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  • American Geophysical Union  (40,572)
  • 2010-2014  (32,139)
  • 1975-1979  (8,433)
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  • 1
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    Geogenic and atmospheric sources for volatile organic compounds in fumarolic emissions from Mt. Etna and Vulcano Island (Sicily, Italy) (2012)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: In this paper, fluid source(s) and processes controlling the chemical composition of VOCs (Volatile Organic Compounds) in gas discharges from Mt. Etna and Vulcano Island (Sicily, Italy) were investigated. The main composition of the Etnean and Volcano gas emissions is produced by mixing, to various degrees, of “magmatic” and “hydrothermal” components. VOCs are dominated by alkanes, alkenes and aromatics, with minor, though significant, concentrations of O-, S- and Cl(F)-substituted compounds. The main mechanism for the production of alkanes is likely related to pyrolysis of organic matter-bearing sediments that interact with the ascending magmatic fluids. Alkanes are then converted to alkene and aromatic compounds via catalytic reactions (dehydrogenation and dehydroaromatization, respectively). Nevertheless, an abiogenic origin for the light hydrocarbons cannot be ruled out. Oxidative processes of hydrocarbons at relatively high temperatures and oxidizing conditions, typical of these volcanic-hydrothermal fluids, may explain the production of alcohols, esters, aldehydes, as well as O- and S-bearing heterocycles. By comparing the concentrations of hydrochlorofluorocarbons (HCFCs) in the fumarolic discharges with respect to those of background air, it is possible to highlight that they have a geogenic origin likely due to halogenation of both methane and alkenes. Finally, CFC (chlorofluorocarbon) abundances appear to be consistent with background air, although the strong air contamination that affects the Mt. Etna fumaroles may mask a possible geogenic contribution for these compounds. On the other hand, no CFCs were detected in the Vulcano gases, which are characterized by low air contribution. Nevertheless, a geogenic source for these compounds cannot be excluded on the basis of the present data.
    Description: Published
    Description: D17305
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: etna, vulcano, VOC ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Gas seepage and seismogenic structures along the North-Anatolian Fault in the eastern Sea of Marmara (2012)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: We carried out a combined geophysical and gas-geochemical survey on an active fault strand along the North-Anatolian Fault (NAF) system in the Gulf of İzmit (eastern Sea of Marmara), providing for the first time in this area data on the distribution of methane (CH4) and other gases dissolved in the bottom seawater, as well as the CH4 isotopic composition. Based on high-resolution morphobathymetric data and chirp-sonar seismic reflection profiles we selected three areas with different tectonic features associated to the NAF system, where we performed visual and instrumental seafloor inspections, including in-situ measurements of dissolved CH4, and sampling of the bottom water. Starting from background values of 2-10 nM, methane concentration in the bottom seawater increases abruptly up to 20 nM over the main NAF trace. CH4 concentration peaks up to ~120 nM were detected above mounds related probably to gas and fluids expulsion. Methane is microbial (δ13CCH4: -67.3 and -76 ‰ vs. VPDB), and was found mainly associated with pre- Holocene deposits topped by a 10-20 m thick draping of marine mud. The correlation between tectonic structures and gas-seepages at the seafloor suggests that the NAF in the Gulf of İzmit could represent a key site for long-term combined monitoring of fluid exhalations and seismicity to assess their potential as earthquake precursors.
    Description: Published
    Description: Q10018
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: submarine ; gas seepage ; active fault ; Marmara sea ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Tephra sedimentation during the 2010 Eyjafjallajökull eruption (Iceland) from deposit, radar, and satellite observations (2012)
    American Geophysical Union
    Details
    Publication Date: 2023-01-16
    Description: The April–May 2010 eruption of the Eyjafjallajökull volcano (Iceland) was characterized by a nearly continuous injection of tephra into the atmosphere that affected various economic sectors in Iceland and caused a global interruption of air traffic. Eruptive activity during 4–8 May 2010 was characterized based on short-duration physical parameters in order to capture transient eruptive behavior of a long-lasting eruption (i.e., total grain-size distribution, erupted mass, and mass eruption rate averaged over 30 min activity). The resulting 30 min total grain-size distribution based on both ground and Meteosat Second Generation-Spinning Enhanced Visible and Infrared Imager (MSG-SEVIRI) satellite measurements is characterized by Mdphi of about 2 and a fine-ash content of about 30 wt %. The accumulation rate varied by 2 orders of magnitude with an exponential decay away from the vent, whereas Mdphi shows a linear increase until about 18 km from the vent, reaching a plateau of about 4.5 between 20 and 56 km. The associated mass eruption rate is between 0.6 and 1.2 × 105 kg s−1. In situ sampling showed how fine ash mainly fell as aggregates of various typologies. About 5 to 9 wt % of the erupted mass remained in the cloud up to 1000 km from the vent, suggesting that nearly half of the ash 〉7 settled as aggregates within the first 60 km. Particle sphericity and shape factor varied between 0.4 and 1 with no clear correlation to the size and distance from vent. Our experiments also demonstrate how satellite retrievals and Doppler radar grain-size detection can provide a real-time description of the source term but for a limited particle-size range.
    Description: Published
    Description: B12202
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: MSG-SEVIRI, PLUDIX ; particle aggregation ; settling velocity ; tephra deposits ; weak plumes ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Palaeoenvironmental conditions in the Gulf of Alaska (NE Pacific) during the Mid Pleistocene Transition (2014)
    American Geophysical Union
    In:  EPIC3AGU Fall Meeting, San Francisco, CA, USA, 2014-12-14-2014-12-19American Geophysical Union
    Details
    Publication Date: 2022-09-29
    Description: The Mid Pleistocene Transition (MPT) constitutes a fundamental shift in Earth's climate system from a 41 ka to a 100 ka periodicity in glacial oscillations. The exact timing and mechanism(s) that caused this change from a low- to high-amplitude glacial variability are still under debate and only recently Pena & Goldstein (2014) suggested that a disruption of the thermohaline circulation at about 900 ka BP and a subsequent change in ocean circulation might have acted as a trigger for the onset of 100 ka glacial-interglacial cycles. Most studies targeting the MPT are based on Atlantic sediment records whereas only few data sets are available from the North Pacific (see e.g. Clark et al., 2006 and McClymont et al., 2013 for reviews). IODP Expedition 341 distal deep-water site U1417 in the Gulf of Alaska (subpolar NE Pacific) now provided a continuous sediment record for reconstructing Miocene to Late Pleistocene changes in the sea surface conditions and how these relate to orbital and millennial scale climate variability. Here we present organic geochemical biomarker data covering the 1.5 Ma to 0.1 Ma time interval with special focus on the MPT. Alkenone, sterol, n-alkane and C25 highly branched isoprenoid data are used to reconstruct sea surface temperatures, primary productivity and terrigenous organic matter input (via sea ice, icebergs, meltwater discharge or aeolian transport). In addition, the diatom concentration and the species composition of the diatom assemblage deliver information on changes in palaeoproductivity and nutrient (silicate) availability. A major change in the environmental setting between 1.2 and 0.8 Ma is recorded by the biomarkers. This shift seems to be associated with a significant cooling of the surface waters in the Gulf of Alaska. Matching this shift, a significant change in the main components of the diatom community occurred between 1.2 and 0.8 Ma. References Clark, P.U., Archer, D., Pollard, D., Blum, J.D., Rial, J.A., Brovkin, V., Mix, A.C., Pisias, N.G., Roy, M., 2006. Quaternary Science Reviews, 25, (23–24), 3150-3184. McClymont, E.L., Sosdian, S.M., Rosell-Melé, A., Rosenthal, Y., 2013. Earth-Science Reviews, 123, 173-193. Pena, L.D. and Goldstein, S.L., 2014. Science, 345, 318-322.
    Repository Name: EPIC Alfred Wegener Institut
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  • 5
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    Climate-Ice Sheet Interactions through the Pliocene-Pleistocene: Preliminary Results from IODP Expedition 341 (Gulf of Alaska) (2014)
    American Geophysical Union
    In:  EPIC3AGU Fall Meeting, San Francisco, CA, USA, 2014-12-14-2014-12-19American Geophysical Union
    Details
    Publication Date: 2022-09-29
    Description: Since the Pliocene, global climate history is distinguished by the transition into a colder world, dominated by the onset and intensification of major Northern Hemisphere glaciations which have also changed in their duration and intensity. Potential drivers for these events include falling atmospheric CO2, progressive sub-glacial erosion, tectonic uplift, and associated feedbacks. At present, isolating climate as the driver of evolving continental ice volume since the Pliocene is hindered by the limited long term data sets which directly link climate changes to evidence for ice-sheet advance/retreat, erosion, and tectonic evolution over million year timescales. IODP Expedition 341 drilled a cross-margin transect in the Gulf of Alaska from ice-proximal sites on the continental shelf to distal sites in the deep Pacific. This study focuses on the distal site (Site U1417, c.4190 m water depth) which contains variable biogenic and terrigenous contributions, and evidence for deposition through pelagic, mass movement and glacial processes. Our aim is to investigate links between north-east Pacific paleoceanography and the history of the north-west Cordilleran ice sheet, neither of which are fully understood given limited data pre-dating the Last Glacial Maximum. We reconstruct SSTs during the mid-Pliocene, Plio-Pleistocene Transition (PPT) and mid-Pleistocene transition (MPT) using the UK37’ index. We consider the interaction between SSTs and primary production by examining the absolute and relative abundances of plankton biomarkers (e.g. for haptophytes, diatoms and dinoflagellates), carbon/nitrogen ratios, stable isotopes (δ13C, δ15N) and diatom assemblages. Links between these climatic events and the north-west Cordilleran ice-sheet advance/retreat history are initially made using shipboard stratigraphy; emerging data sets on ice-rafting from members of the Expedition 341 Scientific Party will refine these relationships.
    Repository Name: EPIC Alfred Wegener Institut
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  • 6
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    Arctic sea ice variability during the last deglaciation: a biomarker approach (2014)
    American Geophysical Union
    In:  EPIC3AGU Fall Meeting, San Francisco, CA, USA, 2014-12-14-2014-12-19American Geophysical Union
    Details
    Publication Date: 2022-09-29
    Description: The last transition from full glacial to current interglacial conditions was accompanied by distinct short-term climate fluctuations caused by changes in the global ocean circulation system. Most palaeoceanographic studies focus on the documentation of the behaviour of the Atlantic Meridional Overturning Circulation (AMOC) during the last deglaciation in response to freshwater forcing events. In this respect, the role of Arctic sea ice remained relatively unconsidered - primarily because of the difficulty of its reconstruction. Here we present new proxy data on late glacial (including the Last Glacial Maximum; LGM) and deglacial sea ice variability in the Arctic Ocean and its main gateway - the Fram Strait - and how these changes in sea ice coverage contributed to AMOC perturbations observed during Heinrich Event 1 and the Younger Dryas. Recurrent short-term advances and retreats of sea ice in Fram Strait, prior and during the LGM, are in line with a variable (or intermittent) North Atlantic heat flow along the eastern corridor of the Nordic Seas. Possibly in direct response to the initial freshwater discharge from melting continental ice-sheets, a permanent sea ice cover established only at about 19 ka BP (i.e. post-LGM) and lasted until 17.6 ka BP, when an abrupt break-up of this thick ice cover and a sudden discharge of huge amounts of sea ice and icebergs through Fram Strait coincided with the weakening of the AMOC during Heinrich Event 1. Similarly, another sea ice maximum at about 12.8 ka BP is associated with the slowdown of the AMOC during the Younger Dryas. The new data sets clearly highlight the important role of Arctic sea ice for the re-organisation of the oceanographic setting in the North Atlantic during the last deglaciation. Further studies and sensitivity experiments to identify crucial driving (and feedback) mechanisms within the High Latitude ice-ocean-atmosphere system will contribute the understanding of rapid climate changes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 7
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    Late Pleistocene biogenic sedimentation in the Gulf of Alaska: A biogeochemical perspective from IODP Expedition 341 (2014)
    American Geophysical Union
    In:  EPIC3AGU Fall Meeting, San Francisco, CA, USA, 2014-12-14-2014-12-19American Geophysical Union
    Details
    Publication Date: 2022-09-29
    Description: Reconstructing the timing and nature of past changes in aquatic productivity in the Gulf of Alaska (GoA) can shed light on the primary processes driving biogeochemical cycling over geologic timescales. Here, we present sedimentologic, physical property, stable isotope, and biogenic opal concentration data from IODP Expedition 341 Sites U1417 and U1419 and identify intervals where diatom ooze lithofacies and geochemical evidence for increased algal productivity are prevalent during the Pleistocene. Sites U1417 and U1419 are located in the center and the margin of the Fe-limited GoA, respectively, and they offer the potential to characterize past changes in biogeochemical cycling during different Pleistocene time intervals. Site U1419 cores were collected from a small slope basin at the edge of the continental shelf. Sediment cores reveal two prominent ~6-m-thick intervals of diatomaceous ooze. Between these intervals are numerous 20-cm-thick sections of biogenic-rich sediment, interbedded with gray mud that commonly contains lonestones. Based on preliminary age models, the two diatom ooze intervals likely correspond to the Holocene and MIS 3, while the intervening interbedded glacigenic and biogenic sediment can broadly be ascribed to MIS 2. Diatomaceous ooze and diatom-rich sediments are generally characterized by lower magnetic susceptibility, natural gamma ray, bulk density, and higher b* color reflectance. Initial C & N concentration and stable isotopic data show elevated concentrations and more positive stable isotope values during the Holocene and MIS 3, which approximate the isotopic signature of modern phytoplankton measured in the GoA. Within the glacial period, the biogenic-rich intervals are also characterized by more positive C and N isotopic values. When combined with the shipboard physical property data, the stable isotopic results are indicative of millennial-scale variations in productivity and/or changes in glacial ice extent in the GoA during the last glacial period. We will discuss these results in the context of an improved isotope stratigraphy and ongoing work examining multiple interglacial productivity variations at Site U1417.
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
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    Pilot projects for publishing and citing ocean data (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-06-09
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Eos 93, no. 43 (2012): 425-426.
    Description: In the ocean sciences, a project was started in 2008 to bring together scientists, data managers, and library experts to explore means to (1) increase the submission of data to data centers, (2) make data more accessible for reuse, (3) link data more closely to traditional journal publications, and (4) create a system that gives more credit to data generators. This project is a joint effort among the Scientific Committee on Oceanic Research, the International Oceanographic Data and Information Exchange (IODE) of the United Nations Educational, Scientific and Cultural Organization’s Intergovernmental Oceanographic Commission, and the Marine Biological Laboratory Woods Hole Oceanographic Institution (MBLWHOI) Library.
    Description: 2013-04-23
    Repository Name: Woods Hole Open Access Server
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  • 9
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    Glacial‐interglacial circulation changes inferred from 231Pa/230Th sedimentary record in the North Atlantic region (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 24 (2009): PA2204, doi:10.1029/2008PA001696.
    Description: Studies from the subtropical western and eastern Atlantic Ocean, using the 231Pa/230Th ratio as a kinematic proxy for deep water circulation, provided compelling evidence for a strong link between climate and the rate of meridional overturning circulation (MOC) over the last deglaciation. In this study, we present a compilation of existing and new sedimentary 231Pa/230Th records from North Atlantic cores between 1710 and 4550 m water depth. Comparing sedimentary 231Pa/230Th from different depths provides new insights into the evolution of the geometry and rate of deep water formation in the North Atlantic during the last 20,000 years. The 231Pa/230Th ratio measured in upper Holocene sediments indicates slow water renewal above ∼2500 m and rapid flushing below, consistent with our understanding of modern circulation. In contrast, during the Last Glacial Maximum (LGM), Glacial North Atlantic Intermediate Water (GNAIW) drove a rapid overturning circulation to a depth of at least ∼3000 m depth. Below ∼4000 m, water renewal was much slower than today. At the onset of Heinrich event 1, transport by the overturning circulation declined at all depths. GNAIW shoaled above 3000 m and significantly weakened but did not totally shut down. During the Bølling‐Allerød (BA) that followed, water renewal rates further decreased above 2000 m but increased below. Our results suggest for the first time that ocean circulation during that period was quite distinct from the modern circulation mode, with a comparatively higher renewal rate above 3000 m and a lower renewal rate below in a pattern similar to the LGM but less accentuated. MOC during the Younger Dryas appears very similar to BA down to 2000 m and slightly slower below.
    Description: The LSCE-WHOI cooperation has been supported by a NSF-CNRS cooperative grant NSF INT-0233483. Analytical measurements in LSCE have been supported by French Programme National d’Etude de la Dynamique du Climat, Commissariat a` l’Energie Atomique, and Centre National de la Recherche Scientifique. The participation of J.F.M. in this project was supported in part by grants from the U.S.-NSF, WHOI-OCCI, and the Gary Comer Science and Education Foundation. R.F.’s participation was supported by grants from NSERC and the Canadian Foundation for Climate and Atmospheric Science.
    Keywords: MOC
    Repository Name: Woods Hole Open Access Server
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  • 10
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    Model simulations of the Bay of Fundy Gyre : 2. Hindcasts for 2005–2007 reveal interannual variability in retentiveness (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C09005, doi:10.1029/2008JC004948.
    Description: A persistent gyre at the mouth of the Bay of Fundy results from a combination of tidal rectification and buoyancy forcing. Here we assess recent interannual variability in the strength of the gyre using data assimilative model simulations. Realistic hindcast representations of the gyre are considered during cruises in 2005, 2006, and 2007. Assimilation of shipboard and moored acoustic Doppler current profiler velocities is used to improve the skill of the simulations, as quantified by comparison with nonassimilated drifter trajectories. Our hindcasts suggest a weakening of the gyre system during May 2005. Retention of simulated passive particles in the gyre during that period was highly reduced. A recovery of the dense water pool in the deep part of the basin by June 2006 resulted in a return to particle retention characteristics similar to climatology. Retention estimates reached a maximum during May 2007 (subsurface) and June–July 2007 (near surface). Interannual variability in the strength of the gyre was primarily modulated by the stratification of the dense water pool inside the Grand Manan Basin. These changes in stratification were associated with mixing conditions the preceding fall–winter and/or advectively driven modification of water mass properties.
    Description: The preparation of this paper was supported by NSF grant OCE-0430724, NIEHS grant 1P50-ES01274201 (Woods Hole Center for Oceans and Human Health), andNOAAgrant NA06NOS4780245 (GOMTOX). Additional support was provided by NSF grant DMS-0417769.
    Keywords: Bay of Fundy ; Model simulations ; Gyre hindcast
    Repository Name: Woods Hole Open Access Server
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  • 11
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    Correction to “Using altimetry to help explain patchy changes in hydrographic carbon measurements” (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C12099, doi:10.1029/2009JC005835.
    Keywords: Modeling ; Climate ; Carbon
    Repository Name: Woods Hole Open Access Server
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  • 12
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    Seismic structure of the southern Gulf of California from Los Cabos block to the East Pacific Rise (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): B03307, doi:10.1029/2007JB005113.
    Description: Multichannel reflection and coincident wide-angle seismic data collected during the 2002 Premier Experiment, Sea of Cortez, Addressing the Development of Oblique Rifting (PESCADOR) experiment provide the most detailed seismic structure to date of the southern Gulf of California. Multichannel seismic (MCS) data were recorded with a 6-km-long streamer, 480-channel, aboard the R/V Maurice Ewing, and wide-angle data was recorded by 19 instruments spaced every ∼12 km along the transect. The MCS and wide-angle data reveal the seismic structure across the continent-ocean transition of the rifted margin. Typical continental and oceanic crust are separated by a ∼75-km-wide zone of extended continental crust dominated by block-faulted basement. Little lateral variation in crustal thicknesses and seismic velocities is observed in the oceanic crust, suggesting a constant rate of magmatic productivity since seafloor spreading began. Oceanic crustal thickness and mean crustal velocities suggest normal mantle temperature (1300°C) and passive mantle upwelling at the early stages of seafloor spreading. The crustal thickness, width of extended continental crust, and predicted temperature conditions all indicate a narrow rift mode of extension. On the basis of upper and lower crust stretching factors, an excess of lower crust was found in the extended continental crust. Total extension along transect 5W is estimated to be ∼35 km. Following crustal extension, new oceanic crust ∼6.4-km-thick was formed at a rate of ∼48 mm a−1 to accommodate plate separation.
    Description: This work was supported by the National Science Foundation MARGINS program, grant OCE-0112152.
    Keywords: Rifting ; Seismic ; Wide-angle ; Refractions
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  • 13
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    Observing system simulation experiments with ensemble Kalman filters in Nantucket Sound, Massachusetts (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C01011, doi:10.1029/2010JC006428.
    Description: Observing system simulation experiments (OSSEs) were performed for Nantucket Sound, Massachusetts, as a pilot study for the design of optimal monitoring networks in the coastal ocean. Experiments were carried out using the ensemble Kalman filter (EnKF) for data assimilation with ensemble transform Kalman filter (EnTKF) and proper orthogonal decomposition (POD) for selecting the optimal monitoring sites. The singular evolutive interpolated Kalman filter (SEIK) was compared with EnKF for the data assimilation efficiency. Running the unstructured grid Finite-Volume Community Ocean Model (FVCOM) with perturbed initial fields of currents, water temperature, and salinity show that in this shallow coastal system, the velocity and surface elevation are able to restore themselves back to the true state over an inertial time scale after perturbation without data assimilation, while the water temperature and salinity are not. This suggests that in this vertically well mixed region with strong tidal influence, monitoring should be targeted at water properties rather than velocities. By placing measurement sites at an entrance or exit or a location with the maximum signal variance (EnTKF) or at extrema of the dominant EOF spatial modes (POD), we evaluated the capability of EnTKF and POD in designing the optimal monitoring site for the forecast model system in this region. The results suggest that understanding the multiscale dynamical nature of the system is essential in designing an optimal monitoring network since “optimal” sites suggested by an assimilation method may only represent a local-scale feature that has little influence on a region-wide system. Comparing EnKF and SEIK simulations shows that SEIK can significantly improve the data assimilation efficiency by reducing the ensemble number and increasing the convergence rate.
    Description: This publication is the result of research sponsored by the MIT Sea Grant College Program under NOAA grant NA06OAR4170019; MIT SG projects 2006‐RC‐103, 2006‐R/RC‐102, 2006‐R/RC‐107, and 2008‐R/RC‐107; NERACOOS; and MWRA funds as well as U.S. GLOBEC Northwest Atlantic/Georges Bank Program NSF grants (OCE‐0234545, OCE‐0227679, OCE‐0606928, OCE‐ 0712903, OCE‐0732084, and OCE‐0726851).
    Keywords: Observing system simulation experiments ; EnKF ; FVCOM ; Data assimilation ; Nantucket Sound
    Repository Name: Woods Hole Open Access Server
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  • 14
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    Correction to “Noble gas signatures of abyssal gabbros and peridotites at an Indian Ocean core complex” (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q02010, doi:10.1029/2004GC000695.
    Keywords: Atlantis Bank ; Gabbro ; Clinopyroxene ; High temperature alteration
    Repository Name: Woods Hole Open Access Server
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  • 15
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    Lava deposition history in ODP Hole 1256D : insights from log-based volcanostratigraphy (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 11 (2010): Q05003, doi:10.1029/2009GC002933.
    Description: A log-based volcanic stratigraphy of Ocean Drilling Program Hole 1256D provides a vertical cross-section view of in situ upper crust formed at the East Pacific Rise (EPR) with unprecedented resolution. This stratigraphy model comprises ten electrofacies, principally identified from formation microscanner images. In this study, we build a lava flow stratigraphy model for the extrusive section in Hole 1256D by correlating these electrofacies with observations of flow types from the modern EPR, such as sheet flows and breccias, and pillow lavas and their distribution. The resulting flow stratigraphy model for the Hole 1256D extrusive section represents the first realization of detailed in situ EPR upper oceanic crust construction processes that have been detected only indirectly from remote geophysical data. We correlated the flow stratigraphy model with surface geology observed from the southern EPR (14°S) by Shinkai 6500 dives in order to obtain the relationship between lava flow types and ridge axis-ridge slope morphology. This dive information was also used to give a spatial-time reference frame for modeling lava deposition history in Hole 1256D. In reconstructing the lava deposition history, we interpreted that the origins of the ∼100 m thick intervals with abundant pillow lavas in Hole 1256D are within the axial slope where pillow lavas were observed during the Shinkai 6500 dives and previous EPR surveys. This correlation could constrain the lava deposition history in Hole 1256D crust. Using the lateral scale of ridge axis–ridge slope topography from the Shinkai 6500 observations and assuming the paleospreading rate was constant, 50% of the extrusive rocks in Hole 1256D crust were formed within ∼2000 m of the ridge axis, whereas nearly all of the remaining extrusive section was formed within ∼3000 m of the ridge axis. These results are consistent with the upper crustal construction model previously suggested by seismic studies.
    Description: S.U. was supported by the Center of Deep Earth Exploration (CDEX) for travel fares and by Monbusho grant-in-aid for research 18540472.
    Keywords: Ocean Drilling Program ; Hole 1256D ; Volcanostratigraphy ; East Pacific Rise ; Wireline logging
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    Depth-shifting cores incompletely recovered from the upper oceanic crust, IODP Hole 1256D (2010)
    American Geophysical Union
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q08O11, doi:10.1029/2008GC002010.
    Description: Seafloor drilling operations, especially those in crustal rocks, yield incomplete recovery of drilled sections, and depths of the recovered core pieces are assigned with some uncertainty. Here we present a new depth-shifting method that is simple and rapid, requires little subjective input, and is applicable to any core-log integration problem where sufficient comparable data have been collected in both the open hole and from the recovered core. Over the depth range for which both core and log data have been collected, an automatic algorithm selected the best new depth for each piece. The criteria for determining the best depth were as follows: (1) find new depths for as many pieces as possible, and (2) minimize the difference between core density and log density. In this study, depth-shifting is applied at Integrated Ocean Drilling Program (IODP) Hole 1256D, which is our first opportunity to study a section of intact, in situ upper ocean crust drilled down to gabbro. The new depths significantly improve the agreement between an independent data set and the logging record.
    Description: Funding for this research was provided by a JOI/USSSP Post-Expedition Award to L.A.G. Mick Spillane of the NOAA Center for Tsunami Research provided tide calculations using OSU TPXO6.2.
    Keywords: Ocean drilling ; Core-log integration ; IODP Site 1256
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    Axial high topography and partial melt in the crust and mantle beneath the western Galapagos Spreading Center (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q12005, doi:10.1029/2008GC002100.
    Description: The hot spot-influenced western Galápagos Spreading Center (GSC) has an axial topographic high that reaches heights of ∼700 m relative to seafloor depth ∼25 km from the axis. We investigate the cause of the unusual size of the axial high using a model that determines the flexural response to loads resulting from the thermal and magmatic structure of the lithosphere. The thermal structure simulated is appropriate for large amounts of cooling by hydrothermal circulation, which tends to minimize the amount of partial melt needed to explain the axial topography. Nonetheless, results reveal that the large axial high near 92°W requires that either the crust below the magma lens contains 〉35% partial melt or that 20% melt is present in the lower crust and at least 3% in the mantle within a narrow column (〈∼10 km wide) extending to depths of 45–65 km. Because melt fractions 〉35% in the crust are considered unreasonable, it is likely that much of the axial high region of the GSC is underlain by a narrow region of partially molten mantle of widths approaching those imaged seismically beneath the East Pacific Rise. A narrow zone of mantle upwelling and melting, driven largely by melt buoyancy, is a plausible explanation.
    Description: Ito was supported by grants NSF-OCE- 0327051 and NSF-OCE-0351234.
    Keywords: Axial high ; Galapagos Spreading Center ; Partial melt ; Lithospheric flexure
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    High dimethylsulfide photolysis rates in nitrate-rich Antarctic waters (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 31 (2004): L11307, doi:10.1029/2004GL019863.
    Description: The photochemistry of dimethylsulfide (DMS) was examined in the Southern Ocean to assess its impact on the biogeochemical dynamics of DMS in Antarctic waters. Very high DMS photolysis rate constants (0.16–0.23 h−1) were observed in surface waters exposed to full sunlight. DMS photolysis rates increased linearly with added nitrate concentrations, and 35% of the DMS loss in unamended samples was attributed to the photochemistry of ambient nitrate (29 μM). Experiments with optical filters showed that the UV-A band of sunlight (320–400 nm) accounted for ~65% of DMS photolysis suggesting that dissolved organic matter was the main photosensitizer for DMS photolysis. During the austral spring, DMS photolysis was the dominant loss mechanism under non-bloom and non-ice cover conditions owing to the high doses and deep penetration of UV radiation in the water column, low observed microbial consumption rates, and high in situ nitrate concentrations.
    Description: This work was supported by NSF (OPP- 0230499, DJK; OPP-0230497, RPK).
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    Globally elevated titanium, tantalum, and niobium (TITAN) in ocean island basalts with high 3He/4He (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q04027, doi:10.1029/2007GC001876.
    Description: We report evidence for a global Ti, Ta, and Nb (TITAN) enriched reservoir sampled by ocean island basalts (OIBs) with high 3He/4He ratios, an isotopic signature associated with the deep mantle. Excesses of Ti (and to a lesser degree Nb and Ta) correlate remarkably well with 3He/4He in a data set of global OIBs, demonstrating that a major element signature is associated with the high 3He/4He mantle. Additionally, we find that OIBs with high 3He/4He ratios have moderately radiogenic 187Os/188Os (〉0.135). The TITAN enrichment and radiogenic 187Os/188Os in high 3He/4He OIBs indicate that they are melts of a mantle domain that hosts a nonprimitive (nonchondritic) component. The observation of TITAN enrichment in the high 3He/4He mantle may be important in balancing the Earth's budget for the TITAN elements. Understanding the origin of the TITAN enrichment is important for constraining the evolution of the enigmatic high 3He/4He mantle domain.
    Description: Funds for helium measurements were provided by NSF-OCE to M.D.K. Funds for major and trace element analyses were provided by NSF-EAR 0509891 to S.R.H.
    Keywords: He-3/He-4 ; FOZO ; PHEM ; C ; OIB ; Eclogite
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    Correction to “Newtonian versus non-Newtonian upper mantle viscosity : implications for subduction initiation” (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L24316, doi:10.1029/2005GL025264.
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    Correction to “Recent western South Atlantic bottom water warming” (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L21604, doi:10.1029/2006GL028294.
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    Large-scale responses of complex-shaped coastlines to local shoreline stabilization and climate change (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): F03033, doi:10.1029/2009JF001486.
    Description: When modeling the large-scale (〉 km) evolution of coastline morphology, the influence of natural forces is not the only consideration; ongoing direct human manipulations can substantially drive geomorphic change. In this paper, we couple a human component to a numerical model of large-scale coastline evolution, incorporating beach “nourishment” (periodically placing sand on the beach, also called “beach replenishment” or “beach fill”). Beach nourishment is the most prevalent means humans employ to alter the natural shoreline system in our case study, the Carolina coastline. Beach nourishment can cause shorelines adjacent to those that are nourished to shift both seaward and landward. When we further consider how changes to storm behaviors could change wave climates, the magnitude of morphological change induced by beach nourishment can rival that expected from sea level rise and affect the coast as far as tens of kilometers away from the nourishment site. In some instances, nonlocal processes governing large-scale cuspate-cape coastline evolution may transmit the human morphological “signal” over surprisingly large (hundreds of kilometer) distances.
    Description: The National Science Foundation (DEB 0507987) and the Duke University Center on Global Change supported this work.
    Keywords: Coastline evolution ; Beach nourishment ; Climate change
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    Comparison of atmospheric mercury speciation and deposition at nine sites across central and eastern North America (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): D18306, doi:10.1029/2010JD014064.
    Description: This study presents 〉5 cumulative years of tropospheric mercury (Hg) speciation measurements, over the period of 2003–2009, for eight sites in the central and eastern United States and one site in coastal Puerto Rico. The purpose of this research was to identify local and regional processes that impact Hg speciation and deposition (wet + dry) across a large swath of North America. Sites sampled were selected to represent both a wide range of mercury exposure and environmental conditions. Seasonal mean concentrations of elemental Hg (1.27 ± 0.31 to 2.94 ± 1.57 ng m−3; inline equation ± σ), reactive gaseous mercury (RGM; 1.5 ± 1.6 to 63.3 ± 529 pg m−3), and fine particulate Hg (1.2 ± 1.4 to 37.9 ± 492 pg m−3) were greatest at sites impacted by Hg point sources. Diel bin plots of Hgo and RGM suggest control by a variety of local/regional processes including impacts from Hg point sources and boundary layer/free tropospheric interactions as well as from larger-scale processes affecting Hg speciation (i.e., input of the global Hg pool, RGM formed from oxidation of Hgo by photochemical compounds at coastal sites, and elemental Hg depletion during periods of dew formation). Comparison of wet Hg deposition (measured), RGM and fine particulate Hg dry deposition (calculated using a multiple resistance model), and anthropogenic point source emissions varied significantly between sites. Significant correlation between emission sources and dry deposition was observed but was highly dependant upon inclusion of data from two sites with exceptionally high deposition. Findings from this study highlight the importance of environmental setting on atmospheric Hg cycling and deposition rates.
    Description: Funding for this research was provided by the USGS Toxic Substances Hydrology Program, U.S. Department of Interior Landscapes Program, the USGS Mendenhall Postdoctoral Program, the USGS Energy Program, and by U.S. EPA STAR grant R829798.
    Keywords: Atmospheric mercury ; Wet deposition ; Dry deposition ; Diel patterns
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    Drought legacies influence the long-term carbon balance of a freshwater marsh (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): G00H02, doi:10.1029/2009JG001215.
    Description: Experimental manipulations provide a powerful tool for understanding an ecosystem's response to environmental perturbation. We combined paired eddy covariance towers with an experimental manipulation of water availability to determine the response of marsh carbon balance to drought. We monitored the Net Ecosystem Exchange of CO2 (NEE) in two ponds from 2004 to 2009 at the San Joaquin Freshwater Marsh (SJFM), and subjected one of the ponds to a yearlong drought treatment in 2007. The two ponds experienced similar flooding and environmental regimes before and after the drought, ensuring that differences between ponds were largely attributable to the 2007 drought. Drought substantially reduced surface greenness, as measured by the Enhanced Vegetation Index (EVI) and photosynthetic carbon sequestration, primarily by inhibiting leaf area development. Respiratory carbon losses were less influenced by drought than photosynthetic carbon gains. The effect of the drought lasted several years, with delayed leaf area development and peak carbon uptake rates during the subsequent year, and reduced leaf area for a couple of years. The combined effect of the drought and legacy effects created an overall loss of carbon that was equivalent to 4 years of the maximum annual carbon sequestration observed over a decade. Our results indicate that drought can have long-term impacts on ecosystem carbon balance and that future projected drought increases in Southern California will have a negative impact on marsh carbon sequestration.
    Keywords: Wetlands ; NEE ; Phenology ; Disturbance legacies ; Drought
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    Geochemistry of lavas from the 2005–2006 eruption at the East Pacific Rise, 9°46′N–9°56′N : implications for ridge crest plumbing and decadal changes in magma chamber compositions (2010)
    American Geophysical Union
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 11 (2010): Q05T09, doi:10.1029/2009GC002977.
    Description: Detailed mapping, sampling, and geochemical analyses of lava flows erupted from an ∼18 km long section of the northern East Pacific Rise (EPR) from 9°46′N to 9°56′N during 2005–2006 provide unique data pertaining to the short-term thermochemical changes in a mid-ocean ridge magmatic system. The 2005–2006 lavas are typical normal mid-oceanic ridge basalt with strongly depleted incompatible trace element patterns with marked negative Sr and Eu/Eu* anomalies and are slightly more evolved than lavas erupted in 1991–1992 at the same location on the EPR. Spatial geochemical differences show that lavas from the northern and southern limits of the 2005–2006 eruption are more evolved than those erupted in the central portion of the fissure system. Similar spatial patterns observed in 1991–1992 lavas suggest geochemical gradients are preserved over decadal time scales. Products of northern axial and off-axis fissure eruptions are consistent with the eruption of cooler, more fractionated lavas that also record a parental melt component not observed in the main suite of 2005–2006 lavas. Radiogenic isotopic ratios for 2005–2006 lavas fall within larger isotopic fields defined for young axial lavas from 9°N to 10°N EPR, including those from the 1991–1992 eruption. Geochemical data from the 2005–2006 eruption are consistent with an invariable mantle source over the spatial extent of the eruption and petrogenetic processes (e.g., fractional crystallization and magma mixing) operating within the crystal mush zone and axial magma chamber (AMC) before and during the 13 year repose period. Geochemical modeling suggests that the 2005–2006 lavas represent differentiated residual liquids from the 1991–1992 eruption that were modified by melts added from deeper within the crust and that the eruption was not initiated by the injection of hotter, more primitive basalt directly into the AMC. Rather, the eruption was driven by AMC pressurization from persistent or episodic addition of more evolved magma from the crystal mush zone into the overlying subridge AMC during the period between the two eruptions. Heat balance calculations of a hydrothermally cooled AMC support this model and show that continual addition of melt from the mush zone was required to maintain a sizable AMC over this time interval.
    Description: This work has been supported by NSF grants OCE‐0525863 and OCE‐0732366 (D. J. Fornari and S. A. Soule), OCE‐0636469 (K. H. Rubin), and OCE‐ 0138088 (M. R. Perfit), as well as postdoctoral fellowship funds from the University of Florida.
    Keywords: Mid-ocean ridge basalt ; East Pacific Rise ; Eruption ; Trace elements ; Radiogenic isotopes ; Fractional crystallization
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    Net community production and gross primary production rates in the western equatorial Pacific (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 24 (2010): GB4001, doi:10.1029/2009GB003651.
    Description: Net community production (NCP) and gross primary production (GPP) are two key metrics for quantifying the biological carbon cycle. In this study, we present a detailed characterization of NCP and GPP in the western equatorial Pacific during August and September 2006. We use continuous measurements of dissolved gases (O2 and Ar) in the surface water in order to quantify NCP at subkilometer scale resolution. We constrain GPP in discrete samples using the triple isotopic composition of O2. We find the average NCP in the western equatorial Pacific is 5.9 ± 0.9 mmol O2 m−2 d−1 (equivalent to 1.5 ± 0.2 mol C m−2 yr−1 with error estimates reflecting 1σ confidence levels) and the average GPP is 121 ± 34 mmol O2 m−2 d−1 (equivalent to 32 ± 9 mol C m−2 yr−1). The measurements reveal significant spatial variability on length scales as small as 50 km. The NCP/GPP ratio is 5.7% ± 1.8%. We also present results for NCP and GPP in the coastal area off Papua New Guinea and for GPP in the central Pacific along the equator.
    Description: This work was supported by the NSF Chemical Oceanography and the Office of Polar Programs, by the NOAA climate and global change program (fellowship to RHRS), and by Princeton University (Hess fellowship to RHRS).
    Keywords: Production ; Triple oxygen isotopes ; Equatorial pacific
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    Sediment transport and deposition on a river-dominated tidal flat : an idealized model study (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C10040, doi:10.1029/2010JC006248.
    Description: A 3-D hydrodynamic model is used to investigate how different size classes of river-derived sediment are transported, exported and trapped on an idealized, river-dominated tidal flat. The model is composed of a river channel flanked by sloping tidal flats, a configuration motivated by the intertidal region of the Skagit River mouth in Washington State, United States. It is forced by mixed tides and a pulse of freshwater and sediment with various settling velocities. In this system, the river not only influences stratification but also contributes a significant cross-shore transport. As a result, the bottom stress is strongly ebb-dominated in the channel because of the seaward advance of strong river flow as the tidal flats drain during ebbs. Sediment deposition patterns and mass budgets are sensitive to settling velocity. The lateral sediment spreading scales with an advective distance (settling time multiplied by lateral flow speed), thereby confining the fast settling sediment classes in the channel. Residual sediment transport is landward on the flats, because of settling lag, but is strongly seaward in the channel. The seaward transport mainly occurs during big ebbs and is controlled by a length scale ratio Ld/XWL, where Ld is a cross-shore advective distance (settling time multiplied by river outlet velocity), and XWL is the immersed cross-shore length of the intertidal zone. Sediment trapping requires Ld/XWL 〈 1, leading to more trapping for the faster settling classes. Sensitivity studies show that including stratification and reducing tidal range both favor sediment trapping, whereas varying channel geometries and asymmetry of tides has relatively small impacts. Implications of the modeling results on the south Skagit intertidal region are discussed.
    Description: SNC is supported by a WHOI/USGS postdoctoral scholarship. The field program on the Skagit intertidal region is supported by an ONR grant N00014-08-1-0790.
    Keywords: Sediment trapping ; Tidal flat
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    A box model test of the freshwater forcing hypothesis of abrupt climate change and the physics governing ocean stability (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 25 (2010): PA4222, doi:10.1029/2010PA001936.
    Description: Observations and an ocean box model are combined in order to test the adequacy of the freshwater forcing hypothesis to explain abrupt climate change given the uncertainties in the parameterization of vertical buoyancy transport in the ocean. The combination is carried out using Bayesian stochastic inversion, which allows us to infer changes in the mass balance of Northern Hemisphere (NH) ice sheets and in the meridional transports of mass and heat in the Atlantic Ocean that would be required to explain Dansgaard-Oeschger Interstadials (DOIs) from 30 to 39 kyr B.P. The mean sea level changes implied by changes in NH ice sheet mass balance agree in amplitude and timing with reconstructions from the geologic record, which gives some support to the freshwater forcing hypothesis. The inversion suggests that the duration of the DOIs should be directly related to the growth of land ice. Our results are unaffected by uncertainties in the representation of vertical buoyancy transport in the ocean. However, the solutions are sensitive to assumptions about physical processes at polar latitudes.
    Description: This material is based upon work supported by the National Science Foundation under grant OCE‐0402363 and Department of Energy grant DE‐FG02‐08ER64619.
    Keywords: Inversion ; MOC ; Abrupt ; Sea level ; Coral ; Mixing
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    Lower crustal variability and the crust/mantle transition at the Atlantis Massif oceanic core complex (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 37 (2010): L2430, doi:10.1029/2010GL045165.
    Description: Seismic refraction data provide new constraints on the structure of the lower oceanic crust and its variability across the Atlantis Massif oceanic core complex, ∼30°N on the Mid-Atlantic Ridge. A 40 km-long spreading-parallel profile constrains P-wave velocities to depths of up to ∼7 km beneath the seafloor. Two shorter spreading-perpendicular lines provide coverage to ∼2 km depth. The anomalous character of the massif's central dome crust is clear compared to the neighboring rift valley and similar-age crust on the opposite ridge flank. The domal core of the massif, unroofed via detachment faulting, has velocities 〉7.0 km/s at depths below ∼2.5 km sub-seafloor, increasing to 7.5–7.8 km/s over the depth range 4.8–6.8 km. Within the core complex, the Moho does not appear to be sharp as no PmP arrivals are observed. Within the axial valley, velocities do not reach mantle-transition zone values in the uppermost 6 km. We infer that crust there is of normal thickness but that a thinner than average mafic section is present in the central massif. Near IODP Hole U1309D, located on the central dome, there is a low velocity gradient interval at 1–3 km depth with velocities of 6.6–6.8 km/s, that coincides with a 3–5 km wide region where shallower velocities are highest. Given the predominantly gabbroic section recovered from the 1.4 km deep drillhole, this seismic structure suggests that the mafic body extends a few km both laterally and vertically.
    Description: NSF grants provided support for the data acquisition, initial interpretation (Collins OCE‐9633114 and OCE‐ 9819297) and subsequent processing and analysis (Blackman OCE‐ 0927442).
    Keywords: Atlantis Massif ; Marine refraction ; Oceanic crust ; Mid-Atlantic Ridge
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    A nonhydrostatic version of FVCOM : 2. Mechanistic study of tidally generated nonlinear internal waves in Massachusetts Bay (2011)
    American Geophysical Union
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C12049, doi:10.1029/2010JC006331.
    Description: The generation, propagation, and dissipation processes of large-amplitude nonlinear internal waves in Massachusetts Bay during the stratified season were examined using the nonhydrostatic Finite-Volume Coastal Ocean Model (FVCOM-NH). The model reproduced well the characteristics of the high-frequency internal waves observed in Massachusetts Bay in August 1998. The model experiments suggested that internal waves over Stellwagen Bank are generated by the interaction of tidal currents with steep bottom topography through a process of forming a large-density front on the western slope of the bank by the release of an initial density perturbation near ebb-flood transition, nonlinear steepening of the density front into a deep density depression, and disintegrating of the density depression into a wave train. Earth's rotation tends to transfer the cross-bank tidal kinetic energy into the along-bank direction and thus reduces the intensity of the density perturbation at ebb-flood transition and density depression in the flood period. The internal wave packet propagates as a leading edge feature of the internal tidal wave, and the faster propagation speed of the high-frequency internal waves in Massachusetts Bay is caused by Earth's rotation. The model experiments suggested that bottom friction can significantly influence the cross-bank scale of the density perturbation and thus the density depression during wave generation and the dissipation during the wave's shoaling. Inclusion of vertical mixing using the Mellor-Yamada level 2.5 turbulence closure model had only a marginal effect on wave evolution. The model results support the internal wave theory proposed by Lee and Beardsley (1974) but are in disagreement with the lee-wave mechanism proposed by Maxworthy (1979).
    Description: This research was supported by NOAA g r a n t s DOC/NOAA/NA04NMF4720332 and DOC/NOAA/ NA05NMF4721131, U.S. GLOBEC Northwest Atlantic/Georges Bank Program NSF grants (OCE‐0606928, OCE‐0712903, OCE‐0732084, OCE‐0726851, OCE0814505), and MIT Sea Grant funds (2006‐RC‐103 and 2010‐R/RC‐116), NOAA NERACOOS Program for the UMASSD team and the Smith Chair in Coastal Oceanography, and NOAA grant (NA‐17RJ1223) for R.C. Beardsley. C. Chen’s contribution is also supported by Shanghai Ocean University under grants A‐2302‐10‐0003 and 09320503700 and the State Key Laboratory for Estuarine and Coastal Research, East China Normal University.
    Keywords: Nonhydrostatic dynamics ; Internal waves ; Stellwagen Bank ; Massachusetts Bay
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    Evidence from the Florida Straits for Younger Dryas ocean circulation changes (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 26 (2011): PA1205, doi:10.1029/2010PA002032.
    Description: The waters passing through the Florida Straits today reflect both the western portion of the wind-driven subtropical gyre and the northward flow of the upper waters which cross the equator, compensating North Atlantic Deep Water export as part of the large-scale Atlantic meridional overturning circulation. It has been postulated from various lines of evidence that the overturning circulation was weaker during the Younger Dryas cold event of the last deglaciation. We show here that the contrast in the oxygen isotopic composition of benthic foraminiferal tests across the Florida Current is reduced during the Younger Dryas. This most likely reflects a decrease in the density gradient across the channel and a decrease in the vertical shear of the Florida Current. This reduced shear is consistent with the postulated reduction in the Atlantic meridional overturning circulation. We find that the onset of this change in density structure and flow at the start of the Younger Dryas is very abrupt, occurring in less than 70 years.
    Description: We thank the National Science Foundation (grants OCE‐0648258 and OCE‐0096472) and the Comer Science and Education Foundation for supporting this research. MWS was supported by a NOAA Global Change Postdoctoral Fellowship.
    Keywords: Florida Straits ; Younger Dryas ; Florida Current
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  • 32
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    In situ δ7Li, Li/Ca, and Mg/Ca analyses of synthetic aragonites (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 12 (2011): Q03001, doi:10.1029/2010GC003322.
    Description: In situ secondary ion mass spectrometry (SIMS) analyses of δ7Li, Li/Ca, and Mg/Ca were performed on five synthetic aragonite samples precipitated from seawater at 25°C at different rates. The compositions of δ7Li in bulk aragonites and experimental fluids were measured by multicollector inductively coupled plasma–mass spectrometry (MC-ICP-MS). Both techniques yielded similar δ7Li in aragonite when SIMS analyses were corrected to calcium carbonate reference materials. Fractionation factors α7Li/6Li range from 0.9895 to 0.9923, which translates to a fractionation between aragonite and fluid from −10.5‰ to −7.7‰. The within-sample δ7Li range determined by SIMS is up to 27‰, exceeding the difference between bulk δ7Li analyses of different aragonite precipitates. Moreover, the centers of aragonite hemispherical bundles (spherulites) are enriched in Li/Ca and Mg/Ca relative to spherulite fibers by up to factors of 2 and 8, respectively. The Li/Ca and Mg/Ca ratios of spherulite fibers increase with aragonite precipitation rate. These results suggest that precipitation rate is a potentially important consideration when using Li isotopes and elemental ratios in natural carbonates as a proxy for seawater composition and temperature.
    Description: SIMS analyses were supported by U.S. NSF, EAR, Instrumentation and Facilities Program. The development of the method for bulk d7Li analysis and the MC‐ICP‐MS measurements were covered by NSF grant EAR/IF‐0318137. Precipitation experiments were supported by NSF through grants OCE‐0402728, OCE‐0527350, and OCE‐0823527 to Glenn Gaetani and Anne Cohen and through grant EAR‐0337481 to Bruce Watson.
    Keywords: Isotope ; Aragonite ; Rate ; SIMS ; Magnesium ; Lithium
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  • 33
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    Deep South China Sea circulation (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L05601, doi:10.1029/2010GL046626.
    Description: The analysis of an updated monthly climatology of observed temperature and salinity from the U.S. Navy Generalized Digital Environment Model reveals a basin-scale cyclonic circulation over the deep South China Sea (SCS). The cyclonic circulation lies from about 2400 m to the bottom. The boundary current transport of the cyclonic circulation is around 3.0 Sv. Our results suggest that the cyclonic circulation is mainly forced by the Luzon overflow, with bottom topography playing an important role. The structures of potential temperature, salinity, and potential density in the deep SCS are consistent with the existence of the cyclonic circulation. Specifically, low salinity water is found in the interior region west of Luzon Island, and surrounded by saline Pacific water in boundary current regions to the north, west and southwest. Our results show the potential density distribution and the corresponding cyclonic circulation in deep SCS are primarily controlled by salinity variations in the deep basin.
    Description: G. Wang was supported by the National Basic Research Program (2007CB816003) and the National Natural Science Foundation of China (40976017, 40730843); S.‐P. Xie by the US National Foundation (NSF), the Changjiang Scholar and Qianren Programs; T. Qu by NSF (OCE10‐29704).
    Keywords: Deep South China Sea circulation ; Boundary current
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    Lithospheric structures and Precambrian terrane boundaries in northeastern Botswana revealed through magnetotelluric profiling as part of the Southern African Magnetotelluric Experiment (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): B02401, doi:10.1029/2010JB007740.
    Description: Within the framework of the Southern African Magnetotelluric Experiment a focused study was undertaken to gain improved knowledge of the lithospheric geometries and structures of the westerly extension of the Zimbabwe craton (ZIM) into Botswana, with the overarching aim of increasing our understanding of southern African tectonics. The area of interest is located in northeastern Botswana, where Kalahari sands cover most of the geological terranes and very little is known about lithospheric structures and thicknesses. Some of the regional-scale terrane boundary locations, defined based on potential field data, are not sufficiently accurate for local-scale studies. Investigation of the NNW-SSE orientated, 600 km long ZIM line profile crossing the Zimbabwe craton, Magondi mobile belt, and Ghanzi-Chobe belt showed that the Zimbabwe craton is characterized by thick (∼220 km) resistive lithosphere, consistent with geochemical and geothermal estimates from kimberlite samples of the nearby Orapa and Letlhakane pipes (∼175 km west of the profile). The lithospheric mantle of the Ghanzi-Chobe belt is resistive, but its lithosphere is only about 180 km thick. At crustal depths a northward dipping boundary between the Ghanzi-Chobe and the Magondi belts is identified, and two middle to lower crustal conductors are discovered in the Magondi belt. The crustal terrane boundary between the Magondi and Ghanzi-Chobe belts is found to be located further to the north, and the southwestern boundary of the Zimbabwe craton might be further to the west, than previously inferred from the regional potential field data.
    Description: In addition to the funding and logistical support provided by SAMTEX consortium members (Council for Geoscience, Geological Surveys Botswana and Namibia, De Beers Group Services, Rio Tinto Exploration, and BHP Billiton), this work was also supported by research grants from National Science Foundation’s Continental Dynamics program (USA, EAR‐0309584 and EAR‐0455242), the Department of Science and Technology (South Africa), and Science Foundation Ireland (Ireland, grant 05/RFP/GEO001).
    Keywords: Magnetotellurics ; Zimbabwe craton ; Lithospheric structures ; Southern Africa
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    Glacial flour dust storms in the Gulf of Alaska : hydrologic and meteorological controls and their importance as a source of bioavailable iron (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L06602, doi:10.1029/2010GL046573.
    Description: Iron is an essential micronutrient that limits primary productivity in much of the ocean, including the Gulf of Alaska (GoA). However, the processes that transport iron to the ocean surface are poorly quantified. We combine satellite and meteorological data to provide the first description of widespread dust transport from coastal Alaska into the GoA. Dust is frequently transported from glacially-derived sediment at the mouths of several rivers, the most prominent of which is the Copper River. These dust events occur most frequently in autumn, when coastal river levels are low and riverbed sediments are exposed. The dust plumes are transported several hundred kilometers beyond the continental shelf into iron-limited waters. We estimate the mass of dust transported from the Copper River valley during one 2006 dust event to be between 25–80 ktons. Based on conservative estimates, this equates to a soluble iron loading of 30–200 tons. We suggest the soluble Fe flux from dust originating in glaciofluvial sediment deposits from the entire GoA coastline is two to three times larger, and is comparable to the annual Fe flux to GoA surface waters from eddies of coastal origin. Given that glaciers are retreating in the coastal GoA region and in other locations, it is important to examine whether fluxes of dust are increasing from glacierized landscapes to the ocean, and to assess the impact of associated Fe on marine ecosystems.
    Description: We appreciate support from the USGS CMGP, NCCWSC, the Mendenhall postdoc program, the Woods Hole PEP intern program, and from NASA‐IDS.
    Keywords: Dust ; Glacier ; Iron ; Aerosol ; Climate change ; Micronutrient
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    Application of an inverse method to interpret 231Pa/230Th observations from marine sediments (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 26 (2011): PA1212, doi:10.1029/2010PA002022.
    Description: Records of 231Pa/230Th from Atlantic sediments have been interpreted to reflect changes in ocean circulation during the geologic past. Such interpretations should be tested with due regard to the limited spatial coverage of 231Pa/230Th data and the uncertainties in our current understanding of the behavior of both nuclides in the ocean. Here an inverse method is used to evaluate the information contained in 231Pa/230Th compilations for the Holocene, Last Glacial Maximum (LGM), and Heinrich Event 1 (H1). An estimate of the abyssal circulation in the modern Atlantic Ocean is obtained by combining hydrographic observations and dynamical constraints. Then sediment 231Pa/230Th data for each time interval are combined with an advection-scavenging model in order to determine their (in)consistency with the modern circulation estimate. We find that the majority of sediment 231Pa/230Th data for the Holocene, LGM, or H1 can be brought into consistency with the modern circulation if plausible assumptions are made about the large-scale distribution of 231Pa and about model uncertainties. Moreover, the adjustments in the data needed to reach compatibility with a hypothetical state of no flow (no advection) are positively biased for each time interval, suggesting that the 231Pa/230Th data (including that for H1) are more consistent with a persistence of some circulation than with no circulation. Our study does not imply that earlier claims of a circulation change during the LGM or H1 are inaccurate, but that these claims cannot be given a rigorous basis given the current uncertainties involved in the analysis of the 231Pa/230Th data.
    Description: O.M. acknowledges the support from the U.S. National Science Foundation. J.F.M. acknowledges support from the U.S. National Science Foundation and the Comer Research and Education Foundation.
    Keywords: Pa-231/Th-230 ; Meridional overturning circulation ; Inverse method ; Heinrich Event
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    How is the ocean filled? (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L06604, doi:10.1029/2011GL046769.
    Description: The ocean surface rapidly exchanges heat, freshwater, and gases with the atmosphere, but once water sinks into the ocean interior, the inherited properties of seawater are closely conserved. Previous water-mass decompositions have described the oceanic interior as being filled by just a few different property combinations, or water masses. Here we apply a new inversion technique to climatological tracer distributions to find the pathways by which the ocean is filled from over 10,000 surface regions, based on the discretization of the ocean surface at 2° by 2° resolution. The volume of water originating from each surface location is quantified in a global framework, and can be summarized by the estimate that 15% of the surface area fills 85% of the ocean interior volume. Ranked from largest to smallest, the volume contributions scaled by surface area follow a power-law distribution with an exponent of −1.09 ± 0.03 that appears indicative of the advective-diffusive filling characteristics of the ocean circulation, as demonstrated using a simple model. This work quantifies the connection between the surface and interior ocean, allowing insight into ocean composition, atmosphere-ocean interaction, and the transient response of the ocean to a changing climate.
    Description: GG and PH were funded by NSF award 0645936. GG was also supported by the J. Lamar Worzel Assistant Scientist Fund and the Penzance Endowed Fund in Support of Assistant Scientists. PH was also supported by NSF award OCE‐0960787.
    Keywords: Water masses ; Deep-water formation ; Physical oceanography ; Ocean pathways ; Inverse methods ; Steady-state circulation
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  • 38
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    Nonlinear internal waves over New Jersey's continental shelf (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C03022, doi:10.1029/2010JC006332.
    Description: Ship and mooring data collected off the coast of New Jersey are used to describe the nonlinear internal wave (NLIW) field and the background oceanographic conditions that formed the waveguide on the shelf. The subinertial, inertial, and tidal circulation are described in detail, and the background fluid state is characterized using the coefficients of the extended Korteweg–de Vries equation. The utility of this type of analysis is demonstrated in description of an amplitude-limited, flat wave. NLIWs observed over most of the month had typical displacements of −8 m, but waves observed from 17–21 August were almost twice as large with displacements near −15 m. During most of the month, wave packets occurred irregularly at a fixed location, and often more than one packet was observed per M2 tidal period. In contrast, the arrival times of the large-amplitude wave groups observed over 17–21 August were more closely phased with the barotropic tide. The time span in which the largest NLIWs were observed corresponded to neap barotropic conditions, but when the shoreward baroclinic energy flux was elevated. During the time of large NLIWs, near-inertial waves were a dominate contributor to the internal motions on the shelf and apparently regulated wave formation, as destructive/constructive modulation of the M2 internal tide by the inertial wavefield at the shelf break corresponded to stronger/weaker NLIWs on the shelf.
    Description: This work was funded by the Office of Naval Research.
    Keywords: Nonlinear internal waves ; Shelf processes ; Internal tide
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    Response and impact of equatorial ocean dynamics and tropical instability waves in the tropical Atlantic under global warming : a regional coupled downscaling study (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): C03026, doi:10.1029/2010JC006670.
    Description: A regional coupled model is used for a dynamic downscaling over the tropical Atlantic based on a global warming simulation carried out with the Geophysical Fluid Dynamics Laboratory CM2.1. The regional coupled model features a realistic representation of equatorial ocean dynamical processes such as the tropical instability waves (TIWs) that are not adequately simulated in many global coupled climate models. The coupled downscaling hence provides a unique opportunity to assess their response and impact in a changing climate. Under global warming, both global and regional models exhibit an increased (decreased) rainfall in the tropical northeast (South) Atlantic. Given this asymmetric change in mean state, the regional model produces the intensified near-surface cross-equatorial southerly wind and zonal currents. The equatorial cold tongue exhibits a reduced surface warming due to the enhanced upwelling. It is mainly associated with the increased vertical velocities driven by cross-equatorial wind, in contrast to the equatorial Pacific, where thermal stratification is suggested to be more important under global warming. The strengthened upwelling and zonal currents in turn amplify the dynamic instability of the equatorial ocean, thereby intensifying TIWs. The increased eddy heat flux significantly warms the equator and counters the effect of enhanced upwelling. Zonal eddy heat flux makes the largest contribution, suggesting a need for sustained monitoring of TIWs with spatially denser observational arrays in the equatorial oceans. Overall, results suggest that eddy heat flux is an important factor that may impact the mean state warming of equatorial oceans, as it does in the current climate.
    Description: H.S. acknowledges the support from the NOAA Climate and Global Change Postdoctoral Fellowship Program and the Penzance Endowed Fund in Support of Assistant Scientists at WHOI. H.S. and S.‐P.X. are thankful for support from NOAA, NSF, and the Japan Agency for Marine‐Earth Science and Technology.
    Keywords: Climate change ; Ocean mesoscale eddy ; Equatorial Atlantic
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    The Wrangel Island Polynya in early summer : trends and relationships to other polynyas and the Beaufort Sea High (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L05503, doi:10.1029/2011GL050691.
    Description: Polynyas, regions of reduced sea ice concentration relative to their surroundings, are important features of the polar climate system in which enhanced fluxes of heat, moisture, and momentum can occur between the atmosphere and ocean. As such, they play a significant role in many atmospheric, oceanographic and biological processes. There are concerns that in a warming climate, in which there is a trend towards a reduction in sea ice cover, that the location, size and duration of many polynyas may change resulting in climatological and ecological impacts. In this paper, we identify an early summer manifestation of the Wrangel Island polynya that forms in the western Chuckchi Sea. We show that over the past 30 years there has been an increased frequency of occurrence as well as a doubling in the size of the polynya. The polynya is shown to form when there is an enhanced easterly flow over the Chukchi Sea that is associated with an anomalously intense Beaufort Sea High (BSH), a closed anti-cyclonic atmospheric circulation that forms over the Beaufort Sea. We also show that there has been a concomitant trend towards a more intense BSH over the same time period and we propose that this trend is responsible for the observed changes in the Wrangel Island polynya. Given its large and increasing size, the early summer polynya may also play an important and unaccounted role in the physical and biological oceanography of the western Chukchi Sea.
    Description: GWKM was supported by the Natural Science and Engineering Research Council of Canada. RSP was supported by the NOAA project NA08-OAR4320895.
    Description: 2012-09-15
    Keywords: Chukchi Sea ; Polynya
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  • 41
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    Evaluation of Arctic sea ice thickness simulated by Arctic Ocean Model Intercomparison Project models (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): C00D13, doi:10.1029/2011JC007257.
    Description: Six Arctic Ocean Model Intercomparison Project model simulations are compared with estimates of sea ice thickness derived from pan-Arctic satellite freeboard measurements (2004–2008); airborne electromagnetic measurements (2001–2009); ice draft data from moored instruments in Fram Strait, the Greenland Sea, and the Beaufort Sea (1992–2008) and from submarines (1975–2000); and drill hole data from the Arctic basin, Laptev, and East Siberian marginal seas (1982–1986) and coastal stations (1998–2009). Despite an assessment of six models that differ in numerical methods, resolution, domain, forcing, and boundary conditions, the models generally overestimate the thickness of measured ice thinner than ∼2 m and underestimate the thickness of ice measured thicker than about ∼2 m. In the regions of flat immobile landfast ice (shallow Siberian Seas with depths less than 25–30 m), the models generally overestimate both the total observed sea ice thickness and rates of September and October ice growth from observations by more than 4 times and more than one standard deviation, respectively. The models do not reproduce conditions of fast ice formation and growth. Instead, the modeled fast ice is replaced with pack ice which drifts, generating ridges of increasing ice thickness, in addition to thermodynamic ice growth. Considering all observational data sets, the better correlations and smaller differences from observations are from the Estimating the Circulation and Climate of the Ocean, Phase II and Pan-Arctic Ice Ocean Modeling and Assimilation System models.
    Description: This research is supported by the National Science Foundation Office of Polar Programs covering awards of AOMIP collaborative research projects: ARC-0804180 (M.J.), ARC-0804010 (A.P.), ARC-0805141 (W.M.), ARC080789, and ARC0908769 (J.Z.). This research is also supported by the Russian Foundation of Basic Research, projects 09-05-00266 and 09-05-01231. At the National Oceanography Centre Southampton, this study was funded by the UK Natural Environment Research Council as a contribution to the Marine Centres’ Strategic Research Programme Oceans 2025.
    Description: 2012-09-15
    Keywords: AOMIP ; ICESat ; Ice thickness ; Sea ice
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  • 42
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    Isotopic signals (18O, 2H, 3H) of six major rivers draining the pan-Arctic watershed (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 26 (2012): GB1027, doi:10.1029/2011GB004159.
    Description: We present the results of a 4-year collaborative sampling effort that measured δ18O, δ2H values and 3H activities in the six largest Arctic rivers (the Ob, Yenisey, Lena, Kolyma, Yukon and Mackenzie). Using consistent sampling and data processing protocols, these isotopic measurements provide the best available δ2H and 3H estimates for freshwater fluxes from the pan-Arctic watershed to the Arctic Ocean and adjacent seas, which complements previous efforts with δ18O and other tracers. Flow-weighted annual δ2H values vary from −113.3‰ to −171.4‰ among rivers. Annual 3H fluxes vary from 0.68 g to 4.12 g among basins. The integration of conventional hydrological and landscape observations with stable water isotope signals, and estimation of areal yield of 3H provide useful insights for understanding water sources, mixing and evaporation losses in these river basins. For example, an inverse correlation between the slope of the δ18O-δ2H relation and wetland extent indicates that wetlands play comparatively important roles affecting evaporation losses in the Yukon and Mackenzie basins. Tritium areal yields (ranging from 0.760 to 1.695 10−6 g/km2 per year) are found to be positively correlated with permafrost coverage within the studied drainage basins. Isotope-discharge relationships demonstrate both linear and nonlinear response patterns, which highlights the complexity of hydrological processes in large Arctic river basins. These isotope observations and their relationship to discharge and landscape features indicate that basin-specific characteristics significantly influence hydrological processes in the pan-Arctic watershed.
    Description: Funding for this research was provided by the U.S. National Science Foundation (OPP-0229302), the National Science and Engineering Research Council of Canada (Discovery grant to JJG and IRD fellowship to YY), the U.S. Geological Survey and the Water Resources Division in the Department of Indian Affairs and Northern Development, Canada.
    Description: 2012-09-22
    Keywords: Arctic rivers ; Discharge anormaly ; Flow-weighted flux ; Stable water isotopes ; Tritium
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  • 43
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    Northern Bering Sea tip jets (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L08807, doi:10.1029/2012GL051537.
    Description: Low-level regions of high wind speed known as tip jets have been identified near Cape Farewell, Greenland's southernmost point. These wind systems contribute to this area being the windiest location on the ocean's surface and play an important role in the regional weather and climate. Here we present the first analysis of the wind systems that make the Siberian coast of the northern Bering Sea the windiest location in the North Pacific Ocean during the boreal winter. In particular we show that tips jets characterized by enhanced northeasterly winds occur in the vicinity of the two prominent headlands along the coast, Cape Navarin and Cape Olyutorsky. The advance of sea ice in the region is shown to impact the frequency and location of the high speed winds in the vicinity of these two capes. Furthermore, we show that these jets are associated with the interaction of extra-tropical cyclones with the high topography of the Koryak Mountain range, situated just inland of the capes. The windstress imparted to the ocean via the tip jets is argued to help drive the formation of dense water in winter in the northern Bering Sea, thus playing an important role in the regional oceanic circulation.
    Description: GWKM was supported by the Natural Science and Engineering Research Council of Canada. RSP was funded by grant NA08OAR43200895 from the National Oceanic and Atmospheric Administration.
    Description: 2012-10-28
    Keywords: Air-sea interaction ; Tip jets ; Topographic flow distortion
    Repository Name: Woods Hole Open Access Server
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    Electromagnetic constraints on a melt region beneath the central Mariana back-arc spreading ridge (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 13 (2012): Q10017, doi:10.1029/2012GC004326.
    Description: An electrical resistivity profile across the central Mariana subduction system shows high resistivity in the upper mantle beneath the back-arc spreading ridge where melt might be expected to exist. Although seismic data are equivocal on the extent of a possible melt region, the question arises as to why a 2-D magnetotelluric (MT) survey apparently failed to image any melt. We have run forward models and inversions that test possible 3-D melt geometries that are consistent with the MT data and results of other studies from the region, and that we use to place upper bounds on the possible extent of 3-D melt region beneath the spreading center. Our study suggests that the largest melt region that was not directly imaged by the 2-D MT data, but that is compatible with the observations as well as the likely effects of melt focusing, has a 3-D shape on a ridge-segment scale focused toward the spreading center and a resistivity of 100 Ω-m that corresponds to ∼0.1–∼1% interconnected silicate melt embedded in a background resistivity of ∼500 Ω-m. In contrast to the superfast spreading southern East Pacific Rise, the 3-D melt region suggests that buoyant mantle upwelling on a ridge-segment scale is the dominant process beneath the slow-spreading central Mariana back-arc. A final test considers whether the inability to image a 3-D melt region was a result of the 2-D survey geometry. The result reveals that the 2-D transect completed is useful to elucidate a broad range of 3-D melt bodies.
    Description: TM and NS are supported by the scientific program of “TAIGA” (Trans-crustal Advection and In situ reaction of Global sub-seafloor Aquifer)” sponsored by the MEXT of Japan, and are also supported by the JSPS for Grant-In-Aid for Scientific Research (21244070). Participation in the Marianas experiment by RLE and ADC was supported by NSF grant OCE0405641.
    Description: 2013-04-25
    Keywords: Back-arc spreading ridge ; Central Mariana Trough ; Electrical resistivity structure ; Upper mantle melting
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    “Equator Crossing” of Shatsky Rise?: New insights on Shatsky Rise tectonic motion from the downhole magnetic architecture of the uppermost lava sequences at Tamu Massif (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L21301, doi:10.1029/2012GL052967.
    Description: Shatsky Rise is a Large Igneous Province (LIP) currently located in the northwestern Pacific. New downhole magnetic logging data from Integrated Ocean Drilling Program (IODP) Hole U1347A at Tamu Massif of Shatsky Rise captured the magnetic architecture in the uppermost lava sequence, providing a rare opportunity to investigate a time series of the intra-plate volcanism in conjunction with the Pacific plate construction history centered at the triple junction. Logging data results indicate that Tamu Massif was formed during normal polarity periods south of the paleoequator and crossed the equator at some point in the M19–M17 period. Combining these new observations with previous interpretations of the massif's tectonic history, a time series of the latitudinal tectonic motion of a LIP and the underlying Pacific plate during the plateau formation is postulated.
    Description: This project was supported by the IODP-US Science Support Program (Consortium for Ocean Leadership) Expedition 324 Post Expedition Award.
    Description: 2013-05-03
    Keywords: Integrated Ocean Drilling Program ; Downhole logging ; Large igneous province ; Magnetic architecture
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    The character of seafloor ambient noise recorded offshore New Zealand : results from the MOANA ocean bottom seismic experiment (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 13 (2012): Q10011, doi:10.1029/2012GC004201.
    Description: We analyze the characteristics of ambient noise recorded on ocean-bottom seismographs using data from the 2009–2010 MOANA (Marine Observations of Anisotropy Near Aotearoa) seismic experiment deployed west and east of South Island, New Zealand. Microseism and infragravity noise peaks are clear on data recorded on the vertical channel of the seismometer and on the pressure sensor. The noise levels in the infragravity band (〈0.03 Hz) on the horizontal seismometer channels are too high to show the infragravity peak. There is a small difference (~0.25 Hz versus ~0.2 Hz) in microseism peak frequencies between the two sides of the South Island on all three seismic channels. Our results show clear depth dependence between the peak frequency of infragravity waves and the water depth. We find that the product of water depth and wave number at the peak frequency is a constant, koH = 1.5. This relationship can be used to determine the variation of phase and group velocity of infragravity waves with water depth, and the location of the infragravity peak and corresponding noise notch at any water depth. These estimates of spectral characteristics, particularly low noise bands, are useful for future OBS deployments.
    Description: The collection of OBS data was supported by the National Science Foundation Continental Dynamics program under grants EAR-0409564, EAR-0409609, and EAR-0409835.
    Description: 2013-04-16
    Keywords: New Zealand ; OBS ; Continental shelf ; Infragravity wave ; Noise
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    Opal (Zn/Si) ratios as a nearshore geochemical proxy in coastal Antarctica (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 23 (2008): PA2218, doi:10.1029/2007PA001576.
    Description: During the last 50 years, the Antarctic Peninsula has experienced rapid warming with associated retreat of 87% of marine and tidewater glacier fronts. Accelerated glacial retreat and iceberg calving may have a significant impact on the freshwater and nutrient supply to the phytoplankton communities of the highly productive coastal regions. However, commonly used biogenic carbonate proxies for nutrient and salinity conditions are not preserved in sediments from coastal Antarctica. Here we describe a method for the measurement of zinc to silicon ratios in diatom opal, (Zn/Si)opal, which is a potential archive in Antarctic marine sediments. A core top calibration from the West Antarctic Peninsula shows (Zn/Si)opal is a proxy for mixed layer salinity. We present down-core (Zn/Si)opal paleosalinity records from two rapidly accumulating sites taken from nearshore environments off the West Antarctic Peninsula which show an increase in meltwater input in recent decades. Our records show that the recent melting in this region is unprecedented for over 120 years.
    Description: The work was funded as part of NERC Antarctic Funding Initiative AFI4– 02. K.R.H. is funded by NERC grant NER/S/A/2004/12390.
    Keywords: Opal ; Zinc ; Salinity
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    Impacts of temporal CO2 and climate trends on the detection of ocean anthropogenic CO2 accumulation (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 25 (2011): GB3023, doi:10.1029/2010GB004009.
    Description: A common approach for estimating the oceanic uptake of anthropogenic carbon dioxide (Canthro) depends on the linear approximation of oceanic dissolved inorganic carbon (DIC) from a suite of physical and biological ocean parameters. The extended multiple linear regression (eMLR) method assumes that baseline correlations and the resulting residual fields will remain constant with time even under the influence of secular climate changes. The validity of these assumptions over the 21st century is tested using a coupled carbon-climate model. Findings demonstrate that the influence of both changing climate and changing chemistry beyond 2–4 decades invalidates the assumption that the residual fields will remain constant resulting in significant errors in the eMLR estimate of Canthro. This study determines that the eMLR method is unable to describe Canthro uptake for a sampling interval of greater than 30 years if the error is to remain below 20% for many regions in the Southern Ocean, Atlantic Ocean, and western Pacific Ocean. These results suggest that, for many regions of the ocean basins, hydrographic field investigations have to be repeated at approximately decadal timescales in order to accurately predict the uptake of Canthro by the ocean if the eMLR method is used.
    Description: This work was supported by NOAA grant NA07OAR4310098 (SCD and RW) and funding from the University of Hong Kong (NFG).
    Keywords: Anthropogenic carbon detection ; Global ocean model ; Impact of global change ; Ocean carbon sink
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    Spatial distribution of air-sea heat fluxes over the sub-polar North Atlantic Ocean (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L18806, doi:10.1029/2012GL053097.
    Description: On a variety of spatial and temporal scales, the energy transferred by air-sea heat and moisture fluxes plays an important role in both atmospheric and oceanic circulations. This is particularly true in the sub-polar North Atlantic Ocean, where these fluxes drive water-mass transformations that are an integral component of the Atlantic Meridional Overturning Circulation (AMOC). Here we use the ECMWF Interim Reanalysis to provide a high-resolution view of the spatial structure of the air-sea turbulent heat fluxes over the sub-polar North Atlantic Ocean. As has been previously recognized, the Labrador and Greenland Seas are areas where these fluxes are large during the winter months. Our particular focus is on the Iceland Sea region where, despite the fact that water-mass transformation occurs, the winter-time air-sea heat fluxes are smaller than anywhere else in the sub-polar domain. We attribute this minimum to a saddle point in the sea-level pressure field, that results in a reduction in mean surface wind speed, as well as colder sea surface temperatures associated with the regional ocean circulation. The magnitude of the heat fluxes in this region are modulated by the relative strength of the Icelandic and Lofoten Lows, and this leads to periods of ocean cooling and even ocean warming when, intriguingly, the sensible and latent heat fluxes are of opposite sign. This suggests that the air-sea forcing in this area has large-scale impacts for climate, and that even modest shifts in the atmospheric circulation could potentially impact the AMOC.
    Description: GWKM was supported by the Natural Science and Engineering Research Council of Canada. IAR was funded in part by NCAS (the National Centre for Atmospheric Sciences) and by NERC grant NE/I005293/1. RSP was funded by grant OCE-0959381 fromthe US National Science Foundation.
    Description: 2013-03-27
    Keywords: Air-sea interaction ; Climate variability ; Water mass transformation
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    Chalk-Ex—fate of CaCO3 particles in the mixed layer : evolution of patch optical properties (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C07020, doi:10.1029/2008JC004902.
    Description: The fate of particles in the mixed layer is of great relevance to the global carbon cycle as well as to the propagation of light in the sea. We conducted four manipulative field experiments called “Chalk-Ex” in which known quantities of uniform, calcium carbonate particles were injected into the surface mixed layer. Since the production term for these patches was known to high precision, the experimental design allowed us to focus on terms associated with particle loss. The mass of chalk in the patches was evaluated using the well-calibrated light-scattering properties of the chalk plus measurements from a variety of optical measurements and platforms. Patches were surveyed with a temporal resolution of hours over spatial scales of tens of kilometers. Our results demonstrated exponential loss of the chalk particles with time from the patches. There was little evidence for rapid sinking of the chalk. Instead, horizontal eddy diffusion appeared to be the major factor affecting the dispersion of the chalk to concentrations below the limits of detection. There was unequivocal evidence of subduction of the chalk along isopycnals and subsequent formation of thin layers. Shear dispersion is the most likely mechanism to explain these results. Calculations of horizontal eddy diffusivity were consistent with other mixed layer patch experiments. Our results provide insight into the importance of physics in the formation of subsurface particle maxima in the sea, as well as the importance of rapid coccolith production and critical patch size for maintenance of natural coccolithophore blooms in nature.
    Description: We would like to thank the Office of Naval Research/Optical and Biological Oceanography Program for their support of Chalk-Ex with awards N000140110042 (WMB) and N00014-01-1-0141 (AJP). Additional funding for this work came from ONR (N00014-05-1- 0111) and NASA (NNG04Gl11G, NNX08AC27G, NNG04HZ25C) to W.M.B.
    Keywords: Calcium carbonate ; PIC ; Chalk ; Coccoliths ; Coccolithophores ; Eddy diffusion
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    Correction to “Evidence for asymmetric nonvolcanic rifting and slow incipient oceanic accretion from seismic reflection data on the Newfoundland margin” (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): B12403, doi:10.1029/2006JB004769.
    Keywords: Nonvolcanic margin ; Seismic reflection ; Continental extension
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    A secondary ionization mass spectrometry calibration of Cibicidoides pachyderma Mg/Ca with temperature (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q04009, doi:10.1029/2007GC001620.
    Description: An evaluation of C. pachyderma Mg/Ca using a new suite of warm water multicores from the Florida Straits shows that the slope of Mg/Ca with temperature is shallower than previously thought. Using secondary ionization mass spectrometry, we have documented that the distribution of magnesium within the polished walls of foraminiferal tests is Gaussian, suggesting that the Mg/Ca in these samples is not affected by the addition of a secondary high-magnesium calcite in the walls. The Mg/Ca within a typical C. pachyderma test varies by about ±20% (1σ/μ · 100), and the variability increases slightly in tests with higher Mg/Ca. The regression of C. pachyderma Mg/Ca with temperature has a slope of 0.13 ± 0.05 mmol mol−1 per °C, indistinguishable from the slope observed in inductively coupled plasma–mass spectrometry measurements from a different subset of the same multicores, but about one half the slope of previously published calibrations. The largest differences between the calibrations comes at the warm water end of the regression, where previously published C. pachyderma Mg/Ca values from Little Bahama Bank are at least 3 mmol mol−1 higher than observed in these new cores. The reasons for this difference are not fully known but are most likely related to diagenesis at Little Bahama Bank.
    Description: This research was supported by several grants from the National Science Foundation: OCE0096469 to W.B.C. for cruise support to collect the Florida Straits cores; ATM0502428 and OCE0550271 to W. B. C. for support to obtain the Mg/Ca data on the ion probe; and OCE0425522 and OCE0550150 to T. M. for the core top calibration study using ICP-MS.
    Keywords: Magnesium ; Benthic foraminifera ; Temperature ; Ion probe
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  • 53
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    MORB generation beneath the ultraslow spreading Southwest Indian Ridge (9–25°E) : major element chemistry and the importance of process versus source (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q05004, doi:10.1029/2008GC001959.
    Description: We report highly variable mid-ocean ridge basalt (MORB) major element and water concentrations from a single 1050-km first-order spreading segment on the ultraslow spreading Southwest Indian Ridge, consisting of two supersegments with strikingly different spreading geometry and ridge morphology. To the east, the 630 km long orthogonal supersegment (〈10° obliquity) dominantly erupts normal MORB with progressive K/Ti enrichment from east to west. To the west is the 400 km long oblique supersegment (up to 56° obliquity) with two robust volcanic centers erupting enriched MORB and three intervening amagmatic accretionary segments erupting both N-MORB and E-MORB. The systematic nature of the orthogonal supersegments' ridge morphology and MORB composition ends at 16°E, where ridge physiography, lithologic abundance, crustal structure, and basalt chemistry all change dramatically. We attribute this discontinuity and the contrasting characteristics of the supersegments to localized differences in the upper mantle thermal structure brought on by variable spreading geometry. The influence of these differences on the erupted composition of MORB appears to be more significant at ultraslow spreading rates where the overall degree of melting is lower. In contrast to the moderate and rather constant degrees of partial melting along the orthogonal supersegment, suppression of mantle melting on the oblique supersegment due to thickened lithosphere means that the bulk source is not uniformly sampled, as is the former. On the oblique supersegment, more abundant mafic lithologies melt deeper thereby dominating the more enriched aggregate melt composition. While much of the local major element heterogeneity can be explained by polybaric fractional crystallization with variable H2O contents, elevated K2O and K/Ti cannot. On the basis of the chemical and tectonic relationship of these enriched and depleted basalts, their occurrence requires a multilithology mantle source. The diversity and distribution of MORB compositions, especially here at ultraslow spreading rates, is controlled not only by the heterogeneity of the underlying mantle, but also more directly by the local thermal structure of the lithosphere (i.e., spreading geometry) and its influence on melting processes. Thus at ultraslow spreading rates, process rather than source may be the principle determiner of MORB composition.
    Description: This work was originally funded in large part by NSF grants OCE-9907630 and OCE-0526905 and more recently by OPP-0425785.
    Keywords: MORB ; Ultraslow spreading ; Lithospheric thickness ; Melt focusing
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    Th-234 deficit and excess in the Southern Ocean during spring 2001 : particle export and remineralization (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 31 (2004): L12301, doi:10.1029/2004GL019744.
    Description: 234Th deficit and excess were examined in the upper 500 m of the Southern Ocean from Sub-Antarctic to Seasonal Ice Zones (Australian sector) during austral spring 2001. 234Th fluxes at 100 m indicate that particle export was low in the North (46.9–51.0°S), minimal in the Polar and Inter-Polar Frontal Zones and high in the South (≥61°S). These results are in tight agreement with new production estimates from the same cruise. Our data indicate that Polar and Inter-Polar Frontal Zones were not zones of intense export in the Australian sector at this time of year, in contrast with other sectors of the Southern Ocean. Also, we highlight the usefulness of 234Th excess below the mixed layer as a tool to study mesopelagic remineralization.
    Description: K.O. Buesseler was supported by WHOI Ocean Life Institute Fellowship and US National Science Foundation.
    Keywords: Th-234
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    Rapid change in freshwater content of the Arctic Ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 36 (2009): L10602, doi:10.1029/2009GL037525.
    Description: The dramatic reduction in minimum Arctic sea ice extent in recent years has been accompanied by surprising changes in the thermohaline structure of the Arctic Ocean, with potentially important impact on convection in the North Atlantic and the meridional overturning circulation of the world ocean. Extensive aerial hydrographic surveys carried out in March–April, 2008, indicate major shifts in the amount and distribution of fresh-water content (FWC) when compared with winter climatological values, including substantial freshening on the Pacific side of the Lomonosov Ridge. Measurements in the Canada and Makarov Basins suggest that total FWC there has increased by as much as 8,500 cubic kilometers in the area surveyed, effecting significant changes in the sea-surface dynamic topography, with an increase of about 75% in steric level difference from the Canada to Eurasian Basins, and a major shift in both surface geostrophic currents and freshwater transport in the Beaufort Gyre.
    Description: Support for this work was provided by the National Science Foundation Office of Polar Programs under grants 0352687, 0634097 (MGM); 0633979, 0806115 (AP); 0633885, 0352754, 0634226 (MAS, JHM); and 06341222 (MBA).
    Keywords: Freshwater content ; Arctic change
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    Bottom pressure signals at the TAG deep-sea hydrothermal field : evidence for short-period, flow-induced ground deformation (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 36 (2009): L19301, doi:10.1029/2009GL040006.
    Description: Bottom pressure measurements acquired from the TAG hydrothermal field on the Mid-Atlantic Ridge (26°N) contain clusters of narrowband spectral peaks centered at periods from 22 to 53.2 minutes. The strongest signal at 53.2 min corresponds to 13 mm of water depth variation. Smaller, but statistically significant, signals were also observed at periods of 22, 26.5, 33.4, and 37.7 min (1–4 mm amplitude). These kinds of signals have not previously been observed in the ocean, and they appear to represent vertical motion of the seafloor in response to hydrothermal flow - similar in many ways to periodic terrestrial geysers. We demonstrate that displacements of 13 mm can be produced by relatively small flow-induced pressures (several kPa) if the source region is less than ∼100 m below the seafloor. We suggest that the periodic nature of the signals results from a non-linear relationship between fluid pore pressure and crustal permeability.
    Keywords: Ground ; Displacement ; Hydrothermal
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    Global N removal by freshwater aquatic systems using a spatially distributed, within-basin approach (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 22 (2008): GB2026, doi:10.1029/2007GB002963.
    Description: We explored the role of aquatic systems in the global N cycle using a spatially distributed, within-basin, aquatic nitrogen (N) removal model, implemented within the Framework for Aquatic Modeling in the Earth System (FrAMES-N). The model predicts mean annual total N (TN) removal by small rivers (with drainage areas from 2.6–1000 km2), large rivers, lakes, and reservoirs, using a 30′ latitude × longitude river network to route and process material from continental source areas to the coastal zone. Mean annual aquatic TN removal (for the mid-1990s time period) is determined by the distributions of aquatic TN inputs, mean annual hydrological characteristics, and biological activity. Model-predicted TN concentrations at basin mouths corresponded well with observations (median relative error = −12%, interquartile range of relative error = 85%), an improvement over assumptions of uniform aquatic removal across basins. Removal by aquatic systems globally accounted for 14% of total N inputs to continental surfaces, but represented 53% of inputs to aquatic systems. Integrated aquatic removal was similar in small rivers (16.5% of inputs), large rivers (13.6%), and lakes (15.2%), while large reservoirs were less important (5.2%). Bias related to runoff suggests improvements are needed in nonpoint N input estimates and/or aquatic biological activity. The within-basin approach represented by FrAMES-N will improve understanding of the freshwater nutrient flux response to anthropogenic change at global scales.
    Description: This work was funded by NASA-IDS (NNXO7AF28G, NNG04GH75G), NSF-LTER OCE-9726921, and NOAA (NA17RJ2612 – 344 to Princeton University).
    Keywords: Nitrogen ; River network ; Global
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    Impact of oceanic circulation on biological carbon storage in the ocean and atmospheric pCO2 (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 22 (2008): GB3007, doi:10.1029/2007GB002958.
    Description: We use both theory and ocean biogeochemistry models to examine the role of the soft-tissue biological pump in controlling atmospheric CO2. We demonstrate that atmospheric CO2 can be simply related to the amount of inorganic carbon stored in the ocean by the soft-tissue pump, which we term (OCS soft ). OCS soft is linearly related to the inventory of remineralized nutrient, which in turn is just the total nutrient inventory minus the preformed nutrient inventory. In a system where total nutrient is conserved, atmospheric CO2 can thus be simply related to the global inventory of preformed nutrient. Previous model simulations have explored how changes in the surface concentration of nutrients in deepwater formation regions change the global preformed nutrient inventory. We show that changes in physical forcing such as winds, vertical mixing, and lateral mixing can shift the balance of deepwater formation between the North Atlantic (where preformed nutrients are low) and the Southern Ocean (where they are high). Such changes in physical forcing can thus drive large changes in atmospheric CO2, even with minimal changes in surface nutrient concentration. If Southern Ocean deepwater formation strengthens, the preformed nutrient inventory and thus atmospheric CO2 increase. An important consequence of these new insights is that the relationship between surface nutrient concentrations, biological export production, and atmospheric CO2 is more complex than previously predicted. Contrary to conventional wisdom, we show that OCS soft can increase and atmospheric CO2 decrease, while surface nutrients show minimal change and export production decreases.
    Description: While at MIT, I.M. was supported by the NOAA Postdoctoral Program in Climate and Global Change, administered by the University Corporation for Atmospheric Research.
    Keywords: Atmospheric carbon ; Preformed nutrients ; Remineralized nutrients
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    Oceanic sources, sinks, and transport of atmospheric CO2 (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 23 (2009): GB1005, doi:10.1029/2008GB003349.
    Description: We synthesize estimates of the contemporary net air-sea CO2 flux on the basis of an inversion of interior ocean carbon observations using a suite of 10 ocean general circulation models (Mikaloff Fletcher et al., 2006, 2007) and compare them to estimates based on a new climatology of the air-sea difference of the partial pressure of CO2 (pCO2) (Takahashi et al., 2008). These two independent flux estimates reveal a consistent description of the regional distribution of annual mean sources and sinks of atmospheric CO2 for the decade of the 1990s and the early 2000s with differences at the regional level of generally less than 0.1 Pg C a−1. This distribution is characterized by outgassing in the tropics, uptake in midlatitudes, and comparatively small fluxes in thehigh latitudes. Both estimates point toward a small (∼ −0.3 Pg C a−1) contemporary CO2 sink in the Southern Ocean (south of 44°S), a result of the near cancellation between a substantial outgassing of natural CO2 and a strong uptake of anthropogenic CO2. A notable exception in the generally good agreement between the two estimates exists within the Southern Ocean: the ocean inversion suggests a relatively uniform uptake, while the pCO2-based estimate suggests strong uptake in the region between 58°S and 44°S, and a source in the region south of 58°S. Globally and for a nominal period between 1995 and 2000, the contemporary net air-sea flux of CO2 is estimated to be −1.7 ± 0.4 Pg C a−1 (inversion) and −1.4 ± 0.7 Pg C a−1 (pCO2-climatology), respectively, consisting of an outgassing flux of river-derived carbon of ∼+0.5 Pg C a−1, and an uptake flux of anthropogenic carbon of −2.2 ± 0.3 Pg C a−1 (inversion) and −1.9 ± 0.7 Pg C a−1 (pCO2-climatology). The two flux estimates also imply a consistent description of the contemporary meridional transport of carbon with southward ocean transport throughout most of the Atlantic basin, and strong equatorward convergence in the Indo-Pacific basins. Both transport estimates suggest a small hemispheric asymmetry with a southward transport of between −0.2 and −0.3 Pg C a−1 across the equator. While the convergence of these two independent estimates is encouraging and suggests that it is now possible to provide relatively tight constraints for the net air-sea CO2 fluxes at the regional basis, both studies are limited by their lack of consideration of long-term changes in the ocean carbon cycle, such as the recent possible stalling in the expected growth of the Southern Ocean carbon sink.
    Description: Core financial support for this study came from the National Aeronautics and Space Administration under grant NAG5-12528 to NG and SMF, with additional support by the U.S. National Science Foundation. M. Gloor was supported by the EBI nd EEE institutes at the University of Leeds. M. Gerber, SM, FJ, and AM thank the European Commission for support through CarboOcean (511176-2) and the NOCES project (EVK2-CT-2001- 00134). TT has been supported by NOAA grant NAO30AR4320179P27.
    Keywords: Air-sea carbon flux ; Carbon flux ; Anthropogenic CO2
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    Physical mechanisms for the offshore detachment of the Changjiang Diluted Water in the East China Sea (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C02002, doi:10.1029/2006JC003994.
    Description: Physical mechanisms for the summertime offshore detachment of the Changjiang Diluted Water (CDW) into the East China Sea are examined using the high-resolution, unstructured-grid, Finite-Volume Coastal Ocean Model (FVCOM). The model results suggest that isolated low salinity water lens detected west of Cheju Island can be formed by (1) a large-scale adjustment of the flow field to the Changjiang discharge and (2) the detachment of anticyclonic eddies as a result of baroclinic instability of the CDW front. Adding the Changjiang discharge intensifies the clockwise vorticity of the subsurface current (originating from the Taiwan Warm Current) flowing along the 50-m isobath and thus drives the low-salinity water in the northern coastal area of the Changjiang mouth offshore over a submerged plateau that extends toward Cheju Island. Given a model horizontal resolution of less than 1.0 km, the CDW front becomes baroclinically unstable and forms a chain of anticyclonic and cyclonic eddies. The offshore detachment of anticyclonic eddies can carry the CDW offshore. This process is enhanced under northward winds as a result of the spatially nonuniform interaction of wind-induced Ekman flow and eddy-generated frontal density currents. Characteristics of the model-predicted eddy field are consistent with previous theoretical studies of baroclinic instability of buoyancy-driven coastal density currents and existing satellite imagery. The plume stability is controlled by the horizontal Ekman number. In the Changjiang, this number is much smaller than the criterion suggested by a theoretical analysis.
    Description: The development of FVCOM is supported by the Massachusetts Fisheries Institute through NOAA grants DOC/ NOAA/NA04NMF4720332 and DOC/NOAA/NA05NMF4721131 and also the U.S. GLOBEC Northwest Atlantic/Georges Bank program through NSF grants OCE-0234545 and OCE-0227679, NOAA grant NA160P2323 and ONR subcontract grant from Woods Hole Oceanographic Institution. P. Ding is supported by the Chinese National Key Basic Research Project grant 2002CB412403. X. Mao is supported by the National Natural Science Foundation of China (NSFC) grant 40576079.
    Keywords: Unstructured grid model ; Eddies ; River plume baroclinic instability
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    Application and comparison of Kalman filters for coastal ocean problems : an experiment with FVCOM (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C05011, doi:10.1029/2007JC004548.
    Description: Twin experiments were made to compare the reduced rank Kalman filter (RRKF), ensemble Kalman filter (EnKF), and ensemble square-root Kalman filter (EnSKF) for coastal ocean problems in three idealized regimes: a flat bottom circular shelf driven by tidal forcing at the open boundary; an linear slope continental shelf with river discharge; and a rectangular estuary with tidal flushing intertidal zones and freshwater discharge. The hydrodynamics model used in this study is the unstructured grid Finite-Volume Coastal Ocean Model (FVCOM). Comparison results show that the success of the data assimilation method depends on sampling location, assimilation methods (univariate or multivariate covariance approaches), and the nature of the dynamical system. In general, for these applications, EnKF and EnSKF work better than RRKF, especially for time-dependent cases with large perturbations. In EnKF and EnSKF, multivariate covariance approaches should be used in assimilation to avoid the appearance of unrealistic numerical oscillations. Because the coastal ocean features multiscale dynamics in time and space, a case-by-case approach should be used to determine the most effective and most reliable data assimilation method for different dynamical systems.
    Description: P. Malanotte-Rizzoli and J. Wei were supported by the Office of Naval Research (ONR grant N00014-06-1- 0290); C. Chen and Q. Xu were supported by the U.S. GLOBEC/Georges Bank program (through NSF grants OCE-0234545, OCE-0227679, OCE- 0606928, OCE-0712903, OCE-0726851, and OCE-0814505 and NOAA grant NA-16OP2323), the NSF Arctic research grants ARC0712903, ARC0732084, and ARC0804029, and URI Sea Grant R/P-061; P. Xue was supported through the MIT Sea Grant 2006-RC-103; Z. Lai, J. Qi, and G. Cowles were supported through the Massachusetts Marine Fisheries Institute (NOAA grants NA04NMF4720332 and NA05NMF4721131); and R. Beardsley was supported through U.S. GLOBEC/Georges Bank NSF grant OCE-02227679, MIT Sea Grant NA06OAR1700019, and the WHOI Smith Chair in Coastal Oceanography.
    Keywords: Kalman filters ; Data assimilation ; Ocean modeling
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    Somali Current rings in the eastern Gulf of Aden (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C09039, doi:10.1029/2005JC003338.
    Description: New satellite-based observations reveal that westward translating anticyclonic rings are generated as a portion of the Somali Current accelerates northward through the Socotra Passage near the mouth of the Gulf of Aden. Rings thus formed exhibit azimuthal geostrophic velocities exceeding 50 cm/s, are comparable in overall diameter to the width of the Gulf of Aden (250 km), and translate westward into the gulf at 5–8 cm/s. Ring generation is most notable in satellite ocean color imagery in November immediately following the transition between southwest (boreal summer) and northeast (winter) monsoon regimes. The observed rings contain anomalous fluid within their core which reflects their origin in the equator-crossing Somali Current system. Estimates of Socotra Passage flow variability derived from satellite altimetry provide evidence for a similar ring generation process in May following the winter-to-summer monsoon transition. Cyclonic recirculation eddies are observed to spin up on the eastern flank of newly formed rings with the resulting vortex pair translating westward together. Recent shipboard and Lagrangian observations indicate that vortices of both sign have substantial vertical extent and may dominate the lateral circulation at all depths in the eastern Gulf of Aden.
    Description: This investigation is a component of the Red Sea Outflow Experiment (REDSOX) sponsored by the U.S. National Science Foundation through grants OCE 98-18464 and OCE 04-24647 to the Woods Hole Oceanographic Institution and OCE 98-19506 and OCE 03-51116 to the University of Miami.
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    Influence of rain on air-sea gas exchange : lessons from a model ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C08S18, doi:10.1029/2003JC001806.
    Description: Rain has been shown to significantly enhance the rate of air-water gas exchange in fresh water environments, and the mechanism behind this enhancement has been studied in laboratory experiments. In the ocean, the effects of rain are complicated by the potential influence of density stratification at the water surface. Since it is difficult to perform controlled rain-induced gas exchange experiments in the open ocean, an SF6 evasion experiment was conducted in the artificial ocean at Biosphere 2. The measurements show a rapid depletion of SF6 in the surface layer due to rain enhancement of air-sea gas exchange, and the gas transfer velocity was similar to that predicted from the relationship established from freshwater laboratory experiments. However, because vertical mixing is reduced by stratification, the overall gas flux is lower than that found during freshwater experiments. Physical measurements of various properties of the ocean during the rain events further elucidate the mechanisms behind the observed response. The findings suggest that short, intense rain events accelerate gas exchange in oceanic environments.
    Description: Funding was provided by a generous grant from the David and Lucile Packard Foundation.
    Keywords: Gas exchange ; Rain ; SF6 ; Turbulence ; Stratification
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    Scalar flux profile relationships over the open ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C08S09, doi:10.1029/2003JC001960.
    Description: The most commonly used flux-profile relationships are based on Monin-Obukhov (MO) similarity theory. These flux-profile relationships are required in indirect methods such as the bulk aerodynamic, profile, and inertial dissipation methods to estimate the fluxes over the ocean. These relationships are almost exclusively derived from previous field experiments conducted over land. However, the use of overland measurements to infer surface fluxes over the ocean remains questionable, particularly close to the ocean surface where wave-induced forcing can affect the flow. This study investigates the flux profile relationships over the open ocean using measurements made during the 2000 Fluxes, Air-Sea Interaction, and Remote Sensing (FAIRS) and 2001 GasEx experiments. These experiments provide direct measurement of the atmospheric fluxes along with profiles of water vapor and temperature. The specific humidity data are used to determine parameterizations of the dimensionless gradients using functional forms of two commonly used relationships. The best fit to the Businger-Dyer relationship [ Businger, 1988 ] is found using an empirical constant of a q = 13.4 ± 1.7. The best fit to a formulation that has the correct form in the limit of local free convection [e.g., Wyngaard, 1973 ] is found using a q = 29.8 ± 4.6. These values are in good agreement with the consensus values from previous overland experiments and the Coupled Ocean-Atmosphere Response Experiment (COARE) 3.0 bulk algorithm [ Fairall et al., 2003 ]; e.g., the COARE algorithm uses empirical constants of 15 and 34.2 for the Businger-Dyer and convective forms, respectively. Although the flux measurements were made at a single elevation and local similarity scaling is applied, the good agreement implies that MO similarity is valid within the marine atmospheric surface layer above the wave boundary layer.
    Description: The FAIRS work was supported by the Office of Naval Research grant N00014-00-1-0403 while the GasEx work was supported by the National Science Foundation grant OCE-9986724.
    Keywords: Air-sea fluxes ; Flux profile relationships ; Marine boundary layer
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    Assessment of skill and portability in regional marine biogeochemical models : role of multiple planktonic groups (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): C08001, doi:10.1029/2006JC003852.
    Description: Application of biogeochemical models to the study of marine ecosystems is pervasive, yet objective quantification of these models' performance is rare. Here, 12 lower trophic level models of varying complexity are objectively assessed in two distinct regions (equatorial Pacific and Arabian Sea). Each model was run within an identical one-dimensional physical framework. A consistent variational adjoint implementation assimilating chlorophyll-a, nitrate, export, and primary productivity was applied and the same metrics were used to assess model skill. Experiments were performed in which data were assimilated from each site individually and from both sites simultaneously. A cross-validation experiment was also conducted whereby data were assimilated from one site and the resulting optimal parameters were used to generate a simulation for the second site. When a single pelagic regime is considered, the simplest models fit the data as well as those with multiple phytoplankton functional groups. However, those with multiple phytoplankton functional groups produced lower misfits when the models are required to simulate both regimes using identical parameter values. The cross-validation experiments revealed that as long as only a few key biogeochemical parameters were optimized, the models with greater phytoplankton complexity were generally more portable. Furthermore, models with multiple zooplankton compartments did not necessarily outperform models with single zooplankton compartments, even when zooplankton biomass data are assimilated. Finally, even when different models produced similar least squares model-data misfits, they often did so via very different element flow pathways, highlighting the need for more comprehensive data sets that uniquely constrain these pathways.
    Description: This research was supported by the U.S. National Science Foundation through the JGOFS Synthesis and Modeling Project (OCE-0097285) and the National Aeronautics and Space Agency (NAG5-11259 and NNG05GO04G), as well as numerous other grants to the various investigators who participated.
    Keywords: Ecosystem model comparison ; Biogeochemical data assimilation ; Phytoplankton functional groups
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    Biogeochemical iron budgets of the Southern Ocean south of Australia : decoupling of iron and nutrient cycles in the subantarctic zone by the summertime supply (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 23 (2009): GB4034, doi:10.1029/2009GB003500.
    Description: Climate change is projected to significantly alter the delivery (stratification, boundary currents, aridification of landmasses, glacial melt) of iron to the Southern Ocean. We report the most comprehensive suite of biogeochemical iron budgets to date for three contrasting sites in subantarctic and polar frontal waters south of Australia. Distinct regional environments were responsible for differences in the mode and strength of iron supply mechanisms, with higher iron stocks and fluxes observed in surface northern subantarctic waters, where atmospheric iron fluxes were greater. Subsurface waters southeast of Tasmania were also enriched with particulate iron, manganese and aluminum, indicative of a strong advective source from shelf sediments. Subantarctic phytoplankton blooms are thus driven by both seasonal iron supply from southward advection of subtropical waters and by wind-blown dust deposition, resulting in a strong decoupling of iron and nutrient cycles. We discuss the broader global significance our iron budgets for other ocean regions sensitive to climate-driven changes in iron supply.
    Description: T.W. was supported by a BDI grant from CNRS and Région PACA, by CNRS PICS project 3604, and by the “Soutien à la mer” CSOA CNRS-INSU. P.W.B. was supported by the New Zealand FRST Coasts and Oceans OBI. This research was supported by the Australian Government Cooperative Research Centres Programme through the Antarctic Climate and Ecosystems CRC (ACE CRC) and Australian Antarctic Science project 2720.
    Keywords: Iron ; Southern Ocean ; Biogeochemical budget ; Subantarctic ; Polar ; Australian sector
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    Importance of carbon-nitrogen interactions and ozone on ecosystem hydrology during the 21st century (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): G01020, doi:10.1029/2008JG000826.
    Description: There is evidence that increasing CO2 concentrations have reduced evapotranspiration and increased runoff through reductions in stomatal conductance during the twentieth century. While this process will continue to counteract increased evapotranspiration associated with future warming, it is highly dependent upon concurrent changes in photosynthesis, especially due to CO2 fertilization, nitrogen limitation, and ozone exposure. A new version of the Terrestrial Ecosystem Model (TEM-Hydro) was developed to examine the effects of carbon and nitrogen on the water cycle. We used two climate models (NCAR CCSM3 and DOE PCM) and two emissions scenarios (SRES B1 and A2) to examine the effects of climate, elevated CO2, nitrogen limitation, and ozone exposure on the hydrological cycle in the eastern United States. While the direction of future runoff changes is largely dependent upon predicted precipitation changes, the effects of elevated CO2 on ecosystem function (stomatal closure and CO2 fertilization) increase runoff by 3–7%, as compared to the effects of climate alone. Consideration of nitrogen limitation and ozone damage on photosynthesis increases runoff by a further 6–11%. Failure to consider the effects of the interactions among nitrogen, ozone, and elevated CO2 may lead to significant regional underestimates of future runoff.
    Description: This study was funded by the Interdisciplinary Science Program of the U.S. National Aeronautics and Space Administration (NNG04GJ80G, NNG04GM39G), the Dynamic Global Economic Modeling of Greenhouse Gas Emissions and Mitigation from Land-Use Activities of the U.S. Environmental Protection Agency (XA-83240101), and the Nonlinear Response to Global Change in Linked Aquatic and Terrestrial Ecosystems of the U.S. EPA (XA-83326101).
    Keywords: Ecohydrology
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    Freshwater content variability in the Arctic Ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C03051, doi:10.1029/2003JC001940.
    Description: Arctic Ocean model simulations have revealed that the Arctic Ocean has a basin-wide oscillation with cyclonic and anticyclonic circulation anomalies (Arctic Ocean Oscillation (AOO)) that has a prominent decadal variability [Proshutinsky and Johnson, 1997]. This study explores how the simulated AOO affects the Arctic Ocean stratification and its relationship to the sea ice cover variations. The simulation uses the Princeton Ocean Model coupled to sea ice [Häkkinen and Mellor, 1992; Häkkinen, 1999]. The surface forcing is based on National Centers for Environmental Prediction/National Center for Atmospheric Research Reanalysis and its climatology, of which the latter is used to force the model spin-up phase. Our focus is to investigate the competition between ocean dynamics and ice formation/melt on the Arctic basin-wide freshwater balance. We find that changes in the Atlantic water inflow can explain almost all of the simulated freshwater anomalies in the main Arctic basin. The Atlantic water inflow anomalies are an essential part of AOO, which is the wind driven barotropic response to the Arctic Oscillation (AO). The baroclinic response to AO, such as Ekman pumping in the Beaufort Gyre, and ice melt/freeze anomalies in response to AO are less significant considering the whole Arctic freshwater balance.
    Description: We gratefully acknowledge the support from National Science Foundation under Grant No OPP-0230184 (AP) and from NASA Headquarters (SH).
    Keywords: Fresh water ; Arctic ; Variability
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    Barotropic tides on the southeast New England shelf : a view from a hybrid data assimilative modeling approach (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C08002, doi:10.1029/2005JC003254.
    Description: A high-resolution hybrid data assimilative (DA) modeling system is used to study barotropic tides and tidal dynamics on the southeast New England shelf. In situ observations include tidal harmonics of 5 major tidal constituents [M2, S2, N2, O1, and K1] analyzed from coastal sea level and bottom pressure gauges. The DA system consists of both forward and inverse models. The former is the three-dimensional, finite difference, nonlinear Regional Ocean Modeling System (ROMS). The latter is a three-dimensional linearized, frequency domain, finite element model TRUXTON. The DA system assimilates in situ observations via the inversion for the barotropic tidal open boundary conditions (OBCs). Model skill is evaluated by comparing the misfits between the observed and modeled tidal harmonics. The assimilation scheme is found effective and efficient in correcting the tidal OBCs, which in turn improve ROMS tidal solutions. Up to 50% decreases of model/data misfits are achieved after inverse data assimilation. Co-amplitude and co-phase maps and tidal current ellipses for each of 5 tidal constituents are generated, revealing complex tidal variability in this transition region between the tidally amplified Gulf of Maine in the northeast and the tidally much less energetic Middle Atlantic Bight in the southwest. Detailed examinations on the residual circulation, energetics, and momentum balances of the M2 tide reveal the key roles of the unique bottom bathymetry of Nantucket Shoals and the complex coastal geometry in affecting the regional tidal dynamics.
    Description: This work was supported by WHOI Coastal Ocean Institute Research Award. J.W. acknowledges support of the Office of Naval Research.
    Keywords: Continental shelf ; Barotropic tides ; Numerical modeling ; Data assimilation
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    Significance of cyclonic SubTropical Oceanic Rings of Magnitude (STORM) eddies for the carbon budget of the euphotic layer in the subtropical northeast Atlantic (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2003. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 108, C12 (2003): 3383, doi:10.1029/2003JC001884.
    Description: The interannual and seasonal variability of cyclonic eddies budded from the Azores Current during the period 1993–1999 in the northeast subtropical Atlantic region (20°N–34°N; 19°W–35°W) was studied by using TOPEX/Poseidon and ERS-1/2 altimeter images, the operational ocean mesoscale forecasting system SOPRANE, and a mesoscale eddies automatic detection system. Seventeen cyclonic eddies were detected and monitored for time periods ranging from 50 to 360 days. They were characterized by mean westward velocity, amplitude, diameter, and eccentricity of about 2 km d−1, 8 cm, 187 km and 0.7, respectively. The generation of cyclonic eddies was subjected to an important interannual variability, especially in 1995 when the activity of cyclonic eddies in the northeast Atlantic was more intense and associated with parallel changes in the eddy energy of the Azores Current. Seventy-five percent of the mesoscale features were generated throughout the October–February period. Significant relationships were found between the seasonal NAO index and both the annual eddy kinetic and potential energy in the Azores Current region and also the total annual area occupied by STORM eddies, calculated with a 1-year phase lag. The outcome of this study was used to estimate the contribution of STORM eddies to the organic carbon deficit measured in the northeast subtropical Atlantic. On average, these eddies accounted for 〈1% of the net community production in the region.
    Description: This work has been done by CLS under contract (98.87.064.00.470.29.25) with SHOM/ CMO. This study was funded by the European Commission under the CANIGO contract MAS3CT960060 and CICYT. B. Mouriño was supported by a FPU fellowship from the Ministerio de Educacio´n y Cultura (Spain).
    Keywords: Mesoscale eddies ; Organic carbon deficit ; Subtropical northeast Atlantic
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    How does ocean biology affect atmospheric pCO2? Theory and models (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C07032, doi:10.1029/2007JC004598.
    Description: This paper examines the sensitivity of atmospheric pCO2 to changes in ocean biology that result in drawdown of nutrients at the ocean surface. We show that the global inventory of preformed nutrients is the key determinant of atmospheric pCO2 and the oceanic carbon storage due to the soft-tissue pump (OCS soft ). We develop a new theory showing that under conditions of perfect equilibrium between atmosphere and ocean, atmospheric pCO2 can be written as a sum of exponential functions of OCS soft . The theory also demonstrates how the sensitivity of atmospheric pCO2 to changes in the soft-tissue pump depends on the preformed nutrient inventory and on surface buffer chemistry. We validate our theory against simulations of nutrient depletion in a suite of realistic general circulation models (GCMs). The decrease in atmospheric pCO2 following surface nutrient depletion depends on the oceanic circulation in the models. Increasing deep ocean ventilation by increasing vertical mixing or Southern Ocean winds increases the atmospheric pCO2 sensitivity to surface nutrient forcing. Conversely, stratifying the Southern Ocean decreases the atmospheric CO2 sensitivity to surface nutrient depletion. Surface CO2 disequilibrium due to the slow gas exchange with the atmosphere acts to make atmospheric pCO2 more sensitive to nutrient depletion in high-ventilation models and less sensitive to nutrient depletion in low-ventilation models. Our findings have potentially important implications for both past and future climates.
    Description: While at MIT, I.M. was supported by the NOAA Postdoctoral Program in Climate and Global Change, administered by the University Corporation for Atmospheric Research.
    Keywords: Carbon cycle ; Preformed nutrient ; Nutrient depletion
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    Using altimetry to help explain patchy changes in hydrographic carbon measurements (2010)
    American Geophysical Union
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): C09013, doi:10.1029/2008JC005183.
    Description: Here we use observations and ocean models to identify mechanisms driving large seasonal to interannual variations in dissolved inorganic carbon (DIC) and dissolved oxygen (O2) in the upper ocean. We begin with observations linking variations in upper ocean DIC and O2 inventories with changes in the physical state of the ocean. Models are subsequently used to address the extent to which the relationships derived from short-timescale (6 months to 2 years) repeat measurements are representative of variations over larger spatial and temporal scales. The main new result is that convergence and divergence (column stretching) attributed to baroclinic Rossby waves can make a first-order contribution to DIC and O2 variability in the upper ocean. This results in a close correspondence between natural variations in DIC and O2 column inventory variations and sea surface height (SSH) variations over much of the ocean. Oceanic Rossby wave activity is an intrinsic part of the natural variability in the climate system and is elevated even in the absence of significant interannual variability in climate mode indices. The close correspondence between SSH and both DIC and O2 column inventories for many regions suggests that SSH changes (inferred from satellite altimetry) may prove useful in reducing uncertainty in separating natural and anthropogenic DIC signals (using measurements from Climate Variability and Predictability's CO2/Repeat Hydrography program).
    Description: This report was prepared by K.B.R. under awards NA17RJ2612 and NA08OAR4320752, which includes support through the NOAA Office of Climate Observations (OCO). The statements, findings, conclusions, and recommendations are those of the authors and do not necessarily reflect the views of the National Oceanic and Atmospheric Administration or the U.S. Department of Commerce. Support for K.B.R. was also provided by the Carbon Mitigation Initiative (CMI) through the support of BP, Amaco, and Ford. R.M.K. was supported by NOAA grants NA17RJ2612, NA08OAR4320752, and NA08OAR4310820. F.F.P. was supported by the European Union FP6 CARBOOCEAN Integrated project (contract 51176), the French OVIDE project, and the Spanish Salvador de Madariaga program (PR2006– 0523). This work was also supported by the European NOCES project (EVK2-CT201-00134). Y.Y. and A.I. are partly supported by CREST, JST of Japan. The long-term OISO observational program in the South Indian Ocean is supported by the following three French institutes: INSU (Institut National des Sciences de l’Univers), IPSL (Institute Pierre-Simon Laplace), and IPEV (Institut Paul-Emile Victor).
    Keywords: Modeling ; Climate ; Carbon
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    Precision requirements for space-based XCO2 data (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): D10314, doi:10.1029/2006JD007659.
    Description: Precision requirements are determined for space-based column-averaged CO2 dry air mole fraction (XCO2) data. These requirements result from an assessment of spatial and temporal gradients in XCO2, the relationship between XCO2 precision and surface CO2 flux uncertainties inferred from inversions of the XCO2 data, and the effects of XCO2 biases on the fidelity of CO2 flux inversions. Observational system simulation experiments and synthesis inversion modeling demonstrate that the Orbiting Carbon Observatory mission design and sampling strategy provide the means to achieve these XCO2 data precision requirements.
    Description: This work was supported by the Orbiting Carbon Observatory (OCO) project through NASA’s Earth System Science Pathfinder (ESSP) program. SCO and JTR were supported by a NASA IDS grant (NAG5-9462) to JTR.
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    Secular sea level change in the Russian sector of the Arctic Ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C03042, doi:10.1029/2003JC002007.
    Description: Sea level is a natural integral indicator of climate variability. It reflects changes in practically all dynamic and thermodynamic processes of terrestrial, oceanic, atmospheric, and cryospheric origin. The use of estimates of sea level rise as an indicator of climate change therefore incurs the difficulty that the inferred sea level change is the net result of many individual effects of environmental forcing. Since some of these effects may offset others, the cause of the sea level response to climate change remains somewhat uncertain. This paper is focused on an attempt to provide first-order answers to two questions, namely, what is the rate of sea level change in the Arctic Ocean, and furthermore, what is the role of each of the individual contributing factors to observed Arctic Ocean sea level change? In seeking answers to these questions we have discovered that during the period 1954–1989 the observed sea level over the Russian sector of the Arctic Ocean is rising at a rate of approximately 0.123 cm yr−1 and that after correction for the process of glacial isostatic adjustment this rate is approximately 0.185 cm yr−1. There are two major causes of this rise. The first is associated with the steric effect of ocean expansion. This effect is responsible for a contribution of approximately 0.064 cm yr−1 to the total rate of rise (35%). The second most important factor is related to the ongoing decrease of sea level atmospheric pressure over the Arctic Ocean, which contributes 0.056 cm yr−1, or approximately 30% of the net positive sea level trend. A third contribution to the sea level increase involves wind action and the increase of cyclonic winds over the Arctic Ocean, which leads to sea level rise at a rate of 0.018 cm yr−1 or approximately 10% of the total. The combined effect of the sea level rise due to an increase of river runoff and the sea level fall due to a negative trend in precipitation minus evaporation over the ocean is close to 0. For the Russian sector of the Arctic Ocean it therefore appears that approximately 25% of the trend of 0.185 cm yr−1, a contribution of 0.048 cm yr−1, may be due to the effect of increasing Arctic Ocean mass.
    Description: This material is based upon work supported by the National Science Foundation under grant 0136432.
    Keywords: Arctic ; Sea level rise ; Decadal variability ; Steric effects ; Inverted barometer effect ; Glacial isostatic adjustment
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    Physical properties of hydrate-bearing sediments (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Reviews of Geophysics 47 (2009): RG4003, doi:10.1029/2008RG000279.
    Description: Methane gas hydrates, crystalline inclusion compounds formed from methane and water, are found in marine continental margin and permafrost sediments worldwide. This article reviews the current understanding of phenomena involved in gas hydrate formation and the physical properties of hydrate-bearing sediments. Formation phenomena include pore-scale habit, solubility, spatial variability, and host sediment aggregate properties. Physical properties include thermal properties, permeability, electrical conductivity and permittivity, small-strain elastic P and S wave velocities, shear strength, and volume changes resulting from hydrate dissociation. The magnitudes and interdependencies of these properties are critically important for predicting and quantifying macroscale responses of hydrate-bearing sediments to changes in mechanical, thermal, or chemical boundary conditions. These predictions are vital for mitigating borehole, local, and regional slope stability hazards; optimizing recovery techniques for extracting methane from hydrate-bearing sediments or sequestering carbon dioxide in gas hydrate; and evaluating the role of gas hydrate in the global carbon cycle.
    Description: This work is the product of a Department of Energy (DOE)–sponsored Physical Property workshop held in Atlanta, Georgia, 16–19 March 2008. The workshop was supported by Department of Energy contract DE-AI21-92MC29214. U.S. Geological Survey contributions were supported by the Gas Hydrate Project of the U.S. Geological Survey's Coastal and Marine Geology Program. Lawrence Berkeley National Laboratory contributions were supported by the Assistant Secretary for Fossil Energy, Office of Oil and Natural Gas, through the National Energy Technology Laboratory of the U.S. DOE under contract DE-AC02-05CH11231. Georgia Institute of Technology contributions were supported by the Goizueta Foundation, DOE DE-FC26-06NT42963, and the DOE-JIP administered by Chevron award DE-FC26-610 01NT41330. Rice University contributions were supported by the DOE under contract DE-FC26-06NT42960.
    Keywords: Physical properties ; Hydrate-bearing sediment ; Gas hydrate
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    Origin of the smooth zone in early Cretaceous North Atlantic magnetic anomalies (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 37 (2010): L01304, doi:10.1029/2009GL040984.
    Description: Late Jurassic-Early Cretaceous marine magnetic anomalies observed in the North Atlantic exhibit an abrupt change in character in M5-M15 crust. The anomalies are smoother with low amplitudes, and are difficult to correlate among nearby profiles. The accepted explanation for the origin of this smooth zone is diminished resolution and anomaly interference due to slow spreading rates, which narrows the widths of polarity reversals in the crust and causes interference among sea-surface anomalies. Magnetic modeling of these anomalies indicates that neither slow spreading rates alone nor slow spreading rates in combination with a decrease in geomagnetic field intensity can explain the basic character of the smooth zone. Combined with other geophysical evidence, our study suggests that one consequence of slow spreading rates that is responsible for the magnetic “smooth zone” is a thinned crustal basalt layer or a non-basaltic magnetic source layer resulting from low melt supply during a period of ultra-slow spreading.
    Description: This work was supported by the Jane & R. Ken Williams '45 Chair of Ocean Drilling Science and Technology.
    Keywords: Mid-oceanic ridge processes ; Marine magnetics and paleomagnetics ; Ocean core complex
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    Fluid inclusion evidence for subsurface phase separation and variable fluid mixing regimes beneath the deep-sea PACMANUS hydrothermal field, Manus Basin back arc rift, Papua New Guinea (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): B03201, doi:10.1029/2003JB002579.
    Description: Altered volcanic rocks were cored from over 350 m below the seafloor at the Papua New Guinea-Australia-Canada Manus Basin Hydrothermal Field (PACMANUS) deep-sea hydrothermal field, in the eastern Manus back arc basin. Fluid inclusions in anhydrite veins reveal phase separation and fluid mixing beneath the seafloor. The anhydrite precipitated from high-temperature fluids (150–385°C). At Roman Ruins, a site of active high-temperature venting (220–276°C, measured by submersible), the fluid inclusion thermal depth profile is uniform and high temperature (242–368°C). At Snowcap, a site of warm water effusion (6–65°C), the fluid inclusions indicate high temperatures at depth (270–385°C) but both low and high temperatures in the shallower section. This indicates a flow regime dominated by vertical advection and shallow entrainment and mixing with cool seawater. Inclusions at Snowcap exhibit extreme salinity variations due to phase separation at temperatures above 350°C. Fluids contain Na, Cl, Fe, Zn, Mg, and Ba and a minor gas component such as CO2 or CH4. Most inclusions at Roman Ruins exhibit salinities that fall within the range of those observed at modern active vent sites along the mid-ocean ridge system. Fluid inclusion temperatures support a hypothesis, developed previously from Sr-isotopic analysis, that the subseafloor at Snowcap is characterized by mixing between deep-sourced hot hydrothermal fluids and cold seawater-like fluid. Both heating of seawater and cooling of upwelling hydrothermal fluids can be recognized by combining isotopic and fluid inclusion data. In contrast to Snowcap, the regime at Roman Ruins is less varied, with uniformly high-temperature upwelling fluids that have hydrothermally dominated Sr-isotopic ratios.
    Description: W.B. and D.A.V. thank JOI/USSAC for support and S.R. acknowledges a NERC grant (NER/T/S/2000/0024).
    Keywords: Fluid inclusions ; Ocean Drilling Program ; Anhydrite
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    Variational analysis of drifter positions and model outputs for the reconstruction of surface currents in the central Adriatic during fall 2002 (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C04004, doi:10.1029/2007JC004148.
    Description: In this paper we present an application of a variational method for the reconstruction of the velocity field in a coastal flow in the central Adriatic Sea, using in situ data from surface drifters and outputs from the ROMS circulation model. The variational approach, previously developed and tested for mesoscale open ocean flows, has been improved and adapted to account for inhomogeneities on boundary current dynamics over complex bathymetry and coastline and for weak Lagrangian persistence in coastal flows. The velocity reconstruction is performed using nine drifter trajectories over 45 d, and a hierarchy of indirect tests is introduced to evaluate the results as the real ocean state is not known. For internal consistency and impact of the analysis, three diagnostics characterizing the particle prediction and transport, in terms of residence times in various zones and export rates from the boundary current toward the interior, show that the reconstruction is quite effective. A qualitative comparison with sea color data from the MODIS satellite images shows that the reconstruction significantly improves the description of the boundary current with respect to the ROMS model first guess, capturing its main features and its exchanges with the interior when sampled by the drifters.
    Description: Four of the authors are supported by the Office of Naval Research, V.T. and A.G. under grants N00014-05-1-0094 and N00014-05-1-0095, P.M.P. under grant N00014-03-1-0291, and S.C. under grant N00014-05-1-0730. CNR-ISMAR activity was partially supported by P.O.R. ‘‘CAINO’’ (Regione Puglia), VECTOR (Italian MIUR) project, and ECOOP (EU project).
    Keywords: Coastal circulation ; Flow reconstruction ; Lagrangian analysis
    Repository Name: Woods Hole Open Access Server
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    Large-eddy simulation of the tidal-cycle variations of an estuarine boundary layer (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C08003, doi:10.1029/2009JC005702.
    Description: The estuarine boundary layer affected by a horizontal density gradient exhibits temporal evolution over a tidal cycle, in a manner similar to the diurnal cycle of the ocean surface mixed layer. A large eddy simulation (LES) model is developed to investigate the physics controlling the growth of the boundary layer during the flood tide and restratification during the ebb tide. Turbulent kinetic energy, momentum and salt fluxes, bottom stress, and energy dissipation rates calculated from the LES model all show a strong flood-ebb asymmetry. Analysis of the turbulent kinetic energy (TKE) budget shows a primary balance between shear production and dissipation in the well-mixed boundary layer over the tidal cycle. However, TKE transport term is found to be important across the edge of the boundary layer during the flood tide so turbulent energy generated in the bottom boundary layer can be transferred to the stratified pycnocline region. Tidal straining leads to a small and weakly convective region inside the boundary layer during the flood tide but the strain-induced buoyancy flux does not make a significant contribution to the turbulence generation. Additional LES runs are conducted by switching off the baroclinic pressure gradient term in the momentum equation and the tidal straining term in the salinity equation to show that the baroclinic pressure gradient is the main mechanism responsible for generating the flood-ebb mixing asymmetry.
    Description: This work is supported by grants OCE-0451699 (M.L.), OCE-0452380 (U.P. and S.R.), and OCE-0451740 (W.R.G.) from the National Science Foundation.
    Keywords: Estuarine mixing ; Large Eddy Simulations ; Tidal straining
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    Reconstruction and analysis of the Chukchi Sea circulation in 1990–1991 (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C08023, doi:10.1029/2009JC005453.
    Description: The Chukchi Sea (CS) circulation reconstructed for September 1990 to October 1991 from sea ice and ocean data is presented and analyzed. The core of the observational data used in this study comprises the records from 12 moorings deployed in 1990 and 1991 in U.S. and Russian waters and two hydrographic surveys conducted in the region in the fall of 1990 and 1991. The observations are processed by a two-step data assimilation procedure involving the Pan-Arctic Ice-Ocean Modeling and Assimilation System (employing a nudging algorithm for sea ice data assimilation) and the Semi-implicit Ocean Model [utilizing a conventional four-dimensional variational (4D-var) assimilation technique]. The reconstructed CS circulation is studied to identify pathways and assess residence times of Pacific water in the region; quantify the balances of volume, freshwater, and heat content; and determine the leading dynamical factors configuring the CS circulation. It is found that in 1990–1991 (high AO index and a cyclonic circulation regime) Pacific water transiting the CS toward the Canada basin followed two major pathways, namely via Herald Canyon (Herald branch of circulation, 0.23 Sv) and between Herald Shoal and Cape Lisburne (central branch of circulation and Alaskan Coastal Current, 0.32 Sv). The annual mean flow through Long Strait was negligible (0.01 Sv). Typical residence time of Pacific water in the region varied between 150 days for waters entering the CS in September and 270 days for waters entering in February/March. Momentum balance analysis reveals that geostrophic balance between barotropic pressure gradient and Coriolis force dominated for most of the year. Baroclinic effects were important for circulation only in the regions with large horizontal salinity gradients associated with the fresh Alaskan and Siberian coastal currents and the Cape Lisburne and Great Siberian polynyas. In the polynyas, the baroclinic effects were due to strong salinification and convection processes associated with sea ice formation.
    Description: Panteleev, Proshutinsky, Nechaev, and Zhang were supported by the NSF ARC‐0632154 award. Panteleev was also partially funded by JAMSTEC, Japan, the International Arctic Research Center, and a project funded by the North Pacific Research Board. Woodgate was supported by NSF awards ARC‐0632154 and ARC‐0531026.
    Keywords: Chukchi Sea ; 4D-var data assimilation
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    Detecting anthropogenic CO2 changes in the interior Atlantic Ocean between 1989 and 2005 (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C11028, doi:10.1029/2010JC006251.
    Description: Repeat observations along the meridional Atlantic section A16 from Iceland to 56°S show substantial changes in the total dissolved inorganic carbon (DIC) concentrations in the ocean between occupations from 1989 through 2005. The changes correspond to the expected increase in DIC driven by the uptake of anthropogenic CO2 from the atmosphere, but the ΔDIC is more varied and larger, in some locations, than can be explained solely by this process. Concomitant large changes in oxygen (O2) suggest that processes acting on the natural carbon cycle also contribute to ΔDIC. Precise partial pressure of CO2 measurements suggest small but systematic increases in the bottom waters. To isolate the anthropogenic CO2 component (ΔCanthro) from ΔDIC, an extended multilinear regression approach is applied along isopycnal surfaces. This yields an average depth-integrated ΔCanthro of 0.53 ± 0.05 mol m−2 yr−1 with maximum values in the temperate zones of both hemispheres and a minimum in the tropical Atlantic. A higher decadal increase in the anthropogenic CO2 inventory is found for the South Atlantic compared to the North Atlantic. This anthropogenic CO2 accumulation pattern is opposite to that seen for the entire Anthropocene up to the 1990s. This change could perhaps be a consequence of the reduced downward transport of anthropogenic CO2 in the North Atlantic due to recent climate variability. Extrapolating the results for this section to the entire Atlantic basin (63°N to 56°S) yields an uptake of 5 ± 1 Pg C decade−1, which corresponds to about 25% of the annual global ocean uptake of anthropogenic CO2 during this period.
    Description: The CLIVAR/CO2 cruises are cosponsored by the physical and chemical oceanography divisions of the National Science Foundation and the Climate Observation Division of the Climate Program Office of NOAA. Support from the program managers involved is greatly appreciated. We also acknowledge a grant from NOAA (NOAA‐NA07OAR4310098), which supported part of the postcruise data analysis contributing to this manuscript. N.G. also acknowledges support from ETH Zurich.
    Keywords: Carbon cycling ; Biogeochemical cycles, processes, and modeling ; Oceans
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    Momentum balances on the inner continental shelf at Martha's Vineyard Coastal Observatory (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C12023, doi:10.1029/2009JC005578.
    Description: The subtidal, depth-average momentum balances in 12 m and 27 m water depth are investigated using observations from 2001 to 2007 of water velocity, temperature, and density; bottom pressure; surface gravity waves; and wind stress. In the fluctuating across-shelf momentum budget, the dominant terms are surface wind stress, pressure gradient, and Coriolis acceleration. The balance is a combination of (1) the geostrophic balance expected at midshelf sites and (2) the coastal setup and setdown balance driven by the across-shelf wind stress expected where surface and bottom boundary layers overlap. At the 12 m site, the estimated wave radiation stress gradient due to surface gravity wave shoaling is also large but is uncorrelated with the observed pressure gradient. A simple model suggests the wave radiation stress gradient is balanced by an across-shelf pressure gradient with a spatial scale too small to resolve with this mooring array. In the fluctuating along-shelf momentum balance, the dominant terms are surface wind stress, pressure gradient, and bottom stress at the shallower site, but the other estimated terms are not negligible. Our results support the Grant and Madsen (1986) formulation for wave-induced bottom stress. The fluctuating along-shelf pressure gradient is mainly a local sea level response to wind forcing, not a remotely generated pressure gradient. A strong correlation between along-shelf velocity and along-shelf wind stress at the shallower site is captured by a simple steady model of imbalance between wind stress and pressure gradient balanced by linear bottom drag.
    Description: This research was funded by the Ocean Sciences Division of the National Science Foundation under grants OCE‐ 0241292 and OCE‐0548961 and by the National Aeronautics and Space Administration Headquarters under grant NNG04GL03G and the Earth System Science Fellowship grant NNG04GQ14H. MVCO is partly funded by the Woods Hole Oceanographic Institution and the Jewett/EDUC/ Harrison Foundation. CBLAST 2003 was funded by the Office of Naval Research contracts N00014‐01‐1‐0029 and N00014‐05‐10090 for the Low‐Wind Component of the Coupled Boundary Layers Air‐Sea Transfer Experiment. The F ADCP, T1 and T2 moorings, and temperature measurements near the Node in 2003 were funded by the National Science Foundation Small Grant for Exploratory Research OCE‐0337892 (“Observational Mesoscale Context for Oceanic Turbulence Measurements Obtained during CBLAST‐Low”).
    Keywords: Inner shelf ; Momentum budget ; Coastal
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    Network strain filter : a new tool for monitoring and detecting transient deformation signals in GPS arrays (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): B12418, doi:10.1029/2010JB007442.
    Description: We have developed a tool to detect transient deformation signals from large-scale (principally GPS) geodetic arrays, referred to as a Network Strain Filter (NSF). The strategy is to extract spatially and temporally coherent signals by analyzing data from entire geodetic networks simultaneously. The NSF models GPS displacement time series as a sum of contributions from secular motion, transient displacements, site-specific local benchmark motion, reference frame errors, and white noise. Transient displacements are represented by a spatial wavelet basis with temporally varying coefficients that are estimated with a Kalman filter. A temporal smoothing parameter is also estimated online by the filter. The problem is regularized in the spatial domain by minimizing a smoothing (Laplacian) norm of the transient strain rate field. To test the performance of the NSF, we carried out numerical tests using the Southern California Integrated GPS Network station distribution and a 3 year long synthetic transient in a 6 year time series. We demonstrate that the NSF can identify the transient signal, even when the colored noise amplitude is comparable to that of transient signal. Application of the method to actual GPS data from the Japanese GPS network (GEONET) on the Boso Peninsula also shows that the NSF can detect transient motions resulting from aseismic fault slip.
    Description: We thank the Grant‐in‐Aid for Young Scientists [KAKENHI(18740283)] of the Ministry of Education, Culture, Sports, Science and Technology of Japan and the postdoctoral fellowships for research abroad of the Japan Society for the Promotion of Science. We also acknowledge support from NASA grant NNG04GC93G. This research was supported by the Southern California Earthquake Center. SCEC is funded by NSF Cooperative Agreement EAR‐0529922 and USGS Cooperative Agreement 07HQAG0008.
    Keywords: Strain transients
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    Deep ocean circulation and transport where the East Pacific Rise at 9–10°N meets the Lamont seamount chain (2011)
    American Geophysical Union
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    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C12073, doi:10.1029/2010JC006426.
    Description: We report the first 3-D numerical model study of abyssal ocean circulation and transport over the steep topography of the East Pacific Rise (EPR) and adjoining Lamont seamount chain in the eastern tropical Pacific. We begin by comparing results of hydrodynamical model calculations with observations of currents, hydrography, and SF6 tracer dispersion taken during Larval Dispersal on the Deep East Pacific Rise (LADDER) field expeditions in 2006–2007. Model results are then used to extend observations in time and space. Regional patterns are pronounced in their temporal variability at M2 tidal and subinertial periods. Mean velocities show ridge-trapped current jets flowing poleward west and equatorward east of the ridge, with time-varying magnitudes (weekly average maximum of ∼10 cm s−1) that make the jets important features with regard to ridge-originating particle/larval transport. Isotherms bow upward over the ridge and plunge downward into seamount flanks below ridge crest depth. The passage (P1) between the EPR and the first Lamont seamount to the west is a choke point for northward flux at ridge crest depths and below. Weekly averaged velocities show times of anticyclonic flow around the Lamont seamount chain as a whole and anticyclonic flow around individual seamounts. Results show that during the LADDER tracer experiment SF6 reached P1 from the south in the western flank jet. A short-lived change in regional flow direction, just at the time of SF6 arrival at P1, started the transport of SF6 to the west on a course south of the seamounts, as field observations suggest. Approximately 20 days later, a longer-lasting shift in regional flow from west to SSE returned a small fraction of the tracer to the EPR ridge crest.
    Description: The work of the lead author was funded by NOAA’s Pacific Marine Environmental Laboratory and by NOAA’s Vents Program. The work of the other authors has been supported by the Biological and Physical Oceanography Sections of the Division of Ocean Sciences of the NSF under grants OCE‐0424953 and OCE‐0425361, Larval Dispersion along the Deep East Pacific Rise (LADDER).
    Keywords: Mid-ocean ridge ; Abyssal ocean currents ; Numerical model ; SF6 tracer ; Inverse calculation ; Eastern tropical Pacific
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    An open-ocean forcing in the East China and Yellow seas (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C12056, doi:10.1029/2010JC006179.
    Description: Recent studies have demonstrated that the annual mean barotropic currents over the East China and Yellow seas (ECYS) are forced primarily by the oceanic circulation in the open-ocean basin through the Kuroshio Current (KC), the western boundary current of the subtropical gyre in the North Pacific Ocean. The local wind stress forcing plays an important but secondary role. Those previous results were mainly qualitative and from a simple barotropic model forced by a steady wind stress field. They remain to be tested in a more complete 3-D model with both wind stress and buoyancy fluxes. In addition, the seasonal variability of major ECYS currents may involve different forcing mechanisms than their annually averaged fields do, and this can only be addressed when a seasonally varying forcing is used in the model. In this paper, we will address these issues by using a 3-D baroclinic model. Our results confirm the finding from the previous studies that the KC is the primary forcing mechanism for major annually mean currents in the ECYS, which include the Taiwan Strait Current, the Tsushima Warm Current, and the Yellow Sea Warm Current (YSWC), etc. However, the local monsoonal forcing plays a prominent role in modulating the seasonal variability of all major currents in the region. A deep northwestward intrusion of the YSWC in winter, for instance, is mainly due to a robustly developed China Coastal Current and Korea Coastal Current, which draw water along the Yellow Sea Trough to feed the southward flows along the west and east coasts of the Yellow Sea.
    Description: This work was supported by the National Basic Research Program of China (2005CB422302), the International Science and Technology Cooperation Program of China (2006DFB21250), the Program of Introducing Talents of Discipline to Universities (B07036), the National Natural Science Foundation of China (41006003), and the U.S. National Science Foundation.
    Keywords: East China and Yellow seas ; Kuroshio Current ; POM
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    A reduced estimate of the strength of the ocean's biological carbon pump (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L04606, doi:10.1029/2011GL046735.
    Description: A major term in the global carbon cycle is the ocean's biological carbon pump which is dominated by sinking of small organic particles from the surface ocean to its interior. Several different approaches to estimating the magnitude of the pump have been used, yielding a large range of estimates. Here, we use an alternative methodology, a thorium isotope tracer, that provides direct estimates of particulate organic carbon export. A large database of thorium-derived export measurements was compiled and extrapolated to the global scale by correlation with satellite sea surface temperature fields. Our estimates of export efficiency are significantly lower than those derived from the f-ratio, and we estimate global integrated carbon export as ∼5 GtC yr−1, lower than most current estimates. The lack of consensus amongst different methodologies on the strength of the biological carbon pump emphasises that our knowledge of a major planetary carbon flux remains incomplete.
    Keywords: Carbon export ; Thorium-234 ; Satellite data
    Repository Name: Woods Hole Open Access Server
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  • 87
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    China's terrestrial carbon balance : contributions from multiple global change factors (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 25 (2011): GB1007, doi:10.1029/2010GB003838.
    Description: The magnitude, spatial, and temporal patterns of the terrestrial carbon sink and the underlying mechanisms remain uncertain and need to be investigated. China is important in determining the global carbon balance in terms of both carbon emission and carbon uptake. Of particular importance to climate-change policy and carbon management is the ability to evaluate the relative contributions of multiple environmental factors to net carbon source and sink in China's terrestrial ecosystems. Here the effects of multiple environmental factors (climate, atmospheric CO2, ozone pollution, nitrogen deposition, nitrogen fertilizer application, and land cover/land use change) on net carbon balance in terrestrial ecosystems of China for the period 1961–2005 were modeled with newly developed, detailed historical information of these changes. For this period, results from two models indicated a mean land sink of 0.21 Pg C per year, with a multimodel range from 0.18 to 0.24 Pg C per year. The models' results are consistent with field observations and national inventory data and provide insights into the biogeochemical mechanisms responsible for the carbon sink in China's land ecosystems. In the simulations, nitrogen deposition and fertilizer applications together accounted for 61 percent of the net carbon storage in China's land ecosystems in recent decades, with atmospheric CO2 increases and land use also functioning to stimulate carbon storage. The size of the modeled carbon sink over the period 1961–2005 was reduced by both ozone pollution and climate change. The modeled carbon sink in response to per unit nitrogen deposition shows a leveling off or a decline in some areas in recent years, although the nitrogen input levels have continued to increase.
    Description: This study has been supported by NASA IDS Program (NNG04GM39C), NASA LCLUC Pr o g ram (NNX08AL73G_S01), and China’s Ministry of Science and Technology (MOST) 973 Program (2002CB412500).
    Keywords: China ; Terrestrial carbon sink ; Ecosystem model
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  • 88
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    Initial rise of bubbles in cohesive sediments by a process of viscoelastic fracture (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 116 (2011): B04207, doi:10.1029/2010JB008133.
    Description: An understanding of the mechanics of bubble rise in sediments is essential because of the role of bubbles in releasing methane to the atmosphere and the formation and melting of gas hydrates. Past models to describe and predict the rise of other buoyant geological bodies through a surrounding solid (e.g., magmas and hydrofractures) appear not to be applicable to bubbles in soft sediments, and this paper presents a new model for gas bubble rise in soft, fine-grained, cohesive sediments. Bubbles in such sediments are essentially “dry” (little if any free water) and grow through a process of elastic expansion and fracture that can be described using the principles of linear elastic fracture mechanics, which assume the existence of a spectrum of flaws within the sediment fabric. By extending this theory, we predict that bubbles initially rise by preferential propagation of a fracture in a (sub) vertical direction. We present a criterion for initial bubble rise. Once rise is initiated, the speed of rise is controlled by the viscoelastic response of the sediments to stress. Using this new bubble rise model, we estimate rise velocities to be of the order of centimeters per second. We again show that capillary pressure plays no substantive role in controlling bubble growth or rise.
    Description: This research was funded by the U.S. Office of Naval research through grants N00014‐08‐0818 and N00014‐05‐1‐0175 (project managers J. Eckman and T. Drake). Support was also provided by the Natural Sciences and Engineering Council of Canada and by the Killam Trust.
    Keywords: Methane ; Fracture ; Bubbles ; Viscoelasticity
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  • 89
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    Farallon slab detachment and deformation of the Magdalena Shelf, southern Baja California (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L09307, doi:10.1029/2011GL050828.
    Description: Subduction of the Farallon plate beneath northwestern Mexico stalled by ~12 Ma when the Pacific-Farallon spreading-ridge approached the subduction zone. Coupling between remnant slab and the overriding North American plate played an important role in the capture of the Baja California (BC) microplate by the Pacific Plate. Active-source seismic reflection and wide-angle seismic refraction profiles across southwestern BC (~24.5°N) are used to image the extent of remnant slab and study its impact on the overriding plate. We infer that the hot, buoyant slab detached ~40 km landward of the fossil trench. Isostatic rebound following slab detachment uplifted the margin and exposed the Magdalena Shelf to wave-base erosion. Subsequent cooling, subsidence and transtensional opening along the shelf (starting ~8 Ma) starved the fossil trench of terrigenous sediment input. Slab detachment and the resultant rebound of the margin provide a mechanism for rapid uplift and exhumation of forearc subduction complexes.
    Description: This work was funded by the NSF Margins Program, grant number OCE-0112058.
    Description: 2012-11-08
    Keywords: Adakite ; Exhumation ; Rifting ; Seismic refraction ; Subduction ; Transtension
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    Correction to “Isotopic characterization of aerosol organic carbon components over the eastern United States” (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): D15399, doi:10.1029/2012JD018478.
    Description: 2013-01-04
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  • 91
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    Isotopic characterization of aerosol organic carbon components over the eastern United States (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): D13303, doi:10.1029/2011JD017153.
    Description: Carbon isotopic signatures (δ13C, Δ14C) of aerosol particulate matter total organic carbon (TOC) and operationally defined organic carbon (OC) components were measured in samples from two background sites in the eastern U.S. TOC and water-soluble OC (WSOC) δ13C values (−27 to −24‰) indicated predominantly terrestrial C3 plant and fossil derived sources. Total solvent extracts (TSE) and their aliphatic, aromatic, and polar OC components were depleted in δ13C (−30 to −26‰) relative to TOC and WSOC. Δ14C signatures of aerosol TOC and TSE (−476 to +25‰) suggest variable fossil contributions (~5–50%) to these components. Aliphatic OC while comprising a small portion of the TOC (〈1%), was dominated by fossil-derived carbon (86 ± 3%), indicating its potential utility as a tracer for fossil aerosol OC inputs. In contrast, aromatic OC contributions (〈1.5%) contained approximately equal portions contemporary (52 ± 8%) and fossil (48 ± 8%) OC. The quantitatively significant polar OC fraction (6–25% of TOC) had fossil contributions (30 ± 12%) similar to TOC (26 ± 7%) and TSE (28 ± 9%). Thus, much of both of the fossil and contemporary OC is deduced to be oxidized, polar material. Aerosol WSOC consistently showed low fossil content (〈8%) relative to the TOC (5–50%) indicating that the majority of fossil OC in aerosol particulates is insoluble. Therefore, on the basis of solubility and polarity, aerosols are predicted to partition differently once deposited to watersheds, and these chemically distinct components are predicted to contribute in quantitatively and qualitatively different ways to watershed carbon biogeochemistry and cycling.
    Description: ASW was partially supported by a Graduate Fellowship from the Hudson River Foundation during the course of this study. Additional funding for this work came from a NOSAMS student internship award, a fellowship award from Sun Trust Bank administered through the VIMS Foundation, a student research grant from VIMS, and the following NSF awards: DEB Ecosystems grant DEB-0234533, Chemical Oceanography grant OCE-0327423, and Integrated Carbon Cycle Research Program grant EAR-0403949 to JEB; and Chemical Oceanography grant OCE-0727575 to RMD and JEB.
    Description: 2013-01-04
    Keywords: Aerosols ; Isotopes ; Organic carbon ; Particulate matter ; Radiocarbon ; Water soluble organic carbon
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  • 92
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    Exploring preserved fossil dinoflagellate and haptophyte DNA signatures to infer ecological and environmental changes during deposition of sapropel S1 in the eastern Mediterranean (2011)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 26 (2011): PA2204, doi:10.1029/2010PA001948.
    Description: In this study we used a comparative multiproxy survey (fossil DNA, calcareous nannofossils, and lipid biomarkers) to test whether preserved genetic signatures provide an accurate view of haptophyte and dinoflagellate populations during deposition of the eastern Mediterranean sapropel S1 and the organic carbon-depleted oxidized marls flanking the S1 and to see if we could identify important environmental indicator species that did not fossilize and escaped previous microscopic identification. The marls above and below the S1 contained low concentrations of lipid biomarkers diagnostic for dinoflagellates and haptophytes (i.e., dinosterol and long-chain alkenones), but 500 base pair long ribosomal DNA fragments of these protists were below the detection limit. In contrast, dinoflagellate and haptophyte DNA could be recovered from the organic carbon-rich S1, but the most abundant sequences did not represent species that were part of the nannofossil (this study) or previously described dinocyst composition. The oldest section of S1 (9.8 to ∼8 14C kyr B.P.) revealed a predominance of dinoflagellate phylotypes, which were previously only detected in anoxic Black Sea sediments. In the same section of the core, the most abundant haptophyte sequence showed highest similarity with uncultivated haptophytes that were previously shown to grow mixotrophically as predators of picocyanobacteria, an adaptation that promotes growth in oligotrophic marine waters. Sequences with highest similarities to clones found in marine surface waters predominated in the S1 after ∼8 14C kyr B.P. We discuss whether the shifts in haptophyte and dinoflagellate populations inferred from the preserved DNA reflect known environmental changes that occurred during the formation of sapropel S1.
    Description: This work was supported by grants and prizes from the Netherlands Organization for Scientific Research (NWO Open Competition grant 813.03.001 to M.J.L.C., NWO Pass2 grant to G.J.d.L., and the Spinoza prize to J.S.S.D.) as well as NSF‐OCE Chemical Oceanography grant 0825020 to M.J.L.C.
    Keywords: Paleogenetics ; Mediterranean sapropels ; Lipid biomarkers
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    Effusive and explosive volcanism on the ultraslow-spreading Gakkel Ridge, 85°E (2012)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 13 (2012): Q10005, doi:10.1029/2012GC004187.
    Description: We use high-definition seafloor digital imagery and multibeam bathymetric data acquired during the 2007 Arctic Gakkel Vents Expedition (AGAVE) to evaluate the volcanic characteristics of the 85°E segment of the ultraslow spreading Gakkel Ridge (9 mm yr−1 full rate). Our seafloor imagery reveals that the axial valley is covered by numerous, small-volume (order ~1000 m3) lava flows displaying a range of ages and morphologies as well as unconsolidated volcaniclastic deposits with thicknesses up to 10 cm. The valley floor contains two prominent volcanic lineaments made up of axis-parallel ridges and small, cratered volcanic cones. The lava flows appear to have erupted from a number of distinct source vents within the ~12–15 km-wide axial valley. Only a few of these flows are fresh enough to have potentially erupted during the 1999 seismic swarm at this site, and these are associated with the Oden and Loke volcanic cones. We model the widespread volcaniclastic deposits we observed on the seafloor as having been generated by the explosive discharge of CO2 that accumulated in (possibly deep) crustal melt reservoirs. The energy released during explosive discharge, combined with the buoyant rise of hot fluid, lofted fragmented clasts of rapidly cooling magma into the water column, and they subsequently settled onto the seafloor as fall deposits surrounding the source vent.
    Description: We gratefully acknowledge the financial support of the National Aeronautics and Space Administration, the National Science Foundation (N.S.F.), the International Polar Year 2007–2008, and Woods Hole Oceanographic Institution; and the graduate support provided by N.S.F., the NDSEG Fellowship, and WHOI Deep Ocean Exploration Institute.
    Description: 2013-04-06
    Keywords: Mid-ocean ridge ; Seafloor morphology ; Submarine explosive volcanism ; Ultraslow spreading
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  • 94
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    Inverse estimates of anthropogenic CO2 uptake, transport, and storage by the ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 20 (2006): GB2002, doi:10.1029/2005GB002530.
    Description: Regional air-sea fluxes of anthropogenic CO2 are estimated using a Green's function inversion method that combines data-based estimates of anthropogenic CO2 in the ocean with information about ocean transport and mixing from a suite of Ocean General Circulation Models (OGCMs). In order to quantify the uncertainty associated with the estimated fluxes owing to modeled transport and errors in the data, we employ 10 OGCMs and three scenarios representing biases in the data-based anthropogenic CO2 estimates. On the basis of the prescribed anthropogenic CO2 storage, we find a global uptake of 2.2 ± 0.25 Pg C yr−1, scaled to 1995. This error estimate represents the standard deviation of the models weighted by a CFC-based model skill score, which reduces the error range and emphasizes those models that have been shown to reproduce observed tracer concentrations most accurately. The greatest anthropogenic CO2 uptake occurs in the Southern Ocean and in the tropics. The flux estimates imply vigorous northward transport in the Southern Hemisphere, northward cross-equatorial transport, and equatorward transport at high northern latitudes. Compared with forward simulations, we find substantially more uptake in the Southern Ocean, less uptake in the Pacific Ocean, and less global uptake. The large-scale spatial pattern of the estimated flux is generally insensitive to possible biases in the data and the models employed. However, the global uptake scales approximately linearly with changes in the global anthropogenic CO2 inventory. Considerable uncertainties remain in some regions, particularly the Southern Ocean.
    Description: This research was financially supported by the National Aeronautics and Space Administration under grant NAG5- 12528. N. G. also acknowledges support by the National Science Foundation (OCE-0137274). Climate and Environmental Physics, Bern acknowledges support by the European Union through the Integrated Project CarboOcean and the Swiss National Science Foundation.
    Keywords: Anthropogenic CO2 ; Carbon cycle ; Inverse modeling
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  • 95
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    Natural variability and anthropogenic trends in oceanic oxygen in a coupled carbon cycle–climate model ensemble (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 23 (2009): GB1003, doi:10.1029/2008GB003316.
    Description: Internal and externally forced variability in oceanic oxygen (O2) are investigated on different spatiotemporal scales using a six-member ensemble from the National Center for Atmospheric Research CSM1.4-carbon coupled climate model. The oceanic O2 inventory is projected to decrease significantly in global warming simulations of the 20th and 21st centuries. The anthropogenically forced O2 decrease is partly compensated by volcanic eruptions, which cause considerable interannual to decadal variability. Volcanic perturbations in oceanic oxygen concentrations gradually penetrate the ocean's top 500 m and persist for several years. While well identified on global scales, the detection and attribution of local O2 changes to volcanic forcing is difficult because of unforced variability. Internal climate modes can substantially contribute to surface and subsurface O2 variability. Variability in the North Atlantic and North Pacific are associated with changes in the North Atlantic Oscillation and Pacific Decadal Oscillation indexes. Simulated decadal variability compares well with observed O2 changes in the North Atlantic, suggesting that the model captures key mechanisms of late 20th century O2 variability, but the model appears to underestimate variability in the North Pacific. Our results suggest that large interannual to decadal variations and limited data availability make the detection of human-induced O2 changes currently challenging.
    Description: This study is supported by the EU projects CARBOOCEAN (511176-2) and EUROCEANS (511106-2) and the Swiss National Science Foundation.
    Keywords: Oxygen variability ; Coupled carbon climate model ; Volcano
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  • 96
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    Interannual variations in continental-scale net carbon exchange and sensitivity to observing networks estimated from atmospheric CO2 inversions for the period 1980 to 2005 (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 22 (2008): GB3025, doi:10.1029/2007GB003082.
    Description: Interannually varying net carbon exchange fluxes from the TransCom 3 Level 2 Atmospheric Inversion Intercomparison Experiment are presented for the 1980 to 2005 time period. The fluxes represent the model mean, net carbon exchange for 11 land and 11 ocean regions after subtraction of fossil fuel CO2 emissions. Both aggregated regional totals and the individual regional estimates are accompanied by a model uncertainty and model spread. We find that interannual variability is larger on the land than the ocean, with total land exchange correlated to the timing of both El Niño/Southern Oscillation (ENSO) as well as the eruption of Mt. Pinatubo. The post-Pinatubo negative flux anomaly is evident across much of the tropical and northern extratropical land regions. In the oceans, the tropics tend to exhibit the greatest level of interannual variability, while on land, the interannual variability is slightly greater in the tropics and northern extratropics. The interannual variation in carbon flux estimates aggregated by land and ocean across latitudinal bands remains consistent across eight different CO2 observing networks. The interannual variation in carbon flux estimates for individual flux regions remains mostly consistent across the individual observing networks. At all scales, there is considerable consistency in the interannual variations among the 13 participating model groups. Finally, consistent with other studies using different techniques, we find a considerable positive net carbon flux anomaly in the tropical land during the period of the large ENSO in 1997/1998 which is evident in the Tropical Asia, Temperate Asia, Northern African, and Southern Africa land regions. Negative anomalies are estimated for the East Pacific Ocean and South Pacific Ocean regions. Earlier ENSO events of the 1980s are most evident in southern land positive flux anomalies.
    Keywords: Carbon cycle ; Atmospheric inversion ; Interannual variability
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    Modeling transport and fate of riverine dissolved organic carbon in the Arctic Ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 23 (2009): GB4006, doi:10.1029/2008GB003396.
    Description: The spatial distribution and fate of riverine dissolved organic carbon (DOC) in the Arctic may be significant for the regional carbon cycle but are difficult to fully characterize using the sparse observations alone. Numerical models of the circulation and biogeochemical cycles of the region can help to interpret and extrapolate the data and may ultimately be applied in global change sensitivity studies. Here we develop and explore a regional, three-dimensional model of the Arctic Ocean in which, for the first time, we explicitly represent the sources of riverine DOC with seasonal discharge based on climatological field estimates. Through a suite of numerical experiments, we explore the distribution of DOC-like tracers with realistic riverine sources and a simple linear decay to represent remineralization through microbial degradation. The model reproduces the slope of the DOC-salinity relationship observed in the eastern and western Arctic basins when the DOC tracer lifetime is about 10 years, consistent with published inferences from field data. The new empirical parameterization of riverine DOC and the regional circulation and biogeochemical model provide new tools for application in both regional and global change studies.
    Description: I.M.M. and M.J.F. are grateful to National Science Foundation for financial support.
    Keywords: Arctic Ocean ; Ocean circulation ; Biogeochemical processes
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    Correction to “Forcing of tropical Atlantic sea surface temperatures during the mid-Pleistocene transition” (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA1019, doi:10.1029/2005PA001134.
    Keywords: Sea-surface temperatures ; Mid-Pleistocene transition ; Tropical Atlantic
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  • 99
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    Stability of North Atlantic water masses in face of pronounced climate variability during the Pleistocene (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 19 (2004): PA2008, doi:10.1029/2003PA000921.
    Description: Geochemical profiles from the North Atlantic Ocean suggest that the vertical δ13C structure of the water column at intermediate depths did not change significantly between glacial and interglacial time over much of the Pleistocene, despite large changes in ice volume and iceberg delivery from nearby landmasses. The most anomalous δ13C profiles are from the extreme interglaciations of the late Pleistocene. This compilation of data suggests that, unlike today (an extreme interglaciation), the two primary sources of northern deep water, Norwegian-Greenland Sea and Labrador Sea/subpolar North Atlantic, had different characteristic δ13C values over most of the Pleistocene. We speculate that the current open sea ice conditions in the Norwegian-Greenland Sea are a relatively rare occurrence and that the high-δ13C deep water that forms in this region today is geologically unusual. If northern source deep waters can have highly variable δ13C, then this likelihood must be considered when inferring past circulation changes from benthic δ13C records.
    Description: National Science Foundation grants OCE-0118005 and OCE-0118001, which supported MER and DWO.
    Keywords: Paleoceanography ; North Atlantic Deep Water ; Pleistocene
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  • 100
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    Constructing the crust along the Galapagos Spreading Center 91.3°–95.5°W : correlation of seismic layer 2A with axial magma lens and topographic characteristics (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): B10310, doi:10.1029/2004JB003066.
    Description: Multichannel seismic reflection data are used to infer crustal accretion processes along the intermediate spreading Galapagos Spreading Center. East of 92.5°W, we image a magma lens beneath the ridge axis that is relatively shallow (1.0–2.5 km below the seafloor) and narrow (∼0.5–1.5 km, cross-axis width). We also image a thin seismic layer 2A (0.24–0.42 km) that thickens away from the ridge axis by as much as 150%. West of 92.7°W, the magma lens is deeper (2.5–4.5 km) and wider (0.7–2.4 km), and layer 2A is thicker (0.36–0.66 km) and thickens off axis by 〈40%. The positive correlation between layer 2A thickness and magma lens depth supports the interpretation of layer 2A as the extrusive volcanic layer with thickness controlled by the pressure on the magma lens and its ability to push magma to the surface. Our findings also suggest that narrower magma lenses focus diking close the ridge axis such that lava flowing away from the ridge axis will blanket older flows and thicken the extrusive crust off axis. Flow of lava away from the ridge axis is probably promoted by the slope of the axial bathymetric high, which is largest east of 92.5°W. West of ∼94°W the “transitional” axial morphology lacks a prominent bathymetric high and layer 2A no longer thickens off axis. We detect no magma lens west of 94.7°W where a small axial valley appears. The above changes can be linked to the westward decrease in the magma and heat flux associated with the fading influence of the Galapagos hot spot on the Galapagos Spreading Center.
    Description: This project was funded by NSF-OCE- 0002189.
    Keywords: Layer 2A ; Mid-ocean ridges ; Shallow melt lens
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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