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  • 551.9  (18)
  • English  (18)
  • Russian
  • 2020-2023
  • 2020-2022  (18)
  • 1990-1994
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  • 2020-2023
  • 2020-2022  (18)
  • 1990-1994
  • 2010-2014  (20)
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  • 1
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    Evolution of Magmatism in the New Hebrides Island Arc and in Initial Back-Arc Rifting, SW Pacific (2021)
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    Publication Date: 2021-07-26
    Description: We present new geochemical and isotopic data for rock samples from two island arc volcanoes, Erromango and Vulcan Seamount, and from a 500 m thick stratigraphic profile of lava flows exposed on the SW flank of Vate Trough back-arc rift of the New Hebrides Island Arc (NHIA). The basalts from the SW rift flank of Vate Trough have ages of ~0.5 Ma but are geochemically similar to those erupting along the active back-arc rift. The weak subduction component in the back-arc basalts implies formation by decompression melting during early rifting and rifting initiation by tectonic processes rather than by lithosphere weakening by arc magma. Melting beneath Vate Trough is probably caused by chemically heterogeneous and hot mantle that flows in from the North Fiji Basin in the east. The melting zone beneath Vate Trough back-arc is separate from that of the arc front, but a weak slab component suggests fluid transport from the slab. Immobile incompatible element ratios in South NHIA lavas overlap with those of the Vate Trough depleted back-arc basalts, suggesting that enriched mantle components are depleted by back-arc melting during mantle flow. The slab component varies from hydrous melts of subducted sediments in the Central NHIA to fluids from altered basalts in the South NHIA. The volcanism of Erromango shows constant compositions for 5 million years, that is, there is no sign for variable depletion of the mantle or for a change of slab components due to collision of the D'Entrecasteaux Ridge as in lava successions further north.
    Keywords: 551.9 ; subduction zone ; back-arc basalt ; sediment subduction
    Language: English
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  • 2
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    Sampling soil water along the pF curve for δ2H and δ18O analysis (2021)
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    Publication Date: 2021-07-23
    Description: Soil water stable isotopes are widely used across disciplines (e.g., hydrology, ecology, soil science, and biogeochemistry). However, the full potential of stables isotopes as a tool for characterizing the origin, flow path, transport processes and residence times of water in different eco-, hydro-, and geological compartments has not yet been exploited. This is mainly due to the large variety of different methods for pore water extraction. While recent work has shown that matric potential affects the equilibrium fractionation, little work has examined how different water retention characteristics might affect the sampled water isotopic composition. Here, we present a simple laboratory experiment with two well-studied standard soils differing in their physico-chemical properties (e.g., clayey loam and silty sand). Samples were sieved, oven-dried and spiked with water of known isotopic composition to full saturation. For investigating the effect of water retention characteristics on the extracted water isotopic composition, we used pressure extractors to sample isotopically labelled soil water along the pF curve. After pressure extraction, we further extracted the soil samples via cryogenic vacuum extraction. The null hypothesis guiding our work was that water held at different tensions shows the same isotopic composition. Our results showed that the sampled soil water differed isotopically from the introduced isotopic label over time and sequentially along the pF curve. Our and previous studies suggest caution in interpreting isotope results of extracted soil water and a need to better characterize processes that govern isotope fractionation with respect to soil water retention characteristics. In the future, knowledge about soil water retention characteristics with respect to soil water isotopic composition could be applied to predict soil water fractionation effects under natural and non-stationary conditions. In this regard, isotope retention characteristics as an analog to water retention characteristics have been proposed as a way forward since matric potential affects the equilibrium fractionation between the bound water and the water vapour.
    Keywords: 551.9 ; pF value ; soil water isotopes ; soil water pool ; δ2H and δ18O analysis
    Language: English
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  • 3
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    Cryptic metasomatic agent measured in situ in Variscan mantle rocks: Melt inclusions in garnet of eclogite, Granulitgebirge, Germany (2021)
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    Publication Date: 2021-07-26
    Description: Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.
    Keywords: 551.9 ; clinopyroxenite ; eclogite ; melt inclusions ; metasomatism ; orogenic peridotite
    Language: English
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  • 4
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    The Preparation and Preliminary Characterisation of Three Synthetic Andesite Reference Glass Materials (ARM-1, ARM-2, ARM-3) for In Situ Microanalysis (2021)
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    Publication Date: 2021-07-27
    Description: Three synthetic reference glasses were prepared by directly fusing and stirring 3.8 kg of high-purity oxide powders to provide reference materials for microanalytical work. These glasses have andesitic major compositions and are doped with fifty-four trace elements in nearly identical abundance (500, 50, 5 µg g−1) using oxide powders or element solutions, and are named ARM-1, 2 and 3, respectively. We further document that sector-field (SF) ICP-MS (Element 2 or Element XR) is capable of sweeping seventy-seven isotopes (from 7Li to 238U, a total of sixty-eight elements) in 1 s and, thus, is able to quantify up to sixty-eight elements by laser sampling. Micro- and bulk analyses indicate that the glasses are homogeneous with respect to major and trace elements. This paper provides preliminary data for the ARM glasses using a variety of analytical techniques (EPMA, XRF, ICP-OES, ICP-MS, LA-Q-ICP-MS and LA-SF-ICP-MS) performed in ten laboratories. Discrepancies in the data of V, Cr, Ni and Tl exist, mainly caused by analytical limitations. Preliminary reference and information values for fifty-six elements were calculated with uncertainties [2 relative standard error (RSE)] estimated in the range of 1–20%.
    Keywords: 551.9 ; glass reference materials ; microanalysis ; sector-field ICP-MS ; LA-ICP-MS ; multiple-element quantification
    Language: English
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  • 5
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    Implications of Reactions Between SO2 and Basaltic Glasses for the Mineralogy of Planetary Crusts (2021)
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    Publication Date: 2021-07-27
    Description: Basalts are ubiquitous in volcanic systems on several planetary bodies, including the Earth, Mars, Venus, and Jupiter's moon Io, and are commonly associated with sulfur dioxide (SO2) degassing. We present the results of an experimental study of reactions between SO2 and basaltic glasses. We examined Fe-free basalt, and Fe-bearing tholeiitic and alkali basalts with a range of Fe3+/Fetotal (0.05 to 0.79) that encompass the oxygen fugacities proposed for most terrestrial planetary bodies. Tholeiitic and alkali basalts were exposed to SO2 at 600, 700, and 800 °C for 1 hr and 24 hr. Surface coatings formed on the reacted basalts; these contain CaSO4, MgSO4, Na2SO4, Na2Ca(SO4)2, Fe2O3, Fe3O4, Fe-Ti-(Al)-oxides, and TiO2. Additionally, the SO2-basalt reaction drives nucleation of crystalline phases in the substrate to form pyroxenes and possible Fe-oxides. A silica-rich layer forms between the substrate and sulfate coatings. More oxidized basalts may readily react with SO2 to form coatings dominated by large Ca-sulfate and oxide grains. On less oxidized basalts (NNO−1.5 to NNO−5), reactions with SO2 will form thin, fine-grained aggregates of sulfates; such materials are less readily detected by spectroscopy and spectrometry techniques. In contrast, in very reduced basalts (lower than NNO−5), typical of the Moon and Mercury, SO2 is typically a negligible component in the magmatic gas, and sulfides are more likely.
    Keywords: 552.26 ; 551.9 ; gas-solid reaction ; sulfur dioxide ; planetary crust ; sulfate ; volcanology ; geochemistry
    Language: English
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  • 6
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    NanoSr – A New Carbonate Microanalytical Reference Material for In Situ Strontium Isotope Analysis (2021)
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    Publication Date: 2021-07-23
    Description: The in situ measurement of Sr isotopes in carbonates by MC-ICP-MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well-characterised carbonate reference materials for Sr mass fractions 〉 1000 µg g−1 are available, there is a lack of well-characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g−1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution-based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP-MS in different laboratories. The 87Sr/86Sr ratio was determined by well-established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA-MC-ICP-MS, which resulted in 87Sr/86Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low-Sr, low-REE carbonate samples. NanoSr is available from the corresponding author.
    Keywords: 551.9 ; strontium isotopes ; laser ablation ; reference material ; calcium carbonate ; nanopowder ; MC-ICP-MS
    Language: English
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  • 7
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    Intercalibration of Mg Isotope Delta Scales and Realisation of SI Traceability for Mg Isotope Amount Ratios and Isotope Delta Values (2021)
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    Publication Date: 2021-07-21
    Description: The continuous improvement of analytical procedures using multi-collector technologies in ICP-mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM-AE143, ERM-AE144, ERM-AE145, IRMM-009 and NIST SRM 980 were cross-calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ25/24Mg values and less than 0.037‰ for the δ26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM-AE143 anchors all magnesium δ-scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM-AE144 and ERM-AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θapp, the fractionation relationship ln α(25/24Mg)/ln α(26/24Mg).
    Keywords: 551.9 ; delta scale ; traceability ; scale anchor ; absolute isotope ratio ; comparability ; triple isotope fractionation
    Language: English
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  • 8
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    Near-Complete Local Reduction of Arctic Stratospheric Ozone by Severe Chemical Loss in Spring 2020 (2021)
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    Publication Date: 2021-09-27
    Description: In the Antarctic ozone hole, ozone mixing ratios have been decreasing to extremely low values of 0.01–0.1 ppm in nearly all spring seasons since the late 1980s, corresponding to 95–99% local chemical loss. In contrast, Arctic ozone loss has been much more limited and mixing ratios have never before fallen below 0.5 ppm. In Arctic spring 2020, however, ozonesonde measurements in the most depleted parts of the polar vortex show a highly depleted layer, with ozone loss averaged over sondes peaking at 93% at 18 km. Typical minimum mixing ratios of 0.2 ppm were observed, with individual profiles showing values as low as 0.13 ppm (96% loss). The reason for the unprecedented chemical loss was an unusually strong, long-lasting, and cold polar vortex, showing that for individual winters the effect of the slow decline of ozone-depleting substances on ozone depletion may be counteracted by low temperatures.
    Keywords: 551.9 ; ozone ; stratosphere ; ozone loss ; Arctic ; ozone hole ; temperature
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  • 9
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    Vortex-Wide Detection of Large Aspherical NAT Particles in the Arctic Winter 2011/12 Stratosphere (2021)
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    Publication Date: 2021-09-27
    Description: Micron-sized HNO3-containing particles in polar stratospheric clouds are known to denitrify the polar winter stratosphere and support chemical ozone loss. We show that populations of nitric acid trihydrate (NAT) particles with volume-equivalent median radii of 3–7 μm can be detected vortex-wide by means of infrared limb sounding. Key for detection are the applied optical characteristics of highly aspherical particles consisting of the β-NAT phase. Spectroscopic signatures and ambient conditions of detected populations show that these particles play a key role in denitrification of the Arctic winter stratosphere. Complementary gas-phase HNO3 observations indicate collocated highly efficient HNO3 sequestration within days and are consistent with measured spectral signals of populations of large NAT particles. High amounts of condensed gas-phase equivalent HNO3 exceeding 10 ppbv and long persistence of detected populations, despite expected gravitational settling, imply that our understanding of the particles is incomplete.
    Keywords: 551.9 ; polar winter ; stratosphere ; denitrification ; nitric acid trihydrate ; infrared limb sounding
    Language: English
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  • 10
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    Sources of Uncertainty in Regional and Global Terrestrial CO2 Exchange Estimates (2021)
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    Publication Date: 2021-09-27
    Description: The Global Carbon Budget 2018 (GCB2018) estimated by the atmospheric CO 2 growth rate, fossil fuel emissions, and modeled (bottom-up) land and ocean fluxes cannot be fully closed, leading to a “budget imbalance,” highlighting uncertainties in GCB components. However, no systematic analysis has been performed on which regions or processes contribute to this term. To obtain deeper insight on the sources of uncertainty in global and regional carbon budgets, we analyzed differences in Net Biome Productivity (NBP) for all possible combinations of bottom-up and top-down data sets in GCB2018: (i) 16 dynamic global vegetation models (DGVMs), and (ii) 5 atmospheric inversions that match the atmospheric CO 2 growth rate. We find that the global mismatch between the two ensembles matches well the GCB2018 budget imbalance, with Brazil, Southeast Asia, and Oceania as the largest contributors. Differences between DGVMs dominate global mismatches, while at regional scale differences between inversions contribute the most to uncertainty. At both global and regional scales, disagreement on NBP interannual variability between the two approaches explains a large fraction of differences. We attribute this mismatch to distinct responses to El Niño–Southern Oscillation variability between DGVMs and inversions and to uncertainties in land use change emissions, especially in South America and Southeast Asia. We identify key needs to reduce uncertainty in carbon budgets: reducing uncertainty in atmospheric inversions (e.g., through more observations in the tropics) and in land use change fluxes, including more land use processes and evaluating land use transitions (e.g., using high-resolution remote-sensing), and, finally, improving tropical hydroecological processes and fire representation within DGVMs.
    Keywords: 551.9 ; atmospheric inversions ; global carbon budget ; dynamic global vegetation models ; carbon cycle
    Language: English
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  • 11
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    Seasonality of Organic Matter Degradation Regulates Nutrient and Metal Net Fluxes in a High Energy Sandy Beach (2021)
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    Publication Date: 2021-10-12
    Description: During seawater circulation in permeable intertidal sands, organic matter degradation alters the composition of percolating fluids and remineralization products discharge into surficial waters. Concurrently, coastal seawater nutrient and organic matter composition change seasonally due to variations in pelagic productivity. To assess seasonal changes in organic matter degradation in the intertidal zone of a high energy beach (Spiekeroog Island, southern North Sea, Germany), we analyzed shallow pore waters for major redox constituents (oxygen [O2], manganese [Mn], and iron [Fe]) and inorganic nitrogen species (nitrite [NO2−], nitrate [NO3−], and ammonium [NH4+]) in March, August, and October. Surface water samples from a local time series station were used to monitor seasonal changes in pelagic productivity. O2 and NO3− were the dominating pore water constituents in March and October. Dissolved Mn, Fe, and NH4+ were more widely distributed in August. Seasonal changes in seawater temperature as well as organic matter and nitrate supply by seawater were assumed to affect microbial rates and degradation pathways. Pore water and seawater variability led to seasonally changing constituent effluxes to surface waters. Mn, Fe, and NH4+ effluxes are minimal in March and reached their maximum in August. Furthermore, the intertidal sands switched from a net dissolved inorganic nitrogen sink in March to a net source in August. In conclusion, seasonal effects on intertidal pore water biogeochemistry affect constituent fluxes across the sediment-water interface. The seasonality of the beach bioreactor must be considered when fluxes are extrapolated to annual timescales.
    Keywords: 551.9 ; submarine groundwater discharge ; subterranean estuary ; oxygen ; nitrogen ; manganese ; iron
    Language: English
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  • 12
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    Could oxalate-extractable phosphorus replace phosphorus fractionation schemes in soil phosphorus prospections?—A case study in the prehistoric Milseburg hillfort (Germany) (2021)
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    Publication Date: 2021-10-14
    Description: A geoarchaeological soil phosphorus (P) prospection is used to identify a gate within the prehistoric rampart of the Milseburg hillfort (Hesse, Germany). This study compares the application of a P fractionation scheme and P extraction with ammonium-oxalate. We hypothesized that oxalate-extractable P (P-ox) and the related degree of P saturation (DPS) could replace the more expensive and time-consuming fractionation schemes for geoarchaeological investigations. Comparing the results, the P fractionation helped to verify the existence of another section of the prehistoric ramparts and to identify the location of a gate within it. It also helped to discover the archaeologically relevant soil depths in the investigated area. This information could not be retrieved from the P-ox data alone. Soil P-ox contents and DPS values are relatively unspecific with regard to prehistoric land use. However, DPS at least indicates settled versus unsettled areas. Still, the results of the P fractionation more clearly delineate Iron Age land use areas including settlement, non-settlement, rampart, and rampart gap (probable gate). Thus, in geoarchaeological contexts, this method seems to be preferable to a singular P-ox extraction. However, for better results, P-ox determination could be integrated into a P fractionation scheme.
    Keywords: 551.9 ; 631.4 ; Milseburg ; oxalate-extractable phosphorus ; phosphorus fractionation ; phosphorus saturation ; soil phosphorus prospection
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  • 13
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    How Important is Denitrification in Riparian Zones? Combining End-Member Mixing and Isotope Modeling to Quantify Nitrate Removal from Riparian Groundwater (2021)
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    Publication Date: 2021-10-14
    Description: Riparian zones are important buffer zones for streams as they are hotspots of nitrate transformation and removal in agricultural catchments. However, mixing of water from different sources and various transformation processes can complicate the quantification of nitrate turnover in riparian zones. In this study, we analyzed nitrate concentration and isotope data in riparian groundwater along a 2-km stream section in central Germany. We developed a mathematical model combining end-member mixing and isotope modeling to account for mixing of river water and groundwater and quantify nitrate transformation in riparian groundwater. This enabled us to explicitly determine the extent of denitrification (as process leading to permanent nitrate removal from riparian groundwater) and transient nitrate removal by additional processes associated with negligible isotope fractionation (e.g., plant uptake and microbial assimilation) and to perform an extensive uncertainty analysis. Based on the nitrogen isotope data of nitrate, the simulations suggest a mean removal of up to 27% by additional processes and only about 12% by denitrification. Nitrate removal from riparian groundwater by additional processes exceeded denitrification particularly in winter and at larger distance from the river, underlining the role of the river as organic carbon source. This highlights that nitrate consumption by additional processes predominates at the field site, implying that a substantial fraction of agricultural nitrogen input is not permanently removed but rather retained in the riparian zone. Overall, our model represents a useful tool to better compare nitrogen retention to permanent nitrogen removal in riparian zones at various temporal and spatial scales.
    Keywords: 551.9 ; denitrification ; riparian zones ; nitrate ; isotope analysis ; mixing model ; eutrophication
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  • 14
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    Sediment Properties Drive Spatial Variability of Potential Methane Production and Oxidation in Small Streams (2021)
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    Publication Date: 2021-10-14
    Description: Emissions of the potent greenhouse gas methane (CH4) from streams and rivers are a significant component of global freshwater methane emissions. The distribution of CH4 production and oxidation within stream sections and in vertical sediment profiles is not well understood, and the environmental controls on CH4 production and emission in such systems create a significant challenge for assessing larger-scale dynamics. Here we investigate factors driving the spatial variability of sediment potential methane production (PMP) and potential methane oxidation (PMO) in a temperate stream network in Germany. PMP was highly variable, ranging from 5 × 10−4 to 28.58 μg CH4 gDW−1 d−1 and PMO ranged from 0.43 μg CH4 gDW−1 d−1 to 14.41 μg CH4 gDW−1 d−1. Important drivers of spatial variability of PMP and PMO in the sediments of the stream main-stem were related to fine sediment fraction and organic carbon content. At smaller spatial scale, that is, in a sub-catchment stream section, the drivers were more complex and included sediment nitrogen and organic carbon content, as well as porewater dissolved organic carbon, dissolved organic matter quality, and metal concentrations. As with reservoirs and impounded rivers, fine sediment deposition and organic carbon content were found to be key controls on the spatial variability of CH4 production and oxidation. These findings enhance our understanding of CH4 dynamics, improve the potential for identifying CH4 production hotspots in small streams, and provide a potential means for upscaling emission rates in larger-scale assessments.
    Keywords: 551.9 ; carbon cycle ; streams ; methane ; sediment ; porewater ; grain size
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  • 15
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    Stable Carbon Isotope Studies of CH4 Dynamics Via Water and Plant Pathways in a Tropical Thai Paddy: Insights Into Diel CH4 Transportation (2021)
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    Publication Date: 2021-10-14
    Description: Separate evaluation of methane (CH4) emission dynamics (e.g., oxidation, production, and transportation) at the soil-plant-atmosphere and soil-water-atmosphere interfaces has been limited in tropical rice paddies, but it is crucial for comprehending the entire CH4 cycles. We investigated CH4 oxidation, production, and transportation through plant and water pathways during the reproductive stage in a tropical Thailand rice paddy field using natural abundance carbon stable isotope ratios (δ13CH4 and δ13CO2). Mass balance equations using δ13CH4 and δ13CO2 in soil gases indicated that CH4 oxidation in the planted soil exceeded those in the interrow soil due to oxygen supply through rice roots. In addition, at 1–11 cm depth acetate fermentation was the dominant process in the planted soil, whereas in the interrow soil the dominant process was H2/CO2 reduction. The water pathway showed a significant negative correlation between CH4 flux and released δ13CH4 over 24 hr, driven by a diel change in episodic ebullition, steady ebullition, and diffusion, all due to diel changes in soil temperature and atmospheric pressure. In contrast, the plant pathway showed a significant positive relationship between CH4 flux and emitted δ13CH4 throughout one day. A comparison of the diel change in emitted δ13CH4 between the water and plant pathways showed that the rice plants transported CH4 in soil bubbles without any large isotopic fractionation. The diel change in the plant-mediated CH4 transportation was mainly controlled by diel changes in soil bubble expansion and CH4 diffusion through plants, which were probably regulated by diel changes in soil temperature and atmospheric pressure.
    Keywords: 551.9 ; CH4 ; carbon stable isotopes ; rice paddy ; plant pathway ; water pathway ; diel CH4 transportation
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  • 16
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    Influence of Ocean Circulation and Benthic Exchange on Deep Northwest Atlantic Nd Isotope Records During the Past 30,000 Years (2021)
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    Publication Date: 2021-10-01
    Description: Neodymium (Nd) isotopes extracted from authigenic sediment phases are increasingly used as a proxy for past variations in water mass provenance. To better constrain the controls of water mass provenance and nonconservative effects on the archived Nd isotope signal, we present a new depth transect of Nd isotope reconstructions from the Blake Bahama Outer Ridge along the North American continental margin covering the past 30 ka. We investigated five sediment cores that lie directly within the main flow path of the Deep Western Boundary Current, a major advection route of North Atlantic Deep Water. We found offsets between core tops and seawater Nd isotopic compositions that are observed elsewhere in the Northwest Atlantic. A possible explanation for this is the earlier suggested redistribution of sediment by nepheloid layers at intermediate as well as abyssal depths, transporting material downslope and along the continental margin. These processes potentially contributed to Nd isotope excursions recorded in Northwest Atlantic sediment cores during the Bølling-Allerød and early Holocene. An Atlantic-wide comparison of Nd isotope records shows that the early Holocene excursions had an additional contribution from conservative advection of unradiogenic dissolved Nd. Nevertheless, the trends of the Nd isotope records are in general agreement with previous reconstructions of water mass provenance from the entire Atlantic and also reveal millennial-scale changes during the last deglaciation in temporal high resolution, which have rarely been reported before. Further, the new records confirm that during cold periods the Northwest Atlantic was bathed by an increased contribution of southern sourced water.
    Keywords: 551.9 ; neodymium isotopes ; deglaciation ; water masses ; Last Glacial Maximum ; benthic exchange
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  • 17
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    Effects of Temperature and Light on Methane Production of Widespread Marine Phytoplankton (2021)
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    Publication Date: 2021-12-01
    Description: Methane (CH4) production in the ocean surface mixed layer is a widespread but still largely unexplained phenomenon. In this context marine algae have recently been described as a possible source of CH4 in surface waters. In the present study we investigated the effects of temperature and light intensity (including daylength) on CH4 formation from three widespread marine algal species Emiliania huxleyi, Phaeocystis globosa, and Chrysochromulina sp. Rates of E. huxleyi increased by 210% when temperature increased in a range from 10°C to 21.5°C, while a further increase in temperature (up to 23.8°C) showed reduction of CH4 production rates. Our results clearly showed that CH4 formation of E. huxleyi is controlled by light: When light intensity increased from 30 to 2,670 μmol m−2 s−1, CH4 emission rates increased continuously by almost 1 order of magnitude and was more than 1 order of magnitude higher when the daylength (light period) was extended from 6/18 hr light-dark cycle to continuous light. Furthermore, light intensity is also an important factor controlling CH4 emissions of Chrysochromulina sp. and P. globosa and could therefore be a species-independent regulator of phytoplankton CH4 production. Based on our results, we might conclude that extensive blooms of E. huxleyi could act as a main regional source of CH4 in surface water, since blooming of E. huxleyi is related to the seasonal increase in both light and temperature, which also stimulate CH4 production. Under typical global change scenarios, E. huxleyi will increase its CH4 production in the future.
    Keywords: 551.9 ; 557.7 ; marine phytoplacton ; CH4 production ; temperature influence ; light intensity influence ; daylength influence
    Language: English
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    Silicon Isotopes in an EMIC's Ocean: Sensitivity to Runoff, Iron Supply, and Climate (2021)
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    Publication Date: 2021-10-26
    Description: The isotopic composition of Si in biogenic silica (BSi), such as opal buried in the oceans' sediments, has changed over time. Paleorecords suggest that the isotopic composition, described in terms of δ30Si, was generally much lower during glacial times than today. There is consensus that this variability is attributable to differing environmental conditions at the respective time of BSi production and sedimentation. The detailed links between environmental conditions and the isotopic composition of BSi in the sediments remain, however, poorly constrained. In this study, we explore the effects of a suite of offset boundary conditions during the Last Glacial Maximum (LGM) on the isotopic composition of BSi archived in sediments in an Earth System Model of intermediate complexity (EMIC). Our model results suggest that a change in the isotopic composition of Si supply to the glacial ocean is sufficient to explain the observed overall low(er) glacial δ30Si in BSi. All other processes explored trigger model responses of either wrong sign or magnitude or are inconsistent with a recent estimate of bottom water oxygenation in the Atlantic Sector of the Southern Ocean. Caveats, mainly associated with generic uncertainties in today's pelagic biogeochemical modules, remain.
    Keywords: 551.9 ; 551.9 ; Earth System Model ; silicon isotopes ; Last Glacial Maximum ; biogeochemical modeling ; ocean ; sediment
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