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  • ddc:551.9  (32)
  • ddc:631.4  (9)
  • English  (41)
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  • 2020-2023  (41)
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  • 1
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    Nitrogen and Phosphorus Control Soil Methane Uptake in Tropical Montane Forests (2021)
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    Publication Date: 2022-04-04
    Description: Tropical forests contribute about one third to global annual CH4 uptake by soils. Understanding the factors that control the soil‐atmosphere exchange of CH4 at a large scale is a critical step to improve the CH4 flux estimate for tropical soils, which is presently poorly constrained. Since tropical forest degradation often involves shifts in nutrient availabilities, it is critical to evaluate how this will affect soil CH4 flux. Here, we report how nitrogen (N; 50 kg N ha−1 yr−1), phosphorus (P; 10 kg P ha−1 yr−1), and combined N + P additions affect soil CH4 fluxes across an elevation gradient of tropical montane forests. We measured soil CH4 fluxes in a nutrient application experiment at different elevations over a period of 5 years. Nutrient additions increased soil CH4 uptake after 4–5 years of treatment but effects were not uniform across elevations. At 1,000 m, where total soil P was high, we detected mainly N limitation of soil CH4 uptake. At 2,000 m, where total soil P was low, a strong P limitation of soil CH4 uptake was observed. At 3,000 m, where total P was low in the organic layer but high in mineral soil, we found N limitation of soil CH4 uptake. Our results show that projected increases of N and P depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrient status and plant‐microbial competition for N and P.
    Description: Plain Language Summary: CH4 is a potent greenhouse gas that contributes to global warming. Tropical forests are a natural sink of CH4 but increasing nutrient depositions due to industrialization may alter the sink strength of tropical forests. Our results show that projected increases of nitrogen and phosphorus depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrients and plant‐microbial competition.
    Description: Key Points: Projected increases in nitrogen and phosphorus depositions in the tropics will stimulate soil methane uptake in tropical montane forests. The direction, magnitude, and timing of nutrient deposition effects on soil methane uptake will depend on forests' nutrient status. Nutrient limitations on ecosystem processes have to be investigated in actual field conditions.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.25625/XLNKNK
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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  • 2
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    Iron Exports From Catchments Are Constrained by Redox Status and Topography (2022)
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    Publication Date: 2022-04-04
    Description: Fe(III) hydroxides stabilize organic carbon (OC) and P in soils. Observations of rising stream Fe concentrations are controversially posited to result from a flushing of iron‐rich deeper soil layers or a decrease of competing electron acceptors inhibiting Fe reduction (NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and SO42− $\mathrm{S}{{\mathrm{O}}_{4}}^{2-}$). Here, we argue that catchment topography constrains the release of Fe, OC, and P to streams. We therefore incubated organic topsoil and mineral subsoil and modified the availability of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$. We found that Fe leaching was highest in topsoil. Fe, OC, and P released at quantities proportional to their ratios in the source soil. Supply of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ reduced Fe leaching to 18% and increased pore water OC:Fe and P:Fe ratios. Subsoil, however, was an insignificant Fe source (〈0.5%). Here, the leached quantities of Fe, OC and P were highly disproportionate to the soil source with an excess of released OC and P. We tested if experimental findings scale up using data from 88 German catchments representing gradients in NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ concentration and topography. Average stream Fe concentrations increased with decreasing NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and were high in catchments with shallow topography where high groundwater levels support reductive processes and topsoils are hydrologically connected to streams; but Fe concentrations were low in catchments with steep topography where flow occurs primarily through subsoils. OC:Fe and P:Fe ratios in the streams similarly varied by NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and topography. This corroborates the findings from the laboratory experiment and suggests that catchment topography and competing electron acceptors constrain the formation of Fe‐reducing conditions and control the release of Fe, OC, and P to streams.
    Description: Plain Language Summary: Iron is the second most abundant metal in the crust; its cycle is tightly connected to those of carbon, oxygen, and sulfur. The oxidized form (FeIII) is almost insoluble, but Fe can be mobilized by complexation or microbial Fe reduction. Both processes depend on availability of organic C. We found that Fe concentrations in streams were constrained by the topography of catchments and NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ abundance. Shallower catchments are characterized by higher groundwater tables connecting the organic topsoils efficiently to streams. NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ suppresses Fe reduction as a competing electron acceptor to Fe. We conclude that trends in soil wetness or atmospheric N deposition can change the stability of Fe and thus the release of PO43− $\mathrm{P}{{\mathrm{O}}_{4}}^{3-}$ and harmful metals to surface waters.
    Description: Key Points: Organic topsoils leach substantial amounts of Fe when incubated in the absence of NO3, a competing electron acceptor that inhibits Fe reduction. Shallow catchments with fluvially coupled topsoils and low NO3 availability release 200 fold more Fe than steep ones with high NO3 abundance. Catchment topography and NO3 availability explain 62%–64% of the variability of Fe concentration and OC:Fe and P:Fe ratios across 88 streams.
    Description: EFRE‐Europe
    Description: https://doi.org/10.4211/hs.43601618877945c5a46b715aa98db729
    Keywords: ddc:551.9
    Language: English
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  • 3
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    Vertically Divergent Responses of SOC Decomposition to Soil Moisture in a Changing Climate (2022)
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    Publication Date: 2022-04-07
    Description: The role of soil moisture for organic matter decomposition rates remains poorly understood and underrepresented in Earth System Models (ESMs). We apply the Dual Arrhenius Michaelis‐Menten (DAMM) model to a selection of ESM soil temperature and moisture outputs to investigate their effects on decomposition rates, at different soil depths, for a historical period and a future climate period. Our key finding is that the inclusion of soil moisture controls has diverging effects on both the speed and direction of projected decomposition rates (up to ±20%), compared to a temperature‐only approach. In the top soil, the majority of these changes is driven by substrate availability. In deeper soil layers, oxygen availability plays a relatively stronger role. Owing to these different moisture controls along the soil depth, our study highlights the need for depth‐resolved inclusion of soil moisture effects on decomposition rates within ESMs. This is particularly important for C‐rich soils in regions which may be subject to strong future warming and vertically opposing moisture changes, such as the peat soils at northern high latitudes.
    Description: Plain Language Summary: Soils contain a lot of carbon (C). Earth System Models (ESMs) predict that the amount of C released from soils into the atmosphere as CO2 will increase in response to increased warming and microbial activity. Soil moisture also controls microbial C decomposition, but most ESMs do not yet describe this process very well. In this study we apply a simple equation to different ESMs, to see how both temperature and soil moisture change microbial decomposition under future climate. First, we show that the speed of C released into the atmosphere changes when we include soil moisture changes, compared to what is expected due to warming alone. Second, we found that the future speed at which carbon that can be decomposed in the topsoil mainly depends on how much carbon microbes have access to, but that in the deeper soil this process becomes much more affected by the absence/presence of oxygen. Including these soil moisture interactions in ESMs for different soil depths is important to predict whether soils will store more or less C in the future. Our findings are particularly relevant for high latitude soils which store large amounts of C, will warm fast, and experience frequent (re)wetting and drying.
    Description: Key Points: Considering soil moisture effects can change modeled decomposition rates by up to ±20% compared to considering only temperature effects. The majority of these changes are driven by substrate availability, in particular in the top soil. In the subsoil, oxygen availability becomes an increasingly important factor.
    Description: Norwegian Research Council
    Description: https://doi.org/10.5281/zenodo.5654554
    Keywords: ddc:631.4
    Language: English
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  • 4
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    Is the soil moisture precipitation feedback enhanced by heterogeneity and dry soils? A comparative study (2021)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-04-01
    Description: The interaction between the land surface and the atmosphere is a crucial driver of atmospheric processes. Soil moisture and precipitation are key components in this feedback. Both variables are intertwined in a cycle, that is, the soil moisture – precipitation feedback for which involved processes and interactions are still discussed. In this study the soil moisture – precipitation feedback is compared for the sempiternal humid Ammer catchment in Southern Germany and for the semiarid to subhumid Sissili catchment in West Africa during the warm season, using precipitation datasets from the Climate Hazards Group InfraRed Precipitation with Station data (CHIRPS), from the German Weather Service (REGNIE) and simulation datasets from the Weather Research and Forecasting (WRF) model and the hydrologically enhanced WRF‐Hydro model. WRF and WRF‐Hydro differ by their representation of terrestrial water flow. With this setup we want to investigate the strength, sign and variables involved in the soil moisture – precipitation feedback for these two regions. The normalized model spread between the two simulation results shows linkages between precipitation variability and diagnostic variables surface fluxes, moisture flux convergence above the surface and convective available potential energy in both study regions. The soil moisture – precipitation feedback is evaluated with a classification of soil moisture spatial heterogeneity based on the strength of the soil moisture gradients. This allows us to assess the impact of soil moisture anomalies on surface fluxes, moisture flux convergence, convective available potential energy and precipitation. In both regions the amount of precipitation generally increases with soil moisture spatial heterogeneity. For the Ammer region the soil moisture – precipitation feedback has a weak negative sign with more rain near drier patches while it has a positive signal for the Sissili region with more rain over wetter patches. At least for the observed moderate soil moisture values and the spatial scale of the Ammer region, the spatial variability of soil moisture is more important for surface‐atmosphere interactions than the actual soil moisture content. Overall, we found that soil moisture heterogeneity can greatly affect the soil moisture – precipitation feedback.
    Description: WRF and WRF‐hydro model simulations are used to determine the sign and analyse the mechanisms of the soil moisture ‐ precipitation feedback for the sempiternal humid Ammer catchment in Southern Germany and for the semiarid to subhumid Sissili catchment in West Africa during the warm season. The generation of moist convection is favoured over surfaces with moderately high soil moisture gradients in the Ammer region, while for the Sissili region the location of precipitation tends to be related to areas with high soil moisture gradients. For the Ammer region the soil moisture – precipitation feedback has a weak negative sign with more rain near drier patches while it has a positive signal for the Sissili region with more rain over wetter patches.
    Description: Untersuchung des Klimas des südlichen Afrikas – ein Brückenschlag vom frühen Holozän bis heute
    Description: Transregional Collaborative Research Center
    Keywords: ddc:551.57 ; ddc:631.4
    Language: English
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  • 5
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    Water Isotopic Signature of Surface Snow Metamorphism in Antarctica (2021)
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    Publication Date: 2022-04-01
    Description: Water isotope ratios of ice cores are a key source of information on past temperatures. Through fractionation within the hydrological cycle, temperature is imprinted in the water isotopic composition of snowfalls. However, this signal of climatic interest is modified after deposition when snow remains at the surface exposed to the atmosphere. Comparing time series of surface snow isotopic composition at Dome C with satellite observations of surface snow metamorphism, we found that long summer periods without precipitation favor surface snow metamorphism altering the surface snow isotopic composition. Using excess parameters (combining D,17O, and 18O fractions) allow the identification of this alteration caused by sublimation and condensation of surface hoar. The combined measurement of all three isotopic compositions could help identifying ice core sections influenced by snow metamorphism in sites with very low snow accumulation.
    Description: Plain Language Summary: Water isotopes in ice core records are often used to reconstruct past climate temperature variations. Classically, the temperature signal is thought to be imprinted in water isotopes of precipitation, and then archived in the ice core as it falls, and in cold areas of Antarctica, piles up for very long period. Here, we show that the surface snow isotopic composition varies in between precipitation events, suggesting that there might be more than one contribution to the isotopic signal in ice core records. This is particularly important for low accumulation sites, where the snow at the surface remains exposed for very long time periods. The combined use of several isotopic ratios in surface snow helps us disentangle the processes that create this signal.
    Description: Key Points: During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. The d‐excess and 17O‐excess of the snow is a proxy of snow metamorphism for low accumulation regions.
    Description: FP7 Ideas: European Research Council (FP7 Ideas) http://dx.doi.org/10.13039/100011199
    Description: Foundation Prince Albert of Monaco
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: DFG project CLIMAIC
    Description: https://doi.pangaea.de/10.1594/PANGAEA.934273
    Keywords: ddc:551.31 ; ddc:551.9
    Language: English
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  • 6
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    Importance of sources of variability, scales and experimental design: A case study about the effects of biochar and slurry application on soil properties in agricultural silty loam soils (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-04-01
    Description: In designed experiments, different sources of variability and an adequate scale of measurement need to be considered, but not all approaches in common usage are equally valid. In order to elucidate the importance of sources of variability and choice of scale, we conducted an experiment where the effects of biochar and slurry applications on soil properties related to soil fertility were studied for different designs: (a) for a field‐scale sampling design with either a model soil (without natural variability) as an internal control or with composited soils, (b) for a design with a focus on amendment variabilities, and (c) for three individual field‐scale designs with true field replication and a combined analysis representative of the population of loess‐derived soils. Three silty loam sites in Germany were sampled and the soil macroaggregates were crushed. For each design, six treatments (0, 0.15 and 0.30 g slurry‐N kg−1 with and without 30 g biochar kg−1) were applied before incubating the units under constant soil moisture conditions for 78 days. CO2 fluxes were monitored and soils were analysed for macroaggregate yields and associated organic carbon (C). Mixed‐effects models were used to describe the effects. For all soil properties, results for the loess sites differed with respect to significant contributions of fixed effects for at least one site, suggesting the need for a general inclusion of different sites. Analysis using a multilevel model allowed generalizations for loess soils to be made and showed that site:slurry:biochar and site:slurry interactions were not negligible for macroaggregate yields. The use of a model soil as an internal control enabled observation of variabilities other than those related to soils or amendments. Experiments incorporating natural variability in soils or amendments resulted in partially different outcomes, indicating the need to include all important sources of variability. Highlights Effects of biochar and slurry applications were studied for different designs and mixed‐effects models were used to describe the effects. Including an internal control allowed observation of, e.g., methodological and analytical variabilities. The results suggested the need for a general inclusion of different sites. Analysis using a multilevel model allowed generalizations for loess soils. The results indicated the need to include all important sources of variability.
    Keywords: ddc:631.4
    Language: English
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  • 7
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    Impacts of Drying and Rewetting on the Radiocarbon Signature of Respired CO2 and Implications for Incubating Archived Soils (2021)
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    Publication Date: 2022-04-01
    Description: The radiocarbon signature of respired CO2 (∆14C‐CO2) measured in laboratory soil incubations integrates contributions from soil carbon pools with a wide range of ages, making it a powerful model constraint. Incubating archived soils enriched by “bomb‐C” from mid‐20th century nuclear weapons testing would be even more powerful as it would enable us to trace this pulse over time. However, air‐drying and subsequent rewetting of archived soils, as well as storage duration, may alter the relative contribution to respiration from soil carbon pools with different cycling rates. We designed three experiments to assess air‐drying and rewetting effects on ∆14C‐CO2 with constant storage duration (Experiment 1), without storage (Experiment 2), and with variable storage duration (Experiment 3). We found that air‐drying and rewetting led to small but significant (α 〈 0.05) shifts in ∆14C‐CO2 relative to undried controls in all experiments, with grassland soils responding more strongly than forest soils. Storage duration (4–14 y) did not have a substantial effect. Mean differences (95% CIs) for experiments 1, 2, and 3 were: 23.3‰ (±6.6), 19.6‰ (±10.3), and 29.3‰ (±29.1) for grassland soils, versus −11.6‰ (±4.1), 12.7‰ (±8.5), and −24.2‰ (±13.2) for forest soils. Our results indicate that air‐drying and rewetting soils mobilizes a slightly older pool of carbon that would otherwise be inaccessible to microbes, an effect that persists throughout the incubation. However, as the bias in ∆14C‐CO2 from air‐drying and rewetting is small, measuring ∆14C‐CO2 in incubations of archived soils appears to be a promising technique for constraining soil carbon models.
    Description: Plain Language Summary: Soils play a key role in the global carbon cycle by sequestering carbon from the atmosphere for decades to millennia. However, it is unclear if they will continue to do so as the climate changes. Microbial decomposition of soil organic matter returns carbon back to the atmosphere, and radiocarbon dating of this returning CO2 (∆14C‐CO2) can be used to quantify how long carbon is stored in ecosystems. Incubating archived soils could provide unique insight into soil carbon sequestration potential by quantifying the change in ∆14C‐CO2 over time. However, air‐drying, duration of archiving, and subsequent rewetting of soils may bias estimates of sequestration potential by altering the balance of younger versus older carbon leaving the soil. We compared ∆14C‐CO2 from soils incubated with and without air‐drying and archiving, and found that the air‐dried soils appeared to release slightly older carbon than soils that had never been air‐dried. The amount of time the soils were archived did not have an effect. Since the bias from air‐drying and rewetting was small, incubating archived soils appears to be a promising technique for improving our ability to model soil carbon cycling under global climate change.
    Description: Key Points: ∆14C of CO2 measured in incubations of archived soils provides additional constraints for soil carbon models. Air‐drying and rewetting soils shifted the ∆14C of respired CO2 by 10‰–20‰ independent of the duration of storage. Differences in direction and magnitude of ∆14C‐CO2 shifts between forests and grasslands depended on sampling year and system C dynamics.
    Description: EC, H2020, H2020 Priority Excellent Science, H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663
    Description: https://doi.org/10.5281/zenodo.4959705
    Keywords: ddc:551.9 ; ddc:631.41 ; ddc:550.724
    Language: English
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    Do tree species affect decadal changes in soil organic carbon and total nitrogen stocks in Danish common garden experiments? (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-04-01
    Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.
    Description: Deutsche Forschungsgemeinschaff (DFG)
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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    Assessing the robustness of carbonate‐associated sulfate during hydrothermal dolomitization of the Latemar platform, Italy (2021)
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    Publication Date: 2022-03-30
    Description: Carbonate‐associated sulfate (CAS) is an important proxy for reconstructing marine sulfur cycling throughout Earth's history. In order to assess the impact of carbonate neomorphism on δ34SCAS data, a mineralogical‐spatial transect from early diagenetic limestone into low‐temperature hydrothermal dolostone was analyzed in the middle Triassic Latemar platform interior, northern Italy. This study addresses the yet unconstrained question whether hydrothermal dolostone preserves a marine δ34SCAS signature and, hence, might represent an archive for past seawater sulfate. In this study, δ34SCAS values were measured in low‐temperature hydrothermal dolostone and compared with data from their corresponding precursor limestone. Results shown here reveal that δ34SCAS values for dolostone and precursor limestone are indistinguishable. This points to a rock‐buffered middle Triassic marine δ34S signature not affected by hydrothermal alteration. Hence, hydrothermal dolostone represents, under favorable conditions, an archive for unraveling past marine sulfur cycling.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.9 ; ddc:552
    Language: English
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    Increased petrogenic and biospheric organic carbon burial in sub‐Antarctic fjord sediments in response to recent glacier retreat (2021)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-03-30
    Description: Fjords are recognized as hotspots of organic carbon (OC) burial in the coastal ocean. In fjords with glaciated catchments, glacier discharge carries large amounts of suspended matter. This sedimentary load includes OC from bedrock and terrigenous sources (modern vegetation, peat, soil deposits), which is either buried in the fjord or remineralized during export, acting as a potential source of CO2 to the atmosphere. In sub‐Antarctic South Georgia, fjord‐terminating glaciers have been retreating during the past decades, likely as a response to changing climate conditions. We determine sources of OC in surface sediments of Cumberland Bay, South Georgia, using lipid biomarkers and the bulk 14C isotopic composition, and quantify OC burial at present and for the time period of documented glacier retreat (between 1958 and 2017). Petrogenic OC is the dominant type of OC in proximity to the present‐day calving fronts (60.4 ± 1.4% to 73.8 ± 2.6%) and decreases to 14.0 ± 2.7% outside the fjord, indicating that petrogenic OC is effectively buried in the fjord. Beside of marine OC, terrigenous OC comprises 2.7 ± 0.5% to 7.9 ± 5.9% and is mostly derived from modern plants and Holocene peat and soil deposits that are eroded along the flanks of the fjord, rather than released by the retreating fjord glaciers. We estimate that the retreat of tidewater glaciers between 1958 and 2017 led to an increase in petrogenic carbon accumulation of 22% in Cumberland West Bay and 6.5% in Cumberland East Bay, suggesting that successive glacier retreat does not only release petrogenic OC into the fjord, but also increases the capacity of OC burial.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:552 ; ddc:551.9
    Language: English
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    Past and Future Climate Variability Uncertainties in the Global Carbon Budget Using the MPI Grand Ensemble (2021)
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    Publication Date: 2022-03-25
    Description: Quantifying the anthropogenic fluxes of CO2 is important to understand the evolution of carbon sink capacities, on which the required strength of our mitigation efforts directly depends. For the historical period, the global carbon budget (GCB) can be compiled from observations and model simulations as is done annually in the Global Carbon Project's (GCP) carbon budgets. However, the historical budget only considers a single realization of the Earth system and cannot account for internal climate variability. Understanding the distribution of internal climate variability is critical for predicting the future carbon budget terms and uncertainties. We present here a decomposition of the GCB for the historical period and the RCP4.5 scenario using single‐model large ensemble simulations from the Max Planck Institute Grand Ensemble (MPI‐GE) to capture internal variability. We calculate uncertainty ranges for the natural sinks and anthropogenic emissions that arise from internal climate variability, and by using this distribution, we investigate the likelihood of historical fluxes with respect to plausible climate states. Our results show these likelihoods have substantial fluctuations due to internal variability, which are partially related to El Niño‐Southern Oscillation (ENSO). We find that the largest internal variability in the MPI‐GE stems from the natural land sink and its increasing carbon stocks over time. The allowable fossil fuel emissions consistent with 3 C warming may be between 9 and 18 Pg C yr−1. The MPI‐GE is generally consistent with GCP's global budgets with the notable exception of land‐use change emissions in recent decades, highlighting that human action is inconsistent with climate mitigation goals.
    Description: Key Points: We use a single‐model large ensemble to estimate uncertainties from internal climate variability in the global carbon budget. The land sink accounts for most internal climate uncertainty which may permit 9–18 Pg C yr−1 in allowable emissions by 2050 (for 3°C warming).
    Description: European Union's Horizon 2020
    Keywords: ddc:551.9 ; ddc:551.6
    Language: English
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    Large‐scale detection and quantification of harmful soil compaction in a post‐mining landscape using multi‐configuration electromagnetic induction (2021)
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    Publication Date: 2022-03-25
    Description: Fast and accurate large‐scale localization and quantification of harmfully compacted soils in recultivated post‐mining landscapes are of particular importance for mining companies and the following farmers. The use of heavy machinery during recultivation imposes soil stress and can cause irreversible subsoil compaction limiting crop growth in the long term. To overcome or guide classical point‐scale methods to determine compaction, fast methods covering large areas are required. In our study, a recultivated field of the Garzweiler mine in North Rhine‐Westphalia, Germany, with known variability in crop performance was intensively studied using non‐invasive electromagnetic induction (EMI) and electrode‐based electrical resistivity tomography (ERT). Additionally, soil bulk density, volumetric soil water content and soil textures were analysed along two transects covering different compaction levels. The results showed that the measured EMI apparent electrical conductivity (ECa) along the transects was highly correlated (R2 〉 .7 for different dates and depths below 0.3 m) to subsoil bulk density. Finally, the correlations established along the transects were used to predict harmful subsoil compaction within the field, whereby a spatial probabilistic map of zones of harmful compaction was developed. In general, the results revealed the feasibility of using the EMI derived ECa to predict harmful compaction. They can be the basis for quick monitoring of the recultivation process and implementation of necessary melioration to return a well‐structured soil with good water and nutrient accessibility, and rooting depths for increased crop yields to the farmers.
    Description: BonaRes (Module A)
    Keywords: ddc:631.4
    Language: English
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    Last Glacial central Mediterranean hydrology inferred from Lake Trasimeno’s (Italy) calcium carbonate geochemistry (2021)
    Details
    Publication Date: 2022-03-24
    Description: There is still a paucity of hydrological data explaining the relationship between (rapid, millennial‐scale) climate forcing and Mediterranean rainfall since the Last Glacial. We show that distinct lake‐level fluctuations at Lake Trasimeno (Italy) are associated with changing aridity in the central Mediterranean during the last ~47 800 years. The lake‐level fluctuations are reconstructed based on carbonate mineral content and carbonate mineral species, as well as the stable oxygen and carbon isotope (δ18O and δ13C) geochemistry of endogenic carbonates. Low lake levels are linked to high carbonate, Mg‐calcite and aragonite contents, and high δ18O and δ13C values. Inferred hydrological changes are linked to glacial–interglacial and, tentatively within the limitations of our chronology, to millennial‐scale climate variability as well as the intensity of the Atlantic Meridional Overturning Circulation (AMOC). Prior to the Last Glacial Maximum (LGM), during intervals equivalent to Marine Isotope Stage 3 (MIS 3), a stronger AMOC associated with Greenland interstadial periods (Dansgaard/Oeschger (D/O) warm periods) and stronger Asian monsoon probably coincide with increased precipitation in central Italy as inferred from high lake levels at Lake Trasimeno. Periods of weak AMOC intensity such as during Greenland stadials (D/O cold periods), during Heinrich events, and weak Asian monsoons are correlated with lake level lowstands, which imply relatively dry conditions in central Italy. Lake Trasimeno’s water level during the LGM and the Lateglacial (MIS 2) is relatively stable, with recorded changes showing distinct similarities to orbital configurations. Although muted, high latitude climate forcing is still evident in the data during peak glacial conditions. The transition from D/O‐like hydrological variability at Lake Trasimeno during MIS 3 to orbitally controlled fluctuations during the Lateglacial to Holocene transition coincides with an increasing amplitude in local winter and summer insolation, probably indicating increasing seasonality and a larger temperature gradient between low‐ and high‐latitude settings.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Keywords: ddc:551.9
    Language: English
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  • 14
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    Detrital apatite geochemistry and thermochronology from the Oligocene/Miocene Alpine foreland record the early exhumation of the Tauern Window (2021)
    Details
    Publication Date: 2022-03-24
    Description: The early exhumation history of the Tauern Window in the European Eastern Alps and its surface expression is poorly dated and quantified, partly because thermochronological and provenance information are sparse from the Upper Austrian Northern Alpine Foreland Basin. For the first time, we combine a single‐grain double‐dating approach (Apatite Fission Track and U‐Pb dating) with trace‐element geochemistry analysis on the same apatites to reconstruct the provenance and exhumation history of the late Oligocene/early Miocene Eastern Alps. The results from 22 samples from the Chattian to Burdigalian sedimentary infill of the Upper Austrian Northern Alpine Foreland Basin were integrated with a 3D seismic‐reflection data set and published stratigraphic reports. Our highly discriminative data set indicates an increasing proportion of apatites (from 6% to 23%) with Sr/Y values 〈0.1 up‐section and an increasing amount of apatites (from 24% to 38%) containing 〉1,000 ppm light rare‐earth elements from Chattian to Burdigalian time. The number of U‐Pb ages with acceptable uncertainties increases from 40% to 59% up‐section, with mostly late Variscan/Permian ages, while an increasing number of grains (10%–27%) have Eocene or younger apatite fission track cooling ages. The changes in the apatite trace‐element geochemistry and U‐Pb data mirror increased sediment input from an ≥upper amphibolite‐facies metamorphic source of late Variscan/Permian age – probably the Ötztal‐Bundschuh nappe system – accompanied by increasing exhumation rates indicated by decreasing apatite fission track lag times. We attribute these changes to the surface response to upright folding and doming in the Penninic units of the future Tauern Window starting at 29–27 Ma. This early period of exhumation (0.3–0.6 mm/a) is triggered by early Adriatic indentation along the Giudicarie Fault System.
    Description: Science Foundation Ireland http://dx.doi.org/10.13039/501100001602
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.701 ; ddc:551.9
    Language: English
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  • 15
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    Tephra Deposition and Bonding With Reactive Oxides Enhances Burial of Organic Carbon in the Bering Sea (2021)
    Details
    Publication Date: 2022-03-24
    Description: Preservation of organic carbon (OC) in marine sediments exerts a major control on the cycling of carbon in the Earth system. In these marine environments, OC preservation may be enhanced by diagenetic reactions in locations where deposition of fragmental volcanic material called tephra occurs. While the mechanisms by which this process occurs are well understood, site‐specific studies of this process are limited. Here, we report a study of sediments from the Bering Sea (IODP Site U1339D) to investigate the effects of marine tephra deposition on carbon cycling during the Pleistocene and Holocene. Our results suggest that tephra layers are loci of OC burial with distinct δ13C values, and that this process is primarily linked to bonding of OC with reactive metals, accounting for ∼80% of all OC within tephra layers. In addition, distribution of reactive metals from the tephra into non‐volcanic sediments above and below the tephra layers enhances OC preservation in these sediments, with ∼33% of OC bound to reactive phases. Importantly, OC‐Fe coupling is evident in sediments 〉700,000 years old. Thus, these interactions may help explain the observed preservation of OC in ancient marine sediments.
    Description: Plain Language Summary: The burial of organic carbon (OC) in marine sediments is one of the major carbon sinks on Earth, meaning that it removes carbon dioxide from the ocean‐atmosphere system. However, the speed at which burial occurs varies across the globe, and is dependent on a range of factors, from the amount of nutrients in the water column, to the type of sediment. Despite evidence suggesting that when tephra is deposited to the seafloor carbon burial is enhanced, very little work has been done to investigate this process. We have therefore analyzed sediments from the Bering Sea, where volcanoes from the Aleutian Islands and Kamchatka regularly deposit tephra in the ocean. We found that OC burial is indeed associated with ash deposition, and importantly, that OC is preserved in the ash layers themselves. We show here that this carbon is preserved effectively because of chemical reactions between the OC and reactive iron, which is released by the ash, creating conditions which preserve carbon for hundreds of thousands of years.
    Description: Key Points: Tephra layers are loci of marine organic carbon (OC) burial with distinct carbon isotopic compositions. Preservation primarily linked to association of OC with reactive iron phases, accounting for ∼80% of all OC in tephra layers. OC‐reactive Fe coupling is observed in sediments 〉700,000 years old, indicating long‐term persistence of these complexes.
    Description: NERC
    Keywords: ddc:551.9
    Language: English
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    Chemical Evolution of the Exceptional Arctic Stratospheric Winter 2019/2020 Compared to Previous Arctic and Antarctic Winters (2021)
    Details
    Publication Date: 2022-03-28
    Description: The winter 2019/2020 showed the lowest ozone mixing ratios ever observed in the Arctic winter stratosphere. It was the coldest Arctic stratospheric winter on record and was characterized by an unusually strong and long‐lasting polar vortex. We study the chemical evolution and ozone depletion in the winter 2019/2020 using the global Chemistry and Transport Model ATLAS. We examine whether the chemical processes in 2019/2020 are more characteristic of typical conditions in Antarctic winters or in average Arctic winters. Model runs for the winter 2019/2020 are compared to simulations of the Arctic winters 2004/2005, 2009/2010, and 2010/2011 and of the Antarctic winters 2006 and 2011, to assess differences in chemical evolution in winters with different meteorological conditions. In some respects, the winter 2019/2020 (and also the winter 2010/2011) was a hybrid between Arctic and Antarctic conditions, for example, with respect to the fraction of chlorine deactivation into HCl versus ClONO2, the amount of denitrification, and the importance of the heterogeneous HOCl + HCl reaction for chlorine activation. The pronounced ozone minimum of less than 0.2 ppm at about 450 K potential temperature that was observed in about 20% of the polar vortex area in 2019/2020 was caused by exceptionally long periods in the history of these air masses with low temperatures in sunlight. Based on a simple extrapolation of observed loss rates, only an additional 21–46 h spent below the upper temperature limit for polar stratospheric cloud formation and in sunlight would have been necessary to reduce ozone to near zero values (0.05 ppm) in these parts of the vortex.
    Description: Key Points: The Arctic stratospheric winter 2019/2020 showed the lowest ozone mixing ratios ever observed and was one of the coldest on record. Chemical evolution of the Arctic winter 2019/2020 was a hybrid between typical Arctic and typical Antarctic conditions. Only an additional 21–46 h below PSC temperatures and in sunlight would have been necessary to reduce ozone to near zero locally.
    Description: International Multidisciplinary Drifting Observatory for the Study of the Arctic Climate (MOSAiC)
    Keywords: ddc:551.5 ; ddc:551.9
    Language: English
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  • 17
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    Determination of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl in Geological Reference Materials and Chondrites by Isotope Dilution ICP-MS (2020)
    Details
    Publication Date: 2022-11-28
    Description: Mass fractions of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl were determined via isotope dilution quadrupole ICP-MS in twenty-one geological reference materials (RMs) and the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3). The RMs comprise basaltic/mafic (BCR-2, BE-N, BHVO-1, BHVO-2, BIR-1, BRP-1, JB-2, OKUM, W-2, WS-E), intermediate/felsic (AGV-2, G-2, JA-2, RGM-1), ultramafic (DTS-2b, MUH-1, PCC-1, UB-N) and sedimentary (MAG-1, OU-6) rocks. Pressure digestion was applied for nonbasaltic samples to ensure effective sample digestion. For basaltic RMs, hot plate digestion was found to be sufficient for a quantitative recovery of the target elements. To minimise interferences and increase ion beam intensities during isotope ratio analyses by ICP-MS, separation of the target elements was carried out from single sample aliquots using a novel anion exchange procedure. The intermediate precision (2s) estimated from two to four replicate analyses was usually 〈 4% and results are in agreement with literature data, where available. Especially for Ag and Tl, the intermediate precision was compromised, likely due to low ion beam intensities and, hence, higher background and blank contributions. For ultramafic RMs, nugget effects and incomplete digestion might compromise the intermediate precision. Results for the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3) agree well with previously reported data.
    Keywords: ddc:551.9 ; isotope dilution ; chalcophile elements ; geological reference materials ; chondrites ; Q-ICP-MS
    Language: English
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    Chemical Geodynamics Insights From a Machine Learning Approach (2022)
    Details
    Publication Date: 2022-12-07
    Description: The radiogenic isotope heterogeneity of oceanic basalts is often assessed using 2D isotope ratio diagrams. But because the underlying data are at least six dimensional (87Sr/86Sr, 143Nd/144Nd, 176Hf/177Hf, and 208,207,206Pb/204Pb), it is important to examine isotopic affinities in multi‐dimensional data space. Here, we apply t‐distributed stochastic neighbor embedding (t‐SNE), a multi‐variate statistical data analysis technique, to a recent compilation of radiogenic isotope data of mid ocean ridge (MORB) and ocean island basalts (OIB). The t‐SNE results show that the apparent overlap of MORB‐OIB data trends in 2‐3D isotope ratios diagrams does not exist in multi‐dimensional isotope data space, revealing that there is no discrete “component” that is common to most MORB‐OIB mantle sources on a global scale. Rather, MORB‐OIB sample stochastically distributed small‐scale isotopic heterogeneities. Yet, oceanic basalts with the same isotopic affinity, as identified by t‐SNE, delineate several globally distributed regional domains. In the regional geodynamic context, the isotopic affinity of MORB and OIB is caused by capturing of actively upwelling mantle by adjacent ridges, and thus melting of mantle with similar origin in on, near, and off‐ridge settings. Moreover, within a given isotopic domain, subsidiary upwellings rising from a common deep mantle root often feed OIB volcanism over large surface areas. Overall, the t‐SNE results define a fundamentally new basis for relating isotopic variations in oceanic basalts to mantle geodynamics, and may launch a 21st century era of “chemical geodynamics.”
    Description: Plain Language Summary: The isotopic heterogeneity of basalts erupted at mid ocean ridges (MORB) and ocean islands (OIB) reflects the chemical evolution of Earth's mantle. The visual inspection of various 2D isotope ratio diagrams has fueled a four decade‐long discussion whether basalt heterogeneity reflects melting of only a small number of mantle components, and in particular, whether the apparent overlap of local data trends in global 2D isotope ratio diagrams indicates that melting of a common mantle component contributes to most MORB‐OIB. Here, we use multi‐variate statistical data analysis to show that the apparent overlap of MORB‐OIB data trends in 2D isotope ratio diagrams does not exist in multi‐dimensional isotope data space. Our finding invalidates any inference made for mantle compositional evolution based on the previously proposed existence of a common mantle component, its potential nature or distribution within the mantle. Rather, global MORB‐OIB sample small‐scale isotopic heterogeneities that are distributed stochastically in the Earth's mantle. Yet, MORB‐OIB with the same isotopic affinity, as identified by our multi‐variate data analysis, delineate several globally distributed regional domains. Within the regional geodynamic context, this discovery forms a fundamentally new basis for relating isotopic variations in MORB‐OIB to mantle geodynamics.
    Description: Key Points: Multi‐variate statistical data analysis (t‐distributed stochastic neighbor embedding) identifies global Sr‐Nd‐Hf‐Pb isotopic affinities of oceanic basalts. There is no “common mantle component;” rather, global mid ocean ridge‐ocean island basalts sample stochastically distributed small‐scale isotopic heterogeneities. Globally distributed regional domains of isotopically alike oceanic lavas define a new basis for relating isotopic variations to geodynamics.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711
    Description: DAAD, German Academic Exchange Service
    Description: https://doi.org/10.25625/0SVW6S
    Description: https://doi.org/10.25625/BQENGN
    Keywords: ddc:551.9 ; mantle heterogeneity ; MORB ; OIB ; geodynamics ; t‐SNE ; radiogenic isotopes ; machine learning
    Language: English
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    Probability Distributions of Radiocarbon in Open Linear Compartmental Systems at Steady‐State (2022)
    Details
    Publication Date: 2022-06-26
    Description: Radiocarbon (14C) is commonly used as a tracer of the carbon cycle to determine how fast carbon moves between different reservoirs such as plants, soils, rivers, or oceans. However such studies mostly emphasize the mean value (as Δ14C) of an unknown probability distribution. We introduce a novel algorithm to compute Δ14C distributions from knowledge of the age distribution of carbon in linear compartmental systems at steady‐state. Our results demonstrate that the shape of the distributions might differ according to the speed of cycling of ecosystem compartments and their connectivity within the system, and might contain multiple peaks and long tails. The distributions are also sensitive to the variations of Δ14C in the atmosphere over time, as influenced by the counteracting anthropogenic effects of fossil‐fuel emissions (14C‐free) and nuclear weapons testing (excess 14C). Lastly, we discuss insights that such distributions can offer for sampling and design of experiments aiming to capture the precise variance of Δ14C values present in the multi‐compartmental ecosystems.
    Description: Plain Language Summary: Radiocarbon (14C) is a radioactive isotope of carbon prominent in environmental sciences for tracing the dynamics of ecosystems, especially as recent changes in atmospheric radiocarbon allow tracking excess 14C created by nuclear weapons testing in the atmosphere on timescales shorter than what can be determined using radioactive decay. For climate change mitigation, a crucial uncertainty is the time carbon captured through photosynthesis spends in ecosystems before being released. For this purpose, radiocarbon can be valuable as a biological tracer; however, it is necessary to accurately link the real age of carbon and its radiocarbon age, as they usually differ. Forests and soils are open systems, connecting components with intrinsically different cycling timescales, so that the mean age comes from an age distribution that is usually unknown. Here, we developed an algorithm to compute the 14C contents for models consisting of multiple interconnected carbon pools. Our approach offers more accurate estimations of the mean 14C content of the system and computations of the distribution of 14C within the system at different points in time. Results obtained from this method can provide additional insights on the dynamics of the carbon cycle in multiple compartments, and can help to better interpret observations.
    Description: Key Points: Probability distributions of radiocarbon in ecosystem compartments can be derived from carbon age distributions. The shape of these distributions vary according to the speed of carbon cycling and the year of observation. Probability distributions of radiocarbon provide insights to study carbon dynamics and to interpret radiocarbon data.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Max‐Planck‐Gesellschaft (MPG) http://dx.doi.org/10.13039/501100004189
    Description: https://doi.org/10.5281/zenodo.6373329
    Keywords: ddc:551.9
    Language: English
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    Multi‐Band Raman Analysis of Radiation Damage in Zircon for Thermochronology: Partial Annealing and Mixed Signals (2022)
    Details
    Publication Date: 2022-06-24
    Description: Four zircon Raman bands were previously calibrated to give consistent estimates of the accumulated self‐irradiation α‐dose in unannealed volcanic samples. Partial annealing of radiation damage produces inconsistent values because of differences in the relative annealing sensitivities. The damage estimates based on the external rotation band (DER) at ∼356 cm−1 and that based on the ν2(SiO4) band (D2) at ∼438 cm−1 are the most and least sensitive to damage annealing. The D2/DER‐ratio thus provides a numerical estimate of the extent of geologic annealing that a zircon sample has experienced. This ratio characterizes the thermal history of a zircon sample but also its state of radiation damage during the course of its geologic history, and thus the manner in which this state influences other thermochronologic methods. Meaningful interpretation of the zircon Raman age requires that the spectra are free of measurement artifacts. The major artifacts result from micrometer‐scale gradients of the damage densities within a zircon grain due to uranium and thorium zoning. The micrometer‐sized sampled volume may span different densities, producing overlapping spectra, causing apparent peak broadening, overestimated damage densities, and zircon Raman ages. The D3/D2‐ratio of the damage densities calculated from the ν3(SiO4) and ν2(SiO4) bands, most and least affected by overlap, is an efficient indicator of a meaningless signal. It reveals overlap in annealed and unannealed samples, because the used bands have similar responses to annealing. Multi‐band Raman maps can be converted to damage‐ratio maps for screening zircon mounts, and selecting spots for thermochronologic investigations.
    Description: Plain Language Summary: Radioactive processes cause damage to the lattice of zircon crystals. This damage can be measured with a Raman instrument. Such measurements are important for methods determining the ages and thermal histories of zircon grains in rocks. Thus, the Raman measurements must be reliable and meaningful. This work proposes tools for detecting effects that hinder the interpretation of zircon Raman data. These effects are mixed signals and loss of damage due to exposure to elevated temperatures in the geologic environment. Zircon Raman spectra have different bands that respond differently to mixed signals and temperature. The ratio of the damage estimates from the least and most temperature‐sensitive bands thus indicates partial annealing. Raman spectra of zoned zircons often straddle areas with different lattice damage. Their overlapping signals cause artificial band broadening, and a damage overestimation. The ratio of the damage estimated from the least and the most affected bands identifies mixed signals and allows to reject unsuitable samples. The damage ratios can also be plotted in maps for damage screening and for selecting optimal spots for measurements.
    Description: Key Points: Annealing and inhomogeneous damage are two main factors hindering radiation‐damage estimation for zircon Raman dating. Comparison of internal and external Raman bandwidths allows to detect partial annealing of radiation damage in zircon. Comparison of internal Raman bandwidths allows to detect artifactual broadening in zoned zircon.
    Description: Studienstiftung des Deutschen Volkes (Studienstiftung) http://dx.doi.org/10.13039/501100004350
    Description: http://dx.doi.org/10.25532/OPARA-155
    Keywords: ddc:549 ; ddc:551.9
    Language: English
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    Electrochemical Properties of Peat Particulate Organic Matter on a Global Scale: Relation to Peat Chemistry and Degree of Decomposition (2022)
    Details
    Publication Date: 2022-06-22
    Description: Methane production in peatlands is controlled by the availability of electron acceptors for microbial respiration, including peat dissolved organic matter (DOM) and particulate organic matter (POM). Despite the much larger mass of POM in peat, knowledge on the ranges of its electron transfer capacities—electron accepting capacity (EAC), and electron donating capacity (EDC)—is scarce in comparison to DOM and humic and fulvic acids. Moreover, it is unclear how peat POM chemistry and decomposition relate to its EAC and EDC. To address these knowledge gaps, we compiled peat samples with varying carbon contents from mid to high latitude peatlands and analyzed their EACPOM and EDCPOM, element ratios, decomposition indicators, and relative amounts of molecular structures as derived from mid infrared spectra. Peat EACPOM and EDCPOM are smaller (per gram carbon) than EAC and EDC of DOM and terrestrial and aquatic humic and fulvic acids and are highly variable within and between sites. Both are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. Element ratio‐based models failed to predict EACPOM and EDCPOM, while mid infrared spectra‐based models can predict peat EACPOM to a large extent, but not EDCPOM. We suggest a conceptual model that describes how vegetation chemistry and decomposition control polymeric phenol and quinone contents as drivers of peat EDCPOM and EACPOM. The conceptual model implies that we need mechanistic models or spatially resolved measurements to understand the variability in peat EDCPOM and EACPOM and thus its role in controlling methane formation.
    Description: Plain Language Summary: Peatlands accumulated large amounts of carbon via photosynthesis and slow decomposition of senesced plant material. Microorganisms within the peat form methane. For this reason, peatlands are important global sources of the greenhouse gas methane and therefore can contribute to climate change. In order to produce methane, the microorganisms have to transfer electrons between compounds in respiration processes. Only recently, it has been found that the peat itself can reversibly transfer electrons and that its capacities to reversibly accept electron accepting capacity (EAC) and reversibly donate electron donating capacity (EDC) electrons are large. We investigated which conditions favor large or small EAC and EDC of peat so that we can better explain methane formation. We argue that vegetation and decomposition control the amount of phenols and quinones—molecules in the peat that presumably are responsible for most of the peat's EAC and EDC. The EAC and EDC probably are largest for peat formed from vegetation rich in quinones and phenols, such as shrubs, and smaller for other vegetation types, for example, certain mosses. Intense decomposition may reduce both the EAC and EDC.
    Description: Key Points: Peat particulate organic matter electron accepting and donating capacities per grams of carbon are smaller than for humic and fulvic acids. Both capacities are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. We explain these patterns with parent vegetation chemistry and conditions during decomposition.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: CAS | Youth Innovation Promotion Association (YIPA) http://dx.doi.org/10.13039/501100012492
    Description: https://github.com/henningte/redoxpeat
    Keywords: ddc:551.9
    Language: English
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    BEST PRACTICE GUIDELINE Measurement of carbon dioxide, methane and nitrous oxide fluxes between soil-vegetation-systems and the atmosphere using non-steady state chambers (2022)
    Arbeitsgruppe Bodengase, Deutsche Bodenkundliche Gesellschaft | Göttingen
    Details
    Publication Date: 2022-06-23
    Description: This Best Practice Guideline was been initiated by the Working Group Soil Gases (AG Bodengase) of the German Soil Science Society (Deutsche Bodenkundliche Gesellschaft). Our intention was to collect and aggregate the expertise of different working groups in our field. As a compendium, this guideline may help both beginners and experts to meet the practical and theoretical challenges of measuring soil gas fluxes with non-steady state chamber systems.
    Description: German Soil Science Society, Working Group Soil Gases
    Description: manual
    Keywords: ddc:631.4
    Language: English
    Type: doc-type:book
    Format: 70
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    Thermolab: A Thermodynamics Laboratory for Nonlinear Transport Processes in Open Systems (2022)
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    Publication Date: 2022-06-28
    Description: We developed a numerical thermodynamics laboratory called “Thermolab” to study the effects of the thermodynamic behavior of nonideal solution models on reactive transport processes in open systems. The equations of the state of internally consistent thermodynamic data sets are implemented in MATLAB functions and form the basis for calculating Gibbs energy. A linear algebraic approach is used in Thermolab to compute Gibbs energy of mixing for multicomponent phases to study the impact of the nonideality of solution models on transport processes. The Gibbs energies are benchmarked with experimental data, phase diagrams, and other thermodynamic software. Constrained Gibbs minimization is exemplified with MATLAB codes and iterative refinement of composition of mixtures may be used to increase precision and accuracy. All needed transport variables such as densities, phase compositions, and chemical potentials are obtained from Gibbs energy of the stable phases after the minimization in Thermolab. We demonstrate the use of precomputed local equilibrium data obtained with Thermolab in reactive transport models. In reactive fluid flow the shape and the velocity of the reaction front vary depending on the nonlinearity of the partitioning of a component in fluid and solid. We argue that nonideality of solution models has to be taken into account and further explored in reactive transport models. Thermolab Gibbs energies can be used in Cahn‐Hilliard models for nonlinear diffusion and phase growth. This presents a transient process toward equilibrium and avoids computational problems arising during precomputing of equilibrium data.
    Description: Plain Language Summary: The behavior of Earth materials, rocks, minerals, melts, fluids, and gases is important to predict physical processes in the Earth with computer models. The purpose of this is to study how the changes of variables such as fluid and solid composition influence the diffusion, fluid flow, and reaction in rocks. Here, we present a set of computer codes, called Thermolab, to calculate important physical properties such as density and chemical composition of solids, fluids, and melts in chemical equilibrium. The calculations are based on the Gibbs energy that exists for every material. We use computer codes, written in MATLAB/OCTAVE language, to show how this Gibbs energy is calculated and used to compute chemical equilibrium and find the physical properties such as density and chemical composition. We discuss techniques for accurate calculation of chemical equilibrium and physical properties in real rocks. Finally, we use Thermolab to formulate a computer model of fluids reacting with rocks. We find that chemical composition of the fluid and rock strongly affects the speed and shape of the boundary between reacted and unreacted rock. Thermolab can be used in phase growth models to investigate the way in which rocks develop toward equilibrium.
    Description: Key Points: Thermolab: a set of MATLAB codes is presented to perform equilibrium and nonequilibrium thermodynamic calculations. Local thermodynamic equilibrium is used to study effects of nonideality of solution models on nonlinear transport processes. Nonlinear diffusion processes are investigated with Thermolab providing a transient natural physical process toward equilibrium.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Russian Ministry of Science and Higher Education
    Description: https://hansjcv.github.io/Thermolab/
    Description: https://doi.org/10.5281/zenodo.6383253
    Keywords: ddc:551.9 ; ddc:541.36
    Language: English
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    Toward Reconciling Radiocarbon Production Rates With Carbon Cycle Changes of the Last 55,000 Years (2022)
    Details
    Publication Date: 2022-06-28
    Description: Since it is currently not understood how changes in 14C production rate (Q), and in the carbon cycle, can be combined to explain the reconstructed atmospheric Δ14C record, we discuss possible reasons for this knowledge gap. Reviewing the literature, we exclude that changes in the content of atoms in the atmosphere, which produce cosmogenic 14C after being hit by galactic cosmic rays, might be responsible for parts of the observed differences. When combining Q with carbon cycle changes, one needs to understand the changes in the atmospheric 14C inventory, which are partially counterintuitive. For example, during the Last Glacial Maximum, Δ14C was ∼400‰ higher compared with preindustrial times, but the 14C inventory was 10% smaller. Some pronounced changes in atmospheric Δ14C do not correspond to any significant changes in the atmospheric 14C inventory, since CO2 was changing simultaneously. Using two conceptually different models (BICYCLE‐SE and LSG‐OGCM), we derive hypothetical Qs by forcing the models with identical atmospheric CO2 and Δ14C data. Results are compared with the most recent data‐based estimates of Q derived from cosmogenic isotopes. Millennial‐scale climate change connected to the bipolar seesaw is missing in the applied models, which might explain some, but probably not all, of the apparent model‐data disagreement in Q. Furthermore, Q based on either data from marine sediments or ice cores contains offsets, suggesting an interpretation deficit in the current data‐based approaches.
    Description: Key Points: No important change found in the level of precursor material, which produces cosmogenic radiocarbon after being hit by galactic cosmic rays. Transient changes in the bipolar seesaw are needed in applied carbon cycle models to improve interpretation of the radiocarbon cycle. Sediment core‐ and ice core‐based radiocarbon production rates differ systematically, suggesting missing processes.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Swedish Research Concil
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: https://doi.org/10.1594/PANGAEA.871273
    Description: https://www.ncdc.noaa.gov/paleo-search/study/31772
    Description: https://doi.org/10.1594/PANGAEA.914500
    Description: https://www.iceandclimate.nbi.ku.dk/data/
    Description: https://doi.org/10.1594/PANGAEA.932965
    Keywords: ddc:551.9
    Language: English
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    Precipitation and Lake Water Evaporation Recorded by Terrestrial and Aquatic n‐Alkane δ2H Isotopes in Lake Khar Nuur, Mongolia (2022)
    Details
    Publication Date: 2022-06-28
    Description: The compound‐specific hydrogen isotopic composition (δ2H) of n‐alkanes is a valuable proxy to investigate hydrological conditions in lake sediments. While terrestrial n‐alkanes reflect the isotopic signal of the local precipitation, aquatic n‐alkanes incorporate the isotopic signal of the lake's water, which can be strongly modulated by evaporative enrichment. So far, the spatial distribution of the terrestrial and aquatic δ2H signal within lakes have not systematically been investigated. Here, we present compound‐specific δ2H results of terrestrial (δ2HC31) and aquatic (δ2HC23) n‐alkanes of surface sediment samples from Lake Khar Nuur, a semi‐arid and high‐altitude lake in the Mongolian Altai, and additionally investigate the δ2H signal of topsoils from the catchment. Our results show that the majority of the n‐alkane δ2H values from the catchment topsoils correspond well with modeled local growing season precipitation (JJAS). However, few samples in the northern catchment show more positive δ2H values possibly due to increased evapo(transpi)ration by southward exposition and shallower soils there. The only small variability of δ2HC31 in the surface sediments is in the range of most topsoils δ2H from the catchment, and thus, well reflects local growing season precipitation. δ2HC23 in surface sediment samples from the central and deepest parts of the lake, that is, the lake's sediment accumulation zones, shows distinctly more positive δ2HC23 values due to evaporative lake water enrichment. Consequently, Δaq‐terr, which is the isotopic offset between δ2HC23 and δ2HC31, indicates distinct lake water enrichment in the lake's accumulation zones and is a valuable proxy to investigate past hydrological changes.
    Description: Key Points: The hydrogen isotopic composition of terrestrial C31 n‐alkanes reflects the local growing season precipitation at Lake Khar Nuur. Aquatic C23 n‐alkanes incorporate the isotopic signal of the lake's water, which is strongly modulated by evaporative enrichment. The isotopic offset between C23 and C31 is a valuable proxy for evaporation in the lake and past hydrological changes in the catchment.
    Description: https://doi.pangaea.de/10.1594/PANGAEA.940115
    Keywords: ddc:551.9
    Language: English
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    Microbially promoted calcite precipitation in the pelagic redoxcline: Elucidating the formation of the turbid layer (2022)
    Details
    Publication Date: 2022-10-12
    Description: Large bell‐shaped calcite formations called “Hells Bells” were discovered underwater in the stratified cenote El Zapote on the Yucatán Peninsula, Mexico. Together with these extraordinary speleothems, divers found a white, cloudy turbid layer into which some Hells Bells partially extend. Here, we address the central question if the formation of the turbid layer could be based on microbial activity, more specifically, on microbially induced calcite precipitation. Metagenomic and metatranscriptomic profiling of the microbial community in the turbid layer, which overlaps with the pelagic redoxcline in the cenote, revealed chemolithoautotrophic Hydrogenophilales and unclassified β‐Proteobacteria as the metabolic key players. Bioinformatic and hydrogeochemical data suggest chemolithoautotrophic oxidation of sulfide to zero‐valent sulfur catalyzed by denitrifying organisms due to oxygen deficiency. Incomplete sulfide oxidation via nitrate reduction and chemolithoautotrophy are both proton‐consuming processes, which increase the pH in the redoxcline favoring authigenic calcite precipitation and may contribute to Hells Bells growth. The observed mechanism of microbially induced calcite precipitation is potentially applicable to many other stagnant sulfate‐rich water bodies.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: CONACYT‐FONCICYT‐DADC
    Description: https://doi.org/10.11588/data/TMYLWS
    Description: https://doi.org/10.11588/data/GYLDH5
    Keywords: ddc:551.9
    Language: English
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    Geostandards and Geoanalytical Research Bibliographic Review 2020 (2022)
    Weis, Ulrike ; Stoll, Brigitte ; Förster, Michael W. ; [et al.]
    Details
    Publication Date: 2022-10-19
    Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image
    Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).
    Keywords: ddc:551.9
    Language: English
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    A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride (2022)
    Details
    Publication Date: 2022-08-04
    Description: Due to their availability, low cost, nontoxicity, and tunability, polymeric carbon nitrides (CNx) represent one of the most attractive materials classes for the development of fully sustainable photo(electro)catalytic systems for solar‐driven water splitting. However, the development of CNx‐based photoanodes for visible light‐driven water oxidation to dioxygen is rather challenging, particularly due to issues related to photoelectrode stability and effective coupling of the light absorber with water oxidation catalysts. Herein, a triadic photoanode comprising a porous TiO2 electron collector scaffold sensitized by CNx coupled to a molecular cobalt polyoxometalate (CoPOM = [Co4(H2O)2(PW9O34)2]10) catalyst is reported. Complete water oxidation to dioxygen under visible (λ 〉 420 nm) light irradiation is demonstrated, with photocurrents down to relatively low bias potentials (0.2 V vs RHE). Furthermore, polyethyleneimine (PEI), a cationic polymer is shown to act as an effective and non‐sacrificial electrostatic linker for immobilization of the anionic CoPOM onto the negatively charged surface of CNx. The optimized deposition of CoPOM using the PEI linker translates directly into improved efficiency of the transfer of photogenerated holes to water molecules and to enhanced oxygen evolution. This work thus provides important design rules for effective immobilization of POM‐based catalysts into soft‐matter photoelectrocatalytic architectures for light‐driven water oxidation.
    Description: A triadic photoanode comprised of a porous TiO2 electron collector scaffold sensitized by polymeric carbon nitride and coupled to a molecular cobalt polyoxometalate (CoPOM) catalyst exhibits visible (λ 〉 420 nm) light‐driven water oxidation to dioxygen. The beneficial role of the cationic polyethyleneimine polymer as an effective electrostatic linker for immobilization of CoPOM onto carbon nitride is highlighted.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Vector Stiftung http://dx.doi.org/10.13039/501100013912
    Keywords: ddc:551.9
    Language: English
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    Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany (2022)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
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    Application of mixed‐effects modelling and rule‐based models to explain copper variation in soil profiles of southern Germany (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-10-01
    Description: Copper (Cu) is an essential element for plants and microorganisms and at larger concentrations a toxic pollutant. A number of factors controlling Cu dynamics have been reported, but information on quantitative relationships is scarce. We aimed to (i) quantitatively describe and predict soil Cu concentrations (CuAR) in aqua regia considering site‐specific effects and effects of pH, soil organic carbon (SOC) and cation exchange capacity (CEC), and (ii) study the suitability of mixed‐effects modelling and rule‐based models for the analysis of long‐term soil monitoring data. Thirteen uncontaminated long‐term monitoring soil profiles in southern Germany were analysed. Since there was no measurable trend of increasing CuAR concentrations with time in the respective depth ranges of the sites, data from different sampling dates were combined and horizon‐specific regression analyses including model simplifications were carried out for 10 horizons. Fixed‐ and mixed‐effects models with the site as a random effect were useful for the different horizons and significant contributions (either of main effects or interactions) of SOC, CEC and pH were present for 9, 8 and 7 horizons, respectively. Horizon‐specific rule‐based cubist models described the CuAR data similarly well. Validations of cubist models and mixed‐effects models for the CuAR concentrations in A horizons were successful for the given population after random splitting into calibration and validation samples, but not after independent validations with random splitting according to sites. Overall, site, CEC, SOC and pH provide important information for a description of CuAR concentrations using the different regression approaches. Highlights: Information on quantitative relationships for factors controlling Cu dynamics is scarce. Site, CEC, SOC and pH provide important information for a description of Cu concentrations. Validations of cubist models and mixed‐effects models for A horizons were successful for a closed population of sites.
    Description: Bavarian State Ministry of the Environment and Consumer Protection http://dx.doi.org/10.13039/501100010219
    Description: Ministry of Agriculture and Environment Mecklenburg‐Western Pomerania
    Keywords: ddc:631.4
    Language: English
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    Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons (2022)
    de Graaf, Stefan ; Vonhof, Hubert B. ; Reijmer, John J. G. ; [et al.]
    Details
    Publication Date: 2022-10-01
    Description: Internal water in cold‐water and tropical coral skeletons was extracted and measured for its oxygen and hydrogen isotope ratios. Water was extracted by crushing pieces of coral hard tissue in a percussion device connected to either a cavity ring‐down spectroscopy (CRDS) system or an isotope ratio mass spectrometry (IRMS) system. Despite most samples yielding sufficient water, each analytical system produces distinct isotope patterns. Experiments show that several characteristics specific to biominerals give rise to discrepancies and analytical artefacts that preclude the acquisition of reproducible isotope data. The main complication is that internal water in biogenic carbonates is distributed in an open interconnected micro‐network that readily exchanges with external water and potentially facilitates interaction with hydration water in the finely dispersed organic matrix in the coral skeleton. Furthermore, only an isotopically fractionated part of the internal water is released from the coral skeletons upon crushing. Altogether, isotope ratio measurement of internal water in corals with bulk crushing techniques does not give primary fluid isotope ratios useful for (palaeo‐)environmental or microbiological studies. As the resulting isotope patterns can show systematic behaviour per technique, isotope data may be erroneously interpreted to reflect the original calcifying fluid when using only a single technique to isotopically characterise internal fluids in coral skeletons.
    Description: Key Points: Free water trapped inside coral skeletons was extracted and isotopically analyzed on two commonly used techniques for fluid inclusion isotope analysis. Measured oxygen and hydrogen isotope ratios do not reproduce between the techniques due to several analytical artefacts. The water extracted from coral skeletons is not of primary origin.
    Description: Nederlandse Organisatie voor Wetenschappelijk Onderzoek http://dx.doi.org/10.13039/501100003246
    Description: Western Indian Ocean Marine Science Association http://dx.doi.org/10.13039/501100009106
    Keywords: ddc:551.9
    Language: English
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    Benthic Carbon Remineralization and Iron Cycling in Relation to Sea Ice Cover Along the Eastern Continental Shelf of the Antarctic Peninsula (2022)
    Details
    Publication Date: 2022-10-04
    Description: Rapid and profound climatic and environmental changes have been predicted for the Antarctic Peninsula with so far unknown impact on the biogeochemistry of the continental shelves. In this study, we investigate benthic carbon sedimentation, remineralization and iron cycling using sediment cores retrieved on a 400 mile transect with contrasting sea ice conditions along the eastern shelf of the Antarctic Peninsula. Sediments at comparable water depths of 330–450 m showed sedimentation and remineralization rates of organic carbon, ranging from 2.5 to 13 and 1.8–7.2 mmol C m−2 d−1, respectively. Both rates were positively correlated with the occurrence of marginal sea ice conditions (5%–35% ice cover) along the transect, suggesting a favorable influence of the corresponding light regime and water column stratification on algae growth and sedimentation rates. From south to north, the burial efficiency of organic carbon decreased from 58% to 27%, while bottom water temperatures increased from −1.9 to −0.1°C. Net iron reduction rates, as estimated from pore‐water profiles of dissolved iron, were significantly correlated with carbon degradation rates and contributed 0.7%–1.2% to the total organic carbon remineralization. Tightly coupled phosphate‐iron recycling was indicated by significant covariation of dissolved iron and phosphate concentrations, which almost consistently exhibited P/Fe flux ratios of 0.26. Iron efflux into bottom waters of 0.6–4.5 μmol Fe m−2 d−1 was estimated from an empirical model. Despite the deep shelf waters, a clear bentho‐pelagic coupling is indicated, shaped by the extent and duration of marginal sea ice conditions during summer, and likely to be affected by future climate change.
    Description: Plain Language Summary: The seafloor of the shallow shelf seas plays a significant role in the recycling of organic carbon and acts as a nutrient source for algae growth in the upper water layers. In Antarctic waters, the change in sea ice cover has a great impact on the growth of algae and the subsequent sinking of organic carbon to the seafloor. With global warming, profound changes in sea ice cover are expected for the Antarctic Peninsula. To better understand its imprint on the seafloor, we collected sediment samples from different locations along the eastern shelf of the Antarctic Peninsula and measured how changes in sea ice cover influence the accumulation and recycling of organic carbon. We found that moderate sea ice cover of 5%–35% increases the amount of organic carbon received by the seafloor and that the fraction that is buried in the sediments decreases from south (58%) to north (27%). We further measured that more iron, an important micro‐nutrient for algae growth, can be released from the seafloor the more organic carbon accumulates. Thus, sea ice conditions determine the organic carbon accumulation, turnover, and nutrient release at the seafloor, which are likely to be affected by future climate change.
    Description: Key Points: Antarctic shelf sediments underlying marginal sea ice cover exhibit high sedimentation and remineralization rates of organic carbon. A high degree of sedimentary Fe‐recycling is found which scales with organic carbon remineralization rates. Coupling between P and Fe recycling is observed with a constant P/Fe flux ratio of 0.26 for sediments with high Fe and P recycling rates.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research http://dx.doi.org/10.13039/501100003207
    Description: https://doi.org/10.1594/PANGAEA.942455
    Keywords: ddc:551.9
    Language: English
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    Millimetre scale aeration of the rhizosphere and drilosphere (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-10-04
    Description: Soil aeration is a critical factor for oxygen‐limited subsoil processes, as transport by diffusion and advection is restricted by the long distance to the free atmosphere. Oxygen transport into the soil matrix is highly dependent on its connectivity to larger pore channels like earthworm and root colonised biopores. Here we hypothesize that the soil matrix around biopores represents different connectivity depending on biopore genesis and actual coloniser. We analysed the soil pore system of undisturbed soil core samples around biopores generated or colonised by roots and earthworms and compared them with the pore system of soil, not in the immediacy of a biopore. Oxygen partial pressure profiles and gas relative diffusion was measured in the rhizosphere and drilosphere from the biopore wall into the bulk soil with microelectrodes. The measurements were linked with structural features such as porosity and connectivity obtained from X‐ray tomography and image analysis. Aeration was enhanced in the soil matrix surrounding biopores in comparison to the bulk soil, shown by higher oxygen concentrations and higher relative diffusion coefficients. Biopores colonised by roots presented more connected lateral pores than earthworm colonised ones, which resulted in enhanced aeration of the rhizosphere compared to the drilosphere. This has influenced biotic processes (microbial turnover/mineralization or root respiration) at biopore interfaces and highlights the importance of microstructural features for soil processes and their dependency on the biopore's coloniser.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:631.4
    Language: English
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    Arctic – Atlantic Exchange of the Dissolved Micronutrients Iron, Manganese, Cobalt, Nickel, Copper and Zinc With a Focus on Fram Strait (2022)
    Details
    Publication Date: 2022-10-04
    Description: The Arctic Ocean is considered a source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the gateway of Fram Strait (FS). However, there is a paucity of trace element data from across the Arctic Ocean gateways, and so it remains unclear how Arctic and North Atlantic exchange shapes micronutrient availability in the two ocean basins. In 2015 and 2016, GEOTRACES cruises sampled the Barents Sea Opening (GN04, 2015) and FS (GN05, 2016) for dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn). Together with the most recent synopsis of Arctic‐Atlantic volume fluxes, the observed trace element distributions suggest that FS is the most important gateway for Arctic‐Atlantic dissolved micronutrient exchange as a consequence of Intermediate and Deep Water transport. Combining fluxes from FS and the Barents Sea Opening with estimates for Davis Strait (GN02, 2015) suggests an annual net southward flux of 2.7 ± 2.4 Gg·a−1 dFe, 0.3 ± 0.3 Gg·a−1 dCo, 15.0 ± 12.5 Gg·a−1 dNi and 14.2 ± 6.9 Gg·a−1 dCu from the Arctic toward the North Atlantic Ocean. Arctic‐Atlantic exchange of dMn and dZn were more balanced, with a net southbound flux of 2.8 ± 4.7 Gg·a−1 dMn and a net northbound flux of 3.0 ± 7.3 Gg·a−1 dZn. Our results suggest that ongoing changes to shelf inputs and sea ice dynamics in the Arctic, especially in Siberian shelf regions, affect micronutrient availability in FS and the high latitude North Atlantic Ocean.
    Description: Plain Language Summary: Recent studies have proposed that the Arctic Ocean is a source of micronutrients such as dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn) to the North Atlantic Ocean. However, data at the Arctic Ocean gateways including Fram Strait and the Barents Sea Opening have been missing to date and so the extent of Arctic micronutrient transport toward the Atlantic Ocean remains unquantified. Here, we show that Fram Strait is the most important gateway for Arctic‐Atlantic micronutrient exchange which is a result of deep water transport at depths 〉500 m. Combined with a flux estimate for Davis Strait, this study suggests that the Arctic Ocean is a net source of dFe, dNi and dCu, and possibly also dCo, toward the North Atlantic Ocean. Arctic‐Atlantic dMn and dZn exchange seems more balanced. Properties in the East Greenland Current showed substantial similarities to observations in the upstream Central Arctic Ocean, indicating that Fram Strait may export micronutrients from Siberian riverine discharge and shelf sediments 〉3,000 km away. Increasing Arctic river discharge, permafrost thaw and coastal erosion, all consequences of ongoing climate change, may therefore alter future Arctic Ocean micronutrient transport to the North Atlantic Ocean.
    Description: Key Points: Fram Strait is the major gateway for Arctic‐Atlantic exchange of the dissolved micronutrients Fe, Mn, Co, Ni, Cu and Zn. The Arctic is a net source of dissolved Fe, Co, Ni and Cu to the Nordic Seas and toward the North Atlantic; Mn and Zn exchange are balanced. Waters of the Central Arctic Ocean, including the Transpolar Drift, are the main drivers of gross Arctic micronutrient export.
    Description: German Research Foundation
    Description: Netherlands Organization for Scientific Research
    Description: https://doi.pangaea.de/10.1594/PANGAEA.859558
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871030
    Description: https://doi.pangaea.de/10.1594/PANGAEA.868396
    Description: https://doi.pangaea.de/10.1594/PANGAEA.905347
    Description: https://dataportal.nioz.nl/doi/10.25850/nioz/7b.b.jc
    Description: https://doi.pangaea.de/10.1594/PANGAEA.933431
    Description: https://www.bco-dmo.org/dataset/718440
    Description: https://doi.org/10.1594/PANGAEA.936029
    Description: https://doi.org/10.1594/PANGAEA.936027
    Description: https://doi.pangaea.de/10.1594/PANGAEA.927429
    Keywords: ddc:551.9
    Language: English
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    Growth of microaerophilic Fe(II)‐oxidizing bacteria using Fe(II) produced by Fe(III) photoreduction (2022)
    Details
    Publication Date: 2022-06-17
    Description: Iron(II) (Fe(II)) can be formed by abiotic Fe(III) photoreduction, particularly when Fe(III) is organically complexed. Light‐influenced environments often overlap or even coincide with oxic or microoxic geochemical conditions, for example, in sediments. So far, it is unknown whether microaerophilic Fe(II)‐oxidizing bacteria are able to use the Fe(II) produced by Fe(III) photoreduction as electron donor. Here, we present an adaption of the established agar‐stabilized gradient tube approach in comparison with liquid cultures for the cultivation of microaerophilic Fe(II)‐oxidizing microorganisms by using a ferrihydrite‐citrate mixture undergoing Fe(III) photoreduction as Fe(II) source. We quantified oxygen and Fe(II) gradients with amperometric and voltammetric microelectrodes and evaluated microbial growth by qPCR of 16S rRNA genes. We showed that gradients of dissolved Fe(II) (maximum Fe(II) concentration of 1.25 mM) formed in the gradient tubes when incubated in blue or UV light (400–530 nm or 350–400 nm). Various microaerophilic Fe(II)‐oxidizing bacteria (Curvibacter sp. and Gallionella sp.) grew by oxidizing Fe(II) that was produced in situ by Fe(III) photoreduction. Best growth for these species, based on highest gene copy numbers, was observed in incubations using UV light in both liquid culture and gradient tubes containing 8 mM ferrihydrite‐citrate mixtures (1:1), due to continuous light‐induced Fe(II) formation. Microaerophilic Fe(II)‐oxidizing bacteria contributed up to 40% to the overall Fe(II) oxidation within 24 h of incubation in UV light. Our results highlight the potential importance of Fe(III) photoreduction as a source of Fe(II) for Fe(II)‐oxidizing bacteria by providing Fe(II) in illuminated environments, even under microoxic conditions.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Ministerium für Wissenschaft, Forschung und Kunst Baden‐Württemberg http://dx.doi.org/10.13039/501100003542
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:579.317 ; ddc:551.9
    Language: English
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    Simulated Future Trends in Marine Nitrogen Fixation Are Sensitive to Model Iron Implementation (2022)
    Details
    Publication Date: 2022-06-17
    Description: Biological nitrogen fixation is an important oceanic nitrogen source, potentially stabilizing marine fertility in an increasingly stratified and nutrient‐depleted ocean. Iron limitation of low latitude primary producers has been previously demonstrated to affect simulated regional ecosystem responses to climate warming or nitrogen cycle perturbation. Here we use three biogeochemical models that vary in their representation of the iron cycle to estimate change in the marine nitrogen cycle under a high CO2 emissions future scenario (RCP8.5). The first model neglects explicit iron effects on biology (NoFe), the second utilizes prescribed, seasonally cyclic iron concentrations and associated limitation factors (FeMask), and the third contains a fully dynamic iron cycle (FeDyn). Models were calibrated using observed fields to produce near‐equivalent nutrient and oxygen fits, with productivity ranging from 49 to 75 Pg C yr−1. Global marine nitrogen fixation increases by 71.1% with respect to the preindustrial value by the year 2100 in NoFe, while it remains stable (0.7% decrease in FeMask and 0.3% increase in FeDyn) in explicit iron models. The mitigation of global nitrogen fixation trend in the models that include a representation of iron originates in the Eastern boundary upwelling zones, where the bottom‐up control of iron limitation reduces export production with warming, which shrinks the oxygen deficient volume, and reduces denitrification. Warming‐induced trends in the oxygen deficient volume in the upwelling zones have a cascading effect on the global nitrogen cycle, just as they have previously been shown to affect tropical net primary production.
    Description: Plain Language Summary: Phytoplankton need nutrients to grow. Two of those nutrients are nitrogen and iron. Climate change projections suggest that in the future there could be less nitrogen supplied to the surface ocean, which might reduce phytoplankton growth. Less phytoplankton growth could impact a wide range of ocean services, like fishing and fossil carbon draw‐down. However, some phytoplankton have the ability to add “new” nitrogen to the surface ocean directly from the atmosphere. In this study, we explore how this biological fixation of new nitrogen might change into the future using three models. These models differ in how iron is represented, but all do equally well in representing the observed nutrient and oxygen distribution. Biological nitrogen fixation slightly decreases with climate change in the very complex iron model and the moderately complex iron model, but it increases strongly (by more than 70% by the year 2100) in the model that does not include iron effects on biology. Our study addresses the importance of iron models and how they can change our view of how the ocean responds to climate change.
    Description: Key Points: Models performing similarly with respect to global NO3, PO4, and O2 distributions yield diverse responses in marine N2 fixation to warming. Marine N2 fixation trends are sensitive to whether iron limits primary production in upwelling regions, for example, the Eastern Tropical Pacific.
    Description: Helmholtz Research School for Ocean System Science and Technology
    Description: New Zealand Ministry of Business, Innovation and Employment
    Description: https://data.geomar.de/downloads/20.500.12085/673e7de0-20ab-4dd3-afe9-c4bfb00b1faf/
    Keywords: ddc:551.9
    Language: English
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    The Effect of Land Use Classification on the Gas‐Phase and Particle Composition of the Troposphere: Tree Species Versus Forest Type Information (2022)
    Details
    Publication Date: 2022-06-17
    Description: Relationships between vegetation and air quality are intricate and still not fully understood. For regional air quality assessments, a better understanding of the diverse feedback mechanisms is crucial. The present article investigates the impact of land use data set detailedness on air quality predictions. Therefore, two different land use data sets were applied for simulations with COSMO‐MUSCAT for Germany in May 2014. One data set includes detailed information about tree species while the second one obtains generalized widely applied land use classes including mixed and coniferous forests. Moreover, we examined the role of agricultural NO soil emissions, agricultural biomass density enhancements, and model resolution. For a more comprehensive implementation of the secondary organic aerosol (SOA) formation, the SOA module was extended considering additional biogenic volatile organic compound (BVOC) precursor groups from isoprene, α‐pinene, limonene, and sesquiterpene oxidations. The model studies showed substantial differences in BVOC emission patterns between the two land use data sets. The application of detailed tree species information leads to complex BVOC emission patterns with high emission spots. In contrast, coarser forest information lead to standardized comprehensive emissions which result in 50% higher BVOC emissions. These differences affect both the atmospheric oxidizing potential and the production rates of SOA precursors. Land use induced regional differences (tree species minus forest information) in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%) concentrations, and SOA (−60%) mass are modeled. Overall, the simulations demonstrate that detailed land use information, extended organic chemistry treatment, and high spatial resolution are mandatory for air quality assessments.
    Description: Plain Language Summary: Trees are associated with being the lungs of the atmosphere as they filter out harmful substances from the air, they store CO2, and produce oxygen via photosynthesis. Other by‐products of photosynthesis are biogenic volatile organic compounds (BVOCs). BVOCs are chemical substances with a high vapor pressure already at room temperatures, so they quickly evaporate from the leaves into the surrounding air and are responsible for the characteristic forest smell. The amount and composition of BVOC emissions strongly depend on the tree species. Every plant has its own distinct emission properties. The chemical degradation of BVOCs impacts the chemical composition of the troposphere and is connected to ground level ozone production and the formation of secondary organic aerosols (SOA), contributing substantially to particulate matter (PM). On a global scale, standardized BVOC emission information on forest levels are often used, but for regional air quality assessments detailed plant specific information is crucial, but still often lacking. Therefore, two different land use data sets were applied in the present study to investigate the impact of standardized forest versus detailed tree‐species information for Germany in May 2014. The study reveals changes in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%), and SOA (−60%) concentrations.
    Description: Key Points: Detail of land use data sets crucial for biogenic volatile organic compound emission strength and composition. Composition and concentration variation of these organic compounds induce changes in regional air quality predictions. Detailed land use information, extended organic matter treatment, and high‐resolution simulations are mandatory for air quality assessments.
    Description: Deutsche Bundesstiftung Umwelt (DBU) http://dx.doi.org/10.13039/100007636
    Description: https://doi.org/10.5281/zenodo.4783106
    Description: http://ebas.nilu.no/
    Keywords: ddc:551.5 ; ddc:551.9
    Language: English
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    Effects of the Hydrous Domain in the Mantle Wedge on Magma Formation and Mixing at the Northeast Lau Spreading Center, SW Pacific (2022)
    Details
    Publication Date: 2022-08-09
    Description: Abundant volcanic activity occurs in the back‐arc region of the northern Tofua island arc where the Northeast Lau Spreading Center (NELSC) propagates southwards into older crust causing the formation of numerous seamounts at the propagating rift tip. An off‐axis volcanic diagonal ridge (DR) occurs at the eastern flank of the NELSC, linking the large rear‐arc volcano Niuatahi with the NELSC. New geochemical data from the NELSC, the southern propagator seamounts, and DR reveal that the NELSC lavas are tholeiitic basalts whereas the rear‐arc volcanoes typically erupt lavas with boninitic composition. The sharp geochemical boundary probably reflects the viscosity contrast between off‐axis hydrous harzburgitic mantle and dry fertile mantle beneath the NELSC. The new data do not indicate an inflow of Samoa plume mantle into the NELSC, confirming previously published He isotope data. The NELSC magmas form by mixing of an enriched and a depleted Indian Ocean‐type upper mantle end‐member implying a highly heterogeneous upper mantle composition in this area. Most NELSC lavas are little affected by a slab component implying that melting is adiabatic beneath the spreading center. The DR lavas show the influence of a component from the subducted Louisville Seamount Chain, which was previously thought to be restricted to the nearby arc volcanoes Niuatoputapu and Tafahi. This signature is rarely detected along the NELSC implying little mixing of melts from the low‐viscosity hydrous portion of the mantle wedge beneath the rear‐arc volcanoes into the melting region of the dry mantle beneath the NELSC.
    Description: Plain Language Summary: Volcanic activity is abundant at subduction zones and the chemical analysis of the erupted rocks allows to determine the material transport in the Earth's mantle. The Northeast Lau Spreading Center (NELSC) forms by extension and volcanism behind the northern Tofua island arc. Several large volcanic structures occur east of the NELSC and the lavas of these off‐axis volcanoes are chemically and isotopically distinct implying little mixing with the magmas of the NELSC. The differences suggest decompression melting of relatively dry mantle beneath the NELSC whereas the off‐axis volcanoes reflect melting of water‐rich mantle affected by fluids from the subducting Pacific Plate. The sharp geochemical boundary between the NELSC and off‐axis volcanoes is probably due to a large viscosity contrast between hydrous harzburgitic mantle and dry fertile mantle. Element and isotope ratios indicate that the NELSC magmas form by mixing of enriched and depleted portions of the upper mantle, and we do not find evidence for inflow of the Samoa deep mantle plume from the north. Some of the off‐axis lavas contain a component from a volcanic chain that was subducted some 4 million years ago and that was previously only known in two volcanoes of the Tofua island arc.
    Description: Key Points: Variably enriched mantle sources melt beneath the Northeast Lau Spreading Center (NELSC) but there is no evidence for Samoa mantle plume inflow. Relatively dry fertile mantle beneath NELSC causes sharp geochemical boundary with hydrous harzburgitic North Tonga mantle wedge. Subducted Louisville Seamount Chain material affects rear‐arc volcanism.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.21 ; ddc:551.116 ; ddc:551.9
    Language: English
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  • 39
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    Responses of soil organic carbon, aggregate diameters, and hydraulic properties to long‐term organic and conventional farming on a Vertisol in India (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-08-09
    Description: Organic matter management can improve soil structural properties. This is crucial for agricultural soils in tropical regions threatened by high rainfall intensities. Compared to conventional farming, organic farming is usually deemed to increase organic carbon and improve soil structural properties such as stability and permeability. However, how much, if any, buildup of organic carbon is possible or indeed occurring also depends on soil type and environmental factors. We compared the impact of seven years of organic farming (annually 13.6 t ha−1 of composted manure) with that of conventional practices (2 t ha−1 of farmyard manure with 150–170 kg N ha−1 of mineral fertilizers) on soil structural properties. The study was conducted on a Vertisol in India with a two‐year crop rotation of cotton soybean wheat. Despite large differences in organic amendment application, organic carbon was not significantly different at 9.6 mg C g−1 on average in the topsoil. However, the size distribution of water‐stable aggregates shifted toward more aggregates 〈137 μm in the organic systems. Cumulative water intake was lower compared to the conventional systems, leading to higher runoff and erosion. These changes might be related to the lower pH and higher exchangeable sodium in the organic systems. Our results indicate that higher application of organic amendments did not lead to higher soil organic carbon and associated improvement in soil structures properties compared to integrated fertilization in this study. Chemical properties may dominate soil aggregation retarding the uptake and integration of organic amendments for sustainable agricultural intensification in tropical, semiarid climates.
    Description: Biovision Foundation for Ecological Development http://dx.doi.org/10.13039/501100015593
    Description: Coop Sustainability Fund
    Description: Swiss Agency for Development and Cooperation (SDC)
    Description: Foundation fiat panis http://dx.doi.org/10.13039/501100011087
    Description: Liechtenstein Development Service http://dx.doi.org/10.13039/501100015698
    Description: https://doi.org/10.6084/m9.figshare.18665612
    Keywords: ddc:631.4
    Language: English
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  • 40
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    Collisional mixing between inner and outer solar system planetesimals inferred from the Nedagolla iron meteorite (2021)
    Details
    Publication Date: 2022-07-28
    Description: The ungrouped iron meteorite Nedagolla is the first meteorite with bulk Mo, Ru, and Ni isotopic compositions that are intermediate between those of the noncarbonaceous (NC) and carbonaceous (CC) meteorite reservoirs. The Hf‐W chronology of Nedagolla indicates that this mixed NC–CC isotopic composition was established relatively late, more than 7 Myr after solar system formation. The mixed NC–CC isotopic composition is consistent with the chemical composition of Nedagolla, which combines signatures of metal segregation under more oxidizing conditions (relative depletions in Mo and W), characteristic for CC bodies, and more reducing conditions (high Si and Cr contents), characteristic for some NC bodies, in a single sample. These data combined suggest that Nedagolla formed as the result of collisional mixing of NC and CC core material, which partially re‐equilibrated with silicate mantle material that predominantly derives from the NC body. These mixing processes might have occurred during a hit‐and‐run collision between two differentiated bodies, which also provides a possible pathway for Nedagolla's extreme volatile element depletion. As such, Nedagolla provides the first isotopic evidence for early collisional mixing of NC and CC bodies that is expected as a result of Jupiter's growth.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.9 ; ddc:549.112
    Language: English
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  • 41
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    Response of subsoil organic matter contents and physical properties to long‐term, high‐rate farmyard manure application (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-07-26
    Description: Application of farmyard manure (FYM) is common practice to improve physical and chemical properties of arable soil and crop yields. However, studies on effects of FYM application mainly focussed on topsoils, whereas subsoils have rarely been addressed so far. We, therefore, investigated the effects of 36‐year FYM application with different rates of annual organic carbon (OC) addition (0, 469, 938 and 1875 g C m−2 a−1) on OC contents of a Chernozem in 0–30 cm (topsoil) and 35–45 cm (subsoil) depth. We also investigated its effects on soil structure and hydraulic properties in subsoil. X‐ray computed tomography was used to analyse the response of the subsoil macropore system (≥19 μm) and the distribution of particulate organic matter (POM) to different FYM applications, which were related to contents in total OC (TOC) and water‐extractable OC (WEOC). We show that FYM‐C application of 469 g C m−2 a−1 caused increases in TOC and WEOC contents only in the topsoil, whereas rates of ≥938 g C m−2 a−1 were necessary for TOC enrichment also in the subsoil. At this depth, the subdivision of TOC into different OC sources shows that most of the increase was due to fresh POM, likely by the stimulation of root growth and bioturbation. The increase in subsoil TOC went along with increases in macroporosity and macropore connectivity. We neither observed increases in plant‐available water capacity nor in unsaturated hydraulic conductivity. In conclusion, only very high application of FYM over long periods can increase OC content of subsoil at our study site, but this increase is largely based on fresh, easily degradable POM and likely accompanied by high C losses when considering the discrepancy between OC addition rate by FYM and TOC response in soil. Highlights A new image processing procedure to distinguish fresh and decomposed POM. The increase of subsoil C stock based to a large extend on fresh, labile POM. Potential of arable subsoils for long‐term C storage by large FYM application rates is limited. The increase in TOC has no effect on hydraulic properties of the subsoil.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:631.4
    Language: English
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