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  • GEOPHYSICS  (426)
  • Chemical Engineering  (301)
  • PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR  (301)
  • 1965-1969  (1,028)
  • 1965  (1,028)
Collection
Publisher
Years
  • 1965-1969  (1,028)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 54-58 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The diffusion of carbon dioxide through ethanol-water, benzene toluene, and carbon tetrachloride benzene was studied over the entire range of compositions for the solvent pairs. The results were interpreted in terms of an effective binary diffusion coefficient. Two semiempirical correlations were derived with the aid of absolute reaction rate theory to predict the effective binary diffusion coefficient from the binary diffusion coefficients of the solute in the individual pure solvents. These equations, although only crude approximations, reproduced the experimental data for six diffusion systems fairly well, including the highly nonideal solvent mixture ethanol-water.
    Additional Material: 1 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 73-79 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Studies of the air oxidation of aquoeus sodium sulfite solutions were made in simple bubble contacting columns of 3-, 4-, and 6-in. diameter. Superficial gas rates up to 300 lb./hr.-sq.ft. were used. Contacting action is described in detail, and comparisons with air-water data show the marked influence of small, ionic bubbles. Mass transfer and dynamic gas holdup data are presented, and the former are compared with mass transfer data for bubble-cap trays.
    Additional Material: 11 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 85-95 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis of the stability of a packed-bed reactor is presented subject to a model including axial and radial gradients in the interparticle field and gradients plus reaction in the intraparticle field. The stability of the entire reactor is characterized in terms of various stable and unstable conditions inside the porous particles. Simplifications in the mathematical model are shown to be invalid in many situations.
    Additional Material: 10 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 138-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: If air flows concurrently with a liquid, there are critical air velocities above which two-dimensional and three-dimensional waves appear at the interface. The physical process responsible for these transitions is as follows: The disturbance in the velocity field in the air caused by these waves gives rise to pressure and shear stress variations over the wavy surface. Pressure variations in phase with the wave slope and shear stress variations in phase with the wave height transmit energy from the air flow to the liquid film. If the rate at which energy is transmitted to the waves by these mechanisms is not larger than the rate of viscous dissipation in the liquid, the waves will decay.The model of the gas flow proposed by Miles and Benjamin is used to calculate shear stress and pressure variations over the wavy surface. The agreement between predicted and measured critical air velocities, wave lengths, and wave velocities is good.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 164-167 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized method has been developed for the prediction of the diffusivity and thermal conductivity of nonpolar gases for temperatures up to 10,000°K. This method is applicable to monatomic gases and to diatomic gases existing in their molecular and dissociated states. Dimensional analysis has been used to obtain relationships for self- and mutual diffusivities and for the translational contribution to the thermal conductivity of these substances. For the internal contribution to thermal conductivity, a modified Eucken-factor relationship is presented. Furthermore, relationships have been developed for the calculation of these transport properties for the equilibrium mixture of a dissociating gas.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 29-33 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 41-45 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work utilizes the developments of the foregoing paper (10) to analyze adsorption data, in the form of breakthrough curves, for ethyl alcohol on silica gel at 90° to 155°C. It was found that for the smallest particle size, and in the lower part of the temperature range, the overall rate was determined by the surface adsorption process. At other conditions intraparticle diffusion was also a significant resistance in the overall process. The theoretical breakthrough curves agreed well with the experimental ones, so that the surface rate constant and diffusivity could be calculated.Analysis of the diffusivity results showed that surface migration on the pore walls was the predominant contribution rather than gas-phase diffusion in the pore volume.
    Additional Material: 6 Ill.
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  • 8
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 59-64 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental equipment to study the film boiling of liquid nitrogen on a porous heat source with vapor suction was developed. The electrically heated element was a 3.69 in. sintered stainless steel screen, which was also used as a resistance thermometer in conjunction with an a.c. potentiometric circuit. In preliminary work, this mode of heat transfer was unstable, but stability was achieved by placing a porous flow control element on the liquid side of the heater. It was found that the Nusselt number was a function of only the Reynolds number; the heat transfer coefficient was increased by a factor of as much as 2.5 over the heat transfer coefficient in normal film boiling; it was possible to vary independently any two of the three variables, heat flux, flow rate through the plate, and temperature difference; and the generated vapor was considerably superheated. Fluctuations in the local surface temperature were measured in film boiling from both porous and nonporous flat plates, indicating that momentary solid-liquid contacts can occur, for all practical purposes, in film boiling.
    Additional Material: 9 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 96-99 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The experimental procedure for determining the initial hydrate formation conditions along the univariant gas-water rich liquid-hydrate locus through the measurement of equilibrium pressures and temperatures alone in a constant volume system has been successfully applied to several binary gas mixtures with water to pressures as high as 15,000 lb./sq. in.The general hydrate theory of van der Waals and Platteeuw, after appropriate modifications, was found valid for the accurate prediction of the initial hydrate formation conditions for selected mixtures of argon-methane and argon-nitrogen.The calculated methane-argon compositions in the hydrate phase are presented as a function of the methane-argon composition in the gas phase on a water-free basis but were not verified experimentally.
    Additional Material: 6 Ill.
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