ALBERT

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Quanxi Zhang , Jingjing Tian , Yunlong Bai , Zhenhua Yang , Huifang Zhang , Ziqiang Meng The present study was designed to investigate the mechanisms underlying the effects of SO2 on functions of the isolated perfused hearts in rats. The results suggest that both SO2 and SO2 derivatives (sulfite: bisulfite, 3:1, M/M) elicited a negative inotropic effect. At high concentrations, the effects of SO2 or its derivatives on heart functions might be related to the increasing of reactive oxygen species (ROS) contents and decreasing of ATPase activities as well as the potentially damaging effects on the hearts; while at low concentrations, SO2 or its derivatives might modulate heart functions mainly through the NO signal transduction pathway.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Lei Li , Xinqiang Shen , Yunlong Wang , Hang Jiang , Mei Jiang The toxicity effects of Alexandriurn minuturn and Gymnodiniurn on the embryonic development of Sparus macrocephalus were tested through the toxicological experiments about hatching spawns and developing larvae of Sparus macrocephalus . Alexandriurn minuturn and Gymnodiniurn solution was diluted into three groups (about 3000cell/ml, 1500cell/ml, 500cell/ml). The results showed that the hatch of the spawns was sensitive to both kinds of the algae. And the toxicity results from Alexandriurn minuturn were inferior to that from Gymnodiniurn . The test of larvae 96-LC50 showed that, larvae was more susceptible to the Gymnodiniurn and produced certain resistance to the toxicity of the algae. Both the Alexandriurn minuturn and Gymnodiniurn restrained body length and weight increase as well as ATPase and GSH-PX enzyme activities of the larvae, while restrain from Gymnodiniurn was stronger. In conclusion, the effects on growth and development of Sparus macrocephalus spawns and larvae resulted from Gymnodiniurn was much higher than that from Alexandriurn minuturn .

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Xiaodong Ding , Shirong Zhang , Shuyi Li , Xinrong Liao , Rongping Wang To test the hypothesis that exogenous silicon (Si) would mediate the detoxification of Chromium (Cr) on pakchoi ( Brassica Chinensis L.) growing in Cr-contaminated soil, a pot experiment that 0, 50, 100 and 200 mg·kg -1 Cr (Na 2 Cr 2 O 7 2H 2 O) were supplied to soil together with 0, 0.5, 1.0 and 1.5 g·kg-1 Si (Na2SiO3) for 48 days, was studied. Results showed that supplying Si improved the growth of pakchoi in low Cr level. However, the shoot dry weight decreased with the increasing Si supplied in high Cr level. Compared with under non-Cr stress, the application of Si significantly increased the activities of POD, SOD and CAT of pakchoi under excess Cr. However, antioxidant enzymes activities displayed no difference under three Cr levels supplied. Shoot Cr accumulation decreased, while root Cr concentration increased, which was ascribed to the formation of precipitation-bound, “organic matter bound” Cr and the reduction of exchangeable-bound Cr fractions in the soil. Furthermore, the rhizosphere soil pH increased with Si level under either Cr level, suggesting that exogenous Si would induce the alkalization in the rhizosphere mediated detoxification of Cr on pakchoi by promoting the formation of precipitation-bound, organic matter bound Cr in Cr-contaminated soil, thereby probably decreasing Cr uptake from Cr-contaminated soil. These results proved direct evidence that Si played a mediated role, which decreased Cr uptake and improved the stabilization of Cr in Cr- contaminated soil.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Shuyi Li , Shirong Zhang , Xiaodong Ding , Xinrong Liao , Rongping Wang A field experiment of foliar application of silicon sol, cerium sol and silicon-cerium composite sol of different concentrations on Lettuce in field mildly combined Cd/Pb contaminated soil, was conducted to study effects of the application on yield, quality, antioxidant enzymes (SOD, POD) activities and Cd/Pb absorption, and hence to determine optimum concentration of the silicon sols and cerium sols to be sprayed for relieving toxicity of Cd/Pb. Results showed that spraying silicon and cerium sols could promote growth of Lettuce, increase contents of vitamin C and soluble sugar, and reduce nitrite content, enhance activities of SOD and POD, and inhibit the absorption of Cd/Pb and decrease the content and accumulation of Cd/Pb in shoots and roots, and reduce the risk of Cd/Pb to human body through food chain, while spraying silicon-cerium composite sol of 0.50 g·kg -1 silicon sols (SiO2) and 0.20 g·kg -1 cerium sols (CeO 2 ) was the most significant in effect.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Fayun Li , Guoqiang Wu , Shui Hu , Zhiping Fan , Qun Gao The negative effect of deicing salt on surface water have been reported by a number of studies, but there is a lack of knowledge about the effects of deicing salt on the growth behavior and the change of biochemical composition of algal Chlorella vulgaris ( C. vulgaris ). Algal were cultured at different concentration of deicing salt, algal cell densities, chlorophyll (a), protein and polysaccharides contents were measured. The results of this work showed that deicing salt had statistically significant inhibitory effects ( P 〈0.01) on the cell growth of algae, and the best-fit predictive equation of algal cell densities ( D algal, algal cells m/l) versus concentration of deicing salt ( C salt, g/l) after 7- day culture in this experiment was presented as a quadratic equation with C salt being the independent variable and D algal being the dependent variable (R 2 =0.944, P 〈0.01). The contents of chlorophyll (a) in C. vulgaris cell exposed to different concentrations of deicing salt suggested that the chlorophyll (a) content significantly decreased ( P 〈0.05) with the concentration of deicing salt higher than 4 g/l. Deicing salts also caused the trend of proteins contents decrease in C. vulgaris cells, and significantly increased ( P 〈0.05) the contents of polysaccharides in algae cell at 2 g/l deicing salt, however, the change of that was not significantly affected at deicing salt concentrations higher than 2 g/l.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Zhenhua Yang , Yuexia Zhang , Quanxi Zhang , Tianxing Pei , Ziqiang Meng A number of studies on sulfur dioxide (SO 2 ) in toxicology and pharmacology have been reported, however spectral properties of SO 2 and its derivatives were seldom investigated. We investigated the absorption spectra of SO 2 , sodium sulfite (Na 2 SO 3 ), sodium bisulfite (NaHSO3) and sodium metabisulfite (Na 2 S 2 O 5 ) in aqueous solution. In the meanwhile, the effects of HCl on spectral properties of SO 2 and its derivatives were also investigated. We found that gaseous SO 2 in ethanol, n-butyl-alcohol and glycerol had a characteristic absorption peak at 276 nm. Na 2 S 2 O 5 and NaHSO 3 exhibited an absorption peak at 257 nm. Absorption of SO 2 at 276 nm was strongly enhanced in the presence of HCl. NaHSO3, Na 2 SO 3 and Na 2 S 2 O 5 also exhibited absorption at 276 nm with the addition of HCl, which was enhanced with the increase of HCl concentration. Importantly, two conclusions have been reached on the basis of our results. First, we attributed the absorbing power of SO 2 to SO 2 molecule, rather than hydrated sulfur dioxide. Second, absorption of SO 2 strongly enhanced by HCl at 276 nm was due to H + , instead of the formation of a complex SO 2 Cl-. Primary studies also indicated that NaHSO 3 and Na 2 S 2 O5 with HCl had a similar effect as SO 2 did in rat thoracic aortic rings, which prompted us believe that NaHSO3 and Na2S2O5 with HCl may be acted as a donor of SO2 in biology and other area.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yuexia Zhang , Zhenhua Yang , Dan Guo , Hong Geng , Chuan Dong In the study, we present the results of thermodynamic simulation of CaSO4 water-salt systems containing Ca 2+ , Mg 2+ , Na + , K + and HCO - 3 at 37°C. The results showed that the solubility of CaSO phase increased with increasing NaCl as wells as KCl concentration in the range of 0.0 to 2.0 M and 0.0 to 1.0 M, respectively. Remarkably, enhanced effect of MgCl 2 on the solubility of CaSO 4 phase was much larger than that of KCl or NaCl. The only exception was CaCl 2 , which was found to reduce solubility value of CaSO4 in aqueous solution at 37°C with the increase of CaCl 2 concentration. Also, the solubility of CaSO4 phase in mixed salt solutions was investigated at 37°C. The common ion effect was the main factor on the solubility of CaSO 4 in the mixed salts solution. Furthermore, CaSO 4 solubility was reduced by small amounts of NaHCO 3 in mixed solutions. These studies are of relevance in the estimating the changes of various salts in blood plasma and production of salt with low impurities of Ca2+ and SO 4 2- ions, as well as estimating oceanic-containing CaSO 4 uptake of CO 2 .

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Huimin Zhao , Hongtao Wang , Xie Quan , Feng Tan Tetracycline (TC), a widely used broad spectrum antibiotic, is excreted to environment seriously. Because of its harmful effects, it is essential to establish an effective method for TC determintation. In this work, we fabricated an electrochemical sensor for TC detection based on molecularly imprinted technique. The molecularly imprinted polymer was thermalpolymerized on Ti substrate electrodeposited with micro-nano Pt cluster (MIP-Pt/Ti). The linear range was in a TC concentration range from 0.1 to 10 mg L-1, and the detection limit was 0.026 mg L-1 (S/N = 3). The current change of TC on MIP-Pt/Ti electrode was 10 and 14 times than that of CTC and CAP, respectively. The results indicated that this electrochemical sensor exhibited good sensitivity and selectivity for TC.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Hongbo Xu , Wanping Zhang , Xiaoshun Zhang , Jing Wang , Jian Wang A new cloud point extraction procedure was established for the simultaneous preconcentration and determination of cobalt(II), nickel(II), and copper(II) ions in water samples. After complexation with 2-(5-bromo-2-pyridylazo)-5- (diethylamino) phenol (5-Br-PADAP), the analytes could be competitively extracted in a surfactant octylphenoxy polyethoxyethanol (TritonX-114), prior to determination by flame atomic absorption spectrometry (FAAS). The effects of pH, the concentrations of chelating agent and surfactant, equilibration temperature and time, sample volume, etc on CPE were studied. The preconcentration factor obtained was 25 and the limits of detection (DL) obtained for cobalt(II), nickel(II), and copper(II) were 2.4, 1.7 and 1.5 ng·mL−1, respectively. Standard reference material of poplar leaf (GBW 07604) was analyzed by the proposed methods, giving results of cobalt(II), nickel(II), and copper(II) found contents in consistency with the standard values. The presented preconcentration procedure was successfully applied to determination cobalt(II), nickel(II), and copper(II) in water samples.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Duanping Xu , Changjian Gu , Xiao Chen Humic acid (HA) was isolated from lignite. Flocculent HA was made and used to adsorb and remove dye acid red 3R from aqueous solution. The adsorption experiments were carried out in a batch process to observe the effect of various parameters such as contact time, dose of flocculent HA, ionic strength (NaCl) as well as adsorption kinetics and isotherm. Results showed that adsorption of acid red 3R on flocculent HA could reach equilibrium at less than 180 min. The adsorption kinetics obeyed the pseudo-second order model (R2=0.994). The adsorption was described with Freundlich equation on the basis of value of regression coefficient (R2=0.984). The removal rate of the dye increased with the increase of the dose of flocculent HA, while it decreased with the addition of NaCl in the aqueous solution. These suggested that the adsorption mechanism was the electrostatic attraction, to form hydrogen bonds, and van der waals’ force between molecules of HA and acid red 3R. Conclusion was made that flocculent HA isolated from lignite could be used as an adsorbent to remove the dye from aqueous solution.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Shouliang Huo , Zhuoshi He , Jing Su , Beidou Xi , Chaowei Zhu Artificial neural network (ANN), a data driven modeling approach, is proposed to predict the water quality indicators of Lake Fuxian, the deepest lake of southwest China. To determine the non-linear relationships between the water quality factors and the eutrophication indicators, several ANN models was chosen for the investigation. A commonly used back-propagation neural network model was used to relate the key factors that influence a number of water quality indicators such as dissolved oxygen (DO), total phosphorus (TP), chlorophyll-a (Chl-a), and secchi disk depth (SD) in Lake Fuxian. The measured data were fed to the input layer, representing forcing functions to control the in- lake bio-chemical processes. Eutrophication indicators such as DO, TN, Chl-a and SD were represented in the output layers. The results indicated that the back-propagation neural network model performs good in ten months prediction and the neural network is able to predict these indicators with reasonable accuracy. This study also suggested that the neural network is a valuable tool for lake management.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yiran Du , Bo Gao , Huaidong Zhou , Xinxin Ju , Hong Hao , Shuhua Yin Due to the continuous urbanization and industrialization in many countries of the world, heavy metals are continuously emitted into the terrestrial environment and pose a great threat on human health. A detailed study was conducted to determine the concentrations of six heavy metals (Cr, Ni, Cu, Zn, Cd and Pb) in road dusts in urban parks of Beijing, and assessed the health risk of these metals for local people. The dust samples were collected from 13 different urban parks in Beijing, China. The health risk was assessed using Hazard Quotient ( HQ ) and Health Index ( HI ). The results show that the average concentrations of Cr, Ni, Cu, Zn, Cd, Pb in the dust samples are 69.33, 25.97, 72.13, 219.20 0.64 and 201.82 mg/kg, respectively. The concentrations of Cu, Zn, Cd and Pb were much higher than those in the background value of Chinese soil. The assessment of health risk indicated that there were mainly three exposure pathways for people: ingestion, dermal contact and inhalation. The main exposure pathway of heavy metals to both children and adults is ingestion. The values of HQ and HI are lower than the safe level (=1), indicating no health risk exists in present condition. Meanwhile, the HI value for children is higher than that for adults, indicating that children have higher potential health risk than adults in Beijing parks.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Juan Chen , Yuanbo Xie , Wei Li Energy consumption leads to air pollution, which is a great threat to residents’ health. According to the requirements of energy and environment during “12th Five Year” period in Beijing, this paper set two different energy-constraint scenarios, applying an integrated energy-environment-health model to quantitatively evaluate Beijing's residents’ health damage caused by energy consumption. The results showed that: compared with low-constraint scenario, up to 2015, the high-constraint scenario can reduce totally 6501 cases of mortality, in which 1200 cases are related to SO2; 2489 cases are related to NOX; 1693 cases are related to PM10; 1119 cases are related to PM2.5. Therefore restricting energy consumption and improving energy structure are conductive to the reduction of atmospheric pollutants and the protection of population health.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Shuming Ma , Shushen Zhang , Yu Chen , Hongbo Zheng To meet the practical deficiency in the management of major environmental risk source, one of key issues in environmental management, especially in China, a major environmental risk source management system was developed based on the technology of ArcGIS Engine, .NET, and Oracle. The system used a C / S structure. Three function modules were designed. They are basic environmental information management module, enterprise risk source reporting module and risk source audit & management module. The system was applied to Da Gushan Peninsula, China.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yuan Qin , Yi Wang , Huiqiong Wang , Jinsuo Gao , Zhenping Qu The dynamic adsorption/desorption behavior of VOCs (C7H8) was evaluated for mesoporous SBA-15 silicas with four kinds of morphologies and pore sizes on a fixed bed unit. The SBA-15 silica with interconnected rodlike morphology exhibited exceptionally good breakthrough behavior, a higher adsorption capacity, and better desorption performance for toluene. The large dynamic VOC capacity of the interconnected rodlike silica was attributed to the pore system of the micropores and mesopore size, group-togethering rods which can aggregate to enhance the ability of adsorption, together with the smoother surface.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yaxin Su , Liming Ren , Wenyi Deng Waste tire powder was used to reduce NO emission by reburning and burnout in a two-stage furnace with simulated flue gas. Ceramic tubes were used as the flow reactor. The reburning temperature was 1150 °C and burnout temperature was 1250 °C respectively. The simulated flue gas consisted 16.8% vol. CO2, 1.95% vol. O2, and 0.05% and 0.08% vol. NO in a helium base. 4 kinds of ashes were used to abate the reburning intermediate products, HCN and NH3 in order to improve the final NO reduction efficiency after burnout. Resutls showed that waste tire was very good reburning fuel. More than 95% NO reduction efficiency was achieved after reburning of waste tire when the stoichiometric ratio for reburning, SR2, was 0.9. When waste tire powder was mixed with lignite ash collected by baghouse at power plant and used as reburning fuel, the final NO reduction efficiency after reburning and burnout was as high as 86%, which was very close to that of natural gas. Further test showed that lignite ash could effectively reduce HCN and NH3 during reburning. The present research demonstrated that waste tire is a very effective reburning fuel.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Jinlong Yan , Guixiang Quan , Cheng Ding The effects of heavy metals contamination on soil are quite alarming and can cause huge disturbances in the ecological balance and health of living creatures on earth. Effects of the heavy metals combined pollution of lead (Pb 2+ ) and cadmium (Cd 2+ ) cations on soil urease activity and nitrification were studied by soil incubation method to evaluate whether there is a synergistic interaction on soil enzyme activities, nutrient cycling and pollutants. Results showed that activated effect on soil urease activity was found only in the low concentrations (such as 0.5 mg/kg Pb2+ and 0.5 mg/kg Cd2+ combined) than the control, and the inhibitory effect was existed in most of the higher concentrations ( P 〈 0.05). With the increasing of Pb2+ concentration in soil from 0.5 mg/kg to 100.0 mg/kg combined with 0.5 mg/kg of Cd2+, the soil urease activity decreased and varied as the incubation proceeded. At the same time, soil nitrification was also inhibited in a certain degree with the threat of heavy metals contamination, and the nitrifying activity in contaminated soil samples were significantly lower than the control. A statistical analysis indicated that there were some correlations between the inhibition of soil urease activities and nitrification.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Shuang Li , Wenhua Song , Minling Gao This study chose the propiconazole and nano-zinc oxide of different particle size as the study object. The single and combined toxicity on the mouse embryonic fibroblast cell (NIH/3T3) was researched. The results showed that the cell growth was inhibited by propiconazole and nano zinc oxide of different concentrations, and it presents a dose- response relationship. When the two substances are combined, the combined of nanoscale particles produces the antagonism effect, and the combined of micron scale particles could generate synergy effect.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yuying Dong , Jing Wang , Ling Ding , Yaoye Liu There is little information about the influence of organic solvents for low water-solubility compounds on Photobacterium phosphoreum toxicity test, though it appears likely that much of data were obtained by using solutions prepared with the cosolvents or surfactants. In this study the influence of five stock solvents, including dimethyl sulphoxide (DMSO), acetone, aether, ethanol, tetrahydrofuran, on Photobacterium phosphoreum toxicity test were measured and different effective concentration (EC) values were obtained. DMSO was selected as the most suitable solvent of chemical compounds with low water-solubility according to its good characters and less toxicity effect to Photobacterium phospherum . Chlorobenzene and nitrobenzene, whose toxicity can be detected even if without any solvent, were selected to testify the effect of DMSO to toxicity of chemicals to Photobacterium phopherum . It was demonstrated that DMSO (its concentration no more than 0.20mol·L-1) had little effect on the toxicity of organic chemicals with EC value no more than 10%. The successful application of DMSO used as cosolvent provides a good example and a good idea to improve traditional acute toxicity test of Photobacterium phopherum .

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Gary R.W. Denton , Sara Namazi Radon (Rn) is a naturally occurring, radioactive gas that impacts air quality world-wide. It is a known carcinogen and considered by the United States Environmental Protection Agency (U.S. EPA) to be the second leading cause of lung cancer after tobacco smoking. Of several known isotopes of radon, 222 Rn is the most stable with a half-life of approximately four days. This particular isotope is associated with the uranium ( 238 U) decay series and accounts for most public ionizing radiation exposures. Most global indoor 222 Rn emanates from granitic bedrocks located underneath buildings. While such rocks are absent on Guam, the karst limestone formations that overlay the island's basement volcanics (basalt) are of biogenic origin and are believed to be a significant source of radon. In a recent multi-year survey conducted on Guam by the local EPA, indoor 222 Rn levels exceeded the U.S. EPA air quality standard of 4 pCi/L in ~40% of all buildings tested. Concentrations were log-normally distributed and exceeded 300 pCi/L in two instances. Weighted average indoor 222 Rn levels were generally much higher in villages from the northern half of the island where limestone coverage predominates. The relationship between 222 Rn and lung cancer incidence on Guam was examined in the study reported here. The results were strongly suggestive of a hormetic effect existing between the two variables. Possible confounding effects attributable to smoking and ethnicity were examined and found to be insignificant. In fact, ethnic groups predominantly confined to the northern half of the island (i.e., Filipinos and all other Asians as a collective group) showed considerably lower cancer incidence and mortality rates than the indigenous Chamorro people who are well represented island-wide. The findings of the study lend further weight to numerous other reports that suggest low-level exposures to 222 Rn have a beneficial health effect. They also support a growing critique of the rationale behind the U.S. EPA adopted linear-no-threshold toxicological model, which assumes that any dose of radiation is harmful, no matter how small. Finally, they also imply that the current U.S. EPA action level of 4 pCi/L for indoor radon is overly conservative and needlessly prompting homeowners to install radon mitigation systems into buildings that really don’t need them.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yingkui Zhao , Susan B. Marriott Metal mining used to be a major source of heavy-metal contamination for river systems and in England and Wales affected areas exceed 4000 km2. Under flooding conditions, heavy metals stored in riverbeds and floodplains can be remobilised and become secondary sources of diffuse pollution. During remobilisation, heavy-metal species and their association with soil/sediment particles have been changed. This paper investigates heavy metals in floodplain sediments of the River Severn, UK. Four floodplains representing the upper catchment (Caersws), the middle reaches (The Burf and Berwick Farm) and the lower catchment (Tewkesbury Ham) were studied for the concentration and distribution of Pb, Zn, Cu, Co and Cd and their associations with sediment particles. In the floodplain sediment from Caersws, heavy metals are associated with sand-sized particles and are in the form of native metals. With increasing distance downstream, these particles are broken into smaller fragments and heavy metals are released into the system where they combine with finer particles and are deposited on floodplains downstream during flooding. The highest concentrations of Pb are in the floodplain sediment at Caersws and the concentration decreases downstream due to “dilution” by local sediment supply and fragmentation. Across the floodplain, heavy metals are deposited adjacent to the present channel in the upper reaches, but are deposited in localities further away from the channel on the other floodplains further downstream, reflecting the fact that heavy-metal association with sediment particles controls their distribution. Concentration of heavy metals along vertical profiles increases first and then decreases with depth with peak values reached at varying depth between profiles. This pattern of variation along profile reflects the history of heavy metal accumulation, which is determined by the rate of heavy metal release from mining sites upstream. Although the varying depth that peak value reaches at different profiles is affected by translocation and hydroperiod, it still corresponds with the change of historical mining output upstream and can be used to calculate the sedimentation rate of floodplain surfaces.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Kazumi Akimoto , Kiyoshi Takikawa , Koichi Yakita , Takaomi Hokamura , Yukihide Shimasaki , Keisuke Mori , Izumi Sakamoto , Yoshiyuki Takino The purposes of this study are to understand mercury accumulation and diffusion based on topographic, sedimentologic, and biologic information obtained by acoustic equipment and an ROV after dredging in Minamata Bay and Yatsushiro Sea. Differences in contrast of acoustic reflections made clear the sediment distribution and the ROV investigation provided the vertical distribution of the biota and substrate. Rocks and blocks are distributed above 5 m water depth, coarse sand with rich molluscan fragments between 5 and 12m, and mud below 12m, with these sediments controlling the biota. The video shows that many depressions by ray's predation are distributed on sandy bottoms and burrows of benthic organisms on muddy bottoms. These facts suggest the possibility that a supply of mercury-free sediment moves from the sub-surface to the surface by burrowing, that mercury is concentrated by the benthos inhabiting the sediment surface, and that diffusion occurs by the predation of nekton.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Beibei Liu , Dong Qu , Xin Chen , Qinfen Li , Lixu Peng Chemical fraction plays an influential role in solubility and potential bioavailability of heavy metals in soils. Seasonally flooding and iron reduction are significant environmental processes of paddy soil. They may influence the fractionation of cooper (Cu) in paddy soil. In this study, an anaerobic incubation experiment was conducted to simulate the anaerobic environment of flooded paddy soil. The fractionations of native and spiked Cu in paddy soil were determined using a modified sequential extraction procedure (SEP) method. The effects of flooding time on Cu fractions were determined. The effects of ferrihydrite on Cu fractions were also investigated to understand the interaction between Cu contamination and iron reduction process. The results showed that the native Cu in soil were most in the residual and organic matter fractions, but the more available fractions, such as, the exchangeable and carbonates fractions occupied only a little proportion. After flooding, the native Cu in soil released from organic matter fraction and crystalloid ferric oxides fraction, and transferred to the easy extracted fractions, such as, amorphous ferric oxides, carbonates and exchangeable fractions. The spiked Cu was easily absorbed by carbonates and organic matter in soil, but after flooding, the two fractions transferred into ferric oxides fraction, especially amorphous ferric oxides fraction. Similar phenomena were observed after adding ferrihydrite in soil except for the disposal of added 400 mg/kg Cu. The process of iron reduction was inhibited significantly by Cu contamination and the inhibition of Cu contamination to iron reduction decreased after adding ferrihydrite. The transformation of Cu fractions had significant relation to the process of iron anaerobic reduction in paddy soil.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yoshihiro Deguchi , Zhen Zhen Wang , Jun Jie Yan , Ji Ping Liu Since the demands for lowering the burdens on the environment will continue to grow steadily, understanding of pollutant emission characteristics becomes more and more important to minimize environmental disruption. These pollutant emission conditions cannot be estimated in real-time using conventional mass-based methods because of their low concentrations in air or exhaust gases. Therefore, new evaluation criteria are required for better understanding of their characteristics. In this study, the laser breakdown time-of-flight mass spectrometry was developed and applied to hydrocarbons to detect the elemental composition of gas phase materials. The laser wavelength dependence of this method was evaluated using 1064 and 266 nm laser outputs. Signals from fragments of hydrocarbons appeared using 266 nm. On the other hand, it was found that the mass spectra of atoms can be detected using the 1064 nm laser breakdown process without intermediate fragment signals. This feature is important to detect atomic signals of the measured materials without the interference of fragmentations. The pressure effect was also evaluated to enhance the detection limit. The higher pressure tends to induce the higher atomic signals. The detection limit can easily reach to ppb or less. The signal intensity was proportional to the concentration of hydrocarbons introduced. The method was applied to various hydrocarbons and the breakdown characteristics of these molecules were taken for the quantitative analysis. Compared with conventional measurements, this method has a lot of merits of the simple signal analysis, real-time and sensitive detection features. The method can cover various industrial applications including the exhaust analysis of combustors, environmental monitoring of air, and plant monitoring for safety and security.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Duoxi Yao , Zheng Chen , Kui Zhao , Qing Yang , Wenying Zhang Nanotechnology is a new booming science, which has leaped huge significant achievements for only short dozens of years, and created so much wealth for human beings. Their usages on environmental security have been ignored by public, however, multiples of evidences have been demonstrated nano-materials would perform different influence upon a variety of organism. Here, this article concerns that situations and challenges to separate or detect the nano- particles contained in the products or the environment. Meanwhile, a case was presented to introduce an available approach to prepare the nano-colloid (nano-TiO2) for environmental risks research. Therefore, it's necessary for the relevance authorities to formulate effective or available detections upon nano-materials. And the key point should be focused on the normalization of nano-materials control and the establishments on environmental risk assessment upon nano-materials, which will finally promote the developments on the fields of nanotechnology.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): K.G. Rosin , Ravinder Kaur , S.D. Singh , P. Singh , D.S. Dubey Pollution of groundwater due to industrial and municipal wastewaters is of a rising concern in many cities and industrial clusters of India. Faridabad - a peri-urban agricultural area is one such industrial site in district Haryana, India. The primary aim of this investigation was, to assess extend of ground water contamination in the peri-urban agricultural sites around Faridabad, Haryana and to assess its contribution due to salt/trace metal laden agricultural irrigation waters. For this, a detailed survey on the farming practices, soils and surface/sub-surface irrigation waters of 30 spatially separated villages around study area was conducted. The surveyed information was used for estimating deep percolation loss, salt/heavy metal leaching and thus vulnerability of ground waters at each sample site to salt/heavy metals by means of a field scale decision support system - IMPASSE © . Analysis showed that the study area was saline (i.e., ECmean = 4.79 2.76 dS/m, Clmean = 2043.30 457.26 ppm and Fmean = 11.57 4.83 ppm). These salt affected agricultural lands were found to be irrigated with (good to marginally alkali) canal, (marginally alkali to alkali) drain and (good to alkali) tube well waters. As a result, the mean EC (2.85 0.85 dS/m), Cl (1227.85 remove-image>295.93 ppm) and F (6.26 2.12 ppm) concentrations in the root zone leachates from each test site, were found to be far beyond their permissible limits of 0.75 dS/m, 1000 ppm and 1.5 ppm. Even the soil root zone water soluble concentrations of some trace metals (viz., Cr: 0.06 0.00 ppm; Ni: 0.02 0.01 ppm, and Pb:0.05 0.01 ppm) were observed to be of some threat to the deep percolating waters. However, the vulnerability assessments indicated that due to existing cropping pattern and deeper water table depths, the study area ground waters were not yet vulnerable to these salts/trace metals in the root zone leachates, and that the presence of salts in the study area ground waters was primarily geogenic

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Kaimin Shih , Fei Wang With global distribution, persistence nature, and strong bioaccumulation, the fate and transport of perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) in natural environment have recently attracted strong attentions. As boehmite is a common form of hydrated aluminum oxide existing in soils and sediments, this study successfully revealed the adsorption behavior of PFOS and PFOA on boehmite and the influence from solution chemistry. The results of kinetic experiments show that the adsorption equilibrium can be achieved within 48 hours and the boehmite surface is generally receptive to PFOS and PFOA adsorption. The adsorption isotherms estimated the maximum adsorption capacities of PFOS and PFOA on boehmite to be 0.877 μg/m 2 and 0.633 μg/m2, respectively. The increase of pH can lead to a moderate decrease of PFOS and PFOA adsorption, owing to the increase of ligand exchange reaction and the decrease of electrostatic interaction. With the compression of electrical double layers, the competitive adsorption from the other ions and the Ca2+ bridging effect between perfluorochemicals have demonstrated their negative influence for PFOS and PFOA adsorption on boehmite surface. Finally, humic acid (HA) also showed significant retardant effects on the sorption of perfluorooctanesulfonate (PFOS) and perfluorobutanesulfonate (PFBuS) on boehmite.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Yanan Zheng , Xilai Zheng , Zengwen Gao , Yuxiang Zhang Based on the analysis of seawater quality monitoring data, the grey predication method (GM (1, 1) model) was used to predict seawater quality in the Rigs-to-Reefs area of the Chengdao oil field. The result shows that petroleum pollutants and dissolved oxygen concentration will take on an increasing tendency from 2011 to 2015, and heavy metal Hg and Cd will be still kept at a low level. In addition, COD concentration has been gradually decreasing. On the whole, the prediction results indicate that the seawater quality of Rigs-to-Reefs area accords with the second-class seawater quality standard (GB3097-1997) and meets the requirement of artificial reef construction.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Zrafi Ines , Bakhrouf Amina , Rouabhia Mahmoud , Saidane-Mosbahi Dalila Levels, composition profiles and sources of hydrocarbons were analyzed in surface marine sediment samples collected from Khniss Coast in Tunisia. The total Hydrocarbon (TH) concentrations ranged from 2280 μg/g to 7700 μg/g. The sedimentary non-aromatic hydrocarbon (NAH) and aromatic hydrocarbon (AH) concentrations ranged from 1020 to 2320 μg/g, and from 240 to 680 μg/g, respectively. The higher level of total concentration of 17 polycyclic aromatic hydrocarbons ∑17PAHs is equal to 14.59 ng/g. The PAH profiles showed that the ∑4–5-ring compounds were the major PAHs detected in the sampling sites. Characteristic ratios of Anth/(Anth+ Phe), and Flu/(Flu + Pyr) indicated that PAHs could originate from petrogenic and pyrolytic sources. Petroleum contamination associated with increased marine activity and high eutrophization statue in Khniss area which can have side-effects on the ecosystems and human safety, must be controlled.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Fanxiu Li Set pair analysis (SPA) is a new method to describe and process the system uncertainty and has been applied in many areas recently. In view of the uncertainty and complexity in the process of water quality evaluation of water supply networks, the paper introduced a new model-varying coefficient of discrepancy degree based on set pair analysis theory. In the model, a new effective method to the determination of discrepancy degree coefficient i is suggested. As an example, the paper evaluated water quality conditions of water supply networks from 3 monitoring spots by the model. The results of the assessment are in concordance with other evaluation methods. Compared with the other evaluation method, this model is perfect, the evaluating result is more reasonable and its resolving power is higher.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Adrian Spence , Claion Robinson Here we report on a spectro-chemical approach to investigate the adsorption of dissolved Cd ions to montmorillonite (M) in the presence of a mixed consortium of soil bacteria. Results indicate that the order of metal-loading was M- microbial complex > microbial biomass > M. Surface interactions of Cd with M-microbial complex have also been confirmed, and we speculate that after binding to M, additional proton binding sites on microbial cells function as binding sites for Cd ions thereby enhancing the metal binding capacity of the mineral. There is also evidence to suggest that hydrogen bonding, cation bridging and ion-exchange are important mechanisms in the adsorption of metal ions to clay-organo complexes.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Wanjun Fu , Guilan Ma 108 vegetable samples were collected from Jilin suburb vegetable production base, and Pb of samples was measured using graphite furnace atomic absorption spectrophotometer (GF- AAS). Results showed that the average Pb of vegetable was 0.06 mg·kg-1 fresh weight, with only 1.5% above the Safety Requirements. Single-factor contaminant index was utilized for assessment. It was found that vegetable Pb order as following: leaf vegetables>fruit vegetables, dark vegetables>light vegetables. The average daily intake (DI) Pb of per standard person was urban 21.6 μg •d-1 and rural 18.7 μg •d-1, as well as economical family 22.1 μg •d-1and poor 18.3 μg •d-1, indicating that vegetable Pb in Jilin suburbs were safety. The Pb health risk was assessed based on the target hazard quotients (THQ). The study showed that THQurban =THQhigh >THQmedium >THQlow =THQrural, indicating the health risk via vegetable consumption in rural was relative lower than that in urban area. Assessment results proved that the vegetables Pb in this area is no health risk to persons.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Xueqin Liao , Wei Li , Jinxiang Hou Coal accounts for more than 70% of total energy consumption in China. Kinds of ecological problems resulting from coal mining have become increasingly serious, which directly threaten regional ecological security and people's normal production and livelihood in some areas. Ecological vulnerability is the overall performance of the ecosystem change under mining development, thus evaluation of ecological vulnerability based on GIS in Fuxin mining master plan environmental impact assessment was presented in this article. According to ecological condition of Fuxin, the ecological vulnerability index was established synthetically reflecting ecological environmental status, ecological sensitivity and landscape spatial structure, including 9 indictors. The study area was divided into 247 grids, then the EVI value of each grid was calculated by comprehensive evaluation and the results were divided into 5 levels by Zonal Statistic analysis of ArcGIS. Combining the distribution of vulnerability classification with the important ecological function area and natural reserves in the scope of planning, the research area was plotted into five types of zone, i.e., appropriate exploitation zone, optimized exploitation zone, moderate exploitation zone, restrictive exploitation zone and forbidden exploitation zone. Several adjustment suggestions were put forward to optimize the layout of Fuxin mining area and guide the ecological protection during coal exploitation.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Mingda Liu , Yue Li , Wei Zhang , Yaojing Wang In this paper, we collected 295 soil samples from Chaoyang as the experiment material, then identify the concentration and spatial distribution of zinc (Zn) in agricultural soils on the basis of The integrated pollution index (IPI) and index geoaccumulation (Igeo). The concentration of Zn in soils of Chaoyang are from 22.787 to 669.597 mg kg-1,with an average concentration of 107.082 mg·kg-1. And results of the evaluation show that the pollution excess rate is 2.03%, which indicated that most of samples are slightly polluted. Compared two evaluation methods, integrated pollution index focuses on the evaluation of pollution results, the Geo accumulation index method is more accurate and objective.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Quanxi Zhang , Jian Zhang , Zhenhua Yang , Yuexia Zhang , Ziqiang Meng The aim of this study is to explore the association between PM2.5 (particulate matter with aerodynamic diameter less than 2.5 μm) and daily outpatient number for respiratory and cardiovascular diseases in a place where dust events are most frequent. During the study period, all hospitals in Wuwei, Gansu province, northwest of China were selected. The results suggest that there were associations between PM2.5 and the increasing of respiratory and cardiovascular diseases outpatient visits for males and females during the period when dust events frequently happen. PM2.5 was one of the main hazardous factors for these diseases during the study period.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Bo Chen , Shaobin Lin , Sheng Wu , Wenhua Li , Wenrong Chen Samples from Peifeng were studied to further investigate the influence of particle specific surface area, oil dosage, system energy input and the concentration of electrolyte on the cleaning of Fujian coal with oil agglomeration. The results showed that specific surface area of coal particles around 24m 2 g -1 led to the minimum value of ash content 3.14% obtained, and sulfur content decrease from 2.0% to 0.44%; After 10 min of stirring at 2400r min-1, the minimum product ash content 3.8% was obtained. Within the dosage range studied, considerable ash content reduction occurred with NaCl in appropriate concentrations used, in contrary, the other five other electrolytes would, to varying degrees, put a raise on ash content. No positive correlation was shown between product ash content and solid concentration, in fact, the former fell with the increasing of the latter within a certain range.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Zhen Zhen Wang , Yoshihiro Deguchi , Jun Jie Yan , Ji Ping Liu It has been highly recognized heavy metals pollution concerns the environment, as well as human health. Mercury (Hg) pollution has greatly increased and been considered as a global pollutant because of its long residence time in surrounding. This paper describes the rapid detection of mercury using laser breakdown time-of-flight mass spectrometry at high sensitivity without fragmentation interference from other species. Two irradiation wavelengths 1064 nm and 532 nm were employed under various experimental conditions. The second harmonic 532 nm performs excellent measurement results. The influence of pressure on mercury signal intensity displays a liner growth when increasing the pressure. These results also show as the laser power increased, nitrogen signal intensity increased, but mercury signal intensity increased first and then decreased. Experiment with different buffer gases clarified the recombination of Hg ions and electrons when increasing the laser power, resulting in the decrease of mercury signal intensity. According to these measurement results, the method of enlarging focus area and reducing laser power by tilting the focus lens was applied to decrease the recombination rate to enhance the detection limit. It is demonstrated that the detection limit with 1ppb can be acquired facilely.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Jing Yang , Ning Wang , Yafen Li The objectives of this study were to characterize the spatial distribution of Hg in topsoil at Jia-Pi-Gou(JPG), a centuried gold mine area, and to evaluate the Hg pollution risks. A total of 28 soil samples were collected by a stratified random sampling technique. Descriptive statistics and ANN were used to analyze the data. The results show that the mean value of Hg in the soil was 0.203mg·kg -1 , higher than Chinese Soil Environmental Quality Standard's soil quality standard. In the ANN figure the high concentrations of Hg are found in three main spots, two of which are gold mine and one of which is gold mine tailing and the three spots are the center of high concentration. The geo- accumulation index assessment shows that all farmland topsoil in JPG is contaminated by Hg, while different sampling sites are contaminated to different levels, among all 53.57% are beyond heavily contaminated.

Description: Publication date: 2013 Source: Procedia Environmental Sciences, Volume 18 Author(s): Ting Yao , Chunxiang He , Peng Zhang , Hui Gao , Chuanguang Zhou Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in surface water collected from the Jinzhou Bay in North China were analyzed using gas chromatography to reveal their horizontal distribution tendencies and trace their sources. Total PCB concentrations ranged from 215.4 to 3161 ng/L. The level of PCB in the opening of the Bay was higher than the inner Bay. The predominated components were 5- and 6-chlorinated PCBs, indicating these residual PCBs derived from paint additives. Total OCP concentrations ranged from 4.165 to 136.8 ng/L, whose isomer concentrations’ ratios implied the usage of technical HCH and lindane.

Description: Publication date: 2014 Source: Procedia Environmental Sciences, Volume 22 Author(s): Herman van Os , Rien Herber , Bert Scholtens The decision-making process for subsurface activities in the Netherlands has been unable to cope with the driving forces related to social acceptance in several recently proposed subsurface activities. We therefore investigated the possibility to include the triangle of social acceptance in the decision-making process. Our conceptual model relates the stakeholders, their goals and the driving forces to each other. We developed a framework, which describes the interaction between eleven design criteria for a Decision Support System (DSS). This framework will enable us to design a better, from a social acceptance perspective, DSS for subsurface activities in the Netherlands. Since the goals addressed in the decision-making process are very broad and the stakeholders are quite diverse, a single uniform DSS is not able to provide a satisfactory solution. We therefore suggest to design a DSS that is matched with each class of social acceptance.

Description: Publication date: 2014 Source: Procedia Environmental Sciences, Volume 22 Author(s): Yoshie Inada , Shinobu Izumi , Motoya Koga , Shigehito Matsubara We are developing a planning support system for welfare urban design. If we quantify the optimal route (the route that is the easiest to pass through) for challenged people, we will be able to select the areas that require adjustment in terms of accessibility with greater efficiency. In this paper we report on our development of the prototype system to present an optimal route for wheelchair users, and also, the two workshops we had for evaluating the accuracy of the resulted optimal route.

Description: Publication date: 2014 Source: Procedia Environmental Sciences, Volume 22 Author(s): Erfaneh Allameh , Mohammadali Heidari , Bauke De Vries , Harry Timmermans , Mohammad Masoud , Farhang Mozaffar Almost everyone would agree that teleworking is increasingly growing; but beyond this broad statement, we know little about how people behave when they work at home and how they balance their work and life. User comfort and productivity cannot be addressed properly, without a deep understanding of usersʼ working behavior. This gap is even deeper when it comes to the domain of smart homes as new types of housing which aim to enhance working at home. Hence, more user-centered studies are needed to comprehend the interrelationships among housing, technology, daily life and the work activities. In this paper, we use the outputs of an experiment to model usersʼ work activities in a smart home. The experiment was conducted among 254 respondents, who were asked to explore a smart home in a virtual environment and then to arrange their daily activities including work related activities in the virtual smart home. A choice modeling approach, based on the Multinomial Logit Model (MNL), is applied to model how an individual works at a smart home given influential factors such as the individualsʼ socio-demographic profile and their current lifestyle. Two features of working in a smart home are covered in this paper, namely, “the integration of work activities with other daily activities” and “the location of work activities in the house”. The results give better insight into the future trends of working at home and the effects of smart homes on working behavior of people. The results can be used in further developments of both smart homes and teleworking.

Description: Publication date: 2014 Source: Procedia Environmental Sciences, Volume 22 Author(s): Jinhee Kim , Soora Rasouli , Harry Timmermans Hybrid choice models have been developed as an extension of discrete choice models, particularly multinomial logit models, in an attempt to include attitudinal variables. The quintessence of hybrid choice models is that a model of attitude formation is estimated and the estimated attitudes are added to the commonly used set of attributes in discrete choice models: attributes of the choice alternatives and socio-demographic variables. The most commonly applied model is based on linear specifications, both for the attitude model and the utility function. In this review paper, we discuss the principles underlying the hybrid choice model, summarize the specifications used in previous applications of the model and then continue discussing recent progress that added social influence to the model specification and replaced the linear specification of the utility function with a nonlinear function.

Description: Publication date: 2014 Source: Procedia Environmental Sciences, Volume 22 Author(s): Yountaik Leem , Sang Ho Lee , Jungho Yoon To overcome many difficulties in sustaining the satisfying quality of life for a large population 1 , urban spaces are evolving toward more efficient spaces by combination with ICTs (information and communication technologies) and raising the possibility to provide improved urban services which can enrich the quality of life of the citizen. In many cities over the world, a good number of public and private services in transportation, environment, urban safety from crime or disaster, health and other fields are designed and implemented with IT infrastructure. In spite of the expectation of cost-effective urban services based on the linkage between data and systems, obstructions in administrative and technical domains have made it difficult to be implemented. In this study, two advanced ICTs based urban services, which were developed by linkage and convergence of urban information and systems of Korea were introduced and analysed. The structural design of system convergence and data sharing scheme of Carbon Emission Monitoring System (CEMS) in Sejong City uses UIS (Urban Information System for local authorities), GIS data and other data provided by the public agencies, such as Korea Meteorological Administration for the monitoring and analysing the characteristics of the energy consumption of household 2 . Another system, Urban Integrated CCTV Control System (ICCS) in Anyang City, shows integrated CCTV networks for crime prevention, traffic control and public facility management to provide extended urban services, such as disaster prevention, police investigation and others. Qualitative and Quantitative effects analyses with technical and policy directions were suggested for the development and improvement of future urban services for a liveable city.

Description: Global land acquisitions, often dubbed ‘land grabbing’ are increasingly becoming drivers of land change. We use the tools of network science to describe the connectivity of the global acquisition system. We find that 126 countries participate in this form of global land trade. Importers are concentrated in the Global North, the emerging economies of Asia, and the Middle East, while exporters are confined to the Global South and Eastern Europe. A small handful of countries account for the majority of land acquisitions (particularly China, the UK, and the US), the cumulative distribution of which is best described by a power law. We also find that countries with many land trading partners play a disproportionately central role in providing connectivity across the network with the shortest trading path between any two countries traversing either China, the US, or the UK over a third of the time. The land acquisition network is characterized by very few trading cliques and therefore ...

Description: Possible future changes of clustering and return periods (RPs) of European storm series with high potential losses are quantified. Historical storm series are identified using 40 winters of reanalysis. Time series of top events (1, 2 or 5 year return levels (RLs)) are used to assess RPs of storm series both empirically and theoretically. Additionally, 800 winters of general circulation model simulations for present (1960–2000) and future (2060–2100) climate conditions are investigated. Clustering is identified for most countries, and estimated RPs are similar for reanalysis and present day simulations. Future changes of RPs are estimated for fixed RLs and fixed loss index thresholds. For the former, shorter RPs are found for Western Europe, but changes are small and spatially heterogeneous. For the latter, which combines the effects of clustering and event ranking shifts, shorter RPs are found everywhere except for Mediterranean countries. These changes are generally not statisti...

Description: The 2012 drought in Northeast Brazil was the harshest in decades, with potentially significant impacts on the vegetation of the unique semi-arid caatinga biome and on local livelihoods. Here, we use a coupled climate–vegetation model (CCM3-IBIS) to: (1) investigate the role of the Pacific and Atlantic oceans in the 2012 drought, and; (2) evaluate the response of the caatinga vegetation to the 2012 climate extreme. Our results indicate that anomalous sea surface temperatures (SSTs) in the Atlantic Ocean were the primary factor forcing the 2012 drought, with Pacific Ocean SST having a larger role in sustaining typical climatic conditions in the region. The drought strongly influenced net primary production in the caatinga, causing a reduction in annual net ecosystem exchange indicating a reduction in amount of CO 2 released to the atmosphere.

Description: Peatlands in Amazonian Peru are known to store large quantities of carbon, but there is high uncertainty in the spatial extent and total carbon stocks of these ecosystems. Here, we use a multi-sensor (Landsat, ALOS PALSAR and SRTM) remote sensing approach, together with field data including 24 forest census plots and 218 peat thickness measurements, to map the distribution of peatland vegetation types and calculate the combined above- and below-ground carbon stock of peatland ecosystems in the Pastaza-Marañon foreland basin in Peru. We find that peatlands cover 35 600 ± 2133 km 2 and contain 3.14 (0.44–8.15) Pg C. Variation in peat thickness and bulk density are the most important sources of uncertainty in these values. One particular ecosystem type, peatland pole forest, is found to be the most carbon-dense ecosystem yet identified in Amazonia (1391 ± 710 Mg C ha −1 ). The novel approach of combining optical and radar remote sensing with above- and below-groun...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 112-121 Simon N., Gosling , Nigel W., Arnell , Jason A., Lowe We present simulations of the impact of climate change on global water scarcity for five greenhouse gas emissions mitigation policy scenarios and compare them with a business-as-usual emissions scenario. A global water scarcity model is driven by climate change projections from 21 global climate models (GCMs). An aggressive policy scenario that gives a 50% chance of avoiding a 2°C global-mean temperature rise from pre-industrial times could avoid almost 40% of the business as usual global impacts by 2100. However, mitigation policy does not completely eliminate the impacts of climate change. For any given GCM, the avoided impacts are affected more...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 136-145 Eleni, Karali , Mark D.A., Rounsevell , Ruth, Doherty Although there is a large body of research into complex land-use/cover change (LUCC), the mechanisms that underlie land transformation are still poorly understood. To a large extent this results from the limited attention that has been paid to the human dimension in LUCC studies. While environmental processes are described by detailed and sophisticated frameworks, human behaviour has often been theorised in oversimplified ways. This paper presents a novel approach to the analysis of rural LUCC that integrates agent-based models (ABMs) with a multi-phase social survey. Findings from the application of the latter to a farming area in Switzerland are used...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 146-152 Etsushi, Kato , Michio, Kawamiya , Tsuguki, Kinoshita , Akihiko, Ito In the preparatory phase of IPCC AR5 development, Representative Concentration Pathways (RCPs) have been constructed by Integrated Assessment Models (IAMs) groups as new forcing scenarios used for climate modeling and earth system modeling groups. In the process of RCP 6.0 scenario development, which has been conducted by the Asia-Pacific Integrated Model (AIM), we constructed a scenario of spatially explicit long-term aerosol emissions from biomass burning and net land-use change CO2 emissions in order to complement energy use and industrial emissions scenarios projected by socio-economic component of AIM.To estimate the emissions from biomass burning, we incorporate a vegetation fire component into...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 153-161 Nikolinka G., Koleva , Uwe A., Schneider , Bruce A., McCarl This study uses mathematical programming to examine alternative assumptions about regulations of external costs from pesticide applications in US agriculture. We find that, without external cost regulation, climate change benefits from increased agricultural production in the US may be more than offset by increased environmental costs. The internalization of the pesticide externalities increase farmers’ production costs but increase farmers’ income because of price adjustments and associated welfare shifts from consumers to producers. Our results also show that full internalizations of external pesticide costs substantially reduces preferred pesticide applications rates for corn and soybeans as climate change.

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 15-26 Muhammad, Afzal , Martin G., Mansell , Alexandre S., Gagnon The objective of this research is to analyse temporal changes in historic rainfall variability across Scotland using different measures of variability. The CUSUM and sequential Mann-Kendall test applied to records from 28 weather stations with up to 80 years of daily precipitation data reveal the occurrence of abrupt changes in the rainfall trends. Most weather stations show a turning point between 1978 and 1985, although some stations situated in Eastern Scotland have more than one turning point. The temporal changes in rainfall variability across Scotland are presented using a number of measures of variability.

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 96-103 Sarah, Cornell Nitrogen-containing organic matter in rain and aerosol makes up a substantial proportion – 25–35% – of the total nitrogen in atmospheric deposition. Despite this quantitative significance, it is “invisible” in current policy; and existing global air quality and nitrogen deposition monitoring programmes routinely measure nitrate and ammonium but not the organic component. Although recent research, especially in Asia and Latin America, is helping to build up a global picture of organic nitrogen deposition, data sets are sparse and the chemical composition of the organic matter is relatively poorly characterised. As a result, its role in ecosystems and Earth system processes...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 3-14 Cat, Downy , Sarah, Cornell

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 1-2 Sarah, Cornell , Cat, Downy ESS2010 was the first Open Science Conference of the international collaborative initiative AIMES, and was convened and organized by QUEST, the UK's directed research programme for Earth System science. The conference showcased advances in Earth system modelling, deploying observations and process understanding to develop more quantitative and predictive understanding of the interactions of the climate system, the biosphere and the anthroposphere. These tools extend understanding of the system dynamics of biogeochemical cycles, and give perspectives on the relationships between climate, ecosystems and human needs. As Earth system science is a global research endeavour, and its remit has important societal and...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 104-111 Simon N., Gosling , Jason A., Lowe We compare heat-related mortality impacts for three European cities, London, Lisbon and Budapest, under five climate change policies representing different dates at which carbon dioxide (CO2) emissions peak, rates at which emissions decline, and emissions floors, and compare them with a non-mitigation business-as-usual emissions scenario, for three time periods, the 2030s, 2050s and 2080s. Under an SRES A1B business-as-usual emissions scenario and using climate projections from 21 GCMs, heat-related mortality rates (per 100,000 of the population) attributable to climate change in the 2080s are simulated to be in the range 2-6 for London, 4-50 for Lisbon and 10-24 for Budapest....

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 122-135 N.J., Grigg , F., Boschetti , M., Brede , J.J., Finnigan We demonstrate an approach to low-dimensional modeling of world population, carbon dioxide (CO2) emissions and gross domestic product (GDP) interactions in a way that explicitly characterizes the variability in the data informing model assumptions and the uncertainty in functional relationships. Our model choice was informed by the following considerations and choices. First, even a low-dimensional conceptualization of the interactions between these three global variables requires a model to illuminate the consequences of chains of cause and effect and feedback loops. Such interactions warrant analysis as they offer insights into influences on aggregate global dynamics. Second, rates are constrained to be...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 60-69 Mohammad, Aurangojeb The relationship between particle number concentration and the established air quality indicators such as PM10 and NO2 is very important regarding the environmental quality of air. The results of this study revealed that correlation of the number of particles and NO2 depends on the mixing processes in the atmosphere, such as the formation of boundary layer and mixing layer. The diurnal variation of the correlation of the number of particles and PM10 is related to their sources and life times in an urban atmosphere. The effect of the wind speed and rainfall is strong in the correlation of NO2 and...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 35-49 M. de C., Alves , L.G., de Carvalho , E.A., Pozza , L., Sanches , J.C. de S., Maia Geoinformation techniques were applied to develop predictive models to study the areas of risk to soybean rust (Phakopsora pachyrhizi Sydow) in soybean (Glycine max L.); coffee leaf rust (Hemileia vastatrix Berk & Br) in coffee; and black Sigatoka (Mycosphaerella fijiensis var. difformis) in banana, considering Brazil's climatic characterization and the distribution of soybean, coffee and banana crops. Temperature and rainfall data were obtained for the period from 1950 to 2000, for which observational data are available, and of simulations for 2020, 2050 and 2080 using the SRES A2 climate change scenarios. Using principal components analysis, a single variable was generated...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 27-34 Akinori, Ito , Yan, Feng Iron is an essential nutrient for phytoplankton. Although iron-containing dust mobilized from arid regions supplies the majority of the iron to the oceans, the key flux in terms of the biogeochemical response to atmospheric deposition is the amount of soluble or bioavailable iron. Atmospheric processing of mineral aerosols by anthropogenic pollutants (e.g. sulfuric acid) may transform insoluble iron into soluble forms. Previous studies have suggested higher iron solubility in smaller particles, as they are subject to more thorough atmospheric processing due to a longer residence time than coarse particles. On the other hand, the specific mineralogy of iron in dust...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 70-87 Peter G., Baines An analysis is made of global sea surface temperature (SST) data sets over the past 110 years to determine the principal patterns of climate variability on time scales longer than ENSO, and to relate these to likely dynamical processes. Taking 5-year running means, the most recent versions of the interpolated global data from the UK Hadley Centre and the US NOAA are analysed using singular value decomposition, and described as coherent global patterns that have a physical/dynamical basis. These patterns are: Global Warming, the Pacific Decadal Oscillation, the Atlantic Multi-decadal Oscillation and the Pacific Gyre Oscillation. Each of these patterns,...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 50-59 C., Arcidiacono-Bársony , P., Ciais , N., Viovy , N., Vuichard Tropical deforestation is a major driver of climate change accounting for ∼12% of global anthropogenic CO2 emissions. A mitigation strategy named Reduction Emission from Deforestation and forest Degradation (REDD) has been developed to tackle emissions due to forest loss in developing countries. REDD will be the core instrument in any post-2012 climate agreement according to the final document of the 15th UN Conference of the Parties. Nonetheless, REDD's implementation presents several political and scientific challenges. A review of current and future deforestation estimates in terms of forest surface change, carbon densities, and carbon fluxes is under preparation to aid the...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 88-95 Sarah, Cornell Economics – specifically, monetary valuation – has been given a pivotal role in ecosystem conservation. This is a retrogressive step, undoing important sustainability principles and practices that should have been embedded in environmental policy and management action. The concept of ecosystem services is a useful framework for understanding the dependency of human society on its natural environment, but it needs to be part of a larger solution that recognizes the complexity of the socio-ecological system, and the issues of equity and justice that pertain to sustainable responses to global environmental change. There have been a few recent critical analyses of...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 162-168 Ken’ichi, Matsumoto , Toshihiko, Masui This study purposes to analyze economic aspects of defined climate policies applying the AIM/CGE[Global] model to understand the economic consequences of abating a large amount of greenhouse gas emissions to avoid dangerous climate change. As a result, higher carbon prices and larger decreases in GDP are observed when emissions are abated more deeply. However, such GDP losses are rather small and insignificant compared to the GDP growth throughout this century. These results suggest that although it is challenging to abate emissions until the level to avoid dangerous climate change, there is a sufficient possibility to achieve it from economic perspectives.

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 169-179 Kieran, O’Driscoll , Tatjana, Ilyina , Thomas, Pohlmann , Bernhard, Mayer , Peter, Damm The environmental fate of selected persistent organic pollutants (POPs) in the North Sea system is modelled with a high resolution Fate and Transport Ocean Model (FANTOM) that uses hydrodynamic model output from the Hamburg Shelf Ocean Model (HAMSOM). Large amounts of POPs enter the North Sea from the surrounding highly populated, industrialised and agricultural countries. Major pathways to the North Sea are atmospheric deposition and river inputs, with additional contributions coming from bottom sediments and adjacent seas. The model domain covers the entire North Sea region, extending northward as far as the Shetland Islands, and includes adjacent basins such as...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 180-193 Yasin M.S., Salah , Mary C., Scholes This study examined the mass loss and CO2 production from Pinus patula (Schlecht et Cham) leaf litter collected from fertilized plots in the Mpumalanga Province. Litter decomposition increased with increasing temperature. Warming between 15 and 18°C significantly increased the amount of CO2 emissions from the litter. Mass loss positively correlated with temperature levels. Nitrogen fertilizer applications had significant effects on litter decomposition rate but a minor effect on litter nitrogen quality. Litter quality was not a strong predictor of decomposition rates implying temperature is the major factor influencing the decomposition rate of Pinus patula needle litter. Results of this study...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 194-198 Carol Ann, Stannard , Richard J., Aspinall Modelling land system change using scientific approaches that integrate the human and environmental systems are increasingly needed. Integrated models are dependent upon our ability, not only to understand and describe the systems, but also to couple different modelling approaches. By promoting and supporting the Global Land Project science plan, the GLP Nodal Office of Integration and Modelling has contributed to the international research agenda through events which have brought together researchers from a broad range of disciplines to address the issues involved in modelling coupled human-environmental systems.

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 199-205 P.J., Telford , J., Lathière , N.L., Abraham , A.T., Archibald , P., Braesicke , ... The eruption of Mt. Pinatubo in June 1991 was the largest in the twentieth century. One of its effects was to produce cooler and drier conditions in the years following the eruption. We present the results of an integrated model study of the effect of these climatic changes on the emissions of isoprene from the biosphere. Our emissions model simulations showed that global isoprene emissions were reduced by 9% from 1990 to 1992. When incorporated into our model of global atmospheric chemistry this reduction of isoprene emissions led to an increase in the tropospheric OH burden of 2%. This caused...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 206-215 Christopher, Vernon , Erica, Thompson , Sarah, Cornell Contemporary increases in atmospheric carbon dioxide concentration are in large part the result of anthropogenic carbon dioxide emissions from fossil fuel combustion. Scenario analysis is commonly used to generate projections of future carbon dioxide emissions, the resulting atmospheric concentrations and climate impact. In most scenario modelling published to date, carbon dioxide emission scenarios are based on demand-side (socioeconomic and technology) factors. The fossil fuel resource is assumed ample enough that supply-side factors do not drive future emission scenarios. This review of the literature on non-renewable resource extraction rate modelling and empirical studies of the global fossil fuel resource base suggests...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 6, 2011, Pages 216-221 Sönke, Zaehle , Colin, Prentice , Sarah, Cornell Complex Earth system models, and their various sub-components, are not yet subject to rigorous evaluation against observations as much as they should be, despite the existence of hundreds of proposed diagnostics. A concerted process is urgently needed to make this the norm, not the exception. Earth Observation, field observations and palaeo data can be applied to contexts as diverse as wildfire, marine ecosystems, the land carbon cycle, and greenhouse gases. Model evaluation (by comparing models and benchmark data) and model weighting (defining the ‘quality’ of models on the basis of such a comparison) should be considered as separate issues. Systematic...

Description: Author(s): Gregory P Asner Affiliation(s): Carnegie Institution for Science, 260 Panama Street, Stanford, CA 94305, USA

Description: We introduce a simplified version of the soccer ball model (SBM) developed by Niedermeier et al (2014 Geophys. Res. Lett. 41 [http://dx.doi.org/10.1002/2013GL058684] 736–741 ) into the Community Atmospheric Model version 5 (CAM5). It is the first time that SBM is used in an atmospheric model to parameterize the heterogeneous ice nucleation. The SBM, which was simplified for its suitable application in atmospheric models, uses the classical nucleation theory to describe the immersion/condensation freezing by dust in the mixed-phase cloud regime. Uncertain parameters (mean contact angle, standard deviation of contact angle probability distribution, and number of surface sites) in the SBM are constrained by fitting them to recent natural dust (Saharan dust) datasets. With the SBM in CAM5, we investigate the sensitivity of modeled cloud properties to the SBM parameters, and find significant seasonal and regional differences in the sensitivity among the...

Description: Despite a large body of legislation, high nutrient loads are still emitted in European inland waters. In the present study we evaluate a set of alternative scenarios aiming at reducing nitrogen and phosphorus emissions from anthropogenic activities to all European Seas. In particular, we tested the full implementation of the European Urban Waste Water Directive, which controls emissions from point source. In addition, we associated the full implementation of this Directive with a ban of phosphorus-based laundry detergents. Then we tested two human diet scenarios and their impacts on nutrient emissions. We also developed a scenario based on an optimal use of organic manure. The impacts of all our scenarios were evaluated using a statistical model of nitrogen and phosphorus fate (GREEN) linked to an agro-economic model (CAPRI). We show that the ban of phosphorus-based laundry detergents coupled with the full implementation of the Urban Waste Water Directive is the most effective ap...

Description: Description unavailable

Description: In the Alberta oil sands region, insufficient knowledge of pre-disturbance reference conditions has undermined the ability of the Regional Aquatics Monitoring Program (RAMP) to detect pollution of the Athabasca River, because sampling began three decades after the industry started and the river naturally erodes oil-bearing strata. Here, we apply a novel approach to characterize pre-industrial reference metal concentrations in river sediment downstream of Alberta oil sands development by analyzing metal concentrations in sediments deposited in floodplain lakes of the Athabasca Delta during 1700–1916, when they were strongly influenced by Athabasca River floodwaters. We compared results to metal concentrations in surficial bottom sediments sampled by RAMP (2010–2013) at downstream sites of the Athabasca River and distributaries. When normalized to lithium content, concentrations of vanadium (a metal of concern in the oil sands region) and other priority pollutants (Be, Cd, Cr, Cu, ...

Description: Amazon forests represent nearly half of all tropical vegetation biomass and, through photosynthesis and respiration, annually process more than twice the amount of estimated carbon (CO 2 ) from fossil fuel emissions. Yet the seasonality of Amazon canopy cover, and the extent to which seasonal fluctuations in water availability and photosynthetically available radiation influence these processes, is still poorly understood. Implementing six remotely sensed data sets spanning nine years (2003–2011), with reported field and flux tower data, we show that southern equatorial Amazon forests exhibit a distinctive seasonal signal. Seasonal timing of water availability, canopy biomass growth and net leaf flush are asynchronous in regions with short dry seasons and become more synchronous across a west-to-east longitudinal moisture gradient of increasing dry season. Forest cover is responsive to seasonal disparities in both water and solar radiation availability, temporally adjust...

Description: Estimates of global thunderstorm activity have been made predominately by direct measurements of lightning discharges around the globe, either by optical measurements from satellites, or using ground-based radio antennas. In this paper we propose a new methodology in which thunderstorm clusters are constructed based on the lightning strokes detected by the World Wide Lightning Location Network (WWLLN) in the very low frequency range. We find that even with low lightning detection efficiency on a global scale, the spatial and temporal distribution of global thunderstorm cells is well reproduced. This is validated by comparing the global diurnal variations of the thunderstorm cells, and the currents produced by these storms, with the well-known Carnegie Curve, which represents the mean diurnal variability of the global atmospheric electric circuit, driven by thunderstorm activity. While the Carnegie Curve agrees well with our diurnal thunderstorm cluster variations, there is little...

Description: Climate change might impact crop yields considerably and anticipated transformations of agricultural systems are needed in the coming decades to sustain affordable food provision. However, decision-making on transformational shifts in agricultural systems is plagued by uncertainties concerning the nature and geography of climate change, its impacts, and adequate responses. Locking agricultural systems into inadequate transformations costly to adjust is a significant risk and this acts as an incentive to delay action. It is crucial to gain insight into how much transformation is required from agricultural systems, how robust such strategies are, and how we can defuse the associated challenge for decision-making. While implementing a definition related to large changes in resource use into a global impact assessment modelling framework, we find transformational adaptations to be required of agricultural systems in most regions by 2050s in order to cope with climate change. However,...

Description: Subgrid-scale variability is one of the main reasons why parameterizations are needed in large-scale models. Although some parameterizations started to address the issue of subgrid variability by introducing a subgrid probability distribution function for relevant quantities, the spatial structure has been typically ignored and thus the subgrid-scale interactions cannot be accounted for physically. Here we present a new statistical-physics-like approach whereby the spatial autocorrelation function can be used to physically capture the net effects of subgrid cloud interaction with radiation. The new approach is able to faithfully reproduce the Monte Carlo 3D simulation results with several orders less computational cost, allowing for more realistic representation of cloud radiation interactions in large-scale models.

Description: Unprecedented wet conditions are reported in the 2014 summer (December–March) in South-western Amazon, with rainfall about 100% above normal. Discharge in the Madeira River (the main southern Amazon tributary) has been 74% higher than normal (58 000 m 3 s −1 ) at Porto Velho and 380% (25 000 m 3 s −1 ) at Rurrenabaque, at the exit of the Andes in summer, while levels of the Rio Negro at Manaus were 29.47 m in June 2014, corresponding to the fifth highest record during the 113 years record of the Rio Negro. While previous floods in Amazonia have been related to La Niña and/or warmer than normal tropical South Atlantic, the 2014 rainfall and flood anomalies are associated with warm condition in the western Pacific-Indian Ocean and with an exceptionally warm Subtropical South Atlantic. Our results suggest that the tropical and subtropical South Atlantic SST gradient is a main driver for moisture transport from the Atlantic toward south-western A...

Description: Correcting biases in atmospheric variables prior to impact studies or dynamical downscaling can lead to new biases as dynamical consistency between the ‘corrected’ fields is not maintained. Use of these bias corrected fields for subsequent impact studies and dynamical downscaling provides input conditions that do not appropriately represent intervariable relationships in atmospheric fields. Here we investigate the consequences of the lack of dynamical consistency in bias correction using a measure of model consistency—the potential vorticity (PV). This paper presents an assessment of the biases present in PV using two alternative correction techniques—an approach where bias correction is performed individually on each atmospheric variable, thereby ignoring the physical relationships that exists between the multiple variables that are corrected, and a second approach where bias correction is performed directly on the PV field, thereby keeping the system dynamically coherent throug...

Description: Very large-fires (VLFs) have widespread impacts on ecosystems, air quality, fire suppression resources, and in many regions account for a majority of total area burned. Empirical generalized linear models of the largest fires (〉5000 ha) across the contiguous United States (US) were developed at ∼60 km spatial and weekly temporal resolutions using solely atmospheric predictors. Climate−fire relationships on interannual timescales were evident, with wetter conditions than normal in the previous growing season enhancing VLFs probability in rangeland systems and with concurrent long-term drought enhancing VLFs probability in forested systems. Information at sub-seasonal timescales further refined these relationships, with short-term fire weather being a significant predictor in rangelands and fire danger indices linked to dead fuel moisture being a significant predictor in forested lands. Models demonstrated agreement in capturing the observed spatial and temporal variability incl...

Description: The IPCC Guidelines propose 3 Tier levels for greenhouse gas monitoring within the forest land category with a hierarchical order in terms of accuracy, data requirements and complexity. Due to missing data and/or capacities, many developing countries, potentially interested in the reducing emissions from deforestation and forest degradation scheme, have to rely on Tier 1 default values with highest uncertainties. A possible way to increase the credibility of uncertain estimates is to apply a conservative approach, for which standard statistical information is needed. However, such information is currently not available for the IPCC values. In our study we combine a recent global forest mask, an ecological zoning map and the pan-tropical AGB datasets of Saatchi and Baccini to derive mean forest AGB values per ecological zone and continent as well as their corresponding confidence intervals. Such analysis can be considered transparent as the datasets/methodologies are well document...

Description: In permafrost soils, ‘excess ice’, also referred to as ground ice, exists in amounts exceeding soil porosity in forms such as ice lenses and wedges. Here, we incorporate a simple representation of excess ice in the Community Land Model (CLM4.5) to investigate how excess ice affects projected permafrost thaw and associated hydrologic responses. We initialize spatially explicit excess ice obtained from the Circum-Arctic Map of Permafrost and Ground-Ice Conditions. The excess ice in the model acts to slightly reduce projected soil warming by about 0.35 °C by 2100 in a high greenhouse gas emissions scenario. The presence of excess ice slows permafrost thaw at a given location with about a 10 year delay in permafrost thaw at 3 m depth at most high excess ice locations. The soil moisture response to excess ice melt is transient and depends largely on the timing of thaw with wetter/saturated soil moisture conditions persisting slightly longer due to delayed post-thaw drainage. Based on ...

Description: There is increasing concern about water constraints limiting oil and gas production using hydraulic fracturing (HF) in shale plays, particularly in semiarid regions and during droughts. Here we evaluate HF vulnerability by comparing HF water demand with supply in the semiarid Texas Eagle Ford play, the largest shale oil producer globally. Current HF water demand (18 billion gallons, bgal; 68 billion liters, bL in 2013) equates to ∼16% of total water consumption in the play area. Projected HF water demand of ∼330 bgal with ∼62 000 additional wells over the next 20 years equates to ∼10% of historic groundwater depletion from regional irrigation. Estimated potential freshwater supplies include ∼1000 bgal over 20 yr from recharge and ∼10 000 bgal from aquifer storage, with land-owner lease agreements often stipulating purchase of freshwater. However, pumpage has resulted in excessive drawdown locally with estimated declines of ∼100–200 ft in ∼6% of the western play area since HF bega...

Description: A nitrogen (N) budget for Denmark has been developed for the years 1990 to 2010, describing the inputs and outputs at the national scale and the internal flows between relevant sectors of the economy. Satisfactorily closing the N budgets for some sectors of the economy was not possible, due to missing or contradictory information. The budgets were nevertheless considered sufficiently reliable to quantify the major flows. Agriculture was responsible for the majority of inputs, though fisheries and energy generation also made significant contributions. Agriculture was the main source of N input to the aquatic environment, whereas agriculture, energy generation and transport all contributed to emissions of reactive N gases to the atmosphere. Significant reductions in inputs of reactive N have been achieved during the 20 years, mainly by restricting the use of N for crop production and improving livestock feeding. This reduction has helped reduce nitrate leaching by about half. Measu...

Description: The 30-year normalized-difference vegetation index (NDVI) time series from AVHRR/MODIS satellite sensors was used in this study to assess the regional vegetation dynamic changes in the Tao River Basin, which cuts across the Eastern Tibetan Plateau (ETP) and the Southwestern Loess Plateau (SLP). First, principal component and correlation analyses were carried out to determine the key climatic variables driving ecological change in the region. Then, regression models were tested to correlate NDVI with the selected climatic variables to determine their predictive power. Finally, Sen’s slope method was used to determine how terrestrial vegetation has responded to regional climate change in the region. The results indicated an average winter season NDVI value of 0.14 in the ETP but only 0.04 in the SLP. Primarily driven by increasing temperature, vegetation growth has generally been enhanced since 1981; spring NDVI increased by 0.03 every 10 years in the ETP and 0.02 in the SLP. Furth...

Description: Ammonia emissions from livestock production can have negative impacts on nearby protected sites and ecosystems that are sensitive to eutrophication and acidification. Trees are effective scavengers of both gaseous and particulate pollutants from the atmosphere making tree belts potentially effective landscape features to support strategies aiming to reduce ammonia impacts. This research used the MODDAS-THETIS a coupled turbulence and deposition turbulence model, to examine the relationships between tree canopy structure and ammonia capture for three source types—animal housing, slurry lagoon, and livestock under a tree canopy. By altering the canopy length, leaf area index, leaf area density, and height of the canopy in the model the capture efficiencies varied substantially. A maximum of 27% of the emitted ammonia was captured by tree canopy for the animal housing source, for the slurry lagoon the maximum was 19%, while the livestock under trees attained a maximum of 60% recaptu...

Description: It is known that carbon dioxide emissions cause the Earth to warm, but no previous study has focused on examining how long it takes to reach maximum warming following a particular CO 2 emission. Using conjoined results of carbon-cycle and physical-climate model intercomparison projects (Taylor et al 2012, Joos et al 2013), we find the median time between an emission and maximum warming is 10.1 years, with a 90% probability range of 6.6–30.7 years. We evaluate uncertainties in timing and amount of warming, partitioning them into three contributing factors: carbon cycle, climate sensitivity and ocean thermal inertia. If uncertainty in any one factor is reduced to zero without reducing uncertainty in the other factors, the majority of overall uncertainty remains. Thus, narrowing uncertainty in century-scale warming depends on narrowing uncertainty in all contributing factors. Our results indicate that benefit from avoided climate damage from avoided CO 2

Description: Author(s): Deniz Karman Affiliation(s): Department of Civil and Environmental Engineering, Carleton University, Ottawa, Canada

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 12-17 Shaoqing, Chen , Bin, Chen , Meirong, Su The importance of addressing cumulative environmental impact of large development projects on rivers has been increasingly highlighted. Consideration to potential impact pathways may be difficult, however, without appropriate analytical methods. By introducing ecological network model, this paper focuses on the quantification of the cause-effect relationships inherent the cumulative effects of dam construction from a holistic perspective. With Lancang river of Longitudinal Range-Gorge Region (LRGR) as an example, the risk-based interaction instead of the conventional energy or material flow of ecological network model has been created to conceptualize the cumulative effects network model. Based on this model, the network structural and...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 37-42 Chi, Li , Longlong, Lai As a piece of forestland under special protection and a specific site for tourism and leisure, national forest parks have already become an important carrier for forest tourism and drawn more and more attention from all walks of the society. This paper is a case study of Baicaowa National Forest Park in Chengde, which focuses on the development and utilization of forest parks based on the experiences strategy. It claims that during the planning of tourism facilities of national forest parks, principles of “thematic experience” (including temporal, spatial and physical experiences), “profound experience” and “educational experience” should be adopted to...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 18-24 Gengyuan, Liu , Zhifeng, Yang , Bin, Chen This emergy-based urban economic account provided a historical portrait of the urban economy and its structures to understand the overload of the biosphere‘s assimilative capacity. The basic situation of the urban economy, involving the indigenous resources base, emergy consumption patterns, emergy exports and imports, was investigated, accounted and discussed. Using a series of ratios and indices arising from emergy analysis, including emergy intensity, environmental load ratio and environmental sustainability, this paper analyzed the economic development in Beijing during the years of 1999 to 2006 and the heavy pressure it has put on the environment. Results showed that the development of...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 29-36 Xianchun, Tan , Junyi, Xu , Sheng, Wang With the research on some critical technology going deeply, the problem of technology route and project approach for the saving energy & reducing consumption have become the focus of municipal wastewater treatment process. In this article, LCA (Life Cycle Analysis) is applied to identify and compare the energy consumption of each stage of different technologies in municipal wastewater treatment from the view of whole process. This is carried out after reviewing the condition of energy utilizing of typical technologies in China. And some measures are brought forward to improve the efficiency of energy utilizing. Integrated Oxidation Ditch (IOD) is taken...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 81-86 Gengyuan, Liu , Zhifeng, Yang , Bin, Chen This emergy-based four angle model application is used to depict the variations of urban metabolic profile (energy and money) based on the changes experienced across the economic sectors over the years. The urban metabolic structure and efficiency results obtained for Beijing are compared to those for other European cities. In addition, for the Beijing's case, the study creates the foundation for a future analysis comparing the development of Beijing with that of Rome. The results imply that over three decade Beijing's urbanizing movement has greatly promoted the sustained development of the real estate and growth of urban household. The results...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 60-64 Shaoqing, Chen , Bin, Chen , Meirong, Su City interaction, though of great importance in the context of market-oriented economy, has rarely been studied quantitatively compared to structure and function inside the city due to the tribulation when acquiring and disposing the relational data between cities. Herein, we quantified city-to-city relations in ecological and economic contexts with the application of emergy analysis, which proved to be a promising approach to evaluating various city flows on a common basis. Emergy diagram of urban system was constructed, and the related relational data were chosen from the ecological and economic aspects respectively to form two integrated indicator systems incorporating the transfer...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 120-130 Dacheng, Liu , XiaoouYang , Xianchun, Tian , Ruihao, Wu , Li, Wang In the near future, energy conservation and pollution reduction became two of the most significant factors in economic development and social circulate. For analyzing the issue, several models were applied involving the fields of mathematical optimization, economics theory, dynamics model and industrial management. Specifically, they are MARKAL model, Input-Output model, LEAP model and Systemic Dynamics model. In the paper, a collaborative distributed database and an integrated simulation were developed for the Economics-Energy-Environment (3E) system, especially four models were firstly synthesize in a unique way which achieve securities economically, environmentally, as well as in a sense of energy source. The integrated...

Description: Publication year: 2011 Source: Procedia Environmental Sciences, Volume 5, 2011, Pages 199-207 Shan, Cao , Chi, Li The establishment of low-carbon eco-city planning in the pattern of low-carbon economic development and the low-carbon society consumption with cities as a unit can remove the bottleneck for urban development, promote sustainable urban development and provide ample opportunities for industry upgrading and transformation in cities. The paper highlights the low-carbon eco-city planning ideas and development strategies and introduces the practical exploration of the planning with the new eco-city of Tianjin as an example.