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  • 1
    Publication Date: 2024-05-10
    Description: Seaweeds and their bioactive compounds, particularly polysaccharides and phenolics can be regarded as great dietary supplements with gut health benefits and prebiotics. These components are resistant to digestion by enzymes present in the human gastrointestinal tract, also selectively stimulate the growth of beneficial gut bacteria and the production of fermentation products such as short chain fatty acids. Commonly, the health benefits of seaweed components are assessed by including them in an in vitro anaerobic fermentation system containing human fecal inocula that mimics the environment of the human large bowel. Regarding to the complex interactions between dietary components, gastrointestinal physiological processes, and gut microbiota are difficult to model in vitro. Consequently it is important to follow up the promising in vitro results with in vivo animal or human testing. The aim of this chapter is to have a comprehensive review on the application of seaweeds and seaweed-derived metabolites as prebiotics, and understand the trends, gaps and future directions of both scientific and industrial developments. This work contributes to develop and expand new platform of seaweed utilization for higher-value products, particularly to functional food and nutraceutical industries in order to serve the social demand for health awareness and support economic development.
    Type: Book chapter , PeerReviewed
    Format: text
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  • 2
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    Elsevier
    In:  EPIC3Current Opinion in Neurobiology, Elsevier, 60, pp. 55-66, ISSN: 0959-4388
    Publication Date: 2024-05-10
    Description: Animal life is rhythmic. Here we provide an overview of various rhythmic behaviors, connected environmental factors and endogenous mechanisms. We not only cover terrestrial species, but also highlight aquatic environments with typically complex interconnected rhythms. We further address diel, seasonal and potential lunar rhythms of humans. While we cannot be complete, we aim to emphasize three aspects: First, to raise awareness for the all-encompassing presence of behavioral rhythms and their importance in ecology and evolution. Second, to raise awareness how limited our mechanistic understanding is, besides analyses in a small set of model species. Finally, we discuss how anthropogenic effects can affect behavioral rhythmicity and how this might affect ecosystems in the future, as ‘For the times they are a-changin'’.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
    Publication Date: 2024-03-21
    Description: Due to their large heat and moisture storage capabilities, the tropics are fundamental in modulating both regional and global climate. Furthermore, their thermal response during past extreme warming periods, such as super interglacials, is not fully resolved. In this regard, we present high-resolution (analytical) foraminiferal geochemical (δ18O and Mg/Ca) records for the last 1800 kyr from the shallow (487 m) Inner Sea drift deposits of the Maldives archipelago in the equatorial Indian Ocean. Considering the diagenetic susceptibility of these proxies, in carbonate-rich environments, we assess the integrity of a suite of commonly used planktonic and benthic foraminifera geochemical datasets (Globigerinoides ruber (white), Globigerinita glutinata (with bulla), Pulleniatina obliquiloculata (with cortex) and Cibicides mabahethi) and their use for future paleoceanographic reconstructions. Using a combination of spot Secondary Ion Mass Spectrometer, Electron Probe Micro-Analyzer and Scanning Electron Microscope image data, it is evident that authigenic overgrowths are present on both the external and internal test (shell) surfaces, yet the degree down-core as well as the associated bias is shown to be variable across the investigated species and proxies. Given the elevated authigenic overgrowth Mg/Ca (∼12–22 mmol/mol) and δ18O values (closer to the benthic isotopic compositions) the whole-test planktonic G. ruber (w) geochemical records are notably impacted beyond ∼627.4 ka (24.7 mcd). Yet, considering the setting (i.e. bottom water location) for overgrowth formation, the benthic foraminifera δ18O record is markedly less impacted with only minor diagenetic bias beyond ∼790.0 ka (28.7 mcd). Even though only the top of the G. ruber (w) and C. mabahethi records (whole-test data) would be suitable for paleo-reconstructions of absolute values (i.e. sea surface temperature, salinity, seawater δ18O), the long-term cycles, while dampened, appear to be preserved. Furthermore, planktonic species with thicker-tests (i.e. P. obliquiloculata (w/c)) might be better suited, in comparison to thinner-test counter-parts (i.e. G. glutinata (w/b), G. ruber (w)), for traditional whole-test geochemical studies in shallow, carbonate-rich environments. A thicker test equates to a smaller overall bias from the authigenic overgrowth. Overall, if the diagenetic impact is constrained, as done in this study, these types of diagenetically altered geochemical records can still significantly contribute to studies relating to past tropical seawater temperatures, latitudinal scale ocean current shifts and South Asian Monsoon dynamics
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2024-01-31
    Description: The authors regret that the specified units of bioirrigation activity (Ic) and the indices (i.e. IPc,AFDM, IPc,WM, BPc,WM, BPc,AFDM) were incorrect in the original publication. Bioirrigation activity was presented in l/m25 min rather than in l/m2h and the indices were calculated per experimental core rather than per m2. Nevertheless, this does not affect the results and also the conclusions remain unchanged. AICc values for the best models of IPc,AFDM, IPc,WM, BPc,WM, BPc,AFDM have not changed in relation to each other, although they differ in value. The corrected version of Appendix B includes the corrected statistical details (i.e. AICc values). The corrected version of the Fig. 1 is provided below. The authors would like to apologize for any inconvenience caused.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 5
    Publication Date: 2023-11-29
    Description: Caldera footprints and erupted magma volumes provide a unique constraint on vertical dimensions of upper crustal magma reservoirs that feed explosive silicic eruptions. Here we define a Vertical Separation (VS) ratio in which we compare the geometric vertical extent with the range of depths indicated petrologically by melt inclusion water and CO2 saturation pressures for fifteen caldera-forming eruptions spanning ∼100 km3 to ∼103 km3 in volume. We supplement melt inclusion saturation pressures with rhyolite-MELTS barometry and plagioclase-melt hygrometry to generate a petrologic image of magma reservoir architecture. We find that pre-eruptive upper crustal magma reservoirs range from contiguous bodies (where petrologic and geometric estimates match closely) to vertically dispersed structures. Vertically dispersed pre-eruptive reservoirs are more common among intermediate-volume eruptions than among the smallest and largest caldera-forming eruptions. We infer that the architecture of magma reservoirs tracks the thermomechanical evolution of large volcanic systems.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2023-11-21
    Description: Highlights -He isotopic R/Ra of emitted gas decreases moving away from Albani Hills volcano -Total soil flux of endogenous CO2 at Lavinio-Tor Caldara is estimated to 20 ton/day -Tor Caldara gas has the highest H2S content (up to 6.3 vol.%) of central Italy -Repetition of soil CO2 flux survey shows that flux increases during earthquakes -Gas air concentration monitoring shows that H2S is the killer gas of small animals
    Description: Gas hazard was evaluated at Lavinio-Tor Caldara, the southernmost gas-discharging zone of the quiescent Albani Hills volcano in central Italy. Also this zone, like the other gas discharges of this volcanic complex, is located above a structural high of the buried Mesozoic carbonate basement, which represents the main reservoir for gas rising from depth. All extensional faults affecting the carbonates are leaking pathways along which gas may rise to the surface creating hazardous conditions. Gas is dominated by CO2 (〉90 vol.%) and the second component at Lavinio-Tor Caldara is H2S that displays the highest content (4.0-6.3 vol.%) of all gas manifestations of the Rome region. This H2S enrichment corresponds to a marked decrease in 3He/4He (R/Ra) isotopic ratio suggesting that gas was contaminated in an upper crustal environment. The main gas discharge occurs at the natural reserve of Tor Caldara, in zones where past sulphur mining excavations removed the surficial impervious cover, or along a ditch. Comparison of the results of four soil CO2 flux surveys carried out in 2005-2018 at Miniera Grande within Tor Caldara, indicates that the highest soil CO2 release occurs shortly after local earthquakes. Continuous monitoring of CO2 and H2S air concentration and of wind speed has been carried out for four months in twelve anomalous gas realising sites of Tor Caldara. Results indicate that only H2S reaches lethal concentration (〉250 ppm) near the soil in no wind nights, explaining the presence of small dead animals. At Lavinio, the main soil gas release occurs near old water wells that likely produced a gas blowout during drilling. A total release of over 20 tons/day from 2.93 km2 of gas of endogenous origin, has been estimated for the Lavinio-Tor Caldara area by a detailed soil CO2 flux survey (2,572 measurement points over an area of 3.65 km2). The main structural lineaments of the area have N-S and W-E directions, but also NE-SW and NW-SE directions are well represented. Some sectors of the investigated area are exposed to a severe gas hazard for people and animals and precautionary measures should be adopted.
    Description: Published
    Description: 106985
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: •Lavinio-Tor Caldara, southern periphery of Albani Hills volcano ; •He isotopic R/Ra values ; •Soil CO2 flux surveys ; •CO2 and H2S air concentration monitoring ; •Gas chemistry ; •Gas hazard assessment ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2023-11-21
    Description: Trace volatile elements like He are key for understanding the mantle source signature of magmas and to better constrain the relative roles of subduction and crustal processes to the variability of along-arc chemical and isotopic signatures of magmatic fluids. Here we report on noble gas abundances and isotopic data of Fluid Inclusions (FIs) in eruptive products and/or fumarolic gases from the Colombia-Ecuador segment of Andean Northern Volcanic Zone (NVZ). FIs in olivine phenocrysts from Ecuador (El Reventador, Cotopaxi and Tungurahua) yield air-normalized corrected 3He/4He ratios of 7.0–7.4 RA, within the MORB range (8 ± 1 RA). With exception of the Cotopaxi lavas (opx 〈 〈oliv.), these are indistinguishable of those obtained for their cogenetic orthopyroxene pairs and of gas emissions previously reported in literature. Olivine phenocrysts from Nevado del Ruiz fissure lavas also yield the highest 3He/4He (8.5 ± 0.3 RA) for this volcanic system, which is in the range of fumarolic gases for Galeras (previously reported as high as 8.8 RA and here measured to a maximum of 8.3 ± 0.1 RA). Our dataset highlights disparities between isotope signatures of eruptive products from Ecuador (avg. ~7.2 RA) and those reported for the Colombian portion of the NVZ (avg. ~8.5 RA). Previous studies on the geochemistry of erupted products put in evidence significant along-arc variations ascribed either to the involvement of different slab components, or to variable depths of evolution of arc magmas within the continental crust. However, the same variation is not discernible in the signature of noble gases, especially helium, from FIs and gas emissions analyzed in this study, with little inter-variation between Cotopaxi, Reventador and Tungurahua (all within 0.2 RA from the Ecuador average of 7.2) and Galeras and Nevado del Ruiz, whose maximum values differ by ~0.3 RA. We therefore suggest a homogenous MORB-like 3He/4He signature for the mantle wedge beneath this arc segment, whereby along-arc variations in crustal thickness (from 〈35 km at the northernmost part of the segment to ≥50 km at the Ecuadorian arc segment) may factor largely into the variability recorded on our data set. The first CO2/3He ratios obtained in FIs from Andean rocks support the hypothesis of increasing crustal contamination from Colombia to Ecuador, concomitant with increasing crustal thicknesses under the respective arc regions.
    Description: Published
    Description: 119966
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Andean Volcanic Belt ; Northern Volcanic Zone ; Fluid inclusions ; Noble gases ; Helium ; Crustal thickness ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2023-11-21
    Description: Azerbaijan hosts the highest density of subaerial mud volcanoes on Earth. The morphologies characterizing these structures vary depending on their geological setting, frequency of eruption, and transport processes during the eruptions. Lokbatan is possibly the most active mud volcano on Earth exhibiting impressive bursting events every ∼5 years. These manifest with impressive gas flares that may reach more than 100 meters in height and the bursting of thousands of m3 of mud breccia resulting in spectacular mud flows that extend for more than 1.5 kilometres. Unlike other active mud volcanoes, to our knowledge Lokbatan never featured any visual evidence of enduring diffuse degassing (e.g., active pools and gryphons) at and near the central crater. Only a very small new-born gryphon was intermittently active in 2019 (with negligible flow). Gas flux measurements completed with a closed-chamber technique reveal extremely low values throughout the structure with average CH4 = 1.36 tonnes yr−1 and CO2 = 11.85 tonnes yr−1. We suggest that after eruptive events, the mud breccia is able to seal the structure preventing gas release and thereby promoting overpressure build-up in the subsurface. This self-sealing mechanism allows a fast recharge of Lokbatan resulting in more frequent and powerful explosive episodes. Our field observations reveal the presence of large (up to ∼50,000 m3) stratified blocks that were originally part of a large crater cone. These blocks were rafted 〉1 km from the vent on top of mud breccia flows. We use a model based on lubrication theory to show that it is reasonable to transport blocks this large and this far provided the underlying mud flow was thick enough and the blocks are large enough. The presence of large rafted blocks is not a unique phenomenon observed at Lokbatan mud volcano and is documented at other large-scale structures both onshore and offshore.
    Description: Published
    Description: 116699
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Lokbatan mud volcano Azerbaijan ; rafted mud breccia megablocks ; gas flux ; self-sealing ; explosive eruptions ; lubrication theory ; Solid Earth ; Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2023-11-16
    Description: Lascar (5592 m a.s.l.) and Lastarria (5697 m a.s.l.) are Chilean active stratovolcanoes located in the Central Volcanic Zone (CVZ; 16°S to 28°S) that have developed on top of a 71 km thick continental crust. Independently of the similarities in their Plinian/Vulcanian eruptive styles, their complex magmatic feeding structures and the origins of their magmatic fluids still necessitate constraints in order to improve the reliability of geochemical monitoring. Here we investigate the petrography, bulk-rock chemistry, and mineral chemistry in products from the 1986–1993 explosive eruptive cycle at Lascar and from several Holocene eruptive sequences at Lastarria. These data are integratedwith measurements of the noble gas isotopes in fluid inclusions (FIs) of minerals fromthe same products as well as in fumarole gases. The geochemistry ofminerals and rocks shows that the studied products belong to high-K–calc-alkaline series typical of subduction-related settings, and provide evidence of differentiation,mixing, and crustal assimilation that are higher at Lastarria. The contribution of slab sediments and fluids to magma genesis in thewedge is limited, suggesting a homogeneous mantle beneath CVZ. The deepest crystallization processes occurred at variable levels of the plumbing systems according to the lithostatic equivalent depths estimated with mineral equilibrium geobarometers at Lascar (15–29 km) and Lastarria (~20–40 km). The 40Ar/36Ar and 4He/20Ne ratios in FIs and fumarole gases indicate the presence of some degree of air contamination in the fluids from both volcanoes. The 3He/4He values at Lascar (6.9–7.3 Ra) are relatively homogeneous and comparable to those of fumaroles, suggesting a main zone of magma crystallization and degassing. In contrast, the 3He/4He values at Lastarria (5.31–8.01 Ra) vary over a wide range, suggesting various magma storage levels and providing evidence of crustal contamination, as indicated by the rock chemistry.We argue thatmantle beneath the two volcanoes has a MORB-like signature of 3He/4He, while local crustal contamination explains the lower ratios measured at Lascar.
    Description: Published
    Description: 105615
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Lascar ; Lastarria ; noble gases ; Fluid inclusions ; Crustal contamination ; Mantle wedge ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2023-11-16
    Description: Submarine methane emissions in the Tuscan Archipelago have been studied since the 1960s, both for economic and research purposes. Offshore gas seepage is mainly concentrated southward and westward of Elba island, along N–S faults related to recent extensional activity in the Tuscan shelf and N–S trending positive magnetic anomalies, which have been interpreted as serpentinites associated with ophiolitic rocks due to their very high magnetic susceptibility. This study focuses on the gas chemistry of a new emission site corresponding to a shallow water mud volcano in the Scoglio d’Affrica area. The Scoglio d’Affrica seep has a gas composition typical of mud volcanoes, with methane as the prevalent component (95 vol%) and minor gases which include carbon dioxide, nitrogen and trace amounts of helium. The combined stable C and H isotope composition of CH4 (δ13C and δ2H) and the enrichment in heavy carbon isotopes of CO2, highlight a prevalent secondary microbial origin for these fluids (δ13C~− 35.8‰ vs VPDB; δ2H~− 166‰ vs VSMOW; δ13CCO2 up to + 21.7‰ vs VPDB). Thus, in spite of the occurrence of positive magnetic anomalies, a possible abiotic origin of methane is excluded. Moreover, the gas from the mud volcano is extremely depleted in 3He and presents typical 3He/4He ratios of a geological setting in which radiogenic crustal helium is strongly predominant. A photo-mosaic of the mud volcano is also reported. A possible connection with other submarine methane emissions in the Tuscan Archipelago is limited to emissions located few kilometers from the Scoglio d’Affrica area. Recent emissions in the area suggest that gases similar in composition from distinct reservoirs, find their way to the surface from Eocene deposits in different time intervals and through different faults and fractures, placed along the Elba-Pianosa ridge.
    Description: Published
    Description: 104722
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Submarine emission ; Mud volcano ; Methane ; Gas geochemistry ; Tyrrhenian sea ; Geochemistry ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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