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  • Inorganic Chemistry  (3,890)
  • Cell & Developmental Biology
  • Tectonics
  • 2020-2022  (2)
  • 1930-1934
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Year
  • 1
    Publication Date: 2021-06-15
    Description: Sicily hosts many natural manifestations that include thermal waters, gas discharges and mud volcanoes. Due to the significant geodynamic and geological differences, the fluid discharges along a NE-WS–oriented transect that run from the Peloritani Mts. to the Sciacca Plain shows a large variability in water and gas chemical and isotopic compositions. The studied waters are characterized by Ca-HCO3, Ca(Mg)-SO4, Ca-Cl and Na-Cl compositions produced by distinct geochemical processes such as water-rock-gas interactions, mixing between deep and shallow aquifers and seawater and direct and reverse ion exchanges. The gas chemistry is dominated by CO2 to the east and CO2-N2 to the west of the study area, whereas the central part shows mud volcanoes discharging CH4-rich gases. Water isotopes suggest that the thermal waters are fed by a meteoric recharge, although isotopic exchange processes between thermal fluids and host rocks at temperature 〉150°C are recognized. Accordingly, liquid geothermometry suggests equilibrium temperatures up to 220°C. The carbon in CO2 and helium isotopes of the emissions from the westernmost sector of Sicily indicate that these two gases consists of up to 40 % of a mantle component, the latter decreasing to the east down to 10% where CO2 of thermometamorphic origin dominates. Accordingly, conceptual models of the fluid circulation for the western, central and eastern sectors are proposed. The regional geothermal reservoir, hosted in carbonates in the western sector and locally outcropping, is of low to medium temperature. Higher temperature conditions (up to 200-220°C) are suggested by geothermometry and probably related to deeper levels of the system. Sicily can be regarded as a potentially suitable area for future investigations to evaluate specific activities aimed at exploiting the geothermal resource.
    Description: Published
    Description: 102120
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Fluid geochemistry ; Stable isotopes ; Geothermal exploration ; Dissolved gases ; Tectonics ; 03. Hydrosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-10-16
    Description: High strain rates and intense seismic activity characterize both the boundaries and the interior of the Aegean–Anatolian plate: the availability of geodetic and geophysical data makes this region ideal to make detailed models of continental deformation. Although the deformation occurring in the Aegean–Anatolian plate may be regarded as the primary effect of the Arabian indenter push, it has already been demonstrated that this mechanism cannot account for the observed extrusion/rotation of the whole plate. We investigate the present-day steady-state anelastic deformation of the Aegean–Anatolian plate by a thin plate thermomechanical finite element (FE) model that accounts for realistic rheological mechanisms and lateral variations of lithospheric properties. Studying the region with uniform models, where average values for thermal and geometric parameters are chosen, we find that two tectonic features, in addition to the Arabian plate push, are critical to reproduce a velocity field that gives a reasonable fit to the observations. The first is the E–W constraint of NW continental Greece, related to the collision between the Aegean–Anatolian plate and the Apulia–Adriatic platform, required in the model to attain the SW orientation of the velocity field along the Hellenic Arc. The second is the trench suction force (TSF) due to subduction of the African lithosphere, which is needed to fit the observed mean extrusion velocity of 30 mm yr−1 along the Hellenic Arc. Uniform models are useful to study the sensitivity to the interplay of rheological/thermal parameters in a simplified framework but, in all cases, predict a strong deformation localized along the Hellenic Arc, whereas geodetic and seismological data show that the highest strain rates are located in western Anatolia. Furthermore, uniform models are non-unique in the sense that since we model a vertically averaged thin plate, different thermal and rheological parameters can be combined to yield the same lithospheric strength. We account for internal sources of deformation with heterogeneous models, where the available constraints on lateral variations of crustal thickness and surface heat flow have been included. The heterogeneous distribution of lithospheric strength contributes to ameliorate the fit to geodetic and stress data, since the predicted velocity field is characterized by an acceleration from E to W, with a sharp increase in the proximity of the western margin of the Anatolian peninsula, where the highest rates of intraplate deformation are observed. In our model this partitioning of the deformation is due to the different rheology of the Aegean Sea, which, being slightly deformable, transmits the TSF to the western margin of Anatolia. Our results are consistent with the interpretation of the Aegean–Anatolian system as a single, rheologically heterogeneous plate.
    Description: Published
    Description: 760-780
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Rheology ; Tectonics ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 185 (1930), S. 267-279 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 186 (1930), S. 289-323 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 186 (1930), S. 324-336 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Die aus Platinchloridlösung und Arsenwasserstoff erhaltene schwarzsamtne Fällung ist ein mehr oder weniger sauerstoffhaltiges Gemenge wechselnden Platin-Arsengehaltes mit beigemengtem Platin, vielleicht auch Arsen. Die TIVOLI'sche Verbindung PtAsOH entsteht nicht, auch demgemäß nicht beim Glühen der Fällung in CO2 die TIVOLI'sche Verbindung Pt3As2, sondern ebenfalls nur wechselnd zusammengesetzte Legierungen.2. Die ähnlichen Fällungen aus der wäßrigen Lösung von K2PtCl4 waren ärmer an Sauerstoff und Arsen.3. Die analogen Fällungen aus der Lösung von PtCl6H2 in Essigester oder Alkohol explodierten bei Zutritt von Luft durch den Gehalt organischer Bestandteile. Nach starkem Trocknen entsprach die Fällung aus Alkohol der sauerstofffreien Formel PtAs, mit Beimengung metallischen Platins.4. Auch aus der Sodaschmelze von Arsenik und Platinschwamm entstehen nur geschmolzene Legierungen wechselnder Zusammensetzung von geringerem Platingehalt als PtAs, entspricht.5. Sichergestellt ist nur die Existenz der Verbindung PtAs2, die im geschlossenen Rohr unter heftiger Reaktion darstellbar ist aus den beiden Bestandteilen mit überschüssigem Arsen, das im C02-Strom bei 500° zu entfernen ist und ebenso bei 650° im geschlossenen evakuierten Rohr an die kälteren Enden sublimiert. Seine chemische Angreifbarkeit durch Säuren wurde beschrieben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 186 (1930), S. 365-372 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Aktivierungswärme des festen Kupfersulfids in seiner Reaktion mit Wasserstoff hat sich zu 30,2 Kcal (bezogen auf ein Mol des entstehenden Schwefelwasserstoffs) ergeben.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 187 (1930), S. 401-403 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 188 (1930), S. 1-13 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Phenylglyoxylsäure läßt sich mit primären Aminen und Aminosäuren bei 137° katalytisch in Benzaldehyd und Kohlendioxyd spalten. Als Zwischenstoffe entstehen dabei Iminoderivate der Phenylglyoxylsäure. Die aktivsten Katalysatoren sind die α-Amino-säuren. Stets kommt die Katalyse infolge von Nebenreaktionen vorzeitig zum Stehen.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 188 (1930), S. 52-59 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 188 (1930), S. 90-113 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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