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  • Chemical Engineering  (386)
  • 1970-1974  (386)
  • 1971  (386)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 3-4 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enthalpies of the coexisting equilibrium vapor and liquid mixtures of the ethane-n-butane-n-pentane system are computed at several pressures. Saturated liquid enthalpies are obtained by using a new multicomponent Clapeyron equation with the B-W-R equation of state and the experimental temperature-composition data for the ternary mixture. Saturated vapor enthalpies are calculated by applying the B-W-R equation to the vapor mixture. Ideal gas state enthalpies are used in both vapor and liquid enthalpy calculations.
    Additional Material: 1 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 30-37 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For certain classes of chemical reactions, it is possible to increase the yield of the desired products by choosing appropriate variable-volume operating policies. An analysis of the steady state and semibatch operation of a stirred tank reactor demonstrates operating policies for both the isothermal and adiabatic case to maximize the steady state yield and to produce an improved semibatch yield. Computations carried out by using an analogue computer with a digital logic expansion system demonstrate further relationships between yield increase and operating policy.
    Additional Material: 13 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 51-56 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Models for the laminar sublayer of turbulent pipe flow are reviewed. The observations of the sublayer by Popovich and Hummel and the experimental fluctuation frequencies obtained by Shaw and Hanratty are used with the models to evaluate experimental heat and mass transfer data. The eddy diffusivity model and a parallel conductance model appear to be consistent with the experimental data.
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 81-85 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of viscosity and diffusivity variations on concentration polarization during the ultrafiltration of protein solutions in two-dimensional stagnation flows is investigated by numerical integration of the equations of continuity and motion. It is found that these effects are surprisingly small and insensitive to the forms of concentration dependence postulated. The high Schmidt numbers and low permeation rates characteristic of these systems result in considerable simplification of the analysis and permit use of a modified Chilton-Colburn relation for predicting the onset of sludge formation at the membrane-solution interface. The predicted dependence on Schmidt number agrees with published experimental data for other boundary-layer flows and suggests the possibility of improved prediction of equipment performance.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 246-248 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 255-256 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 7
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 272-280 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of simultaneous, noncatalytic solid-gas reaction systems has been analyzed in terms of the selectivity and effectiveness factor, based on the unreacted core shrinking model. The reaction systems discussed include the first-order independent, parallel, and consecutive reactions with the simultaneous influences of heat and mass transfer. The effects of various chemical and transport properties on the stability, selectivity, and effectiveness factor of the system are discussed. The pseudosteady state approximation is employed to reduce the mathematical difficulties.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 291-294 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is made of the Van der Waals forces of two different species when separated by a third continuous component. Results show that under certain circumstances, attractions as well as repulsions can exist between the two different species. The theory is applied to a fibrous bed coalescer to determine what type of material would best serve as a coalescence medium.
    Additional Material: 1 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 335-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The periodic process utilizes a rapid pressure swing cycle in an adsorbent bed to effect the separation of gas mixtures. During the first portion of a cycle the compressed gas mixture flows into the adsorbent-filled column. Next, while the feed gas is restrained, an exhaust orifice is opened at the feed end of the column providing depressurization. The product stream is enriched in the component exhibiting the lowest coefficient of adsorption.A mathematical model based upon the assumption of instantaneous equilibrium between the gas phase and the adsorbed gas was formulated and solved to simulate the periodic, adsorption process. The measured nitrogen content of the product gas stream was found to correlate with the ratio of the product gas rate to the feed gas rate.At 24°C. the calculated pressure response, feed gas flow rate, and product gas composition correspond favorably with related experimental measurements for all values of the feed gas pressure, cycling frequency, and product gas flow rate within the ranges investigated.
    Additional Material: 11 Ill.
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