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  • Chemical Engineering  (691)
  • 1985-1989  (691)
  • 1988  (691)
  • 1
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 13-19 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The kinetics of crystallization during anioiiic polymerization of ∊-caprolactam was studied by the adiabatic temperature rise method, A new kinetic model for the non-isothermal crystallization was derived and the possibility of its application was Investigated. By evaluating the parameters in the model for the given adiabatic system, the crystallization behavior during the; polymerization process was analyzed. The experimental and calculated temperature rise showed a very good agreement, which indicated that the model equation was appropriate to describe the non-isothermal reaction-induced crystallization kinetics in this study. The melting temperature of the reaction mixture increased steadily due to the change of the crystal structure with conversion. The equilibrium crystallinity was higher when the crystallization started in the presence of unreacted monomer than when the crystallization occurred after polymerization was completed. At lower conversion, the reaction mixture was less viscous, a condition that made transport to the liquid-crystal interlace easier, and thus the activation energy for transport decreased. On the other hand, the increasing mobility resulted in difficulty in forming stable nuclei arid the free energy of nucleation increased.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 69-80 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Investigations of instability of phase morphology of blends of nylons with polyethylenes and polystyrenes and the effects of “compatibilizing” additives or “agents” are described. Annealing coarsens the phase morphology of blends of nylons with polyethylenes and polystyrenes. Phase growth is observed for various periods of annealing time. The addition of compatibilizing agents, specifically maleic anhydride grafted polyolefins to polyethylene-nylon blends and syrene-maleic anhydride copolymers to polystyrene-nylon blends, stabilize the phase dimensions. Styene-maleic anhydride copolymer is found more effective than styrene acrylonitrile copolymer as a compatibilizing agent. The mechanisms of this behavior are critically discussed.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 147-156 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: This paper discusses a computer control system for ram velocity of an injection molding machine using optimal state feedback based on the linear quadratic control theory. A new approach for the selection of appropriate weighting matrices is presented in this context. The simulation results reveal that the optimal controller has improved performance over the conventional PID controller presently used, having faster speed of response, significantly better tracking performance, and better noise filtering properties. The execution speed and the core storage requirements would allow implementation even on a small online computer.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 165-169 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Film embossing is a mechanical process in which a flat film is transformed into an embossed product. During the process, thermal and stress fields are applied Lo the polymer, causing changes in the microstructure and physical dimensions of the material. The engineering analysis of the process requires the study of various aspects relating to the characterization of the microstructure before and after embossing, A variety of techniques were employed to characterize the properties and microstructure of the embossed film in relation to: crystallinity, orientation, mechanical properties, and dimensions of the embossed films. The thermal treatment of the polymer film was shown to be the most significant factor in the process. By controlling the thermal treatment of the film, it is possible to manipulate the properties and dimensions of the embossed film. The important aspects: influencing thermal treatment include the radiation heater temperature, preheat roll temperature, line velocity, and film thickness. The initial film orientation and embossing pressure have a minor effect on the final properties of the embossed film. The main effect of the embossing pressure is on the bulk thickness of the embossed film.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 8
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 257-274 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A detailed model for emulsion polymerization is compared with extensive data from continuous stirred tank reactors. Model predictions are compared with both steady-state and dynamic data, for polymerization of styrene, methyl methacrylate, and vinyl acetate. Good agreement between model and experiment is achieved with one set of parameters and without any data fitting. The results show that the model is capable of predicting all of the experimentally observed phenomena including steady-state multiplicity, sustained oscillations, ignition and extinction dynamics, and overshoot during start-up.
    Zusätzliches Material: 47 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 321-332 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A mathematical model is developed for simulating the pultrusion process of unsaturated polyester resin, using a mechanistic kinetic model based on free radical polymerization. In their previous publications (Refs. 1 and 7), Han and Lee used the mechanistic model to simulate the curing behavior of unsaturated polyester resins under isothermal conditions, employing the differential scanning calorimetry data obtained for a range of single initiators and multiple initiator systems. For the sake of mathematical convenience, a pultrusion die of cylindrical geometry was considered. The mathematical model developed permits one to choose any number of initiators when predicting the distributions of the degree of cure and temperature in both the radial and axial directions of the die. The effects of material variables (e.g., the type and concentration of mixed initiators) and processing conditions (e.g., pulling speed and die temperature distribution) on the performance of the pultrusion are evaluated.
    Zusätzliches Material: 22 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 189-199 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Post mold thermal processing of epoxy encapsulated semiconductor devices is accomplished in order to optimize the properties of the encapsulating material. Traditionally, such processes were believed to alter solely the state of cure in such systems. We have examined the effects of aging at temperatures close to, but below the molding temperature via dynamic mechanical spectroscopy, Fourier transform infrared spectroscopy, and differential scanning calorimetry as a function of molding temperature. The large property changes observed during aging for samples molded at the lowest temperatures studied were attributed to physical aging phenomena in the presence of low levels of chemical reaction. As the molding temperature was increased chemical aging, phenomena began to precede the volume recovery associated with physical aging, and the overall property shift was altered. It is the intent of this paper to examine in detail the microstructural basis for such observations, as well as the time dependence of the overall property shifts.
    Zusätzliches Material: 19 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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