier  (13)
  • American Association for the Advancement of Science
  • Springer Science + Business Media
  • 2010-2014  (13)
Collection
Keywords
Publisher
Years
Year
  • 1
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    Carbonate assimilation in magmas: a reappraisal based on experimental petrology (2010)
    Elsevier
    Details
    Publication Date: 2020-11-13
    Description: The main effect of magma-carbonate interaction on magma differentiation is the formation of a silica-undersaturated, alkali-rich residual melt. Such a desilication process was explained as the progressive dissolution of CaCO3 in melt by consumption of SiO2 and MgO to form diopside sensu stricto. Magma chambers emplaced in carbonate substrata, however, are generally associated with magmatic skarns containing clinopyroxene with a high Ca-Tschermak activity in their paragenesis. Data are presented from magma-carbonate interaction experiments, demonstrating that carbonate assimilation is a complex process involving more components than so far assumed. Experimental results show that, during carbonate assimilation, a diopside-hedenbergite-Ca-Tschermak clinopyroxene solid solution is formed and that Ca-Tschermak/diopside and hedenbergite/diopside ratios increase as a function of the progressive carbonate assimilation. Accordingly, carbonate assimilation reaction should be written as follows, taking into account all the involved magmatic components: CaCO3solid+SiO2melt+MgOmelt+FeOmelt+Al2O3melt → (Di-Hd-CaTs)sssolid+CO2fluid The texture of experimental products demonstrates that carbonate assimilation produces three-phases (solid, melt, and fluid) whose main products are: i) diopside-hedenbergite-Ca-Tschermak clinopyroxene solid solution; ii) silica-undersaturated CaO-rich melt; and iii) C-O-H fluid phase. The silica undersaturation of the melt and, more importantly, the occurrence of a CO2-rich fluid phase, must be taken into account as they significantly affect partition coefficients and the redox state of carbonated systems, respectively.
    Description: TRIGS Project “Sixth Framework Programme of the European Commission and to the New and Emerging Science and Technology Pathfinder". Project FIRB MIUR “Development of innovative technologies for the environmental protection from natural events”.
    Description: Published
    Description: 503-514
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: carbonate assimilation ; skarns ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Carbonate-derived CO2 purging magma at depth: Influence on the eruptive activity of Somma-Vesuvius, Italy (2012)
    Elsevier
    Details
    Publication Date: 2020-11-30
    Description: Mafic phenocrysts from selected products of the last 4 ka volcanic activity at Mt. Vesuvius were investigated for their chemical and O-isotope composition, as a proxy for primary magmas feeding the system. 18O/16O ratios of studied Mg-rich olivines suggest that near-primary shoshonitic to tephritic melts experienced a flux of sedimentary carbonate-derived CO2, representing the early process of magma contamination in the roots of the volcanic structure. Bulk carbonate assimilation (physical digestion) mainly occurred in the shallow crust, strongly influencing magma chamber evolution. On a petrological and geochemical basis the effects of bulk sedimentary carbonate digestion on the chemical composition of the near-primary melts are resolved from those of carbonate-released CO2 fluxed into magma. An important outcome of this process lies in the effect of external CO2 in changing the overall volatile solubility of the magma, enhancing the ability of Vesuvius mafic magmas to rapidly rise and explosively erupt at the surface.
    Description: Published
    Description: 84-95
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: stable-isotope ; magma geochemistry ; CO2-degassing ; Vesuvius ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Shifting styles of basaltic explosive activity during the 2002-03 eruption of Mt. Etna, Italy (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The 2002–03 flank eruption of Etna was characterized by two months of explosive activity that produced copious ash fallout, constituting a major source of hazard and damage over all eastern Sicily. Most of the tephra were erupted from vents at 2750 and 2800 m elevation on the S flank of the volcano, where different eruptive styles alternated. The dominant style of explosive activity consisted of discrete to pulsing magma jets mounted by wide ash plumes, which we refer to as ash-rich jets and plumes. Similarly, ash-rich explosive activity was also briefly observed during the 2001 flank eruption of Etna, but is otherwise fairly uncommon in the recent history of Etna. Here, we describe the features of the 2002–03 explosive activity and compare it with the 2001 eruption in order to characterize ash-rich jets and plumes and their transition with other eruptive styles, including Strombolian and ash explosions, mainly through chemical, componentry and morphology investigations of erupted ash. Past models explain the transition between different styles of basaltic explosive activity only in terms of flow conditions of gas and liquid. Our findings suggest that the abundant presence of a solid phase (microlites) may also control vent degassing and consequent magma fragmentation and eruptive style. In fact, in contrast with the Strombolian or Hawaiian microlite-poor, fluidal, sideromelane clasts, ash-rich jets and plumes produce crystal-rich tachylite clasts with evidence of brittle fragmentation, suggesting that high groundmass crystallinity of the very top part of the magma column may reduce bubble movement while increasing fragmentation efficiency.
    Description: Published
    Description: 110-122
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; basaltic explosive activity ; ash-rich jet and plume ; tachylite ; sideromelane ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    The feeding system of Agnano–Monte Spina eruption (Campi Flegrei, Italy): Dragging the past into present activity and future scenarios (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Magmatic processes triggering eruptions at Campi Flegrei caldera (southern Italy) and their relationships with the widespread emissions of fluids and caldera unrest episodes, are poorly constrained. The 4.1 ka B.P. Agnano–Monte Spina eruption, the reference event for a future large-size explosive eruption at Campi Flegrei, was investigated to shed light, through melt inclusion and isotope analyses, on the geochemical processes operating in the plumbing system. Chemical and isotopic data on whole rocks and glasses suggest that at least two magma batches mixed during the course of the eruption. Melt inclusion data highlight the pre-eruption storage conditions of two magmatic end-members. One end-member is like the less differentiated (shoshonitic) Campi Flegrei erupted magma, while the other could be a residual of the Neapolitan Yellow Tuff magma. Mixing between these two components was driven by a large gas phase which sustained the ascent of magmas of deep provenance. The H2O and CO2 contents in pyroxene-hosted melt inclusions yield entrapment pressures between 107 and 211 MPa, corresponding to depths between 4 and 8 km. The degassing trends reveal two extreme patterns. One pattern, already documented in the literature, is the volatile signature of poorly differentiated magmas ascending from more than 8 km depth, while the other is related to a gas-dominated magma, flushed by a CO2-rich gas phase partly released from the deep reservoir. This study provides a conceptual frame for unrest phases at Campi Flegrei, such as the 1982–84 event. Uplift phases can be related to closed-system ascent of magmas and fluids from more than 8 km depth, and their emplacement at shallow levels. This leads the shallow system to store, and then progressively release, the accumulated gas. In this view, both unrest episodes and eruptions could be strongly influenced by both the achievement of a critical upper limit of gas storage in the shallow magmatic reservoir and the stress and fracturing state of the roof rocks. The present results help to constrain the pre-eruptive conditions expected at Campi Flegrei caldera in case of a future large-size eruptive event.
    Description: In press
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Sr and Nd isotopes ; Melt inclusions ; Gas flushing ; Magma mixing ; Bradyseismic crises ; Explosive eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Pantelleria Island, located in the Sicily Channel Rift Zone (Italy), is the type locality for the peralkaline rhyolitic rocks called pantellerites. In the last 50 ka, after the large Green Tuff caldera-forming eruption, volcanic activity at Pantelleria has consisted of effusive and explosive eruptions mostly vented inside and along the rim of the caldera and producing silicic lava flows, lava domes and poorly dispersed pantelleritic pumice fall deposits. Basaltic cinder cones and lava flows are only present outside the caldera in the NW sector of the island. The most recent basaltic (Cuddie Rosse, 20 ka) and pantelleritic (Cuddia Randazzo and Cuddia del Gallo, 6 ka) pyroclastic products were sampled to investigate magmatic volatile contents through the study of melt inclusions. The melt inclusions in pyroxene and olivine phenocrysts of Cuddie Rosse scoriae have an alkali basalt composition. The dissolved volatiles comprise 0.9–1.6 wt.% H2O, several hundred ppm of CO2, 1600–2000 ppm of sulphur and 500–900 ppm of chlorine. The water–carbon dioxide couple gives a confining pressure 2 kbar prior to the eruption. This result indicates that episodes of magma ponding and crystallization occurred in the upper crust prior to eruption. The melt inclusions in feldspar, fayalite and aenigmatite phenocrysts of Cuddia del Gallo and Cuddia Randazzo pumice have a pantelleritic composition (Agpaitic Indices 1.3–2.1), up to 4.4 wt.% H2O, 8700 ppm Cl, 6000 ppm F, and CO2 below the detection limit. Sulphur averaging 420 ppm has been measured in Cuddia Randazzo melt inclusions. These data indicate relatively high volatile contents for these low-energy Strombolian-type eruptions. Melt inclusions in Cuddia del Gallo pumice show the most evolved composition (Agpaitic Indices 2–2.1) and the highest volatile content, in agreement with fluid saturation conditions in the magma chamber prior to the eruption. This implies a confining pressure of 1 kbar for the top of the pantelleritic reservoir. The composition of melt inclusions and mineralogical assemblage of Cuddia Randazzo pumice indicate that it has a lower evolutionary degree (Agpaitic Indices 1.3–1.8) and lower pre-eruptive Cl and H2O contents than Cuddia del Gallo pumice. An increase in pressure due to the exsolution of volatiles in the upper part of the pantelleritic reservoir may have triggered the Cuddia del Gallo explosive eruption. Evidence of widespread pre-eruptive mingling between trachytes and pantellerites suggests that the intrusion of trachytic magma into the pantelleritic reservoir likely played a major role in destabilizing the magma system just prior to the Cuddia Randazzo event.
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Pantelleria ; peralkaline ; volatiles ; melt inclusions ; eruptive style ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Magma vesiculation and infrasonic activity at Stromboli open conduit volcano (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Explosive activity at Stromboli is explained in terms of dynamics of large gas bubbles that ascend in the magma conduit and burst at the free surface generating acoustic pressure that propagates as infrasonic signals in the atmosphere. The rate and the amplitude of the infrasonic activity is directly linked to the rate and the overpressure of the bursting gas bubbles and thus reflects the rate at which magma column degasses under non-equilibrium pressure conditions. We investigate the link between explosive degassing and magma vesiculation by comparing the rate of infrasonic activity with the bubble size distributions (BSDs) of scoria clasts collected during several days of explosive activity at Stromboli. BSDs of scoria show a characteristic power law distribution, which reflect a gas bubble concentration mainly controlled by a combined process of bubble nucleation and coalescence. The cumulative distribution of the infrasonic pressure follows two power laws, indicating a clear separation between the frequent, but weak, bursting of small gas bubbles (puffing) and the more energetic explosions of large gas slugs. The exponents of power laws derived for puffing and explosive infrasonic activity show strongly correlated (0.96) changes with time indicating that when the puffing rate is high, the number of energetic explosions is also elevated. This correlation suggests that both puffing and explosive activity are driven by the same magma degassing dynamics. In addition, changes of both infrasonic power law exponents are very well correlated (0.92 with puffing and 0.87 with explosions) with variations of the BSD exponents of the scoria clasts, providing evidence of the strong interplay between scoria vesiculation and magma explosivity. Our analysis indicates that variable magma vesiculation regimes recorded in the scoria correlate with the event number and energy of the explosive activity. We propose that monitoring infrasound on active volcanoes may be an alternative way to look at the vesiculation process in open conduit systems.
    Description: Published
    Description: 274-280
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Strombolian activity ; magma vesiculation ; infrasound ; conduit dynamics ; explosive volcanism ; bubble size distribution ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Comment on ‘Conduit convection, magma mixing, and melt inclusion trends at persistent degassing volcanoes’ by Fred Witham, published in Earth Planetary Science Letters (2011) 301, 345–352 (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: No abstract
    Description: Published
    Description: 306-308
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; Stromboli ; volatiles ; melt inclusions ; magma mixing ; magma degassing ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Dependence of clinopyroxene composition on cooling rate in basaltic magmas: Implications for thermobarometry (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The compositional variation of clinopyroxene and the partitioning ofmajor elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H2O=1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca,Mg, Fe2+ and Si and enriched inNa, Fe3+, Al (mainlyAlIV), and Ti. Di andHd versus CaTs and CaFeTs forma continuous binary solid solution characterized by higher amounts of tschermakitic componentswith increasing cooling rate. Two parameters (DH=Di+Hd and TE=CaTs+CaFeTs+En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions. Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of cpx–meltKdFe–Mg remain almost constant. Therefore, the Fe2–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic coolingmagmas, giving rise to possiblemismatches in the application of thermobarometers. The results of our study are consistentwith that observed at themargin of dikes or inthe exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.
    Description: Published
    Description: 302-312
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: cooling rate ; clinopyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Transient effects of magma ascent dynamics along a geometrically variable dome-feeding conduit (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The transient dynamics of magma ascent during dome-forming eruptions were investigated and the effects of magma chamber pressure perturbations on eruption rate are illustrated. The numerical model DOMEFLOW, developed by the authors for this work, is applied to the problem. DOMEFLOW is a transient 1.5D isothermal two-phase flow model of magma ascent through an axisymmetric conduit of variable radius, which accounts for gas exsolution, bubble growth, crystallization induced by degassing, permeable gas loss through overlying magma and through conduit walls, as well as viscosity changes due to crystallization and degassing. For runs in which chamber pressure increases, the time required to reach the new steady state (transition time) is a complex function of the pressure perturbation, while for decreasing chamber pressure, transition time is a monotonic function of the magnitude of the pressure perturbation. The transition to the new steady state is mainly controlled by magma compressibility, travel time (time required for one parcel of magma to travel from chamber to surface), and the time over which the pressure perturbation occurs. Results of many runs (〉 300) were analyzed using dimensional analysis to reveal a general relationship which predicts the temporal evolution of magma effusion rate for a given sudden increase in chamber pressure; the product of the change in steady-state extrusion rate and the time required to reach the new steady state is linearly proportional to the normalized change in chamber pressure, the volume of the conduit, and the ratio of top and bottom conduit radii, and inversely proportional to the cubic root of volatile fraction. This relationship is used to interpret observed variations in two ongoing dome-building eruptions, the Soufrière Hills volcano, Montserrat, and Merapi volcano, Indonesia.
    Description: Published
    Description: 541-553
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: conduit dynamics ; conduit geometry ; magma ascent ; effusion rate ; computational model ; dome-building ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Pantelleria Island, located in the Sicily Channel Rift Zone (Italy), is the type locality for the peralkaline rhyolitic rocks called pantellerites. In the last 50 ka, after the large Green Tuff caldera-forming eruption, volcanic activity at Pantelleria has consisted of effusive and explosive eruptions mostly vented inside and along the rim of the caldera and producing silicic lava flows, lava domes and poorly dispersed pantelleritic pumice fall deposits. Basaltic cinder cones and lava flows are only present outside the caldera in the NW sector of the island. The most recent basaltic (Cuddie Rosse, 20 ka) and pantelleritic (Cuddia Randazzo and Cuddia del Gallo, 6 ka) pyroclastic products were sampled to investigate magmatic volatile contents through the study of melt inclusions. The melt inclusions in pyroxene and olivine phenocrysts of Cuddie Rosse scoriae have an alkali basalt composition. The dissolved volatiles comprise 0.9–1.6 wt.% H2O, several hundred ppm of CO2, 1600–2000 ppm of sulphur and 500–900 ppm of chlorine. The water–carbon dioxide couple gives a confining pressure 2 kbar prior to the eruption. This result indicates that episodes of magma ponding and crystallization occurred in the upper crust prior to eruption. The melt inclusions in feldspar, fayalite and aenigmatite phenocrysts of Cuddia del Gallo and Cuddia Randazzo pumice have a pantelleritic composition (Agpaitic Indices 1.3–2.1), up to 4.4 wt.% H2O, 8700 ppm Cl, 6000 ppm F, and CO2 below the detection limit. Sulphur averaging 420 ppm has been measured in Cuddia Randazzo melt inclusions. These data indicate relatively high volatile contents for these low-energy Strombolian-type eruptions. Melt inclusions in Cuddia del Gallo pumice show the most evolved composition (Agpaitic Indices 2–2.1) and the highest volatile content, in agreement with fluid saturation conditions in the magma chamber prior to the eruption. This implies a confining pressure of 1 kbar for the top of the pantelleritic reservoir. The composition of melt inclusions and mineralogical assemblage of Cuddia Randazzo pumice indicate that it has a lower evolutionary degree (Agpaitic Indices 1.3–1.8) and lower pre-eruptive Cl and H2O contents than Cuddia del Gallo pumice. An increase in pressure due to the exsolution of volatiles in the upper part of the pantelleritic reservoir may have triggered the Cuddia del Gallo explosive eruption. Evidence of widespread pre-eruptive mingling between trachytes and pantellerites suggests that the intrusion of trachytic magma into the pantelleritic reservoir likely played a major role in destabilizing the magma system just prior to the Cuddia Randazzo event.
    Description: Published
    Description: 191-201
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Pantelleria ; peralkaline ; volatiles ; melt inclusions ; eruptive style ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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