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  • 01.02. Ionosphere  (1)
  • Abiogenesis  (1)
  • Springer  (2)
  • MDPI Publishing
  • 2020-2022  (2)
  • 1
    Publication Date: 2020-10-20
    Description: Pyrite and organic matter closely coexist in some hydrothermally-altered gabbroic xenoliths from the Hyblean Plateau, Sicily. The representative sample consists of plagioclase, Fe-oxides, clinopyroxene, pyrite and minor amounts of many other minerals. Plagioclase displays incipient albitization, clinopyroxene is deeply corroded. Pyrite grains are widely replaced by spongy-textured magnetite, which locally hosts Ca-(and Fe-)sulfate micrograins and blebs of condensed organic matter. Whole-rock trace element distribution evidences that incompatible elements, particularly the fluid-mobile Ba, U and Pb, are significantly enriched with respect to N-MORB values. The mineralogical and geochemical characteristics of the sample, and its U-Pb zircon age of 216.9 ± 6.7 MA, conform to the xenolith-based viewpoint that the unexposed Hyblean basement is a relict of the Ionian Tethys lithospheric domain, mostly consisting of abyssal-type serpentinized peridotites with small gabbroic intrusions. Circulating hydrothermal fluids there favored the formation of hydrocarbons trough Fischer-Tropsch-type organic synthesis, giving also rise to sulfidization episodes. Subsequent variations in temperature and redox conditions of the system induced partial de-sulfidization, Fe-oxides precipitation and sulfate-forming reactions, also promoting poly-condensation and aromatization of the already-formed hydrocarbons. Here we show organic matter adhering to a crystal face of a microscopic pyrite grain. Pyrite surfaces, as abiotic analogues of enzymes, can adsorb and concentrate organic molecules, also acting as catalysts for a broad range of proto-biochemical reactions. The present data therefore may support established abiogenesis models suggesting that pyrite surfaces carried out primitive metabolic cycles in suitable environments of the early Earth, such as endolithic recesses in mafic rocks permeated by hydrothermal fluids.
    Description: Published
    Description: 19-47
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Abiogenesis ; FTT synthesis ; Hydrothermal system ; Pyrite ; Sicily ; Xenoliths
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-09-01
    Description: This paper is a final review of the Simplified Ionospheric Regional Model (SIRM) devel- oped as a prototype in the early 1990s and improved in the following years. By means of an algorithm based on the Fourier synthesis, the SIRM model in its prototype version pro- vides predicted monthly median values of the main ionospheric characteristics such as: the ordinary wave critical frequencies (foE, foF1, and foF2) of the E, F1, and F2 ionospheric layers; the lowest virtual height (h’F) of the ordinary trace of the F region; the obliquity factor for a distance of 3000 km (M(3000)F2). Instead, the improved version focuses only on foF2 and M(3000)F2. The SIRM model has been largely employed in the framework of different international research projects as the climatological reference to output foF2 and M(3000)F2 monthly median predictions, but in its SIRMUP version is used also as a nowcasting model and as an intermediate step of complex procedures for a near real- time three-dimensional representation of the ionospheric electron density. In this regard, some results provided by both SIRM and SIRMUP for telecommunication applications are shown. Moreover, the mathematical treatment concerning both the phase correction of the Fourier synthesis and the fundamental steps carried out to define the SIRM algorithm in its final version, never published so far, will be described in detail in dedicated Appendices. Finally, for the first time the SIRM code is now downloadable for the benefit of users.
    Description: Published
    Description: 1143-1178
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Keywords: SIRM ; SIRMUP ; foF2 ; M(3000)F2 ; Regional modelling ; 01.02. Ionosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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